JP2533763B2 - Bath salts containing film-like components - Google Patents
Bath salts containing film-like componentsInfo
- Publication number
- JP2533763B2 JP2533763B2 JP61256323A JP25632386A JP2533763B2 JP 2533763 B2 JP2533763 B2 JP 2533763B2 JP 61256323 A JP61256323 A JP 61256323A JP 25632386 A JP25632386 A JP 25632386A JP 2533763 B2 JP2533763 B2 JP 2533763B2
- Authority
- JP
- Japan
- Prior art keywords
- water
- film
- components
- soluble film
- bath
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 235000019341 magnesium sulphate Nutrition 0.000 title description 4
- 229910052943 magnesium sulfate Inorganic materials 0.000 title description 2
- 239000013040 bath agent Substances 0.000 claims description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 8
- 239000003205 fragrance Substances 0.000 claims description 8
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 239000000975 dye Substances 0.000 description 13
- 102000004190 Enzymes Human genes 0.000 description 10
- 108090000790 Enzymes Proteins 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 238000003860 storage Methods 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 238000003287 bathing Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000004090 dissolution Methods 0.000 description 4
- 230000007774 longterm Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229920000609 methyl cellulose Polymers 0.000 description 4
- 239000001923 methylcellulose Substances 0.000 description 4
- 235000010981 methylcellulose Nutrition 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000004040 coloring Methods 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 239000010200 folin Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000011782 vitamin Substances 0.000 description 2
- 229940088594 vitamin Drugs 0.000 description 2
- 229930003231 vitamin Natural products 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- 238000000862 absorption spectrum Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 description 1
- -1 granular Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- 230000036962 time dependent Effects 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
【発明の詳細な説明】 ＜産業上の利用分野＞ 本発明は、水溶性フィルム状成分を含む入浴剤に関す
る。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a bath agent containing a water-soluble film-like component.
＜従来の技術とその問題点＞ 従来、入浴剤は、液状、粉状、顆粒状、或いは打錠を
問わず、有効成分、色素、香料等の全ての組成成分を、
単に混合、乳化混合或いは成分の一部を造粒化し、着色
を施したものであった。<Conventional technology and its problems> Conventionally, a bathing agent, regardless of whether it is liquid, powder, granular, or tablet, contains all the composition components such as active ingredients, pigments, and fragrances.
It was obtained by simply mixing, emulsifying and mixing, or granulating a part of the components and coloring.
従って、入浴剤の使用時においては、これらの組成成
分は、造粒化されている場合でも、その溶解に要する時
間が長く、使用時において不快感を与えるものであっ
た。Therefore, when the bath salt is used, these composition components, even when granulated, take a long time to be dissolved, which causes discomfort during use.
更に、組成成分の一部、例えば香料や色素をカプセル
化や、造粒化した場合、多成分に比べ、溶解までに要す
る時間が長いだけでなく、浴槽に沈む、又は浮遊した状
態で溶解するものであるため、浴槽中での均一分散に
は、消費者が自ら攪拌する等の物理的な力が必要であっ
た。Further, when a part of the composition components, for example, a fragrance or a dye is encapsulated or granulated, not only the time required for dissolution is longer than that of the multi-component, but it also sinks in a bath or dissolves in a floating state. Therefore, the uniform dispersion in the bath requires physical force such as stirring by the consumer.
本発明は、上記従来技術の有する問題点を解決するこ
とができ、含有される色素、酵素、香料等の保存時にお
ける安定性に優れた水溶性フィルム状成分を含む入浴剤
を提供することを目的とする。The present invention is capable of solving the above-mentioned problems of the prior art, and provides a bath agent containing a water-soluble film-like component having excellent stability during storage of contained dyes, enzymes, perfumes, and the like. To aim.
