IL94072A - שיטה להכנת עדשת מגע צבעונית - Google Patents

שיטה להכנת עדשת מגע צבעונית

Info

Publication number: IL94072A
Authority: IL; Israel
Prior art keywords: lens; functional groups; alkyl; polymer; hydrogen
Prior art date: 1989-04-14

Application number

IL9407290A

Other languages

English (en)

Other versions

IL94072A0 (en

Original Assignee

Schering Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-04-14

Filing date

1990-04-12

Publication date

1994-06-24

1990-04-12 Application filed by Schering Corp filed Critical Schering Corp

1991-01-31 Publication of IL94072A0 publication Critical patent/IL94072A0/xx

1994-06-24 Publication of IL94072A publication Critical patent/IL94072A/he

Links

238000000034 method Methods 0.000 title claims abstract description 30
125000000524 functional group Chemical group 0.000 claims abstract description 60
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 40
229910052739 hydrogen Inorganic materials 0.000 claims abstract description 32
239000001257 hydrogen Substances 0.000 claims abstract description 32
125000000217 alkyl group Chemical group 0.000 claims abstract description 29
229910052799 carbon Inorganic materials 0.000 claims abstract description 20
229910052757 nitrogen Inorganic materials 0.000 claims abstract description 20
125000003118 aryl group Chemical group 0.000 claims abstract description 17
125000004430 oxygen atom Chemical group O* 0.000 claims abstract description 15
229920000642 polymer Polymers 0.000 claims description 68
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 33
239000000178 monomer Substances 0.000 claims description 30
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 29
239000000049 pigment Substances 0.000 claims description 24
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 22
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 20
-1 glycerol ester Chemical class 0.000 claims description 20
238000000576 coating method Methods 0.000 claims description 17
239000011248 coating agent Substances 0.000 claims description 16
229920001477 hydrophilic polymer Polymers 0.000 claims description 16
239000000203 mixture Substances 0.000 claims description 16
150000001721 carbon Chemical group 0.000 claims description 15
229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims description 12
WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 12
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 8
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
SFPNZPQIIAJXGL-UHFFFAOYSA-N 2-ethoxyethyl 2-methylprop-2-enoate Chemical compound CCOCCOC(=O)C(C)=C SFPNZPQIIAJXGL-UHFFFAOYSA-N 0.000 claims description 7
125000005907 alkyl ester group Chemical group 0.000 claims description 7
238000006243 chemical reaction Methods 0.000 claims description 7
230000002209 hydrophobic effect Effects 0.000 claims description 7
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 4
125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 4
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 4
125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 4
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 3
125000002947 alkylene group Chemical group 0.000 claims description 3
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
125000004356 hydroxy functional group Chemical group O* 0.000 claims 1
150000001875 compounds Chemical class 0.000 abstract description 16
238000002360 preparation method Methods 0.000 abstract description 6
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
125000004432 carbon atom Chemical group C* 0.000 abstract 1
239000000976 ink Substances 0.000 description 59
229920003270 Cymel® Polymers 0.000 description 45
JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 44
239000003054 catalyst Substances 0.000 description 34
238000012360 testing method Methods 0.000 description 32
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 24
LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 24
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 21
239000004615 ingredient Substances 0.000 description 19
239000011230 binding agent Substances 0.000 description 14
229920005989 resin Polymers 0.000 description 14
239000011347 resin Substances 0.000 description 14
239000012948 isocyanate Substances 0.000 description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
229940116333 ethyl lactate Drugs 0.000 description 12
239000004408 titanium dioxide Substances 0.000 description 12
LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 11
239000002904 solvent Substances 0.000 description 11
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 9
