JPH0242365B2 - - Google Patents
Info
- Publication number
- JPH0242365B2 JPH0242365B2 JP11011083A JP11011083A JPH0242365B2 JP H0242365 B2 JPH0242365 B2 JP H0242365B2 JP 11011083 A JP11011083 A JP 11011083A JP 11011083 A JP11011083 A JP 11011083A JP H0242365 B2 JPH0242365 B2 JP H0242365B2
- Authority
- JP
- Japan
- Prior art keywords
- component
- compound
- compounds
- solid
- polymerization method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 thioalcohols Chemical class 0.000 claims description 47
- 238000006243 chemical reaction Methods 0.000 claims description 37
- 238000000034 method Methods 0.000 claims description 36
- 150000002430 hydrocarbons Chemical group 0.000 claims description 34
- 238000006116 polymerization reaction Methods 0.000 claims description 33
- 125000002734 organomagnesium group Chemical group 0.000 claims description 31
- 150000001875 compounds Chemical class 0.000 claims description 28
- 239000007787 solid Substances 0.000 claims description 28
- 239000003054 catalyst Substances 0.000 claims description 25
- 150000001336 alkenes Chemical class 0.000 claims description 23
- 239000011777 magnesium Substances 0.000 claims description 23
- 239000011949 solid catalyst Substances 0.000 claims description 22
- 125000004432 carbon atom Chemical group C* 0.000 claims description 19
- 239000005046 Chlorosilane Substances 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 17
- 150000003609 titanium compounds Chemical class 0.000 claims description 16
- 229910052782 aluminium Inorganic materials 0.000 claims description 15
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 14
- 150000002902 organometallic compounds Chemical class 0.000 claims description 13
- 239000001257 hydrogen Substances 0.000 claims description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 239000010936 titanium Substances 0.000 claims description 10
- 150000003682 vanadium compounds Chemical class 0.000 claims description 10
- 150000001299 aldehydes Chemical class 0.000 claims description 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 8
- 150000002363 hafnium compounds Chemical class 0.000 claims description 8
- 150000003755 zirconium compounds Chemical class 0.000 claims description 8
- 150000004820 halides Chemical class 0.000 claims description 7
- 239000000376 reactant Substances 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 125000004429 atom Chemical group 0.000 claims description 6
- 229910052796 boron Inorganic materials 0.000 claims description 6
- 150000002170 ethers Chemical class 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 5
- 229910052790 beryllium Inorganic materials 0.000 claims description 5
- 150000001735 carboxylic acids Chemical class 0.000 claims description 5
- 229910052744 lithium Inorganic materials 0.000 claims description 5
- 150000002576 ketones Chemical class 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 125000005843 halogen group Chemical group 0.000 claims description 3
- 229910052806 inorganic carbonate Inorganic materials 0.000 claims description 3
- 229910001853 inorganic hydroxide Inorganic materials 0.000 claims description 3
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 claims description 3
- 239000008247 solid mixture Substances 0.000 claims description 3
- 239000006104 solid solution Substances 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 150000004760 silicates Chemical class 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- 150000003568 thioethers Chemical class 0.000 claims description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 61
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 22
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 20
- 239000005977 Ethylene Substances 0.000 description 20
- 125000000217 alkyl group Chemical group 0.000 description 18
- SLLGVCUQYRMELA-UHFFFAOYSA-N chlorosilicon Chemical compound Cl[Si] SLLGVCUQYRMELA-UHFFFAOYSA-N 0.000 description 16
- 229930195733 hydrocarbon Natural products 0.000 description 16
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 15
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 15
- 239000000243 solution Substances 0.000 description 14
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 13
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical compound Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 13
- 150000002901 organomagnesium compounds Chemical class 0.000 description 12
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- 239000004215 Carbon black (E152) Substances 0.000 description 11
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 125000001931 aliphatic group Chemical group 0.000 description 10
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 8
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 8
- 125000003118 aryl group Chemical group 0.000 description 8
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 7
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 7
- 239000002002 slurry Substances 0.000 description 7
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 6
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 6
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 6
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 6
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 6
- 230000000379 polymerizing effect Effects 0.000 description 6
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 6
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 5
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 5
- 235000019441 ethanol Nutrition 0.000 description 5
- 229910052736 halogen Inorganic materials 0.000 description 5
- 150000002367 halogens Chemical group 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- 239000012429 reaction media Substances 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- 239000011343 solid material Substances 0.000 description 5
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 5
- 239000005052 trichlorosilane Substances 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- KTQYJQFGNYHXMB-UHFFFAOYSA-N dichloro(methyl)silicon Chemical compound C[Si](Cl)Cl KTQYJQFGNYHXMB-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 230000000737 periodic effect Effects 0.000 description 4
- 239000006228 supernatant Substances 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- MSXVEPNJUHWQHW-UHFFFAOYSA-N 2-methylbutan-2-ol Chemical compound CCC(C)(C)O MSXVEPNJUHWQHW-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 3
- 125000002723 alicyclic group Chemical group 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 238000010908 decantation Methods 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000012299 nitrogen atmosphere Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- PMBXCGGQNSVESQ-UHFFFAOYSA-N 1-Hexanethiol Chemical compound CCCCCCS PMBXCGGQNSVESQ-UHFFFAOYSA-N 0.000 description 2
- ZRKMQKLGEQPLNS-UHFFFAOYSA-N 1-Pentanethiol Chemical compound CCCCCS ZRKMQKLGEQPLNS-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Chemical group CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- JKRZOJADNVOXPM-UHFFFAOYSA-N Oxalic acid dibutyl ester Chemical compound CCCCOC(=O)C(=O)OCCCC JKRZOJADNVOXPM-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 2
- HQMRIBYCTLBDAK-UHFFFAOYSA-M bis(2-methylpropyl)alumanylium;chloride Chemical compound CC(C)C[Al](Cl)CC(C)C HQMRIBYCTLBDAK-UHFFFAOYSA-M 0.000 description 2
- SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 description 2
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 2
- WQAQPCDUOCURKW-UHFFFAOYSA-N butanethiol Chemical compound CCCCS WQAQPCDUOCURKW-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 2
- 150000001733 carboxylic acid esters Chemical class 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- HJXBDPDUCXORKZ-UHFFFAOYSA-N diethylalumane Chemical compound CC[AlH]CC HJXBDPDUCXORKZ-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- ZMXPNWBFRPIZFV-UHFFFAOYSA-M dipropylalumanylium;chloride Chemical compound [Cl-].CCC[Al+]CCC ZMXPNWBFRPIZFV-UHFFFAOYSA-M 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 2
- SHZIWNPUGXLXDT-UHFFFAOYSA-N ethyl hexanoate Chemical compound CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- IUYHWZFSGMZEOG-UHFFFAOYSA-M magnesium;propane;chloride Chemical compound [Mg+2].[Cl-].C[CH-]C IUYHWZFSGMZEOG-UHFFFAOYSA-M 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
