IL84329A - Proxycarboxylic acid sulfonic acids, their preparation and the bleaching mixtures containing them - Google Patents

Proxycarboxylic acid sulfonic acids, their preparation and the bleaching mixtures containing them

Info

Publication number: IL84329A
Authority: IL; Israel
Prior art keywords: group; compound; composition; acid; ooh
Prior art date: 1986-11-03

Application number

IL8432987A

Other languages

English (en)

Hebrew (he)

Other versions

IL84329A0 (en

Original Assignee

Monsanto Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-11-03

Filing date

1987-11-02

Publication date

1995-03-30

1987-11-02 Application filed by Monsanto Co filed Critical Monsanto Co

1988-04-29 Publication of IL84329A0 publication Critical patent/IL84329A0/xx

1995-03-30 Publication of IL84329A publication Critical patent/IL84329A/en

Links

239000000203 mixture Substances 0.000 title claims abstract description 123
239000007844 bleaching agent Substances 0.000 title claims abstract description 32
239000002253 acid Substances 0.000 title abstract description 52
150000007513 acids Chemical class 0.000 title abstract description 39
150000003457 sulfones Chemical class 0.000 title abstract description 33
238000002360 preparation method Methods 0.000 title description 20
125000004432 carbon atom Chemical group C* 0.000 claims abstract description 47
239000003599 detergent Substances 0.000 claims abstract description 33
229910052799 carbon Inorganic materials 0.000 claims abstract description 10
229910052717 sulfur Inorganic materials 0.000 claims abstract description 5
125000004434 sulfur atom Chemical group 0.000 claims abstract description 5
150000001875 compounds Chemical class 0.000 claims description 63
229910052760 oxygen Inorganic materials 0.000 claims description 50
239000001301 oxygen Substances 0.000 claims description 50
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 49
239000007787 solid Substances 0.000 claims description 44
125000000217 alkyl group Chemical group 0.000 claims description 39
238000000034 method Methods 0.000 claims description 38
238000004061 bleaching Methods 0.000 claims description 37
SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical compound OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 claims description 29
230000008569 process Effects 0.000 claims description 21
229910014569 C—OOH Inorganic materials 0.000 claims description 17
239000004094 surface-active agent Substances 0.000 claims description 17
125000003118 aryl group Chemical group 0.000 claims description 10
239000003945 anionic surfactant Substances 0.000 claims description 9
XCRBXWCUXJNEFX-UHFFFAOYSA-N peroxybenzoic acid Chemical group OOC(=O)C1=CC=CC=C1 XCRBXWCUXJNEFX-UHFFFAOYSA-N 0.000 claims description 9
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 7
125000000129 anionic group Chemical group 0.000 claims description 6
125000001183 hydrocarbyl group Chemical group 0.000 claims description 6
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
239000002736 nonionic surfactant Substances 0.000 claims description 4
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
239000002888 zwitterionic surfactant Substances 0.000 claims description 3
239000012736 aqueous medium Substances 0.000 claims description 2
125000003884 phenylalkyl group Chemical group 0.000 claims 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 73
239000000047 product Substances 0.000 description 50
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 44
229910001868 water Inorganic materials 0.000 description 36
239000000463 material Substances 0.000 description 32
-1 sulfone peroxy-carboxylic acid compound Chemical class 0.000 description 31
239000011541 reaction mixture Substances 0.000 description 29
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 27
239000004327 boric acid Substances 0.000 description 27
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 26
239000000243 solution Substances 0.000 description 25
229960002163 hydrogen peroxide Drugs 0.000 description 22
239000003795 chemical substances by application Substances 0.000 description 21
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 18
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
150000003839 salts Chemical class 0.000 description 18
238000009472 formulation Methods 0.000 description 17
239000011734 sodium Substances 0.000 description 17
229910052708 sodium Inorganic materials 0.000 description 17
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 15
238000012360 testing method Methods 0.000 description 15
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 14
AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 14
238000013019 agitation Methods 0.000 description 14
238000001816 cooling Methods 0.000 description 14
239000002243 precursor Substances 0.000 description 14
150000004965 peroxy acids Chemical group 0.000 description 13
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
239000008367 deionised water Substances 0.000 description 12
229910021641 deionized water Inorganic materials 0.000 description 12
230000000694 effects Effects 0.000 description 11
239000004744 fabric Substances 0.000 description 11
239000011521 glass Substances 0.000 description 11
