JPH0132065B2 - - Google Patents
Info
- Publication number
- JPH0132065B2 JPH0132065B2 JP9511080A JP9511080A JPH0132065B2 JP H0132065 B2 JPH0132065 B2 JP H0132065B2 JP 9511080 A JP9511080 A JP 9511080A JP 9511080 A JP9511080 A JP 9511080A JP H0132065 B2 JPH0132065 B2 JP H0132065B2
- Authority
- JP
- Japan
- Prior art keywords
- adhesive
- board
- gypsum board
- strength
- base paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000853 adhesive Substances 0.000 claims description 30
- 230000001070 adhesive effect Effects 0.000 claims description 30
- 229910052602 gypsum Inorganic materials 0.000 claims description 23
- 239000010440 gypsum Substances 0.000 claims description 23
- 239000012948 isocyanate Substances 0.000 claims description 11
- 150000002513 isocyanates Chemical class 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000011505 plaster Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 description 9
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- 239000002023 wood Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 4
- 239000002344 surface layer Substances 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- VXGWAWGQKJMAMN-UHFFFAOYSA-N (carbamoylamino) acetate Chemical compound CC(=O)ONC(N)=O VXGWAWGQKJMAMN-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 238000007718 adhesive strength test Methods 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
Description
本発明は石膏ボード原紙に含浸する樹脂を利用
して棧の接着強度を高めた棧貼着石膏ボードの製
造方法に関する。
石膏ボードを素材にした天井板などにおいて、
長さが90cm以上の長尺品は通常石膏ボードの長手
方向と幅方向にジエルトンやプライウツドなどの
反りの少い樹種よりなる棧を貼着している。上記
棧を貼着する理由は石膏ボードの撓み量を低減さ
せて施工性を向上すると共に、天井板を取り付け
る時に各種の釘を用いて天井板を天井根太や野縁
に固定するために用いるからである。このような
棧貼着石膏ボードの製造方法は一般に、棧組み立
て機で棧を組み立て、接着剤をロールコータで
180gr/m2〜250gr/m2程度塗布した後、この棧を
石膏ボードに貼り付け、プレスマシンを用いて2
〜3Kg/m2の圧力で加圧し、製造している。この
場合使用する接着剤は一般に酢酸ビニルエマルジ
ヨン、エチレン酢酸ビニルエマルジヨン、無水マ
レイン酸エマルジヨンやユリア酢酸エマルジヨン
などのエマルジヨンタイプの接着剤を用いてい
る。
ここで石膏ボードは、石膏を芯とし、該石膏板
の両面と長手方向の側面を石膏ボード用原紙で被
覆した成形板である。一般に石膏ボード用原紙は
数層の原紙からなり、石膏に接する内側の1〜3
層は、石膏の芯と原紙とが充分に接着するようポ
ーラスに抄造し、石膏の針状結晶が食い込み易い
ようになつている。これとは逆に棧が貼着される
表面側は、表面強度を高めるためにサイジングを
きかせて密に抄造している為、表面に比べて耐水
性があり、例えば1滴の水を吸水するのに約1時
間位い要する。その為に原紙の表面に塗布される
エマルジヨンタイプの接着剤はボード用原紙内に
浸透せず、前記棧はボード原紙の表面層に接着す
る状態になつている。従つて石膏ボードと棧との
接着強度試験を実施すると、殆んど全てのものが
ボード用原紙の紙間より剥離し、接着強度はボー
ド用原紙の紙間強度によつて左右されている。通
常紙間強度は1.3〜2.1Kg/cm2であり現状ではこれ
以上紙間強度を増強できないために棧の接着強度
を充分維持することができず、施工時に棧が剥離
するという問題がある。また、天井板の目地部の
間隙を通じて湿つた温かい空気が流れるため、冬
期においては前記棧やその付近のボード表面に結
露し、このため接着強度は気乾状態時の約50%近
くも著しく低下する。
以上のように従来の棧貼着石膏ボードの棧は石
膏ボード原紙の表面層にのみ接着されるため紙間
強度以上の接着強度を得ることができなかつたの
に対し、本発明は石膏ボードの原紙表面層から石
膏部分にまで含浸する樹脂を介して棧を接合する
ことにより、その接着強度を高めたものであり、
その構成は、未反応イソシアネートを含有するイ
ソシアネートプレポリマーを有機溶剤に溶解して
なる溶解液を石膏ボードの棧貼着部に塗付して含
浸させ、次いで直ちに含水性接着剤を塗付した棧
を該棧貼着部に貼り付け、該接着剤の水分により
前記プレポリマーを樹脂化させて貼着することを
特徴とする。
以上に本発明を実施例と共に詳細に説明する。
本発明における未反応イソシアネートを含有す
るイソシアネートプリポリマーとは、重合反応を
途中の段階で止めたイソシアネート重合体であ
り、粘度100〜200cps/25℃のものが好適である。
そして、該イソシアネートプレポリマーをメテル
エチルケトン、キシロール、トロールなどの溶剤
で希釈して粘度を20cps/25℃、好ましくは
5cps/25℃以下にし浸透性を良くした溶解液を用
いるとよい。該溶解液をロールコータで石膏ボー
ドに50〜100gr/m2塗布し、次いで直ちに含水性
接着剤を塗布した棧を接着させる。ここで含水性
接着剤とは前記プリポリマーの吸水する水分を含
む接着剤であり、例えば従来のエマルジヨンタイ
プの接着剤であればよい。上記溶解液を塗布した
棧貼着部に該接着剤を塗布した棧を貼り合せる
と、ボード原紙の表面から石膏層の1〜2mmまで
含浸したイソシアネートプレポリマーが接着剤の
水分と反応し、樹脂化する。前記棧は該樹脂に接
合される。ここで該棧は該樹脂を介して直接石膏
層に接合する状態となるのでその接合強度はボー
ド原紙の紙間強度に依存することがなく、極めて
大きい接合強度を達成することができる。又、ポ
リイソシアネート樹脂が防水膜の働きをするため
に、結露を生じた場合にも本発明の接着強度は、
従来のエマルジヨンタイプの接着剤だけを用いて
接着した気乾状態の接着強度よりも強く、勝れた
特徴を具えている。
次に本発明の実施例および比較例を示す。
実施例 1
本発明に係る棧貼石膏ボードを次の条件で製造
し、その接着強度を測定した。測定結果を第1表
に示す。
接着条件
イソシアネートプレポリマー(未反応イソシア
ネート30%含有、粘度150cps/25℃)100部にメ
チルエチルケトンを300部混合した。その時の粘
度は2cps/25℃であつた。これをせつこうボード
にロールコータで65gr/m2塗布し、比較例1と同
じ条件で木材を接着させた。
The present invention relates to a method for manufacturing a gypsum board with a laminate bonded to it, which uses a resin impregnated into a gypsum board base paper to increase the adhesive strength of the gypsum board. For ceiling panels made of gypsum board, etc.
