JPH02160230A - 写真用内部画像生成乳剤 - Google Patents

写真用内部画像生成乳剤

Info

Publication number: JPH02160230A
Authority: JP; Japan
Prior art keywords: silver; core; emulsion; octahedral; photographic
Prior art date: 1988-04-27
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP10479489A

Other languages

English (en)

Japanese (ja)

Inventor

Arnd Dr Kriebel

アルント・クリエべル

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Novartis AG

Original Assignee

Ciba Geigy AG

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-04-27

Filing date

1989-04-26

Publication date

1990-06-20

1989-04-26 Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG

1990-06-20 Publication of JPH02160230A publication Critical patent/JPH02160230A/ja

Status Pending legal-status Critical Current

Links

239000000839 emulsion Substances 0.000 title claims abstract description 107
229910052709 silver Inorganic materials 0.000 claims abstract description 48
239000004332 silver Substances 0.000 claims abstract description 48
238000000034 method Methods 0.000 claims abstract description 24
ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 claims abstract description 19
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims abstract description 13
JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 claims abstract description 12
229910021612 Silver iodide Inorganic materials 0.000 claims abstract description 12
229940045105 silver iodide Drugs 0.000 claims abstract description 12
238000000576 coating method Methods 0.000 claims abstract description 10
239000011248 coating agent Substances 0.000 claims abstract description 9
-1 silver halide Chemical class 0.000 claims description 36
239000013078 crystal Substances 0.000 claims description 33
239000000463 material Substances 0.000 claims description 24
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 19
229910052737 gold Inorganic materials 0.000 claims description 19
239000010931 gold Substances 0.000 claims description 19
238000003384 imaging method Methods 0.000 claims description 13
238000011161 development Methods 0.000 claims description 11
ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 claims description 11
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 10
238000004519 manufacturing process Methods 0.000 claims description 10
239000011593 sulfur Substances 0.000 claims description 10
229910052717 sulfur Inorganic materials 0.000 claims description 10
206010070834 Sensitisation Diseases 0.000 claims description 8
239000003795 chemical substances by application Substances 0.000 claims description 8
230000008313 sensitization Effects 0.000 claims description 8
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 7
238000004061 bleaching Methods 0.000 claims description 4
238000009792 diffusion process Methods 0.000 claims description 3
238000012546 transfer Methods 0.000 claims description 3
238000005406 washing Methods 0.000 claims description 3
238000001035 drying Methods 0.000 claims 2
230000035945 sensitivity Effects 0.000 abstract description 12
238000001556 precipitation Methods 0.000 abstract description 3
GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 abstract description 2
OIPQUBBCOVJSNS-UHFFFAOYSA-L bromo(iodo)silver Chemical compound Br[Ag]I OIPQUBBCOVJSNS-UHFFFAOYSA-L 0.000 abstract 2
239000010410 layer Substances 0.000 description 17
239000000243 solution Substances 0.000 description 16
IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 12
230000018109 developmental process Effects 0.000 description 10
150000001875 compounds Chemical class 0.000 description 7
NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Substances [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 6
239000003607 modifier Substances 0.000 description 5
239000000126 substance Substances 0.000 description 5
CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
108010010803 Gelatin Proteins 0.000 description 4
238000009826 distribution Methods 0.000 description 4
239000000975 dye Substances 0.000 description 4
229920000159 gelatin Polymers 0.000 description 4
239000008273 gelatin Substances 0.000 description 4
