JP4664497B2 - 巨大細孔を有する触媒を用いてベンゼンポリカルボン酸またはその誘導体を水素化する方法 - Google Patents

巨大細孔を有する触媒を用いてベンゼンポリカルボン酸またはその誘導体を水素化する方法 Download PDF

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Publication number
JP4664497B2
JP4664497B2 JP2000525365A JP2000525365A JP4664497B2 JP 4664497 B2 JP4664497 B2 JP 4664497B2 JP 2000525365 A JP2000525365 A JP 2000525365A JP 2000525365 A JP2000525365 A JP 2000525365A JP 4664497 B2 JP4664497 B2 JP 4664497B2
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Prior art keywords
catalyst
support
phthalate
hydrogenation
pyromellitate
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Expired - Fee Related
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JP2000525365A
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Japanese (ja)
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JP2001526252A5 (ja
JP2001526252A (ja
Inventor
ブルンナー メラニー
ベトヒャー アルント
ブライトシャイデル ボリス
ハルプリッター クラウス
ヘンケルマン ヨッヘム
ティル リュシアン
ピンコス ロルフ
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BASF SE
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BASF SE
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Priority claimed from DE19756913A external-priority patent/DE19756913A1/de
Priority claimed from DE1998132088 external-priority patent/DE19832088A1/de
Application filed by BASF SE filed Critical BASF SE
Publication of JP2001526252A publication Critical patent/JP2001526252A/ja
Publication of JP2001526252A5 publication Critical patent/JP2001526252A5/ja
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/303—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by hydrogenation of unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C69/75—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring of acids with a six-membered ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
JP2000525365A 1997-12-19 1998-12-18 巨大細孔を有する触媒を用いてベンゼンポリカルボン酸またはその誘導体を水素化する方法 Expired - Fee Related JP4664497B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
DE19756913.7 1997-12-19
DE19756913A DE19756913A1 (de) 1997-12-19 1997-12-19 Verfahren zur Hydrierung von Benzendicarbonsäureestern unter Verwendung eines Makroporen aufweisenden Katalysators
DE1998132088 DE19832088A1 (de) 1998-07-16 1998-07-16 Verfahren zur Hydrierung von Benzolpolycarbonsäuren oder Derivaten davon unter Verwendung eines Makroporen aufweisenden Katalysators
DE19832088.4 1998-07-16
PCT/EP1998/008346 WO1999032427A1 (de) 1997-12-19 1998-12-18 Verfahren zur hydrierung von benzolpolycarbonsäuren oder derivaten davon unter verwendung eines makroporen aufweisenden katalysators

Publications (3)

Publication Number Publication Date
JP2001526252A JP2001526252A (ja) 2001-12-18
JP2001526252A5 JP2001526252A5 (ja) 2008-03-06
JP4664497B2 true JP4664497B2 (ja) 2011-04-06

Family

ID=26042688

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000525365A Expired - Fee Related JP4664497B2 (ja) 1997-12-19 1998-12-18 巨大細孔を有する触媒を用いてベンゼンポリカルボン酸またはその誘導体を水素化する方法

Country Status (16)

Country Link
US (2) US6284917B1 (2)
EP (2) EP1042273B1 (2)
JP (1) JP4664497B2 (2)
KR (1) KR100688403B1 (2)
CN (1) CN100406428C (2)
AU (1) AU759882B2 (2)
BR (1) BR9813786B1 (2)
CA (1) CA2315223C (2)
DE (2) DE59808306D1 (2)
ES (2) ES2386347T3 (2)
ID (1) ID30388A (2)
IN (1) IN2000CH00123A (2)
MX (1) MX218972B (2)
MY (1) MY129474A (2)
TW (1) TWI243188B (2)
WO (1) WO1999032427A1 (2)

Families Citing this family (180)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR9813786B1 (pt) * 1997-12-19 2013-11-12 Processo para hidrogenar di(isononil)ftalato ou di(isodecil)ftalato ou uma mistura de dois ou mais destes
