IL117123A - Acrylic emulsion coatings for rubber objects - Google Patents

Acrylic emulsion coatings for rubber objects

Info

Publication number: IL117123A
Authority: IL; Israel
Prior art keywords: copolymer; monomers; acrylic based; weight; rubber article
Prior art date: 1995-02-14

Application number

IL11712396A

Other languages

English (en)

Hebrew (he)

Other versions

IL117123A0 (en

Original Assignee

Avery Dennison Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-02-14

Filing date

1996-02-13

Publication date

2002-04-21

1995-02-14 Priority claimed from US08/388,030 external-priority patent/US5691069A/en

1995-06-07 Priority claimed from US08/486,948 external-priority patent/US5712346A/en

1996-02-13 Application filed by Avery Dennison Corp filed Critical Avery Dennison Corp

1996-06-18 Publication of IL117123A0 publication Critical patent/IL117123A0/xx

2002-04-21 Publication of IL117123A publication Critical patent/IL117123A/en

Links

229920001971 elastomer Polymers 0.000 title claims abstract description 79
239000005060 rubber Substances 0.000 title claims abstract description 79
239000000839 emulsion Substances 0.000 title claims abstract description 62
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 60
238000000576 coating method Methods 0.000 title claims abstract description 47
229920001577 copolymer Polymers 0.000 claims abstract description 156
239000000178 monomer Substances 0.000 claims abstract description 99
229920001296 polysiloxane Polymers 0.000 claims abstract description 40
239000011248 coating agent Substances 0.000 claims abstract description 38
230000009477 glass transition Effects 0.000 claims abstract description 36
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 16
-1 fatty acid esters Chemical class 0.000 claims abstract description 14
125000005250 alkyl acrylate group Chemical group 0.000 claims abstract description 11
229920002554 vinyl polymer Polymers 0.000 claims abstract description 11
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 10
125000000217 alkyl group Chemical group 0.000 claims abstract description 5
235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 4
239000000194 fatty acid Substances 0.000 claims abstract description 4
229930195729 fatty acid Natural products 0.000 claims abstract description 4
239000007900 aqueous suspension Substances 0.000 claims abstract description 3
125000005395 methacrylic acid group Chemical group 0.000 claims abstract description 3
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 32
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 32
239000000203 mixture Substances 0.000 claims description 28
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 18
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 16
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 13
239000003945 anionic surfactant Substances 0.000 claims description 6
238000007720 emulsion polymerization reaction Methods 0.000 claims description 5
150000001408 amides Chemical class 0.000 claims description 4
150000001735 carboxylic acids Chemical class 0.000 claims description 4
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 3
239000007795 chemical reaction product Substances 0.000 claims description 3
FZHYLXLEEBXHEG-UHFFFAOYSA-N 2-methyl-3-(2-methylpropoxy)prop-2-enamide Chemical compound CC(C)COC=C(C)C(N)=O FZHYLXLEEBXHEG-UHFFFAOYSA-N 0.000 claims 1
RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 claims 1
239000000243 solution Substances 0.000 description 22
239000000725 suspension Substances 0.000 description 22
239000000701 coagulant Substances 0.000 description 21
239000007787 solid Substances 0.000 description 21
238000004519 manufacturing process Methods 0.000 description 19
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
239000004094 surface-active agent Substances 0.000 description 16
229920000642 polymer Polymers 0.000 description 15
ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 14
229920000126 latex Polymers 0.000 description 14
238000000034 method Methods 0.000 description 13
239000003054 catalyst Substances 0.000 description 12
239000004816 latex Substances 0.000 description 12
150000003839 salts Chemical class 0.000 description 12
239000008367 deionised water Substances 0.000 description 11
229910021641 deionized water Inorganic materials 0.000 description 11
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 10
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 8
238000000151 deposition Methods 0.000 description 8
KCTMTGOHHMRJHZ-UHFFFAOYSA-N n-(2-methylpropoxymethyl)prop-2-enamide Chemical compound CC(C)COCNC(=O)C=C KCTMTGOHHMRJHZ-UHFFFAOYSA-N 0.000 description 8
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 7
238000005345 coagulation Methods 0.000 description 6
230000015271 coagulation Effects 0.000 description 6
239000000843 powder Substances 0.000 description 6
239000008149 soap solution Substances 0.000 description 6
229920002472 Starch Polymers 0.000 description 5
229910000019 calcium carbonate Inorganic materials 0.000 description 5
235000013870 dimethyl polysiloxane Nutrition 0.000 description 5
229920003052 natural elastomer Polymers 0.000 description 5
229920001194 natural rubber Polymers 0.000 description 5
229920000435 poly(dimethylsiloxane) Polymers 0.000 description 5
239000008107 starch Substances 0.000 description 5
235000019698 starch Nutrition 0.000 description 5