＜問題点を解決するための手段及び構成＞ 本発明によれば、色素、酵素、香料の少なくとも１種
と、フィルム形成成分としてのトリグルコ多糖及びポリ
ビニルアルコールとを含有する水溶性フィルム状成分を
含む入浴剤が提供される。<Means and Structure for Solving Problems> According to the present invention, a water-soluble film-like component containing at least one of a dye, an enzyme, and a fragrance, and triglucopolysaccharide and polyvinyl alcohol as film-forming components is included. Bath salts are provided.
本発明において、水溶性フィルム状成分は、色素、酵
素、香料の少なくとも１種を含有し、またフィルム形成
成分として、トリグルコ多糖及びポリビニルアルコール
とを必須成分として含有する。この水溶性フィルム状成
分の製造は、例えば、フィルム形成成分に、色素、酵
素、香料の少なくとも１種、必要に応じて各種ビタミン
等を配合し、水溶性のフィルム状組成物とした後、フィ
ルム形成し、乾燥等を行って調製するのが好ましい。こ
の際必要に応じて、溶媒として水を使用することもでき
る。またフィルム形成成分として、グリセリン等を含有
させることもできる。In the present invention, the water-soluble film-like component contains at least one of a dye, an enzyme and a fragrance, and also contains triglucopolysaccharide and polyvinyl alcohol as essential components as film-forming components. This water-soluble film-like component is produced, for example, by adding at least one kind of dye, enzyme, perfume, and optionally various vitamins to the film-forming component to prepare a water-soluble film-like composition, and then forming a film. It is preferably prepared by forming, drying and the like. At this time, water may be used as a solvent, if necessary. In addition, glycerin or the like can be contained as a film forming component.
水溶性フィルム状成分の厚みや、フィルム形成成分の
配合割合を調節することにより、溶解時間、溶解温度、
溶解pH等を調節することができる。By adjusting the thickness of the water-soluble film-like component and the mixing ratio of the film-forming component, the dissolution time, the dissolution temperature,
The dissolution pH and the like can be adjusted.
本発明の入浴剤は、前記水溶性フィルム状成分を含有
するので、浴場へ投入した場合、迅速に溶解させること
ができる。また、水溶性フィルム状成分に色素を含有さ
せる場合、フィルム表面に所望の模様をプリントするこ
ともできる。Since the bath agent of the present invention contains the above-mentioned water-soluble film-like component, it can be rapidly dissolved when it is put into a bath. When a dye is contained in the water-soluble film component, a desired pattern can be printed on the film surface.
また、入浴剤成分として不安定な成分である色素、酵
素、香料、更には各種ビタミンの長期保存時の品質安定
性を向上させることができる。In addition, it is possible to improve the quality stability of long-term storage of dyes, enzymes, fragrances, and various vitamins, which are unstable components as bathing agent components.
更に、水溶性フィルム状成分を、任意の形状（例えば
ハート形、星形）とすることによって、製品の外観を楽
しいものとして、購買意欲を増大させることができる。Furthermore, by making the water-soluble film-like component into an arbitrary shape (for example, a heart shape or a star shape), the appearance of the product can be made enjoyable, and the willingness to purchase can be increased.
＜実施例＞ 次に本発明を実施例に基づいて具体的に説明する。<Examples> Next, the present invention will be specifically described based on Examples.
製造例１ 第１表に示す組成にしたがって、以下の製造方法で水
溶性フィルム状成分（ａ〜ｈ）を調製した。Production Example 1 Water-soluble film components (a to h) were prepared according to the composition shown in Table 1 by the following production method.