DE19927977A1 (de) * 1999-06-18 2000-12-21 Basf Ag Verwendung von Cyclohexanpolycarbonsäuren als Weichmacher zur Herstellung toxikologisch günstig zu bewertender Kunststoffe
DE19927978A1 (de) * 1999-06-18 2000-12-21 Basf Ag Ausgewählte Cyclohexan-1,3- und 1,4-dicarbonsäureester
PL358278A1 (en) * 2000-03-13 2004-08-09 Basf Aktiengesellschaft Agrotechnical formulation
CN101024704B (zh) * 2001-02-16 2010-08-18 巴斯福股份公司 烷基取代环己烷二羧酸及其衍生物的用途
DE10128242A1 (de) 2001-06-11 2002-12-12 Basf Ag Verfahren zur Hydrierung organischer Verbindungen
DE10146869A1 (de) * 2001-09-24 2003-04-24 Oxeno Olefinchemie Gmbh Alicyclische Polycarbonsäureestergemische mit hohem trans-Anteil und Verfahren zu deren Herstellung
US8653184B2 (en) 2001-09-25 2014-02-18 Exxonmobil Chemical Patents Inc. Plasticised polyvinyl chloride and processes for making the same
EP1432758B1 (en) 2001-09-25 2008-11-26 ExxonMobil Chemical Patents Inc. Plasticised polyvinyl chloride
DE10147776A1 (de) * 2001-09-27 2003-07-03 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von alicyclischen Polycarbonsäureestern aus Partialestern aromatischer Polycarbonsäuren
DE10203386A1 (de) * 2002-01-29 2003-07-31 Basf Ag Einteilige Verschlussvorrichtung aus PVC
DE10225565A1 (de) 2002-06-10 2003-12-18 Oxeno Olefinchemie Gmbh Katalysator und Verfahren zur Hydrierung von aromatischen Verbindungen
DE10232868A1 (de) * 2002-07-19 2004-02-05 Oxeno Olefinchemie Gmbh Feinporiger Katalysator und Verfahren zur Hydrierung von aromatischen Verbindungen
DE10253802A1 (de) * 2002-11-18 2004-06-03 Degussa Ag Verfahren zur Hydrierung von aromatischen Urethanen in Gegenwart eines geträgerten Rutheniumkatalysators
GB0227086D0 (en) 2002-11-20 2002-12-24 Exxonmobil Res & Eng Co Hydrogenation processes
GB0227087D0 (en) * 2002-11-20 2002-12-24 Exxonmobil Chem Patents Inc Hydrogenation of benzene polycarboxylic acids or derivatives thereof
US7591887B2 (en) 2003-03-14 2009-09-22 Basf Se Printing inks comprising cyclohexane polycarboxylic acid derivatives
DE10317870A1 (de) * 2003-04-17 2004-11-04 Crompton Vinyl Additives Gmbh Neues Stabilisatorsystem zur Stabilisierung von halogenhaltigen Polymeren
EP1475071B1 (de) * 2003-05-09 2008-02-27 Basf Aktiengesellschaft Kosmetische Zusammensetzungen enthaltend Cyclohexanpolycarbonsäurederivate
US7547805B2 (en) * 2004-02-17 2009-06-16 Exxonmobil Research And Engineering Company Catalytic preparation of severely sterically hindered amino-ether alcohols using a metal loaded catalyst
JP4682157B2 (ja) * 2004-02-17 2011-05-11 エクソンモービル リサーチ アンド エンジニアリング カンパニー 高活性粉末触媒を用いる高度立体障害アミノ−エーテルアルコールおよびジアミノポリアルケニルエーテルの改良合成
DE102004029732A1 (de) * 2004-06-21 2006-01-19 Basf Ag Hilfsmittel enthaltend Cyclohexanpolycarbonsäurederivate
US7252865B2 (en) 2004-09-20 2007-08-07 Eastman Kodak Company Protective films containing compatible plasticizer compounds useful in polarizing plates for displays and their method of manufacture
DE102004063637A1 (de) * 2004-12-31 2006-07-13 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von alicyclischen Carbonsäuren oder deren Derivaten
DE102004063673A1 (de) * 2004-12-31 2006-07-13 Oxeno Olefinchemie Gmbh Verfahren zur kontinuierlichen katalytischen Hydrierung von hydrierbaren Verbindungen an festen, im Festbett angeordneten Katalysatoren mit einem wasserstoffhaltigen Gas
JP5530054B2 (ja) * 2005-01-19 2014-06-25 三井化学株式会社 オレフィン重合体製造用固体状チタン触媒成分、オレフィン重合用触媒およびオレフィン重合体の製造方法
US7888438B2 (en) * 2005-01-19 2011-02-15 Mitsui Chemicals, Inc. Catalyst for olefin polymerization and process for olefin polymerization