238000010438 heat treatment Methods 0.000 description 11
150000002148 esters Chemical class 0.000 description 10
238000001914 filtration Methods 0.000 description 10
239000004615 ingredient Substances 0.000 description 10
239000002245 particle Substances 0.000 description 9
238000010992 reflux Methods 0.000 description 9
238000003860 storage Methods 0.000 description 9
238000006243 chemical reaction Methods 0.000 description 8
239000002002 slurry Substances 0.000 description 8
125000001174 sulfone group Chemical group 0.000 description 8
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 7
239000012190 activator Substances 0.000 description 7
239000007795 chemical reaction product Substances 0.000 description 7
239000000975 dye Substances 0.000 description 7
239000008187 granular material Substances 0.000 description 7
229940098779 methanesulfonic acid Drugs 0.000 description 7
239000003760 tallow Substances 0.000 description 7
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
229960000583 acetic acid Drugs 0.000 description 6
229910052783 alkali metal Inorganic materials 0.000 description 6
150000001340 alkali metals Chemical class 0.000 description 6
235000014113 dietary fatty acids Nutrition 0.000 description 6
239000000194 fatty acid Substances 0.000 description 6
229930195729 fatty acid Natural products 0.000 description 6
238000010979 pH adjustment Methods 0.000 description 6
239000011591 potassium Substances 0.000 description 6
229910052700 potassium Inorganic materials 0.000 description 6
239000000843 powder Substances 0.000 description 6
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
239000004698 Polyethylene Substances 0.000 description 5
230000002378 acidificating effect Effects 0.000 description 5
239000000460 chlorine Substances 0.000 description 5
229910052801 chlorine Inorganic materials 0.000 description 5
239000011248 coating agent Substances 0.000 description 5
238000000576 coating method Methods 0.000 description 5
150000004665 fatty acids Chemical class 0.000 description 5
239000003921 oil Substances 0.000 description 5
235000019198 oils Nutrition 0.000 description 5
238000005502 peroxidation Methods 0.000 description 5
229920000573 polyethylene Polymers 0.000 description 5
150000004760 silicates Chemical class 0.000 description 5
238000005406 washing Methods 0.000 description 5
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 4
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 4
235000013162 Cocos nucifera Nutrition 0.000 description 4
244000060011 Cocos nucifera Species 0.000 description 4
229920000742 Cotton Polymers 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
229920000388 Polyphosphate Polymers 0.000 description 4
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
125000001931 aliphatic group Chemical group 0.000 description 4
238000004458 analytical method Methods 0.000 description 4
150000004649 carbonic acid derivatives Chemical class 0.000 description 4
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
238000000605 extraction Methods 0.000 description 4
239000012362 glacial acetic acid Substances 0.000 description 4
125000000623 heterocyclic group Chemical group 0.000 description 4
239000012071 phase Substances 0.000 description 4
239000001205 polyphosphate Substances 0.000 description 4
235000011176 polyphosphates Nutrition 0.000 description 4
159000000001 potassium salts Chemical class 0.000 description 4
239000000344 soap Substances 0.000 description 4
GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
239000002904 solvent Substances 0.000 description 4
230000006641 stabilisation Effects 0.000 description 4
238000011105 stabilization Methods 0.000 description 4
239000012258 stirred mixture Substances 0.000 description 4
238000003756 stirring Methods 0.000 description 4
125000001424 substituent group Chemical group 0.000 description 4
238000004448 titration Methods 0.000 description 4
ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 4
239000010457 zeolite Substances 0.000 description 4
GWOLZNVIRIHJHB-UHFFFAOYSA-N 11-mercaptoundecanoic acid Chemical compound OC(=O)CCCCCCCCCCS GWOLZNVIRIHJHB-UHFFFAOYSA-N 0.000 description 3
FBFBNGJZFXSFFY-UHFFFAOYSA-N 3-(2-carboxyethylsulfonyl)propanoic acid Chemical compound OC(=O)CCS(=O)(=O)CCC(O)=O FBFBNGJZFXSFFY-UHFFFAOYSA-N 0.000 description 3
HJOHWICBMURIRO-UHFFFAOYSA-N 3-cyclohexylsulfonylpropanoic acid Chemical compound OC(=O)CCS(=O)(=O)C1CCCCC1 HJOHWICBMURIRO-UHFFFAOYSA-N 0.000 description 3
NQMGODXTYQRCQN-UHFFFAOYSA-N 3-decylsulfonylpropanoic acid Chemical compound CCCCCCCCCCS(=O)(=O)CCC(O)=O NQMGODXTYQRCQN-UHFFFAOYSA-N 0.000 description 3
ZFCZFJRIZRQGCJ-UHFFFAOYSA-N 4-methylsulfonylbenzenecarboperoxoic acid Chemical compound CS(=O)(=O)C1=CC=C(C(=O)OO)C=C1 ZFCZFJRIZRQGCJ-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical class C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
IAZDPXIOMUYVGZ-WFGJKAKNSA-N Dimethyl sulfoxide Chemical compound [2H]C([2H])([2H])S(=O)C([2H])([2H])[2H] IAZDPXIOMUYVGZ-WFGJKAKNSA-N 0.000 description 3
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
229910019142 PO4 Inorganic materials 0.000 description 3
XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