241000254173 Coleoptera Species 0.000 description 9
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
150000002825 nitriles Chemical class 0.000 description 9
RWHRFHQRVDUPIK-UHFFFAOYSA-N 50867-57-7 Chemical compound CC(=C)C(O)=O.CC(=C)C(O)=O RWHRFHQRVDUPIK-UHFFFAOYSA-N 0.000 description 8
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 8
IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 8
229920003987 resole Polymers 0.000 description 8
GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 7
230000004913 activation Effects 0.000 description 7
238000006116 polymerization reaction Methods 0.000 description 7
239000011521 glass Substances 0.000 description 6
ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
229920000877 Melamine resin Polymers 0.000 description 5
XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 5
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
239000002318 adhesion promoter Substances 0.000 description 4
BGTOWKSIORTVQH-UHFFFAOYSA-N cyclopentanone Chemical compound O=C1CCCC1 BGTOWKSIORTVQH-UHFFFAOYSA-N 0.000 description 4
125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 4
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
238000010528 free radical solution polymerization reaction Methods 0.000 description 3
RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 3
238000012956 testing procedure Methods 0.000 description 3
QEQBMZQFDDDTPN-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy benzenecarboperoxoate Chemical compound CC(C)(C)OOOC(=O)C1=CC=CC=C1 QEQBMZQFDDDTPN-UHFFFAOYSA-N 0.000 description 2
UUGLSEIATNSHRI-UHFFFAOYSA-N 1,3,4,6-tetrakis(hydroxymethyl)-3a,6a-dihydroimidazo[4,5-d]imidazole-2,5-dione Chemical compound OCN1C(=O)N(CO)C2C1N(CO)C(=O)N2CO UUGLSEIATNSHRI-UHFFFAOYSA-N 0.000 description 2
KDCGOANMDULRCW-UHFFFAOYSA-N 7H-purine Chemical compound N1=CNC2=NC=NC2=C1 KDCGOANMDULRCW-UHFFFAOYSA-N 0.000 description 2
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
239000004593 Epoxy Substances 0.000 description 2
YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
HQXDNQWWLUFFBS-UHFFFAOYSA-N [(4,6-diamino-1,3,5-triazin-2-yl)-(methoxymethyl)amino]methanol;formaldehyde Chemical compound O=C.COCN(CO)C1=NC(N)=NC(N)=N1 HQXDNQWWLUFFBS-UHFFFAOYSA-N 0.000 description 2
230000002378 acidificating effect Effects 0.000 description 2
GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical class OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 2
MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
230000008901 benefit Effects 0.000 description 2
230000008275 binding mechanism Effects 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
238000004040 coloring Methods 0.000 description 2
238000009500 colour coating Methods 0.000 description 2
QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
VVYDVQWJZWRVPE-UHFFFAOYSA-L dimethyltin(2+);diiodide Chemical compound C[Sn](C)(I)I VVYDVQWJZWRVPE-UHFFFAOYSA-L 0.000 description 2
229920001971 elastomer Polymers 0.000 description 2
125000005448 ethoxyethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 2
IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical class O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 2
150000002314 glycerols Chemical class 0.000 description 2
230000036571 hydration Effects 0.000 description 2
238000006703 hydration reaction Methods 0.000 description 2
239000000017 hydrogel Substances 0.000 description 2
CBOIHMRHGLHBPB-UHFFFAOYSA-N hydroxymethyl Chemical compound O[CH2] CBOIHMRHGLHBPB-UHFFFAOYSA-N 0.000 description 2
239000003999 initiator Substances 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
230000007246 mechanism Effects 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
239000003607 modifier Substances 0.000 description 2
230000001473 noxious effect Effects 0.000 description 2
YNPNZTXNASCQKK-UHFFFAOYSA-N phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
239000003505 polymerization initiator Substances 0.000 description 2
230000009257 reactivity Effects 0.000 description 2
239000000126 substance Substances 0.000 description 2
231100000331 toxic Toxicity 0.000 description 2
230000002588 toxic effect Effects 0.000 description 2
229920002554 vinyl polymer Polymers 0.000 description 2
JWYVGKFDLWWQJX-UHFFFAOYSA-N 1-ethenylazepan-2-one Chemical compound C=CN1CCCCCC1=O JWYVGKFDLWWQJX-UHFFFAOYSA-N 0.000 description 1
XXVUSJBWYAWVQV-UHFFFAOYSA-N 1-ethenylpiperidine-2,6-dione Chemical compound C=CN1C(=O)CCCC1=O XXVUSJBWYAWVQV-UHFFFAOYSA-N 0.000 description 1
UGIJCMNGQCUTPI-UHFFFAOYSA-N 2-aminoethyl prop-2-enoate Chemical compound NCCOC(=O)C=C UGIJCMNGQCUTPI-UHFFFAOYSA-N 0.000 description 1
ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
BNCADMBVWNPPIZ-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical compound COCN(COC)C1=NC(N(COC)COC)=NC(N(COC)COC)=N1 BNCADMBVWNPPIZ-UHFFFAOYSA-N 0.000 description 1
KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
HVKBEYVSISVMBF-UHFFFAOYSA-N 6-diazenyl-2-n-(methoxymethyl)-1,3,5-triazine-2,4-diamine;formaldehyde Chemical compound O=C.COCNC1=NC(N)=NC(N=N)=N1 HVKBEYVSISVMBF-UHFFFAOYSA-N 0.000 description 1
GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical class NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 description 1
CGLVZFOCZLHKOH-UHFFFAOYSA-N 8,18-dichloro-5,15-diethyl-5,15-dihydrodiindolo(3,2-b:3',2'-m)triphenodioxazine Chemical compound CCN1C2=CC=CC=C2C2=C1C=C1OC3=C(Cl)C4=NC(C=C5C6=CC=CC=C6N(C5=C5)CC)=C5OC4=C(Cl)C3=NC1=C2 CGLVZFOCZLHKOH-UHFFFAOYSA-N 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
229910052684 Cerium Chemical group 0.000 description 1
FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000003377 acid catalyst Substances 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
238000005815 base catalysis Methods 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
238000012662 bulk polymerization Methods 0.000 description 1
239000000919 ceramic Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
239000003431 cross linking reagent Substances 0.000 description 1
238000011161 development Methods 0.000 description 1
LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
230000009977 dual effect Effects 0.000 description 1
SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
238000009472 formulation Methods 0.000 description 1
125000001046 glycoluril group Chemical class [H]C12N(*)C(=O)N(*)C1([H])N(*)C(=O)N2* 0.000 description 1
238000000227 grinding Methods 0.000 description 1
QFOJTGAPBXCVOK-UHFFFAOYSA-N hexyl 2-ethylhexaneperoxoate Chemical compound CCCCCCOOC(=O)C(CC)CCCC QFOJTGAPBXCVOK-UHFFFAOYSA-N 0.000 description 1
150000002483 hydrogen compounds Chemical class 0.000 description 1
PZOUSPYUWWUPPK-UHFFFAOYSA-N indole Natural products CC1=CC=CC2=C1C=CN2 PZOUSPYUWWUPPK-UHFFFAOYSA-N 0.000 description 1
RKJUIXBNRJVNHR-UHFFFAOYSA-N indolenine Natural products C1=CC=C2CC=NC2=C1 RKJUIXBNRJVNHR-UHFFFAOYSA-N 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
235000013980 iron oxide Nutrition 0.000 description 1
VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
150000002513 isocyanates Chemical class 0.000 description 1
239000000463 material Substances 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
229940088644 n,n-dimethylacrylamide Drugs 0.000 description 1
YLGYACDQVQQZSW-UHFFFAOYSA-N n,n-dimethylprop-2-enamide Chemical compound CN(C)C(=O)C=C YLGYACDQVQQZSW-UHFFFAOYSA-N 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
239000003973 paint Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
229920001568 phenolic resin Polymers 0.000 description 1
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
230000008569 process Effects 0.000 description 1
FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
150000003254 radicals Chemical class 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
230000036632 reaction speed Effects 0.000 description 1
238000011160 research Methods 0.000 description 1
210000003660 reticulum Anatomy 0.000 description 1
238000007493 shaping process Methods 0.000 description 1
229920005573 silicon-containing polymer Polymers 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
229960002317 succinimide Drugs 0.000 description 1
239000000725 suspension Substances 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
230000008961 swelling Effects 0.000 description 1
229930192474 thiophene Natural products 0.000 description 1
NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/00009—Production of simple or compound lenses
- B29D11/00038—Production of contact lenses
- B29D11/00048—Production of contact lenses composed of parts with dissimilar composition
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
- G02B1/043—Contact lenses
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/02—Lenses; Lens systems ; Methods of designing lenses
- G02C7/04—Contact lenses for the eyes
- G02C7/049—Contact lenses having special fitting or structural features achieved by special materials or material structures
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2339/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Derivatives of such polymers
- C08J2339/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
- C08J2339/06—Homopolymers or copolymers of N-vinyl-pyrrolidones
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers

Landscapes

Physics & Mathematics (AREA)
General Physics & Mathematics (AREA)
Health & Medical Sciences (AREA)
Optics & Photonics (AREA)
Ophthalmology & Optometry (AREA)
Engineering & Computer Science (AREA)
Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
General Health & Medical Sciences (AREA)
Mechanical Engineering (AREA)
Manufacturing & Machinery (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Eyeglasses (AREA)
Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Joining Of Glass To Other Materials (AREA)
Coloring (AREA)
Surface Treatment Of Optical Elements (AREA)
Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
Treatments Of Macromolecular Shaped Articles (AREA)

IL9407290A 1989-04-14 1990-04-12 שיטה להכנת עדשת מגע צבעונית IL94072A (he)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US33807789A	1989-04-14	1989-04-14

Publications (2)

Publication Number	Publication Date
IL94072A0 IL94072A0 (en)	1991-01-31
IL94072A true IL94072A (he)	1994-06-24

Family

ID=23323315

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL9407290A IL94072A (he)	1989-04-14	1990-04-12	שיטה להכנת עדשת מגע צבעונית

Country Status (22)

Country	Link
US (1)	US5272010A (he)
EP (2)	EP0467977A1 (he)
JP (1)	JPH0623264B2 (he)
KR (1)	KR0171571B1 (he)
CN (1)	CN1045126C (he)
AT (1)	ATE139549T1 (he)
AU (1)	AU631425B2 (he)
BR (1)	BR9007294A (he)
CA (1)	CA2051387C (he)
CZ (1)	CZ187690A3 (he)
DE (1)	DE69027475T2 (he)
DK (1)	DK0393532T3 (he)
ES (1)	ES2088395T3 (he)
HK (1)	HK1007434A1 (he)
IL (1)	IL94072A (he)
NZ (1)	NZ233317A (he)
PL (1)	PL163759B1 (he)
PT (1)	PT93750B (he)
RU (1)	RU2049097C1 (he)
SG (1)	SG43306A1 (he)
WO (1)	WO1990012840A2 (he)
ZA (1)	ZA902842B (he)

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RU2258948C1 (ru) *	2003-02-26	2005-08-20	Международный центр "Институт прикладной оптики" Национальной академии наук Украины	Термочувствительная контактная линза
US8147728B2 (en) *	2004-04-01	2012-04-03	Novartis Ag	Pad transfer printing of silicone hydrogel lenses using colored ink
CN1947033B (zh) *	2004-04-21	2013-07-10	诺瓦提斯公司	用于制备有色硅氧烷水凝胶镜片的可固化有色墨水
JP5064218B2 (ja) *	2004-07-28	2012-10-31	ノバルティスアーゲー	ハイドロゲルレンズ用水性インク
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CN101308218B (zh) *	2007-05-15	2011-01-05	鸿富锦精密工业（深圳）有限公司	有色镜片的制作方法
EP2443182A2 (en) *	2009-06-15	2012-04-25	DSM IP Assets B.V.	Phosphorylcholine-based amphiphilic silicones for medical applications
MY158165A (en) *	2009-12-17	2016-09-15	Novartis Ag	Pad transfer printing method for making colored contact lenses
EP2555751B8 (en)	2010-04-03	2018-02-14	Praful Doshi	Methods of coating a contact lens
US10413506B2 (en)	2010-04-03	2019-09-17	Praful Doshi	Medical devices including medicaments and methods of making and using same including enhancing comfort, enhancing drug penetration, and treatment of myopia
SG187026A1 (en)	2010-07-30	2013-02-28	Novartis Ag	A silicone hydrogel lens with a crosslinked hydrophilic coating
KR20120039398A (ko) *	2010-10-15	2012-04-25	삼성전자주식회사	에어로젤, 에어로젤용 조성물, 에어로젤 복합체 및 이들의 제조방법
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1990
- 1990-04-12 US US07/768,910 patent/US5272010A/en not_active Expired - Lifetime
- 1990-04-12 ZA ZA902842A patent/ZA902842B/xx unknown
- 1990-04-12 CA CA002051387A patent/CA2051387C/en not_active Expired - Fee Related
- 1990-04-12 EP EP90906695A patent/EP0467977A1/en active Pending
- 1990-04-12 SG SG1996007875A patent/SG43306A1/en unknown
- 1990-04-12 IL IL9407290A patent/IL94072A/he not_active IP Right Cessation
- 1990-04-12 BR BR909007294A patent/BR9007294A/pt not_active IP Right Cessation
- 1990-04-12 PT PT93750A patent/PT93750B/pt not_active IP Right Cessation
- 1990-04-12 ES ES90107106T patent/ES2088395T3/es not_active Expired - Lifetime
- 1990-04-12 WO PCT/US1990/001868 patent/WO1990012840A2/en not_active Ceased
- 1990-04-12 JP JP2506440A patent/JPH0623264B2/ja not_active Expired - Fee Related
- 1990-04-12 RU SU905010138A patent/RU2049097C1/ru active
- 1990-04-12 AT AT90107106T patent/ATE139549T1/de not_active IP Right Cessation
- 1990-04-12 AU AU55290/90A patent/AU631425B2/en not_active Ceased
- 1990-04-12 KR KR1019900702589A patent/KR0171571B1/ko not_active Expired - Fee Related
- 1990-04-12 EP EP90107106A patent/EP0393532B1/en not_active Expired - Lifetime
- 1990-04-12 DK DK90107106.8T patent/DK0393532T3/da active
- 1990-04-12 NZ NZ233317A patent/NZ233317A/en unknown
- 1990-04-12 DE DE69027475T patent/DE69027475T2/de not_active Expired - Fee Related
- 1990-04-13 CN CN90102059A patent/CN1045126C/zh not_active Expired - Fee Related
- 1990-04-13 PL PL90284779A patent/PL163759B1/pl unknown
- 1990-04-13 CZ CS901876A patent/CZ187690A3/cs unknown
1998
- 1998-06-25 HK HK98106610A patent/HK1007434A1/en not_active IP Right Cessation