- 239000005048 methyldichlorosilane Substances 0.000 description 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- JYVLIDXNZAXMDK-UHFFFAOYSA-N pentan-2-ol Chemical compound CCCC(C)O JYVLIDXNZAXMDK-UHFFFAOYSA-N 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- SUVIGLJNEAMWEG-UHFFFAOYSA-N propane-1-thiol Chemical compound CCCS SUVIGLJNEAMWEG-UHFFFAOYSA-N 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 2
- 150000003623 transition metal compounds Chemical class 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 2
- YGRHYJIWZFEDBT-UHFFFAOYSA-N tridecylaluminum Chemical compound CCCCCCCCCCCCC[Al] YGRHYJIWZFEDBT-UHFFFAOYSA-N 0.000 description 2
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 2
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 2
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 2
- NLSXASIDNWDYMI-UHFFFAOYSA-N triphenylsilanol Chemical compound C=1C=CC=CC=1[Si](C=1C=CC=CC=1)(O)C1=CC=CC=C1 NLSXASIDNWDYMI-UHFFFAOYSA-N 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 2
- ZWVMLYRJXORSEP-LURJTMIESA-N (2s)-hexane-1,2,6-triol Chemical compound OCCCC[C@H](O)CO ZWVMLYRJXORSEP-LURJTMIESA-N 0.000 description 1
- MBNMGGKBGCIEGF-UHFFFAOYSA-N 1,1-diethoxypropane Chemical compound CCOC(CC)OCC MBNMGGKBGCIEGF-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 description 1
- MPPPKRYCTPRNTB-UHFFFAOYSA-N 1-bromobutane Chemical compound CCCCBr MPPPKRYCTPRNTB-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 description 1
- ZYVYEJXMYBUCMN-UHFFFAOYSA-N 1-methoxy-2-methylpropane Chemical compound COCC(C)C ZYVYEJXMYBUCMN-UHFFFAOYSA-N 0.000 description 1
- NOGFHTGYPKWWRX-UHFFFAOYSA-N 2,2,6,6-tetramethyloxan-4-one Chemical compound CC1(C)CC(=O)CC(C)(C)O1 NOGFHTGYPKWWRX-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- JDTUPLBMGDDPJS-UHFFFAOYSA-N 2-methoxy-2-phenylethanol Chemical compound COC(CO)C1=CC=CC=C1 JDTUPLBMGDDPJS-UHFFFAOYSA-N 0.000 description 1
- VSYZXASVWVQEMR-UHFFFAOYSA-N 2-methylbuta-1,3-dienylalumane Chemical compound CC(=C[AlH2])C=C VSYZXASVWVQEMR-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- HRAQMGWTPNOILP-UHFFFAOYSA-N 4-Ethoxy ethylbenzoate Chemical compound CCOC(=O)C1=CC=C(OCC)C=C1 HRAQMGWTPNOILP-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- ICMAFTSLXCXHRK-UHFFFAOYSA-N Ethyl pentanoate Chemical compound CCCCC(=O)OCC ICMAFTSLXCXHRK-UHFFFAOYSA-N 0.000 description 1
- 101000687448 Homo sapiens REST corepressor 1 Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical compound CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000004111 Potassium silicate Substances 0.000 description 1
- 102100024864 REST corepressor 1 Human genes 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 229910007926 ZrCl Inorganic materials 0.000 description 1
- GUMQWPGMMSFQEQ-UHFFFAOYSA-M [I-].CC(C)(C)[Mg+] Chemical compound [I-].CC(C)(C)[Mg+] GUMQWPGMMSFQEQ-UHFFFAOYSA-M 0.000 description 1
- LQHZUFWVUJVYQR-UHFFFAOYSA-M [I-].CCCC[Mg+] Chemical compound [I-].CCCC[Mg+] LQHZUFWVUJVYQR-UHFFFAOYSA-M 0.000 description 1
- CDKFWIMBZAUBRS-UHFFFAOYSA-M [I-].CC[Mg+] Chemical compound [I-].CC[Mg+] CDKFWIMBZAUBRS-UHFFFAOYSA-M 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- WETWJCDKMRHUPV-UHFFFAOYSA-N acetyl chloride Chemical compound CC(Cl)=O WETWJCDKMRHUPV-UHFFFAOYSA-N 0.000 description 1
- 239000012346 acetyl chloride Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 125000005336 allyloxy group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- TZIHFWKZFHZASV-UHFFFAOYSA-N anhydrous methyl formate Natural products COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 1
- 229940071248 anisate Drugs 0.000 description 1
- 150000003934 aromatic aldehydes Chemical class 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- OBNCKNCVKJNDBV-UHFFFAOYSA-N butanoic acid ethyl ester Natural products CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 description 1
- YHASWHZGWUONAO-UHFFFAOYSA-N butanoyl butanoate Chemical compound CCCC(=O)OC(=O)CCC YHASWHZGWUONAO-UHFFFAOYSA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- MRGZQUIZFIEMBS-UHFFFAOYSA-L butoxy(dichloro)alumane Chemical compound [Cl-].[Cl-].CCCCO[Al+2] MRGZQUIZFIEMBS-UHFFFAOYSA-L 0.000 description 1
- CJABGEWOQJDKDE-UHFFFAOYSA-N butoxy(dioctyl)alumane Chemical compound CCCCCCCC[Al](OCCCC)CCCCCCCC CJABGEWOQJDKDE-UHFFFAOYSA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- SHOVVTSKTTYFGP-UHFFFAOYSA-L butylaluminum(2+);dichloride Chemical compound CCCC[Al](Cl)Cl SHOVVTSKTTYFGP-UHFFFAOYSA-L 0.000 description 1
- DVECBJCOGJRVPX-UHFFFAOYSA-N butyryl chloride Chemical compound CCCC(Cl)=O DVECBJCOGJRVPX-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- QABCGOSYZHCPGN-UHFFFAOYSA-N chloro(dimethyl)silicon Chemical compound C[Si](C)Cl QABCGOSYZHCPGN-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 125000000853 cresyl group Chemical group C1(=CC=C(C=C1)C)* 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 1
- PFMKUUJQLUQKHT-UHFFFAOYSA-N dichloro(ethyl)silicon Chemical compound CC[Si](Cl)Cl PFMKUUJQLUQKHT-UHFFFAOYSA-N 0.000 description 1
- RFUDQCRVCDXBGK-UHFFFAOYSA-L dichloro(propyl)alumane Chemical compound [Cl-].[Cl-].CCC[Al+2] RFUDQCRVCDXBGK-UHFFFAOYSA-L 0.000 description 1
- JJSGABFIILQOEY-UHFFFAOYSA-M diethylalumanylium;bromide Chemical compound CC[Al](Br)CC JJSGABFIILQOEY-UHFFFAOYSA-M 0.000 description 1
- PPQUYYAZSOKTQD-UHFFFAOYSA-M diethylalumanylium;iodide Chemical compound CC[Al](I)CC PPQUYYAZSOKTQD-UHFFFAOYSA-M 0.000 description 1
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- FSBVERYRVPGNGG-UHFFFAOYSA-N dimagnesium dioxido-bis[[oxido(oxo)silyl]oxy]silane hydrate Chemical compound O.[Mg+2].[Mg+2].[O-][Si](=O)O[Si]([O-])([O-])O[Si]([O-])=O FSBVERYRVPGNGG-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 125000004119 disulfanediyl group Chemical group *SS* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- GCPCLEKQVMKXJM-UHFFFAOYSA-N ethoxy(diethyl)alumane Chemical compound CCO[Al](CC)CC GCPCLEKQVMKXJM-UHFFFAOYSA-N 0.000 description 1
- XGAIERUWZADBAO-UHFFFAOYSA-N ethoxy-bis(2-methylpropyl)alumane Chemical compound CCO[Al](CC(C)C)CC(C)C XGAIERUWZADBAO-UHFFFAOYSA-N 0.000 description 1
- ZPUKPAPWEWUPTC-UHFFFAOYSA-N ethyl 4-ethylbenzoate Chemical compound CCOC(=O)C1=CC=C(CC)C=C1 ZPUKPAPWEWUPTC-UHFFFAOYSA-N 0.000 description 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
- UKFXDFUAPNAMPJ-UHFFFAOYSA-N ethylmalonic acid Chemical compound CCC(C(O)=O)C(O)=O UKFXDFUAPNAMPJ-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- TVQGDYNRXLTQAP-UHFFFAOYSA-N heptanoic acid ethyl ester Natural products CCCCCCC(=O)OCC TVQGDYNRXLTQAP-UHFFFAOYSA-N 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QNVRIHYSUZMSGM-UHFFFAOYSA-N hexan-2-ol Chemical compound CCCCC(C)O QNVRIHYSUZMSGM-UHFFFAOYSA-N 0.000 description 1
- JARKCYVAAOWBJS-UHFFFAOYSA-N hexanal Chemical compound CCCCCC=O JARKCYVAAOWBJS-UHFFFAOYSA-N 0.000 description 1
- IOANYFLVSWZRND-UHFFFAOYSA-N hydroxy(tripropyl)silane Chemical compound CCC[Si](O)(CCC)CCC IOANYFLVSWZRND-UHFFFAOYSA-N 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- BVRHQICYSINRIG-UHFFFAOYSA-N iron;magnesium;silicic acid Chemical compound [Mg].[Mg].[Mg].[Fe].O[Si](O)(O)O.O[Si](O)(O)O BVRHQICYSINRIG-UHFFFAOYSA-N 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 125000003253 isopropoxy group Chemical group [H]C([H])([H])C([H])(O*)C([H])([H])[H] 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- DQDWATOXYCARFV-UHFFFAOYSA-M magnesium;2-methanidylpropane;bromide Chemical compound [Mg+2].[Br-].CC(C)[CH2-] DQDWATOXYCARFV-UHFFFAOYSA-M 0.000 description 1
- YSMZEMQBSONIMJ-UHFFFAOYSA-M magnesium;2-methanidylpropane;chloride Chemical compound [Mg+2].[Cl-].CC(C)[CH2-] YSMZEMQBSONIMJ-UHFFFAOYSA-M 0.000 description 1
- UKZCGMDMXDLAGZ-UHFFFAOYSA-M magnesium;2-methylpropane;bromide Chemical compound [Mg+2].[Br-].C[C-](C)C UKZCGMDMXDLAGZ-UHFFFAOYSA-M 0.000 description 1
- CQRPUKWAZPZXTO-UHFFFAOYSA-M magnesium;2-methylpropane;chloride Chemical compound [Mg+2].[Cl-].C[C-](C)C CQRPUKWAZPZXTO-UHFFFAOYSA-M 0.000 description 1
- IWCVDCOJSPWGRW-UHFFFAOYSA-M magnesium;benzene;chloride Chemical compound [Mg+2].[Cl-].C1=CC=[C-]C=C1 IWCVDCOJSPWGRW-UHFFFAOYSA-M 0.000 description 1
- WSHFRLGXCNEKRX-UHFFFAOYSA-M magnesium;butane;bromide Chemical compound [Mg+2].[Br-].CC[CH-]C WSHFRLGXCNEKRX-UHFFFAOYSA-M 0.000 description 1
- LWLPYZUDBNFNAH-UHFFFAOYSA-M magnesium;butane;bromide Chemical compound [Mg+2].[Br-].CCC[CH2-] LWLPYZUDBNFNAH-UHFFFAOYSA-M 0.000 description 1
- YNLPNVNWHDKDMN-UHFFFAOYSA-M magnesium;butane;chloride Chemical compound [Mg+2].[Cl-].CC[CH-]C YNLPNVNWHDKDMN-UHFFFAOYSA-M 0.000 description 1
- QUXHCILOWRXCEO-UHFFFAOYSA-M magnesium;butane;chloride Chemical compound [Mg+2].[Cl-].CCC[CH2-] QUXHCILOWRXCEO-UHFFFAOYSA-M 0.000 description 1
