JPH0196186A - アリールシランの製造法 - Google Patents

アリールシランの製造法

Info

Publication number: JPH0196186A
Authority: JP; Japan
Prior art keywords: cobalt; rhodium; aromatic hydrocarbon; disilane; organic phosphorus
Prior art date: 1987-10-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP62253065A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0513956B2 (2

Inventor

Masato Tanaka

正人田中

Toshiyasu Sakakura

俊康坂倉

Yuko Tokunaga

祐子徳永

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

National Institute of Advanced Industrial Science and Technology AIST

Original Assignee

Agency of Industrial Science and Technology

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1987-10-07

Filing date

1987-10-07

Publication date

1989-04-14

1987-10-07 Application filed by Agency of Industrial Science and Technology filed Critical Agency of Industrial Science and Technology

1987-10-07 Priority to JP62253065A priority Critical patent/JPH0196186A/ja

1989-04-14 Publication of JPH0196186A publication Critical patent/JPH0196186A/ja

1993-02-23 Publication of JPH0513956B2 publication Critical patent/JPH0513956B2/ja

Status Granted legal-status Critical Current

Links

238000004519 manufacturing process Methods 0.000 title claims description 9
239000010948 rhodium Substances 0.000 claims abstract description 19
150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract description 14
229910052703 rhodium Inorganic materials 0.000 claims abstract description 14
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims abstract description 14
150000002903 organophosphorus compounds Chemical class 0.000 claims abstract description 13
PZPGRFITIJYNEJ-UHFFFAOYSA-N disilane Chemical compound [SiH3][SiH3] PZPGRFITIJYNEJ-UHFFFAOYSA-N 0.000 claims abstract description 11
229910017052 cobalt Inorganic materials 0.000 claims abstract description 10
239000010941 cobalt Substances 0.000 claims abstract description 10
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 10
XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims abstract description 8
XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical compound OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims abstract description 5
230000001678 irradiating effect Effects 0.000 claims abstract description 4
125000005538 phosphinite group Chemical group 0.000 claims abstract description 4
229910000073 phosphorus hydride Inorganic materials 0.000 claims abstract description 4
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims abstract description 3
229910052741 iridium Inorganic materials 0.000 claims description 4
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 4
150000002504 iridium compounds Chemical class 0.000 claims description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract description 12
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract description 9
CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 abstract description 6
239000002994 raw material Substances 0.000 abstract description 5
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 abstract description 4
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 abstract description 4
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract description 3
229910052753 mercury Inorganic materials 0.000 abstract description 3
239000000126 substance Substances 0.000 abstract description 3
229910052736 halogen Inorganic materials 0.000 abstract description 2
150000002367 halogens Chemical class 0.000 abstract description 2
239000000463 material Substances 0.000 abstract description 2
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 abstract description 2
229910052721 tungsten Inorganic materials 0.000 abstract description 2
