JP2017141461A5 - - Google Patents
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- Publication number
- JP2017141461A5 JP2017141461A5 JP2017055585A JP2017055585A JP2017141461A5 JP 2017141461 A5 JP2017141461 A5 JP 2017141461A5 JP 2017055585 A JP2017055585 A JP 2017055585A JP 2017055585 A JP2017055585 A JP 2017055585A JP 2017141461 A5 JP2017141461 A5 JP 2017141461A5
- Authority
- JP
- Japan
- Prior art keywords
- cold water
- copolymer
- voh
- vam
- vinyl acetate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 229920001577 copolymer Polymers 0.000 claims description 9
- 238000004090 dissolution Methods 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 20
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical group CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims 15
- 125000005250 alkyl acrylate group Chemical group 0.000 claims 8
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims 7
- 229920005604 random copolymer Polymers 0.000 claims 7
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims 1
- 238000013019 agitation Methods 0.000 claims 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201061459979P | 2010-12-22 | 2010-12-22 | |
| US61/459,979 | 2010-12-22 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2015216584A Division JP6117893B2 (ja) | 2010-12-22 | 2015-11-04 | 冷水可溶性ポリビニルアルコール／アルキルアクリレートコポリマーおよびそれらのフィルム |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2017141461A JP2017141461A (ja) | 2017-08-17 |
| JP2017141461A5 true JP2017141461A5 (2) | 2017-12-07 |
| JP6454745B2 JP6454745B2 (ja) | 2019-01-16 |
Family
ID=45478541
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013546257A Active JP5931088B2 (ja) | 2010-12-22 | 2011-12-16 | 冷水可溶性ポリビニルアルコール／アルキルアクリレートコポリマーおよびそれらのフィルム |
| JP2015216584A Active JP6117893B2 (ja) | 2010-12-22 | 2015-11-04 | 冷水可溶性ポリビニルアルコール／アルキルアクリレートコポリマーおよびそれらのフィルム |
| JP2017055585A Active JP6454745B2 (ja) | 2010-12-22 | 2017-03-22 | 冷水可溶性ポリビニルアルコール／アルキルアクリレートコポリマーおよびそれらのフィルム |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013546257A Active JP5931088B2 (ja) | 2010-12-22 | 2011-12-16 | 冷水可溶性ポリビニルアルコール／アルキルアクリレートコポリマーおよびそれらのフィルム |
| JP2015216584A Active JP6117893B2 (ja) | 2010-12-22 | 2015-11-04 | 冷水可溶性ポリビニルアルコール／アルキルアクリレートコポリマーおよびそれらのフィルム |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US10316124B2 (2) |
| EP (1) | EP2655447B1 (2) |
| JP (3) | JP5931088B2 (2) |
| CN (1) | CN103403043A (2) |
| ES (1) | ES2543044T3 (2) |
| WO (1) | WO2012087821A1 (2) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10808210B2 (en) | 2013-03-15 | 2020-10-20 | Monosol, Llc | Water-soluble film for delayed release |
| JP6246891B2 (ja) * | 2013-03-15 | 2017-12-13 | モノソル リミテッド ライアビリティ カンパニー | 遅延放出用の水溶性フィルム |
| EP3432049B1 (en) | 2013-12-06 | 2024-07-31 | 3M Innovative Properties Co. | Semi-submersible microscope objective for in a multiphoton stereolithography process |
| EP3088429B1 (en) | 2013-12-25 | 2020-02-05 | Kuraray Co., Ltd. | Modified polyvinyl alcohol and water-soluble film containing same |
| US10898821B2 (en) * | 2015-06-02 | 2021-01-26 | Moose Creative Management Pty Limited | Adhesive toy beads |
| BR112018001645A2 (pt) * | 2015-08-31 | 2018-09-18 | Wacker Chemie Ag | pacote de aditivos |
| RU2760028C2 (ru) | 2016-04-13 | 2021-11-22 | МОНОСОЛ, ЭлЭлСи | Водорастворимая пленка, пакеты из пленки и способы их получения и применения |
| CN109311574A (zh) | 2016-06-13 | 2019-02-05 | 蒙诺苏尔有限公司 | 水溶性小包装 |
