JP3306809B2 - ガラスのミル添加物およびそれを含む融着シール材料 - Google Patents

ガラスのミル添加物およびそれを含む融着シール材料

Info

Publication number: JP3306809B2
Authority: JP; Japan
Prior art keywords: glass; pyrophosphate; mill additive; mill; sealing
Prior art date: 1990-10-09
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

JP25350491A

Other languages

English (en)

Japanese (ja)

Other versions

JPH04231349A (ja

Inventor

ケイコーネリアスローレン

リーフランシスゲイロード

アーサーティックポール

Original Assignee

コーニング・インコーポレーテッド

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-10-09

Filing date

1991-10-01

Publication date

2002-07-24

1991-10-01 Application filed by コーニング・インコーポレーテッド filed Critical コーニング・インコーポレーテッド

1992-08-20 Publication of JPH04231349A publication Critical patent/JPH04231349A/ja

2002-07-24 Application granted granted Critical

2002-07-24 Publication of JP3306809B2 publication Critical patent/JP3306809B2/ja

2017-07-24 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000011521 glass Substances 0.000 title claims description 111
239000000654 additive Substances 0.000 title claims description 40
230000000996 additive effect Effects 0.000 title claims description 27
239000000463 material Substances 0.000 title claims description 22
230000004927 fusion Effects 0.000 title claims description 10
239000000203 mixture Substances 0.000 claims description 41
238000007789 sealing Methods 0.000 claims description 25
XZTWHWHGBBCSMX-UHFFFAOYSA-J dimagnesium;phosphonato phosphate Chemical compound [Mg+2].[Mg+2].[O-]P([O-])(=O)OP([O-])([O-])=O XZTWHWHGBBCSMX-UHFFFAOYSA-J 0.000 claims description 23
YLTFFKMNPJHDPJ-UHFFFAOYSA-N O(F)F.[P].[Sn] Chemical group O(F)F.[P].[Sn] YLTFFKMNPJHDPJ-UHFFFAOYSA-N 0.000 claims description 13
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
239000003566 sealing material Substances 0.000 claims description 12
229910052751 metal Inorganic materials 0.000 claims description 11
239000002184 metal Substances 0.000 claims description 11
229910052698 phosphorus Inorganic materials 0.000 claims description 11
235000011180 diphosphates Nutrition 0.000 claims description 10
239000011701 zinc Substances 0.000 claims description 10
229910052725 zinc Inorganic materials 0.000 claims description 9
XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 claims description 8
229910052742 iron Inorganic materials 0.000 claims description 8
229910052758 niobium Inorganic materials 0.000 claims description 8
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 6
229910052782 aluminium Inorganic materials 0.000 claims description 6
150000001768 cations Chemical class 0.000 claims description 6
238000000034 method Methods 0.000 claims description 6
229910052750 molybdenum Inorganic materials 0.000 claims description 6
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
HUTDDBSSHVOYJR-UHFFFAOYSA-H bis[(2-oxo-1,3,2$l^{5},4$l^{2}-dioxaphosphaplumbetan-2-yl)oxy]lead Chemical compound [Pb+2].[Pb+2].[Pb+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O HUTDDBSSHVOYJR-UHFFFAOYSA-H 0.000 claims description 5
229910052726 zirconium Inorganic materials 0.000 claims description 5
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
229910017052 cobalt Inorganic materials 0.000 claims description 4
239000010941 cobalt Substances 0.000 claims description 4
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
239000002178 crystalline material Substances 0.000 claims description 4
239000011733 molybdenum Substances 0.000 claims description 4
229910052721 tungsten Inorganic materials 0.000 claims description 4
239000010937 tungsten Substances 0.000 claims description 4
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
239000004855 amber Substances 0.000 claims description 3
229910052785 arsenic Inorganic materials 0.000 claims description 3
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 3
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 3
239000005394 sealing glass Substances 0.000 claims description 2
229910052787 antimony Inorganic materials 0.000 claims 1
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims 1
229910052797 bismuth Inorganic materials 0.000 claims 1
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims 1
229910052793 cadmium Inorganic materials 0.000 claims 1
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims 1
229940096405 magnesium cation Drugs 0.000 claims 1
230000007704 transition Effects 0.000 description 24
239000000945 filler Substances 0.000 description 19
QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(ii) oxide Chemical compound [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 description 16
229910019142 PO4 Inorganic materials 0.000 description 11
239000013078 crystal Substances 0.000 description 11
230000000694 effects Effects 0.000 description 11
239000011777 magnesium Substances 0.000 description 11
235000021317 phosphate Nutrition 0.000 description 11
238000005259 measurement Methods 0.000 description 10
239000010955 niobium Substances 0.000 description 10
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
239000005385 borate glass Substances 0.000 description 8
229910001429 cobalt ion Inorganic materials 0.000 description 8
XLJKHNWPARRRJB-UHFFFAOYSA-N cobalt(2+) Chemical group [Co+2] XLJKHNWPARRRJB-UHFFFAOYSA-N 0.000 description 8
229910052718 tin Inorganic materials 0.000 description 8
239000010452 phosphate Substances 0.000 description 7
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 7
238000012360 testing method Methods 0.000 description 7
230000008859 change Effects 0.000 description 6
-1 iron-nickel-aluminum Chemical compound 0.000 description 6
239000000843 powder Substances 0.000 description 6
239000005361 soda-lime glass Substances 0.000 description 6
150000002500 ions Chemical class 0.000 description 5
JQJCSZOEVBFDKO-UHFFFAOYSA-N lead zinc Chemical compound [Zn].[Pb] JQJCSZOEVBFDKO-UHFFFAOYSA-N 0.000 description 5
ZPPSOOVFTBGHBI-UHFFFAOYSA-N lead(2+);oxido(oxo)borane Chemical compound [Pb+2].[O-]B=O.[O-]B=O ZPPSOOVFTBGHBI-UHFFFAOYSA-N 0.000 description 5
229910001425 magnesium ion Inorganic materials 0.000 description 5
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
239000011575 calcium Substances 0.000 description 4
239000000919 ceramic Substances 0.000 description 4
238000002425 crystallisation Methods 0.000 description 4
230000008025 crystallization Effects 0.000 description 4
GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 4
150000003013 phosphoric acid derivatives Chemical class 0.000 description 4
229910000838 Al alloy Inorganic materials 0.000 description 3
229910001030 Iron–nickel alloy Inorganic materials 0.000 description 3
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
229910045601 alloy Inorganic materials 0.000 description 3
239000000956 alloy Substances 0.000 description 3
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
239000006121 base glass Substances 0.000 description 3
239000005388 borosilicate glass Substances 0.000 description 3
238000000576 coating method Methods 0.000 description 3
238000001816 cooling Methods 0.000 description 3
239000006066 glass batch Substances 0.000 description 3
230000009477 glass transition Effects 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
239000011574 phosphorus Substances 0.000 description 3
239000000377 silicon dioxide Substances 0.000 description 3
238000006467 substitution reaction Methods 0.000 description 3
229910000500 β-quartz Inorganic materials 0.000 description 3
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 2
239000000853 adhesive Substances 0.000 description 2
230000001070 adhesive effect Effects 0.000 description 2
229910052784 alkaline earth metal Inorganic materials 0.000 description 2
238000000137 annealing Methods 0.000 description 2
238000013459 approach Methods 0.000 description 2
229910052788 barium Inorganic materials 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
238000004031 devitrification Methods 0.000 description 2
NKZSPGSOXYXWQA-UHFFFAOYSA-N dioxido(oxo)titanium;lead(2+) Chemical compound [Pb+2].[O-][Ti]([O-])=O NKZSPGSOXYXWQA-UHFFFAOYSA-N 0.000 description 2
229910000174 eucryptite Inorganic materials 0.000 description 2
239000000156 glass melt Substances 0.000 description 2
229910021397 glassy carbon Inorganic materials 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000000155 melt Substances 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
239000002245 particle Substances 0.000 description 2
238000000646 scanning calorimetry Methods 0.000 description 2
239000005368 silicate glass Substances 0.000 description 2
239000007787 solid Substances 0.000 description 2
229910052845 zircon Inorganic materials 0.000 description 2
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
229910000505 Al2TiO5 Inorganic materials 0.000 description 1
239000004254 Ammonium phosphate Substances 0.000 description 1
229910015902 Bi 2 O 3 Inorganic materials 0.000 description 1
229910001374 Invar Inorganic materials 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