239000010937 tungsten Substances 0.000 abstract description 2
150000004700 cobalt complex Chemical class 0.000 abstract 1
229910052738 indium Inorganic materials 0.000 abstract 1
APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 abstract 1
150000002472 indium compounds Chemical class 0.000 abstract 1
238000006243 chemical reaction Methods 0.000 description 9
238000000034 method Methods 0.000 description 6
-1 aromatic halide Chemical class 0.000 description 5
YWWDBCBWQNCYNR-UHFFFAOYSA-N trimethylphosphine Chemical compound CP(C)C YWWDBCBWQNCYNR-UHFFFAOYSA-N 0.000 description 4
NEXSMEBSBIABKL-UHFFFAOYSA-N hexamethyldisilane Chemical compound C[Si](C)(C)[Si](C)(C)C NEXSMEBSBIABKL-UHFFFAOYSA-N 0.000 description 3
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 3
KXFSUVJPEQYUGN-UHFFFAOYSA-N trimethyl(phenyl)silane Chemical compound C[Si](C)(C)C1=CC=CC=C1 KXFSUVJPEQYUGN-UHFFFAOYSA-N 0.000 description 3
KUCAPSLVHGFOHX-UHFFFAOYSA-N 1-methylphosphole Chemical compound CP1C=CC=C1 KUCAPSLVHGFOHX-UHFFFAOYSA-N 0.000 description 2
QIMMUPPBPVKWKM-UHFFFAOYSA-N 2-methylnaphthalene Chemical compound C1=CC=CC2=CC(C)=CC=C21 QIMMUPPBPVKWKM-UHFFFAOYSA-N 0.000 description 2
LTEQMZWBSYACLV-UHFFFAOYSA-N Hexylbenzene Chemical compound CCCCCCC1=CC=CC=C1 LTEQMZWBSYACLV-UHFFFAOYSA-N 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
238000004821 distillation Methods 0.000 description 2
150000002503 iridium Chemical class 0.000 description 2
IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 2
230000000269 nucleophilic effect Effects 0.000 description 2
150000003003 phosphines Chemical class 0.000 description 2
239000002904 solvent Substances 0.000 description 2
HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
239000008096 xylene Substances 0.000 description 2
QRRVMWPNMMLSGD-UHFFFAOYSA-N (2-dimethylphosphanylphenyl)-dimethylphosphane Chemical compound CP(C)C1=CC=CC=C1P(C)C QRRVMWPNMMLSGD-UHFFFAOYSA-N 0.000 description 1
KZPYGQFFRCFCPP-UHFFFAOYSA-N 1,1'-bis(diphenylphosphino)ferrocene Chemical compound [Fe+2].C1=CC=C[C-]1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=C[C-]1P(C=1C=CC=CC=1)C1=CC=CC=C1 KZPYGQFFRCFCPP-UHFFFAOYSA-N 0.000 description 1
OPNUROKCUBTKLF-UHFFFAOYSA-N 1,2-bis(2-methylphenyl)guanidine Chemical compound CC1=CC=CC=C1N\C(N)=N\C1=CC=CC=C1C OPNUROKCUBTKLF-UHFFFAOYSA-N 0.000 description 1
QFMZQPDHXULLKC-UHFFFAOYSA-N 1,2-bis(diphenylphosphino)ethane Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)CCP(C=1C=CC=CC=1)C1=CC=CC=C1 QFMZQPDHXULLKC-UHFFFAOYSA-N 0.000 description 1
GZDVNUHKYJNVNT-UHFFFAOYSA-N 3-dimethylphosphanylpropyl(dimethyl)phosphane Chemical compound CP(C)CCCP(C)C GZDVNUHKYJNVNT-UHFFFAOYSA-N 0.000 description 1
BCJVBDBJSMFBRW-UHFFFAOYSA-N 4-diphenylphosphanylbutyl(diphenyl)phosphane Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)CCCCP(C=1C=CC=CC=1)C1=CC=CC=C1 BCJVBDBJSMFBRW-UHFFFAOYSA-N 0.000 description 1
XLTRLRBXMJBVPL-UHFFFAOYSA-N 9,10-dibutylanthracene Chemical compound C1=CC=C2C(CCCC)=C(C=CC=C3)C3=C(CCCC)C2=C1 XLTRLRBXMJBVPL-UHFFFAOYSA-N 0.000 description 1
RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
239000007818 Grignard reagent Substances 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
CUJRVFIICFDLGR-UHFFFAOYSA-N acetylacetonate Chemical compound CC(=O)[CH-]C(C)=O CUJRVFIICFDLGR-UHFFFAOYSA-N 0.000 description 1
125000005595 acetylacetonate group Chemical group 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
239000001273 butane Substances 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
SFAZXBAPWCPIER-UHFFFAOYSA-N chloro-[chloro(dimethyl)silyl]-dimethylsilane Chemical compound C[Si](C)(Cl)[Si](C)(C)Cl SFAZXBAPWCPIER-UHFFFAOYSA-N 0.000 description 1
