JPH0134933B2 - - Google Patents

Info

Publication number: JPH0134933B2
Authority: JP; Japan
Prior art keywords: stage; rare earth; alkali; extraction; aqueous solution
Prior art date: 1981-11-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP56180729A

Other languages

English (en)

Japanese (ja)

Other versions

JPS5884118A (ja

Inventor

Tsugio Kaneko

Taiichiro Miwa

Tomokichi Nagaoka

Masaru Shimoyama

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mitsubishi Chemical Corp

Original Assignee

Mitsubishi Kasei Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-11-11

Filing date

1981-11-11

Publication date

1989-07-21

1981-11-11 Application filed by Mitsubishi Kasei Corp filed Critical Mitsubishi Kasei Corp

1981-11-11 Priority to JP56180729A priority Critical patent/JPS5884118A/ja

1983-05-20 Publication of JPS5884118A publication Critical patent/JPS5884118A/ja

1989-07-21 Publication of JPH0134933B2 publication Critical patent/JPH0134933B2/ja

Status Granted legal-status Critical Current

Links

238000000605 extraction Methods 0.000 claims description 65
229910052761 rare earth metal Inorganic materials 0.000 claims description 45
239000003513 alkali Substances 0.000 claims description 43
239000007864 aqueous solution Substances 0.000 claims description 43
150000002910 rare earth metals Chemical class 0.000 claims description 36
239000002994 raw material Substances 0.000 claims description 27
-1 phosphate ester Chemical class 0.000 claims description 18
239000002253 acid Substances 0.000 claims description 17
239000003795 chemical substances by application Substances 0.000 claims description 17
238000000926 separation method Methods 0.000 claims description 17
238000005201 scrubbing Methods 0.000 claims description 14
239000008346 aqueous phase Substances 0.000 claims description 13
238000000034 method Methods 0.000 claims description 12
239000004480 active ingredient Substances 0.000 claims description 8
238000010979 pH adjustment Methods 0.000 claims description 7
150000002148 esters Chemical class 0.000 claims description 6
229910019142 PO4 Inorganic materials 0.000 claims description 4
125000000217 alkyl group Chemical group 0.000 claims description 4
125000004432 carbon atom Chemical group C* 0.000 claims description 4
230000003068 static effect Effects 0.000 claims description 4
238000003756 stirring Methods 0.000 claims description 4
239000010452 phosphate Substances 0.000 claims description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 33
239000007788 liquid Substances 0.000 description 16
239000000243 solution Substances 0.000 description 12
229910052692 Dysprosium Inorganic materials 0.000 description 11
KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 description 11
229910052771 Terbium Inorganic materials 0.000 description 10
GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 description 10
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
229910052500 inorganic mineral Inorganic materials 0.000 description 6
239000011707 mineral Substances 0.000 description 6
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 5
239000000203 mixture Substances 0.000 description 5
229910017604 nitric acid Inorganic materials 0.000 description 5
229910052688 Gadolinium Inorganic materials 0.000 description 4
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
229910052772 Samarium Inorganic materials 0.000 description 4
239000000284 extract Substances 0.000 description 4
UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 4
KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
235000021317 phosphate Nutrition 0.000 description 3
229910052727 yttrium Inorganic materials 0.000 description 3
VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 3
ZDFBXXSHBTVQMB-UHFFFAOYSA-N 2-ethylhexoxy(2-ethylhexyl)phosphinic acid Chemical compound CCCCC(CC)COP(O)(=O)CC(CC)CCCC ZDFBXXSHBTVQMB-UHFFFAOYSA-N 0.000 description 2
NGDQQLAVJWUYSF-UHFFFAOYSA-N 4-methyl-2-phenyl-1,3-thiazole-5-sulfonyl chloride Chemical compound S1C(S(Cl)(=O)=O)=C(C)N=C1C1=CC=CC=C1 NGDQQLAVJWUYSF-UHFFFAOYSA-N 0.000 description 2
QXPQVUQBEBHHQP-UHFFFAOYSA-N 5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-amine Chemical compound C1CCCC2=C1SC1=C2C(N)=NC=N1 QXPQVUQBEBHHQP-UHFFFAOYSA-N 0.000 description 2
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
229910000147 aluminium phosphate Inorganic materials 0.000 description 2
235000011114 ammonium hydroxide Nutrition 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
230000000694 effects Effects 0.000 description 2
ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
238000000622 liquid--liquid extraction Methods 0.000 description 2
230000003472 neutralizing effect Effects 0.000 description 2
239000003960 organic solvent Substances 0.000 description 2
150000003014 phosphoric acid esters Chemical class 0.000 description 2
238000000638 solvent extraction Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
YJVUGDIORBKPLC-UHFFFAOYSA-N terbium(3+);trinitrate Chemical compound [Tb+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O YJVUGDIORBKPLC-UHFFFAOYSA-N 0.000 description 2
DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
229910052693 Europium Inorganic materials 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
239000011260 aqueous acid Substances 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
239000003518 caustics Substances 0.000 description 1
IKNAJTLCCWPIQD-UHFFFAOYSA-K cerium(3+);lanthanum(3+);neodymium(3+);oxygen(2-);phosphate Chemical compound [O-2].[La+3].[Ce+3].[Nd+3].[O-]P([O-])([O-])=O IKNAJTLCCWPIQD-UHFFFAOYSA-K 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
239000012527 feed solution Substances 0.000 description 1
MWFSXYMZCVAQCC-UHFFFAOYSA-N gadolinium(iii) nitrate Chemical compound [Gd+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O MWFSXYMZCVAQCC-UHFFFAOYSA-N 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
239000003350 kerosene Substances 0.000 description 1
229910052747 lanthanoid Inorganic materials 0.000 description 1
150000002602 lanthanoids Chemical class 0.000 description 1
239000000463 material Substances 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
229910052590 monazite Inorganic materials 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
UXBZSSBXGPYSIL-UHFFFAOYSA-N phosphoric acid;yttrium(3+) Chemical compound [Y+3].OP(O)(O)=O UXBZSSBXGPYSIL-UHFFFAOYSA-N 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
YZDZYSPAJSPJQJ-UHFFFAOYSA-N samarium(3+);trinitrate Chemical compound [Sm+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O YZDZYSPAJSPJQJ-UHFFFAOYSA-N 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000008096 xylene Substances 0.000 description 1
229910000164 yttrium(III) phosphate Inorganic materials 0.000 description 1

