HUT73731A - Bleaching compounds comprising peroxyacid activators used with enzymes - Google Patents

Bleaching compounds comprising peroxyacid activators used with enzymes Download PDF

Info

Publication number: HUT73731A
Authority: HU; Hungary
Prior art keywords: alkyl; group; hydrogen; mixtures; aryl
Prior art date: 1993-05-20

Application number

HU9503301A

Other languages

English (en)

Hungarian (hu)

Other versions

HU9503301D0 (en

Inventor

Michael Eugene Burns

Chanchal Kumar Ghosh

Richard Timothy Hartshorn

Alan David Willey

Original Assignee

Procter & Gamble

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1993-05-20

Filing date

1994-05-12

Publication date

1996-09-30

1994-05-12 Application filed by Procter & Gamble filed Critical Procter & Gamble

1996-01-29 Publication of HU9503301D0 publication Critical patent/HU9503301D0/hu

1996-09-30 Publication of HUT73731A publication Critical patent/HUT73731A/hu

Links

239000012190 activator Substances 0.000 title claims abstract description 124
102000004190 Enzymes Human genes 0.000 title claims abstract description 68
108090000790 Enzymes Proteins 0.000 title claims abstract description 68
238000004061 bleaching Methods 0.000 title claims abstract description 61
150000001875 compounds Chemical class 0.000 title claims description 36
150000004965 peroxy acids Chemical class 0.000 title description 4
239000000203 mixture Substances 0.000 claims abstract description 159
239000007844 bleaching agent Substances 0.000 claims abstract description 121
239000003599 detergent Substances 0.000 claims abstract description 109
238000000034 method Methods 0.000 claims abstract description 65
JBKVHLHDHHXQEQ-UHFFFAOYSA-N Caprolactam Natural products O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims abstract description 47
239000004615 ingredient Substances 0.000 claims abstract description 30
229940088598 enzyme Drugs 0.000 claims description 66
-1 octanoyl caprolactam Chemical compound 0.000 claims description 43
244000043261 Hevea brasiliensis Species 0.000 claims description 41
229920003052 natural elastomer Polymers 0.000 claims description 41
229920001194 natural rubber Polymers 0.000 claims description 41
125000000217 alkyl group Chemical group 0.000 claims description 40
238000005406 washing Methods 0.000 claims description 40
239000001257 hydrogen Substances 0.000 claims description 33
229910052739 hydrogen Inorganic materials 0.000 claims description 33
125000003118 aryl group Chemical group 0.000 claims description 31
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 28
125000002877 alkyl aryl group Chemical group 0.000 claims description 27
239000011734 sodium Substances 0.000 claims description 25
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 23
238000004140 cleaning Methods 0.000 claims description 23
229910052708 sodium Inorganic materials 0.000 claims description 23
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 22
102000004882 Lipase Human genes 0.000 claims description 22
108090001060 Lipase Proteins 0.000 claims description 22
239000004367 Lipase Substances 0.000 claims description 19
235000019421 lipase Nutrition 0.000 claims description 19
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 18
239000002245 particle Substances 0.000 claims description 18
229940045872 sodium percarbonate Drugs 0.000 claims description 18
108091005804 Peptidases Proteins 0.000 claims description 17
102000035195 Peptidases Human genes 0.000 claims description 17
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 16
239000004365 Protease Substances 0.000 claims description 16
229940077388 benzenesulfonate Drugs 0.000 claims description 16
239000004744 fabric Substances 0.000 claims description 16
230000000694 effects Effects 0.000 claims description 15
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 15
239000004094 surface-active agent Substances 0.000 claims description 15
SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 claims description 14
FAGGUIDTQQXDSJ-UHFFFAOYSA-N 3-benzoylazepan-2-one Chemical group C=1C=CC=CC=1C(=O)C1CCCCNC1=O FAGGUIDTQQXDSJ-UHFFFAOYSA-N 0.000 claims description 11
102000005575 Cellulases Human genes 0.000 claims description 11
108010084185 Cellulases Proteins 0.000 claims description 11
102000003992 Peroxidases Human genes 0.000 claims description 11
125000004432 carbon atom Chemical group C* 0.000 claims description 10
108010042388 protease C Proteins 0.000 claims description 10
108010065511 Amylases Proteins 0.000 claims description 8
102000013142 Amylases Human genes 0.000 claims description 8
125000004171 alkoxy aryl group Chemical group 0.000 claims description 8
235000019418 amylase Nutrition 0.000 claims description 8
229940025131 amylases Drugs 0.000 claims description 8
125000003342 alkenyl group Chemical group 0.000 claims description 7
125000002947 alkylene group Chemical group 0.000 claims description 7
125000000732 arylene group Chemical group 0.000 claims description 7
230000001580 bacterial effect Effects 0.000 claims description 7