229910008449 SnF 2 Inorganic materials 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
239000004110 Zinc silicate Substances 0.000 description 1
229910007541 Zn O Inorganic materials 0.000 description 1
230000001154 acute effect Effects 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
229910000147 aluminium phosphate Inorganic materials 0.000 description 1
INJRKJPEYSAMPD-UHFFFAOYSA-N aluminum;silicic acid;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O INJRKJPEYSAMPD-UHFFFAOYSA-N 0.000 description 1
229910000148 ammonium phosphate Inorganic materials 0.000 description 1
235000019289 ammonium phosphates Nutrition 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
230000008901 benefit Effects 0.000 description 1
CXKCTMHTOKXKQT-UHFFFAOYSA-N cadmium oxide Inorganic materials [Cd]=O CXKCTMHTOKXKQT-UHFFFAOYSA-N 0.000 description 1
238000001354 calcination Methods 0.000 description 1
239000001506 calcium phosphate Substances 0.000 description 1
229910000389 calcium phosphate Inorganic materials 0.000 description 1
235000011010 calcium phosphates Nutrition 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
239000010432 diamond Substances 0.000 description 1
229910003460 diamond Inorganic materials 0.000 description 1
238000007571 dilatometry Methods 0.000 description 1
238000006073 displacement reaction Methods 0.000 description 1
ZOIVSVWBENBHNT-UHFFFAOYSA-N dizinc;silicate Chemical compound [Zn+2].[Zn+2].[O-][Si]([O-])([O-])[O-] ZOIVSVWBENBHNT-UHFFFAOYSA-N 0.000 description 1
238000000921 elemental analysis Methods 0.000 description 1
238000004534 enameling Methods 0.000 description 1
238000007572 expansion measurement Methods 0.000 description 1
150000002222 fluorine compounds Chemical class 0.000 description 1
238000005187 foaming Methods 0.000 description 1
239000002241 glass-ceramic Substances 0.000 description 1
238000000227 grinding Methods 0.000 description 1
230000006872 improvement Effects 0.000 description 1
229910052850 kyanite Inorganic materials 0.000 description 1
239000010443 kyanite Substances 0.000 description 1
229910052745 lead Inorganic materials 0.000 description 1
239000005355 lead glass Substances 0.000 description 1
CDZXKKXSZAMHFU-UHFFFAOYSA-J lead(2+);phosphonato phosphate Chemical compound [Pb+2].[Pb+2].[O-]P([O-])(=O)OP([O-])([O-])=O CDZXKKXSZAMHFU-UHFFFAOYSA-J 0.000 description 1
238000011068 loading method Methods 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
230000007246 mechanism Effects 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
229910001092 metal group alloy Inorganic materials 0.000 description 1
238000003801 milling Methods 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000004570 mortar (masonry) Substances 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000011236 particulate material Substances 0.000 description 1
239000005365 phosphate glass Substances 0.000 description 1
230000000704 physical effect Effects 0.000 description 1
230000008569 process Effects 0.000 description 1
238000012545 processing Methods 0.000 description 1
230000000750 progressive effect Effects 0.000 description 1
AABBHSMFGKYLKE-SNAWJCMRSA-N propan-2-yl (e)-but-2-enoate Chemical compound C\C=C\C(=O)OC(C)C AABBHSMFGKYLKE-SNAWJCMRSA-N 0.000 description 1
239000010453 quartz Substances 0.000 description 1
230000009467 reduction Effects 0.000 description 1
238000011160 research Methods 0.000 description 1
150000004760 silicates Chemical class 0.000 description 1
HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 1
229910052566 spinel group Inorganic materials 0.000 description 1
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
238000009736 wetting Methods 0.000 description 1
235000019352 zinc silicate Nutrition 0.000 description 1
GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/24—Fusion seal compositions being frit compositions having non-frit additions, i.e. for use as seals between dissimilar materials, e.g. glass and metal; Glass solders
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/12—Silica-free oxide glass compositions
- C03C3/23—Silica-free oxide glass compositions containing halogen and at least one oxide, e.g. oxide of boron
- C03C3/247—Silica-free oxide glass compositions containing halogen and at least one oxide, e.g. oxide of boron containing fluorine and phosphorus
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/18—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing free metals