Landscapes

Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

JP56180729A 1981-11-11 1981-11-11 希土類の分離法 Granted JPS5884118A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP56180729A JPS5884118A (ja)	1981-11-11	1981-11-11	希土類の分離法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP56180729A JPS5884118A (ja)	1981-11-11	1981-11-11	希土類の分離法

Publications (2)

Publication Number	Publication Date
JPS5884118A JPS5884118A (ja)	1983-05-20
JPH0134933B2 true JPH0134933B2 (fr)	1989-07-21

Family

ID=16088277

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP56180729A Granted JPS5884118A (ja)	1981-11-11	1981-11-11	希土類の分離法

Country Status (1)

Country	Link
JP (1)	JPS5884118A (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2594429A1 (fr) *	1986-02-14	1987-08-21	Rhone Poulenc Chimie	Procede d'elimination du plomb de terres rares
US5258167A (en) *	1990-06-01	1993-11-02	Lion Corporation	Extractant for rare earth metal and method for extracting the same
MY164109A (en) *	2011-06-27	2017-11-30	Shinetsu Chemical Co	Method for extracting and separating light rare earth element

1981
- 1981-11-11 JP JP56180729A patent/JPS5884118A/ja active Granted

Also Published As

Publication number	Publication date
JPS5884118A (ja)	1983-05-20

Publication	Publication Date	Title
FI64792C (fi)	1984-01-10	Foerfarande foer behandling av blandningar av oxider av saellsynta jordmetaller och gallium
CN101787451B (zh)	2011-10-26	提高酸性磷型萃取剂萃取分离稀土元素效率的方法
CN106521190B (zh)	2018-06-26	含氨基中性膦萃取剂用于萃取分离锆和/或铪的用途和方法
NO164666B (no)	1990-07-23	Fremgangsmaate for separering av lantanider og yttrium vedvaeske -vaeske-ekstraksjon.
JP5499353B2 (ja)	2014-05-21	希土類元素の抽出・分離方法
US10513754B2 (en)	2019-12-24	Method for recovering thorium and rare earth elements from rare earth waste residues
US20230193419A1 (en)	2023-06-22	Lithium or magnesium extraction processes
Belova et al.	2015	Extraction of rare earth metals, uranium, and thorium from nitrate solutions by binary extractants
CN105734287A (zh)	2016-07-06	一种分离四价铈、钍和稀土的方法
US3575687A (en)	1971-04-20	Process for the selective separation of rare earth metals from their aqueous solutions
US6696589B2 (en)	2004-02-24	Combined supported liquid membrane/strip dispersion process for the removal and recovery of radionuclides
CN106115835A (zh)	2016-11-16	一种含草酸的工业废水的处理方法
CN111254296B (zh)	2020-12-22	一种具有苯乙烯基膦酸双酯结构的铀萃取剂及其应用
JPH0134933B2 (fr)	1989-07-21
CN101573163B (zh)	2013-01-30	用于铜萃取剂制剂的更有效的醚调节剂
AU2009216642B2 (en)	2013-01-17	Method for separating zinc, iron, calcium, copper and manganese from the aqueous solutions of cobalt and/or nickel
US5188735A (en)	1993-02-23	Separation of rare earth values by liquid/liquid extraction
CN1880489B (zh)	2010-05-12	一种高浓度稀土溶液非皂化萃取全分离工艺
US4369165A (en)	1983-01-18	Recovery of tungsten values from alkali tungstate solutions by solvent extraction
EP0514201A1 (fr)	1992-11-19	Procédé de séparation à l'aide d'acides organiques et nouveaux acides organiques
JPS6045261B2 (ja)	1985-10-08	希土類の分離法
KR940000109B1 (ko)	1994-01-05	이트륨(Yttrium)의 분리 방법
JPS632892B2 (fr)	1988-01-21
JPH0377859B2 (fr)	1991-12-11
JPH0568806A (ja)	1993-03-23	エマルジヨン法による金属イオンの抽出法