IL146696A0 - Synthesis method for polymers by controlled radical polymerisation using halogenated xanthates - Google Patents

Synthesis method for polymers by controlled radical polymerisation using halogenated xanthates

Info

Publication number
IL146696A0
IL146696A0 IL14669600A IL14669600A IL146696A0 IL 146696 A0 IL146696 A0 IL 146696A0 IL 14669600 A IL14669600 A IL 14669600A IL 14669600 A IL14669600 A IL 14669600A IL 146696 A0 IL146696 A0 IL 146696A0
Authority
IL
Israel
Prior art keywords
polymers
synthesis method
radical polymerisation
controlled radical
halogenated
Prior art date
Application number
IL14669600A
Other languages
English (en)
Original Assignee
Rhodia Chimie Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Chimie Sa filed Critical Rhodia Chimie Sa
Publication of IL146696A0 publication Critical patent/IL146696A0/xx

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/14Methyl esters, e.g. methyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00Living radical polymerisation
    • C08F2438/03Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)
IL14669600A 1999-06-04 2000-05-26 Synthesis method for polymers by controlled radical polymerisation using halogenated xanthates IL146696A0 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9907096A FR2794463B1 (fr) 1999-06-04 1999-06-04 Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates halogenes
PCT/FR2000/001438 WO2000075207A1 (fr) 1999-06-04 2000-05-26 Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates halogenes

Publications (1)

Publication Number Publication Date
IL146696A0 true IL146696A0 (en) 2002-07-25

Family

ID=9546404

Family Applications (1)

Application Number Title Priority Date Filing Date
IL14669600A IL146696A0 (en) 1999-06-04 2000-05-26 Synthesis method for polymers by controlled radical polymerisation using halogenated xanthates

Country Status (13)

Country Link
US (1) US6777513B1 (de)
EP (1) EP1185570B1 (de)
JP (1) JP3542580B2 (de)
AT (1) ATE293133T1 (de)
AU (1) AU5409900A (de)
CA (1) CA2375849A1 (de)
CZ (1) CZ20014337A3 (de)
DE (1) DE60019419T2 (de)
FR (1) FR2794463B1 (de)
IL (1) IL146696A0 (de)
MX (1) MXPA01012511A (de)
WO (1) WO2000075207A1 (de)
ZA (1) ZA200109549B (de)