- NXPHGHWWQRMDIA-UHFFFAOYSA-M magnesium;carbanide;bromide Chemical compound [CH3-].[Mg+2].[Br-] NXPHGHWWQRMDIA-UHFFFAOYSA-M 0.000 description 1
- CCERQOYLJJULMD-UHFFFAOYSA-M magnesium;carbanide;chloride Chemical compound [CH3-].[Mg+2].[Cl-] CCERQOYLJJULMD-UHFFFAOYSA-M 0.000 description 1
- VXWPONVCMVLXBW-UHFFFAOYSA-M magnesium;carbanide;iodide Chemical compound [CH3-].[Mg+2].[I-] VXWPONVCMVLXBW-UHFFFAOYSA-M 0.000 description 1
- FRIJBUGBVQZNTB-UHFFFAOYSA-M magnesium;ethane;bromide Chemical compound [Mg+2].[Br-].[CH2-]C FRIJBUGBVQZNTB-UHFFFAOYSA-M 0.000 description 1
- YCCXQARVHOPWFJ-UHFFFAOYSA-M magnesium;ethane;chloride Chemical compound [Mg+2].[Cl-].[CH2-]C YCCXQARVHOPWFJ-UHFFFAOYSA-M 0.000 description 1
- LZFCBBSYZJPPIV-UHFFFAOYSA-M magnesium;hexane;bromide Chemical compound [Mg+2].[Br-].CCCCC[CH2-] LZFCBBSYZJPPIV-UHFFFAOYSA-M 0.000 description 1
- GBRJQTLHXWRDOV-UHFFFAOYSA-M magnesium;hexane;chloride Chemical compound [Mg+2].[Cl-].CCCCC[CH2-] GBRJQTLHXWRDOV-UHFFFAOYSA-M 0.000 description 1
- HQDAZWQQKSJCTM-UHFFFAOYSA-M magnesium;octane;chloride Chemical compound [Mg+2].[Cl-].CCCCCCC[CH2-] HQDAZWQQKSJCTM-UHFFFAOYSA-M 0.000 description 1
- UGVPKMAWLOMPRS-UHFFFAOYSA-M magnesium;propane;bromide Chemical compound [Mg+2].[Br-].CC[CH2-] UGVPKMAWLOMPRS-UHFFFAOYSA-M 0.000 description 1
- LVKCSZQWLOVUGB-UHFFFAOYSA-M magnesium;propane;bromide Chemical compound [Mg+2].[Br-].C[CH-]C LVKCSZQWLOVUGB-UHFFFAOYSA-M 0.000 description 1
- XGITVAYMIKUXIN-UHFFFAOYSA-M magnesium;propane;iodide Chemical compound [Mg+2].[I-].C[CH-]C XGITVAYMIKUXIN-UHFFFAOYSA-M 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- UZKWTJUDCOPSNM-UHFFFAOYSA-N methoxybenzene Substances CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 1
- WVWZECQNFWFVFW-UHFFFAOYSA-N methyl 2-methylbenzoate Chemical compound COC(=O)C1=CC=CC=C1C WVWZECQNFWFVFW-UHFFFAOYSA-N 0.000 description 1
- ZKUUVVYMPUDTGJ-UHFFFAOYSA-N methyl 5-hydroxy-4-methoxy-2-nitrobenzoate Chemical compound COC(=O)C1=CC(O)=C(OC)C=C1[N+]([O-])=O ZKUUVVYMPUDTGJ-UHFFFAOYSA-N 0.000 description 1
- 229940095102 methyl benzoate Drugs 0.000 description 1
- 229940017219 methyl propionate Drugs 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- ZWLPBLYKEWSWPD-UHFFFAOYSA-N o-toluic acid Chemical compound CC1=CC=CC=C1C(O)=O ZWLPBLYKEWSWPD-UHFFFAOYSA-N 0.000 description 1
- NUJGJRNETVAIRJ-UHFFFAOYSA-N octanal Chemical compound CCCCCCCC=O NUJGJRNETVAIRJ-UHFFFAOYSA-N 0.000 description 1
- 150000002899 organoaluminium compounds Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pentâ4âenâ2âone Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- ANRQGKOBLBYXFM-UHFFFAOYSA-M phenylmagnesium bromide Chemical compound Br[Mg]C1=CC=CC=C1 ANRQGKOBLBYXFM-UHFFFAOYSA-M 0.000 description 1
- XIPFMBOWZXULIA-UHFFFAOYSA-N pivalamide Chemical compound CC(C)(C)C(N)=O XIPFMBOWZXULIA-UHFFFAOYSA-N 0.000 description 1
- 230000037048 polymerization activity Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- RZWZRACFZGVKFM-UHFFFAOYSA-N propanoyl chloride Chemical compound CCC(Cl)=O RZWZRACFZGVKFM-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- WYVAMUWZEOHJOQ-UHFFFAOYSA-N propionic anhydride Chemical compound CCC(=O)OC(=O)CC WYVAMUWZEOHJOQ-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 125000004014 thioethyl group Chemical group [H]SC([H])([H])C([H])([H])* 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
- JYVWRCIOZLRMKO-UHFFFAOYSA-N tributyl(hydroxy)silane Chemical compound CCCC[Si](O)(CCCC)CCCC JYVWRCIOZLRMKO-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- XBEXIHMRFRFRAM-UHFFFAOYSA-N tridodecylalumane Chemical compound CCCCCCCCCCCC[Al](CCCCCCCCCCCC)CCCCCCCCCCCC XBEXIHMRFRFRAM-UHFFFAOYSA-N 0.000 description 1
- WVMSIBFANXCZKT-UHFFFAOYSA-N triethyl(hydroxy)silane Chemical compound CC[Si](O)(CC)CC WVMSIBFANXCZKT-UHFFFAOYSA-N 0.000 description 1
- NHADXUOUFVKVEB-UHFFFAOYSA-N trihexadecylalumane Chemical compound CCCCCCCCCCCCCCCC[Al](CCCCCCCCCCCCCCCC)CCCCCCCCCCCCCCCC NHADXUOUFVKVEB-UHFFFAOYSA-N 0.000 description 1
- AAPLIUHOKVUFCC-UHFFFAOYSA-N trimethylsilanol Chemical compound C[Si](C)(C)O AAPLIUHOKVUFCC-UHFFFAOYSA-N 0.000 description 1
- 125000006617 triphenylamine group Chemical class 0.000 description 1
- CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940005605 valeric acid Drugs 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
æ¬çºæã¯ãæ°èŠãªè§ŠåªãçšããŠãªã¬ãã€ã³ãé
åããæ¹æ³ãããã«è©³ããã¯ãç¹å®ã®ææ©ãã°ã
ãã·ãŠã æåãâSiâClçµåå«æã®çªçŽ åå
ç©ãé»åäŸäžäœãé·ç§»éå±ååç©ããã³ææ©éå±
ååç©ãçšããŠãªã觊åªã«ãããªã¬ãã€ã³ãéå
ããæ¹æ³ã«é¢ããã ãªã¬ãã€ã³ã®éå觊åªãšããŠãå çŽ åšæåŸè¡šç¬¬
ãæã®é·ç§»éå±ååç©ãšå çŽ åšæåŸè¡šç¬¬
ãæã®ææ©éå±ååç©ãããªããããããããŒ
ã°ã©ãŒè§Šåªç³»ãç¥ãããŠããããè¿å¹Žãé«æŽ»æ§ãª
ã¬ãã€ã³éå觊åªãšããŠãç¡æ©ãã°ãã·ãŠã åå
ç©ãšãã¿ã³ãŸãã¯ãããžãŠã ååç©ãæãã¯ãã
ã«é»åäŸäžäœãããªã觊åªç³»ãããšãã°Polymer
Letters Vol.3ïŒp855æãã¯ç¹å ¬æ39â12105å·å ¬
å ±çããä»æ¹ææ©ãã°ãã·ãŠã ååç©ãšãã¿ã³ãŸ
ãã¯ãããžãŠã ååç©ãæãã¯ããã«é»åäŸäžäœ
ãããªã觊åªç³»ãå€æ°ææ¡ãããŠãããææ©ãã°
ãã·ãŠã 系觊åªã®å Žåãããšãã°ç¹å ¬æ46â
31968å·å ¬å ±ã«ãããŠã¯ãã¢ã«ãããŠã ããã²ã³
ååç©ãšãã¿ã³ååç©ãšææ©ãã°ãã·ãŠã ååç©
ãšãæ··åããéã«ãæ··ååãæ··åæåã¯æ··ååŸã«
ã¢ã«ã«ããŒã«ãã¢ã«ã±ããŒã«ãã¢ã«ã«ãã©ãŒãã
ã¢ã«ã±ãã©ãŒããã«ã«ãã³é žãã«ã«ãã³é žã®ãšã¹
ãã«åã¯å¡©ãã¢ã«ãããåã¯ã±ãã³ãæ·»å ããŠã
ã¢ã«ã±ã³é¡ã110â以äžã§éåããæ¹æ³ãèšèŒã
ããŠããã ãŸãããã«ãç¹å ¬æ50â32270å·å ¬å ±ãç¹å ¬æ
53â46799å·å ¬å ±ãç¹éæ50â95382å·å ¬å ±ãç¹é
æ55â58207å·å ¬å ±ãç¹éæ57â205407å·å ¬å ±ã
ç¹éæ57â205409å·å ¬å ±ã®ææ¡ããªãããŠããã ãŸããç¹å ¬æ56â43046å·å ¬å ±ãç¹å ¬æ57â
9567å·å ¬å ±ãç¹é¡æ52â14940å·ãç¹é¡æ52â
64006å·ãç¹é¡æ52â67303å·ãç¹é¡æ52â68834
å·çã«ãããŠã¯ãææ©ãã°ãã·ãŠã æåãšïŒšâSi
âClçµåå«æã¯ãã«ã·ã©ã³ãåå¿ãããŠåŸããã
掻æ§ææ©ãã°ãã·ãŠã å«æåºäœç©è³ªãçšãããªã¬
ãã€ã³éå觊åªãææ¡ããŠããããããã®è§Šåªç³»
ã¯åªããæ§èœã瀺ãããæºè¶³ããã«ã¯æªã ååã§
ã¯ãªãã æ¬çºæè ãã¯ãææ©ãã°ãã·ãŠã æåâSiâ
Clçµåå«æã¯ãã«ã·ã©ã³ãé»åäŸäžäœååç©ãé·
移éå±ååç©ããã³ææ©éå±ååç©ãçšããŠãªã
觊åªç³»ãçšããéåæ¹æ³ã«ã€ããŠãéææ€èšãã
çµæãåªãããªã¬ãã€ã³ã®éåæ¹æ³ãèŠãåºã
ãã å³ã¡ãæ¬çºæã¯ã ãAã(1)(i) (a)äžè¬åŒMãMgãR1 pR2 qXrYsïŒåŒäžãïŒ
ã¯AlïŒZnïŒïŒ¢ïŒBeïŒLiååãR1ïŒR2ã¯å
äžãŸãã¯ç°ãªã€ãC1ãC10ã®çåæ°ŽçŽ åºã
ïŒïŒ¹ã¯åäžãŸãã¯ç°ãªã€ãOR3ïŒ
OSiR4R5R6ïŒNR7R8ïŒSR9ïŒããã²ã³ãª
ãåºãè¡šãããR3ïŒR4ïŒR5ïŒR6ïŒR7ïŒR8
ã¯æ°ŽçŽ ååãŸãã¯C1ãC10ã®çåæ°ŽçŽ åºã§
ãããR9ã¯C1ãC10ã®çåæ°ŽçŽ åºã§ããã
αâ§ïŒãβïŒïŒãïœïŒïœïŒïœïŒïœâ§ïŒãïœ
ã¯ïŒã®åå䟡ãïœïŒïœïŒïœïŒïœïŒmαïŒ
2βãïŒâŠïŒïœïŒïœïŒïŒïŒÎ±ïŒÎ²ïŒâŠïŒã®é¢
ä¿ã«ãããïŒã§ç€ºãããææ©ãã°ãã·ãŠã
ïŒã¢ã«ãšãæãã¯(a)ãš(b)ãšãŒãã«ãããªãš
ãŒãã«ãã±ãã³ãã¢ã«ããããã«ã«ãã³é ž
ãŸãã¯ãã®èªå°äœãããã¯ã¢ã«ã³ãŒã«ãã
ãªã¢ã«ã³ãŒã«ãã¢ãã³ããéžã°ããé»åäŸ
äžäœãšåå¿ãããæåïŒã¢ã«ãšã (ii) äžè¬åŒHaSiClbR10 4-(a+b)ïŒåŒäžãïœïŒïœã¯
ïŒãã倧ããæ°ã§ïœïŒïœâŠïŒãïŒïŒïœâŠ
ïŒãR10ã¯ççŽ æ°ïŒã20ã®çåæ°ŽçŽ åºãè¡š
ããïŒã§ç€ºãããâSiçµåå«æã¯ãã«ã·
ã©ã³ååç©0.01ã100ã¢ã«ãã次ããéžã°
ããç¡æ©æ äœã®ååšäžæãã¯éåšäžã« (i) ç¡æ©é žåç© (ii) ç¡æ©çé žå¡©ãçªé žå¡©ãç¡«é žå¡© (iii) ç¡æ©æ°Žé žåç© (iv) (i)ã(iii)ãããªãè€å¡©ãåºæº¶äœãªããæ··å
ç©ã åå¿ãããŠãªãåºäœäžã«å«ãŸããâMg
çµåïŒã¢ã«ã«å¯Ÿã㊠(2) 次ããéžã°ããååç©0.05ã20ã¢ã«ãåå¿
ãããŠåŸãããåºäœãã (i) ã¢ã«ããã (ii) ã·ã©ããŒã« (iii) ãã€ãããžãšã³ã·ãããµã³ (3) ãã¿ããŠã ååç©ããããžãŠã ååç©ããž
ã«ã³ããŠã ååç©ãããããŠã ååç©ããã³
ãããã®æ··åç©ãªããåå¿ç©ããéžã°ããïŒ
皮以äžã®æåãã åå¿ãããŠåŸãããåºäœè§Šåªæåãæãã¯ãã
ã« (4) åããã²ã³åãã¿ããŠã ååç©ãã¢ã«ãã
ãŠã ã®ããã²ã³åç©ãçªçŽ ã®ããã²ã³åç©ã
é«ã®ããã²ã³åç©ããéžã°ããæå ã«ããåŠçããŠåŸãããåºäœè§Šåªæå ãBã ææ©éå±ååç©æå ã§ãã€ãŠããããšãããããªã觊åªããªã¬ã
ã€ã³ãšæ¥è§Šããããªã¬ãã€ã³éåæ¹æ³ã§ããã æ¬çºæã®ç¹åŸŽã®ç¬¬äžã¯ã觊åªåœãç¹ã«ãã¿ã³ïŒ
ã°ã©ã åœãã®è§Šåªå¹çãé«ãããšã§ãããå®æœäŸ
ïŒã®å Žå1670KgâPEïŒïœâTiãããã³33400ïœâ
PEïŒïœâåºäœè§ŠåªæåãåŸãããŠããã æ¬çºæã®ç¹åŸŽã®ç¬¬äºã¯ãåŸãããéåäœç²åã®
嵩å¯åºŠã倧ããããšã§ãããæžæ¿éåã«ããå Žå
ïŒå®æœäŸïŒâ(4)ã®å ŽåïŒ0.48ïœïŒcm3ãåŸãããŠã
ãã æ¬çºæã®ç¹åŸŽã®ç¬¬äžã¯ããªã¬ãã€ã³ã®å ±éåæ
ã«ãããå ±éåå¹æãè¯ãããšã§ããã æ¬çºæã®ç¹åŸŽã®ç¬¬åã¯ããªã¬ãã€ã³éåäœãŸã
ã¯ãªã¬ãã€ã³å ±éåäœã®è²çžãè¯ãããšã§ããã æ¬é¡ã«ãããŠäœ¿çšããææ©ãã°ãã·ãŠã æåãš
ããŠã¯ãäžè¬åŒMãMgãR1 pR2 qXrYsïŒåŒäžãïŒã¯
AlïŒZnïŒïŒ¢ïŒBeïŒLiååãR1ïŒR2ã¯åäžãŸãã¯
ç°ãªã€ãC1ã10ã®çåæ°ŽçŽ åºãïŒïŒ¹ã¯åäžãŸã
ã¯ç°ãªã€ãOR3ïŒOSiR4R5R6ïŒNR7R8ïŒSR9ãã
ãã²ã³ãªãåºãè¡šãããR3ïŒR4ïŒR5ïŒR6ïŒR7ïŒ
R8ã¯æ°ŽçŽ ãŸãã¯C1ã10ã®çåæ°ŽçŽ åºã§ãããR9
ã¯C1ã10ã®çåæ°ŽçŽ åºã§ãããαâ§ïŒãβïŒïŒã
ïœïŒïœïŒïœïŒïœâ§ïŒãïœã¯ïŒã®åå䟡ãïœïŒïœïŒ
ïœïŒïœïŒmαïŒ2βãïŒâŠïŒïœïŒïœïŒïŒïŒÎ±ïŒÎ²ïŒâŠ
ïŒã®é¢ä¿ã«ãããïŒã§ç€ºãããææ©ãã°ãã·ãŠã
æåãçšããããšãã§ããã ãã®ååç©ã¯ãææ©ãã°ãã·ãŠã ã®é¯ååç©ã®
圢ãšããŠç€ºãããŠããããR2Mgããã³ããããš
ä»éå±ååç©ãšã®é¯äœã®ãã¹ãŠãå å«ãããã®ã§
ãããäžèšåŒäžã®R1ãªããR9ã§è¡šããããçå
æ°ŽçŽ åºã¯ãã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºãŸãã¯
ã¢ãªãŒã«åºã§ãããããšãã°ãã¡ãã«ããšãã«ã
ãããã«ãããã«ãã¢ãã«ãããã·ã«ããã·ã«ã
ã·ã¯ãããã·ã«ãããšãã«åºçãæããããç¹ã«
R1ã¯ã¢ã«ãã«åºã§ããããšã奜ãŸããããŸãã
R3ãªããR8ã¯æ°ŽçŽ ååã§ããããšã劚ããªãã éçŽ ååïŒãšããŠã¯ãåšæåŸè¡šç¬¬æãªãã第
æã«å±ããéå±å çŽ ã䜿çšã§ããããšãã°ãã
ããªãŠã ãã«ãªãŠã ãã«ã«ã·ãŠã ãããªãªãŠã ã
äºéãããªãŠã ãããŠçŽ ãã¢ã«ãããŠã ããªããŠ
ã çãæããããããç¹ã«ã¢ã«ãããŠã ãäºéã
ããŠçŽ ãããªãªãŠã ããªããŠã ãçåæ°ŽçŽ å¯æº¶æ§
ææ©ãã°ãã·ãŠã é¯äœãäœãæããæ®ã«å¥œãŸã
