HUE030197T2 - A continuous process for the production of vinyl chloride (co) polymers - Google Patents

A continuous process for the production of vinyl chloride (co) polymers Download PDF

Info

Publication number: HUE030197T2
Authority: HU; Hungary
Prior art keywords: reactor; polymerization; initiator; cstr; reactors
Prior art date: 2006-03-24

Application number

HUE07727089A

Other languages

English (en)

Hungarian (hu)

Inventor

Carolina Anna Maria Christina Dirix

Jong Johannes Jacobus Theodorus De

Lambertus Meulenbrugge

Koen Antoon Kornelis Vanduffel

Original Assignee

Akzo Nobel Chemicals Int Bv

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2006-03-24

Filing date

2007-03-20

Publication date

2017-04-28

2007-03-20 Application filed by Akzo Nobel Chemicals Int Bv filed Critical Akzo Nobel Chemicals Int Bv

2017-04-28 Publication of HUE030197T2 publication Critical patent/HUE030197T2/en

Links

229920001577 copolymer Polymers 0.000 title description 13
238000010924 continuous production Methods 0.000 title description 9
238000004519 manufacturing process Methods 0.000 title description 6
238000000034 method Methods 0.000 claims description 66
238000006116 polymerization reaction Methods 0.000 claims description 56
239000000178 monomer Substances 0.000 claims description 34
239000000725 suspension Substances 0.000 claims description 29
229920000642 polymer Polymers 0.000 claims description 14
238000010992 reflux Methods 0.000 claims description 11
238000002156 mixing Methods 0.000 claims description 6
QYUPYXHDDLXBET-UHFFFAOYSA-N 5-methyl-2,4-dioxopyrimidine-1-carbaldehyde Chemical compound CC1=CN(C=O)C(=O)NC1=O QYUPYXHDDLXBET-UHFFFAOYSA-N 0.000 claims 1
241000282836 Camelus dromedarius Species 0.000 claims 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
238000005054 agglomeration Methods 0.000 claims 1
230000002776 aggregation Effects 0.000 claims 1
229910052799 carbon Inorganic materials 0.000 claims 1
NCEXYHBECQHGNR-UHFFFAOYSA-N chembl421 Chemical compound C1=C(O)C(C(=O)O)=CC(N=NC=2C=CC(=CC=2)S(=O)(=O)NC=2N=CC=CC=2)=C1 NCEXYHBECQHGNR-UHFFFAOYSA-N 0.000 claims 1
230000000977 initiatory effect Effects 0.000 claims 1
238000005453 pelletization Methods 0.000 claims 1
241000894007 species Species 0.000 claims 1
239000003999 initiator Substances 0.000 description 83
238000006243 chemical reaction Methods 0.000 description 44
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 39
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
229920000915 polyvinyl chloride Polymers 0.000 description 12
239000004800 polyvinyl chloride Substances 0.000 description 12
229920002451 polyvinyl alcohol Polymers 0.000 description 11
150000002978 peroxides Chemical class 0.000 description 10
235000019422 polyvinyl alcohol Nutrition 0.000 description 10
238000010557 suspension polymerization reaction Methods 0.000 description 9
239000004372 Polyvinyl alcohol Substances 0.000 description 8
239000007900 aqueous suspension Substances 0.000 description 8
238000001816 cooling Methods 0.000 description 8
125000000914 phenoxymethylpenicillanyl group Chemical group CC1(S[C@H]2N([C@H]1C(=O)*)C([C@H]2NC(COC2=CC=CC=C2)=O)=O)C 0.000 description 8
238000011144 upstream manufacturing Methods 0.000 description 8
RPBWMJBZQXCSFW-UHFFFAOYSA-N 2-methylpropanoyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(=O)C(C)C RPBWMJBZQXCSFW-UHFFFAOYSA-N 0.000 description 7
239000006185 dispersion Substances 0.000 description 7
239000007788 liquid Substances 0.000 description 7
239000002904 solvent Substances 0.000 description 7
239000004615 ingredient Substances 0.000 description 6
IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 5
239000000203 mixture Substances 0.000 description 5
239000002245 particle Substances 0.000 description 5
238000003756 stirring Methods 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
239000002519 antifouling agent Substances 0.000 description 4
238000009826 distribution Methods 0.000 description 4
239000012071 phase Substances 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 3
238000012662 bulk polymerization Methods 0.000 description 3
238000007872 degassing Methods 0.000 description 3
230000000694 effects Effects 0.000 description 3
238000007720 emulsion polymerization reaction Methods 0.000 description 3
-1 ethylene, propylene, acrylonitrile Chemical class 0.000 description 3
239000011541 reaction mixture Substances 0.000 description 3
239000000243 solution Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
239000004094 surface-active agent Substances 0.000 description 3