RU2279423C1 (ru) * 2005-03-23 2006-07-10 Ярославский государственный технический университет Способ получения транс-4-алкилзамещенных циклогексанкарбоновых кислот
DE102005028752A1 (de) 2005-06-22 2007-01-04 Oxeno Olefinchemie Gmbh Gemisch von Diisononylestern der 1,2-Cyclohexandicarbonsäure, Verfahren zu deren Herstellung und Verwendung dieser Gemische
US7632962B2 (en) * 2006-04-26 2009-12-15 Eastman Chemical Company Hydrogenation process and catalysts
EP2049254B1 (de) * 2006-07-31 2010-12-15 Basf Se Verfahren zur regenerierung von rutheniumkatalysatoren für die kernhydrierung von phthalaten
MY157680A (en) 2006-12-19 2016-07-15 Basf Se Use of cyclohexane polycarbonic acid esters for the production of coating materials for the coil coating method and the production of coated coils
US20080183004A1 (en) * 2007-01-30 2008-07-31 Nan Ya Plastics Corporation Method of preparing cyclohexanepolycarboxylic acid ester without phthalatic and plasticizer prepared by the same
CN101631761B (zh) * 2007-03-13 2012-12-19 埃克森美孚化学专利公司 批次酯化
CN101631763B (zh) * 2007-03-13 2013-01-02 埃克森美孚化学专利公司 酯生产中的改进
CN101878260B (zh) * 2007-11-30 2014-07-09 埃克森美孚化学专利公司 环己酸的c7-c12仲醇酯
CN101878259A (zh) * 2007-11-30 2010-11-03 埃克森美孚化学专利公司 基于环己烷羧酸c4-c7仲脂族醇酯的组合物
CN101990560A (zh) * 2007-12-21 2011-03-23 埃克森美孚化学专利公司 助增塑剂体系
CN101981106B (zh) * 2008-03-28 2012-12-12 埃克森美孚化学专利公司 多元醇酯增塑剂以及其制备方法
DE102008019275A1 (de) 2008-04-16 2009-10-22 Flint Group Germany Gmbh Migrationsarme Offsetdruckfarbe
DE102008024214A1 (de) 2008-05-19 2009-11-26 Flint Group Germany Gmbh Fotopolymerisierbare Flexodruckelemente für den Druck mit UV-Farben
US20090312470A1 (en) * 2008-06-11 2009-12-17 Ferro Corporation Asymmetric Cyclic Diester Compounds
US20100113664A1 (en) * 2008-06-11 2010-05-06 Ferro Corporation Asymmetric Cyclic Diester Compounds
US8163825B2 (en) * 2008-09-03 2012-04-24 Exxonmobil Chemical Patents Inc. Triglyceride plasticizers having low average levels of branching and process of making the same
CN102239198B (zh) * 2008-12-05 2015-01-21 巴斯夫欧洲公司 作为粘合剂和密封剂用增塑剂的环己烷多羧酸衍生物
ES2602116T3 (es) 2008-12-17 2017-02-17 Basf Se Procedimiento continuo de producción de ciclohexilmetanoles sustituidos
EP2358801A1 (en) 2008-12-18 2011-08-24 ExxonMobil Chemical Patents Inc. Polymer compositions comprising terephthalates
US8476350B2 (en) 2008-12-24 2013-07-02 Exxonmobil Research And Engineering Company Triglyceride plasticizer and process of making
US8299281B2 (en) 2009-03-27 2012-10-30 Exxonmobil Research And Engineering Company Process for making triglyceride plasticizer from crude glycerol
US8329795B2 (en) 2009-07-07 2012-12-11 Exxonmobil Research And Engineering Company Oil based polyols or diacids esterified with oxo-acids or oxo-alcohols for producing plasticizers
WO2011011137A1 (en) 2009-07-21 2011-01-27 Exxonmobil Chemical Patents Inc. Process for the preparation of keto acid esters useful as pvc plasticizers
WO2011051102A1 (en) 2009-10-26 2011-05-05 Exxonmobil Chemical Patents Inc. Improved phthalic anhydride process
ES2554858T3 (es) * 2009-11-03 2015-12-23 Styrolution Europe Gmbh Composiciones termoplásticas con fluidez mejorada
CN102656191B (zh) 2009-12-15 2014-03-19 埃克森美孚化学专利公司 低聚方法和反应器的温度控制
CN102753266B (zh) 2009-12-15 2015-09-02 巴斯夫欧洲公司 用于氢化芳族化合物的催化剂和方法
US8771815B2 (en) 2009-12-17 2014-07-08 Exxonmobil Research And Engineering Company Process for making triglyceride plasticizer
US8568846B2 (en) 2009-12-24 2013-10-29 Exxonmobil Research And Engineering Company Process for making polyol neoalkylester plasticizers from neo acids
US8604114B2 (en) 2009-12-24 2013-12-10 Exxonmobil Research And Engineering Company Aromatic acylation with cyclic anhydride for plasticizer production