ããéå±ååïŒã«å¯Ÿãããã°ãã·ãŠã ã®æ¯Î²ïŒÎ±
ã¯ãä»»æã«èšå®å¯èœã§ãããã奜ãŸããã¯ïŒã
10ãç¹ã«0.5ã10ã®ç¯å²ã®çåæ°ŽçŽ å¯æº¶æ§ã®ææ©
ãã°ãã·ãŠã é¯äœãæ®ã«å¥œãŸããã èšå·Î±ïŒÎ²ïŒïœïŒïœïŒïœïŒïœã®é¢ä¿åŒïœïŒïœïŒ
ïœïŒïœïŒmαïŒ2βã¯ãéå±ååã®åå䟡ãšçœ®æåº
ãšã®ååŠéè«æ§ã瀺ãã奜ãŸããç¯å²ã§ããïŒâŠ
ïŒïœïŒïœïŒïŒïŒÎ±ïŒÎ²ïŒâŠ1.0ã¯ãéå±ååã®åã«
察ããšïŒ¹ã®åã®æ¯ãïŒä»¥äžã§1.0ããå°ã§ãã
ããšã瀺ããç¹ã«å¥œãŸããç¯å²ã¯ïŒã0.8ã§ããã ãããã®ææ©ãã°ãã·ãŠã ååç©ãããã¯ææ©
ãã°ãã·ãŠã é¯äœã¯ãäžè¬åŒRMgQïŒR2MgïŒïŒ²
ã¯åè¿°ã®æå³ã§ãããã¯ããã²ã³ã§ããïŒã§ç€º
ãããææ©ãã°ãã·ãŠã ååç©ãšãäžè¬åŒMRn
ãŸãã¯MRn-1ïŒïŒïŒïŒ²ïŒïœã¯åè¿°ã®æå³ã§ã
ãïŒã§ç€ºãããææ©éå±ååç©ãšãããããµã³ã
ããã¿ã³ãã·ã¯ããããµã³ããã³ãŒã³ããã«ãšã³
çã®äžæŽ»æ§çåæ°ŽçŽ åªäœäžã宀枩ã150âã®éã§
åå¿ãããå¿ èŠãªå Žåã«ã¯ç¶ããŠããããããã«
ã¢ã«ã³ãŒã«ãæ°Žãã·ãããµã³ãã¢ãã³ãã€ãã³ã
ã¡ã«ã«ãã¿ã³ãŸãã¯ãžããªååç©ãšåå¿ãããã
ãšã«ããåæããããããã«ææ©ãã°ãã·ãŠã å
åç©ãããã¯ææ©ãã°ãã·ãŠã é¯äœã¯MgX2ïŒ
RMgXãšMRnïŒMRn-1ããŸãã¯RMgXïŒ
MgR2ãšRoMXn-oããŸãã¯RMgXïŒMgR2ãšYo
MXn-oïŒåŒäžãïŒïŒïŒ²ïŒïŒžïŒïŒ¹ã¯åè¿°ã®ãšããã§
ãã€ãŠãïŒïŒ¹ãããã²ã³ã§ããå Žåãå«ã¿ãïœ
ã¯ïŒãïœã®æ°ã§ããïŒãšã®åå¿ã«ããåæããã
ãšãã§ããã äžè¬ã«ã¯ææ©ãã°ãã·ãŠã ååç©ã¯äžæŽ»æ§çå
æ°ŽçŽ åªäœã«äžæº¶æ§ã§ãããαïŒïŒã§ãããšããã®
ææ©ãã°ãã·ãŠã é¯äœã¯å¯æº¶æ§ã§ããã ãŸããαïŒïŒã§ãããçš®ã®ææ©ãã°ãã·ãŠã å
åç©ãããšãã°secâBu2Mgçã¯çåæ°ŽçŽ åªäœã«
å¯æº¶æ§ã§ããããã®ãããªååç©ãæ¬çºæã«çšã
ãŠå¥œãŸããçµæãäžãã以äžãããã®ææ©ãã°ã
ã·ãŠã ååç©ã«ã€ããŠèª¬æããã äžè¬åŒMgãR1 pR2 qXrYsã«ãããŠR1ïŒR2ã¯æ¬¡ã®äž
ã€ã®çŸ€ïŒïŒïŒïŒïŒïŒïŒïŒã®ããããäžã€ã§ãã
ãã®ãšããã () R1ïŒR2ã®å°ãªããšãäžæ¹ãççŽ ååæ°ïŒã
ïŒã§ããäºçŽãŸãã¯äžçŽã®ã¢ã«ãã«åºã§ããã
ãšã奜ãŸããã¯R1ïŒR2ããšãã«ççŽ ååæ°ïŒ
ãïŒã§ãããå°ãªããšãäžæ¹ãäºçŽãŸãã¯äžçŽ
ã®ã¢ã«ãã«åºã§ããããšã () R1ãšR2ãšã®ççŽ ååæ°ã®äºãã«çžç°ãªãã¢
ã«ãã«åºã§ããããšã奜ãŸããã¯R4ãççŽ æ°
ïŒãŸãã¯ïŒã®ã¢ã«ãã«åºã§ãããR2ãççŽ æ°
ïŒä»¥äžã®ã¢ã«ãã«åºã§ããããšã () R1ïŒR2ã®å°ãªããšãäžæ¹ãççŽ ååæ°ïŒä»¥
äžã®çåæ°ŽçŽ åºã§ããããšã奜ãŸããã¯ãR1ïŒ
R2ããšãã«ççŽ ååæ°ïŒä»¥äžã®ã¢ã«ãã«åºã§
ããããšã 以äžããããã®åºãå ·äœçã«ç€ºããïŒïŒã«ã
ããŠççŽ ååæ°ïŒãïŒã§ããäºçŽãŸãã¯äžçŽã®ã¢
ã«ãã«åºãšããŠã¯ãsecâC4H9ïŒtertâC4H9ã
åããæ¹æ³ãããã«è©³ããã¯ãç¹å®ã®ææ©ãã°ã
ãã·ãŠã æåãâSiâClçµåå«æã®çªçŽ åå
ç©ãé»åäŸäžäœãé·ç§»éå±ååç©ããã³ææ©éå±
ååç©ãçšããŠãªã觊åªã«ãããªã¬ãã€ã³ãéå
ããæ¹æ³ã«é¢ããã ãªã¬ãã€ã³ã®éå觊åªãšããŠãå çŽ åšæåŸè¡šç¬¬
ãæã®é·ç§»éå±ååç©ãšå çŽ åšæåŸè¡šç¬¬
ãæã®ææ©éå±ååç©ãããªããããããããŒ
ã°ã©ãŒè§Šåªç³»ãç¥ãããŠããããè¿å¹Žãé«æŽ»æ§ãª
ã¬ãã€ã³éå觊åªãšããŠãç¡æ©ãã°ãã·ãŠã åå
ç©ãšãã¿ã³ãŸãã¯ãããžãŠã ååç©ãæãã¯ãã
ã«é»åäŸäžäœãããªã觊åªç³»ãããšãã°Polymer
Letters Vol.3ïŒp855æãã¯ç¹å ¬æ39â12105å·å ¬
å ±çããä»æ¹ææ©ãã°ãã·ãŠã ååç©ãšãã¿ã³ãŸ
ãã¯ãããžãŠã ååç©ãæãã¯ããã«é»åäŸäžäœ
ãããªã觊åªç³»ãå€æ°ææ¡ãããŠãããææ©ãã°
ãã·ãŠã 系觊åªã®å Žåãããšãã°ç¹å ¬æ46â
31968å·å ¬å ±ã«ãããŠã¯ãã¢ã«ãããŠã ããã²ã³
ååç©ãšãã¿ã³ååç©ãšææ©ãã°ãã·ãŠã ååç©
ãšãæ··åããéã«ãæ··ååãæ··åæåã¯æ··ååŸã«
ã¢ã«ã«ããŒã«ãã¢ã«ã±ããŒã«ãã¢ã«ã«ãã©ãŒãã
ã¢ã«ã±ãã©ãŒããã«ã«ãã³é žãã«ã«ãã³é žã®ãšã¹
ãã«åã¯å¡©ãã¢ã«ãããåã¯ã±ãã³ãæ·»å ããŠã
ã¢ã«ã±ã³é¡ã110â以äžã§éåããæ¹æ³ãèšèŒã
ããŠããã ãŸãããã«ãç¹å ¬æ50â32270å·å ¬å ±ãç¹å ¬æ
53â46799å·å ¬å ±ãç¹éæ50â95382å·å ¬å ±ãç¹é
æ55â58207å·å ¬å ±ãç¹éæ57â205407å·å ¬å ±ã
ç¹éæ57â205409å·å ¬å ±ã®ææ¡ããªãããŠããã ãŸããç¹å ¬æ56â43046å·å ¬å ±ãç¹å ¬æ57â
9567å·å ¬å ±ãç¹é¡æ52â14940å·ãç¹é¡æ52â
64006å·ãç¹é¡æ52â67303å·ãç¹é¡æ52â68834
å·çã«ãããŠã¯ãææ©ãã°ãã·ãŠã æåãšïŒšâSi
âClçµåå«æã¯ãã«ã·ã©ã³ãåå¿ãããŠåŸããã
掻æ§ææ©ãã°ãã·ãŠã å«æåºäœç©è³ªãçšãããªã¬
ãã€ã³éå觊åªãææ¡ããŠããããããã®è§Šåªç³»
ã¯åªããæ§èœã瀺ãããæºè¶³ããã«ã¯æªã ååã§
ã¯ãªãã æ¬çºæè ãã¯ãææ©ãã°ãã·ãŠã æåâSiâ
Clçµåå«æã¯ãã«ã·ã©ã³ãé»åäŸäžäœååç©ãé·
移éå±ååç©ããã³ææ©éå±ååç©ãçšããŠãªã
觊åªç³»ãçšããéåæ¹æ³ã«ã€ããŠãéææ€èšãã
çµæãåªãããªã¬ãã€ã³ã®éåæ¹æ³ãèŠãåºã
ãã å³ã¡ãæ¬çºæã¯ã ãAã(1)(i) (a)äžè¬åŒMãMgãR1 pR2 qXrYsïŒåŒäžãïŒ
ã¯AlïŒZnïŒïŒ¢ïŒBeïŒLiååãR1ïŒR2ã¯å
äžãŸãã¯ç°ãªã€ãC1ãC10ã®çåæ°ŽçŽ åºã
ïŒïŒ¹ã¯åäžãŸãã¯ç°ãªã€ãOR3ïŒ
OSiR4R5R6ïŒNR7R8ïŒSR9ïŒããã²ã³ãª
ãåºãè¡šãããR3ïŒR4ïŒR5ïŒR6ïŒR7ïŒR8
ã¯æ°ŽçŽ ååãŸãã¯C1ãC10ã®çåæ°ŽçŽ åºã§
ãããR9ã¯C1ãC10ã®çåæ°ŽçŽ åºã§ããã
αâ§ïŒãβïŒïŒãïœïŒïœïŒïœïŒïœâ§ïŒãïœ
ã¯ïŒã®åå䟡ãïœïŒïœïŒïœïŒïœïŒmαïŒ
2βãïŒâŠïŒïœïŒïœïŒïŒïŒÎ±ïŒÎ²ïŒâŠïŒã®é¢
ä¿ã«ãããïŒã§ç€ºãããææ©ãã°ãã·ãŠã
ïŒã¢ã«ãšãæãã¯(a)ãš(b)ãšãŒãã«ãããªãš
ãŒãã«ãã±ãã³ãã¢ã«ããããã«ã«ãã³é ž
ãŸãã¯ãã®èªå°äœãããã¯ã¢ã«ã³ãŒã«ãã
ãªã¢ã«ã³ãŒã«ãã¢ãã³ããéžã°ããé»åäŸ
äžäœãšåå¿ãããæåïŒã¢ã«ãšã (ii) äžè¬åŒHaSiClbR10 4-(a+b)ïŒåŒäžãïœïŒïœã¯
ïŒãã倧ããæ°ã§ïœïŒïœâŠïŒãïŒïŒïœâŠ
ïŒãR10ã¯ççŽ æ°ïŒã20ã®çåæ°ŽçŽ åºãè¡š
ããïŒã§ç€ºãããâSiçµåå«æã¯ãã«ã·
ã©ã³ååç©0.01ã100ã¢ã«ãã次ããéžã°
ããç¡æ©æ äœã®ååšäžæãã¯éåšäžã« (i) ç¡æ©é žåç© (ii) ç¡æ©çé žå¡©ãçªé žå¡©ãç¡«é žå¡© (iii) ç¡æ©æ°Žé žåç© (iv) (i)ã(iii)ãããªãè€å¡©ãåºæº¶äœãªããæ··å
ç©ã åå¿ãããŠãªãåºäœäžã«å«ãŸããâMg
çµåïŒã¢ã«ã«å¯Ÿã㊠(2) 次ããéžã°ããååç©0.05ã20ã¢ã«ãåå¿
ãããŠåŸãããåºäœãã (i) ã¢ã«ããã (ii) ã·ã©ããŒã« (iii) ãã€ãããžãšã³ã·ãããµã³ (3) ãã¿ããŠã ååç©ããããžãŠã ååç©ããž
ã«ã³ããŠã ååç©ãããããŠã ååç©ããã³
ãããã®æ··åç©ãªããåå¿ç©ããéžã°ããïŒ
皮以äžã®æåãã åå¿ãããŠåŸãããåºäœè§Šåªæåãæãã¯ãã
ã« (4) åããã²ã³åãã¿ããŠã ååç©ãã¢ã«ãã
ãŠã ã®ããã²ã³åç©ãçªçŽ ã®ããã²ã³åç©ã
é«ã®ããã²ã³åç©ããéžã°ããæå ã«ããåŠçããŠåŸãããåºäœè§Šåªæå ãBã ææ©éå±ååç©æå ã§ãã€ãŠããããšãããããªã觊åªããªã¬ã
ã€ã³ãšæ¥è§Šããããªã¬ãã€ã³éåæ¹æ³ã§ããã æ¬çºæã®ç¹åŸŽã®ç¬¬äžã¯ã觊åªåœãç¹ã«ãã¿ã³ïŒ
ã°ã©ã åœãã®è§Šåªå¹çãé«ãããšã§ãããå®æœäŸ
ïŒã®å Žå1670KgâPEïŒïœâTiãããã³33400ïœâ
PEïŒïœâåºäœè§ŠåªæåãåŸãããŠããã æ¬çºæã®ç¹åŸŽã®ç¬¬äºã¯ãåŸãããéåäœç²åã®
嵩å¯åºŠã倧ããããšã§ãããæžæ¿éåã«ããå Žå
ïŒå®æœäŸïŒâ(4)ã®å ŽåïŒ0.48ïœïŒcm3ãåŸãããŠã
ãã æ¬çºæã®ç¹åŸŽã®ç¬¬äžã¯ããªã¬ãã€ã³ã®å ±éåæ
ã«ãããå ±éåå¹æãè¯ãããšã§ããã æ¬çºæã®ç¹åŸŽã®ç¬¬åã¯ããªã¬ãã€ã³éåäœãŸã
ã¯ãªã¬ãã€ã³å ±éåäœã®è²çžãè¯ãããšã§ããã æ¬é¡ã«ãããŠäœ¿çšããææ©ãã°ãã·ãŠã æåãš
ããŠã¯ãäžè¬åŒMãMgãR1 pR2 qXrYsïŒåŒäžãïŒã¯
AlïŒZnïŒïŒ¢ïŒBeïŒLiååãR1ïŒR2ã¯åäžãŸãã¯
ç°ãªã€ãC1ã10ã®çåæ°ŽçŽ åºãïŒïŒ¹ã¯åäžãŸã
ã¯ç°ãªã€ãOR3ïŒOSiR4R5R6ïŒNR7R8ïŒSR9ãã
ãã²ã³ãªãåºãè¡šãããR3ïŒR4ïŒR5ïŒR6ïŒR7ïŒ
R8ã¯æ°ŽçŽ ãŸãã¯C1ã10ã®çåæ°ŽçŽ åºã§ãããR9
ã¯C1ã10ã®çåæ°ŽçŽ åºã§ãããαâ§ïŒãβïŒïŒã
ïœïŒïœïŒïœïŒïœâ§ïŒãïœã¯ïŒã®åå䟡ãïœïŒïœïŒ
ïœïŒïœïŒmαïŒ2βãïŒâŠïŒïœïŒïœïŒïŒïŒÎ±ïŒÎ²ïŒâŠ
ïŒã®é¢ä¿ã«ãããïŒã§ç€ºãããææ©ãã°ãã·ãŠã
æåãçšããããšãã§ããã ãã®ååç©ã¯ãææ©ãã°ãã·ãŠã ã®é¯ååç©ã®
圢ãšããŠç€ºãããŠããããR2Mgããã³ããããš
ä»éå±ååç©ãšã®é¯äœã®ãã¹ãŠãå å«ãããã®ã§
ãããäžèšåŒäžã®R1ãªããR9ã§è¡šããããçå
æ°ŽçŽ åºã¯ãã¢ã«ãã«åºãã·ã¯ãã¢ã«ãã«åºãŸãã¯
ã¢ãªãŒã«åºã§ãããããšãã°ãã¡ãã«ããšãã«ã
ãããã«ãããã«ãã¢ãã«ãããã·ã«ããã·ã«ã
ã·ã¯ãããã·ã«ãããšãã«åºçãæããããç¹ã«
R1ã¯ã¢ã«ãã«åºã§ããããšã奜ãŸããããŸãã
R3ãªããR8ã¯æ°ŽçŽ ååã§ããããšã劚ããªãã éçŽ ååïŒãšããŠã¯ãåšæåŸè¡šç¬¬æãªãã第
æã«å±ããéå±å çŽ ã䜿çšã§ããããšãã°ãã
ããªãŠã ãã«ãªãŠã ãã«ã«ã·ãŠã ãããªãªãŠã ã
äºéãããªãŠã ãããŠçŽ ãã¢ã«ãããŠã ããªããŠ
ã çãæããããããç¹ã«ã¢ã«ãããŠã ãäºéã
ããŠçŽ ãããªãªãŠã ããªããŠã ãçåæ°ŽçŽ å¯æº¶æ§
ææ©ãã°ãã·ãŠã é¯äœãäœãæããæ®ã«å¥œãŸã
ããéå±ååïŒã«å¯Ÿãããã°ãã·ãŠã ã®æ¯Î²ïŒÎ±
ã¯ãä»»æã«èšå®å¯èœã§ãããã奜ãŸããã¯ïŒã
10ãç¹ã«0.5ã10ã®ç¯å²ã®çåæ°ŽçŽ å¯æº¶æ§ã®ææ©
ãã°ãã·ãŠã é¯äœãæ®ã«å¥œãŸããã èšå·Î±ïŒÎ²ïŒïœïŒïœïŒïœïŒïœã®é¢ä¿åŒïœïŒïœïŒ
ïœïŒïœïŒmαïŒ2βã¯ãéå±ååã®åå䟡ãšçœ®æåº
ãšã®ååŠéè«æ§ã瀺ãã奜ãŸããç¯å²ã§ããïŒâŠ
ïŒïœïŒïœïŒïŒïŒÎ±ïŒÎ²ïŒâŠ1.0ã¯ãéå±ååã®åã«
察ããšïŒ¹ã®åã®æ¯ãïŒä»¥äžã§1.0ããå°ã§ãã
ããšã瀺ããç¹ã«å¥œãŸããç¯å²ã¯ïŒã0.8ã§ããã ãããã®ææ©ãã°ãã·ãŠã ååç©ãããã¯ææ©
ãã°ãã·ãŠã é¯äœã¯ãäžè¬åŒRMgQïŒR2MgïŒïŒ²
ã¯åè¿°ã®æå³ã§ãããã¯ããã²ã³ã§ããïŒã§ç€º
ãããææ©ãã°ãã·ãŠã ååç©ãšãäžè¬åŒMRn
ãŸãã¯MRn-1ïŒïŒïŒïŒ²ïŒïœã¯åè¿°ã®æå³ã§ã
ãïŒã§ç€ºãããææ©éå±ååç©ãšãããããµã³ã
ããã¿ã³ãã·ã¯ããããµã³ããã³ãŒã³ããã«ãšã³
çã®äžæŽ»æ§çåæ°ŽçŽ åªäœäžã宀枩ã150âã®éã§
åå¿ãããå¿ èŠãªå Žåã«ã¯ç¶ããŠããããããã«
ã¢ã«ã³ãŒã«ãæ°Žãã·ãããµã³ãã¢ãã³ãã€ãã³ã
ã¡ã«ã«ãã¿ã³ãŸãã¯ãžããªååç©ãšåå¿ãããã
ãšã«ããåæããããããã«ææ©ãã°ãã·ãŠã å
åç©ãããã¯ææ©ãã°ãã·ãŠã é¯äœã¯MgX2ïŒ
RMgXãšMRnïŒMRn-1ããŸãã¯RMgXïŒ
MgR2ãšRoMXn-oããŸãã¯RMgXïŒMgR2ãšYo
MXn-oïŒåŒäžãïŒïŒïŒ²ïŒïŒžïŒïŒ¹ã¯åè¿°ã®ãšããã§
ãã€ãŠãïŒïŒ¹ãããã²ã³ã§ããå Žåãå«ã¿ãïœ
ã¯ïŒãïœã®æ°ã§ããïŒãšã®åå¿ã«ããåæããã
ãšãã§ããã äžè¬ã«ã¯ææ©ãã°ãã·ãŠã ååç©ã¯äžæŽ»æ§çå
æ°ŽçŽ åªäœã«äžæº¶æ§ã§ãããαïŒïŒã§ãããšããã®
ææ©ãã°ãã·ãŠã é¯äœã¯å¯æº¶æ§ã§ããã ãŸããαïŒïŒã§ãããçš®ã®ææ©ãã°ãã·ãŠã å
åç©ãããšãã°secâBu2Mgçã¯çåæ°ŽçŽ åªäœã«
å¯æº¶æ§ã§ããããã®ãããªååç©ãæ¬çºæã«çšã
ãŠå¥œãŸããçµæãäžãã以äžãããã®ææ©ãã°ã
ã·ãŠã ååç©ã«ã€ããŠèª¬æããã äžè¬åŒMgãR1 pR2 qXrYsã«ãããŠR1ïŒR2ã¯æ¬¡ã®äž
ã€ã®çŸ€ïŒïŒïŒïŒïŒïŒïŒïŒã®ããããäžã€ã§ãã
ãã®ãšããã () R1ïŒR2ã®å°ãªããšãäžæ¹ãççŽ ååæ°ïŒã
ïŒã§ããäºçŽãŸãã¯äžçŽã®ã¢ã«ãã«åºã§ããã
ãšã奜ãŸããã¯R1ïŒR2ããšãã«ççŽ ååæ°ïŒ
ãïŒã§ãããå°ãªããšãäžæ¹ãäºçŽãŸãã¯äžçŽ
ã®ã¢ã«ãã«åºã§ããããšã () R1ãšR2ãšã®ççŽ ååæ°ã®äºãã«çžç°ãªãã¢
ã«ãã«åºã§ããããšã奜ãŸããã¯R4ãççŽ æ°
ïŒãŸãã¯ïŒã®ã¢ã«ãã«åºã§ãããR2ãççŽ æ°
ïŒä»¥äžã®ã¢ã«ãã«åºã§ããããšã () R1ïŒR2ã®å°ãªããšãäžæ¹ãççŽ ååæ°ïŒä»¥
äžã®çåæ°ŽçŽ åºã§ããããšã奜ãŸããã¯ãR1ïŒ
R2ããšãã«ççŽ ååæ°ïŒä»¥äžã®ã¢ã«ãã«åºã§
ããããšã 以äžããããã®åºãå ·äœçã«ç€ºããïŒïŒã«ã
ããŠççŽ ååæ°ïŒãïŒã§ããäºçŽãŸãã¯äžçŽã®ã¢
ã«ãã«åºãšããŠã¯ãsecâC4H9ïŒtertâC4H9ã
ãåŒã
ãåŒã
ãåŒãçãçšãããã
奜ãŸããã¯äºçŽã®ã¢ã«ãã«åºã§ãããsecâC4H9
ã¯ç¹ã«å¥œãŸããã次ã«ãïŒïŒã«ãããŠççŽ æ°ïŒ
ãŸãã¯ïŒã®ã¢ã«ãã«åºãšããŠã¯ãšãã«åºãããã
ã«åºãæãããããšãã«åºã¯ç¹ã«å¥œãŸããããŸã
ççŽ æ°ïŒä»¥äžã®ã¢ã«ãã«åºãšããŠã¯ããã«åºãã¢
ãã«åºãããã·ã«åºããªã¯ãã«åºçãæãããã
ããã«åºãããã·ã«åºã¯ç¹ã«å¥œãŸãããïŒïŒã«
ãããŠççŽ ååæ°ïŒä»¥äžã®çåæ°ŽçŽ åºãšããŠã¯ã
ãã·ã«åºããªã¯ãã«åºããã·ã«åºãããšãã«åºç
ãæããããã¢ã«ãã«åºã§ããæ¹ã奜ãŸãããã
ãã·ã«åºã¯ç¹ã«å¥œãŸããã æ¬çºæã«çšããããææ©ãã°ãã·ãŠã ååç©
ã¯ãçåæ°ŽçŽ åªäœäžã«å¯æº¶ã§ããããšãéèŠã§ã
ããã¢ã«ãã«åºã®ççŽ ååæ°ãå¢ããšçåæ°ŽçŽ åª
äœã«æº¶ãæããªããã溶液ã®ç²æ§ãé«ããªãåŸå