JKZLOWDYIRTRJZ-UHFFFAOYSA-N 2-[6-(octanoylamino)hexanoyloxy]benzenesulfonic acid Chemical compound CCCCCCCC(=O)NCCCCCC(=O)OC1=CC=CC=C1S(O)(=O)=O JKZLOWDYIRTRJZ-UHFFFAOYSA-N 0.000 claims description 6
241000193422 Bacillus lentus Species 0.000 claims description 6
235000014469 Bacillus subtilis Nutrition 0.000 claims description 6
108700020962 Peroxidase Proteins 0.000 claims description 6
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
239000007864 aqueous solution Substances 0.000 claims description 6
125000000008 (C1-C10) alkyl group Chemical group 0.000 claims description 5
241000193830 Bacillus <bacterium> Species 0.000 claims description 5
244000063299 Bacillus subtilis Species 0.000 claims description 5
108010022999 Serine Proteases Proteins 0.000 claims description 5
102000012479 Serine Proteases Human genes 0.000 claims description 5
108010020132 microbial serine proteinases Proteins 0.000 claims description 5
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims description 5
229940048086 sodium pyrophosphate Drugs 0.000 claims description 5
235000019818 tetrasodium diphosphate Nutrition 0.000 claims description 5
239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 5
241000223258 Thermomyces lanuginosus Species 0.000 claims description 4
239000000654 additive Substances 0.000 claims description 4
125000003545 alkoxy group Chemical group 0.000 claims description 4
125000003710 aryl alkyl group Chemical group 0.000 claims description 4
239000004202 carbamide Substances 0.000 claims description 4
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 4
229910052736 halogen Inorganic materials 0.000 claims description 4
150000002367 halogens Chemical class 0.000 claims description 4
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 4
PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 claims description 4
125000001424 substituent group Chemical group 0.000 claims description 4
GOKVKLCCWGRQJV-UHFFFAOYSA-N 2-[6-(decanoylamino)hexanoyloxy]benzenesulfonic acid Chemical compound CCCCCCCCCC(=O)NCCCCCC(=O)OC1=CC=CC=C1S(O)(=O)=O GOKVKLCCWGRQJV-UHFFFAOYSA-N 0.000 claims description 3
125000003282 alkyl amino group Chemical group 0.000 claims description 3
238000002156 mixing Methods 0.000 claims description 3
150000004967 organic peroxy acids Chemical class 0.000 claims description 3
CMLFRMDBDNHMRA-UHFFFAOYSA-N 2h-1,2-benzoxazine Chemical compound C1=CC=C2C=CNOC2=C1 CMLFRMDBDNHMRA-UHFFFAOYSA-N 0.000 claims description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
HTTLBYITFHMYFK-UHFFFAOYSA-N bentranil Chemical group N=1C2=CC=CC=C2C(=O)OC=1C1=CC=CC=C1 HTTLBYITFHMYFK-UHFFFAOYSA-N 0.000 claims description 2
125000002962 imidazol-1-yl group Chemical group [*]N1C([H])=NC([H])=C1[H] 0.000 claims description 2
239000011591 potassium Chemical group 0.000 claims description 2
229910052700 potassium Chemical group 0.000 claims description 2
239000008137 solubility enhancer Substances 0.000 claims description 2
150000002431 hydrogen Chemical group 0.000 claims 4
241000233866 Fungi Species 0.000 claims 3
125000004356 hydroxy functional group Chemical group O* 0.000 claims 2
150000003355 serines Chemical class 0.000 claims 2
230000000996 additive effect Effects 0.000 claims 1
239000002671 adjuvant Substances 0.000 claims 1
230000008021 deposition Effects 0.000 claims 1
238000010525 oxidative degradation reaction Methods 0.000 claims 1
125000003368 amide group Chemical group 0.000 abstract description 2
239000000243 solution Substances 0.000 description 20
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 17
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
230000002209 hydrophobic effect Effects 0.000 description 15
238000006243 chemical reaction Methods 0.000 description 13
238000009472 formulation Methods 0.000 description 11
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 10
238000003556 assay Methods 0.000 description 10
239000012535 impurity Substances 0.000 description 10
239000000463 material Substances 0.000 description 10
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
239000000047 product Substances 0.000 description 9
FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical group CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 8
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 7
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 7
229910001424 calcium ion Inorganic materials 0.000 description 7
239000002738 chelating agent Substances 0.000 description 7
239000007788 liquid Substances 0.000 description 7
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 6
235000010338 boric acid Nutrition 0.000 description 6
239000003795 chemical substances by application Substances 0.000 description 6
239000004927 clay Substances 0.000 description 6
230000000269 nucleophilic effect Effects 0.000 description 6
238000010992 reflux Methods 0.000 description 6
150000004760 silicates Chemical class 0.000 description 6
239000007787 solid Substances 0.000 description 6
239000003381 stabilizer Substances 0.000 description 6
239000010457 zeolite Substances 0.000 description 6
229910019142 PO4 Inorganic materials 0.000 description 5