MVELOSYXCOVILT-UHFFFAOYSA-N (4-hydroxy-2-methylpentan-2-yl) 7,7-dimethyloctaneperoxoate Chemical compound CC(O)CC(C)(C)OOC(=O)CCCCCC(C)(C)C MVELOSYXCOVILT-UHFFFAOYSA-N 0.000 description 2
241000251468 Actinopterygii Species 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
239000000654 additive Substances 0.000 description 2
239000003638 chemical reducing agent Substances 0.000 description 2
239000000084 colloidal system Substances 0.000 description 2
238000001035 drying Methods 0.000 description 2
239000012467 final product Substances 0.000 description 2
238000010528 free radical solution polymerization reaction Methods 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
239000006174 pH buffer Substances 0.000 description 2
239000000047 product Substances 0.000 description 2
230000001681 protective effect Effects 0.000 description 2
239000002994 raw material Substances 0.000 description 2
239000000376 reactant Substances 0.000 description 2
239000012966 redox initiator Substances 0.000 description 2
239000002002 slurry Substances 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
238000012546 transfer Methods 0.000 description 2
NOBYOEQUFMGXBP-UHFFFAOYSA-N (4-tert-butylcyclohexyl) (4-tert-butylcyclohexyl)oxycarbonyloxy carbonate Chemical compound C1CC(C(C)(C)C)CCC1OC(=O)OOC(=O)OC1CCC(C(C)(C)C)CC1 NOBYOEQUFMGXBP-UHFFFAOYSA-N 0.000 description 1
ALXYZXZBPNKYDD-UHFFFAOYSA-N 2,2-bis(2-ethylhexyl)-7,7-dimethyloctaneperoxoic acid Chemical compound CCCCC(CC)CC(CCCCC(C)(C)C)(CC(CC)CCCC)C(=O)OO ALXYZXZBPNKYDD-UHFFFAOYSA-N 0.000 description 1
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
GTJOHISYCKPIMT-UHFFFAOYSA-N 2-methylundecane Chemical group CCCCCCCCCC(C)C GTJOHISYCKPIMT-UHFFFAOYSA-N 0.000 description 1
NXVGUNGPINUNQN-UHFFFAOYSA-N 2-phenylpropan-2-yl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C1=CC=CC=C1 NXVGUNGPINUNQN-UHFFFAOYSA-N 0.000 description 1
SGVYKUFIHHTIFL-UHFFFAOYSA-N Isobutylhexyl Natural products CCCCCCCC(C)C SGVYKUFIHHTIFL-UHFFFAOYSA-N 0.000 description 1
YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
230000002411 adverse Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
238000010923 batch production Methods 0.000 description 1
NSGQRLUGQNBHLD-UHFFFAOYSA-N butan-2-yl butan-2-yloxycarbonyloxy carbonate Chemical compound CCC(C)OC(=O)OOC(=O)OC(C)CC NSGQRLUGQNBHLD-UHFFFAOYSA-N 0.000 description 1
MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000011161 development Methods 0.000 description 1
229940057404 di-(4-tert-butylcyclohexyl)peroxydicarbonate Drugs 0.000 description 1
239000002270 dispersing agent Substances 0.000 description 1
238000011143 downstream manufacturing Methods 0.000 description 1
238000004945 emulsification Methods 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
238000011049 filling Methods 0.000 description 1
239000000499 gel Substances 0.000 description 1
229910001385 heavy metal Inorganic materials 0.000 description 1
238000002347 injection Methods 0.000 description 1
239000007924 injection Substances 0.000 description 1
VKPSKYDESGTTFR-UHFFFAOYSA-N isododecane Natural products CC(C)(C)CC(C)CC(C)(C)C VKPSKYDESGTTFR-UHFFFAOYSA-N 0.000 description 1
238000010128 melt processing Methods 0.000 description 1
238000005457 optimization Methods 0.000 description 1
150000001451 organic peroxides Chemical class 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
235000020030 perry Nutrition 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
238000005086 pumping Methods 0.000 description 1
238000010926 purge Methods 0.000 description 1
239000012066 reaction slurry Substances 0.000 description 1
238000012216 screening Methods 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000010959 steel Substances 0.000 description 1
NMOALOSNPWTWRH-UHFFFAOYSA-N tert-butyl 7,7-dimethyloctaneperoxoate Chemical compound CC(C)(C)CCCCCC(=O)OOC(C)(C)C NMOALOSNPWTWRH-UHFFFAOYSA-N 0.000 description 1
238000012360 testing method Methods 0.000 description 1
125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1
238000011282 treatment Methods 0.000 description 1
238000010626 work up procedure Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/02—Monomers containing chlorine
- C08F214/04—Monomers containing two carbon atoms
- C08F214/06—Vinyl chloride
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F114/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F114/02—Monomers containing chlorine
- C08F114/04—Monomers containing two carbon atoms
- C08F114/06—Vinyl chloride
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Polymerisation Methods In General (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