150000001412 amines Chemical class 0.000 description 3
229940077388 benzenesulfonate Drugs 0.000 description 3
239000002738 chelating agent Substances 0.000 description 3
235000019864 coconut oil Nutrition 0.000 description 3
239000003240 coconut oil Substances 0.000 description 3
238000000354 decomposition reaction Methods 0.000 description 3
239000000706 filtrate Substances 0.000 description 3
125000002768 hydroxyalkyl group Chemical group 0.000 description 3
239000005457 ice water Substances 0.000 description 3
239000007791 liquid phase Substances 0.000 description 3
238000002156 mixing Methods 0.000 description 3
235000021317 phosphate Nutrition 0.000 description 3
150000003013 phosphoric acid derivatives Chemical class 0.000 description 3
229910052698 phosphorus Inorganic materials 0.000 description 3
239000011574 phosphorus Substances 0.000 description 3
229920005646 polycarboxylate Polymers 0.000 description 3
230000035484 reaction time Effects 0.000 description 3
CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
235000019832 sodium triphosphate Nutrition 0.000 description 3
239000012265 solid product Substances 0.000 description 3
239000003381 stabilizer Substances 0.000 description 3
150000003462 sulfoxides Chemical class 0.000 description 3
238000005303 weighing Methods 0.000 description 3
IUDGNRWYNOEIKF-UHFFFAOYSA-N 11-bromo-undecanoic acid Chemical compound OC(=O)CCCCCCCCCCBr IUDGNRWYNOEIKF-UHFFFAOYSA-N 0.000 description 2
LSGYPWJMTUEPTF-UHFFFAOYSA-N 2-(2-carbonoperoxoylphenyl)sulfonylbenzenecarboperoxoic acid Chemical compound OOC(=O)C1=CC=CC=C1S(=O)(=O)C1=CC=CC=C1C(=O)OO LSGYPWJMTUEPTF-UHFFFAOYSA-N 0.000 description 2
ODJQKYXPKWQWNK-UHFFFAOYSA-N 3,3'-Thiobispropanoic acid Chemical compound OC(=O)CCSCCC(O)=O ODJQKYXPKWQWNK-UHFFFAOYSA-N 0.000 description 2
KENOYUBXYMCHQU-UHFFFAOYSA-N 3-(3-hydroperoxy-3-oxopropyl)sulfonylpropaneperoxoic acid Chemical compound OOC(=O)CCS(=O)(=O)CCC(=O)OO KENOYUBXYMCHQU-UHFFFAOYSA-N 0.000 description 2
KRYOSDLLGJCUAY-UHFFFAOYSA-N 3-decylsulfonylpropaneperoxoic acid Chemical compound CCCCCCCCCCS(=O)(=O)CCC(=O)OO KRYOSDLLGJCUAY-UHFFFAOYSA-N 0.000 description 2
AJBWNNKDUMXZLM-UHFFFAOYSA-N 4-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=C(C(O)=O)C=C1 AJBWNNKDUMXZLM-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
238000005481 NMR spectroscopy Methods 0.000 description 2
PIRUYKRSRWQFTE-UHFFFAOYSA-N OOC(=O)CC1=CC=C(CC(=O)OO)C=C1 Chemical compound OOC(=O)CC1=CC=C(CC(=O)OO)C=C1 PIRUYKRSRWQFTE-UHFFFAOYSA-N 0.000 description 2
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
239000004115 Sodium Silicate Substances 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
229920006362 Teflon® Polymers 0.000 description 2
229910052770 Uranium Inorganic materials 0.000 description 2
229910021536 Zeolite Inorganic materials 0.000 description 2
125000002252 acyl group Chemical group 0.000 description 2
239000002671 adjuvant Substances 0.000 description 2
230000002411 adverse Effects 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
150000001335 aliphatic alkanes Chemical group 0.000 description 2
150000008051 alkyl sulfates Chemical class 0.000 description 2
150000001408 amides Chemical class 0.000 description 2
150000003863 ammonium salts Chemical class 0.000 description 2
239000008346 aqueous phase Substances 0.000 description 2
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
239000000872 buffer Substances 0.000 description 2
239000006172 buffering agent Substances 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
150000007942 carboxylates Chemical class 0.000 description 2
150000001735 carboxylic acids Chemical class 0.000 description 2
125000001309 chloro group Chemical group Cl* 0.000 description 2
239000003086 colorant Substances 0.000 description 2
125000004122 cyclic group Chemical group 0.000 description 2
CMKBCTPCXZNQKX-UHFFFAOYSA-N cyclohexanethiol Chemical compound SC1CCCCC1 CMKBCTPCXZNQKX-UHFFFAOYSA-N 0.000 description 2
VTXVGVNLYGSIAR-UHFFFAOYSA-N decane-1-thiol Chemical compound CCCCCCCCCCS VTXVGVNLYGSIAR-UHFFFAOYSA-N 0.000 description 2
OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 2
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
235000011180 diphosphates Nutrition 0.000 description 2
WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 description 2
238000004851 dishwashing Methods 0.000 description 2
POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
238000005538 encapsulation Methods 0.000 description 2
229910001385 heavy metal Inorganic materials 0.000 description 2
239000012456 homogeneous solution Substances 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
239000012535 impurity Substances 0.000 description 2
239000002563 ionic surfactant Substances 0.000 description 2
238000002955 isolation Methods 0.000 description 2
238000004900 laundering Methods 0.000 description 2
YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
FODOUIXGKGNSMR-UHFFFAOYSA-L magnesium;2-oxidooxycarbonylbenzoate;hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[O-]OC(=O)C1=CC=CC=C1C([O-])=O FODOUIXGKGNSMR-UHFFFAOYSA-L 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
239000002609 medium Substances 0.000 description 2
YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical class OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
239000008055 phosphate buffer solution Substances 0.000 description 2
SIOXPEMLGUPBBT-UHFFFAOYSA-N picolinic acid Chemical compound OC(=O)C1=CC=CC=N1 SIOXPEMLGUPBBT-UHFFFAOYSA-N 0.000 description 2
239000002994 raw material Substances 0.000 description 2
230000009257 reactivity Effects 0.000 description 2
230000000717 retained effect Effects 0.000 description 2
230000000630 rising effect Effects 0.000 description 2
229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
229910000029 sodium carbonate Inorganic materials 0.000 description 2
239000011780 sodium chloride Substances 0.000 description 2
QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 description 2
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
229910052911 sodium silicate Inorganic materials 0.000 description 2
229910052938 sodium sulfate Inorganic materials 0.000 description 2
235000011152 sodium sulphate Nutrition 0.000 description 2
235000010265 sodium sulphite Nutrition 0.000 description 2
239000002689 soil Substances 0.000 description 2
239000007790 solid phase Substances 0.000 description 2
241000894007 species Species 0.000 description 2
238000001228 spectrum Methods 0.000 description 2
230000000087 stabilizing effect Effects 0.000 description 2
238000010186 staining Methods 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
150000003573 thiols Chemical class 0.000 description 2
UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
SFRLSTJPMFGBDP-UHFFFAOYSA-N 1,2-diphosphonoethylphosphonic acid Chemical class OP(O)(=O)CC(P(O)(O)=O)P(O)(O)=O SFRLSTJPMFGBDP-UHFFFAOYSA-N 0.000 description 1
AWOGYVKODMFDOG-UHFFFAOYSA-N 11-methylsulfanylundecanoic acid Chemical compound CSCCCCCCCCCCC(O)=O AWOGYVKODMFDOG-UHFFFAOYSA-N 0.000 description 1
CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical class OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
QGDSNSBHIMFAKG-UHFFFAOYSA-N 2-(2-hydroperoxy-2-oxoethyl)sulfonylethaneperoxoic acid Chemical compound OOC(=O)CS(=O)(=O)CC(=O)OO QGDSNSBHIMFAKG-UHFFFAOYSA-N 0.000 description 1
WDYRPTWUNMHTJL-UHFFFAOYSA-N 2-(carboxymethylsulfonyl)acetic acid Chemical compound OC(=O)CS(=O)(=O)CC(O)=O WDYRPTWUNMHTJL-UHFFFAOYSA-N 0.000 description 1
JTNCEQNHURODLX-UHFFFAOYSA-N 2-phenylethanimidamide Chemical compound NC(=N)CC1=CC=CC=C1 JTNCEQNHURODLX-UHFFFAOYSA-N 0.000 description 1
IJJZLYLFJJUIEA-UHFFFAOYSA-N 3-cyclohexylsulfonylpropaneperoxoic acid Chemical compound OOC(=O)CCS(=O)(=O)C1CCCCC1 IJJZLYLFJJUIEA-UHFFFAOYSA-N 0.000 description 1
QQZMCBWMQBFLBP-UHFFFAOYSA-N 3-decylsulfanylpropanenitrile Chemical compound CCCCCCCCCCSCCC#N QQZMCBWMQBFLBP-UHFFFAOYSA-N 0.000 description 1
HZPCEUKBBVAPOM-UHFFFAOYSA-N 3-methyl-2-(sulfonylmethyl)benzoic acid Chemical compound CC1=C(C(=CC=C1)C(=O)O)C=S(=O)=O HZPCEUKBBVAPOM-UHFFFAOYSA-N 0.000 description 1
KWHCPERWLHBLOT-UHFFFAOYSA-N 4-methylsulfanylbenzoic acid Chemical compound CSC1=CC=C(C(O)=O)C=C1 KWHCPERWLHBLOT-UHFFFAOYSA-N 0.000 description 1
239000005711 Benzoic acid Substances 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
COVZYZSDYWQREU-UHFFFAOYSA-N Busulfan Chemical compound CS(=O)(=O)OCCCCOS(C)(=O)=O COVZYZSDYWQREU-UHFFFAOYSA-N 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
QDHHCQZDFGDHMP-UHFFFAOYSA-N Chloramine Chemical class ClN QDHHCQZDFGDHMP-UHFFFAOYSA-N 0.000 description 1
239000004155 Chlorine dioxide Substances 0.000 description 1
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
102000004190 Enzymes Human genes 0.000 description 1
108090000790 Enzymes Proteins 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical class CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
239000005639 Lauric acid Substances 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
229920001410 Microfiber Polymers 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
229930182556 Polyacetal Natural products 0.000 description 1
241000220317 Rosa Species 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
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UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
239000004809 Teflon Substances 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
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239000003082 abrasive agent Substances 0.000 description 1
150000001242 acetic acid derivatives Chemical class 0.000 description 1
DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
239000003377 acid catalyst Substances 0.000 description 1
230000009471 action Effects 0.000 description 1
239000004480 active ingredient Substances 0.000 description 1
238000005054 agglomeration Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
150000001299 aldehydes Chemical class 0.000 description 1
239000003513 alkali Substances 0.000 description 1
238000005904 alkaline hydrolysis reaction Methods 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
125000002877 alkyl aryl group Chemical group 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
125000005233 alkylalcohol group Chemical group 0.000 description 1
150000004645 aluminates Chemical class 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
BIGPRXCJEDHCLP-UHFFFAOYSA-N ammonium bisulfate Chemical compound [NH4+].OS([O-])(=O)=O BIGPRXCJEDHCLP-UHFFFAOYSA-N 0.000 description 1