GJCAUTWJWBFMFU-UHFFFAOYSA-N chloro-dimethyl-trimethylsilylsilane Chemical compound C[Si](C)(C)[Si](C)(C)Cl GJCAUTWJWBFMFU-UHFFFAOYSA-N 0.000 description 1
238000004587 chromatography analysis Methods 0.000 description 1
150000001868 cobalt Chemical class 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000005859 coupling reaction Methods 0.000 description 1
125000004093 cyano group Chemical group *C#N 0.000 description 1
URYYVOIYTNXXBN-UPHRSURJSA-N cyclooctene Chemical compound C1CCC\C=C/CC1 URYYVOIYTNXXBN-UPHRSURJSA-N 0.000 description 1
239000004913 cyclooctene Substances 0.000 description 1
238000005695 dehalogenation reaction Methods 0.000 description 1
JTBAMRDUGCDKMS-UHFFFAOYSA-N dichloro-[dichloro(methyl)silyl]-methylsilane Chemical compound C[Si](Cl)(Cl)[Si](C)(Cl)Cl JTBAMRDUGCDKMS-UHFFFAOYSA-N 0.000 description 1
ZXMSTCRBSAVFDO-UHFFFAOYSA-N dimethoxy(methyl)phosphane Chemical compound COP(C)OC ZXMSTCRBSAVFDO-UHFFFAOYSA-N 0.000 description 1
LMZLQYYLELWCCW-UHFFFAOYSA-N dimethoxy(phenyl)phosphane Chemical compound COP(OC)C1=CC=CC=C1 LMZLQYYLELWCCW-UHFFFAOYSA-N 0.000 description 1
IVLANTKDSMBTNH-UHFFFAOYSA-N dimethyl-phenyl-trimethylsilylsilane Chemical compound C[Si](C)(C)[Si](C)(C)C1=CC=CC=C1 IVLANTKDSMBTNH-UHFFFAOYSA-N 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
238000004817 gas chromatography Methods 0.000 description 1
150000004795 grignard reagents Chemical class 0.000 description 1
125000005843 halogen group Chemical group 0.000 description 1
238000009815 homocoupling reaction Methods 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
239000000543 intermediate Substances 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
OAADXJFIBNEPLY-UHFFFAOYSA-N methoxy(diphenyl)phosphane Chemical compound C=1C=CC=CC=1P(OC)C1=CC=CC=C1 OAADXJFIBNEPLY-UHFFFAOYSA-N 0.000 description 1
CWGBHCIGKSXFED-UHFFFAOYSA-N methoxy-[methoxy(dimethyl)silyl]-dimethylsilane Chemical compound CO[Si](C)(C)[Si](C)(C)OC CWGBHCIGKSXFED-UHFFFAOYSA-N 0.000 description 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
239000000203 mixture Substances 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 1
229910052698 phosphorus Inorganic materials 0.000 description 1
239000011574 phosphorus Substances 0.000 description 1
239000005297 pyrex Substances 0.000 description 1
238000001953 recrystallisation Methods 0.000 description 1
150000003283 rhodium Chemical class 0.000 description 1
238000000926 separation method Methods 0.000 description 1
SBEQWOXEGHQIMW-UHFFFAOYSA-N silicon Chemical compound [Si].[Si] SBEQWOXEGHQIMW-UHFFFAOYSA-N 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000007787 solid Substances 0.000 description 1
125000000858 thiocyanato group Chemical group *SC#N 0.000 description 1
TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 description 1
BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 1
XEJUFRSVJVTIFW-UHFFFAOYSA-N triethyl(triethylsilyl)silane Chemical compound CC[Si](CC)(CC)[Si](CC)(CC)CC XEJUFRSVJVTIFW-UHFFFAOYSA-N 0.000 description 1
RXJKFRMDXUJTEX-UHFFFAOYSA-N triethylphosphine Chemical compound CCP(CC)CC RXJKFRMDXUJTEX-UHFFFAOYSA-N 0.000 description 1
CYTQBVOFDCPGCX-UHFFFAOYSA-N trimethyl phosphite Chemical compound COP(OC)OC CYTQBVOFDCPGCX-UHFFFAOYSA-N 0.000 description 1
RMZAYIKUYWXQPB-UHFFFAOYSA-N trioctylphosphane Chemical compound CCCCCCCCP(CCCCCCCC)CCCCCCCC RMZAYIKUYWXQPB-UHFFFAOYSA-N 0.000 description 1
RAVACSWYIIPFFV-UHFFFAOYSA-N tris[(4-methoxyphenyl)methyl]phosphane Chemical compound C1=CC(OC)=CC=C1CP(CC=1C=CC(OC)=CC=1)CC1=CC=C(OC)C=C1 RAVACSWYIIPFFV-UHFFFAOYSA-N 0.000 description 1
PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
229910052724 xenon Inorganic materials 0.000 description 1
FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