235000019322 gelatine Nutrition 0.000 description 4
235000011852 gelatine desserts Nutrition 0.000 description 4
239000002245 particle Substances 0.000 description 4
238000000151 deposition Methods 0.000 description 3
230000003595 spectral effect Effects 0.000 description 3
101710134784 Agnoprotein Proteins 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
206010034972 Photosensitivity reaction Diseases 0.000 description 2
239000003082 abrasive agent Substances 0.000 description 2
239000012790 adhesive layer Substances 0.000 description 2
235000010323 ascorbic acid Nutrition 0.000 description 2
229960005070 ascorbic acid Drugs 0.000 description 2
239000011668 ascorbic acid Substances 0.000 description 2
CJPQIRJHIZUAQP-MRXNPFEDSA-N benalaxyl-M Chemical compound CC=1C=CC=C(C)C=1N([C@H](C)C(=O)OC)C(=O)CC1=CC=CC=C1 CJPQIRJHIZUAQP-MRXNPFEDSA-N 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
239000002270 dispersing agent Substances 0.000 description 2
239000002612 dispersion medium Substances 0.000 description 2
238000005259 measurement Methods 0.000 description 2
239000000203 mixture Substances 0.000 description 2
238000005457 optimization Methods 0.000 description 2
230000036211 photosensitivity Effects 0.000 description 2
GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
238000004381 surface treatment Methods 0.000 description 2
150000005206 1,2-dihydroxybenzenes Chemical class 0.000 description 1
150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
229920002522 Wood fibre Polymers 0.000 description 1
SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 1
239000000853 adhesive Substances 0.000 description 1
230000001070 adhesive effect Effects 0.000 description 1
230000032683 aging Effects 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
239000012964 benzotriazole Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
239000004327 boric acid Substances 0.000 description 1
229910010293 ceramic material Inorganic materials 0.000 description 1
239000003153 chemical reaction reagent Substances 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
230000001427 coherent effect Effects 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
239000011258 core-shell material Substances 0.000 description 1
230000006378 damage Effects 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
238000010586 diagram Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000011888 foil Substances 0.000 description 1
239000011521 glass Substances 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
239000011630 iodine Substances 0.000 description 1
230000000873 masking effect Effects 0.000 description 1
238000000691 measurement method Methods 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
239000002667 nucleating agent Substances 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 1
150000004986 phenylenediamines Chemical class 0.000 description 1
229920000728 polyester Polymers 0.000 description 1
239000004848 polyfunctional curative Substances 0.000 description 1
BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
235000019252 potassium sulphite Nutrition 0.000 description 1
JVUYWILPYBCNNG-UHFFFAOYSA-N potassium;oxido(oxo)borane Chemical compound [K+].[O-]B=O JVUYWILPYBCNNG-UHFFFAOYSA-N 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000012545 processing Methods 0.000 description 1
NDGRWYRVNANFNB-UHFFFAOYSA-N pyrazolidin-3-one Chemical class O=C1CCNN1 NDGRWYRVNANFNB-UHFFFAOYSA-N 0.000 description 1
230000005070 ripening Effects 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
230000001235 sensitizing effect Effects 0.000 description 1
235000010265 sodium sulphite Nutrition 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000001228 spectrum Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
230000005469 synchrotron radiation Effects 0.000 description 1
150000003567 thiocyanates Chemical class 0.000 description 1
150000003568 thioethers Chemical class 0.000 description 1
150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
238000001429 visible spectrum Methods 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
239000002025 wood fiber Substances 0.000 description 1