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239000007864 aqueous solution Substances 0.000 description 1
125000006615 aromatic heterocyclic group Chemical group 0.000 description 1
125000003710 aryl alkyl group Chemical group 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
239000002585 base Substances 0.000 description 1
235000010233 benzoic acid Nutrition 0.000 description 1
125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
NDKBVBUGCNGSJJ-UHFFFAOYSA-M benzyltrimethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)CC1=CC=CC=C1 NDKBVBUGCNGSJJ-UHFFFAOYSA-M 0.000 description 1
239000004305 biphenyl Substances 0.000 description 1
235000010290 biphenyl Nutrition 0.000 description 1
238000009835 boiling Methods 0.000 description 1
150000001642 boronic acid derivatives Chemical class 0.000 description 1
125000001246 bromo group Chemical group Br* 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
AZTGOPSQAGBNFT-UHFFFAOYSA-L calcium;sodium;sulfate Chemical compound [Na+].[Ca+2].[O-]S([O-])(=O)=O AZTGOPSQAGBNFT-UHFFFAOYSA-L 0.000 description 1
238000004364 calculation method Methods 0.000 description 1
239000004202 carbamide Substances 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
229920003123 carboxymethyl cellulose sodium Polymers 0.000 description 1
229940063834 carboxymethylcellulose sodium Drugs 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
239000003729 cation exchange resin Substances 0.000 description 1
229940023913 cation exchange resins Drugs 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
235000010980 cellulose Nutrition 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
235000019398 chlorine dioxide Nutrition 0.000 description 1
229910001919 chlorite Inorganic materials 0.000 description 1
229910052619 chlorite group Inorganic materials 0.000 description 1
QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 1
239000002131 composite material Substances 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
239000012043 crude product Substances 0.000 description 1
239000012297 crystallization seed Substances 0.000 description 1
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 1
238000010908 decantation Methods 0.000 description 1
125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
238000002845 discoloration Methods 0.000 description 1
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
238000004821 distillation Methods 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
238000009826 distribution Methods 0.000 description 1
150000002019 disulfides Chemical class 0.000 description 1
JHUXOSATQXGREM-UHFFFAOYSA-N dodecanediperoxoic acid Chemical compound OOC(=O)CCCCCCCCCCC(=O)OO JHUXOSATQXGREM-UHFFFAOYSA-N 0.000 description 1
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
238000005108 dry cleaning Methods 0.000 description 1
229960001484 edetic acid Drugs 0.000 description 1
239000008393 encapsulating agent Substances 0.000 description 1
238000005265 energy consumption Methods 0.000 description 1
125000004185 ester group Chemical group 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
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230000001747 exhibiting effect Effects 0.000 description 1
239000000284 extract Substances 0.000 description 1
239000003925 fat Substances 0.000 description 1
235000019197 fats Nutrition 0.000 description 1
150000002191 fatty alcohols Chemical class 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000012467 final product Substances 0.000 description 1
125000001153 fluoro group Chemical group F* 0.000 description 1
239000003205 fragrance Substances 0.000 description 1
235000021588 free fatty acids Nutrition 0.000 description 1
229940083124 ganglion-blocking antiadrenergic secondary and tertiary amines Drugs 0.000 description 1
125000005456 glyceride group Chemical group 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000001072 heteroaryl group Chemical group 0.000 description 1
125000005842 heteroatom Chemical group 0.000 description 1
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
150000004677 hydrates Chemical class 0.000 description 1
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
125000004356 hydroxy functional group Chemical group O* 0.000 description 1
WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical class Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
238000011534 incubation Methods 0.000 description 1
229910052806 inorganic carbonate Inorganic materials 0.000 description 1
229910052816 inorganic phosphate Inorganic materials 0.000 description 1
239000002198 insoluble material Substances 0.000 description 1
150000004694 iodide salts Chemical class 0.000 description 1
INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
239000007788 liquid Substances 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
231100000053 low toxicity Toxicity 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
229910052943 magnesium sulfate Inorganic materials 0.000 description 1
235000019341 magnesium sulphate Nutrition 0.000 description 1
230000014759 maintenance of location Effects 0.000 description 1