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Geochemistry & Mineralogy (AREA)
Materials Engineering (AREA)
Organic Chemistry (AREA)
Glass Compositions (AREA)
Sealing Material Composition (AREA)

JP25350491A 1990-10-09 1991-10-01 ガラスのミル添加物およびそれを含む融着シール材料 Expired - Lifetime JP3306809B2 (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US598001		1990-10-09
US07/598,001 US5089446A (en)	1990-10-09	1990-10-09	Sealing materials and glasses

Publications (2)

Publication Number	Publication Date
JPH04231349A JPH04231349A (ja)	1992-08-20
JP3306809B2 true JP3306809B2 (ja)	2002-07-24

Family

ID=24393842

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP25350491A Expired - Lifetime JP3306809B2 (ja)	1990-10-09	1991-10-01	ガラスのミル添加物およびそれを含む融着シール材料

Country Status (4)

Country	Link
US (1)	US5089446A (fr)
EP (1)	EP0480188A3 (fr)
JP (1)	JP3306809B2 (fr)
CA (1)	CA2050517C (fr)

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US5958100A (en) *	1993-06-03	1999-09-28	Micron Technology, Inc.	Process of making a glass semiconductor package
US5281560A (en) *	1993-06-21	1994-01-25	Corning Incorporated	Non-lead sealing glasses
CA2143692A1 (fr) *	1994-03-31	1995-10-01	Robert M. Morena	Adhesifs a fusion et leur utilisation dans les tubes cathodiques
US5514629A (en) *	1994-12-09	1996-05-07	Corning Incorporated	Fusion sealing materials and use in CRT
US5500917A (en) *	1994-04-18	1996-03-19	Gould Electronics Inc.	Optical assembly/housing for securing optical fiber components, devices and fibers to the same or to mounting fixtures
US5552092A (en) *	1994-05-31	1996-09-03	Corning Incorporated	Waveguide coupler
JPH08109038A (ja) *	1994-10-06	1996-04-30	Kirin Brewery Co Ltd	ガラス融体の製造法
US6127005A (en)	1999-01-08	2000-10-03	Rutgers University	Method of thermally glazing an article
US6432752B1 (en) *	2000-08-17	2002-08-13	Micron Technology, Inc.	Stereolithographic methods for fabricating hermetic semiconductor device packages and semiconductor devices including stereolithographically fabricated hermetic packages
US6998776B2 (en) *	2003-04-16	2006-02-14	Corning Incorporated	Glass package that is hermetically sealed with a frit and method of fabrication
US20080206589A1 (en) *	2007-02-28	2008-08-28	Bruce Gardiner Aitken	Low tempertature sintering using Sn2+ containing inorganic materials to hermetically seal a device
US20070040501A1 (en)	2005-08-18	2007-02-22	Aitken Bruce G	Method for inhibiting oxygen and moisture degradation of a device and the resulting device
US7722929B2 (en) *	2005-08-18	2010-05-25	Corning Incorporated	Sealing technique for decreasing the time it takes to hermetically seal a device and the resulting hermetically sealed device
US7829147B2 (en) *	2005-08-18	2010-11-09	Corning Incorporated	Hermetically sealing a device without a heat treating step and the resulting hermetically sealed device
US20080048178A1 (en) *	2006-08-24	2008-02-28	Bruce Gardiner Aitken	Tin phosphate barrier film, method, and apparatus
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US7615506B2 (en) *	2006-10-06	2009-11-10	Corning Incorporated	Durable tungsten-doped tin-fluorophosphate glasses
US8115326B2 (en) *	2006-11-30	2012-02-14	Corning Incorporated	Flexible substrates having a thin-film barrier
US8129622B2 (en)	2006-11-30	2012-03-06	Medtronic, Inc.	Insulator for feedthrough
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US8331077B2 (en)	2009-01-12	2012-12-11	Medtronic, Inc.	Capacitor for filtered feedthrough with annular member
US20100177458A1 (en) *	2009-01-12	2010-07-15	Medtronic, Inc.	Capacitor for filtered feedthrough with conductive pad
US8373965B2 (en)	2009-02-10	2013-02-12	Medtronic, Inc.	Filtered feedthrough assembly and associated method
US8084380B2 (en) *	2009-02-27	2011-12-27	Corning Incorporated	Transition metal doped Sn phosphate glass
US9009935B2 (en) *	2009-05-06	2015-04-21	Medtronic, Inc.	Methods to prevent high voltage arcing under capacitors used in filtered feedthroughs
US20110032658A1 (en) *	2009-08-07	2011-02-10	Medtronic, Inc.	Capacitor assembly and associated method
US8563113B2 (en)	2010-04-20	2013-10-22	Corning Incorporated	Multi-laminate hermetic barriers and related structures and methods of hermetic sealing
US10158057B2 (en)	2010-10-28	2018-12-18	Corning Incorporated	LED lighting devices
US9458052B2 (en)	2011-02-22	2016-10-04	Guardian Industries Corp.	Coefficient of thermal expansion filler for vanadium-based frit materials and/or methods of making and/or using the same
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EP0480188A2 (fr)	1992-04-15
CA2050517C (fr)	2002-06-25
US5089446A (en)	1992-02-18
CA2050517A1 (fr)	1992-04-10
EP0480188A3 (en)	1993-03-10

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