OYKPJMYWPYIXGG-UHFFFAOYSA-N 2,2-dimethylbutane;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CCC(C)(C)C OYKPJMYWPYIXGG-UHFFFAOYSA-N 0.000 description 4
229920002261 Corn starch Polymers 0.000 description 4
239000004908 Emulsion polymer Substances 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
239000008120 corn starch Substances 0.000 description 4
238000004132 cross linking Methods 0.000 description 4
239000011521 glass Substances 0.000 description 4
238000002386 leaching Methods 0.000 description 4
229910052751 metal Inorganic materials 0.000 description 4
239000002184 metal Substances 0.000 description 4
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
238000006116 polymerization reaction Methods 0.000 description 4
239000000047 product Substances 0.000 description 4
229920005573 silicon-containing polymer Polymers 0.000 description 4
239000002002 slurry Substances 0.000 description 4
239000000126 substance Substances 0.000 description 4
229920003051 synthetic elastomer Polymers 0.000 description 4
239000005061 synthetic rubber Substances 0.000 description 4
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical class N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 3
230000003115 biocidal effect Effects 0.000 description 3
239000003139 biocide Substances 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
230000008021 deposition Effects 0.000 description 3
150000005690 diesters Chemical class 0.000 description 3
238000000113 differential scanning calorimetry Methods 0.000 description 3
238000007598 dipping method Methods 0.000 description 3
SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 3
WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 3
238000001035 drying Methods 0.000 description 3
150000004678 hydrides Chemical class 0.000 description 3
230000001788 irregular Effects 0.000 description 3
239000000463 material Substances 0.000 description 3
239000011253 protective coating Substances 0.000 description 3
HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 3
229940001584 sodium metabisulfite Drugs 0.000 description 3
235000010262 sodium metabisulphite Nutrition 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
239000004971 Cross linker Substances 0.000 description 2
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
150000001252 acrylic acid derivatives Chemical class 0.000 description 2
239000012190 activator Substances 0.000 description 2
239000011324 bead Substances 0.000 description 2
238000005422 blasting Methods 0.000 description 2
230000000903 blocking effect Effects 0.000 description 2
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
239000000919 ceramic Substances 0.000 description 2
230000001112 coagulating effect Effects 0.000 description 2
239000004205 dimethyl polysiloxane Substances 0.000 description 2
239000003792 electrolyte Substances 0.000 description 2
NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 2
238000006459 hydrosilylation reaction Methods 0.000 description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
238000007654 immersion Methods 0.000 description 2
239000003112 inhibitor Substances 0.000 description 2
239000010985 leather Substances 0.000 description 2
238000005259 measurement Methods 0.000 description 2
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
238000002156 mixing Methods 0.000 description 2
239000003921 oil Substances 0.000 description 2
235000019198 oils Nutrition 0.000 description 2
229920003023 plastic Polymers 0.000 description 2
239000004033 plastic Substances 0.000 description 2
229910052697 platinum Inorganic materials 0.000 description 2
229910052573 porcelain Inorganic materials 0.000 description 2
230000000069 prophylactic effect Effects 0.000 description 2
230000001681 protective effect Effects 0.000 description 2
239000004576 sand Substances 0.000 description 2
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 2
239000000758 substrate Substances 0.000 description 2
239000000454 talc Substances 0.000 description 2
229910052623 talc Inorganic materials 0.000 description 2
235000019818 tetrasodium diphosphate Nutrition 0.000 description 2
238000011282 treatment Methods 0.000 description 2
229920001567 vinyl ester resin Polymers 0.000 description 2
OVYMWJFNQQOJBU-UHFFFAOYSA-N 1-octanoyloxypropan-2-yl octanoate Chemical compound CCCCCCCC(=O)OCC(C)OC(=O)CCCCCCC OVYMWJFNQQOJBU-UHFFFAOYSA-N 0.000 description 1
YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
XSCRXCDDATUDLB-UHFFFAOYSA-N 2-(2-methylpropoxymethyl)prop-2-enamide Chemical compound CC(C)COCC(=C)C(N)=O XSCRXCDDATUDLB-UHFFFAOYSA-N 0.000 description 1
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
HLCKAPCJELMQHY-UHFFFAOYSA-N 2-methylprop-2-enoic acid prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CC(=C)C(O)=O HLCKAPCJELMQHY-UHFFFAOYSA-N 0.000 description 1
DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 description 1
LVGFPWDANALGOY-UHFFFAOYSA-N 8-methylnonyl prop-2-enoate Chemical compound CC(C)CCCCCCCOC(=O)C=C LVGFPWDANALGOY-UHFFFAOYSA-N 0.000 description 1
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical class [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
206010013786 Dry skin Diseases 0.000 description 1
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
244000043261 Hevea brasiliensis Species 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
229920000881 Modified starch Polymers 0.000 description 1
JMWHWNRQSHESJR-UHFFFAOYSA-N OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CC(C)C(C)(C)C Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.CC(C)C(C)(C)C JMWHWNRQSHESJR-UHFFFAOYSA-N 0.000 description 1