US7973194B1 (en) 2010-03-18 2011-07-05 Eastman Chemical Company High solvating cyclohexane dicarboxylate diesters plasticizers
EP2722323B1 (de) 2010-03-24 2018-11-28 Basf Se Verfahren zur Herstellung von 2-Methyl-4-phenyl-2-pentanol
US8450534B2 (en) 2010-03-24 2013-05-28 Basf Se Process for preparing 4-cyclohexyl-2-methyl-2-butanol
US8815992B2 (en) 2010-04-14 2014-08-26 Exxonmobil Research And Engineering Company Tetracarboxylic ester plasticizers
PL2576674T3 (pl) 2010-06-01 2015-02-27 Basf Se Sposób wytwarzania spienialnych kompozycji polimerów styrenowych
US8791185B2 (en) 2010-06-21 2014-07-29 Basf Se 2-ethylhexyl methyl terephthalate as plasticizer in adhesives and sealants
EP2582765B1 (de) 2010-06-21 2014-10-15 Basf Se 2-ethylhexyl-methyl-terephthalat als weichmacher in kleb- und dichtstoffen
EP2619167B1 (en) 2010-09-20 2017-10-25 ExxonMobil Chemical Patents Inc. Process for liquid phase hydrogenation of phthalates
US9771466B2 (en) 2010-12-14 2017-09-26 Exxonmobil Chemical Patents Inc. Glycol ether-based cyclohexanoate ester plasticizers and blends therefrom
JP5859563B2 (ja) 2010-12-23 2016-02-10 スタイロリューション・ヨーロッパ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング 熱可塑性エラストマー組成物及びその製造方法
KR101264148B1 (ko) * 2011-01-18 2013-05-14 한화케미칼 주식회사 디에틸헥실사이클로헥산을 포함하는 벽지용 염화비닐계 수지 조성물
TWI414513B (zh) * 2011-03-01 2013-11-11 Nanya Plastics Corp 一種從苯多羧酸酯氫化成環己烷多羧酸酯的製造方法
KR101930087B1 (ko) * 2011-07-26 2018-12-18 에스케이이노베이션 주식회사 방향족 카르복시산 및/또는 방향족 카르복시산 알킬 에스테르 제조 공정에서 발생하는 부산물로부터 방향족 탄화수소 제조방법
WO2013025277A1 (en) 2011-08-15 2013-02-21 Exxonmobil Chemical Patents Inc. Esters and their preparation and use
EP2565225B1 (de) 2011-08-31 2014-04-16 Basf Se Beschichtete expandierbare Polymerpartikel
EP2565224A1 (de) 2011-08-31 2013-03-06 Basf Se Expandierbare temperaturbeständige Styrol-Copolymere
EP2565223A1 (de) 2011-08-31 2013-03-06 Basf Se Expandierbares Granulat
US9056812B2 (en) 2011-09-16 2015-06-16 Basf Se Process for preparing 4-cyclohexyl-2-methyl-2-butanol
CN106187685A (zh) 2011-09-16 2016-12-07 巴斯夫欧洲公司 制备4‑环己基‑2‑甲基‑2‑丁醇的方法
TWI421240B (zh) 2011-12-12 2014-01-01 Ind Tech Res Inst 苯多羧酸或其衍生物形成環己烷多元酸酯之氫化方法
DE102012001978A1 (de) 2012-02-02 2013-08-08 Voco Gmbh Dentale Kompositmaterialien enthaltend tricyclische Weichmacher
DE102012001979A1 (de) 2012-02-02 2013-08-08 Voco Gmbh Härtbares Gemisch umfassend Weichmacher mit einem polyalicyclischen Strukturelement zur Anwendung bei der Herstellung dentaler Werkstoffe
WO2013149956A2 (en) 2012-04-05 2013-10-10 Basf Se Thermoplastic polyurethanes composition and preparation processes thereof
ITMI20120634A1 (it) 2012-04-17 2013-10-18 Bio On S R L Composizione comprendente almeno un polimero biodegradabile e almeno un plastificante
FR2990210B1 (fr) 2012-05-03 2014-05-02 Roquette Freres Compositions plastifiantes comprenant des accelerateurs de gelification a base d'ester de 1,4 : 3,6-dianhydrohexitol de faible poids molaire
CN102675109A (zh) * 2012-05-24 2012-09-19 江苏康恒化工有限公司 一种增塑剂环己烷-1,2-二甲酸二异辛酯的制备方法
EP2692519A1 (de) 2012-08-02 2014-02-05 Basf Se Wärmeformbeständiger und stabilisierter Schaumstoff aus Styrolcopolymeren
DE102012217665A1 (de) 2012-09-27 2014-03-27 Basf Se Verfahren zur Herstellung von SAN-basierten expandierbaren Polymerpartikeln
DE102012217668A1 (de) 2012-09-27 2014-03-27 Basf Se Flammgeschütztes expandierbares Polymergranulat
ITMI20121641A1 (it) * 2012-10-02 2014-04-03 Polynt S P A Procedimento per l'idrogenazione di esteri di acidi carbossilici aromatici a dare loro omologhi saturi, nuovi usi per detti omologhi, e nuove miscele polimeriche plastificate.