ã§ãããå¿ èŠä»¥äžã«é·éã®ã¢ã«ãã«åºãçšããã
ãšã¯åæ±ãäžå¥œãŸãããªãã ãªããäžèšææ©ãã°ãã·ãŠã ååç©ã¯çåæ°ŽçŽ
溶液ãšããŠçšãããããã該溶液äžã«åŸ®éã®ãšãŒ
ãã«ããšã¹ãã«ãã¢ãã³çã®ã³ã³ãã¬ãã¯ã¹åå€
ããããã«å«æãããããã¯æ®åããŠããŠãå·®æ¯
ããªãçšããããšãã§ãããææ©ãã°ãã·ãŠã æ
åãšããŠææ©ãã°ãã·ãŠã ãã©ã€ããçšããããš
ãå¯èœã§ããã åèšäžè¬åŒäžãαïŒïŒïŒÎ²ïŒïŒïŒïœïŒïŒïŒïœïŒ
ïŒãªãææ©ãã°ãã·ãŠã ãã©ã€ãã«ã€ããŠèª¬æã
ãã ãã®ååç©ã¯ãããããã°ãªãã€ãŒååç©ã§ã
ããäžè¬ã«ãã°ãã·ãŠã ããšãŒãã«æº¶æ¶²äžã®ææ©
ããã²ã³åç©ã«åå¿ãããããšã«ãã€ãŠåæãã
ãããšãŒãã«ã®äžååšäžã«ãããŠãçåæ°ŽçŽ åªè³ª
äžã§ãã®åå¿ãè¡ãããããšãç¥ãããŠãããã©
ã¡ãã䜿çšããããšãã§ããã ãããã®äŸãšããŠã¯ãããšãã°ãã¡ãã«ãã°ã
ã·ãŠã ã¯ããªããã¡ãã«ãã°ãã·ãŠã ããããã
ã¡ãã«ãã°ãã·ãŠã ã¢ã€ãªãã€ãããšãã«ãã°ã
ã·ãŠã ã¯ããªãããšãã«ãã°ãã·ãŠã ããããã
ãšãã«ãã°ãã·ãŠã ã¢ã€ãªãã€ããïœâãŸãã¯
isoâãããã«ãã°ãã·ãŠã ã¯ããªããïœâãŸã
ã¯isoâãããã«ãã°ãã·ãŠã ãããããïœâãŸ
ãã¯isoâãããã«ãã°ãã·ãŠã ã¢ã€ãªãã€ãã
ïœâããã«ãã°ãã·ãŠã ã¯ããªããïœâããã«ã
ã°ãã·ãŠã ãããããïœâããã«ãã°ãã·ãŠã ã¢
ã€ãªãã€ããisoâãsecâãããã¯tertâããã«
ãã°ãã·ãŠã ã¯ããªããisoâãsecâãããã¯
tertâããã«ãã°ãã·ãŠã ãããããisoâãsec
âãããã¯tertâããã«ãã°ãã·ãŠã ã¢ã€ãªãã€
ããïœâã¢ãã«ãã°ãã·ãŠã ã¯ããªããïœâã¢ã
ã«ãã°ãã·ãŠã ãããããããã·ã«ãã°ãã·ãŠã
ã¯ããªããããã·ã«ãã°ãã·ãŠã ããããããªã¯
ãã«ãã°ãã·ãŠã ã¯ããªããããšãã«ãã°ãã·ãŠ
ã ã¯ããªããããšãã«ãã°ãã·ãŠã ããããçã®
ååç©ããªãã³ã«ãããã®ãšãŒãã«é¯åäœãæã
ãããšãã§ããããããã®ãšãŒãã«ååç©ãšããŠ
ã¯ãããšãã°ããžã¡ãã«ãšãŒãã«ããžãšãã«ãšãŒ
ãã«ããžã€ãœãããã«ãšãŒãã«ããžããã«ãšãŒã
ã«ããžã¢ãªã«ãšãŒãã«ãããã©ããããã©ã³ããž
ãªããµã³ãã¢ããœãŒã«çã®åçš®ã®ãšãŒãã«ååç©
ãæããããšãã§ããã çåæ°ŽçŽ å¯æº¶æ§ææ©ãã°ãã·ãŠã æå(a)ãšåå¿
ãããé»åäŸäžäœ(b)ã«ã€ããŠèª¬æããã äžè¬åŒRORâ²ã§è¡šãããããšãŒãã«ã«ã€ããŠ
ã¯ãããã³Râ²ãèèªæãè³éŠæããã³èç°åŒ
çåæ°ŽçŽ åºã§ãããããšãã°ãã¡ãã«ããšãã«ã
ãããã«ãããã«ãã¢ãã«ãããã·ã«ããã·ã«ã
ãªã¯ãã«ãããã·ã«ãã·ã¯ãããã·ã«ãããšã
ã«ããã³ãžã«çã®çåæ°ŽçŽ åºã®å Žåãæããã
ãã ããªãšãŒãã«RSRâ²ã«ã€ããŠããããã³Râ²ã
èèªæãè³éŠæããã³èç°åŒçåæ°ŽçŽ ã§ãããã
ãšãã°ãã¡ãã«ããšãã«ããããã«ãããã«ãã¢
ãã«ãããã·ã«ãã·ã¯ãããã·ã«ãããšãã«çã®
çåæ°ŽçŽ åºã®å Žåãæããããã ã±ãã³RCORâ²ã«ã€ããŠã¯ãããã³Râ²ãèèª
æãè³éŠæããã³èç°åŒçåæ°ŽçŽ åºãããšãã°ã
ã¡ãã«ããšãã«ããããã«ãããã«ãã¢ãã«ãã
ãã·ã«ãã·ã¯ãããã·ã«ãããšãã«çãæããã
ãããç¹ã«ãžã¡ãã«ã±ãã³ããžãšãã«ãšãã³çã
奜ãŸããã ã¢ã«ãããã«ã€ããŠããèèªæãè³éŠæããã³
èç°åŒã¢ã«ããããçšããããã ã«ã«ãã³é žãŸãã¯ãã®èªå°äœãšããŠã¯ãã«ã«ã
ã³é žãã«ã«ãã³é žç¡æ°Žç©ãã«ã«ãã³é žãšã¹ãã«ã
ã«ã«ãã³é žããã²ã³åç©ãã«ã«ãã³é žã¢ãããçš
ããããã ã«ã«ãã³é žãšããŠã¯ãããšãã°ãã®é žãé ¢é žã
ããããªã³é žãé ªé žãåèé žãã·ãŠãŠé žãããã³
é žãã³ãã¯é žããã¬ã€ã³é žãã¢ã¯ãªã«é žãå®æ¯éŠ
é žããã«ã€ã«é žããã¬ãã¿ã«é žçãæããããã ã«ã«ãã³é žç¡æ°Žç©ãšããŠã¯ãããšãã°ãç¡æ°Žé ¢
é žãç¡æ°Žããããªã³é žãç¡æ°Žé ªé žãç¡æ°Žã³ãã¯
é žãç¡æ°Žãã¬ã€ã³é žãç¡æ°Žå®æ¯éŠé žãç¡æ°Žãã¿ã«
é žçãæããããã ã«ã«ãã³é žãšã¹ãã«ãšããŠã¯ãã®é žã¡ãã«ãã
ã³ãšãã«ãé ¢é žã¡ãã«ããšãã«ããããã«ããã
ããªã³é žã¡ãã«ããšãã«ããããã«ãããã«ãé ª
é žãšãã«ãåèé žãšãã«ãã«ããã³é žãšãã«ãïœ
âããã¿ã³é žãšãã«ãã·ãŠãŠé žãžããã«ãã³ãã¯
é žãšãã«ãããã³é žãšãã«ããã¬ã€ã³é žãžãã
ã«ãã¢ã¯ãªã«é žã¡ãã«ãã¢ã¯ãªã«é žãšãã«ãã¡ã¿
ã¯ãªã«é žã¡ãã«ãå®æ¯éŠé žã¡ãã«ããšãã«ããã
ãã«ãããã«ããã«ã€ã«é žã¡ãã«ããšãã«ããã
ãã«ãããã«ãã¢ãã«ãïœâãšãã«å®æ¯éŠé žã¡ã
ã«ããã³ãšãã«ãã¢ãã¹é žã¡ãã«ããšãã«ããã
ãã«ããã³ããã«ãïœâãšããã·å®æ¯éŠé žã¡ã
ã«ããšãã«ãæããããã ã«ã«ãã³é žããã²ã³åç©ãšããŠã¯å¡©é žåç©ã奜
ãŸãããå¡©åã¢ã»ãã«ãå¡©åããããªãã«ãå¡©å
ãããªã«ãå¡©åã¹ã¯ã·ãã«ãå¡©åãã³ãŸã€ã«ãå¡©
åãã«ã€ã«ãæããããã ã«ã«ãã³é žã¢ãããšããŠã¯ããžã¡ãã«ãã«ã ã¢
ããããžã¡ãã«ã¢ã»ãã¢ããããžã¡ãã«ããããª
ã³ã¢ããçãæããããã ã¢ã«ã³ãŒã«ãšããŠã¯ãã¡ãã«ã¢ã«ã³ãŒã«ããšã
ã«ã¢ã«ã³ãŒã«ããããã«ã¢ã«ã³ãŒã«ãããã«ã¢ã«
ã³ãŒã«ãã¢ãã«ã¢ã«ã³ãŒã«ãããã·ã«ã¢ã«ã³ãŒ
ã«ãããšããŒã«ãã¯ã¬ãŸãŒã«çãæãããããã
secâãããã«ã¢ã«ã³ãŒã«ãsecâããã«ã¢ã«ã³ãŒ
ã«ãtertâããã«ã¢ã«ã³ãŒã«ãsecâã¢ãã«ã¢ã«
ã³ãŒã«ãtertâã¢ãã«ã¢ã«ã³ãŒã«ãsecâããã·
ã«ã¢ã«ã³ãŒã«ãããšããŒã«ãïœïŒïœïŒïœâã¯ã¬ãŸ
ãŒã«çã®äºçŽãäžçŽãªããè³éŠæã¢ã«ã³ãŒã«ã奜
ãŸããã ããªã¢ã«ã³ãŒã«ãšããŠã¯ãã¡ãã«ã¡ã«ã«ãã¿
ã³ããšãã«ã¡ã«ã«ãã¿ã³ããããã«ã¡ã«ã«ãã¿
ã³ãããã«ã¡ã«ã«ãã¿ã³ãã¢ãã«ã¡ã«ã«ãã¿ã³ã
ããã·ã«ã¡ã«ã«ãã¿ã³ãããšãã«ã¡ã«ã«ãã¿ã³ç
ãæããããããäºçŽãäžçŽãªããè³éŠæããªã¢
ã«ã³ãŒã«ã奜ãŸããã ã¢ãã³ãšããŠã¯ãèèªæãèç°åŒãªããè³éŠæ
ã¢ãã³ãæããããããäºçŽãªããäžçŽã¢ãã³ã
ããšãã°ãããªã¢ã«ãã«ã¢ãã³ãããªããšãã«ã¢
ãã³ãããªãžã³çã奜ãŸããçµæãäžããã çåæ°ŽçŽ å¯æº¶æ§ææ©ãã°ãã·ãŠã æåãšé»åäŸ
äžäœã®åå¿ã«ã€ããŠã¯ãåå¿ãäžæŽ»æ§åå¿åªäœã
ããšãã°ããããµã³ãããã¿ã³ã®åŠãèèªæçå
æ°ŽçŽ ããã³ãŒã³ããã«ãšã³ããã·ã¬ã³çã®è³éŠæ
çåæ°ŽçŽ ãã·ã¯ããããµã³ãã¡ãã«ã·ã¯ããããµ
ã³çã®èç°åŒçåæ°ŽçŽ ãããã¯ãããã®æ··å溶åª
äžã§è¡ãããšãã§ãããåå¿é åºã«ã€ããŠã¯ãæ
æ©ãã°ãã·ãŠã æåäžã«é»åäŸäžäœãå ããŠãã
æ¹æ³ïŒïŒãé»åäŸäžäœäžã«ææ©ãã°ãã·ãŠã æ
åãå ããŠããæ¹æ³ïŒïŒãäž¡è ãåæã«å ããŠ
ããæ¹æ³ïŒïŒãçšããããšãã§ããã çåæ°ŽçŽ å¯æº¶æ§ææ©ãã°ãã·ãŠã æåãšé»åäŸ
äžäœã®åå¿æ¯çã«ã€ããŠã¯ãææ©ãã°ãã·ãŠã æ
åïŒã¢ã«ã«ã€ããŠãé»åäŸäžäœïŒã¢ã«ä»¥äžã奜ãŸ
ããã¯0.05ã0.8ã¢ã«ã§ããã 次ã«ãäžè¬åŒHaSiClbR10 4-(a+b)ïŒåŒäžãïœïŒïœïŒ
R10ã¯åè¿°ã®æå³ã§ããïŒã§ç€ºãããSiâçµå
å«æã¯ãã«ã·ã©ã³ååç©ã«ã€ããŠèª¬æããã äžèšåŒã«ãããŠR10ã§è¡šããããçåæ°ŽçŽ åº
ã¯ãèèªæçåæ°ŽçŽ åºãèç°åŒçåæ°ŽçŽ åºãè³éŠ
æçåæ°ŽçŽ åºã§ãããããšãã°ãã¡ãã«ããšã
ã«ããããã«ãããã«ãã¢ãã«ãããã·ã«ããã·
ã«ãã·ã¯ãããã·ã«ãããšãã«åºçãæãããã
奜ãŸããã¯ççŽ æ°ïŒã10ã®ã¢ã«ãã«åºã§ãããã¡
ãã«ããšãã«ããããã«çã®äœçŽã¢ã«ãã«åºãç¹
ã«å¥œãŸãããïœïŒïœã®å€ã¯ãïœïŒïœïŒïŒïŒïœïŒïœ
âŠïŒïŒïŒïŒïœâŠïŒã§ããã0.5âŠïœâŠ1.5ã奜ãŸã
ãã ãããã®ååç©ãšããŠã¯ãHSiCl3ïŒ
HSiCl2CH3ïŒHSiCl2C2H5ïŒHSiCl2nâC3H7ïŒ
HSiCl2iâC3H7ïŒHSiCl2nâC4H9ïŒHSiCl2C6H5ïŒ
HSiCl2ïŒïŒâClâC6H4ïŒïŒHSiCl2CHïŒCH2ïŒ
HSiCl2CH2C6H5ïŒHSiCl2ïŒïœâC10H7ïŒïŒ
HSiCl2CH2CHïŒCH2ïŒH2SiClCH3ïŒ
H2SiClC2H5ïŒHSiClïŒCH3ïŒ2ïŒHSiClCH3ïŒïœâ
C3H7ïŒïŒHSiClCH3ïŒC6H5ïŒïŒHSiClïŒC2H5ïŒ2ïŒ
HSiClïŒC6H5ïŒ2çãæãããããããã®ååç©ã
ãã³ãããã®ååç©ããéžã°ããååç©ãšã®æ··å
ç©ãããªãã¯ãã«ã·ã©ã³ååç©ã䜿çšãããããª
ã¯ãã«ã·ã©ã³ãã¢ãã¡ãã«ãžã¯ãã«ã·ã©ã³ããžã¡
ãã«ã¯ãã«ã·ã©ã³ããšãã«ãžã¯ãã«ã·ã©ã³çã奜
ãŸãããããªã¯ãã«ã·ã©ã³ãã¢ãã¡ãã«ãžã¯ãã«
ã·ã©ã³ãç¹ã«å¥œãŸããã åŸè¿°ã®å®æœäŸããã³æ¯èŒäŸããæãããªåŠãã
Siâçµåãå«ãŸãªãã±ã€çŽ ååç©ã䜿çšããå Ž
åã奜ãŸããçµæã¯åŸãããªãã 以äžææ©ãã°ãã·ãŠã æå(i)ãšã¯ãã«ã·ã©ã³å
åç©(ii)ãšã®åå¿ã«ã€ããŠèª¬æããã ææ©ãã°ãã·ãŠã ååç©ãŸãã¯ææ©ãã°ãã·ãŠ
ã é¯äœãšã¯ãã«ã·ã©ã³ååç©ãšã®åå¿ã¯ãäžæŽ»æ§
åå¿åªäœãããšãã°ããããµã³ãããã¿ã³ã®åŠã
èèªæçåæ°ŽçŽ ããã³ãŒã³ããã«ãšã³ããã·ã¬ã³
ã®åŠãè³éŠæçåæ°ŽçŽ ãã·ã¯ããããµã³ãã¡ãã«
ã·ã¯ããããµã³ã®åŠãèç°åŒçåæ°ŽçŽ ããããã¯
ãšãŒãã«ãããã©ããããã©ã³çã®ãšãŒãã«ç³»åª
äœããããã¯ãããã®æ··ååªäœäžã§è¡ãªãããšã
ã§ããã觊åªæ§èœäžãèèªæçåæ°ŽçŽ åªäœã奜ãŸ
ãããåå¿æž©åºŠã¯20ã150âã§å®æœã§ããããå
å¿é²è¡äžã奜ãŸããã¯ã¯ãã«ã·ã©ã³ã®æ²žç¹ä»¥äžã
ããã¯40â以äžã§å®æœããããïŒçš®æåã®åå¿æ¯
çã«ãç¹ã«å¶éã¯ãªãããéåžžææ©ãã°ãã·ãŠã
æåïŒã¢ã«ã«å¯Ÿããã¯ãã«ã·ã©ã³0.01ã100ã¢ã«
ã§ããã奜ãŸããã¯ææ©ãã°ãã·ãŠã æåïŒã¢ã«
ã«å¯Ÿããã¯ãã«ã·ã©ã³æå0.1ã10ã¢ã«ãç¹ã«å¥œ
ãŸããã¯0.2ãïŒã¢ã«ã®ç¯å²ã§ããã åå¿æ¹æ³ã«ã€ããŠã¯ïŒçš®æåãåæã«åå¿åž¯ã«
å°å ¥ãã€ãåå¿ãããåææ·»å ã®æ¹æ³ïŒæ¹æ³âã€ïŒã
ãããã¯ã¯ãã«ã·ã©ã³æåãäºåã«åå¿åž¯ã«ä»èŸŒ
ãã åŸã«ãææ©ãã°ãã·ãŠã æåãåå¿åž¯ã«å°å ¥
ãã€ãåå¿ãããæ¹æ³ïŒæ¹æ³âãïŒããããã¯ææ©
ãã°ãã·ãŠã æåãäºåã«ä»èŸŒã¿ãã¯ãã«ã·ã©ã³
æåãæ·»å ããæ¹æ³ïŒæ¹æ³âãïŒãããããåŸïŒè
ã奜ãŸãããç¹ã«æ¹æ³âãã奜ãŸããçµæãäžã
ãã æå(i)ãš(ii)ã®åå¿ãç¡æ©æ äœã®ååšäžã«è¡ãã
ãšãã§ãããç¡æ©æ äœãšããŠã¯ãäžèšã®ãã®ãçš
ããããšãã§ããã (i) ç¡æ©é žåç© (ii) ç¡æ©çé žå¡©ãçªé žå¡©ãç¡«é žå¡© (iii) ç¡æ©æ°Žé žåç© (iv) (i)ãªãã(iii)ãããªãè€å¡©ãåºæº¶äœãªããæ··å
ç© ç¡æ©æ äœã®å ·äœäŸãšããŠã¯ãã·ãªã«ãã·ãªã«ã¢
ã«ãããæ°Žåã¢ã«ããããã°ãã·ã¢ãããªã¢ãã
ã¿ãã¢ããžã«ã³ãã¢ããªã³é žã«ã«ã·ãŠã ãç¡«é žã
ãªãŠã ãç¡«é žã«ã«ã·ãŠã ãçªé žãã°ãã·ãŠã ãã
ã°ãã·ãŠã ã»ã«ã«ã·ãŠã ãã¢ã«ãããŠã ã·ãªã±ãŒ
ããïŒMgã»CaïŒïŒ¯ã»Al2O3ã»5SiO2ã»nH2Oããçª
é žã«ãªãŠã ã»ã¢ã«ãããŠã ãK2Oã»Al2O3ã»
6SiO2ãããã€ã«ãK2Oã»3Al2O3â6SiO2ã»
2H2Oããçªé žãã°ãã·ãŠã éãïŒMgïŒ
FeïŒ2SiO4ããçªé žã¢ã«ãããŠã ïŒAl2O3ã»SiO2ïŒã
çé žã«ã«ã·ãŠã çãæããããããç¹ã«å¥œãŸãã
ã¯ãã·ãªã«ãªããã·ãªã«ã»ã¢ã«ããã奜ãŸããã
ç¡æ©æ äœã®æ¯è¡šé¢ç©ãã奜ãŸããã¯20m2ïŒïœä»¥
äžãç¹ã«å¥œãŸããã¯90m2ïŒïœä»¥äžã§ããã 次ã«åºäœãšåå¿ãããååç©(2)ã«ã€ããŠèª¬æã
ãã ã¢ã«ãããã«ã€ããŠã¯ãèèªæãèç°åŒããã³
è³éŠæã¢ã«ããããçšããããã¢ã»ãã¢ã«ãã
ããããããªã³ã¢ã«ããããããã«ã¢ã«ãããã
ãã¬ã«ã¢ã«ãããããããµã¢ã«ãããããªã¯ãã¢
ã«ããããã¢ãã¢ã«ã¢ãããããã³ãã¢ã«ããã
çãçšããããšãã§ããã ã·ã©ããŒã«ãšããŠã¯ãããªã¡ãã«ã·ã©ããŒã«ã
ããªãšãã«ã·ã©ããŒã«ãããªãããã«ã·ã©ããŒ
ã«ãããªããã«ã·ã©ããŒã«ãããªããšãã«ã·ã©ã
ãŒã«çã®ä»ãã¯ãã«ã·ã©ã³ã®å æ°Žå解ç©ãããªã·
ã©ããŒã«çãæããããã ãã€ãããžãšã³ã·ãããµã³ãšããŠã¯ãã¡ãã«ã
ã€ããã·ãããµã³
ã¯ç¹ã«å¥œãŸããã次ã«ãïŒïŒã«ãããŠççŽ æ°ïŒ
ãŸãã¯ïŒã®ã¢ã«ãã«åºãšããŠã¯ãšãã«åºãããã
ã«åºãæãããããšãã«åºã¯ç¹ã«å¥œãŸããããŸã
ççŽ æ°ïŒä»¥äžã®ã¢ã«ãã«åºãšããŠã¯ããã«åºãã¢
ãã«åºãããã·ã«åºããªã¯ãã«åºçãæãããã
ããã«åºãããã·ã«åºã¯ç¹ã«å¥œãŸãããïŒïŒã«
ãããŠççŽ ååæ°ïŒä»¥äžã®çåæ°ŽçŽ åºãšããŠã¯ã
ãã·ã«åºããªã¯ãã«åºããã·ã«åºãããšãã«åºç
ãæããããã¢ã«ãã«åºã§ããæ¹ã奜ãŸãããã
ãã·ã«åºã¯ç¹ã«å¥œãŸããã æ¬çºæã«çšããããææ©ãã°ãã·ãŠã ååç©
ã¯ãçåæ°ŽçŽ åªäœäžã«å¯æº¶ã§ããããšãéèŠã§ã
ããã¢ã«ãã«åºã®ççŽ ååæ°ãå¢ããšçåæ°ŽçŽ åª
äœã«æº¶ãæããªããã溶液ã®ç²æ§ãé«ããªãåŸå
ã§ãããå¿ èŠä»¥äžã«é·éã®ã¢ã«ãã«åºãçšããã
ãšã¯åæ±ãäžå¥œãŸãããªãã ãªããäžèšææ©ãã°ãã·ãŠã ååç©ã¯çåæ°ŽçŽ
溶液ãšããŠçšãããããã該溶液äžã«åŸ®éã®ãšãŒ
ãã«ããšã¹ãã«ãã¢ãã³çã®ã³ã³ãã¬ãã¯ã¹åå€
ããããã«å«æãããããã¯æ®åããŠããŠãå·®æ¯
ããªãçšããããšãã§ãããææ©ãã°ãã·ãŠã æ
åãšããŠææ©ãã°ãã·ãŠã ãã©ã€ããçšããããš
ãå¯èœã§ããã åèšäžè¬åŒäžãαïŒïŒïŒÎ²ïŒïŒïŒïœïŒïŒïŒïœïŒ
ïŒãªãææ©ãã°ãã·ãŠã ãã©ã€ãã«ã€ããŠèª¬æã
ãã ãã®ååç©ã¯ãããããã°ãªãã€ãŒååç©ã§ã
ããäžè¬ã«ãã°ãã·ãŠã ããšãŒãã«æº¶æ¶²äžã®ææ©
ããã²ã³åç©ã«åå¿ãããããšã«ãã€ãŠåæãã
ãããšãŒãã«ã®äžååšäžã«ãããŠãçåæ°ŽçŽ åªè³ª
äžã§ãã®åå¿ãè¡ãããããšãç¥ãããŠãããã©
ã¡ãã䜿çšããããšãã§ããã ãããã®äŸãšããŠã¯ãããšãã°ãã¡ãã«ãã°ã
ã·ãŠã ã¯ããªããã¡ãã«ãã°ãã·ãŠã ããããã