4,4,6−トリグルコ多糖粉末をイオン交換水で溶解
し、15〜35％水溶液に調整した。次にポリビニルアルコ
ールをイオン交換水で溶解し、８〜30％水溶液に調整し
た。メチルセルロースをイオン交換水で溶解し15〜35％
水溶液に調整した。その後、第１表に示す各配合量の4,
4,6−トリグルコ多糖粉末、ポリビニルアルコール、メ
チルセルロース（固形量）に、グリセリン、色素、香
料、酵素を各配合量で混合脱泡して調整フィルム可溶液
を作成した。次に、調整フィルム化溶液を、キャスティ
ング法により、ポリエステルフィルム上にコーティング
し、乾燥した後、ポリエステルフィルムから剥離して第
１表に示す組成の水溶性フィルムａ〜ｈを製造した。な
お、水溶性フィルムａ〜ｈの厚さは、それぞれ30μｍ、
20μｍ、25μｍ、52μｍ、30μｍ、30μｍ、30μｍ、30
μｍ、とし、その形状は5mm四角とした。この寸法は、
配合に応じて適当な厚み、大きさ及び形状にカットして
配合することができる。The 4,4,6-triglucopolysaccharide powder was dissolved in ion-exchanged water to prepare a 15-35% aqueous solution. Next, polyvinyl alcohol was dissolved in ion-exchanged water to prepare an 8-30% aqueous solution. Dissolve methyl cellulose in ion-exchanged water 15-35%
An aqueous solution was prepared. After that, 4 of each compounding amount shown in Table 1,
4,6-Triglucopolysaccharide powder, polyvinyl alcohol, and methyl cellulose (solid amount) were mixed and defoamed with glycerin, a dye, a fragrance, and an enzyme at respective compounding amounts to prepare a controllable film solution. Next, the adjusted film forming solution was coated on a polyester film by a casting method, dried, and then peeled off from the polyester film to produce water-soluble films a to h having the composition shown in Table 1. In addition, the thickness of each of the water-soluble films a to h is 30 μm,
20 μm, 25 μm, 52 μm, 30 μm, 30 μm, 30 μm, 30
μm, and the shape was a 5 mm square. This dimension is
It can be blended by cutting it into an appropriate thickness, size and shape depending on the blending.
実施例１及び2,比較例１〜４ 第２表の組成にしたがって製造例で調製した水溶性フ
ィルムを含む入浴剤を調製した。各入浴剤について第３
表に示す各入浴剤の特性を被験者60人について試験し
た。その結果を同表に示す。 Examples 1 and 2, Comparative Examples 1 to 4 A bathing agent containing the water-soluble film prepared in the Production Example was prepared according to the composition shown in Table 2. Third about each bath agent
The properties of each bath salt shown in the table were tested on 60 subjects. The results are shown in the table.
第３表の結果より、本願発明の水溶性フィルムを含む
入浴剤は、他のフィルム形成成分で形成された比較例に
比して、浴槽への付着がなく入浴剤として速やかに溶解
させることができる他、色素の長期保存における品質安
定性が確保されていることがわかる。また香料を水溶性
フィルム中に配合することによって、長期保存における
品質安定性が確保できることがわかる。 From the results shown in Table 3, the bath agent containing the water-soluble film of the present invention does not adhere to the bath and can be rapidly dissolved as a bath agent as compared with Comparative Examples formed of other film-forming components. In addition, it can be seen that the quality stability is ensured during long-term storage of the dye. Further, it is understood that by incorporating the fragrance into the water-soluble film, quality stability can be secured during long-term storage.
実施例３及び比較例５〜８ 第４表の組成にしたがって製造例で調製した水溶性フ
ィルムを含む入浴剤を調製した。各入浴剤について配合
された色素と酵素の経時安定性を調べた。Example 3 and Comparative Examples 5 to 8 A bath agent containing the water-soluble film prepared in the Production Example was prepared according to the composition shown in Table 4. The temporal stability of the dye and the enzyme contained in each bath agent was examined.