Also Published As

Publication number	Publication date
AU631425B2 (en)	1992-11-26
DE69027475T2 (de)	1996-12-12
PT93750B (pt)	1996-10-31
CA2051387A1 (en)	1990-10-15
CN1045126C (zh)	1999-09-15
EP0467977A1 (en)	1992-01-29
ES2088395T3 (es)	1996-08-16
ZA902842B (en)	1990-12-28
BR9007294A (pt)	1992-03-03
PT93750A (pt)	1990-11-20
NZ233317A (en)	1992-04-28
EP0393532A3 (en)	1990-11-28
RU2049097C1 (ru)	1995-11-27
CA2051387C (en)	1996-06-25
AU5529090A (en)	1990-11-16
DE69027475D1 (de)	1996-07-25
IL94072A0 (en)	1991-01-31
ATE139549T1 (de)	1996-07-15
CN1046575A (zh)	1990-10-31
EP0393532A2 (en)	1990-10-24
HK1007434A1 (en)	1999-04-09
KR920700252A (ko)	1992-02-19
SG43306A1 (en)	1997-10-17
JPH04500696A (ja)	1992-02-06
PL163759B1 (pl)	1994-04-29
WO1990012840A3 (en)	1990-11-29
KR0171571B1 (ko)	1999-05-01
WO1990012840A2 (en)	1990-11-01
DK0393532T3 (da)	1996-08-19
CZ187690A3 (en)	1995-02-15
EP0393532B1 (en)	1996-06-19
JPH0623264B2 (ja)	1994-03-30
US5272010A (en)	1993-12-21

Legal Events

Date	Code	Title
1996-07-23	KB	Patent renewed
2000-08-31	KB	Patent renewed
2005-07-25	MM9K	Patent not in force due to non-payment of renewal fees

Publication	Publication Date	Title
AU631425B2 (en)	1992-11-26	Color binding mechanism for contact lenses
HK1007434B (en)	1999-04-09	Color binding mechanism for contact lenses
KR940000833B1 (ko)	1994-02-02	친수성 유색 콘택트 렌즈
US4774035A (en)	1988-09-27	Process of coating an ophthalmic lens
US4668240A (en)	1987-05-26	Pigment colored contact lenses and method for making same
EP1381331B1 (en)	2009-03-11	Method for making a colored contact lens
KR101912572B1 (ko)	2018-10-26	콘택트 렌즈
US5049321A (en)	1991-09-17	Method for forming coated plastic optical elements
CA1298150C (en)	1992-03-31	Colored contact lens and methods for the production thereof
EP3397701B1 (en)	2020-04-15	Curable colored inks for making colored silicone hydrogel lenses
DK170020B1 (da)	1995-05-01	Farvede kontaktlinser og fremgangsmåde til fremstilling heraf
CN113103697B (zh)	2022-08-09	一种氟硅水凝胶彩色隐形眼镜及其制备工艺