HUE07727089A 2006-03-24 2007-03-20 A continuous process for the production of vinyl chloride (co) polymers HUE030197T2 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
EP06111682		2006-03-24
US78752806P	2006-03-31	2006-03-31

Publications (1)

Publication Number	Publication Date
HUE030197T2 true HUE030197T2 (en)	2017-04-28

Family

ID=36847634

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
HUE07727089A HUE030197T2 (en)	2006-03-24	2007-03-20	A continuous process for the production of vinyl chloride (co) polymers

Country Status (11)

Country	Link
US (1)	USRE45940E1 (pl)
CN (1)	CN101405308B (pl)
BR (1)	BRPI0709144B1 (pl)
ES (1)	ES2599581T3 (pl)
HU (1)	HUE030197T2 (pl)
MY (1)	MY148304A (pl)
PL (1)	PL1999169T3 (pl)
RU (1)	RU2434885C2 (pl)
SA (1)	SA07280130B1 (pl)
TW (1)	TWI439471B (pl)
ZA (1)	ZA200809109B (pl)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
KR101941098B1 (ko) *	2016-04-25	2019-01-22	주식회사 엘지화학	염화비닐계 중합체의 제조방법 및 이에 따라 제조된 염화비닐계 중합체
CN114181336A (zh) *	2021-12-16	2022-03-15	安徽天辰化工股份有限公司	一种超小粒径pvc种子及其制备方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
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US3004013A (en) *	1954-04-28	1961-10-10	Detrex Corp	Method for producing finely divided polyvinyl chloride
US2880076A (en) *	1954-04-28	1959-03-31	Detrex Chem Ind	Apparatus for producing polyvinyl chloride
US3007903A (en) *	1956-04-16	1961-11-07	Dow Chemical Co	Continuous polymerization process
JPS5693710A (en)	1979-12-28	1981-07-29	Toagosei Chem Ind Co Ltd	Continuous suspension polymerization of vinyl chloride
JPS56118407A (en)	1980-02-26	1981-09-17	Toagosei Chem Ind Co Ltd	Suspension polymerization method of vinyl chloride
DE3018643C2 (de)	1980-05-16	1982-07-08	Chemische Werke Hüls AG, 4370 Marl	Verfahren zur Herstellung von schlagfest modifizierten Styrolpolymerisaten
DE3029907A1 (de) *	1980-08-07	1982-03-18	Hoechst Ag, 6000 Frankfurt	Kontinuierliches verfahren und vorrichtung zur herstellung eines vinylchlorid-polymerisates in waessriger suspension
GB8300889D0 (en) *	1983-01-13	1983-02-16	Bp Chem Int Ltd	Steric stabilisation of pvc particles against agglomeration
JPH0710892B2 (ja) *	1985-03-08	1995-02-08	鐘淵化学工業株式会社	塩化ビニル系樹脂の製造法
FR2612520A1 (fr) *	1987-03-17	1988-09-23	Atochem	Procede de preparation en emulsion suspendue de polymeres et copolymeres insolubles dans leurs compositions monomeres ou comonomeres
KR100417066B1 (ko)	2001-01-08	2004-02-05	주식회사 엘지화학	내열성이 우수한 열가소성 수지의 제조방법
EP1277765B1 (en) *	2001-06-15	2004-11-24	Saudi Basic Industries Corporation	Process for making skinless PVC
UA77245C2 (uk)	2001-12-21	2006-11-15	Акцо Нобель Н.В.	Спосіб полімеризації суміші, яка містить вінілхлоридний мономер
TW200424217A (en)	2003-05-01	2004-11-16	Akzo Nobel Nv	Increased polymerization reactor output by using a specific initiating system