For long products with a length of 90 cm or more, a piece of wood made of less warped wood such as zielton or plywood is usually attached to the length and width of the gypsum board. The reason for pasting the above-mentioned beams is to reduce the amount of deflection of the gypsum board and improve workability, and also because it is used to fix the ceiling board to the ceiling joists or verge using various nails when installing the ceiling board. It is. The manufacturing method for this type of plasterboard is generally assembling the boards using a board assembly machine and applying adhesive using a roll coater.
After applying approximately 180gr/m 2 to 250gr/m 2 , this sand is pasted on a plasterboard and pressed using a press machine.
It is manufactured under pressure of ~3Kg/ m2 . The adhesive used in this case is generally an emulsion type adhesive such as vinyl acetate emulsion, ethylene vinyl acetate emulsion, maleic anhydride emulsion, or urea acetate emulsion. Here, the gypsum board is a molded board having a core of gypsum and covered with base paper for gypsum board on both sides and longitudinal sides of the gypsum board. In general, base paper for plasterboard consists of several layers of base paper, with the inner layer 1 to 3 in contact with the plaster.
The layer is made porous so that the gypsum core and base paper adhere sufficiently, and the acicular crystals of the gypsum can easily penetrate into the layer. On the other hand, the surface side to which the sandpaper is attached is sized and densely made to increase surface strength, so it is more water resistant than the surface, for example, it absorbs one drop of water. It takes about 1 hour. For this reason, the emulsion type adhesive applied to the surface of the base paper does not penetrate into the base paper for board, and the slats are in a state of adhering to the surface layer of the base paper for board. Therefore, when conducting an adhesive strength test between gypsum board and gypsum board, almost all of the adhesive peels off from the space between the base paper for board, and the adhesive strength is determined by the strength between the base paper for board. Normally, the strength between the sheets is 1.3 to 2.1 Kg/cm 2 , and at present, the strength between the sheets cannot be increased any further, and therefore the adhesive strength of the shingles cannot be maintained sufficiently, leading to the problem that the shingles peel off during construction. In addition, since moist, warm air flows through the gaps in the joints of the ceiling boards, dew condenses on the board surface in the winter and on the surface of the boards in the vicinity, resulting in a significant drop in adhesive strength of approximately 50% compared to when it is air-dried. do. As described above, the laminate of the conventional gypsum board with gypsum board is adhered only to the surface layer of the gypsum board base paper, so it was not possible to obtain an adhesive strength higher than the interpaper strength. The adhesive strength is increased by bonding the wood through a resin that is impregnated from the surface layer of the base paper to the plaster part.
Its composition consists of applying a solution prepared by dissolving an isocyanate prepolymer containing unreacted isocyanate in an organic solvent to the plasterboard area to impregnate it, and then immediately applying a water-containing adhesive to the plasterboard. is attached to the adhesive part, and the prepolymer is turned into a resin by the water content of the adhesive and then attached. The present invention will be described in detail above along with examples. The isocyanate prepolymer containing unreacted isocyanate in the present invention is an isocyanate polymer whose polymerization reaction has been stopped at an intermediate stage, and preferably has a viscosity of 100 to 200 cps/25°C.
