JP2000507151A - 含硫汚染物質、芳香族化合物類および炭化水素類をガスから除去する方法 - Google Patents
含硫汚染物質、芳香族化合物類および炭化水素類をガスから除去する方法Info
- Publication number
- JP2000507151A JP2000507151A JP9525886A JP52588697A JP2000507151A JP 2000507151 A JP2000507151 A JP 2000507151A JP 9525886 A JP9525886 A JP 9525886A JP 52588697 A JP52588697 A JP 52588697A JP 2000507151 A JP2000507151 A JP 2000507151A
- Authority
- JP
- Japan
- Prior art keywords
- gas
- sulfur
- gas stream
- volume
- absorption step
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims abstract description 79
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 76
- 239000011593 sulfur Substances 0.000 title claims abstract description 62
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 62
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 25
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 25
- 239000000356 contaminant Substances 0.000 title claims abstract description 12
- 150000001491 aromatic compounds Chemical class 0.000 title description 9
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims abstract description 34
- 238000010521 absorption reaction Methods 0.000 claims abstract description 31
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 24
- 230000003647 oxidation Effects 0.000 claims abstract description 20
- 150000003464 sulfur compounds Chemical class 0.000 claims abstract description 16
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 12
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract description 3
- 239000007789 gas Substances 0.000 claims description 130
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 32
- 238000005984 hydrogenation reaction Methods 0.000 claims description 18
- 239000000126 substance Substances 0.000 claims description 15
- 239000003345 natural gas Substances 0.000 claims description 14
- 238000000746 purification Methods 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 11
- 238000012545 processing Methods 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- 230000002745 absorbent Effects 0.000 claims description 6
- 239000002250 absorbent Substances 0.000 claims description 6
- 150000003335 secondary amines Chemical class 0.000 claims description 4
- 150000003512 tertiary amines Chemical class 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 abstract description 2
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 1
- 229930195729 fatty acid Natural products 0.000 abstract 1
- 239000000194 fatty acid Substances 0.000 abstract 1
- 150000004665 fatty acids Chemical class 0.000 abstract 1
- 238000011084 recovery Methods 0.000 description 18
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 15
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- 239000000203 mixture Substances 0.000 description 13
- 239000002904 solvent Substances 0.000 description 12
- 230000008929 regeneration Effects 0.000 description 9
- 238000011069 regeneration method Methods 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000006096 absorbing agent Substances 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000008096 xylene Substances 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000004071 soot Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000003795 desorption Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- CRVGTESFCCXCTH-UHFFFAOYSA-N methyl diethanolamine Chemical compound OCCN(C)CCO CRVGTESFCCXCTH-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 150000003463 sulfur Chemical class 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000006477 desulfuration reaction Methods 0.000 description 2
- 230000023556 desulfurization Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- PVXVWWANJIWJOO-UHFFFAOYSA-N 1-(1,3-benzodioxol-5-yl)-N-ethylpropan-2-amine Chemical compound CCNC(C)CC1=CC=C2OCOC2=C1 PVXVWWANJIWJOO-UHFFFAOYSA-N 0.000 description 1
- JCVAWLVWQDNEGS-UHFFFAOYSA-N 1-(2-hydroxypropylamino)propan-2-ol;thiolane 1,1-dioxide;hydrate Chemical compound O.O=S1(=O)CCCC1.CC(O)CNCC(C)O JCVAWLVWQDNEGS-UHFFFAOYSA-N 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- QMMZSJPSPRTHGB-UHFFFAOYSA-N MDEA Natural products CC(C)CCCCC=CCC=CC(O)=O QMMZSJPSPRTHGB-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000112 cooling gas Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1406—Multiple stage absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/75—Multi-step processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
- B01D53/8612—Hydrogen sulfide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
- C01B17/0408—Pretreatment of the hydrogen sulfide containing gases
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