2007
- 2007-03-20 PL PL07727089T patent/PL1999169T3/pl unknown
- 2007-03-20 US US14/452,890 patent/USRE45940E1/en not_active Expired - Fee Related
- 2007-03-20 RU RU2008142137/04A patent/RU2434885C2/ru not_active IP Right Cessation
- 2007-03-20 ES ES07727089.0T patent/ES2599581T3/es active Active
- 2007-03-20 CN CN2007800103631A patent/CN101405308B/zh not_active Expired - Fee Related
- 2007-03-20 BR BRPI0709144-3A patent/BRPI0709144B1/pt not_active IP Right Cessation
- 2007-03-20 HU HUE07727089A patent/HUE030197T2/en unknown
- 2007-03-20 MY MYPI20083722A patent/MY148304A/en unknown
- 2007-03-23 TW TW096110163A patent/TWI439471B/zh not_active IP Right Cessation
- 2007-03-24 SA SA07280130A patent/SA07280130B1/ar unknown
2008
- 2008-10-23 ZA ZA200809109A patent/ZA200809109B/xx unknown

Also Published As

Publication number	Publication date
RU2434885C2 (ru)	2011-11-27
RU2008142137A (ru)	2010-04-27
CN101405308A (zh)	2009-04-08
USRE45940E1 (en)	2016-03-22
PL1999169T3 (pl)	2017-02-28
SA07280130B1 (ar)	2010-11-02
BRPI0709144B1 (pt)	2018-03-13
BRPI0709144A2 (pt)	2011-06-28
TW200745172A (en)	2007-12-16
ES2599581T3 (es)	2017-02-02
CN101405308B (zh)	2012-02-15
MY148304A (en)	2013-03-29
TWI439471B (zh)	2014-06-01
ZA200809109B (en)	2009-07-29

Publication	Publication Date	Title
CA1215500A (en)	1986-12-16	Continuous process and device for the manufacture of a vinyl chloride polymer in aqueous suspension
AU2007229565B2 (en)	2012-05-17	Continuous process for the production of vinyl chloride (co)polymers
US8217124B2 (en)	2012-07-10	Ethylene polymerization in a high pressure reactor with improved initiator feeding
EP2379606B1 (en)	2012-11-28	Method for ethylene polymerization in a tubular reactor with reduced output
US3627744A (en)	1971-12-14	Method for polymerizing vinyl halide polymers
EP3186288B1 (en)	2018-01-31	Process for separating components of a polymer-monomer mixture obtained by high-pressure polymerization of ethylenically unsaturated monomers
AU2004249401B2 (en)	2009-07-09	Polymerization process involving the dosing initiators
USRE45940E1 (en)	2016-03-22	Continuous process for the production of vinyl chloride (co)polymers
EP1230019A1 (en)	2002-08-14	Emulsion polymerization process and reactor for such a process
KR20040068290A (ko)	2004-07-30	중합 반응 중에 초고속 개시제를 연속 첨가하는 방법
US4022744A (en)	1977-05-10	Continuous polymerization process in emulsion
US5447999A (en)	1995-09-05	Vinyl chloride polymerization with recycle return projecting into gas phase region of reactor
JPH10316705A (ja)	1998-12-02	塩化ビニル系重合体の製造方法
US5310832A (en)	1994-05-10	Process for producing vinyl chloride-based polymer
NL1022781C2 (nl)	2004-08-10	Werkwijze voor het produceren van een polymeer op basis van vinylchloride.
WO2007031478A1 (en)	2007-03-22	Loop reactor for emulsion polymerisation
JPH07304806A (ja)	1995-11-21	塩化ビニル系重合体の製造方法
JP2001261709A (ja)	2001-09-26	塩化ビニル系重合体の製造法
JP2000264904A (ja)	2000-09-26	ビニル系重合体の重合方法
JP2004161934A (ja)	2004-06-10	塩化ビニル系重合体の製造方法
JPH0255707A (ja)	1990-02-26	塩化ビニル系樹脂の製造方法