Families Citing this family (87)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6716948B1 (en) 1999-07-31 2004-04-06 Symyx Technologies, Inc. Controlled-architecture polymers and use thereof as separation media
FR2802208B1 (fr) 1999-12-09 2003-02-14 Rhodia Chimie Sa Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates
KR20030081462A (ko) * 2001-02-26 2003-10-17 로디아 쉬미 저에너지 표면의 친수성을 증가시키기 위한 양쪽성 블록코폴리머의 용도
FR2829140B1 (fr) * 2001-09-05 2003-12-19 Rhodia Chimie Sa Procede de synthese de polymeres a fonctions thiols
FR2821620B1 (fr) * 2001-03-02 2003-06-27 Coatex Sas Procede de polymerisation radicalaire controlee de l'acide acrylique et de ses sels, les polymeres de faible polydispersite obtenus, et leurs applications
WO2002090409A2 (fr) * 2001-05-04 2002-11-14 Rhodia Chimie Copolymeres a blocs tensioactifs prepares par polymerisation radicalaire controlee
FR2826658B1 (fr) 2001-06-29 2003-09-05 Rhodia Chimie Sa Synthese de polymeres par voie radicalaire controlee en miniemulsion
FR2829494B1 (fr) * 2001-07-13 2005-10-28 Rhodia Chimie Sa Compositions aqueuses comprenant un microgel chimique associe a un polymere pontant, preparation et utilisation
US6855840B2 (en) 2002-02-11 2005-02-15 University Of Southern Mississippi Chain transfer agents for raft polymerization in aqueous media
US20030158078A1 (en) * 2002-02-11 2003-08-21 Jeanne Chang Detergent composition comprising a block copolymer
FR2835826A1 (fr) 2002-02-14 2003-08-15 Rhodianyl Materiaux composites obtenus a partir de liant hydraulique et de fibres organiques presentant un comportement mecanique ameliore
US6667376B2 (en) * 2002-03-22 2003-12-23 Symyx Technologies, Inc. Control agents for living-type free radical polymerization and methods of polymerizing
FR2842190A1 (fr) 2002-07-10 2004-01-16 Rhodia Performance Fibres Materiaux composites renforces comprenant un liant hydraulique ou chimique,des fibres de polyamide ainsi qu'un ou plusieurs additifs pour comportement mecanique ameliore
FR2842814B1 (fr) * 2002-07-26 2004-10-22 Coatex Sas Procede de polymerisation radicalaire controlee de l'acide acrylique et de ses sels, les polymeres obtenus, et leurs applications.
FR2846973B1 (fr) 2002-11-07 2004-12-17 Rhodia Chimie Sa Composition d'antifroissage comprenant un copolymere a architecture controlee, pour articles en fibres textiles
FR2848556B1 (fr) 2002-12-13 2006-06-16 Bio Merieux Procede de polymerisation radicalaire controlee
US6919409B2 (en) 2003-06-26 2005-07-19 Symyx Technologies, Inc. Removal of the thiocarbonylthio or thiophosphorylthio end group of polymers and further functionalization thereof
JP4725739B2 (ja) 2003-06-26 2011-07-13 Jsr株式会社 フォトレジストポリマー組成物
WO2005000924A1 (en) 2003-06-26 2005-01-06 Symyx Technologies, Inc. Photoresist polymers
US7250475B2 (en) 2003-06-26 2007-07-31 Symyx Technologies, Inc. Synthesis of photoresist polymers
EP1660548B1 (de) * 2003-09-03 2008-08-27 Rhodia Inc. Neues copolymer mit kontrolliertem aufbau und verwendung davon
FR2872038A1 (fr) * 2004-06-23 2005-12-30 Rhodia Chimie Sa Composition cosmetique comprenant un polyorganosiloxane et ses utilisations
FR2872039B1 (fr) * 2004-06-23 2006-08-04 Rhodia Chimie Sa Composition cosmetique comprenant un polyorganosiloxane et ses utilisations
JP2008504411A (ja) 2004-07-01 2008-02-14 ウニベルズィタイト・ヘント (アルキル)アクリル酸部分を含有する単分散性ポリマー、前駆体およびその作製方法ならびにその適用
US7279446B2 (en) 2004-11-15 2007-10-09 Rhodia Inc. Viscoelastic surfactant fluids having enhanced shear recovery, rheology and stability performance
RU2401281C2 (ru) 2005-01-11 2010-10-10 Циба Спешиалти Кемикэлз Холдинг Инк. Способ постмодификации гомо- и сополимеров, полученных регулируемыми процессами свободнорадикальной полимеризации
FR2883291B1 (fr) * 2005-03-17 2010-03-05 Rhodia Chimie Sa Copolymere a blocs pouvant etre utile comme tenseur
FR2885367B1 (fr) * 2005-05-03 2007-07-27 Rhodia Chimie Sa Organosol stabilise par des polymeres sequences amphiphiles
EP1926761A1 (de) * 2005-05-23 2008-06-04 Rhodia Opérations Von vinylphosphonatmonomeren abgeleitetes copolymer mit kontrollierter architektur, herstellungsverfahren dafür und verwendungen davon
JP5000904B2 (ja) * 2006-03-15 2012-08-15 株式会社クラレ 末端にメルカプト基を有するポリビニルアルコール系重合体の製造方法