Then, the isocyanate prepolymer is diluted with a solvent such as methyl ethyl ketone, xylol, trol, etc. to a viscosity of 20 cps/25°C, preferably
It is recommended to use a dissolving solution with improved permeability at 5 cps/25°C or less. The solution is applied to a gypsum board at a rate of 50 to 100 gr/m 2 using a roll coater, and then immediately a laminate coated with a water-containing adhesive is adhered. Here, the water-containing adhesive is an adhesive that contains water absorbed by the prepolymer, and may be, for example, a conventional emulsion type adhesive. When a piece of wood coated with the adhesive is attached to a piece of sand coated with the above solution, the isocyanate prepolymer impregnated from the surface of the board base paper to 1 to 2 mm of the gypsum layer reacts with the moisture in the adhesive, causing the resin to become The beam is bonded to the resin. Here, since the beam is directly bonded to the gypsum layer via the resin, the bonding strength does not depend on the interpaper strength of the board base paper, and extremely high bonding strength can be achieved. In addition, since the polyisocyanate resin acts as a waterproof membrane, the adhesive strength of the present invention is
It has superior properties and is stronger than the air-dry adhesive bonded using only conventional emulsion type adhesives. Next, Examples and Comparative Examples of the present invention will be shown. Example 1 A plaster board according to the present invention was manufactured under the following conditions, and its adhesive strength was measured. The measurement results are shown in Table 1. Adhesion conditions: 300 parts of methyl ethyl ketone was mixed with 100 parts of isocyanate prepolymer (containing 30% unreacted isocyanate, viscosity 150 cps/25°C). The viscosity at that time was 2 cps/25°C. This was applied to plasterboard at 65 gr/m 2 using a roll coater, and wood was bonded under the same conditions as in Comparative Example 1.
【表】
比較例 1
通常の製造方法による木材付き石膏ボード天井
板を次の条件で製造し、その接着強度を測定し
た。測定結果を第2表に示す。
接着条件
(1)接着剤 酢酸ビニールエマルジヨン(固形
分49%)
(2)塗布量 220gr/m2
(3)加圧力 2.5〜3.0Kgf/cm2
(4)加圧時間 20分
(5)木材 ジエルトン[Table] Comparative Example 1 A wood-covered gypsum board ceiling board was manufactured by a normal manufacturing method under the following conditions, and its adhesive strength was measured. The measurement results are shown in Table 2. Adhesion conditions (1) Adhesive vinyl acetate emulsion (solid content 49%) (2) Application amount 220gr/m 2 (3) Pressure force 2.5-3.0Kgf/cm 2 (4) Pressure time 20 minutes (5) Wood Zielton
【表】
上記実施例1および比較例1から明らかなよう
に本発明に係る石膏ボード材の接着強度は従来の
棧接着強度に比べて気乾状態において2倍以上、
結露状態において3倍以上の強さを具えているこ
とが判る。[Table] As is clear from the above-mentioned Example 1 and Comparative Example 1, the adhesive strength of the gypsum board material according to the present invention is more than twice that of the conventional slat adhesive strength in an air-dried state.
It can be seen that it has more than three times the strength under dew condensation.
Claims (1)
ートプレポリマーを有機溶剤に溶解してなる溶解
液を石膏ボードの棧貼着部に塗布して含浸させ、
次いで直ちに含水性接着剤を塗布した棧を該棧貼
着部に貼り付け、該接着剤の水分により前記プレ
ポリマーを樹脂化させて貼着することを特徴とす
る棧貼着石膏ボードの製造方法。1. A solution obtained by dissolving an isocyanate prepolymer containing unreacted isocyanate in an organic solvent is applied to the plaster board area to impregnate it,
A method for manufacturing a gypsum board with a laminate bonded to it, characterized in that immediately afterward, laminate coated with a water-containing adhesive is affixed to the laminate attachment portion, and the prepolymer is converted into a resin by the water content of the adhesive and then adhered. .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9511080A JPS5722188A (en) | 1980-07-14 | 1980-07-14 | Manufacture of sash bar bonded gypsum board |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9511080A JPS5722188A (en) | 1980-07-14 | 1980-07-14 | Manufacture of sash bar bonded gypsum board |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5722188A JPS5722188A (en) | 1982-02-05 |
| JPH0132065B2 true JPH0132065B2 (en) | 1989-06-29 |
Family
ID=14128709
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9511080A Granted JPS5722188A (en) | 1980-07-14 | 1980-07-14 | Manufacture of sash bar bonded gypsum board |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5722188A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5404078A (en) * | 1991-08-20 | 1995-04-04 | Patent-Treuhand-Gesellschaft Fur Elektrische Gluhlampen Mbh | High-pressure discharge lamp and method of manufacture |
-
1980
- 1980-07-14 JP JP9511080A patent/JPS5722188A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5722188A (en) | 1982-02-05 |
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