125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000005259 measurement Methods 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
125000006178 methyl benzyl group Chemical group 0.000 description 1
239000003658 microfiber Substances 0.000 description 1
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150000007522 mineralic acids Chemical class 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
239000004570 mortar (masonry) Substances 0.000 description 1
125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
125000004998 naphthylethyl group Chemical group C1(=CC=CC2=CC=CC=C12)CC* 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
150000002825 nitriles Chemical class 0.000 description 1
MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
LJDZFAPLPVPTBD-UHFFFAOYSA-N nitroformic acid Chemical compound OC(=O)[N+]([O-])=O LJDZFAPLPVPTBD-UHFFFAOYSA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
230000009965 odorless effect Effects 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
238000005457 optimization Methods 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
150000004967 organic peroxy acids Chemical class 0.000 description 1
238000013021 overheating Methods 0.000 description 1
150000003901 oxalic acid esters Chemical class 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
VSXGXPNADZQTGQ-UHFFFAOYSA-N oxirane;phenol Chemical compound C1CO1.OC1=CC=CC=C1 VSXGXPNADZQTGQ-UHFFFAOYSA-N 0.000 description 1
230000020477 pH reduction Effects 0.000 description 1
125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
239000008194 pharmaceutical composition Substances 0.000 description 1
125000006187 phenyl benzyl group Chemical group 0.000 description 1
125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
235000011007 phosphoric acid Nutrition 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
229940081066 picolinic acid Drugs 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
229910052573 porcelain Inorganic materials 0.000 description 1
GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 description 1
229910000343 potassium bisulfate Inorganic materials 0.000 description 1
239000012286 potassium permanganate Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
LOAUVZALPPNFOQ-UHFFFAOYSA-N quinaldic acid Chemical compound C1=CC=CC2=NC(C(=O)O)=CC=C21 LOAUVZALPPNFOQ-UHFFFAOYSA-N 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
238000007127 saponification reaction Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
238000012216 screening Methods 0.000 description 1
238000005204 segregation Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
239000003352 sequestering agent Substances 0.000 description 1
239000010802 sludge Substances 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
229910000342 sodium bisulfate Inorganic materials 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
229960001922 sodium perborate Drugs 0.000 description 1
229940045872 sodium percarbonate Drugs 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
239000002195 soluble material Substances 0.000 description 1
238000013112 stability test Methods 0.000 description 1
239000008107 starch Substances 0.000 description 1
235000019698 starch Nutrition 0.000 description 1
239000007858 starting material Substances 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000000547 substituted alkyl group Chemical group 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
150000003900 succinic acid esters Chemical class 0.000 description 1
230000001180 sulfating effect Effects 0.000 description 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
150000003460 sulfonic acids Chemical class 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
239000008399 tap water Substances 0.000 description 1
235000020679 tap water Nutrition 0.000 description 1
238000010998 test method Methods 0.000 description 1
XGMYMWYPSYIPQB-UHFFFAOYSA-J tetrasodium;2-(1,2-dicarboxylatoethoxy)butanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC(C([O-])=O)OC(C([O-])=O)CC([O-])=O XGMYMWYPSYIPQB-UHFFFAOYSA-J 0.000 description 1
239000004753 textile Substances 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
125000003944 tolyl group Chemical group 0.000 description 1
238000012546 transfer Methods 0.000 description 1
125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
230000000007 visual effect Effects 0.000 description 1
239000003039 volatile agent Substances 0.000 description 1
239000001993 wax Substances 0.000 description 1
230000003313 weakening effect Effects 0.000 description 1
125000005023 xylyl group Chemical group 0.000 description 1
238000004383 yellowing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3945—Organic per-compounds
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/42—Peroxy compounds containing sulfur atoms
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/42—Peroxy compounds containing sulfur atoms
- C07C409/44—Peroxy compounds containing sulfur atoms with sulfur atoms directly bound to the —O—O— groups, e.g. persulfonic acids
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/36—Systems containing two condensed rings the rings having more than two atoms in common
- C07C2602/42—Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing seven carbon atoms