239000002253 acid Substances 0.000 description 5
150000001408 amides Chemical class 0.000 description 5
239000011230 binding agent Substances 0.000 description 5
230000015572 biosynthetic process Effects 0.000 description 5
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 5
239000004327 boric acid Substances 0.000 description 5
229910000019 calcium carbonate Inorganic materials 0.000 description 5
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 5
229920001971 elastomer Polymers 0.000 description 5
239000000945 filler Substances 0.000 description 5
230000002538 fungal effect Effects 0.000 description 5
239000008187 granular material Substances 0.000 description 5
235000021317 phosphate Nutrition 0.000 description 5
229920005646 polycarboxylate Polymers 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
238000000746 purification Methods 0.000 description 5
239000002904 solvent Substances 0.000 description 5
235000000346 sugar Nutrition 0.000 description 5
UJCHIZDEQZMODR-BYPYZUCNSA-N (2r)-2-acetamido-3-sulfanylpropanamide Chemical compound CC(=O)N[C@@H](CS)C(N)=O UJCHIZDEQZMODR-BYPYZUCNSA-N 0.000 description 4
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 4
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
241001669680 Dormitator maculatus Species 0.000 description 4
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
229910021536 Zeolite Inorganic materials 0.000 description 4
229910052783 alkali metal Inorganic materials 0.000 description 4
239000003945 anionic surfactant Substances 0.000 description 4
150000001450 anions Chemical class 0.000 description 4
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
229910052570 clay Inorganic materials 0.000 description 4
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 4
235000014113 dietary fatty acids Nutrition 0.000 description 4
229940071087 ethylenediamine disuccinate Drugs 0.000 description 4
239000000194 fatty acid Substances 0.000 description 4
229930195729 fatty acid Natural products 0.000 description 4
125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
239000002736 nonionic surfactant Substances 0.000 description 4
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
239000010452 phosphate Substances 0.000 description 4
WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 4
229910000342 sodium bisulfate Inorganic materials 0.000 description 4
235000019832 sodium triphosphate Nutrition 0.000 description 4
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 4
238000003786 synthesis reaction Methods 0.000 description 4
239000000454 talc Substances 0.000 description 4
229910052623 talc Inorganic materials 0.000 description 4
MHKLKWCYGIBEQF-UHFFFAOYSA-N 4-(1,3-benzothiazol-2-ylsulfanyl)morpholine Chemical compound C1COCCN1SC1=NC2=CC=CC=C2S1 MHKLKWCYGIBEQF-UHFFFAOYSA-N 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
238000005481 NMR spectroscopy Methods 0.000 description 3
SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical compound OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 description 3
108010056079 Subtilisins Proteins 0.000 description 3
102000005158 Subtilisins Human genes 0.000 description 3
240000008042 Zea mays Species 0.000 description 3
235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 3
235000002017 Zea mays subsp mays Nutrition 0.000 description 3
239000003513 alkali Substances 0.000 description 3
150000001340 alkali metals Chemical class 0.000 description 3
229910052782 aluminium Inorganic materials 0.000 description 3
239000006227 byproduct Substances 0.000 description 3
239000011575 calcium Substances 0.000 description 3
229910052791 calcium Inorganic materials 0.000 description 3
235000005822 corn Nutrition 0.000 description 3
235000019838 diammonium phosphate Nutrition 0.000 description 3
238000005516 engineering process Methods 0.000 description 3
150000004665 fatty acids Chemical class 0.000 description 3
238000005342 ion exchange Methods 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
239000003921 oil Substances 0.000 description 3
108040007629 peroxidase activity proteins Proteins 0.000 description 3
229920000642 polymer Polymers 0.000 description 3
235000018102 proteins Nutrition 0.000 description 3
102000004169 proteins and genes Human genes 0.000 description 3
108090000623 proteins and genes Proteins 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
230000003381 solubilizing effect Effects 0.000 description 3
239000000126 substance Substances 0.000 description 3
150000008163 sugars Chemical class 0.000 description 3
239000006188 syrup Substances 0.000 description 3
235000020357 syrup Nutrition 0.000 description 3
239000003760 tallow Substances 0.000 description 3
238000010998 test method Methods 0.000 description 3
JSYPRLVDJYQMAI-ODZAUARKSA-N (z)-but-2-enedioic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)\C=C/C(O)=O JSYPRLVDJYQMAI-ODZAUARKSA-N 0.000 description 2
OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 2
NARVIWMVBMUEOG-UHFFFAOYSA-N 2-Hydroxy-propylene Natural products CC(O)=C NARVIWMVBMUEOG-UHFFFAOYSA-N 0.000 description 2
