IE35381B1 - 1-hydroxy-2-(1,1-difluoroalkyl)-1h-imidazo(4,5-b)pyridine compounds and ethers and esters and salts thereof - Google Patents

1-hydroxy-2-(1,1-difluoroalkyl)-1h-imidazo(4,5-b)pyridine compounds and ethers and esters and salts thereof

Info

Publication number: IE35381B1
Authority: IE; Ireland
Prior art keywords: nitro; pyridine; give; alkylsulphonyl; hydrogen
Prior art date: 1970-03-20

Application number

IE285/71A

Other languages

English (en)

Other versions

IE35381L (en

Original Assignee

Lilly Co Eli

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1970-03-20

Filing date

1971-03-08

Publication date

1976-02-04

1971-03-08 Application filed by Lilly Co Eli filed Critical Lilly Co Eli

1971-09-20 Publication of IE35381L publication Critical patent/IE35381L/xx

1976-02-04 Publication of IE35381B1 publication Critical patent/IE35381B1/xx

Links

150000002148 esters Chemical class 0.000 title abstract 2
150000003839 salts Chemical class 0.000 title abstract 2
150000002170 ethers Chemical class 0.000 title 1
229910052739 hydrogen Inorganic materials 0.000 abstract 5
238000006243 chemical reaction Methods 0.000 abstract 4
239000001257 hydrogen Substances 0.000 abstract 4
229910052736 halogen Inorganic materials 0.000 abstract 3
150000002367 halogens Chemical class 0.000 abstract 3
150000002431 hydrogen Chemical class 0.000 abstract 3
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
229910052784 alkaline earth metal Inorganic materials 0.000 abstract 2
239000000460 chlorine Substances 0.000 abstract 2
150000001875 compounds Chemical class 0.000 abstract 2
238000006266 etherification reaction Methods 0.000 abstract 2
150000005232 imidazopyridines Chemical class 0.000 abstract 2
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 2
-1 thiocarbonates Chemical class 0.000 abstract 2
FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 abstract 2
YUBHMOQVHOODEI-UHFFFAOYSA-N 5-chloro-2-nitropyridine Chemical compound [O-][N+](=O)C1=CC=C(Cl)C=N1 YUBHMOQVHOODEI-UHFFFAOYSA-N 0.000 abstract 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 abstract 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
239000003513 alkali Substances 0.000 abstract 1
150000001342 alkaline earth metals Chemical class 0.000 abstract 1
150000001345 alkine derivatives Chemical class 0.000 abstract 1
125000004390 alkyl sulfonyl group Chemical group 0.000 abstract 1
150000001412 amines Chemical class 0.000 abstract 1
239000000908 ammonium hydroxide Substances 0.000 abstract 1
150000004657 carbamic acid derivatives Chemical class 0.000 abstract 1
150000004649 carbonic acid derivatives Chemical class 0.000 abstract 1
229910052801 chlorine Inorganic materials 0.000 abstract 1
230000032050 esterification Effects 0.000 abstract 1
238000005886 esterification reaction Methods 0.000 abstract 1
239000011737 fluorine Substances 0.000 abstract 1
229910052731 fluorine Inorganic materials 0.000 abstract 1
239000004009 herbicide Substances 0.000 abstract 1
150000002440 hydroxy compounds Chemical class 0.000 abstract 1
239000012948 isocyanate Substances 0.000 abstract 1
150000002513 isocyanates Chemical class 0.000 abstract 1
230000001590 oxidative effect Effects 0.000 abstract 1
125000005010 perfluoroalkyl group Chemical group 0.000 abstract 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 1
238000007363 ring formation reaction Methods 0.000 abstract 1
229910052708 sodium Inorganic materials 0.000 abstract 1
239000011734 sodium Substances 0.000 abstract 1
239000001117 sulphuric acid Substances 0.000 abstract 1
235000011149 sulphuric acid Nutrition 0.000 abstract 1
150000003558 thiocarbamic acid derivatives Chemical class 0.000 abstract 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/72—Nitrogen atoms
- C07D213/75—Amino or imino radicals, acylated by carboxylic or carbonic acids, or by sulfur or nitrogen analogues thereof, e.g. carbamates
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
- A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/70—Sulfur atoms
- C07D213/71—Sulfur atoms to which a second hetero atom is attached

Landscapes

Life Sciences & Earth Sciences (AREA)
Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Pest Control & Pesticides (AREA)
Plant Pathology (AREA)
Agronomy & Crop Science (AREA)
Engineering & Computer Science (AREA)
Dentistry (AREA)
General Health & Medical Sciences (AREA)
Wood Science & Technology (AREA)
Zoology (AREA)
Environmental Sciences (AREA)
Pyridine Compounds (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)

