IL97287A - Ethylene vinyl acetate flame retardants - Google Patents

Ethylene vinyl acetate flame retardants

Info

Publication number: IL97287A
Authority: IL; Israel
Prior art keywords: polymer composition; bromine; flame retardant; weight; vinyl acetate
Prior art date: 1990-04-17

Application number

IL9728791A

Other languages

English (en)

Hebrew (he)

Other versions

IL97287A0 (en

Original Assignee

Great Lakes Chemical Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-04-17

Filing date

1991-02-20

Publication date

1994-07-31

1991-02-20 Application filed by Great Lakes Chemical Corp filed Critical Great Lakes Chemical Corp

1992-05-25 Publication of IL97287A0 publication Critical patent/IL97287A0/xx

1994-07-31 Publication of IL97287A publication Critical patent/IL97287A/en

Links

229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 title claims abstract description 92
239000005038 ethylene vinyl acetate Substances 0.000 title claims abstract description 91
239000000203 mixture Substances 0.000 title claims abstract description 90
DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 title claims abstract description 82
239000003063 flame retardant Substances 0.000 title claims abstract description 34
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 27
229920000642 polymer Polymers 0.000 claims abstract description 44
229920000578 graft copolymer Polymers 0.000 claims abstract description 24
125000000217 alkyl group Chemical group 0.000 claims abstract description 10
229910052794 bromium Inorganic materials 0.000 claims description 36
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 31
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 31
239000000178 monomer Substances 0.000 claims description 24
229920001519 homopolymer Polymers 0.000 claims description 12
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
229910052739 hydrogen Inorganic materials 0.000 claims 2
239000001257 hydrogen Substances 0.000 claims 2
238000000034 method Methods 0.000 abstract description 20
230000000704 physical effect Effects 0.000 abstract description 13
229920002959 polymer blend Polymers 0.000 abstract 1
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 21
CYLVUSZHVURAOY-UHFFFAOYSA-N 2,2-dibromoethenylbenzene Chemical group BrC(Br)=CC1=CC=CC=C1 CYLVUSZHVURAOY-UHFFFAOYSA-N 0.000 description 19
238000010559 graft polymerization reaction Methods 0.000 description 12
239000000047 product Substances 0.000 description 12
239000000463 material Substances 0.000 description 10
-1 ethylene, propylene Chemical group 0.000 description 9
239000000654 additive Substances 0.000 description 8
229920001577 copolymer Polymers 0.000 description 8
238000012545 processing Methods 0.000 description 8
239000005977 Ethylene Substances 0.000 description 7
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 7
239000003999 initiator Substances 0.000 description 7
150000003440 styrenes Chemical class 0.000 description 7
XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 6
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 6
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
238000006116 polymerization reaction Methods 0.000 description 5
BMSUWQXMTMGEOM-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-ethenylbenzene Chemical compound BrC1=C(Br)C(Br)=C(C=C)C(Br)=C1Br BMSUWQXMTMGEOM-UHFFFAOYSA-N 0.000 description 4
230000008901 benefit Effects 0.000 description 4
229920001971 elastomer Polymers 0.000 description 4
238000012986 modification Methods 0.000 description 4
230000004048 modification Effects 0.000 description 4
230000008569 process Effects 0.000 description 4
150000003254 radicals Chemical class 0.000 description 4
230000000979 retarding effect Effects 0.000 description 4
229920003345 Elvax® Polymers 0.000 description 3
239000004609 Impact Modifier Substances 0.000 description 3
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
238000013459 approach Methods 0.000 description 3
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
239000012986 chain transfer agent Substances 0.000 description 3
238000006243 chemical reaction Methods 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 3
WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
238000002156 mixing Methods 0.000 description 3
229910052760 oxygen Inorganic materials 0.000 description 3
239000001301 oxygen Substances 0.000 description 3
229920003023 plastic Polymers 0.000 description 3
239000004033 plastic Substances 0.000 description 3
229920002857 polybutadiene Polymers 0.000 description 3
229920000573 polyethylene Polymers 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
239000005060 rubber Substances 0.000 description 3
229920001897 terpolymer Polymers 0.000 description 3
JVPKLOPETWVKQD-UHFFFAOYSA-N 1,2,2-tribromoethenylbenzene Chemical compound BrC(Br)=C(Br)C1=CC=CC=C1 JVPKLOPETWVKQD-UHFFFAOYSA-N 0.000 description 2
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
CISIJYCKDJSTMX-UHFFFAOYSA-N 2,2-dichloroethenylbenzene Chemical compound ClC(Cl)=CC1=CC=CC=C1 CISIJYCKDJSTMX-UHFFFAOYSA-N 0.000 description 2
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
239000004831 Hot glue Substances 0.000 description 2
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
239000004698 Polyethylene Substances 0.000 description 2
239000004743 Polypropylene Substances 0.000 description 2
229920003351 Ultrathene® Polymers 0.000 description 2
YMOONIIMQBGTDU-VOTSOKGWSA-N [(e)-2-bromoethenyl]benzene Chemical compound Br\C=C\C1=CC=CC=C1 YMOONIIMQBGTDU-VOTSOKGWSA-N 0.000 description 2
238000012644 addition polymerization Methods 0.000 description 2
239000000853 adhesive Substances 0.000 description 2
230000001070 adhesive effect Effects 0.000 description 2
230000004075 alteration Effects 0.000 description 2