125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 2
240000006439 Aspergillus oryzae Species 0.000 description 2
235000002247 Aspergillus oryzae Nutrition 0.000 description 2
241000194108 Bacillus licheniformis Species 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 2
SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 2
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
229910004298 SiO 2 Inorganic materials 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
150000004996 alkyl benzenes Chemical class 0.000 description 2
150000008051 alkyl sulfates Chemical class 0.000 description 2
235000001014 amino acid Nutrition 0.000 description 2
229940024606 amino acid Drugs 0.000 description 2
150000001413 amino acids Chemical class 0.000 description 2
229910052786 argon Inorganic materials 0.000 description 2
SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical group OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 2
229940092714 benzenesulfonic acid Drugs 0.000 description 2
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid group Chemical group C(C1=CC=CC=C1)(=O)O WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
235000013361 beverage Nutrition 0.000 description 2
230000001851 biosynthetic effect Effects 0.000 description 2
235000011132 calcium sulphate Nutrition 0.000 description 2
229920002678 cellulose Polymers 0.000 description 2
235000010980 cellulose Nutrition 0.000 description 2
238000000576 coating method Methods 0.000 description 2
239000000356 contaminant Substances 0.000 description 2
239000012043 crude product Substances 0.000 description 2
239000000645 desinfectant Substances 0.000 description 2
238000004090 dissolution Methods 0.000 description 2
ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 2
239000000975 dye Substances 0.000 description 2
239000013013 elastic material Substances 0.000 description 2
238000001125 extrusion Methods 0.000 description 2
238000005562 fading Methods 0.000 description 2
238000005187 foaming Methods 0.000 description 2
239000008103 glucose Substances 0.000 description 2
HSEMFIZWXHQJAE-UHFFFAOYSA-N hexadecanamide Chemical compound CCCCCCCCCCCCCCCC(N)=O HSEMFIZWXHQJAE-UHFFFAOYSA-N 0.000 description 2
FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
229910052943 magnesium sulfate Inorganic materials 0.000 description 2
235000019341 magnesium sulphate Nutrition 0.000 description 2
YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 2
NTQYXUJLILNTFH-UHFFFAOYSA-N nonanoyl chloride Chemical compound CCCCCCCCC(Cl)=O NTQYXUJLILNTFH-UHFFFAOYSA-N 0.000 description 2
125000001402 nonanoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
239000000049 pigment Substances 0.000 description 1
229920001223 polyethylene glycol Polymers 0.000 description 1
229920001282 polysaccharide Polymers 0.000 description 1
239000005017 polysaccharide Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
239000002243 precursor Substances 0.000 description 1
125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229940024999 proteolytic enzymes for treatment of wounds and ulcers Drugs 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
238000006268 reductive amination reaction Methods 0.000 description 1
238000011160 research Methods 0.000 description 1
230000002441 reversible effect Effects 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000000344 soap Substances 0.000 description 1
150000003385 sodium Chemical class 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
229960001922 sodium perborate Drugs 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
235000019351 sodium silicates Nutrition 0.000 description 1
239000004328 sodium tetraborate Substances 0.000 description 1
235000010339 sodium tetraborate Nutrition 0.000 description 1
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
239000013042 solid detergent Substances 0.000 description 1
238000001694 spray drying Methods 0.000 description 1
230000003068 static effect Effects 0.000 description 1
231100000240 steatosis hepatitis Toxicity 0.000 description 1
238000003860 storage Methods 0.000 description 1
229940117986 sulfobetaine Drugs 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
239000013589 supplement Substances 0.000 description 1
239000000375 suspending agent Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
239000000271 synthetic detergent Substances 0.000 description 1
108010075550 termamyl Proteins 0.000 description 1
150000004685 tetrahydrates Chemical class 0.000 description 1
UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
150000004684 trihydrates Chemical class 0.000 description 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
239000004474 valine Substances 0.000 description 1
230000002087 whitening effect Effects 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3945—Organic per-compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C11D3/3917—Nitrogen-containing compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C11D3/3917—Nitrogen-containing compounds
- C11D3/392—Heterocyclic compounds, e.g. cyclic imides or lactames