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Detergent Compositions (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Cosmetics (AREA)

IL8432987A 1986-11-03 1987-11-02 Proxycarboxylic acid sulfonic acids, their preparation and the bleaching mixtures containing them IL84329A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US92659286A	1986-11-03	1986-11-03

Publications (2)

Publication Number	Publication Date
IL84329A0 IL84329A0 (en)	1988-04-29
IL84329A true IL84329A (en)	1995-03-30

Family

ID=25453410

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL8432987A IL84329A (en)	1986-11-03	1987-11-02	Proxycarboxylic acid sulfonic acids, their preparation and the bleaching mixtures containing them

Country Status (13)

Country	Link
EP (1)	EP0267175B1 (de)
JP (1)	JPS63165364A (de)
KR (1)	KR910004669B1 (de)
CN (1)	CN1020197C (de)
AT (1)	ATE95812T1 (de)
AU (1)	AU604775B2 (de)
CA (1)	CA1305721C (de)
DE (1)	DE3787784T2 (de)
ES (1)	ES2002615T3 (de)
IL (1)	IL84329A (de)
NO (1)	NO175937C (de)
NZ (1)	NZ222398A (de)
ZA (1)	ZA878212B (de)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4758369A (en) *	1986-11-03	1988-07-19	Monsanto Company	Sulfone peroxycarboxylic acids
EP0334427B1 (de) *	1988-03-21	1992-06-10	Akzo N.V.	Alkylsulphonylpercarbonsäuren und die sie enthaltenden Bleichmittel- und Reinigungszusammensetzungen
US5358654A (en) *	1988-06-22	1994-10-25	Akzo Nobel N.V.	Stable pourable aqueous bleaching compositions comprising solid organic peroxy acids and at least two polymers
US5126066A (en) *	1988-06-22	1992-06-30	Akzo N.V.	Stable, pourable aqueous bleaching compositions comprising solid organic peroxy acids and at least two polymers
US4909953A (en) *	1988-06-30	1990-03-20	The Procter & Gamble Company	Phosphate buffer wash for improved amidoperoxyacid storage stability
US5049298A (en) *	1988-11-25	1991-09-17	Akzo Nv	Process for the preparation of bleaching granules
US5296156A (en) *	1988-11-25	1994-03-22	Akzo N.V.	Bleaching granules
US5039447A (en) *	1988-12-12	1991-08-13	Monsanto Company	Pourable sulfone peracid compositions
US5175310A (en) *	1990-03-16	1992-12-29	Elf Atochem North America, Inc.	Process for producing alkylthio- and arylthio-substituted carboxylic acids and their thioesters
SE500386C2 (sv) *	1990-05-09	1994-06-13	Eka Nobel Ab	Nya diacylerade diperkarboxylsyror, förfarande för framställning därav samt kompositioner innehållande föreningarna för blekning
US5171883A (en) *	1990-10-10	1992-12-15	Monsanto Company	Process for preparing sulfonyl acids
EP0485927A1 (de) *	1990-11-16	1992-05-20	Hoechst Aktiengesellschaft	Sulfimidoperoxicarbonsäuren
US5453214A (en) *	1991-10-04	1995-09-26	Akzo Nobel N.V.	Suspension and agglomeration of amidoperoxyacids
US5234617A (en) *	1992-04-20	1993-08-10	Kathleen B. Hunter	Aqueous liquid bleach compositions with fluorescent whitening agent and polyvinyl pyrrolidone or polyvinyl alcohol
DE69323516T3 (de) *	1992-09-16	2003-03-27	Unilever N.V., Rotterdam	Bleichmittel
EP0588622B2 (de) *	1992-09-16	2002-12-04	Unilever Plc	Bleichmittel
US20060090777A1 (en)	2004-11-01	2006-05-04	Hecht Stacie E	Multiphase cleaning compositions having ionic liquid phase
US7939485B2 (en)	2004-11-01	2011-05-10	The Procter & Gamble Company	Benefit agent delivery system comprising ionic liquid
US7786065B2 (en) *	2005-02-18	2010-08-31	The Procter & Gamble Company	Ionic liquids derived from peracid anions
US8871807B2 (en)	2008-03-28	2014-10-28	Ecolab Usa Inc.	Detergents capable of cleaning, bleaching, sanitizing and/or disinfecting textiles including sulfoperoxycarboxylic acids
NZ587218A (en) *	2008-03-28	2012-04-27	Ecolab Inc	Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents
US12203056B2 (en)	2008-03-28	2025-01-21	Ecolab Usa Inc.	Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents
US8809392B2 (en) *	2008-03-28	2014-08-19	Ecolab Usa Inc.	Sulfoperoxycarboxylic acids, their preparation and methods of use as bleaching and antimicrobial agents
US9321664B2 (en)	2011-12-20	2016-04-26	Ecolab Usa Inc.	Stable percarboxylic acid compositions and uses thereof
EP2831000A4 (de)	2012-03-30	2016-03-30	Ecolab Usa Inc	Verwendung von peressigsäure/wasserstoffperoxid und peroxidreduzierungsmitteln zur behandlung von bohrflüssigkeiten, fracking-flüssigkeiten, rückflusswasser und entsorgungswasser
US20140256811A1 (en)	2013-03-05	2014-09-11	Ecolab Usa Inc.	Efficient stabilizer in controlling self accelerated decomposition temperature of peroxycarboxylic acid compositions with mineral acids
US8822719B1 (en)	2013-03-05	2014-09-02	Ecolab Usa Inc.	Peroxycarboxylic acid compositions suitable for inline optical or conductivity monitoring
US10165774B2 (en)	2013-03-05	2019-01-01	Ecolab Usa Inc.	Defoamer useful in a peracid composition with anionic surfactants
CN113811762A (zh)	2019-05-31	2021-12-17	埃科莱布美国股份有限公司	通过电导率测量和过酸组合物监测过酸浓度的方法
WO2021026410A1 (en)	2019-08-07	2021-02-11	Ecolab Usa Inc.	Polymeric and solid-supported chelators for stabilization of peracid-containing compositions