239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical class [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
238000013006 addition curing Methods 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
239000000443 aerosol Substances 0.000 description 1
238000013019 agitation Methods 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical class [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
125000003277 amino group Chemical group 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
ROPXFXOUUANXRR-BUHFOSPRSA-N bis(2-ethylhexyl) (e)-but-2-enedioate Chemical compound CCCCC(CC)COC(=O)\C=C\C(=O)OCC(CC)CCCC ROPXFXOUUANXRR-BUHFOSPRSA-N 0.000 description 1
ROPXFXOUUANXRR-YPKPFQOOSA-N bis(2-ethylhexyl) (z)-but-2-enedioate Chemical compound CCCCC(CC)COC(=O)\C=C/C(=O)OCC(CC)CCCC ROPXFXOUUANXRR-YPKPFQOOSA-N 0.000 description 1
210000001124 body fluid Anatomy 0.000 description 1
239000010839 body fluid Substances 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000001110 calcium chloride Substances 0.000 description 1
229910001628 calcium chloride Inorganic materials 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
238000005660 chlorination reaction Methods 0.000 description 1
238000010073 coating (rubber) Methods 0.000 description 1
239000012141 concentrate Substances 0.000 description 1
238000010276 construction Methods 0.000 description 1
238000011109 contamination Methods 0.000 description 1
238000001816 cooling Methods 0.000 description 1
238000005336 cracking Methods 0.000 description 1
229920006037 cross link polymer Polymers 0.000 description 1
239000003431 cross linking reagent Substances 0.000 description 1
230000002542 deteriorative effect Effects 0.000 description 1
238000010586 diagram Methods 0.000 description 1
150000001991 dicarboxylic acids Chemical class 0.000 description 1
238000001938 differential scanning calorimetry curve Methods 0.000 description 1
235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
235000011180 diphosphates Nutrition 0.000 description 1
KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 1
230000037336 dry skin Effects 0.000 description 1
238000010894 electron beam technology Methods 0.000 description 1
125000004185 ester group Chemical group 0.000 description 1
WNMORWGTPVWAIB-UHFFFAOYSA-N ethenyl 2-methylpropanoate Chemical compound CC(C)C(=O)OC=C WNMORWGTPVWAIB-UHFFFAOYSA-N 0.000 description 1
MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
BLZSRIYYOIZLJL-UHFFFAOYSA-N ethenyl pentanoate Chemical compound CCCCC(=O)OC=C BLZSRIYYOIZLJL-UHFFFAOYSA-N 0.000 description 1
UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
239000000945 filler Substances 0.000 description 1
239000012467 final product Substances 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
230000026030 halogenation Effects 0.000 description 1
238000005658 halogenation reaction Methods 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
239000000017 hydrogel Substances 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
150000002632 lipids Chemical class 0.000 description 1
150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
239000011859 microparticle Substances 0.000 description 1
239000011707 mineral Substances 0.000 description 1
235000010755 mineral Nutrition 0.000 description 1
229920006173 natural rubber latex Polymers 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
125000001400 nonyl group Chemical class [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
YPMOZWCBANATQH-UHFFFAOYSA-N octyl 7-methyloctanoate Chemical compound CCCCCCCCOC(=O)CCCCCC(C)C YPMOZWCBANATQH-UHFFFAOYSA-N 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
239000002245 particle Substances 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229920006267 polyester film Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920005862 polyol Polymers 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
239000012254 powdered material Substances 0.000 description 1
238000010944 pre-mature reactiony Methods 0.000 description 1
PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
238000000746 purification Methods 0.000 description 1
230000005855 radiation Effects 0.000 description 1
229920002631 room-temperature vulcanizate silicone Polymers 0.000 description 1
238000007788 roughening Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000004447 silicone coating Substances 0.000 description 1
239000000344 soap Substances 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
CSMWJXBSXGUPGY-UHFFFAOYSA-L sodium dithionate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)S([O-])(=O)=O CSMWJXBSXGUPGY-UHFFFAOYSA-L 0.000 description 1
APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
238000005507 spraying Methods 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
238000004381 surface treatment Methods 0.000 description 1
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
238000001029 thermal curing Methods 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1
238000007666 vacuum forming Methods 0.000 description 1
235000015112 vegetable and seed oil Nutrition 0.000 description 1
239000008158 vegetable oil Substances 0.000 description 1
239000002699 waste material Substances 0.000 description 1
238000005303 weighing Methods 0.000 description 1
239000002023 wood Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Chemical class 0.000 description 1