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Detergent Compositions (AREA)
Cosmetics (AREA)

HU9503301A 1993-05-20 1994-05-12 Bleaching compounds comprising peroxyacid activators used with enzymes HUT73731A (en)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date
US6456393A	1993-05-20	1993-05-20
US13369193A	1993-10-07	1993-10-07
US15131693A	1993-11-12	1993-11-12
US19632294A	1994-02-15	1994-02-15

Publications (2)

Publication Number	Publication Date
HU9503301D0 HU9503301D0 (en)	1996-01-29
HUT73731A true HUT73731A (en)	1996-09-30

Family

ID=27490432

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
HU9503301A HUT73731A (en)	1993-05-20	1994-05-12	Bleaching compounds comprising peroxyacid activators used with enzymes

Country Status (14)

Country	Link
EP (1)	EP0699230B1 (fr)
JP (1)	JPH08510780A (fr)
CN (1)	CN1086734C (fr)
AT (1)	ATE170552T1 (fr)
AU (1)	AU6833594A (fr)
BR (1)	BR9406531A (fr)
CA (1)	CA2161212A1 (fr)
CZ (1)	CZ305995A3 (fr)
DE (1)	DE69413028T2 (fr)
ES (1)	ES2120047T3 (fr)
HU (1)	HUT73731A (fr)
MA (1)	MA23200A1 (fr)
PE (1)	PE56994A1 (fr)
WO (1)	WO1994028106A1 (fr)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5755992A (en) *	1994-04-13	1998-05-26	The Procter & Gamble Company	Detergents containing a surfactant and a delayed release peroxyacid bleach system
US5460747A (en) *	1994-08-31	1995-10-24	The Procter & Gamble Co.	Multiple-substituted bleach activators
US5584888A (en) *	1994-08-31	1996-12-17	Miracle; Gregory S.	Perhydrolysis-selective bleach activators
US5686015A (en) *	1994-08-31	1997-11-11	The Procter & Gamble Company	Quaternary substituted bleach activators
EP0792345A1 (fr) *	1994-11-18	1997-09-03	The Procter & Gamble Company	Compositions de blanchiment et additifs de blanchiment comprenant des activateurs de blanchiment efficaces a des concentrations basses de perhydroxyle
US5523434A (en) *	1995-03-15	1996-06-04	The Procter & Gamble Company	Synthesis of bleach activators
JP3320304B2 (ja)	1995-04-20	2002-09-03	花王株式会社	漂白洗剤組成物
DE19609953A1 (de) *	1996-03-14	1997-09-18	Basf Ag	Feste Zusammensetzung aus heterocyclischen Verbindungen und/oder Oximestern und inerten porösen Trägermaterialien und ihre Verwendung als stabile Bleichaktivator-Komponente in Wasch-, Bleich- und Reinigungsmitteln
US6100080A (en) *	1996-12-18	2000-08-08	Novo Nordisk A/S	Method for enzymatic treatment of biofilm
BR9811334A (pt) *	1997-08-20	2000-09-19	Procter & Gamble	Processo para preparação e/ou purificação de amido ácido fenil éster sulfonatos
WO2000003369A2 (fr) *	1998-07-08	2000-01-20	The Procter & Gamble Company	Techniques visant a diminuer ou a empecher la deterioration du caoutchouc lors de blanchiments domestiques