| WO2017218443A1 (en) | 2016-06-13 | 2017-12-21 | The Procter & Gamble Company | Water-soluble unit dose articles made from a combination of different films and containing household care compositions |
| WO2017218414A1 (en) | 2016-06-13 | 2017-12-21 | Monosol, Llc | Use of a first film and a second film to improve seal strength of a water-soluble |
| WO2017218408A1 (en) | 2016-06-13 | 2017-12-21 | Monosol, Llc | Water-soluble unit dose articles made from a combination of different films |
| US10479965B2 (en) | 2016-06-13 | 2019-11-19 | The Procter & Gamble Company | Water-soluble unit dose articles made from a combination of different films and containing household care compositions |
| HUE068143T2 (hu) | 2016-06-13 | 2024-12-28 | Procter & Gamble | Különbözõ filmek kombinációjából készült, vízoldható, háztartási tisztítókészítményeket tartalmazó egyadagos termékek |
| US10858457B2 (en) | 2017-08-17 | 2020-12-08 | Kuraray Co., Ltd. | Particulate polyvinyl alcohol copolymers, process for making and uses of the same |
| JP7124707B2 (ja) | 2017-10-18 | 2022-08-24 | 三菱ケミカル株式会社 | 水溶性フィルム及び薬剤包装体 |
| TWI704868B (zh) | 2018-03-08 | 2020-09-21 | 日商可樂麗股份有限公司 | 農藥用展著劑及農藥散布液 |
| CA3131578A1 (en) | 2019-02-06 | 2020-08-13 | Monosol, Llc | Water-soluble coatings for substrate surfaces |
| CN110713749B (zh) * | 2019-10-16 | 2022-07-29 | 东南大学 | 一种电响应聚合物材料及其制备方法与应用 |
| US12311282B2 (en) | 2022-01-01 | 2025-05-27 | Spin Master Ltd. | Kit with plurality of blocks for constructing craft |
Family Cites Families (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1720806C2 (de) | 1968-03-19 | 1982-09-23 | Hoechst Ag, 6000 Frankfurt | Verfahren zur kontinuierlichen Polymerisation von Vinylestern |
| US3692754A (en) * | 1969-04-05 | 1972-09-19 | Masaaki Hirooka | Highly lactonized copolymers and alternating copolymers using unsaturated ethers |
| US3689469A (en) | 1969-07-15 | 1972-09-05 | Du Pont | Copolymers of vinyl alcohol and methyl methacrylate and uses therefor |
| JPS4936797A (2) | 1972-08-11 | 1974-04-05 | ||
| US4048413A (en) | 1975-12-08 | 1977-09-13 | Scm Corporation | High-conversion drift-free batch-type addition copolymerization |
| US4156047A (en) | 1976-08-18 | 1979-05-22 | E. I. Du Pont De Nemours And Company | Water-soluble films from polyvinyl alcohol compositions |
| DE3312668A1 (de) * | 1983-04-08 | 1984-10-11 | Basf Ag, 6700 Ludwigshafen | Wasserloesliche polymere mit geringer hygroskopie |
| US4618648A (en) | 1985-04-26 | 1986-10-21 | Air Products And Chemicals, Inc. | Copolymers of vinyl alcohol and poly(alkyleneoxy)acrylates |
| JPH0627205B2 (ja) * | 1986-12-27 | 1994-04-13 | 日本合成化学工業株式会社 | アルカリ性物質包装用のポリビニルアルコ−ルフイルム |
| US4948857A (en) | 1987-01-16 | 1990-08-14 | Air Products And Chemicals, Inc. | Copolymers of vinyl acetate and acrylates |
| US4772663A (en) | 1987-01-16 | 1988-09-20 | Air Products And Chemicals, Inc. | Copolymers of vinyl alcohol and acrylates |
| JPS63182313A (ja) | 1987-01-16 | 1988-07-27 | エアー．プロダクツ．アンド．ケミカルス．インコーポレーテッド | 酢酸ビニル−アクリレート系共重合体 |
| US4990335A (en) | 1987-03-25 | 1991-02-05 | E. I. Du Pont De Nemours And Company | Use of vinyl alcohol homopolymer and copolymers for tableting active materials |
| US4885105A (en) * | 1987-05-14 | 1989-12-05 | The Clorox Company | Films from PVA modified with nonhydrolyzable anionic comonomers |
| US4747976A (en) | 1987-05-14 | 1988-05-31 | The Clorox Company | PVA films with nonhydrolyzable anionic comonomers for packaging detergents |