IE285/71A 1970-03-20 1971-03-08 1-hydroxy-2-(1,1-difluoroalkyl)-1h-imidazo(4,5-b)pyridine compounds and ethers and esters and salts thereof IE35381B1 (en)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date
US2153570A	1970-03-20	1970-03-20
US4951970A	1970-06-24	1970-06-24
US10041070A	1970-12-21	1970-12-21

Publications (2)

Publication Number	Publication Date
IE35381L IE35381L (en)	1971-09-20
IE35381B1 true IE35381B1 (en)	1976-02-04

Family

ID=27361659

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IE285/71A IE35381B1 (en)	1970-03-20	1971-03-08	1-hydroxy-2-(1,1-difluoroalkyl)-1h-imidazo(4,5-b)pyridine compounds and ethers and esters and salts thereof

Country Status (7)

Country	Link
BE (1)	BE764591A (fr)
CY (1)	CY799A (fr)
FR (1)	FR2084922A5 (fr)
GB (1)	GB1307489A (fr)
HK (1)	HK17676A (fr)
IE (1)	IE35381B1 (fr)
IL (1)	IL36378A (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4087432A (en) *	1974-05-23	1978-05-02	Eli Lilly And Company	1H-imidazo(4,5-b)pyridine compounds

1971
- 1971-03-08 IE IE285/71A patent/IE35381B1/xx unknown
- 1971-03-09 IL IL36378A patent/IL36378A/xx unknown
- 1971-03-19 BE BE764591A patent/BE764591A/fr unknown
- 1971-03-19 FR FR7109791A patent/FR2084922A5/fr not_active Expired
- 1971-04-19 GB GB2469271*A patent/GB1307489A/en not_active Expired
- 1971-04-19 CY CY799A patent/CY799A/xx unknown
1976
- 1976-03-25 HK HK176/76*UA patent/HK17676A/xx unknown

Also Published As

Publication number	Publication date
IE35381L (en)	1971-09-20
IL36378A (en)	1975-08-31
BE764591A (fr)	1971-09-22
FR2084922A5 (fr)	1971-12-17
HK17676A (en)	1976-04-02
IL36378A0 (en)	1971-05-26
GB1307489A (en)	1973-02-21
CY799A (en)	1976-12-01

Publication	Publication Date	Title
GB916575A (en)	1963-01-23	4-hydroxy-2-butynyl n-(3-halophenyl) carbamates and process for preparing same
GB1499115A (en)	1978-01-25	Process for the production of nitro derivatives of aromatic compounds
GB1340911A (en)	1973-12-19	3,4-dihydro-1,2,3-oxathiazin-4-one derivatives and a process for their preparation
ES8604226A1 (es)	1986-02-01	Procedimiento para preparar (2-oxo-1, 2, 3, 5-tetrahidroimidazo (2, 1-b) quinazolinil) oxialquilamidas
IE35381B1 (en)	1976-02-04	1-hydroxy-2-(1,1-difluoroalkyl)-1h-imidazo(4,5-b)pyridine compounds and ethers and esters and salts thereof
IE36413L (en)	1973-01-09	Hydroxy phenyl amines.
GB1457986A (en)	1976-12-08	Triphenyl-1,2,3-triazolyl-1-methanes processes for their prepa ration and their use as fungicides
GB1209539A (en)	1970-10-21	Fluorosulphonyl biphenyl compounds and their preparation
GB1497752A (en)	1978-01-12	Tertiary amides
KR860002479A (ko)	1986-04-26	8-할로-5, 6-디알콕시퀴나졸린-2,4-디온의 제조방법
ES8308880A1 (es)	1983-10-01	10-(1-aza-(2,2,2)-biciclo-3-octil) 10 h-fenotiazin-2-sulfonamidas.
US3959313A (en)	1976-05-25	Preparation of dithiolium compounds
GB1382259A (en)	1975-01-29	Process for producing quinacridones and intermediates thereof and said intermediates
SU502862A1 (ru)	1976-02-15	Способ получени пропиленхлоргидрина
GB1033773A (en)	1966-06-22	Process for the production of substituted 1,4-dichloro anthraquinones
ES417393A1 (es)	1976-07-16	Un procedimiento para la produccion de imidazoquinoxalinas.
GB1510356A (en)	1978-05-10	Cycloalkene derivatives
GB739210A (en)	1955-10-26	Process of producing dialkylamino alkyl esters of 4-amino-2-hydroxy benzoic acid compounds
JPS5721321A (en)	1982-02-04	Antihyperlipemic agent
JPS5531041A (en)	1980-03-05	Reserpilinic acid derivative
GB1370370A (en)	1974-10-16	Haloakyl esters of sulphonic acids and their use as herbicide antidotes
JPS55120586A (en)	1980-09-17	Novel mitomycins and their preparation
GB1351453A (en)	1974-05-01	Preparation of 4,4-dichlorodiphenyl sulphone
JPS5592320A (en)	1980-07-12	Anti-inflammatory agent comprising aminobenzoic acid as active constituent
GB1232179A (fr)	1971-05-19