DE19900939C2 (de)	1999-01-13	2001-06-07	Clariant Gmbh	Verfahren zur Herstellung von Amidosäurephenylestern
AU2001245278A1 (en)	2000-02-15	2001-11-07	The Procter And Gamble Company	Method for the application of durable press finishes to textile components via the use of hydrophobic bleaching preparation
EP1255889A2 (fr) *	2000-02-15	2002-11-13	The Procter & Gamble Company	Procede d'utilisation de systeme de blanchiment hydrophobes dans la preparation de textiles
JP2003525361A (ja)	2000-02-15	2003-08-26	ザ、プロクター、エンド、ギャンブル、カンパニー	繊維製品の一段階調製方法
US6830591B1 (en)	2000-02-15	2004-12-14	The Procter & Gamble Company	Method for the use of hydrophobic bleaching systems in textile preparation
ATE286876T1 (de) *	2000-06-02	2005-01-15	Eastman Chem Co	Reinigung von phenylestersalzen
US6500973B2 (en)	2000-06-02	2002-12-31	Eastman Chemical Company	Extractive solution crystallization of chemical compounds
DZ3349A1 (fr)	2000-07-28	2002-02-07	Henkel Kgaa	Nouvelle enzyme amylolytique issue de bacillus sp. a 7-7 (dsm 12368) ainsi que produits de lavage et nettoyage contenant ledit enzyme amylolytique
US6569209B2 (en) *	2001-02-27	2003-05-27	The Procter & Gamble Company	Method for the use of hydrophobic bleaching systems in cold batch textile preparation
DE102006036889A1 (de) *	2006-08-04	2008-02-07	Clariant International Limited	Verwendung von Aminoacetonen und deren Salzen als Bleichkraftverstärker für Persauerstoffverbindungen
US9228158B2 (en)	2012-02-01	2016-01-05	Gurtler Industries, Inc.	Composition and method for removing stains derived from chlorhexidine gluconate
CN105907483B (zh) *	2016-05-08	2019-01-15	浙江艾卡医学科技有限公司	一种含氧的多功能洗涤剂组合物
US11525106B2 (en) *	2018-04-16	2022-12-13	Dow Global Technologies Llc	Tetraacetyldiamine and triacetyldiamine derivatives useful as bleach activators

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB8310080D0 (en) *	1983-04-14	1983-05-18	Interox Chemicals Ltd	Bleach composition
GB8415909D0 (en) *	1984-06-21	1984-07-25	Procter & Gamble Ltd	Peracid compounds
US4852989A (en) *	1987-05-08	1989-08-01	The Procter & Gamble Company	Bleaching compounds and compositions comprising fatty peroxyacids salts thereof and precursors therefor having amide moieties in the fatty chain
JPH0696720B2 (ja) *	1989-06-14	1994-11-30	花王株式会社	漂白剤及び漂白洗浄剤組成物
DE3938526A1 (de) *	1989-11-21	1991-05-23	Basf Ag	Verwendung von heterocyclischen verbindungen als bleichaktivatoren oder optische aufheller in wasch- und reinigungsmitteln
DE69324261T2 (de) *	1992-10-23	1999-10-14	The Procter & Gamble Co.	Granulare waschmittel mit protease