なお、色素については、ブリリアントブルーFCFは630
μｍ、ウラニンコンクは490μｍの各吸収スペクトルに
より、色素の残存率を測定した。また酵素については、
ミルクカゼインを基質として、チロジン−フォリン法に
より測定し、１分間に、１μｇのチロジン相当フォリン
呈色を１単位として、酵素活性の残存率を測定した。こ
の経時安定測定における保存条件は、室温、40℃、
75％RHの二つの条件にて50日間及び100日間保存したも
のである。結果を第５表に示す。Regarding the dye, Brilliant Blue FCF is 630
The residual rate of the dye was measured by each absorption spectrum of 490 μm and μm and uranine conc. For enzymes,
Using milk casein as a substrate, measurement was carried out by the tyrosin-folin method, and the residual rate of enzyme activity was measured with 1 μg of thyrozine-equivalent folin coloring as 1 unit per minute. Storage conditions for this time-dependent stable measurement are room temperature, 40 ° C,
It was stored under two conditions of 75% RH for 50 days and 100 days. The results are shown in Table 5.
第５表の結果より、本発明のトリグルコ多糖とポリビ
ニルアルコールとをフィルム形成成分として含む水溶性
フィルム（ａ〜ｄ）を含有する入浴剤は、フィルム形成
成分としてポリビニルアルコールとメチルセルロースを
組合わせた水溶性フィルムｅ、ポリビニルアルコール単
独の水溶性フィルムｆ、トリグルコ多糖単独の水溶性フ
ィルムｇ、メチルセルロース単独の水溶性フィルムｈと
比較して、何れも含有される色素や酵素に対する長期保
存安定性に優れていることがわかる。 From the results of Table 5, the bathing agent containing the water-soluble film (a to d) containing the triglucopolysaccharide of the present invention and polyvinyl alcohol as the film-forming components is a water-soluble mixture of polyvinyl alcohol and methyl cellulose as the film-forming components. Compared with the water-soluble film e, the water-soluble film f of polyvinyl alcohol alone, the water-soluble film g of triglucopolysaccharide alone, and the water-soluble film h of methylcellulose alone, all have excellent long-term storage stability against the dye or enzyme contained therein. You can see that
Claims (1)
ィルム形成成分としてのトリグルコ多糖及びポリビニル
アルコールとを含有する水溶性フィルム状成分を含む入
浴剤。1. A bath agent containing a water-soluble film-like component containing at least one of a dye, oxygen, and a fragrance, and triglucopolysaccharide and polyvinyl alcohol as film-forming components.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61256323A JP2533763B2 (en) | 1986-10-27 | 1986-10-27 | Bath salts containing film-like components |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61256323A JP2533763B2 (en) | 1986-10-27 | 1986-10-27 | Bath salts containing film-like components |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63112510A JPS63112510A (en) | 1988-05-17 |
| JP2533763B2 true JP2533763B2 (en) | 1996-09-11 |
Family
ID=17291073
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61256323A Expired - Lifetime JP2533763B2 (en) | 1986-10-27 | 1986-10-27 | Bath salts containing film-like components |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2533763B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8186010B2 (en) | 2006-12-08 | 2012-05-29 | Nifco Inc. | Retracting mechanism and fixing structure |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10087401B2 (en) * | 2012-03-16 | 2018-10-02 | Monosol, Llc | Water soluble compositions incorporating enzymes, and method of making same |
| US9394092B2 (en) | 2012-04-16 | 2016-07-19 | Monosol, Llc | Powdered pouch and method of making same |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3422055A1 (en) * | 1984-06-14 | 1985-12-19 | Henkel KGaA, 4000 Düsseldorf | WASHING ADDITIVE |
| JPH0796493B2 (en) * | 1985-09-26 | 1995-10-18 | サンスタ−株式会社 | Bath agent |
| JPH0653657B2 (en) * | 1985-09-26 | 1994-07-20 | サンスタ−株式会社 | Bath agent |
-
1986
- 1986-10-27 JP JP61256323A patent/JP2533763B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8186010B2 (en) | 2006-12-08 | 2012-05-29 | Nifco Inc. | Retracting mechanism and fixing structure |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63112510A (en) | 1988-05-17 |
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