Classifications

- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/035—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein characterised by the crystal form or composition, e.g. mixed grain
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/485—Direct positive emulsions
- G03C1/48538—Direct positive emulsions non-prefogged, i.e. fogged after imagewise exposure
- G03C1/48569—Direct positive emulsions non-prefogged, i.e. fogged after imagewise exposure characterised by the emulsion type/grain forms, e.g. tabular grain emulsions
- G03C1/48576—Direct positive emulsions non-prefogged, i.e. fogged after imagewise exposure characterised by the emulsion type/grain forms, e.g. tabular grain emulsions core-shell grain emulsions
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/035—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein characterised by the crystal form or composition, e.g. mixed grain
- G03C2001/03547—Cubooctahedral grains

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Physics & Mathematics (AREA)
General Physics & Mathematics (AREA)
Crystallography & Structural Chemistry (AREA)
Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Inorganic Compounds Of Heavy Metals (AREA)
Silver Salt Photography Or Processing Solution Therefor (AREA)

JP10479489A 1988-04-27 1989-04-26 写真用内部画像生成乳剤 Pending JPH02160230A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
CH1567/88-8		1988-04-27
CH156788		1988-04-27

Publications (1)

Publication Number	Publication Date
JPH02160230A true JPH02160230A (ja)	1990-06-20

Family

ID=4213444

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP10479489A Pending JPH02160230A (ja)	1988-04-27	1989-04-26	写真用内部画像生成乳剤

Country Status (2)

Country	Link
EP (1)	EP0340168A3 (fr)
JP (1)	JPH02160230A (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA2029579A1 (fr) *	1989-12-13	1991-06-14	Elizabeth P. Chang	Emulsions au bromo-iodure d'argent et elements et processus photographiques connexes
US5168035A (en) *	1990-12-27	1992-12-01	Eastman Kodak Company	Process for making a pressure fog-resistant photographic element

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH0614173B2 (ja) *	1984-01-12	1994-02-23	富士写真フイルム株式会社	ハロゲン化銀写真乳剤
DE3581367D1 (de) *	1984-11-02	1991-02-21	Ilford Ag	Verfahren zur herstellung photographischer direktpositivemulsionen.

1989
- 1989-04-18 EP EP19890810292 patent/EP0340168A3/fr not_active Withdrawn
- 1989-04-26 JP JP10479489A patent/JPH02160230A/ja active Pending

Also Published As

Publication number	Publication date
EP0340168A3 (fr)	1990-09-19
EP0340168A2 (fr)	1989-11-02

Publication	Publication Date	Title
US4704349A (en)	1987-11-03	Process for the preparation of photographic direct-positive emulsions
US3501309A (en)	1970-03-17	Direct positive silver halide emulsions containing halogenated cyanine dyes
JPS63138342A (ja)	1988-06-10	発光性色素によつて増感されたハロゲン化銀感光材料
US4863845A (en)	1989-09-05	Internal latent image type direct positive silver halide emulsions and process for producing the same
JPS5977436A (ja)	1984-05-02	写真要素
EP0112162A2 (fr)	1984-06-27	Matériel photographique photosensible aux halogénures d'argent
JPS6054662B2 (ja)	1985-11-30	ハロゲン化銀乳剤
US3942986A (en)	1976-03-09	Photographic element comprising a fogged, direct-positive heterodispersed silver halide emulsion and a fogged, direct-positive monodispersed silver halide
JPS61232444A (ja)	1986-10-16	ハロゲン化銀写真感光材料
JPS581414B2 (ja)	1983-01-11	チヨクセツポジハロゲンカギンニユウザイノセイゾウホウ
JPS62260139A (ja)	1987-11-12	写真直接陽画乳剤の製造方法
JPS6258237A (ja)	1987-03-13	ハロゲン化銀乳剤とその製造方法及び該ハロゲン化銀乳剤を用いたハロゲン化銀感光材料
JPH02160230A (ja)	1990-06-20	写真用内部画像生成乳剤
JPS63199347A (ja)	1988-08-17	鮮鋭性の向上した高感度ハロゲン化銀写真感光材料
SE451040B (sv)	1987-08-24	Direktpositivt fotografiskt element innefattande minst ett emulsionsskikt innehallande platta silvehalogenidkorn
JPS63194252A (ja)	1988-08-11	直接ポジハロゲン化銀写真感光材料
JP2613406B2 (ja)	1997-05-28	直接ポジハロゲン化銀写真感光材料
JPS60260039A (ja)	1985-12-23	黒白直接陽画写真要素
JP2727081B2 (ja)	1998-03-11	直接ポジハロゲン化銀写真感光材料
JPH0455295B2 (fr)	1992-09-02
JP796H (ja)	1994-11-24	ハロゲン化銀写真感光材料
JPS58127920A (ja)	1983-07-30	ハロゲン化銀乳剤
JPH0567009B2 (fr)	1993-09-24
JPH0227340A (ja)	1990-01-30	ハロゲン化銀写真感光材料の処理方法
JPS61232445A (ja)	1986-10-16	ハロゲン化銀写真乳剤の製造方法