ã¡ãã«ãã°ãã·ãŠã ã¢ã€ãªãã€ãããšãã«ãã°ã
ã·ãŠã ã¯ããªãããšãã«ãã°ãã·ãŠã ããããã
ãšãã«ãã°ãã·ãŠã ã¢ã€ãªãã€ããïœâãŸãã¯
isoâãããã«ãã°ãã·ãŠã ã¯ããªããïœâãŸã
ã¯isoâãããã«ãã°ãã·ãŠã ãããããïœâãŸ
ãã¯isoâãããã«ãã°ãã·ãŠã ã¢ã€ãªãã€ãã
ïœâããã«ãã°ãã·ãŠã ã¯ããªããïœâããã«ã
ã°ãã·ãŠã ãããããïœâããã«ãã°ãã·ãŠã ã¢
ã€ãªãã€ããisoâãsecâãããã¯tertâããã«
ãã°ãã·ãŠã ã¯ããªããisoâãsecâãããã¯
tertâããã«ãã°ãã·ãŠã ãããããisoâãsec
âãããã¯tertâããã«ãã°ãã·ãŠã ã¢ã€ãªãã€
ããïœâã¢ãã«ãã°ãã·ãŠã ã¯ããªããïœâã¢ã
ã«ãã°ãã·ãŠã ãããããããã·ã«ãã°ãã·ãŠã
ã¯ããªããããã·ã«ãã°ãã·ãŠã ããããããªã¯
ãã«ãã°ãã·ãŠã ã¯ããªããããšãã«ãã°ãã·ãŠ
ã ã¯ããªããããšãã«ãã°ãã·ãŠã ããããçã®
ååç©ããªãã³ã«ãããã®ãšãŒãã«é¯åäœãæã
ãããšãã§ããããããã®ãšãŒãã«ååç©ãšããŠ
ã¯ãããšãã°ããžã¡ãã«ãšãŒãã«ããžãšãã«ãšãŒ
ãã«ããžã€ãœãããã«ãšãŒãã«ããžããã«ãšãŒã
ã«ããžã¢ãªã«ãšãŒãã«ãããã©ããããã©ã³ããž
ãªããµã³ãã¢ããœãŒã«çã®åçš®ã®ãšãŒãã«ååç©
ãæããããšãã§ããã çåæ°ŽçŽ å¯æº¶æ§ææ©ãã°ãã·ãŠã æå(a)ãšåå¿
ãããé»åäŸäžäœ(b)ã«ã€ããŠèª¬æããã äžè¬åŒRORâ²ã§è¡šãããããšãŒãã«ã«ã€ããŠ
ã¯ãããã³Râ²ãèèªæãè³éŠæããã³èç°åŒ
çåæ°ŽçŽ åºã§ãããããšãã°ãã¡ãã«ããšãã«ã
ãããã«ãããã«ãã¢ãã«ãããã·ã«ããã·ã«ã
ãªã¯ãã«ãããã·ã«ãã·ã¯ãããã·ã«ãããšã
ã«ããã³ãžã«çã®çåæ°ŽçŽ åºã®å Žåãæããã
ãã ããªãšãŒãã«RSRâ²ã«ã€ããŠããããã³Râ²ã
èèªæãè³éŠæããã³èç°åŒçåæ°ŽçŽ ã§ãããã
ãšãã°ãã¡ãã«ããšãã«ããããã«ãããã«ãã¢
ãã«ãããã·ã«ãã·ã¯ãããã·ã«ãããšãã«çã®
çåæ°ŽçŽ åºã®å Žåãæããããã ã±ãã³RCORâ²ã«ã€ããŠã¯ãããã³Râ²ãèèª
æãè³éŠæããã³èç°åŒçåæ°ŽçŽ åºãããšãã°ã
ã¡ãã«ããšãã«ããããã«ãããã«ãã¢ãã«ãã
ãã·ã«ãã·ã¯ãããã·ã«ãããšãã«çãæããã
ãããç¹ã«ãžã¡ãã«ã±ãã³ããžãšãã«ãšãã³çã
奜ãŸããã ã¢ã«ãããã«ã€ããŠããèèªæãè³éŠæããã³
èç°åŒã¢ã«ããããçšããããã ã«ã«ãã³é žãŸãã¯ãã®èªå°äœãšããŠã¯ãã«ã«ã
ã³é žãã«ã«ãã³é žç¡æ°Žç©ãã«ã«ãã³é žãšã¹ãã«ã
ã«ã«ãã³é žããã²ã³åç©ãã«ã«ãã³é žã¢ãããçš
ããããã ã«ã«ãã³é žãšããŠã¯ãããšãã°ãã®é žãé ¢é žã
ããããªã³é žãé ªé žãåèé žãã·ãŠãŠé žãããã³
é žãã³ãã¯é žããã¬ã€ã³é žãã¢ã¯ãªã«é žãå®æ¯éŠ
é žããã«ã€ã«é žããã¬ãã¿ã«é žçãæããããã ã«ã«ãã³é žç¡æ°Žç©ãšããŠã¯ãããšãã°ãç¡æ°Žé ¢
é žãç¡æ°Žããããªã³é žãç¡æ°Žé ªé žãç¡æ°Žã³ãã¯
é žãç¡æ°Žãã¬ã€ã³é žãç¡æ°Žå®æ¯éŠé žãç¡æ°Žãã¿ã«
é žçãæããããã ã«ã«ãã³é žãšã¹ãã«ãšããŠã¯ãã®é žã¡ãã«ãã
ã³ãšãã«ãé ¢é žã¡ãã«ããšãã«ããããã«ããã
ããªã³é žã¡ãã«ããšãã«ããããã«ãããã«ãé ª
é žãšãã«ãåèé žãšãã«ãã«ããã³é žãšãã«ãïœ
âããã¿ã³é žãšãã«ãã·ãŠãŠé žãžããã«ãã³ãã¯
é žãšãã«ãããã³é žãšãã«ããã¬ã€ã³é žãžãã
ã«ãã¢ã¯ãªã«é žã¡ãã«ãã¢ã¯ãªã«é žãšãã«ãã¡ã¿
ã¯ãªã«é žã¡ãã«ãå®æ¯éŠé žã¡ãã«ããšãã«ããã
ãã«ãããã«ããã«ã€ã«é žã¡ãã«ããšãã«ããã
ãã«ãããã«ãã¢ãã«ãïœâãšãã«å®æ¯éŠé žã¡ã
ã«ããã³ãšãã«ãã¢ãã¹é žã¡ãã«ããšãã«ããã
ãã«ããã³ããã«ãïœâãšããã·å®æ¯éŠé žã¡ã
ã«ããšãã«ãæããããã ã«ã«ãã³é žããã²ã³åç©ãšããŠã¯å¡©é žåç©ã奜
ãŸãããå¡©åã¢ã»ãã«ãå¡©åããããªãã«ãå¡©å
ãããªã«ãå¡©åã¹ã¯ã·ãã«ãå¡©åãã³ãŸã€ã«ãå¡©
åãã«ã€ã«ãæããããã ã«ã«ãã³é žã¢ãããšããŠã¯ããžã¡ãã«ãã«ã ã¢
ããããžã¡ãã«ã¢ã»ãã¢ããããžã¡ãã«ããããª
ã³ã¢ããçãæããããã ã¢ã«ã³ãŒã«ãšããŠã¯ãã¡ãã«ã¢ã«ã³ãŒã«ããšã
ã«ã¢ã«ã³ãŒã«ããããã«ã¢ã«ã³ãŒã«ãããã«ã¢ã«
ã³ãŒã«ãã¢ãã«ã¢ã«ã³ãŒã«ãããã·ã«ã¢ã«ã³ãŒ
ã«ãããšããŒã«ãã¯ã¬ãŸãŒã«çãæãããããã
secâãããã«ã¢ã«ã³ãŒã«ãsecâããã«ã¢ã«ã³ãŒ
ã«ãtertâããã«ã¢ã«ã³ãŒã«ãsecâã¢ãã«ã¢ã«
ã³ãŒã«ãtertâã¢ãã«ã¢ã«ã³ãŒã«ãsecâããã·
ã«ã¢ã«ã³ãŒã«ãããšããŒã«ãïœïŒïœïŒïœâã¯ã¬ãŸ
ãŒã«çã®äºçŽãäžçŽãªããè³éŠæã¢ã«ã³ãŒã«ã奜
ãŸããã ããªã¢ã«ã³ãŒã«ãšããŠã¯ãã¡ãã«ã¡ã«ã«ãã¿
ã³ããšãã«ã¡ã«ã«ãã¿ã³ããããã«ã¡ã«ã«ãã¿
ã³ãããã«ã¡ã«ã«ãã¿ã³ãã¢ãã«ã¡ã«ã«ãã¿ã³ã
ããã·ã«ã¡ã«ã«ãã¿ã³ãããšãã«ã¡ã«ã«ãã¿ã³ç
ãæããããããäºçŽãäžçŽãªããè³éŠæããªã¢
ã«ã³ãŒã«ã奜ãŸããã ã¢ãã³ãšããŠã¯ãèèªæãèç°åŒãªããè³éŠæ
ã¢ãã³ãæããããããäºçŽãªããäžçŽã¢ãã³ã
ããšãã°ãããªã¢ã«ãã«ã¢ãã³ãããªããšãã«ã¢
ãã³ãããªãžã³çã奜ãŸããçµæãäžããã çåæ°ŽçŽ å¯æº¶æ§ææ©ãã°ãã·ãŠã æåãšé»åäŸ
äžäœã®åå¿ã«ã€ããŠã¯ãåå¿ãäžæŽ»æ§åå¿åªäœã
ããšãã°ããããµã³ãããã¿ã³ã®åŠãèèªæçå
æ°ŽçŽ ããã³ãŒã³ããã«ãšã³ããã·ã¬ã³çã®è³éŠæ
çåæ°ŽçŽ ãã·ã¯ããããµã³ãã¡ãã«ã·ã¯ããããµ
ã³çã®èç°åŒçåæ°ŽçŽ ãããã¯ãããã®æ··å溶åª
äžã§è¡ãããšãã§ãããåå¿é åºã«ã€ããŠã¯ãæ
æ©ãã°ãã·ãŠã æåäžã«é»åäŸäžäœãå ããŠãã
æ¹æ³ïŒïŒãé»åäŸäžäœäžã«ææ©ãã°ãã·ãŠã æ
åãå ããŠããæ¹æ³ïŒïŒãäž¡è ãåæã«å ããŠ
ããæ¹æ³ïŒïŒãçšããããšãã§ããã çåæ°ŽçŽ å¯æº¶æ§ææ©ãã°ãã·ãŠã æåãšé»åäŸ
äžäœã®åå¿æ¯çã«ã€ããŠã¯ãææ©ãã°ãã·ãŠã æ
åïŒã¢ã«ã«ã€ããŠãé»åäŸäžäœïŒã¢ã«ä»¥äžã奜ãŸ
ããã¯0.05ã0.8ã¢ã«ã§ããã 次ã«ãäžè¬åŒHaSiClbR10 4-(a+b)ïŒåŒäžãïœïŒïœïŒ
R10ã¯åè¿°ã®æå³ã§ããïŒã§ç€ºãããSiâçµå
å«æã¯ãã«ã·ã©ã³ååç©ã«ã€ããŠèª¬æããã äžèšåŒã«ãããŠR10ã§è¡šããããçåæ°ŽçŽ åº
ã¯ãèèªæçåæ°ŽçŽ åºãèç°åŒçåæ°ŽçŽ åºãè³éŠ
æçåæ°ŽçŽ åºã§ãããããšãã°ãã¡ãã«ããšã
ã«ããããã«ãããã«ãã¢ãã«ãããã·ã«ããã·
ã«ãã·ã¯ãããã·ã«ãããšãã«åºçãæãããã
奜ãŸããã¯ççŽ æ°ïŒã10ã®ã¢ã«ãã«åºã§ãããã¡
ãã«ããšãã«ããããã«çã®äœçŽã¢ã«ãã«åºãç¹
ã«å¥œãŸãããïœïŒïœã®å€ã¯ãïœïŒïœïŒïŒïŒïœïŒïœ
âŠïŒïŒïŒïŒïœâŠïŒã§ããã0.5âŠïœâŠ1.5ã奜ãŸã
ãã ãããã®ååç©ãšããŠã¯ãHSiCl3ïŒ
HSiCl2CH3ïŒHSiCl2C2H5ïŒHSiCl2nâC3H7ïŒ
HSiCl2iâC3H7ïŒHSiCl2nâC4H9ïŒHSiCl2C6H5ïŒ
HSiCl2ïŒïŒâClâC6H4ïŒïŒHSiCl2CHïŒCH2ïŒ
HSiCl2CH2C6H5ïŒHSiCl2ïŒïœâC10H7ïŒïŒ
HSiCl2CH2CHïŒCH2ïŒH2SiClCH3ïŒ
H2SiClC2H5ïŒHSiClïŒCH3ïŒ2ïŒHSiClCH3ïŒïœâ
C3H7ïŒïŒHSiClCH3ïŒC6H5ïŒïŒHSiClïŒC2H5ïŒ2ïŒ
HSiClïŒC6H5ïŒ2çãæãããããããã®ååç©ã
ãã³ãããã®ååç©ããéžã°ããååç©ãšã®æ··å
ç©ãããªãã¯ãã«ã·ã©ã³ååç©ã䜿çšãããããª
ã¯ãã«ã·ã©ã³ãã¢ãã¡ãã«ãžã¯ãã«ã·ã©ã³ããžã¡
ãã«ã¯ãã«ã·ã©ã³ããšãã«ãžã¯ãã«ã·ã©ã³çã奜
ãŸãããããªã¯ãã«ã·ã©ã³ãã¢ãã¡ãã«ãžã¯ãã«
ã·ã©ã³ãç¹ã«å¥œãŸããã åŸè¿°ã®å®æœäŸããã³æ¯èŒäŸããæãããªåŠãã
Siâçµåãå«ãŸãªãã±ã€çŽ ååç©ã䜿çšããå Ž
åã奜ãŸããçµæã¯åŸãããªãã 以äžææ©ãã°ãã·ãŠã æå(i)ãšã¯ãã«ã·ã©ã³å
åç©(ii)ãšã®åå¿ã«ã€ããŠèª¬æããã ææ©ãã°ãã·ãŠã ååç©ãŸãã¯ææ©ãã°ãã·ãŠ
ã é¯äœãšã¯ãã«ã·ã©ã³ååç©ãšã®åå¿ã¯ãäžæŽ»æ§
åå¿åªäœãããšãã°ããããµã³ãããã¿ã³ã®åŠã
èèªæçåæ°ŽçŽ ããã³ãŒã³ããã«ãšã³ããã·ã¬ã³
ã®åŠãè³éŠæçåæ°ŽçŽ ãã·ã¯ããããµã³ãã¡ãã«
ã·ã¯ããããµã³ã®åŠãèç°åŒçåæ°ŽçŽ ããããã¯
ãšãŒãã«ãããã©ããããã©ã³çã®ãšãŒãã«ç³»åª
äœããããã¯ãããã®æ··ååªäœäžã§è¡ãªãããšã
ã§ããã觊åªæ§èœäžãèèªæçåæ°ŽçŽ åªäœã奜ãŸ
ãããåå¿æž©åºŠã¯20ã150âã§å®æœã§ããããå
å¿é²è¡äžã奜ãŸããã¯ã¯ãã«ã·ã©ã³ã®æ²žç¹ä»¥äžã
ããã¯40â以äžã§å®æœããããïŒçš®æåã®åå¿æ¯
çã«ãç¹ã«å¶éã¯ãªãããéåžžææ©ãã°ãã·ãŠã
æåïŒã¢ã«ã«å¯Ÿããã¯ãã«ã·ã©ã³0.01ã100ã¢ã«
ã§ããã奜ãŸããã¯ææ©ãã°ãã·ãŠã æåïŒã¢ã«
ã«å¯Ÿããã¯ãã«ã·ã©ã³æå0.1ã10ã¢ã«ãç¹ã«å¥œ
ãŸããã¯0.2ãïŒã¢ã«ã®ç¯å²ã§ããã åå¿æ¹æ³ã«ã€ããŠã¯ïŒçš®æåãåæã«åå¿åž¯ã«
å°å ¥ãã€ãåå¿ãããåææ·»å ã®æ¹æ³ïŒæ¹æ³âã€ïŒã
ãããã¯ã¯ãã«ã·ã©ã³æåãäºåã«åå¿åž¯ã«ä»èŸŒ
ãã åŸã«ãææ©ãã°ãã·ãŠã æåãåå¿åž¯ã«å°å ¥
ãã€ãåå¿ãããæ¹æ³ïŒæ¹æ³âãïŒããããã¯ææ©
ãã°ãã·ãŠã æåãäºåã«ä»èŸŒã¿ãã¯ãã«ã·ã©ã³
æåãæ·»å ããæ¹æ³ïŒæ¹æ³âãïŒãããããåŸïŒè
ã奜ãŸãããç¹ã«æ¹æ³âãã奜ãŸããçµæãäžã
ãã æå(i)ãš(ii)ã®åå¿ãç¡æ©æ äœã®ååšäžã«è¡ãã
ãšãã§ãããç¡æ©æ äœãšããŠã¯ãäžèšã®ãã®ãçš
ããããšãã§ããã (i) ç¡æ©é žåç© (ii) ç¡æ©çé žå¡©ãçªé žå¡©ãç¡«é žå¡© (iii) ç¡æ©æ°Žé žåç© (iv) (i)ãªãã(iii)ãããªãè€å¡©ãåºæº¶äœãªããæ··å
ç© ç¡æ©æ äœã®å ·äœäŸãšããŠã¯ãã·ãªã«ãã·ãªã«ã¢
ã«ãããæ°Žåã¢ã«ããããã°ãã·ã¢ãããªã¢ãã
ã¿ãã¢ããžã«ã³ãã¢ããªã³é žã«ã«ã·ãŠã ãç¡«é žã
ãªãŠã ãç¡«é žã«ã«ã·ãŠã ãçªé žãã°ãã·ãŠã ãã
ã°ãã·ãŠã ã»ã«ã«ã·ãŠã ãã¢ã«ãããŠã ã·ãªã±ãŒ
ããïŒMgã»CaïŒïŒ¯ã»Al2O3ã»5SiO2ã»nH2Oããçª
é žã«ãªãŠã ã»ã¢ã«ãããŠã ãK2Oã»Al2O3ã»
6SiO2ãããã€ã«ãK2Oã»3Al2O3â6SiO2ã»
2H2Oããçªé žãã°ãã·ãŠã éãïŒMgïŒ
FeïŒ2SiO4ããçªé žã¢ã«ãããŠã ïŒAl2O3ã»SiO2ïŒã
çé žã«ã«ã·ãŠã çãæããããããç¹ã«å¥œãŸãã
ã¯ãã·ãªã«ãªããã·ãªã«ã»ã¢ã«ããã奜ãŸããã
ç¡æ©æ äœã®æ¯è¡šé¢ç©ãã奜ãŸããã¯20m2ïŒïœä»¥
äžãç¹ã«å¥œãŸããã¯90m2ïŒïœä»¥äžã§ããã 次ã«åºäœãšåå¿ãããååç©(2)ã«ã€ããŠèª¬æã
ãã ã¢ã«ãããã«ã€ããŠã¯ãèèªæãèç°åŒããã³
è³éŠæã¢ã«ããããçšããããã¢ã»ãã¢ã«ãã
ããããããªã³ã¢ã«ããããããã«ã¢ã«ãããã
ãã¬ã«ã¢ã«ãããããããµã¢ã«ãããããªã¯ãã¢
ã«ããããã¢ãã¢ã«ã¢ãããããã³ãã¢ã«ããã
çãçšããããšãã§ããã ã·ã©ããŒã«ãšããŠã¯ãããªã¡ãã«ã·ã©ããŒã«ã
ããªãšãã«ã·ã©ããŒã«ãããªãããã«ã·ã©ããŒ
ã«ãããªããã«ã·ã©ããŒã«ãããªããšãã«ã·ã©ã
ãŒã«çã®ä»ãã¯ãã«ã·ã©ã³ã®å æ°Žå解ç©ãããªã·
ã©ããŒã«çãæããããã ãã€ãããžãšã³ã·ãããµã³ãšããŠã¯ãã¡ãã«ã
ã€ããã·ãããµã³
ãåŒã
ãšãã«ãã€ããã·ãããµã³
ãåŒããããã«ãã€ãã
ã·ãããµã³
ãåŒãããã«
ãã€ããã·ãããµã³
ãåŒãããšãã«ãã€ãã
ã·ãããµã³
ãåŒãçãæ
ããããã
次ã«æå(2)ã®äœ¿çšéã¯ãæå(1)äžã«å«ãŸãã
âMgçµåïŒã¢ã«åœãã0.05ã20ã¢ã«ã§ããã奜
ãŸããã¯0.1ã10ã¢ã«ãç¹ã«å¥œãŸããã¯0.2ãïŒã¢
ã«ã§ããã ææ©ãã°ãã·ãŠã æåãšã¯ãã«ã·ã©ã³ååç©ã
åå¿ãããŠåŸãããåºäœç©è³ª(1)ãšæå(2)ã®åå¿ã«
ã€ããŠèª¬æããã åå¿ã¯ãäžæŽ»æ§åªäœã®ååšäžãŸãã¯éååšäžã«
ãããŠè¡ããäžæŽ»æ§åªäœãšããŠã¯ãåè¿°ã®èèª
æãè³éŠæãªããèç°åŒçåæ°ŽçŽ ã®ããããçšã
ãŠããããåå¿æã®æž©åºŠã¯ãç¹ã«å¶éã¯ãªããã
奜ãŸããã¯å®€æž©ãã200âã§å®æœããããåºäœ(1)
ãšæå(2)ãåå¿ãããæ¹æ³ã«ã€ããŠã¯ãæžæ¿ç¶æ
ïŒæµåç¶æ ïŒã®åºäœç©è³ª(1)ã«ãæå(2)ãå ããŠã
ãæ¹æ³ïŒïŒãæå(2)äžã«åºäœç©è³ªãå ããŠãã
æ¹æ³ïŒïŒãäž¡è ãåæã«æ·»å ããŠããæ¹æ³ïŒïŒ
çãèããããããæ¹æ³ïŒïŒãšïŒïŒã奜ãŸã
ããå°ãæå(2)ãåå¿ãããåŸããžã¢ã«ãã«ã¢ã«
ãããŠã ãã©ã€ãçã®é žã§åŠçããããšãå¯èœã§
ãããå°åºäœç©è³ª(1)ãæå(2)ãšåå¿ãããåŸãã
åºäœç©è³ªäžã«å«ãŸããçåæ°ŽçŽ åºå«æéã¯ãè¥å¹²
æžå°ããããå°äžå®éã®å«æéã瀺ãããšãéèŠ
ã§ããã æå(2)ãšåå¿ãããåºäœç©è³ªãšåå¿ããããã¿
ã³ååç©ããããžãŠã ååç©ããžã«ã³ããŠã åå
ç©ãããããŠã ååç©ã«ã€ããŠèª¬æããããã¿ã
ãŠã ããããžãŠã ããžã«ã³ããŠã ãããããŠã ã®
ããã²ã³åç©ããªãã·ããã²ã³åç©ãã¢ã«ã³ãã·
ããã²ã³åç©ãã¢ã«ã³ãã·ãããã³ãããã®æ··å
ç©ãçšããããã ãã¿ã³ååç©ãšããŠã¯ãäžè¬åŒTiïŒOR11ïŒ
sX4-sã§è¡šãããããã¿ã³ååç©ãçšããããã
åŒäžïœã¯ïŒâŠïœâŠïŒã®æ°ã§ãããR11ã§è¡šããã
ãççŽ æ°ïŒã20ã®çåæ°ŽçŽ åºãšããŠã¯ãã¡ãã«ã
ãšãã«ãïœããã³isoâãããã«ãïœâãisoâã
ãã³tertâããã«ãïœâïŒisoâïŒsecâããã³
tertâã¢ãã«ãneoâãã³ãã«ãããã·ã«ãïŒâ
ãšãã«ããã·ã«ããããã«ããªã¯ãã«ããã·ã«ã
ãŠã³ãã·ã«ãããã·ã«ãããªãã·ã«ãããã©ãã·
ã«ããããµãã·ã«ããªã¯ã¿ãã·ã«ãã¢ãªã«çã®è
èªæçåæ°ŽçŽ åºãã·ã¯ãããã·ã«ãïŒâã¡ãã«ã·
ã¯ãããã·ã«ãã·ã¯ããã³ãã«çã®èç°åŒçåæ°Ž
çŽ åºãããšãã«ãã¯ã¬ãžã«ããã·ãªã«ããããã«
çã®è³éŠæçåæ°ŽçŽ åºçãæããããããèèªæ
çåæ°ŽçŽ åºã奜ãŸãããäžèšããéžã°ãããã¿ã³
ååç©ããäºçš®ä»¥äžæ··åãã圢ã§çšããããšã¯å¯
èœã§ããã ã§è¡šããããããã²ã³ãšããŠã¯ãå¡©çŽ ãè