JP62253065A 1987-10-07 1987-10-07 アリールシランの製造法 Granted JPH0196186A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP62253065A JPH0196186A (ja)	1987-10-07	1987-10-07	アリールシランの製造法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP62253065A JPH0196186A (ja)	1987-10-07	1987-10-07	アリールシランの製造法

Publications (2)

Publication Number	Publication Date
JPH0196186A true JPH0196186A (ja)	1989-04-14
JPH0513956B2 JPH0513956B2 (2)	1993-02-23

Family

ID=17246002

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP62253065A Granted JPH0196186A (ja)	1987-10-07	1987-10-07	アリールシランの製造法

Country Status (1)

Country	Link
JP (1)	JPH0196186A (2)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2005075807A (ja) *	2003-09-03	2005-03-24	Dow Corning Toray Silicone Co Ltd	オルガノシラン類の製造方法

1987
- 1987-10-07 JP JP62253065A patent/JPH0196186A/ja active Granted

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2005075807A (ja) *	2003-09-03	2005-03-24	Dow Corning Toray Silicone Co Ltd	オルガノシラン類の製造方法

Also Published As

Publication number	Publication date
JPH0513956B2 (2)	1993-02-23

Legal Events

Date	Code	Title	Description
2007-10-07	EXPY	Cancellation because of completion of term

Publication	Publication Date	Title
Kyba et al.	1983	A facile synthesis of 1, 2-bis (phosphino) benzene and related alkylated species
Zhao et al.	2000	Palladium-catalyzed hydrophosphorylation of allenes leading to regio-and stereoselective formation of allylphosphonates
Marshall et al.	2003	Palladium (II) and Palladium (0) Complexes of BINAP (O)(2-(Diphenylphosphino)-2 ‘-(diphenylphosphinyl)-1, 1 ‘-binaphthyl)
Peruzzini et al.	2004	Functionalization of white phosphorus in the coordination sphere of transition metal complexes
Brunker et al.	2005	Chiral palladium (0) trans-stilbene complexes: Synthesis, structure, and oxidative addition of phenyl iodide
Koola et al.	1991	Activation of hydrocarbons by a ruthenium (II)(fluoroalkyl) phosphine hydride complex
Chizhevsky et al.	1999	Synthesis of Mixed-Metal (Ru− Rh) Bimetallacarboranes via exo-nido-and closo-Ruthenacarboranes. Molecular Structures of (η4-C8H12) Rh (μ-H) Ru (PPh3) 2 (η5-C2B9H11) and (CO)(PPh3) Rh (μ-H) Ru (PPh3) 2 (η5-C2B9H11) and Their Anionic closo-Ruthenacarborane Precursors
US5334791A (en)	1994-08-02	Hydrogenation process with transition metal catalysts derived from bifunctional phosphorus-nitrogen ligands
Bertani et al.	2002	Catalytic transformations of diazo compounds promoted by platinum (0) and dicationic platinum (II) complexes
Ye et al.	2006	Synthesis and structure of some ruthenium–rhenium heterodinuclear complexes and their catalytic activity in the addition of carboxylic acids to phenylacetylene
Madalska et al.	2014	Aryl-based ferrocenyl phosphine ligands in the rhodium (I)-catalyzed hydroformylation of olefins
JPH0196186A (ja)	1989-04-14	アリールシランの製造法
Ito et al.	1986	Selective activation of olefinic carbon-hydrogen bonds. Reaction of a hydridomolybdenum complex with methacrylic esters to form hydrido-alkenyl complexes
JPH0196187A (ja)	1989-04-14	アリールシランの製造方法
Fuerte et al.	1999	New chiral diphosphinites: synthesis of Rh complexes. Heterogenisation on zeolites
JPH0541612B2 (2)	1993-06-24
Bruce et al.	2000	Oligomerisation of alkynes at a pentamethylcyclopentadienylruthenium centre
JP4964760B2 (ja)	2012-07-04	ビスホスファイト、並びに該ビスホスファイトおよび第８〜１０族金属化合物を用いたアルデヒド化合物の製造方法
Adams et al.	2006	The importance of cluster fragmentation in the catalytic hydrogenation of phenylacetylene by PtRu5 carbonyl cluster complexes
Mohtachemi et al.	1986	Cleavage and rearrangement of phosphorus-carbon and phosphine-metal bonds in alkyltris (tertiary phosphine) cobalt compounds
Sravani et al.	2013	Facile synthesis of platinum based heterobimetallic carbonyl clusters from bis (1-alkenyl) Pt (II) precursors
JPH0196162A (ja)	1989-04-14	シツフ塩基類の製造法
Matsuzaka et al.	2001	Synthesis, structure and reactivities of the dinuclear μ-η1: η6-arylethynyl ruthenium complexes [Cp (PR3) 2Ru (μ-η1: η6-C CC6H4Me-p) RuCp]· Cl (R= Ph, Me; Cp= η5-C5H5, Cp= η5-C5Me5). The molecular structure of [Cp (PPh3) 2Ru (μ-η1: η6-C CC6H4Me-p) RuCp*]· PF6
Yamamoto et al.	2003	Facile C–N cleavage reactions of secondary and tertiary alkyl amines by P, O chelating rhodium and iridium complexes
Bosch et al.	2010	Synthesis and Reactivity of Rhodium Mono-and Bis (diolefin) Complexes. Characterization of Intermediates in the Rhodium-Catalyzed Cyclotetramerization of Butadiene

JPH0196186A - アリールシランの製造法 - Google Patents

Info

Links

Classifications

Landscapes

Priority Applications (1)

Applications Claiming Priority (1)

Publications (2)

Family

ID=17246002

Family Applications (1)

Country Status (1)

Cited By (1)

Cited By (1)

Also Published As

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