| US5362515A (en) | 1994-02-28 | 1994-11-08 | E. I. Du Pont De Nemours And Company | Poly(vinyl alcohol)copolymer sizes having high capacity to be desized |
| US5436293A (en) | 1994-02-28 | 1995-07-25 | E. I. Du Pont De Nemours And Company | Poly(vinyl alcohol) polymer blend textile sizes with improved ability to be desized |
| JPH0936797A (ja) | 1995-07-17 | 1997-02-07 | Kokusai Electric Co Ltd | 光通信機能付無線呼出受信機 |
| JP2000501136A (ja) * | 1995-11-29 | 2000-02-02 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | ポリビニルアセタールおよびそれらの製造 |
| US6387991B1 (en) | 1995-12-18 | 2002-05-14 | E. I. Du Pont De Nemours & Company | Poly(vinyl alcohol) copolymer ionomers, their preparation and use in textile sizes |
| US6946501B2 (en) | 2001-01-31 | 2005-09-20 | The Procter & Gamble Company | Rapidly dissolvable polymer films and articles made therefrom |
| EP1534216B1 (en) | 2002-08-14 | 2017-01-04 | Givaudan S.A. | Compositions comprising encapsulated material |
| JP4056859B2 (ja) | 2002-11-11 | 2008-03-05 | 日本合成化学工業株式会社 | 水溶性フィルム |
| US6821590B2 (en) | 2003-02-14 | 2004-11-23 | Monosol, Llc | Starch-loaded polyvinyl alcohol copolymer film |
| US7022656B2 (en) * | 2003-03-19 | 2006-04-04 | Monosol, Llc. | Water-soluble copolymer film packet |
| US6818709B1 (en) | 2003-07-11 | 2004-11-16 | Celanese International Corporation | Production of vinyl alcohol copolymers |
| US7786229B2 (en) | 2003-07-11 | 2010-08-31 | Sekisui Specialty Chemicals America, Llc | Vinyl alcohol copolymers for use in aqueous dispersions and melt extruded articles |
| JP2005089655A (ja) | 2003-09-18 | 2005-04-07 | Japan Vam & Poval Co Ltd | ポリビニルアルコール系樹脂およびフィルム |
| JP2005139240A (ja) * | 2003-11-04 | 2005-06-02 | Japan Vam & Poval Co Ltd | 水溶性フィルムおよび個別包装材 |
| US7767282B2 (en) * | 2004-08-10 | 2010-08-03 | E.I. Du Pont De Nemours And Company | Copolymers of vinyl alcohol and itaconic acid and uses thereof |
| US8790632B2 (en) | 2004-10-07 | 2014-07-29 | Actamax Surgical Materials, Llc | Polymer-based tissue-adhesive form medical use |
| US7714086B2 (en) * | 2005-02-23 | 2010-05-11 | The Procter & Gamble Company | Polyvinyl alcohol co-polymer, and water-soluble films and pouches formed therefrom |
| US7622132B2 (en) | 2005-06-27 | 2009-11-24 | Elc Management, Llc | Encapsulated cosmetic composition |
| US7476325B2 (en) | 2005-08-09 | 2009-01-13 | E.I. Du Pont De Nemours And Company | Treatment of recreational water |
| BRPI0604797A (pt) * | 2005-11-30 | 2007-10-09 | Goodyear Tire & Rubber | polìmeros de borracha funcionalizados |
| US7745517B2 (en) | 2006-05-02 | 2010-06-29 | Sekisui Specialty Chemicals America, Llc | Polyvinyl alcohol films with improved resistance to oxidizing chemicals |
| US7781506B2 (en) * | 2007-01-26 | 2010-08-24 | E.I. Du Pont De Nemours And Company | Poly(vinyl alcohol) composition comprising a polyol |
| JP4835719B2 (ja) | 2008-05-22 | 2011-12-14 | ソニー株式会社 | 固体撮像装置及び電子機器 |
-
2011
- 2011-12-16 WO PCT/US2011/065473 patent/WO2012087821A1/en not_active Ceased
- 2011-12-16 US US13/328,338 patent/US10316124B2/en active Active
- 2011-12-16 EP EP11808485.4A patent/EP2655447B1/en not_active Revoked
- 2011-12-16 JP JP2013546257A patent/JP5931088B2/ja active Active
- 2011-12-16 ES ES11808485.4T patent/ES2543044T3/es active Active
- 2011-12-16 CN CN2011800680936A patent/CN103403043A/zh active Pending
-
2015
- 2015-11-04 JP JP2015216584A patent/JP6117893B2/ja active Active
-
2017
- 2017-03-22 JP JP2017055585A patent/JP6454745B2/ja active Active
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