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/14—Dipping a core
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L43/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Compositions of derivatives of such polymers
- C08L43/04—Homopolymers or copolymers of monomers containing silicon

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Polymers & Plastics (AREA)
Medicinal Chemistry (AREA)
Health & Medical Sciences (AREA)
Engineering & Computer Science (AREA)
Mechanical Engineering (AREA)
Wood Science & Technology (AREA)
Materials Engineering (AREA)
Life Sciences & Earth Sciences (AREA)
Paints Or Removers (AREA)
Laminated Bodies (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
Graft Or Block Polymers (AREA)
Moulding By Coating Moulds (AREA)
Compositions Of Macromolecular Compounds (AREA)
Macromonomer-Based Addition Polymer (AREA)
Gloves (AREA)
Processes Of Treating Macromolecular Substances (AREA)

IL11712396A 1995-02-14 1996-02-13 Acrylic emulsion coatings for rubber objects IL117123A (en)

Applications Claiming Priority (5)

Application Number	Priority Date	Filing Date	Title
US38957195A	1995-02-14	1995-02-14
US08/388,030 US5691069A (en)	1995-02-14	1995-02-14	Acrylic emulsion coatings for rubber articles
US48671095A	1995-06-07	1995-06-07
US08/486,948 US5712346A (en)	1995-02-14	1995-06-07	Acrylic emulsion coatings
US08/486,947 US5700585A (en)	1995-02-14	1995-06-07	Acrylic emulsion coatings for formed articles

Publications (2)

Publication Number	Publication Date
IL117123A0 IL117123A0 (en)	1996-06-18
IL117123A true IL117123A (en)	2002-04-21

Family

ID=27541414

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL11712396A IL117123A (en)	1995-02-14	1996-02-13	Acrylic emulsion coatings for rubber objects

Country Status (8)