1994
- 1994-05-12 DE DE69413028T patent/DE69413028T2/de not_active Expired - Fee Related
- 1994-05-12 CA CA002161212A patent/CA2161212A1/fr not_active Abandoned
- 1994-05-12 WO PCT/US1994/005372 patent/WO1994028106A1/fr not_active Ceased
- 1994-05-12 HU HU9503301A patent/HUT73731A/hu unknown
- 1994-05-12 CZ CZ953059A patent/CZ305995A3/cs unknown
- 1994-05-12 JP JP7500721A patent/JPH08510780A/ja not_active Ceased
- 1994-05-12 BR BR9406531A patent/BR9406531A/pt not_active IP Right Cessation
- 1994-05-12 CN CN94192168A patent/CN1086734C/zh not_active Expired - Fee Related
- 1994-05-12 AT AT94916771T patent/ATE170552T1/de not_active IP Right Cessation
- 1994-05-12 AU AU68335/94A patent/AU6833594A/en not_active Abandoned
- 1994-05-12 EP EP94916771A patent/EP0699230B1/fr not_active Expired - Lifetime
- 1994-05-12 ES ES94916771T patent/ES2120047T3/es not_active Expired - Lifetime
- 1994-05-19 MA MA23510A patent/MA23200A1/fr unknown
- 1994-05-20 PE PE1994242837A patent/PE56994A1/es not_active Application Discontinuation

Also Published As

Publication number	Publication date
EP0699230A1 (fr)	1996-03-06
DE69413028D1 (de)	1998-10-08
WO1994028106A1 (fr)	1994-12-08
HU9503301D0 (en)	1996-01-29
CN1124036A (zh)	1996-06-05
AU6833594A (en)	1994-12-20
CZ305995A3 (en)	1996-05-15
CA2161212A1 (fr)	1994-12-08
CN1086734C (zh)	2002-06-26
DE69413028T2 (de)	1999-05-06
PE56994A1 (es)	1995-02-01
EP0699230B1 (fr)	1998-09-02
JPH08510780A (ja)	1996-11-12
ES2120047T3 (es)	1998-10-16
MA23200A1 (fr)	1994-12-31
BR9406531A (pt)	1996-01-02
ATE170552T1 (de)	1998-09-15

Legal Events

Date	Code	Title	Description
1998-06-29	DFA9	Temporary protection cancelled due to abandonment

Publication	Publication Date	Title
HUT73731A (en)	1996-09-30	Bleaching compounds comprising peroxyacid activators used with enzymes
US5998350A (en)	1999-12-07	Bleaching compounds comprising N-acyl caprolactam and/or peroxy acid activators
EP0699232B1 (fr)	1999-07-28	Compositions de blanchiment comprenant des adjuvants a base de n-acyl caprolactame
US5405412A (en)	1995-04-11	Bleaching compounds comprising N-acyl caprolactam and alkanoyloxybenzene sulfonate bleach activators
US5503639A (en)	1996-04-02	Bleaching compounds comprising acyl valerolactam bleach activators
US4634551A (en)	1987-01-06	Bleaching compounds and compositions comprising fatty peroxyacids salts thereof and precursors therefor having amide moieties in the fatty chain
ES2210568T3 (es)	2004-07-01	Potenciadores del blanqueo protectores del color, composiciones y metodos para lavar ropa que emplean los mismos.
EP0170386B1 (fr)	1993-12-08	Combinaisons de blanchiment et compositions contenant des acides gras péroxy, leurs sels et précurseurs
CZ283515B6 (cs)	1998-04-15	Detergentní částice
JPH06501731A (ja)	1994-02-24	ポリヒドロキシ脂肪酸アミドとアルキルアルコキシル化スルフェートとを含んでなる洗剤組成物
CA2079487C (fr)	1997-01-14	Agent de blanchiment sous forme de granules renfermant un amidoperoxyacide
EP0699233B1 (fr)	1999-03-24	Procede de blanchiment avec des compositions comprenant des adjuvants au peroxyacide ayant des fractions amide
HU213043B (en)	1997-01-28	Detergent increasing the enzymatic activity and comprising polyhydroxy fatty acid amides
JPH09512290A (ja)	1997-12-09	キレート剤および酵素を含有する低減された過酸素標白剤レベルの洗剤
JP2914484B2 (ja)	1999-06-28	漂白化合物
CA2162362C (fr)	1999-07-27	Composes de blanchiment renfermant des activateurs de blanchiment a base de caprolactame n-acyle et de sulfonate d'alcanoyloxybenzene
MXPA97003718A (en)	1998-02-01	Whitening compositions and whitening additives comprising effective whitening activators with low perhidrox concentrations
MXPA97005496A (en)	1998-07-03	Detergent compositions that buy from stabilized compounds in polyaminoac