- Industrial Gases (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL1002135A NL1002135C2 (nl) | 1996-01-19 | 1996-01-19 | Werkwijze voor het verwijderen van zwavelbevattende verontreinigingen, aromaten en koolwaterstoffen uit gas. |
| NL1002135 | 1996-01-19 | ||
| PCT/NL1997/000019 WO1997026070A1 (en) | 1996-01-19 | 1997-01-20 | Method for removing sulfur-containing contaminants, aromatics and hydrocarbons from gas |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2000507151A true JP2000507151A (ja) | 2000-06-13 |
Family
ID=19762184
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9525886A Pending JP2000507151A (ja) | 1996-01-19 | 1997-01-20 | 含硫汚染物質、芳香族化合物類および炭化水素類をガスから除去する方法 |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP0885052A1 (id) |
| JP (1) | JP2000507151A (id) |
| KR (1) | KR19990077362A (id) |
| CN (1) | CN1209756A (id) |
| AU (1) | AU1321497A (id) |
| CA (1) | CA2243482A1 (id) |
| ID (1) | ID15833A (id) |
| NL (1) | NL1002135C2 (id) |
| TW (1) | TW372883B (id) |
| WO (1) | WO1997026070A1 (id) |
| ZA (1) | ZA97326B (id) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002265964A (ja) * | 2001-03-07 | 2002-09-18 | Chiyoda Corp | 天然ガスからの硫黄化合物の除去方法 |
| JP2005518271A (ja) * | 2002-02-26 | 2005-06-23 | ルルギ・アクチエンゲゼルシャフト | クラッドガスからメルカプタンを除去する方法 |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0021409D0 (en) | 2000-08-31 | 2000-10-18 | Boc Group Plc | Treatment of a gas stream containing hydrogen sulphide |
| DE10219900B4 (de) | 2002-05-03 | 2004-08-26 | Lurgi Ag | Verfahren zur Reinigung von kohlenwasserstoffhaltigem Gas |
| FR2875236B1 (fr) * | 2004-09-10 | 2006-11-10 | Total Sa | Procede et installation pour le traitement de dso |
| FR2916652B1 (fr) * | 2007-05-30 | 2009-07-24 | Inst Francais Du Petrole | Procede de traitement integre d'un gaz naturel permettant de realiser une desacidification complete |
| CN101480560B (zh) * | 2008-01-09 | 2011-11-30 | 中国石油化工股份有限公司 | 一种采用膜分离处理克劳斯尾气的方法 |
| US8926737B2 (en) * | 2008-11-28 | 2015-01-06 | Shell Oil Company | Process for producing purified natural gas |
| CN108579348A (zh) * | 2014-04-16 | 2018-09-28 | 沙特阿拉伯石油公司 | 改进的硫回收工艺 |
| RU2649442C2 (ru) * | 2016-04-25 | 2018-04-03 | Общество с ограниченной ответственностью "Старт-Катализатор" | Установка, способ и катализатор очистки газообразного углеводородного сырья от сероводорода и меркаптанов |
| WO2018115919A1 (en) * | 2016-12-23 | 2018-06-28 | Total Sa | Integrated process for elemental sulphur treatment |
| CN108452652B (zh) * | 2017-12-04 | 2021-06-08 | 盐城市兰丰环境工程科技有限公司 | 一种工业气体脱硫系统 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4088735A (en) * | 1974-07-10 | 1978-05-09 | Metallgesellschaft Aktiengesellschaft | Process for purifying gases from the gasification of fossil fuels |
| US3989811A (en) * | 1975-01-30 | 1976-11-02 | Shell Oil Company | Process for recovering sulfur from fuel gases containing hydrogen sulfide, carbon dioxide, and carbonyl sulfide |
| FR2501663A1 (fr) * | 1981-03-13 | 1982-09-17 | Technip Cie | Procede et installation de traitement des gaz acides pour la recuperation et la production de soufre et de gaz carbonique |
| US4356161A (en) * | 1981-08-24 | 1982-10-26 | Shell Oil Company | Process for reducing the total sulfur content of a high CO2 -content feed gas |
| DE4206943A1 (de) * | 1992-03-05 | 1993-09-09 | Krupp Koppers Gmbh | Verfahren zur reinigung eines durch vergasung von kohlenstoffhaltigem material gewonnenen gases |
-
1996
- 1996-01-19 NL NL1002135A patent/NL1002135C2/nl not_active IP Right Cessation
-
1997
- 1997-01-15 ZA ZA97326A patent/ZA97326B/xx unknown
- 1997-01-17 TW TW086100466A patent/TW372883B/zh active
- 1997-01-17 ID IDP970125A patent/ID15833A/id unknown
- 1997-01-20 WO PCT/NL1997/000019 patent/WO1997026070A1/en not_active Ceased
- 1997-01-20 KR KR1019980705511A patent/KR19990077362A/ko not_active Withdrawn
- 1997-01-20 JP JP9525886A patent/JP2000507151A/ja active Pending
- 1997-01-20 CA CA002243482A patent/CA2243482A1/en not_active Abandoned
- 1997-01-20 AU AU13214/97A patent/AU1321497A/en not_active Abandoned
- 1997-01-20 EP EP97900808A patent/EP0885052A1/en not_active Ceased
- 1997-01-20 CN CN97191774A patent/CN1209756A/zh active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002265964A (ja) * | 2001-03-07 | 2002-09-18 | Chiyoda Corp | 天然ガスからの硫黄化合物の除去方法 |
| JP2005518271A (ja) * | 2002-02-26 | 2005-06-23 | ルルギ・アクチエンゲゼルシャフト | クラッドガスからメルカプタンを除去する方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU1321497A (en) | 1997-08-11 |
| CN1209756A (zh) | 1999-03-03 |
| ZA97326B (en) | 1997-07-22 |
| EP0885052A1 (en) | 1998-12-23 |
| CA2243482A1 (en) | 1997-07-24 |
| TW372883B (en) | 1999-11-01 |
| KR19990077362A (ko) | 1999-10-25 |
| WO1997026070A1 (en) | 1997-07-24 |
| NL1002135C2 (nl) | 1997-07-22 |
| ID15833A (id) | 1997-08-14 |
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