Country	Link
EP (1)	EP0809565A4 (id)
JP (1)	JPH11507085A (id)
CN (1)	CN1078123C (id)
AU (1)	AU710920B2 (id)
CA (1)	CA2212861A1 (id)
ID (1)	ID23598A (id)
IL (1)	IL117123A (id)
WO (1)	WO1996025278A1 (id)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US6284856B1 (en) *	1995-02-14	2001-09-04	Avery Dennison Corporation	Acrylate, silicone, styrene, urethane copolymer coatings for natural and synthetic rubber articles
WO1999030888A1 (de) *	1997-12-17	1999-06-24	Münch Chemie Labor Gmbh	Vorrichtung und verfahren zur herstellung von puderfreien, proteinarmen tauchartikeln, insbesondere von operations- und untersuchungshandschuhen
KR100499958B1 (ko) *	1999-01-22	2005-07-11	에스케이씨 주식회사	이미지 수용층용 조성물 및 이로부터 형성된 이미지수용층을 구비한 고분자 필름
US6576337B1 (en) *	1999-07-28	2003-06-10	Precision Dippings Marketing Limited	Rubber articles adapted to make weldable seals; their manufacture and use
WO2002068168A2 (en) *	2001-02-21	2002-09-06	National Starch And Chemical Investment	Mold release and anti-blocking coating for powder-free natural or synthetic rubber articles
US20030118761A1 (en)	2001-12-21	2003-06-26	Kimberly-Clark Worldwide, Inc.	Elastomeric articles having improved chemical resistance
US6790933B2 (en) *	2002-08-16	2004-09-14	Kimberly-Clark Worldwide, Inc.	Low protein natural latex articles
US6872761B2 (en) *	2003-04-24	2005-03-29	Henkel Kommanditgesellschaft Auf Aktien	Compositions for acoustic-damping coatings
US7052642B2 (en)	2003-06-11	2006-05-30	Kimberly-Clark Worldwide, Inc.	Composition for forming an elastomeric article
US7767251B2 (en) *	2005-03-16	2010-08-03	Shiping Wang	Repellent elastomeric article
CL2007003131A1 (es) *	2006-11-01	2008-07-04	Lucite Int Inc	Metodo para fabricar un articulo que comprende formular composicion acrilica que tiene un agente de transferencia con grupo que reacciona con isocianato y luego unir a una composicion que contiene isocianato; articulo; metodo que mejora la eficiencia
CN110194815B (zh)	2013-10-29	2022-12-30	阿利吉安斯公司	亲水/疏水的水性聚合物乳液和与其相关的产品和方法
TWI609640B (zh) *	2016-07-12	2018-01-01	帝藝國際貿易股份有限公司	用於製備手套之組合物及利用其製備手套之方法
WO2018174190A1 (ja) *	2017-03-23	2018-09-27	株式会社ネオス	表面処理剤及びその製造方法
CN114276729A (zh) *	2020-09-17	2022-04-05	顶级手套国际有限公司	一种用于涂覆弹性体制品的无硅聚合物涂料组合物及制备其涂覆的弹性体制品的方法
CN112592433A (zh) *	2020-11-27	2021-04-02	擎天材料科技有限公司	水性丙烯酸树脂、涂料组合物及其应用

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US2795564A (en) *	1953-05-13	1957-06-11	Rohm & Haas	Aqueous paint bases and water-base paints and process for preparing them
US3255492A (en) *	1961-05-31	1966-06-14	Galen Entpr Inc	Form for casting seamless, ambidextrous plastic gloves
US4027060A (en) *	1973-10-12	1977-05-31	Sutures, Inc.	Rubber articles having improved slip coatings
FR2272156A2 (en) *	1974-05-21	1975-12-19	Du Pont	Aqueous coating compsn. for flexible substrates - contg. acrylic resin based on four monomers and alkylated melamine-formaldehyde resin
CA1049345A (en) *	1975-06-24	1979-02-27	Pascal E. Esemplare	Rubber articles having improved slip coating
GB8507221D0 (en) *	1985-03-20	1985-04-24	Courtaulds Plc	Polymer compositions
US5214095A (en) *	1988-07-07	1993-05-25	Rohm And Haas Company	Stable aqueous emulsion copolymers with siloxane functionality
ZA90339B (en) *	1989-01-31	1990-12-28	Ici Australia Operations	Silicone coating compositions
US5069965A (en) *	1989-10-18	1991-12-03	Bioresearch, Inc.	Articles having improved slip coatings
US5084514A (en) *	1990-11-14	1992-01-28	Reichhold Chemicals, Inc.	Latex gloves with improved donnability
FR2684107B1 (fr) *	1991-11-27	1995-06-23	Rhone Poulenc Chimie	Dispersions aqueuses de polymeres styrene-acrylate carboxyle et leurs utilisations comme liant dans des compositions adhesives et de revetement.
JP2663079B2 (ja) *	1992-05-05	1997-10-15	昭和高分子株式会社	水性撥水加工用コーティング剤
CA2180839C (en) *	1994-04-20	2000-08-08	Toyoaki Yamauchi	Aqueous silicone-modified acrylate polymer emulsion
AU4920696A (en) *	1995-02-14	1996-09-04	Allegiance Corporation	A multiple dip process for making a powder-free article
US5661208A (en) *	1995-08-11	1997-08-26	Dow Corning Corporation	Rubber and vinyl protectant