çŽ ããšãŠçŽ ãæããããããå¡©çŽ ã奜ãŸããã ãããžãŠã ååç©ãšããŠã¯ãVCl4ïŒVOCl3ïŒ
VOCl2ïŒOnâC4H9ïŒïŒVOClïŒOnâC4H9ïŒ2ïŒVO
ïŒOnâC4H9ïŒ3ïŒVCl3ïŒOC2H5ïŒçãçšãããã
VCl4ïŒVOCl3ã奜ãŸããã ãžã«ã³ããŠã ååç©ãšããŠã¯ãZrCl4ïŒZrïŒOn
âC4H9ïŒ4ïŒZrïŒOCH3ïŒ4ïŒZrïŒOC2H5ïŒ4ïŒZr
ïŒOiPrïŒ4ïŒZrïŒOnPrïŒ4ïŒZrOïŒCH3COOïŒ2çãçšã
ãããã ããããŠã ååç©ãšããŠã¯ãHfCl4ïŒHf
ïŒOnBuïŒ4ïŒHfïŒOPrïŒ4çãçšããããã åºäœç©è³ªãšãã¿ã³ååç©çã®åå¿ã¯äžæŽ»æ§åå¿
åªäœãçšãããããããã¯ãã¿ã³ååç©çãã®ã
ã®ãåå¿åªäœãšããŠçšãããäžæŽ»æ§åå¿åªäœãšã
ãŠã¯ããšãã°ããããµã³ãããã¿ã³ã®åŠãèèªæ
çåæ°ŽçŽ ããã³ãŒã³ããã«ãšã³çã®è³éŠæçåæ°Ž
çŽ ãã·ã¯ããããµã³ãã¡ãã«ã·ã¯ããããµã³çã®
èç°åŒçåæ°ŽçŽ çãæããããããèèªæçåæ°Ž
çŽ ã奜ãŸãããåå¿æž©åºŠã«ã€ããŠã¯ãç¹ã«å¶éã¯
ãªããã宀枩ãªãã150âã®ç¯å²ã§è¡ãã®ã奜ãŸ
ããã ãã¿ã³ååç©ããããžãŠã ååç©ããžã«ã³ããŠ
ã ååç©ãããããŠã ååç©ã®æ··åç©ãªããåå¿
ç©ã«ã€ããŠèª¬æããã æ··åç©ã«ã€ããŠã¯ããããããäºçš®ä»¥äžã®åå
ç©ãæ··åããŠãããããåºäœç©è³ªã®ååšäžãäºçš®
以äžã®ååç©ãæ··åããããšãã§ãããæ··åã¯ã
çåæ°ŽçŽ æº¶åªçã®äžæŽ»æ§æº¶åªäžã«åžéãã圢ã§è¡
ãããšã奜ãŸããããäºçš®ä»¥äžã®æåãã®ãã®ã
åªäœãšããŠçšããããšãã§ããã åå¿ç©ã«ã€ããŠã¯ããããããäºçš®ä»¥äžã®åå
ç©ããåå¿ãããŠçšããããåå¿ã¯ãäžæŽ»æ§çå
æ°ŽçŽ æº¶åªã®ååšäžãäžååšã«è¡ãããšãã§ããã
ããŒã«ãã«çã®ç²ç æ¹æ³ããçšããããšãå¯èœã§
ãããç²ç æ¹æ³ãšããŠã¯ãå転ããŒã«ãã«ãæ¯å
ããŒã«ãã«ãè¡æããŒã«ãã«çã®è¡ç¥ã®æ©æ¢°çç²
ç æ段ãæ¡çšããããšãã§ãããç²ç æéã¯0.5
ã100æéã奜ãŸããã¯ïŒã30æéãç²ç 枩床ã¯ã
ïŒã200âã奜ãŸããã¯10ã150âã§ããã ååºäœç©è³ªãšãã¿ã³ååç©ããããžãŠã ååç©
ãžã«ã³ããŠã ååç©ãããããŠã ååç©ã®åå¿æ
ãªãããåå¿ã®ååŸã«ãããŠææ©éå±ååç©ãå
ããããšãå¯èœã§ãããåºäœç©è³ªãšãã¿ã³ååç©
ãåå¿ãããéã«ååšãããææ©éå±ååç©ãšã
ãŠã¯ãææ©ã¢ã«ãããŠã ååç©ãææ©ãã°ãã·ãŠ
ã ååç©ãçšããããšãã§ãããææ©ã¢ã«ãããŠ
ã ååç©ãšããŠã¯ãäžè¬åŒAlR0 tZ3-tïŒåŒäžãR0ã¯
ççŽ æ°ïŒã10ã®çåæ°ŽçŽ åºãã¯ããã²ã³ããã€
ããã«ã«ãã«ãªãã·åºãã·ããã·åºãæ°ŽçŽ åºãã
éžã°ããåºã§ãã€ãŠãïœã¯ïŒâŠïœâŠïŒãªãæ°ãè¡š
ãããïŒã§è¡šããããææ©ã¢ã«ãããŠã ååç©ã
ãã³ããããéžã°ããææ©ã¢ã«ãããŠã ååç©ã®
æ··åç©ã»åå¿ç©ãçšããããšãã§ããã 奜ãŸããææ©ã¢ã«ãããŠã ååç©ãšããŠã¯ãã
ãªãšãã«ã¢ã«ãããŠã ãããªïœâãããã«ã¢ã«ã
ããŠã ãããªã€ãœãããã«ã¢ã«ãããŠã ãããªïœ
âããã«ã¢ã«ãããŠã ãããªïœâããã«ã¢ã«ãã
ãŠã ãããªããã·ã«ã¢ã«ãããŠã ãããªãªã¯ãã«
ã¢ã«ãããŠã ãããªãã·ã«ã¢ã«ãããŠã ãã€ãœã
ã¬ãã«ã¢ã«ãããŠã ããžãšãã«ã¢ã«ãããŠã ãã€
ãã©ã€ãããžã€ãœããã«ã¢ã«ãããŠã ãã€ãã©ã€
ãããžãšãã«ã¢ã«ãããŠã ã¯ãã©ã€ãããžâïœâ
ãããã«ã¢ã«ãããŠã ã¯ãã©ã€ãããžïœâããã
ã«ã¢ã«ãããŠã ã¯ãã©ã€ãããžã€ãœããã«ã¢ã«ã
ããŠã ã¯ãã©ã€ããã»ã¹ããšãã«ã¢ã«ãããŠã ã¯
ãã©ã€ããã»ã¹ãã€ãœããã«ã¢ã«ãããŠã ã¯ãã©
ã€ããã»ã¹ãâïœâãããã«ã¢ã«ãããŠã ã¯ãã©
ã€ããã»ã¹ãâïœâãããã«ã¢ã«ãããŠã ã¯ãã©
ã€ãããšãã«ã¢ã«ãããŠã ãžã¯ãã©ã€ããïœâã
ããã«ã¢ã«ãããŠã ãžã¯ãã©ã€ããïœâãããã«
ã¢ã«ãããŠã ãžã¯ãã©ã€ããããã«ã¢ã«ãããŠã
ãžã¯ãã©ã€ãããžãšãã«ã¢ã«ãããŠã ãããã€
ãããžãšãã«ã¢ã«ãããŠã ã¢ã€ãªãã€ãçããã³
ãããã®æ··åç©ãæããããã ããããŠåŸãããåºäœè§Šåªæåã¯ããããã
BETæ¯è¡šé¢ç©ã§ç€ºãããè¡šé¢ç©ãæ Œå¥å€§ããã
ãªã¬ãã€ã³ã®éå掻æ§ã倧ã§ãããåŸãããéå
äœã®ç²åæ§ç¶ãããããå ±éåæ§ã«ããããçã®
倧ããªç¹åŸŽãæããŠããã ãã®ç¹åŸŽãåŠäœãªãæ©æ§ã«ãããã®ã§ãããå®
ãã§ã¯ãªãããç¹å®ã®ææ©ãã°ãã·ãŠã æåãšïŒš
âSiâClçµåå«æã¯ãã«ã·ã©ã³ã®åå¿ã«ããåŸã
ãã掻æ§ææ©ãã°ãã·ãŠã å«æåºäœãçšããããš
ã«åºã¥ããã®ãšèããããã æ¬çºæã®åºäœè§Šåªã¯ããã®ãŸãã§ããªã¬ãã€ã³
éåçšè§ŠåªãšããŠæçšã§ããããææ©éå±ååç©
ãšçµåãããšã«ãããããã«åªãã觊åªãšãªãã
ææ©éå±ååç©ãšããŠã¯ãåšæåŸè¡šç¬¬ãæã®
ååç©ã§ãç¹ã«ææ©ã¢ã«ãããŠã ååç©ããã³æ
æ©ãã°ãã·ãŠã ãå«ãé¯äœã奜ãŸããã ææ©ã¢ã«ãããŠã ååç©ãšããŠã¯ãäžè¬åŒ
AlR10 tZ3-tïŒåŒäžãR10ã¯ççŽ ååæ°ïŒã20ã®çå
æ°ŽçŽ åºãã¯æ°ŽçŽ ãããã²ã³ãã¢ã«ã³ãã·ãã¢ãª
ããã·ãã·ããã·åºããéžã°ããåºã§ãããïœã¯
ïŒãïŒã®æ°ã§ããïŒã§ç€ºãããååç©ãåç¬ãŸã
ã¯æ··åç©ãšããŠçšãããäžèšåŒäžãR10ã§è¡šãã
ããççŽ ååæ°ïŒã20ã®çåæ°ŽçŽ åºã¯ãèèªæç
åæ°ŽçŽ ãè³éŠæçåæ°ŽçŽ ãèç°åŒçåæ°ŽçŽ ãå å«
ãããã®ã§ããã ãããã®ååç©ãå ·äœçã«ç€ºããšãããšãã°ã
ããªãšãã«ã¢ã«ãããŠã ãããªãã«ãã«ãããã«
ã¢ã«ãããŠã ãããªã€ãœãããã«ã¢ã«ãããŠã ã
ããªãã«ãã«ããã«ã¢ã«ãããŠã ãããªã€ãœãã
ã«ã¢ã«ãããŠã ãããªããã·ã«ã¢ã«ãããŠã ãã
ãªãªã¯ãã«ã¢ã«ãããŠã ãããªãã·ã«ã¢ã«ãããŠ
ã ãããªããã·ã«ã¢ã«ãããŠã ãããªãããµãã·
ã«ã¢ã«ãããŠã ããžãšãã«ã¢ã«ãããŠã ãã€ãã©
ã€ãããžã€ãœããã«ã¢ã«ãããŠã ãã€ãã©ã€ãã
ãžãšãã«ã¢ã«ãããŠã ãšããã·ãããžã€ãœããã«
ã¢ã«ãããŠã ãšããã·ãããžãªã¯ãã«ã¢ã«ãããŠ
ã ãããã·ãããžã€ãœããã«ã¢ã«ãããŠã ãªã¯ã
ã«ãªãã·ãããžãšãã«ã¢ã«ãããŠã ã¯ããªãããž
ã€ãœããã«ã¢ã«ãããŠã ã¯ããªãããžã¡ãã«ãã
ãã·ããã·ã¢ã«ãããŠã ãžã¡ãã«ããšãã«ã¡ãã«
ãããã·ããã·ã¢ã«ãããŠã ãžãšãã«ããšãã«ãž
ã¡ãã«ã·ããã·ã¢ã«ãããŠã ãžãšãã«ãã¢ã«ãã
ãŠã ã€ãœãã¬ãã«çãããã³ãããã®æ··åç©ãæš
奚ãããã ãããã®ã¢ã«ãã«ã¢ã«ãããŠã ååç©ãåèšã®
åºäœè§Šåªãšçµåãããšã«ãããé«æŽ»æ§ãªè§ŠåªãåŸ
ãããããç¹ã«ããªã¢ã«ãã«ã¢ã«ãããŠã ããžã¢
ã«ãã«ã¢ã«ãããŠã ãã€ãã©ã€ãã¯æãé«ã掻æ§
ãéæããããã奜ãŸããã ææ©ãã°ãã·ãŠã ãå«ãé¯äœãšããŠã¯ãåè¿°ã®
äžè¬åŒMãMgãR1 pR2 qXrYsã§ç€ºãããé¯äœã§ããã
αïŒÎ²ïŒïœïŒïœïŒïœïŒïœïŒïŒïŒR1ïŒR2ïŒïŒžïŒïŒ¹
ã«ã€ããŠã¯ãã§ã«è¿°ã¹ããšããã§ããããçåæ°Ž
çŽ å¯æº¶æ§é¯äœãæãŸãããããβïŒÎ±ã¯0.5ã10
ã奜ãŸããããŸãç¹ã«ïŒãã¢ã«ãããŠã ã§ããé¯
äœã奜ãŸããã åºäœè§Šåªæåãšææ©éå±ååç©ã¯ãéåæ¡ä»¶äž
ã«éåç³»å ã«æ·»å ããŠããããããããããéå
ã«å ç«ã€ãŠçµåããŠãããããŸãçµåããäž¡æå
ã®æ¯çã¯ãåºäœè§ŠåªïŒïœã«å¯Ÿãææ©éå±ååç©ã¯
ïŒã3000ããªã¢ã«ã®ç¯å²ã§è¡ãªãã®ã奜ãŸããã æ¬çºæã®è§ŠåªãçšããŠéåããããªã¬ãã€ã³ã¯
αãªã¬ãã€ã³ã§ãããç¹ã«ãšãã¬ã³ã§ããããã
ã«ãæ¬çºæã®è§Šåªã¯ãåè¿°ã®åŠãé»åäŸäžäœåŠç
ãçµåããããšã«ããããããã¬ã³ã®é«ç«äœèŠå
æ§éåã®ããã«çšããããšãã§ããããŸãããšã
ã¬ã³ãããã¯ãããã¬ã³ãããããã¬ã³ãããã³
âïŒããããµã³âïŒãªã©ã®ã¢ããªã¬ãã€ã³ããã
ã³ãã¿ãžãšã³ãã€ãœãã¬ã³ãªã©ã®ãžãšã³ã®å ±åäž
ã«éåãããããã«çšããããšãããã«ã¯ãžãšã³
ã®éåã«çšããããšãå¯èœã§ããã éåæ¹æ³ãšããŠã¯ãéåžžã®æžæ¿éåã溶液é
åãæ°çžéåãé«å§éåïŒ3000KgïŒcm2以äžçšåºŠïŒ
ãå¯èœã§ããã觊åªãéå溶åªãããšãã°ããã
ãµã³ãããã¿ã³ã®åŠãèèªæçåæ°ŽçŽ ããã³ãŒ
ã³ããã«ãšã³ããã·ã¬ã³ã®åŠãè³éŠæçåæ°ŽçŽ ã
ã·ã¯ããããµã³ãã¡ãã«ã·ã¯ããããµã³ã®åŠãè
ç°åŒçåæ°ŽçŽ ãšããã«åå¿åšã«å°å ¥ããäžæŽ»æ§é°
å²æ°äžã«ãšãã¬ã³ãããã¯ãããã¬ã³ãïŒã3000
KgïŒcm2ã«å§å ¥ããŠã宀枩ãªãã3000âã®æž©åºŠã§é
åãé²ããããšãå¯èœã§ããã æ¬çºæã®å®æœäŸã以äžã«ç€ºãããæ¬çºæã¯ãã
ããã®å®æœäŸã«ãã€ãŠäœãå¶éããããã®ã§ã¯ãª
ãããªããå®æœäŸäžã®MIã¯ã¡ã«ãã€ã³ããã¯ã¹
ãè¡šãããASTM â1238ã«ãã枩床190âã
è·é2.16Kgã®æ¡ä»¶äžã§æž¬å®ãããã®ã§ãããFR
ã¯æž©åºŠ190âãè·é21.6Kgã§æž¬å®ããå€ãMIã§é€
ããåãæå³ããååéååžã®å°ºåºŠã®ïŒã€ã§ã
ãã觊åªå¹çã¯é·ç§»éå±æåïŒïœã»ïŒæéã»ãšã
ã¬ã³ïŒãããã¯ãããã¬ã³ïŒå§åïŒKgïŒcm2åœãã®
ããªããŒçæéïœã§è¡šããããã å®æœäŸ ïŒ (1) ææ©ãã°ãã·ãŠã æåã®åæ 容éïŒã®ãã©ã¹ã³ã«ãçªçŽ é°å²æ°äžãéå±
ãã°ãã·ãŠã ç²æ«50ïœã秀åãããããã·ã¢ã«
ãããŠã ãžã¯ããªã20ïœmolãšïœâãªã¯ã¿ã³
300mlãå ãã100âã«ææž©ãããïœâããã«ã¯
ããªã1molãããã«ãããã1molããã³ïœâ
ãªã¯ã¿ã³0.7ãããªã溶液ããæ¹æäžçŽïŒæ
éã§æ»Žäžãã滎äžçµäºåŸãæŽã«ïŒæéæ¹æããŠ
åå¿ãç¶ãããåºäœéšåãæ¿Ÿå¥ãã濟液ã®åæ
ãè¡ã€ãçµæãMgæ¿åºŠã0.90molïŒãAlæ¿
床0.020molïŒã§ãã€ãããã®æ¿Ÿæ¶²400mlãïŒ
ã®ãã©ã¹ã³ã«ç§€åããïŒâã§æ¹æäžãïœâã
ãã«ã¢ã«ã³ãŒã«130ïœmolãæ·»å ããããã«30
âã§ïŒæéæ¹æãç¶ããŠåå¿ãããããã®åå¿
ã®åæãè¡ã€ãçµæAlMg6ïŒC2H5ïŒ3ïŒïœâ
C4H9ïŒ11ïŒOnâC4H9ïŒååç©æ¿åºŠã¯0.89molïŒ
ã§ãã€ãã (2) ã¯ãã«ã·ã©ã³ãšã®åå¿ã«ããåºäœç©è³ªã®åæ 滎äžããŒããšå·åŽåšãåãã容éïŒã®ãã©
ã¹ã³ãååã«è±æ°ã»ä¹Ÿç¥ããçªçŽ é°å²æ°äžã§ã
ãªã¯ãã«ã·ã©ã³ïŒHSiCl3ïŒ1molïŒã®ïœâã
ãã¿ã³æº¶æ¶²0.65molãä»èŸŒã¿ã50âã«ä¿ã¡ãªã
ãã滎äžããŒããããäžèšææ©ãã°ãã·ãŠã é¯
äœæº¶æ¶²0.5molãïŒæéãããŠæ»Žäžããããã«
50âã§ïŒæéæ¹æããªããåå¿ããããåŸçã«
ããïŒåæŽæ»ãè¡ããåºäœç©è³ªã¹ã©ãªãŒãåŸ
ãããã®åºäœãåé¢ã»ä¹Ÿç¥ããçµæãåºäœïŒïœ
åœããMg9.18ïœmolCl19.15ïœmolãSi1.73ïœ
molãã¢ã«ãã«åº0.60ïœmolãå«æããŠããã (3) åºäœè§Šåªã®åæ çªçŽ 眮æããèå§å®¹åšã«äžèšåºäœ20ïœãå«ã
ã¹ã©ãªãŒããããããªã³ã¢ã«ããã70ïœmolã
ïœâãããµã³ïŒãšãšãã«ãæ¹æäžã80âã§ïŒ
æéåå¿ãããåŸçã«ããäžæŸã¿ãé€å»ããã
ãã«300mlã®ïœâãããµã³ã§ïŒåæŽæ»ããã ãã®ã¹ã©ãªãŒã10âã«ä¿ã¡ãåå¡©åãã¿ã³20
ïœmolïŒ1MolïŒã®ãããµã³æº¶æ¶²ïŒããã³ãžãš
ãã«ã¢ã«ãããŠã ã¯ããªã20ïœmolïŒ1MolïŒ
ã®ãããµã³æº¶æ¶²ïŒãå°å ¥ãã30åéæ¹æäžåå¿
ãããŠåŸã60âã«ææž©ãïŒæéåå¿ãè¡ããå·
åŽåŸãåŸçã«ããäžæŸã¿ãé€å»ããããã«300
mlã®ïœâãããµã³ã§ïŒåæŽæ»ããããã«300ml
ã®ããã¿ã³ãå ãããïŒåºäœïŒïœäžã«å«ãŸãã
ãã¿ã³ã¯2.0ééïŒ ã§ãããçåæ°ŽçŽ åºã¯ã
0.47ïœmolã§ãã€ããïŒ (4) ãšãã¬ã³ã®éåïŒïŒ (3)ã§åæããåºäœè§ŠåªæåãããïŒmgãã
ã³ããªã€ãœããã«ã¢ã«ãããŠã 0.25ïœmolãã
è±æ°Žã»è±æ°ããïœâãããµã³800mlãšãšãã«ã
å éšãè±æ°Žã»è±æ°ãã1.5ãªãŒãã¯ã¬ãŒãŽã«
å°å ¥ããããã³âïŒ 120ïœmolãä»èŸŒã¿ãå
æž©ã80âã«ä¿ã¡ãæ°ŽçŽ ã1.6KgïŒcm2ã®å§åã§å
å§ãã次ã«ãšãã¬ã³ãå°å ¥ãå šå§ãïŒKgïŒcm2ãš
ããããšãã¬ã³ãè£çµŠããããšã«ãããå šå§ã
4.0KgïŒcm2ã®ã²ãŒãžå§ã«ä¿ã¡ã€ã€ãïŒæééå
ãè¡ããéåäœ167ïœãåŸãã觊åªå¹çã¯ã
1670KgâPEïŒïœâTiãMIã¯0.80ïœïŒ10minã§
ãã€ããéåäœç²æ«ã¯åµ©å¯åºŠã0.48ïœïŒcm3ã§ã
ãã105ã149ÎŒã®ç²æ«ã85ééïŒ ä»¥äžã§ãã€
ãã (5) ãšãã¬ã³ã®éåïŒïŒã (3)ã§åæããåºäœè§ŠåªããïŒmgãšããªãšã
ã«ã¢ã«ãããŠã 0.1ïœmolãšãè±æ°Žã»è±æ°ãã
ã·ã¯ããããµã³800mlãšãšãã«ãå éšãè±æ°ã»
也ç¥ãã1.5ãªãŒãã¯ã¬ãŒãã«å°å ¥ããã次
ã«æ°ŽçŽ ïŒïœmolãšãïŒâãªã¯ãã³800ïœmolã
ä»èŸŒãã åŸããªãŒãã¯ã¬ãŒãŽã180âã«ææž©ãã
ãšãã¬ã³ãå°å ¥ãå šå§ã19KgïŒcm2ã®ã²ãŒãžå§ã«
ä¿ã¡ã€ã€ã20åééåãè¡ãã115ïœã®éåäœ
ãåŸãã 觊åªå¹ç 719KgâPEïŒïœâTi MI 0.76ïœïŒ10min FR 30 å¯ åºŠ 0.924ïœïŒcm3 (6) ãšãã¬ã³ã®éåïŒïŒ 容é50ã®ã¹ãã³ã¬ã¹è£œæµååºãªãŒãã¯ã¬ãŒ
ãŽãçšããŠãæ°çžã§ãšãã¬ã³ãéåããã80â
ã«èª¿ç¯ãããªãŒãã¯ã¬ãŒãŽã«ã(3)ã§åæããåº
äœè§ŠåªæåããTiã«ããŠ30mgãšããªãšãã«ã¢
ã«ãããŠã 15ïœmolãã(4)ã§åŸãããªãšãã¬ã³
50ïœãšãšãã«ä»èŸŒã¿ããšãã¬ã³ïŒããã³âïŒïŒ
æ°ŽçŽ ã®ã¢ã«æ¯ãïŒïŒ0.25ïŒ0.02ã®çµæã®ã¬ã¹ã
15cmïŒsecã®é床ã§ãªãŒãã¯ã¬ãŒãã«å°å ¥ãã€
ã€ã10KgïŒcm2ã®ã²ãŒãžå§ã§ïŒæééåãè¡ãã
嵩å¯åºŠ0.44ïœïŒcm2ã®ç²æ«672ïœãåŸãã 觊åªå¹ç 1040ïœâPEïŒïœâTi MI 1.05ïœïŒ10min å¯ åºŠ 0.923ïœïŒcm3 (7) ãšãã¬ã³ã®éåïŒïŒ æ¹ææ©ä»ãªãŒãã¯ã¬ãŒãåé£ç¶éååå¿åšäž
ã«(3)ã§åæããåºäœè§ŠåªãTiã«ããŠ0.05ïœmol
ãšããªãšãã«ã¢ã«ãããŠã ïŒïœmolããïœâã
ããµã³250mlã«åæ£ãããé«å§ãã³ãã§æ¹ææ©
ä»ãªãŒãã¯ã¬ãŒãã«æ³šå ¥ããè¡šïŒã®æ¡ä»¶ã«ä¿
ã¡ãæ°ŽçŽ ã0.2ã¢ã«ïŒ å«æãããšãã¬ã³ãè£çµŠ
ããŠãè¡šïŒã®æ¡ä»¶ã§éåãè¡ãè¡šïŒã®çµæãåŸ
ãã
âMgçµåïŒã¢ã«åœãã0.05ã20ã¢ã«ã§ããã奜