ATE431368T1 (de) * 2006-08-17 2009-05-15 Rhodia Operations Blockcopolymere, verfahren zu deren herstellung und ihre verwendung in emulsionen
FR2911609B1 (fr) * 2007-01-19 2009-03-06 Rhodia Recherches & Tech Copolymere dibloc comprenant des unites derivant du styrene et des unites derivant d'acide acrylique
FR2923487B1 (fr) * 2007-11-09 2009-12-04 Rhodia Operations Copolymere ampholyte a architecture controlee
FI122734B (fi) 2007-05-21 2012-06-15 Kemira Oyj Prosessikemikaali käytettäväksi paperin tai kartongin valmistuksessa
FR2917415B1 (fr) * 2007-06-14 2012-10-12 Rhodia Recherches Et Tech Microgel polymerique comprenant des unites cationiques
FR2921663A1 (fr) 2007-10-02 2009-04-03 Bluestar Silicones France Soc Polyorganosiloxanes a fonction piperidine depourvus de toxicite par contact cutane et utilisation de ces derniers dans des compositions cosmetiques
FR2934154B1 (fr) * 2008-07-23 2010-08-13 Rhodia Operations Emulsions thermosensibles
EP2160945A1 (de) 2008-09-09 2010-03-10 Polymers CRC Limited Antimikrobieller Artikel
EP2160946A1 (de) 2008-09-09 2010-03-10 Polymers CRC Limited Verfahren zur Herstellung eines antimikrobiellen Artikels
FR2937336B1 (fr) 2008-10-22 2011-06-10 Rhodia Operations Composition pour les soins menagers comprenant un nanogel cationique
FR2965264B1 (fr) 2010-09-27 2013-11-29 Rhodia Operations Polymerisation radicalaire controlee de n-vinyl lactames en milieu aqueux
FR2965564B1 (fr) 2010-09-30 2012-10-26 Rhodia Operations Preparation de polymeres hydrophiles de haute masse par polymerisation radicalaire controlee
CN102020744B (zh) * 2010-11-17 2012-07-11 江苏苏博特新材料股份有限公司 醋酸乙烯酯类无皂乳液、可再分散性胶粉及其制备方法
EP2551338A1 (de) 2011-07-27 2013-01-30 Henkel AG & Co. KGaA Waschmittel mit Fleckenentfernungseigenschaften
BR112014009835B1 (pt) 2011-10-24 2021-03-02 Rhodia Operations processo de preparação de polímeros em bloco anfifílicos por polimerização radicalar micelar controlada, polímero em bloco e utilização do polímero
EP2809697B1 (de) 2012-01-31 2017-07-19 Rhodia Operations Lebende poly-(n-vinyl lactam-)reaktive stabilisatoren für eine polymerisierung dispergierter phasen
EP2809698B1 (de) 2012-01-31 2016-01-27 Rhodia Operations Polymerisation von halogenierten vinylmonomeren in der dispergierten phase in anwesenheit von lebenden reaktiven stabilisatoren
FR2987837B1 (fr) 2012-03-09 2014-03-14 Rhodia Operations Polymerisation radicalaire controlee en dispersion eau-dans-l'eau
FR3004458A1 (fr) 2013-04-11 2014-10-17 Rhodia Operations Fluides de fracturation a base de polymeres associatifs et de tensioactifs labiles
FR3011555A1 (fr) 2013-10-04 2015-04-10 Rhodia Operations Polymeres sequences pour le controle du filtrat
EP2896637A1 (de) 2014-01-21 2015-07-22 Rhodia Operations Copolymer mit Einheiten des Typs A, abgeleitet von Carbonsäuremonomeren und Einheiten von Typ B, abgeleitet von Sulfonsäuremonomeren
US10377843B2 (en) 2014-05-12 2019-08-13 Solvay Specialty Polymers Italy S.P.A. Method for the controlled polymerization of fluoromonomers
FR3027309B1 (fr) 2014-10-17 2018-08-10 Rhodia Operations Polymeres polyfonctionnels a base d'unites phosphonates et d'unites amines
FR3034776A1 (fr) 2015-04-07 2016-10-14 Rhodia Operations Polymeres sequences pour le controle du filtrat
FR3034777A1 (fr) 2015-04-07 2016-10-14 Rhodia Operations Polymeres sequences pour le controle du filtrat et de la rheologie
FR3034768B1 (fr) 2015-04-07 2017-05-05 Rhodia Operations Polymeres sequences pour le controle du filtrat
EP3292189A2 (de) 2015-05-04 2018-03-14 Rhodia Operations Copolymere zur schmierung von metallen
FR3037074B1 (fr) 2015-06-03 2017-07-14 Rhodia Operations Agents de suspension obtenus par polymerisation micellaire
FR3043083B1 (fr) 2015-10-30 2019-04-19 Rhodia Operations Polymeres sequences amphiphiles solubles en milieu fortement salin
BR122022001868B1 (pt) 2015-12-10 2022-09-13 Adama Makhteshim Ltd. Composição de material agrícola, método de controle e prevenção de peste e de aperfeiçoamento do crescimento de planta, processo de preparo da composição de material agrícola e uso de um copolímero em bloco
WO2017103635A1 (en) 2015-12-16 2017-06-22 Rhodia Poliamida E Especialidades Ltda Emulsifier system for explosive emulsions