1996
- 1996-02-12 WO PCT/US1996/001866 patent/WO1996025278A1/en not_active Ceased
- 1996-02-12 AU AU49775/96A patent/AU710920B2/en not_active Ceased
- 1996-02-12 CN CN96192822A patent/CN1078123C/zh not_active Expired - Fee Related
- 1996-02-12 EP EP96906380A patent/EP0809565A4/en not_active Withdrawn
- 1996-02-12 JP JP8525055A patent/JPH11507085A/ja active Pending
- 1996-02-12 CA CA002212861A patent/CA2212861A1/en not_active Abandoned
- 1996-02-13 IL IL11712396A patent/IL117123A/en not_active IP Right Cessation
- 1996-02-14 ID IDP990915D patent/ID23598A/id unknown

Also Published As

Publication number	Publication date
CA2212861A1 (en)	1996-08-22
JPH11507085A (ja)	1999-06-22
EP0809565A1 (en)	1997-12-03
WO1996025278A1 (en)	1996-08-22
MX9706202A (es)	1997-10-31
CN1179745A (zh)	1998-04-22
ID23598A (id)	1996-08-22
AU710920B2 (en)	1999-09-30
IL117123A0 (en)	1996-06-18
EP0809565A4 (en)	1998-05-06
CN1078123C (zh)	2002-01-23
AU4977596A (en)	1996-09-04

Legal Events

Date	Code	Title
2002-09-12	FF	Patent granted
2002-09-12	KB	Patent renewed
2006-10-30	MM9K	Patent not in force due to non-payment of renewal fees

Publication	Publication Date	Title
US5700585A (en)	1997-12-23	Acrylic emulsion coatings for formed articles
US5691069A (en)	1997-11-25	Acrylic emulsion coatings for rubber articles
US6284856B1 (en)	2001-09-04	Acrylate, silicone, styrene, urethane copolymer coatings for natural and synthetic rubber articles
AU710920B2 (en)	1999-09-30	Acrylic emulsion coatings for rubber articles
EP0199318B1 (en)	1993-03-03	Dipped rubber article
JP2871099B2 (ja)	1999-03-17	柔軟性ポリ塩化ビニル製品およびその製造方法
EP1317500B1 (en)	2005-12-21	Polymer coating for rubber articles
JPH04292631A (ja)	1992-10-16	離型性および装着性が改良されたラテックス手袋
WO1991005657A1 (en)	1991-05-02	Articles having improved slip coatings
JP2005533674A (ja)	2005-11-10	改良した把持面を有するエラストマー性物品
US20050182156A1 (en)	2005-08-18	Glove made with non-toxic plasticizer ATBC
AU747769B2 (en)	2002-05-23	Acrylic emulsion compositions and process for the production of rubber articles
KR100433993B1 (ko)	2004-09-16	고무제품용아크릴에멀젼코팅
MXPA97006202A (en)	1998-07-03	Acrylic claddings in emulsion for articles of hule or cau
US20040022980A1 (en)	2004-02-05	Water-based coating for rubber articles
US20030175500A1 (en)	2003-09-18	Polymer coating for rubber articles
JPH115284A (ja)	1999-01-12	農業用ポリエチレンテレフタレートフィルム
TH41108B (th)	2014-08-14	การเคลือบด้วยอะครีลิค อิมัลชั่น สำหรับวัตถุประเภทยาง