125000001246 bromo group Chemical class Br* 0.000 description 2
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
238000000576 coating method Methods 0.000 description 2
239000000706 filtrate Substances 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
150000002367 halogens Chemical class 0.000 description 2
230000000670 limiting effect Effects 0.000 description 2
239000000155 melt Substances 0.000 description 2
238000013508 migration Methods 0.000 description 2
230000005012 migration Effects 0.000 description 2
150000001451 organic peroxides Chemical class 0.000 description 2
229920001195 polyisoprene Polymers 0.000 description 2
229920001155 polypropylene Polymers 0.000 description 2
HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical class C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 2
239000007787 solid Substances 0.000 description 2
125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
239000000758 substrate Substances 0.000 description 2
238000012546 transfer Methods 0.000 description 2
HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical group C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 description 1
DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 description 1
LHHMNJZNWUJFOC-UHFFFAOYSA-N 1-chloro-2-[2-chloroethoxy(ethenyl)phosphoryl]oxyethane Chemical compound ClCCOP(=O)(C=C)OCCCl LHHMNJZNWUJFOC-UHFFFAOYSA-N 0.000 description 1
WAEOXIOXMKNFLQ-UHFFFAOYSA-N 1-methyl-4-prop-2-enylbenzene Chemical group CC1=CC=C(CC=C)C=C1 WAEOXIOXMKNFLQ-UHFFFAOYSA-N 0.000 description 1
QEDJMOONZLUIMC-UHFFFAOYSA-N 1-tert-butyl-4-ethenylbenzene Chemical compound CC(C)(C)C1=CC=C(C=C)C=C1 QEDJMOONZLUIMC-UHFFFAOYSA-N 0.000 description 1
YMOONIIMQBGTDU-UHFFFAOYSA-N 2-bromoethenylbenzene Chemical compound BrC=CC1=CC=CC=C1 YMOONIIMQBGTDU-UHFFFAOYSA-N 0.000 description 1
IWTYTFSSTWXZFU-UHFFFAOYSA-N 3-chloroprop-1-enylbenzene Chemical compound ClCC=CC1=CC=CC=C1 IWTYTFSSTWXZFU-UHFFFAOYSA-N 0.000 description 1
CEBRPXLXYCFYGU-UHFFFAOYSA-N 3-methylbut-1-enylbenzene Chemical compound CC(C)C=CC1=CC=CC=C1 CEBRPXLXYCFYGU-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
229920002943 EPDM rubber Polymers 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
239000005062 Polybutadiene Substances 0.000 description 1
229920002367 Polyisobutene Polymers 0.000 description 1
239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
239000004809 Teflon Substances 0.000 description 1
229920006362 Teflon® Polymers 0.000 description 1
239000006096 absorbing agent Substances 0.000 description 1
125000005396 acrylic acid ester group Chemical group 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000001350 alkyl halides Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
239000004599 antimicrobial Substances 0.000 description 1
229910000410 antimony oxide Inorganic materials 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
239000002216 antistatic agent Substances 0.000 description 1
MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000013329 compounding Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
125000000950 dibromo group Chemical group Br* 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
238000007865 diluting Methods 0.000 description 1
238000002845 discoloration Methods 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
239000000975 dye Substances 0.000 description 1
239000000839 emulsion Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical class C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 1
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
239000000945 filler Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
230000006870 function Effects 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
239000012760 heat stabilizer Substances 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000008240 homogeneous mixture Substances 0.000 description 1
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
230000002452 interceptive effect Effects 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
238000004898 kneading Methods 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000002667 nucleating agent Substances 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
238000005502 peroxidation Methods 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920001084 poly(chloroprene) Polymers 0.000 description 1
229920003056 polybromostyrene Polymers 0.000 description 1
229920001083 polybutene Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
230000002028 premature Effects 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
239000012748 slip agent Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
230000003068 static effect Effects 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
238000012360 testing method Methods 0.000 description 1
229920003212 trans-1,4-polyisoprene Polymers 0.000 description 1
XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
210000003462 vein Anatomy 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
- C08F255/026—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms on to ethylene-vinylester copolymers
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F263/00—Macromolecular compounds obtained by polymerising monomers on to polymers of esters of unsaturated alcohols with saturated acids as defined in group C08F18/00
- C08F263/02—Macromolecular compounds obtained by polymerising monomers on to polymers of esters of unsaturated alcohols with saturated acids as defined in group C08F18/00 on to polymers of vinyl esters with monocarboxylic acids
- C08F263/04—Macromolecular compounds obtained by polymerising monomers on to polymers of esters of unsaturated alcohols with saturated acids as defined in group C08F18/00 on to polymers of vinyl esters with monocarboxylic acids on to polymers of vinyl acetate