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1041417A (en) *	1964-08-20	1966-09-07	Procter & Gamble Ltd	Alpha-sulpho peroxy fatty acids and salts
DE2725067A1 (de) *	1977-06-03	1978-12-14	Schuelke & Mayr Gmbh	Alkohlisches desinfektionsmittel mit sporizider wirkung
EP0105690B1 (de) *	1982-09-30	1988-07-13	The Procter & Gamble Company	Bleichmittelzusammensetzungen
GB8415909D0 (en) *	1984-06-21	1984-07-25	Procter & Gamble Ltd	Peracid compounds

1987
- 1987-10-30 EP EP87870151A patent/EP0267175B1/de not_active Expired - Lifetime
- 1987-10-30 ES ES87870151T patent/ES2002615T3/es not_active Expired - Lifetime
- 1987-10-30 AT AT87870151T patent/ATE95812T1/de not_active IP Right Cessation
- 1987-10-30 DE DE87870151T patent/DE3787784T2/de not_active Expired - Fee Related
- 1987-11-02 KR KR1019870012221A patent/KR910004669B1/ko not_active Expired
- 1987-11-02 AU AU80592/87A patent/AU604775B2/en not_active Ceased
- 1987-11-02 NO NO874549A patent/NO175937C/no unknown
- 1987-11-02 JP JP62278141A patent/JPS63165364A/ja active Pending
- 1987-11-02 NZ NZ222398A patent/NZ222398A/xx unknown
- 1987-11-02 CN CN87107801A patent/CN1020197C/zh not_active Expired - Fee Related
- 1987-11-02 IL IL8432987A patent/IL84329A/en not_active IP Right Cessation
- 1987-11-02 CA CA000550796A patent/CA1305721C/en not_active Expired - Lifetime
- 1987-11-02 ZA ZA878212A patent/ZA878212B/xx unknown

Also Published As

Publication number	Publication date
ATE95812T1 (de)	1993-10-15
NO874549L (no)	1988-05-04
DE3787784D1 (de)	1993-11-18
NZ222398A (en)	1989-12-21
KR880006188A (ko)	1988-07-22
CN1020197C (zh)	1993-03-31
ES2002615A4 (es)	1988-09-01
EP0267175B1 (de)	1993-10-13
JPS63165364A (ja)	1988-07-08
KR910004669B1 (ko)	1991-07-09
CN87107801A (zh)	1988-05-18
NO175937C (no)	1995-01-04
IL84329A0 (en)	1988-04-29
ES2002615T3 (es)	1994-12-01
CA1305721C (en)	1992-07-28
NO175937B (no)	1994-09-26
NO874549D0 (no)	1987-11-02
AU604775B2 (en)	1991-01-03
AU8059287A (en)	1988-05-05
EP0267175A2 (de)	1988-05-11
EP0267175A3 (en)	1989-03-01
ZA878212B (en)	1988-07-27
DE3787784T2 (de)	1994-05-05

Legal Events

Date	Code	Title	Description
1998-11-26	RH	Patent void

Publication	Publication Date	Title
US5004558A (en)	1991-04-02	Sulfone peroxycarboxylic acids
AU604775B2 (en)	1991-01-03	Sulfone peroxycarboxylic acids
US4824591A (en)	1989-04-25	Sulfone peroxycarboxylic acids
US4758369A (en)	1988-07-19	Sulfone peroxycarboxylic acids
AU674405B2 (en)	1996-12-19	Peroxyacids
EP0122763B1 (de)	1987-06-16	Bleichmittelzusammensetzungen
CA1340680C (en)	1999-07-27	Imide-aromatic peroxyacids as bleaching agents
US4259201A (en)	1981-03-31	Detergent composition containing organic peracids buffered for optimum performance
US4606838A (en)	1986-08-19	Bleaching compositions comprising alkoxy substituted aromatic peroxyacids
EP0532622B1 (de)	1995-08-09	Peroxyverbindungen
IE59250B1 (en)	1994-01-26	Peracid and bleach activator compounds and use thereof in cleaning compositions
EP0334427B1 (de)	1992-06-10	Alkylsulphonylpercarbonsäuren und die sie enthaltenden Bleichmittel- und Reinigungszusammensetzungen
WO1991015474A1 (en)	1991-10-17	Peroxy acid bleach precursors and detergent compositions containing them
US5078907A (en)	1992-01-07	Unsymmetrical dicarboxylic esters as bleach precursors
US5089166A (en)	1992-02-18	Bleaching and detergent compositions
JP2915020B2 (ja)	1999-07-05	新規なイミド誘導ペルオキシ酸
US5241077A (en)	1993-08-31	Peroxyacids
NO172066B (no)	1993-02-22	Blekeforloeper og bleke/vaskemiddelblanding
EP0195597A1 (de)	1986-09-24	Bleichaktivatoren und diese enthaltende Bleichmittelzusammensetzungen
KR930007850B1 (ko)	1993-08-20	표백세제 조성물
EP0575304B1 (de)	1996-09-25	Sulfonamido Peroxycarbonsäure