US9090553B2 (en) 2012-10-05 2015-07-28 Basf Se Process for preparing cyclohexanepolycarboxylic acid derivatives having a low proportion of by-products
EP2716623A1 (de) 2012-10-05 2014-04-09 Basf Se Verfahren zur Herstellung von Cyclohexanpolycarbonsäure-Derivaten mit geringem Nebenproduktanteil
FR2998569B1 (fr) 2012-11-26 2015-01-09 Roquette Freres Procede de fabrication de compositions de diesters de 1,4 : 3,6-dianhydrohexitol
US9340754B2 (en) 2012-11-27 2016-05-17 Basf Se Process for the preparation of cyclohexyl-substituted tertiary alkanols
US9422227B2 (en) 2012-12-21 2016-08-23 Exxonmobil Research And Engineering Company Substituted naphthalenes as feedstock for plasticizer production
US8829093B2 (en) 2013-01-28 2014-09-09 Exxonmobil Chemical Patents Inc. Alkyl aromatic hydroalkylation for the production of plastisizers
US9534104B2 (en) 2013-01-28 2017-01-03 Exxonmobil Chemical Patents Inc. Plasticizer blends and use thereof
US9085669B2 (en) 2013-01-28 2015-07-21 Exxonmobil Chemical Patents Inc. Alkyl aromatic hydroalkylation for the production of plasticizers
CN105026345A (zh) 2013-03-14 2015-11-04 埃克森美孚化学专利公司 (甲基环己基)甲苯异构体混合物，它们的制备和它们在制造增塑剂中的用途
US9725377B2 (en) 2013-03-14 2017-08-08 Exxonmobil Chemical Patents Inc. Hydroalkylation catalyst and process for use thereof
RU2015143695A (ru) 2013-03-14 2017-04-18 Эксонмобил Кемикэл Пейтентс Инк. Метилзамещенные бифенильные соединения, их получение и их применение для получения пластификаторов
CN105050985A (zh) 2013-03-14 2015-11-11 埃克森美孚化学专利公司 甲基取代的联苯化合物，它们的制备和它们制造增塑剂的用途
WO2014159101A1 (en) 2013-03-14 2014-10-02 Exxonmobil Chemical Patents Inc. Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers
CN105026341A (zh) 2013-03-14 2015-11-04 埃克森美孚化学专利公司 甲基取代的联苯化合物，它们的制备和它们制造增塑剂的用途
JP6083270B2 (ja) * 2013-03-19 2017-02-22 三菱瓦斯化学株式会社 脂環式カルボン酸の製造方法
EP2810982A1 (en) 2013-06-06 2014-12-10 ExxonMobil Chemical Patents Inc. Dialkyl esters of 1,4' cyclohexane di-carboxylic acid and their use as plasticisers
US10130938B2 (en) 2013-10-18 2018-11-20 Exxonmobil Chemical Patents Inc. Hydrogenation catalyst, its method of preparation and use
WO2015057312A1 (en) 2013-10-18 2015-04-23 Exxonmobil Chemical Patents Inc. A hydrogenation catalyst, its method of preparation and use
EP3077453B1 (de) 2013-12-06 2018-03-28 Basf Se Weichmacher-zusammensetzung, die tetrahydrofuranderivate und 1,2-cyclohexandicarbonsäureester enthält
CN103739492A (zh) * 2013-12-31 2014-04-23 河南庆安化工高科技股份有限公司 一种制备环己烷邻二甲酸二高碳醇酯的方法
RU2016132589A (ru) 2014-01-09 2018-02-12 Басф Се Композиция пластификатора, которая содержит производные фурана и сложные эфиры 1,2-циклогександикарбоновой кислоты
MX394632B (es) * 2014-02-07 2025-03-24 Chemours Co Fc Llc Proceso integrado para la produccion de z-1,1,1,4,4,4-hexafluoro-2-buteno.
CN106164164A (zh) 2014-03-27 2016-11-23 新日本理化株式会社 含有非邻苯二甲酸系酯的氯乙烯类树脂用增塑剂和含有该增塑剂的氯乙烯类树脂组合物
DE102015206645A1 (de) 2014-04-16 2015-10-22 Basf Se Verwendung modifizierter Fettsäureester als Weichmacher
DE102015207291A1 (de) 2014-04-24 2016-03-10 Basf Se Weichmacher-Zusammensetzung, die Furanderivate und 1,2-Cyclohexandicarbonsäureester enthält
US9896393B2 (en) 2014-06-13 2018-02-20 Exxonmobil Chemical Patents Inc. Process for preparing dialkylbiphenyl isomer mixtures
US9556103B2 (en) 2014-06-13 2017-01-31 Exxonmobil Chemical Patents Inc. Biphenyl esters, their production and their use in the manufacture of plasticizers
TW201609628A (zh) 2014-07-08 2016-03-16 巴斯夫歐洲公司 包含脂族二羧酸二酯及對苯二甲酸二烷基酯之塑化劑組成物