MX2019006158A (es) 2016-11-29 2019-09-09 Rhodia Operations Sistemas polimerícos para dispersión de partículas.
FR3064641A1 (fr) 2017-04-03 2018-10-05 Rhodia Operations Association pour le controle du filtrat et la migration de gaz
FR3070043B1 (fr) 2017-08-09 2019-08-16 Rhodia Operations Formulation contenant un polymere associatif
PL3682042T3 (pl) 2017-09-14 2022-04-04 Chemetall Gmbh Sposób wstępnej obróbki materiałów aluminiowych, w szczególności kół aluminiowych
WO2019121298A1 (fr) 2017-12-19 2019-06-27 Rhodia Operations Formulations aqueuses de tensioactifs et polymeres associatifs pour la recuperation assistee du petrole
US11118100B2 (en) 2017-12-20 2021-09-14 Rhodia Operations Polymeric systems for particle dispersion
AR114185A1 (es) 2018-01-23 2020-07-29 Adama Makhteshim Ltd Síntesis de 5-cloro-2-[(3,4,4-trifluoro-3-buten-1-il)tio]-tiazol
FR3079833B1 (fr) 2018-04-10 2020-10-09 Rhodia Operations Composition aqueuse gelifiee pour l'extraction petroliere
FR3083238A1 (fr) 2018-07-02 2020-01-03 Rhodia Operations Relargage progressif de chaines polymeres en milieu liquide
JP2022501519A (ja) 2018-07-05 2022-01-06 ケメタル ゲゼルシャフト ミット ベシュレンクテル ハフツング 金属表面を酸性水性組成物で処理して腐食抵抗性を改善する方法
MX2021000135A (es) 2018-07-05 2021-03-25 Chemetall Gmbh Metodo para el tratamiento de superficies metalicas con una composicion acuosa acida y una composicion post-enjuague para mejorar la resistencia a la corrosion.
CN113166947B (zh) 2018-09-07 2023-05-26 凯密特尔有限责任公司 处理含铝基底的表面的方法
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KR20210093242A (ko) 2018-10-08 2021-07-27 케메탈 게엠베하 금속 표면의 ni-무함유 인산염처리 방법 및 이러한 방법에 사용하기 위한 조성물
CN112888809A (zh) 2018-10-08 2021-06-01 凯密特尔有限责任公司 金属表面的无镍磷化方法和用于这种方法的组合物
WO2020173725A1 (en) 2019-02-28 2020-09-03 Rhodia Operations Compositions for high stabilization of emulsions
FR3093514A1 (fr) 2019-03-05 2020-09-11 Rhodia Operations Suspension de polymères associatifs pour le traitement de formations souterraines
CN113557284A (zh) 2019-03-12 2021-10-26 罗地亚经营管理公司 稳定化的减摩剂乳液
MX2021010694A (es) 2019-03-15 2021-10-01 Rhodia Operations Composiciones de polimero y uso de las mismas.
KR102714209B1 (ko) * 2019-12-18 2024-10-04 주식회사 엘지화학 고흡수성 수지의 제조 방법
CN114829473A (zh) 2019-12-20 2022-07-29 罗地亚经营管理公司 用于断裂聚合物的方法
JP6989792B2 (ja) 2019-12-25 2022-01-12 ダイキン工業株式会社 フルオロポリマーの製造方法
MX2023004398A (es) 2020-10-23 2023-07-11 Energy Solutions Us Llc Sistemas polimericos que tienen viscosidad mejorada y propiedades de transporte de apuntalantes.
FR3125296A1 (fr) 2021-07-13 2023-01-20 Rhodia Operations Préparation de polymères séquencés amphiphiles par polymérisation radicalaire micellaire inverse
CN115785576B (zh) * 2022-12-06 2024-04-05 合肥工业大学 一种耐γ-射线辐照可陶瓷化阻燃耐火电缆护套材料及其制备方法
WO2025204124A1 (ja) * 2024-03-29 2025-10-02 Agc株式会社 ポリマーの製造方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3862975A (en) * 1973-07-31 1975-01-28 Goodrich Co B F Process for preparing liquid xanthate-terminated polymers
ATE166363T1 (de) * 1991-02-06 1998-06-15 Commw Scient Ind Res Org Polymerisationsregelung
ES2166092T3 (es) * 1996-07-10 2002-04-01 Du Pont Polimerizacion con caracteristicas vivientes.
FR2764892B1 (fr) * 1997-06-23 2000-03-03 Rhodia Chimie Sa Procede de synthese de polymeres a blocs
CA2309279C (en) * 1997-12-18 2009-07-14 E.I. Du Pont De Nemours And Company Polymerization process with living characteristics and polymers made therefrom
FR2773161B1 (fr) * 1997-12-31 2000-01-21 Rhodia Chimie Sa Procede de synthese de polymeres a blocs
FR2814168B1 (fr) 2000-09-18 2006-11-17 Rhodia Chimie Sa Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee en presence d'un compose disulfure

Also Published As

Publication number Publication date
CZ20014337A3 (cs) 2002-05-15
ATE293133T1 (de) 2005-04-15
JP3542580B2 (ja) 2004-07-14
EP1185570A1 (de) 2002-03-13
FR2794463A1 (fr) 2000-12-08
CA2375849A1 (fr) 2000-12-14
DE60019419D1 (de) 2005-05-19
DE60019419T2 (de) 2006-03-09
AU5409900A (en) 2000-12-28
JP2003501528A (ja) 2003-01-14
WO2000075207A1 (fr) 2000-12-14
US6777513B1 (en) 2004-08-17
ZA200109549B (en) 2002-08-26
EP1185570B1 (de) 2005-04-13
FR2794463B1 (fr) 2005-02-25
MXPA01012511A (es) 2002-07-02

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