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Graft Or Block Polymers (AREA)
Compositions Of Macromolecular Compounds (AREA)

IL9728791A 1990-04-17 1991-02-20 Ethylene vinyl acetate flame retardants IL97287A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US51005590A	1990-04-17	1990-04-17

Publications (2)

Publication Number	Publication Date
IL97287A0 IL97287A0 (en)	1992-05-25
IL97287A true IL97287A (en)	1994-07-31

Family

ID=24029198

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IL9728791A IL97287A (en)	1990-04-17	1991-02-20	Ethylene vinyl acetate flame retardants

Country Status (11)

Country	Link
EP (1)	EP0525094B1 (de)
JP (1)	JPH05507741A (de)
AT (1)	ATE113967T1 (de)
AU (1)	AU643020B2 (de)
CA (1)	CA2036562A1 (de)
DE (1)	DE69105125T2 (de)
DK (1)	DK0525094T3 (de)
ES (1)	ES2065032T3 (de)
IL (1)	IL97287A (de)
MX (1)	MX173993B (de)
WO (1)	WO1991016366A1 (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5077337A (en) *	1990-02-22	1991-12-31	Great Lakes Chemical Corporation	Flame retardant graft copolymers of polypropylene
US5296306A (en) *	1992-11-18	1994-03-22	Great Lakes Chemical Corp.	Flame retardant brominated styrene graft latex coatings
CN1090864A (zh) *	1992-11-18	1994-08-17	大湖化学公司	阻燃溴化苯乙烯接枝胶乳组合物

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3742090A (en) *	1968-05-09	1973-06-26	Toray Industries	Thermoplastic resin composition containing an ethylene-vinyl acetate graft copolymer
US4279808A (en) *	1980-02-14	1981-07-21	Ethyl Corporation	Polybromostyrene resin

1991
- 1991-02-14 AT AT91908751T patent/ATE113967T1/de not_active IP Right Cessation
- 1991-02-14 AU AU77558/91A patent/AU643020B2/en not_active Ceased
- 1991-02-14 JP JP91508292A patent/JPH05507741A/ja active Pending
- 1991-02-14 EP EP91908751A patent/EP0525094B1/de not_active Expired - Lifetime
- 1991-02-14 ES ES91908751T patent/ES2065032T3/es not_active Expired - Lifetime
- 1991-02-14 DK DK91908751.0T patent/DK0525094T3/da active
- 1991-02-14 WO PCT/US1991/000998 patent/WO1991016366A1/en not_active Ceased
- 1991-02-14 DE DE69105125T patent/DE69105125T2/de not_active Expired - Fee Related
- 1991-02-18 CA CA002036562A patent/CA2036562A1/en not_active Abandoned
- 1991-02-20 IL IL9728791A patent/IL97287A/en not_active IP Right Cessation
- 1991-04-15 MX MX025357A patent/MX173993B/es unknown

Also Published As

Publication number	Publication date
JPH05507741A (ja)	1993-11-04
DK0525094T3 (da)	1994-12-05
AU643020B2 (en)	1993-11-04
EP0525094A1 (de)	1993-02-03
WO1991016366A1 (en)	1991-10-31
AU7755891A (en)	1991-11-11
DE69105125D1 (de)	1994-12-15
MX173993B (es)	1994-04-13
IL97287A0 (en)	1992-05-25
DE69105125T2 (de)	1995-03-23
ES2065032T3 (es)	1995-02-01
CA2036562A1 (en)	1991-10-18
EP0525094B1 (de)	1994-11-09
ATE113967T1 (de)	1994-11-15

Legal Events

Date	Code	Title	Description
1996-03-31	CO	Opposition cancelled (oppos. filed against grant of patent)	Free format text: OPPOSITION CANCELLED ON 27.04.95
1998-02-08	RH	Patent void

Publication	Publication Date	Title
US3642950A (en)	1972-02-15	Graft copolymerization on alpha-monoolefin copolymer rubbers to make gum plastics
US5041484A (en)	1991-08-20	Flame retardant hot melt adhesive compositions using brominated styrene/atactic polypropylene graft copolymers
US5077337A (en)	1991-12-31	Flame retardant graft copolymers of polypropylene
US5124404A (en)	1992-06-23	Flame retardant polypropylene molding compositions
AU639398B2 (en)	1993-07-22	Flame retardant hot melt adhesive compositions
GB1591455A (en)	1981-06-24	Flame-retarding resin composition
AU643020B2 (en)	1993-11-04	Flame retardant graft copolymers of ethylene vinyl acetate
JPS5953548A (ja)	1984-03-28	熱可塑性弾性ポリマ−組成物
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