TW201605945A (zh) 2014-07-08 2016-02-16 巴斯夫歐洲公司 包含二羧酸的酯及１，２－環己烷二羧酸的酯之模製化合物
FR3024735B1 (fr) 2014-08-07 2016-08-26 Roquette Freres Composition plastifiante liquide
US10454037B2 (en) 2014-08-18 2019-10-22 Basf Se Organic semiconductor composition comprising a liquid medium
TWI706979B (zh) 2014-08-19 2020-10-11 德商巴斯夫歐洲公司 包含聚合二羧酸酯的塑化劑組成物
TWI686444B (zh) 2014-09-04 2020-03-01 德商巴斯夫歐洲公司 包含聚合二羧酸酯的塑化劑組成物
TW201619120A (zh) 2014-10-09 2016-06-01 巴斯夫歐洲公司 包含飽和二羧酸之環烷基酯及對苯二甲酯之塑化劑組成物
TW201619119A (zh) * 2014-10-09 2016-06-01 巴斯夫歐洲公司 包含飽和二羧酸之環烷基酯及１，２－環己烷二羧酸酯的塑化劑組成物
US9758447B2 (en) 2014-10-24 2017-09-12 Exxonmobil Chemical Patents Inc. Activation of dehydrogenation catalysts
CN105582926B (zh) * 2014-10-24 2018-04-06 中国石油化工股份有限公司 对苯二甲酸加氢催化剂
US9856186B2 (en) 2014-12-19 2018-01-02 Exxonmobil Chemical Patents Inc. Production and use of dialkylbiphenyl isomer mixtures
EP3250635B1 (de) 2015-01-30 2018-10-24 Basf Se Weichmacher-zusammensetzung, die polymere dicarbonsäureester und terephthalsäuredialkylester enthält
US9896570B2 (en) 2015-03-25 2018-02-20 Exxonmobil Chemical Patents Inc. Indane and/or tetralin ester plasticizers, and blends therefrom
KR101905165B1 (ko) * 2015-04-01 2018-10-05 한화케미칼 주식회사 프탈레이트 화합물의 수소화 촉매의 재생 방법
EP3305772A4 (en) 2015-05-27 2018-12-05 New Japan Chemical Co., Ltd. Epoxycyclohexane dicarboxylic acid diester, plasticizer, stabilizer and resin composition
CN105037161B (zh) * 2015-07-08 2017-04-12 中山联成化学工业有限公司 一种连续式合成环己烷多元酸酯的方法
ES2648806T3 (es) 2015-09-28 2018-01-08 Evonik Degussa Gmbh Éster tripentílico del ácido trimelítico
CA2999998A1 (en) 2015-09-30 2017-04-06 Basf Se Plasticizer composition containing polymeric dicarboxylic acid esters and 1,2-cyclohexane dicarboxylic acid esters
PL3356456T3 (pl) 2015-09-30 2019-11-29 Basf Se Kompozycja plastyfikatora zawierająca polimerowe estry kwasu dikarboksylowego i estry dialkilowe kwasu tereftalowego
CA2999936A1 (en) 2015-09-30 2017-04-06 Basf Se Plasticizer composition containing polymeric dicarboxylic acid esters and dicarboxylic acid diesters
CN105315158B (zh) * 2015-11-05 2017-08-22 中海油天津化工研究设计院有限公司 一种制备环己烷二甲酸二元酯的联合工艺方法
US10550242B2 (en) 2016-01-20 2020-02-04 Basf Se Plasticiser composition containing aliphatic dicarboxylic acid esters and diesters selected from 1,2-cyclohexane dicarboxylic acid esters and terephthalic acid esters
EP3214067A1 (de) 2016-03-03 2017-09-06 Basf Se Verfahren zur aufreinigung von cyclohexanpolycarbonsäureestern
JP2019513788A (ja) 2016-04-13 2019-05-30 エクソンモービル ケミカル パテンツ インコーポレイテッド メチル置換ビフェニル化合物の製造
WO2018024591A1 (de) 2016-08-01 2018-02-08 Basf Se Weichmacher-zusammensetzung
WO2018024594A1 (de) 2016-08-01 2018-02-08 Basf Se Weichmacher-zusammensetzung
US11673125B2 (en) 2016-08-18 2023-06-13 The University Of Chicago Metal oxide-supported earth-abundant metal catalysts for highly efficient organic transformations
CN106431913A (zh) * 2016-08-28 2017-02-22 山东成泰化工有限公司 一种制备环己烷邻二甲酸二高碳醇酯的方法
KR20190050983A (ko) 2016-09-09 2019-05-14 엑손모빌 케미칼 패턴츠 인코포레이티드 프탈레이트 에스테르의 수소화 방법
KR101883993B1 (ko) 2016-09-29 2018-07-31 롯데케미칼 주식회사 1,3-사이클로헥산디카르복시산의 제조 방법
US10570084B2 (en) 2016-11-03 2020-02-25 Exxonmobil Research And Engineering Company General purpose plasticizers based on naphthalic acid diesters
EP3320963A1 (de) 2016-11-15 2018-05-16 Basf Se Verfahren zur abreicherung von aromatischem kohlenwasserstoff aus einen rohgasstrom
MX2019010776A (es) 2017-03-16 2020-02-07 Ineos Styrolution Group Gmbh Composicion de elastomero termoplastico estirenico no pegajoso, transparente y muy blando.
PL3424901T3 (pl) 2017-07-05 2021-01-11 Basf Se Uwodornianie związków aromatycznych
KR102324239B1 (ko) 2017-11-06 2021-11-08 한화솔루션 주식회사 방향족 화합물의 수소화 반응용 촉매 및 이의 제조방법
CN109776321B (zh) * 2017-11-13 2022-02-01 中国石油天然气股份有限公司 1，4-环己烷二甲酸二甲酯粗品的提纯方法和脱色方法
KR102275691B1 (ko) 2017-11-21 2021-07-09 한화솔루션 주식회사 사이클로도데카트라이엔의 선택적 수소화 촉매 및 이의 제조방법
WO2019185409A1 (de) 2018-03-29 2019-10-03 Basf Se Pvc-zusammensetzung, enthaltend wenigstens einen weichmacher der wenigstens eine carbonsäureestergruppe aufweist und wenigstens eine carbodiimidverbindung
CN110624537B (zh) * 2018-06-25 2022-08-23 中国石油化工股份有限公司 邻苯二甲酸酯加氢催化剂的制备方法
US11827767B2 (en) * 2018-07-12 2023-11-28 Lg Chem, Ltd. Plasticizer composition comprising cyclohexane polyester-based substance and resin composition comprising the same
DE102018007714A1 (de) 2018-09-29 2020-04-02 Friedrich-Schiller-Universität Jena Weichmacher enthaltende thermoplastische Vinylpolymerzusammensetzungen, deren Herstellung und Verwendung
CN111068724B (zh) * 2018-10-18 2023-05-02 中国石油化工股份有限公司 用于1,4-环己烷二甲酸生产的催化剂和其应用
ES2934584T3 (es) 2018-10-29 2023-02-23 Lg Chemical Ltd Composición de plastificante a base de triéster de ciclohexano y composición de resina que comprende el mismo
TWI704132B (zh) 2019-02-13 2020-09-11 台灣中油股份有限公司 苯多羧酸酯氫化反應形成脂環族多羧酸酯之氫化方法
TWI697479B (zh) 2019-02-15 2020-07-01 台灣中油股份有限公司 製造脂環族多羧酸酯之方法
US12428364B2 (en) 2019-02-25 2025-09-30 Basf Se Method for processing benzene polycarboxylic acid esters and use of same to produce cyclohexane polycarboxylic acid esters
WO2020222536A1 (ko) * 2019-05-02 2020-11-05 주식회사 엘지화학 사이클로헥산 트리에스터계 가소제 조성물 및 이를 포함하는 수지 조성물
EP3747860B1 (de) 2019-06-04 2023-07-26 Basf Se Neue weichmacher auf cyclohexanon-basis
KR20210059399A (ko) * 2019-11-15 2021-05-25 한화솔루션 주식회사 프탈레이트계 화합물의 수소화 방법
CN111036279B (zh) * 2019-12-12 2023-02-10 西安近代化学研究所 应用于邻苯二甲酸二异壬酯加氢合成环己烷-1,2-二甲酸二异壬酯的催化剂的制备方法
CN116018394B (zh) 2020-08-26 2025-01-24 联合利华知识产权控股有限公司 包含羟乙基磺酸盐表面活性剂的洗涤剂组合物
CN112321427A (zh) * 2020-10-28 2021-02-05 中国石油化工股份有限公司 一种邻苯二甲酸二辛酯加氢催化剂及其使用方法
EP4392520A1 (en) 2021-08-25 2024-07-03 Unilever IP Holdings B.V. Detergent composition
WO2023025739A1 (en) 2021-08-25 2023-03-02 Unilever Ip Holdings B.V. Detergent composition
WO2023025738A1 (en) 2021-08-25 2023-03-02 Unilever Ip Holdings B.V. Detergent composition
WO2024022962A1 (en) 2022-07-29 2024-02-01 Unilever Ip Holdings B.V. Laundry detergent composition
EP4638575A1 (en) 2022-12-21 2025-10-29 Basf Se Method for removal of plasticizer from a polymeric material
CN116199580A (zh) * 2023-01-18 2023-06-02 大连理工大学 一种碱金属离子促进的Ru基催化剂在邻苯二甲酸酯增塑剂加氢反应中的应用
WO2024153687A1 (de) 2023-01-19 2024-07-25 Basf Se Verfahren zur herstellung von 1,2-cyclohexandicarbonsäuredialkylestern
GB2630272B (en) 2023-05-15 2025-07-02 Johnson Matthey Plc Ruthenium eggshell catalyst
DE112024002592A5 (de) 2023-06-15 2026-04-09 Basf Se Weichmacher-Zusammensetzung
EP4549419A1 (en) 2023-10-31 2025-05-07 Basf Se Preparation of cycloaliphatic or heterocycloaliphatic compounds by hydrogenation of aromatic or heteroaromatic compounds using hydrogen with low deuterium content
EP4574810A1 (de) 2023-12-18 2025-06-25 Evonik Oxeno GmbH & Co. KG Statische mischer in der herstellung von alicyclischen carbonsäuren und deren estern
WO2025132915A2 (en) 2023-12-20 2025-06-26 Basf Se Method for removal of an additive from a polymeric material
EP4592273A1 (de) 2024-01-29 2025-07-30 Evonik Oxeno GmbH & Co. KG Verfahren zur herstellung von 1,2-cyclohexandicarbonsäuredialkylestern

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2070770A (en) * 1935-10-18 1937-02-16 Du Pont Hydrogenation of alkyl phthalates
US3027398A (en) 1960-02-01 1962-03-27 Du Pont Process for preparing dimethyl 1, 4-cyclohexanedicarboxylate
US3308086A (en) 1963-08-30 1967-03-07 Union Carbide Corp Ethylene copolymers with vinyl esters plasticized with phosphate and carboxylic esters
US3334149A (en) * 1964-07-21 1967-08-01 Eastman Kodak Co Plural stage hydrogenation of dialkyl terephthalate using palladium and then copper chromite
US3730931A (en) * 1970-11-10 1973-05-01 Gen Electric Silicone resins used as surfactants in vinyl chloride foam
JPS5547015B2 (2) * 1973-02-20 1980-11-27
FR2397131A7 (fr) 1977-05-26 1979-02-02 Kleber Colombes Pneumatique pour vehicule apte au service d'hiver
DE2823164A1 (de) * 1978-05-26 1979-11-29 Bayer Ag Verfahren zur herstellung von hexahydrophthalsaeureanhydrid
DE2823165A1 (de) * 1978-05-26 1979-11-29 Bayer Ag Verfahren zur herstellung von cycloaliphatischen carbonsaeureestern
JPS58198439A (ja) * 1982-05-12 1983-11-18 Toray Ind Inc １，４−シクロヘキサンジカルボン酸の製造法
US5028665A (en) * 1989-01-09 1991-07-02 The Dow Chemical Company Polymer hydrogenation catalysts
US5202475A (en) * 1990-09-27 1993-04-13 Eastman Kodak Company Process for preparation of cyclohexanedicarboxylic acid
JP3106411B2 (ja) * 1992-12-21 2000-11-06 東和化成工業株式会社 １，４−シクロヘキサンジカルボン酸の製造方法
JP3331673B2 (ja) * 1993-04-23 2002-10-07 新日本理化株式会社 環状ポリオレフィン系樹脂組成物
JP3268890B2 (ja) * 1993-05-17 2002-03-25 東和化成工業株式会社 １，３−シクロヘキサンジカルボン酸の製造方法
JPH06321823A (ja) * 1993-05-19 1994-11-22 Towa Kasei Kogyo Kk １，３−シクロヘキサンジメタノールの製造方法
US5319129A (en) 1993-06-15 1994-06-07 Eastman Kodak Company Preparation of dimethyl cyclohexanedicarboxylates
US5286898A (en) * 1993-06-15 1994-02-15 Eastman Kodak Company Low pressure process for the hydrogenation of dimethyl benzenedicarboxylates to the corresponding dimethyl cyclohexanedicarboxlates
JPH0711174A (ja) * 1993-06-23 1995-01-13 Hitachi Chem Co Ltd 防汚塗料用組成物
JP3456226B2 (ja) * 1993-06-24 2003-10-14 新日本理化株式会社 ポリオレフィン系樹脂組成物
JP3401888B2 (ja) * 1993-12-20 2003-04-28 新日本理化株式会社 ポリオレフィン系樹脂組成物
JP3834836B2 (ja) * 1995-05-31 2006-10-18 新日本理化株式会社 脂環式ポリカルボン酸エステルの製造方法
DE19533718A1 (de) * 1995-09-12 1997-03-13 Basf Ag Verfahren zur Hydrierung von aromatischen Verbindungen, in denen mindestens eine Aminogruppe an einen aromatischen Kern gebunden ist
JPH09249890A (ja) * 1996-01-12 1997-09-22 New Japan Chem Co Ltd 金属圧延用潤滑油
JP3826404B2 (ja) * 1995-12-12 2006-09-27 新日本理化株式会社 潤滑油
DE19604791A1 (de) 1996-02-09 1997-08-14 Basf Ag Verfahren zur Hydrierung von aromatischen Verbindungen, in denen mindestens eine Hydroxylgruppe an einen aromatischen Kern gebunden ist
US6248924B1 (en) 1996-06-19 2001-06-19 Basf Aktiengesellschaft Process for reacting an organic compound in the presence of a supported ruthenium catalyst
BR9813786B1 (pt) * 1997-12-19 2013-11-12 Processo para hidrogenar di(isononil)ftalato ou di(isodecil)ftalato ou uma mistura de dois ou mais destes

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