ãŸããã¯0.1ã10ã¢ã«ãç¹ã«å¥œãŸããã¯0.2ãïŒã¢
ã«ã§ããã ææ©ãã°ãã·ãŠã æåãšã¯ãã«ã·ã©ã³ååç©ã
åå¿ãããŠåŸãããåºäœç©è³ª(1)ãšæå(2)ã®åå¿ã«
ã€ããŠèª¬æããã åå¿ã¯ãäžæŽ»æ§åªäœã®ååšäžãŸãã¯éååšäžã«
ãããŠè¡ããäžæŽ»æ§åªäœãšããŠã¯ãåè¿°ã®èèª
æãè³éŠæãªããèç°åŒçåæ°ŽçŽ ã®ããããçšã
ãŠããããåå¿æã®æž©åºŠã¯ãç¹ã«å¶éã¯ãªããã
奜ãŸããã¯å®€æž©ãã200âã§å®æœããããåºäœ(1)
ãšæå(2)ãåå¿ãããæ¹æ³ã«ã€ããŠã¯ãæžæ¿ç¶æ
ïŒæµåç¶æ ïŒã®åºäœç©è³ª(1)ã«ãæå(2)ãå ããŠã
ãæ¹æ³ïŒïŒãæå(2)äžã«åºäœç©è³ªãå ããŠãã
æ¹æ³ïŒïŒãäž¡è ãåæã«æ·»å ããŠããæ¹æ³ïŒïŒ
çãèããããããæ¹æ³ïŒïŒãšïŒïŒã奜ãŸã
ããå°ãæå(2)ãåå¿ãããåŸããžã¢ã«ãã«ã¢ã«
ãããŠã ãã©ã€ãçã®é žã§åŠçããããšãå¯èœã§
ãããå°åºäœç©è³ª(1)ãæå(2)ãšåå¿ãããåŸãã
åºäœç©è³ªäžã«å«ãŸããçåæ°ŽçŽ åºå«æéã¯ãè¥å¹²
æžå°ããããå°äžå®éã®å«æéã瀺ãããšãéèŠ
ã§ããã æå(2)ãšåå¿ãããåºäœç©è³ªãšåå¿ããããã¿
ã³ååç©ããããžãŠã ååç©ããžã«ã³ããŠã åå
ç©ãããããŠã ååç©ã«ã€ããŠèª¬æããããã¿ã
ãŠã ããããžãŠã ããžã«ã³ããŠã ãããããŠã ã®
ããã²ã³åç©ããªãã·ããã²ã³åç©ãã¢ã«ã³ãã·
ããã²ã³åç©ãã¢ã«ã³ãã·ãããã³ãããã®æ··å
ç©ãçšããããã ãã¿ã³ååç©ãšããŠã¯ãäžè¬åŒTiïŒOR11ïŒ
sX4-sã§è¡šãããããã¿ã³ååç©ãçšããããã
åŒäžïœã¯ïŒâŠïœâŠïŒã®æ°ã§ãããR11ã§è¡šããã
ãççŽ æ°ïŒã20ã®çåæ°ŽçŽ åºãšããŠã¯ãã¡ãã«ã
ãšãã«ãïœããã³isoâãããã«ãïœâãisoâã
ãã³tertâããã«ãïœâïŒisoâïŒsecâããã³
tertâã¢ãã«ãneoâãã³ãã«ãããã·ã«ãïŒâ
ãšãã«ããã·ã«ããããã«ããªã¯ãã«ããã·ã«ã
ãŠã³ãã·ã«ãããã·ã«ãããªãã·ã«ãããã©ãã·
ã«ããããµãã·ã«ããªã¯ã¿ãã·ã«ãã¢ãªã«çã®è
èªæçåæ°ŽçŽ åºãã·ã¯ãããã·ã«ãïŒâã¡ãã«ã·
ã¯ãããã·ã«ãã·ã¯ããã³ãã«çã®èç°åŒçåæ°Ž
çŽ åºãããšãã«ãã¯ã¬ãžã«ããã·ãªã«ããããã«
çã®è³éŠæçåæ°ŽçŽ åºçãæããããããèèªæ
çåæ°ŽçŽ åºã奜ãŸãããäžèšããéžã°ãããã¿ã³
ååç©ããäºçš®ä»¥äžæ··åãã圢ã§çšããããšã¯å¯
èœã§ããã ã§è¡šããããããã²ã³ãšããŠã¯ãå¡©çŽ ãè
çŽ ããšãŠçŽ ãæããããããå¡©çŽ ã奜ãŸããã ãããžãŠã ååç©ãšããŠã¯ãVCl4ïŒVOCl3ïŒ
VOCl2ïŒOnâC4H9ïŒïŒVOClïŒOnâC4H9ïŒ2ïŒVO
ïŒOnâC4H9ïŒ3ïŒVCl3ïŒOC2H5ïŒçãçšãããã
VCl4ïŒVOCl3ã奜ãŸããã ãžã«ã³ããŠã ååç©ãšããŠã¯ãZrCl4ïŒZrïŒOn
âC4H9ïŒ4ïŒZrïŒOCH3ïŒ4ïŒZrïŒOC2H5ïŒ4ïŒZr
ïŒOiPrïŒ4ïŒZrïŒOnPrïŒ4ïŒZrOïŒCH3COOïŒ2çãçšã
ãããã ããããŠã ååç©ãšããŠã¯ãHfCl4ïŒHf
ïŒOnBuïŒ4ïŒHfïŒOPrïŒ4çãçšããããã åºäœç©è³ªãšãã¿ã³ååç©çã®åå¿ã¯äžæŽ»æ§åå¿
åªäœãçšãããããããã¯ãã¿ã³ååç©çãã®ã
ã®ãåå¿åªäœãšããŠçšãããäžæŽ»æ§åå¿åªäœãšã
ãŠã¯ããšãã°ããããµã³ãããã¿ã³ã®åŠãèèªæ
çåæ°ŽçŽ ããã³ãŒã³ããã«ãšã³çã®è³éŠæçåæ°Ž
çŽ ãã·ã¯ããããµã³ãã¡ãã«ã·ã¯ããããµã³çã®
èç°åŒçåæ°ŽçŽ çãæããããããèèªæçåæ°Ž
çŽ ã奜ãŸãããåå¿æž©åºŠã«ã€ããŠã¯ãç¹ã«å¶éã¯
ãªããã宀枩ãªãã150âã®ç¯å²ã§è¡ãã®ã奜ãŸ
ããã ãã¿ã³ååç©ããããžãŠã ååç©ããžã«ã³ããŠ
ã ååç©ãããããŠã ååç©ã®æ··åç©ãªããåå¿
ç©ã«ã€ããŠèª¬æããã æ··åç©ã«ã€ããŠã¯ããããããäºçš®ä»¥äžã®åå
ç©ãæ··åããŠãããããåºäœç©è³ªã®ååšäžãäºçš®
以äžã®ååç©ãæ··åããããšãã§ãããæ··åã¯ã
çåæ°ŽçŽ æº¶åªçã®äžæŽ»æ§æº¶åªäžã«åžéãã圢ã§è¡
ãããšã奜ãŸããããäºçš®ä»¥äžã®æåãã®ãã®ã
åªäœãšããŠçšããããšãã§ããã åå¿ç©ã«ã€ããŠã¯ããããããäºçš®ä»¥äžã®åå
ç©ããåå¿ãããŠçšããããåå¿ã¯ãäžæŽ»æ§çå
æ°ŽçŽ æº¶åªã®ååšäžãäžååšã«è¡ãããšãã§ããã
ããŒã«ãã«çã®ç²ç æ¹æ³ããçšããããšãå¯èœã§
ãããç²ç æ¹æ³ãšããŠã¯ãå転ããŒã«ãã«ãæ¯å
ããŒã«ãã«ãè¡æããŒã«ãã«çã®è¡ç¥ã®æ©æ¢°çç²
ç æ段ãæ¡çšããããšãã§ãããç²ç æéã¯0.5
ã100æéã奜ãŸããã¯ïŒã30æéãç²ç 枩床ã¯ã
ïŒã200âã奜ãŸããã¯10ã150âã§ããã ååºäœç©è³ªãšãã¿ã³ååç©ããããžãŠã ååç©
ãžã«ã³ããŠã ååç©ãããããŠã ååç©ã®åå¿æ
ãªãããåå¿ã®ååŸã«ãããŠææ©éå±ååç©ãå
ããããšãå¯èœã§ãããåºäœç©è³ªãšãã¿ã³ååç©
ãåå¿ãããéã«ååšãããææ©éå±ååç©ãšã
ãŠã¯ãææ©ã¢ã«ãããŠã ååç©ãææ©ãã°ãã·ãŠ
ã ååç©ãçšããããšãã§ãããææ©ã¢ã«ãããŠ
ã ååç©ãšããŠã¯ãäžè¬åŒAlR0 tZ3-tïŒåŒäžãR0ã¯
ççŽ æ°ïŒã10ã®çåæ°ŽçŽ åºãã¯ããã²ã³ããã€
ããã«ã«ãã«ãªãã·åºãã·ããã·åºãæ°ŽçŽ åºãã
éžã°ããåºã§ãã€ãŠãïœã¯ïŒâŠïœâŠïŒãªãæ°ãè¡š
ãããïŒã§è¡šããããææ©ã¢ã«ãããŠã ååç©ã
ãã³ããããéžã°ããææ©ã¢ã«ãããŠã ååç©ã®
æ··åç©ã»åå¿ç©ãçšããããšãã§ããã 奜ãŸããææ©ã¢ã«ãããŠã ååç©ãšããŠã¯ãã
ãªãšãã«ã¢ã«ãããŠã ãããªïœâãããã«ã¢ã«ã
ããŠã ãããªã€ãœãããã«ã¢ã«ãããŠã ãããªïœ
âããã«ã¢ã«ãããŠã ãããªïœâããã«ã¢ã«ãã
ãŠã ãããªããã·ã«ã¢ã«ãããŠã ãããªãªã¯ãã«
ã¢ã«ãããŠã ãããªãã·ã«ã¢ã«ãããŠã ãã€ãœã
ã¬ãã«ã¢ã«ãããŠã ããžãšãã«ã¢ã«ãããŠã ãã€
ãã©ã€ãããžã€ãœããã«ã¢ã«ãããŠã ãã€ãã©ã€
ãããžãšãã«ã¢ã«ãããŠã ã¯ãã©ã€ãããžâïœâ
ãããã«ã¢ã«ãããŠã ã¯ãã©ã€ãããžïœâããã
ã«ã¢ã«ãããŠã ã¯ãã©ã€ãããžã€ãœããã«ã¢ã«ã
ããŠã ã¯ãã©ã€ããã»ã¹ããšãã«ã¢ã«ãããŠã ã¯
ãã©ã€ããã»ã¹ãã€ãœããã«ã¢ã«ãããŠã ã¯ãã©
ã€ããã»ã¹ãâïœâãããã«ã¢ã«ãããŠã ã¯ãã©
ã€ããã»ã¹ãâïœâãããã«ã¢ã«ãããŠã ã¯ãã©
ã€ãããšãã«ã¢ã«ãããŠã ãžã¯ãã©ã€ããïœâã
ããã«ã¢ã«ãããŠã ãžã¯ãã©ã€ããïœâãããã«
ã¢ã«ãããŠã ãžã¯ãã©ã€ããããã«ã¢ã«ãããŠã
ãžã¯ãã©ã€ãããžãšãã«ã¢ã«ãããŠã ãããã€
ãããžãšãã«ã¢ã«ãããŠã ã¢ã€ãªãã€ãçããã³
ãããã®æ··åç©ãæããããã ããããŠåŸãããåºäœè§Šåªæåã¯ããããã
BETæ¯è¡šé¢ç©ã§ç€ºãããè¡šé¢ç©ãæ Œå¥å€§ããã
ãªã¬ãã€ã³ã®éå掻æ§ã倧ã§ãããåŸãããéå
äœã®ç²åæ§ç¶ãããããå ±éåæ§ã«ããããçã®
倧ããªç¹åŸŽãæããŠããã ãã®ç¹åŸŽãåŠäœãªãæ©æ§ã«ãããã®ã§ãããå®
ãã§ã¯ãªãããç¹å®ã®ææ©ãã°ãã·ãŠã æåãšïŒš
âSiâClçµåå«æã¯ãã«ã·ã©ã³ã®åå¿ã«ããåŸã
ãã掻æ§ææ©ãã°ãã·ãŠã å«æåºäœãçšããããš
ã«åºã¥ããã®ãšèããããã æ¬çºæã®åºäœè§Šåªã¯ããã®ãŸãã§ããªã¬ãã€ã³
éåçšè§ŠåªãšããŠæçšã§ããããææ©éå±ååç©
ãšçµåãããšã«ãããããã«åªãã觊åªãšãªãã
ææ©éå±ååç©ãšããŠã¯ãåšæåŸè¡šç¬¬ãæã®
ååç©ã§ãç¹ã«ææ©ã¢ã«ãããŠã ååç©ããã³æ
æ©ãã°ãã·ãŠã ãå«ãé¯äœã奜ãŸããã ææ©ã¢ã«ãããŠã ååç©ãšããŠã¯ãäžè¬åŒ
AlR10 tZ3-tïŒåŒäžãR10ã¯ççŽ ååæ°ïŒã20ã®çå
æ°ŽçŽ åºãã¯æ°ŽçŽ ãããã²ã³ãã¢ã«ã³ãã·ãã¢ãª
ããã·ãã·ããã·åºããéžã°ããåºã§ãããïœã¯
ïŒãïŒã®æ°ã§ããïŒã§ç€ºãããååç©ãåç¬ãŸã
ã¯æ··åç©ãšããŠçšãããäžèšåŒäžãR10ã§è¡šãã
ããççŽ ååæ°ïŒã20ã®çåæ°ŽçŽ åºã¯ãèèªæç
åæ°ŽçŽ ãè³éŠæçåæ°ŽçŽ ãèç°åŒçåæ°ŽçŽ ãå å«
ãããã®ã§ããã ãããã®ååç©ãå ·äœçã«ç€ºããšãããšãã°ã
ããªãšãã«ã¢ã«ãããŠã ãããªãã«ãã«ãããã«
ã¢ã«ãããŠã ãããªã€ãœãããã«ã¢ã«ãããŠã ã
ããªãã«ãã«ããã«ã¢ã«ãããŠã ãããªã€ãœãã
ã«ã¢ã«ãããŠã ãããªããã·ã«ã¢ã«ãããŠã ãã
ãªãªã¯ãã«ã¢ã«ãããŠã ãããªãã·ã«ã¢ã«ãããŠ
ã ãããªããã·ã«ã¢ã«ãããŠã ãããªãããµãã·
ã«ã¢ã«ãããŠã ããžãšãã«ã¢ã«ãããŠã ãã€ãã©
ã€ãããžã€ãœããã«ã¢ã«ãããŠã ãã€ãã©ã€ãã
ãžãšãã«ã¢ã«ãããŠã ãšããã·ãããžã€ãœããã«
ã¢ã«ãããŠã ãšããã·ãããžãªã¯ãã«ã¢ã«ãããŠ
ã ãããã·ãããžã€ãœããã«ã¢ã«ãããŠã ãªã¯ã
ã«ãªãã·ãããžãšãã«ã¢ã«ãããŠã ã¯ããªãããž
ã€ãœããã«ã¢ã«ãããŠã ã¯ããªãããžã¡ãã«ãã
ãã·ããã·ã¢ã«ãããŠã ãžã¡ãã«ããšãã«ã¡ãã«
ãããã·ããã·ã¢ã«ãããŠã ãžãšãã«ããšãã«ãž
ã¡ãã«ã·ããã·ã¢ã«ãããŠã ãžãšãã«ãã¢ã«ãã
ãŠã ã€ãœãã¬ãã«çãããã³ãããã®æ··åç©ãæš
奚ãããã ãããã®ã¢ã«ãã«ã¢ã«ãããŠã ååç©ãåèšã®
åºäœè§Šåªãšçµåãããšã«ãããé«æŽ»æ§ãªè§ŠåªãåŸ
ãããããç¹ã«ããªã¢ã«ãã«ã¢ã«ãããŠã ããžã¢
ã«ãã«ã¢ã«ãããŠã ãã€ãã©ã€ãã¯æãé«ã掻æ§
ãéæããããã奜ãŸããã ææ©ãã°ãã·ãŠã ãå«ãé¯äœãšããŠã¯ãåè¿°ã®
äžè¬åŒMãMgãR1 pR2 qXrYsã§ç€ºãããé¯äœã§ããã
αïŒÎ²ïŒïœïŒïœïŒïœïŒïœïŒïŒïŒR1ïŒR2ïŒïŒžïŒïŒ¹
ã«ã€ããŠã¯ãã§ã«è¿°ã¹ããšããã§ããããçåæ°Ž
çŽ å¯æº¶æ§é¯äœãæãŸãããããβïŒÎ±ã¯0.5ã10
ã奜ãŸããããŸãç¹ã«ïŒãã¢ã«ãããŠã ã§ããé¯
äœã奜ãŸããã åºäœè§Šåªæåãšææ©éå±ååç©ã¯ãéåæ¡ä»¶äž
ã«éåç³»å ã«æ·»å ããŠããããããããããéå
ã«å ç«ã€ãŠçµåããŠãããããŸãçµåããäž¡æå
ã®æ¯çã¯ãåºäœè§ŠåªïŒïœã«å¯Ÿãææ©éå±ååç©ã¯
ïŒã3000ããªã¢ã«ã®ç¯å²ã§è¡ãªãã®ã奜ãŸããã æ¬çºæã®è§ŠåªãçšããŠéåããããªã¬ãã€ã³ã¯
αãªã¬ãã€ã³ã§ãããç¹ã«ãšãã¬ã³ã§ããããã
ã«ãæ¬çºæã®è§Šåªã¯ãåè¿°ã®åŠãé»åäŸäžäœåŠç
ãçµåããããšã«ããããããã¬ã³ã®é«ç«äœèŠå
æ§éåã®ããã«çšããããšãã§ããããŸãããšã
ã¬ã³ãããã¯ãããã¬ã³ãããããã¬ã³ãããã³
âïŒããããµã³âïŒãªã©ã®ã¢ããªã¬ãã€ã³ããã
ã³ãã¿ãžãšã³ãã€ãœãã¬ã³ãªã©ã®ãžãšã³ã®å ±åäž
ã«éåãããããã«çšããããšãããã«ã¯ãžãšã³
ã®éåã«çšããããšãå¯èœã§ããã éåæ¹æ³ãšããŠã¯ãéåžžã®æžæ¿éåã溶液é
åãæ°çžéåãé«å§éåïŒ3000KgïŒcm2以äžçšåºŠïŒ
ãå¯èœã§ããã觊åªãéå溶åªãããšãã°ããã
ãµã³ãããã¿ã³ã®åŠãèèªæçåæ°ŽçŽ ããã³ãŒ
ã³ããã«ãšã³ããã·ã¬ã³ã®åŠãè³éŠæçåæ°ŽçŽ ã
ã·ã¯ããããµã³ãã¡ãã«ã·ã¯ããããµã³ã®åŠãè
ç°åŒçåæ°ŽçŽ ãšããã«åå¿åšã«å°å ¥ããäžæŽ»æ§é°
å²æ°äžã«ãšãã¬ã³ãããã¯ãããã¬ã³ãïŒã3000
KgïŒcm2ã«å§å ¥ããŠã宀枩ãªãã3000âã®æž©åºŠã§é
åãé²ããããšãå¯èœã§ããã æ¬çºæã®å®æœäŸã以äžã«ç€ºãããæ¬çºæã¯ãã
ããã®å®æœäŸã«ãã€ãŠäœãå¶éããããã®ã§ã¯ãª
ãããªããå®æœäŸäžã®MIã¯ã¡ã«ãã€ã³ããã¯ã¹
ãè¡šãããASTM â1238ã«ãã枩床190âã
è·é2.16Kgã®æ¡ä»¶äžã§æž¬å®ãããã®ã§ãããFR
ã¯æž©åºŠ190âãè·é21.6Kgã§æž¬å®ããå€ãMIã§é€
ããåãæå³ããååéååžã®å°ºåºŠã®ïŒã€ã§ã
ãã觊åªå¹çã¯é·ç§»éå±æåïŒïœã»ïŒæéã»ãšã
ã¬ã³ïŒãããã¯ãããã¬ã³ïŒå§åïŒKgïŒcm2åœãã®
ããªããŒçæéïœã§è¡šããããã å®æœäŸ ïŒ (1) ææ©ãã°ãã·ãŠã æåã®åæ 容éïŒã®ãã©ã¹ã³ã«ãçªçŽ é°å²æ°äžãéå±
ãã°ãã·ãŠã ç²æ«50ïœã秀åãããããã·ã¢ã«
ãããŠã ãžã¯ããªã20ïœmolãšïœâãªã¯ã¿ã³
300mlãå ãã100âã«ææž©ãããïœâããã«ã¯
ããªã1molãããã«ãããã1molããã³ïœâ
ãªã¯ã¿ã³0.7ãããªã溶液ããæ¹æäžçŽïŒæ
éã§æ»Žäžãã滎äžçµäºåŸãæŽã«ïŒæéæ¹æããŠ
åå¿ãç¶ãããåºäœéšåãæ¿Ÿå¥ãã濟液ã®åæ
ãè¡ã€ãçµæãMgæ¿åºŠã0.90molïŒãAlæ¿
床0.020molïŒã§ãã€ãããã®æ¿Ÿæ¶²400mlãïŒ
ã®ãã©ã¹ã³ã«ç§€åããïŒâã§æ¹æäžãïœâã
ãã«ã¢ã«ã³ãŒã«130ïœmolãæ·»å ããããã«30
âã§ïŒæéæ¹æãç¶ããŠåå¿ãããããã®åå¿
ã®åæãè¡ã€ãçµæAlMg6ïŒC2H5ïŒ3ïŒïœâ
C4H9ïŒ11ïŒOnâC4H9ïŒååç©æ¿åºŠã¯0.89molïŒ
ã§ãã€ãã (2) ã¯ãã«ã·ã©ã³ãšã®åå¿ã«ããåºäœç©è³ªã®åæ 滎äžããŒããšå·åŽåšãåãã容éïŒã®ãã©
ã¹ã³ãååã«è±æ°ã»ä¹Ÿç¥ããçªçŽ é°å²æ°äžã§ã
ãªã¯ãã«ã·ã©ã³ïŒHSiCl3ïŒ1molïŒã®ïœâã
ãã¿ã³æº¶æ¶²0.65molãä»èŸŒã¿ã50âã«ä¿ã¡ãªã
ãã滎äžããŒããããäžèšææ©ãã°ãã·ãŠã é¯
äœæº¶æ¶²0.5molãïŒæéãããŠæ»Žäžããããã«
50âã§ïŒæéæ¹æããªããåå¿ããããåŸçã«
ããïŒåæŽæ»ãè¡ããåºäœç©è³ªã¹ã©ãªãŒãåŸ
ãããã®åºäœãåé¢ã»ä¹Ÿç¥ããçµæãåºäœïŒïœ
åœããMg9.18ïœmolCl19.15ïœmolãSi1.73ïœ
molãã¢ã«ãã«åº0.60ïœmolãå«æããŠããã (3) åºäœè§Šåªã®åæ çªçŽ 眮æããèå§å®¹åšã«äžèšåºäœ20ïœãå«ã
ã¹ã©ãªãŒããããããªã³ã¢ã«ããã70ïœmolã
ïœâãããµã³ïŒãšãšãã«ãæ¹æäžã80âã§ïŒ
æéåå¿ãããåŸçã«ããäžæŸã¿ãé€å»ããã
ãã«300mlã®ïœâãããµã³ã§ïŒåæŽæ»ããã ãã®ã¹ã©ãªãŒã10âã«ä¿ã¡ãåå¡©åãã¿ã³20
ïœmolïŒ1MolïŒã®ãããµã³æº¶æ¶²ïŒããã³ãžãš
ãã«ã¢ã«ãããŠã ã¯ããªã20ïœmolïŒ1MolïŒ
ã®ãããµã³æº¶æ¶²ïŒãå°å ¥ãã30åéæ¹æäžåå¿
ãããŠåŸã60âã«ææž©ãïŒæéåå¿ãè¡ããå·
åŽåŸãåŸçã«ããäžæŸã¿ãé€å»ããããã«300
mlã®ïœâãããµã³ã§ïŒåæŽæ»ããããã«300ml
ã®ããã¿ã³ãå ãããïŒåºäœïŒïœäžã«å«ãŸãã
ãã¿ã³ã¯2.0ééïŒ ã§ãããçåæ°ŽçŽ åºã¯ã
0.47ïœmolã§ãã€ããïŒ (4) ãšãã¬ã³ã®éåïŒïŒ (3)ã§åæããåºäœè§ŠåªæåãããïŒmgãã
ã³ããªã€ãœããã«ã¢ã«ãããŠã 0.25ïœmolãã
è±æ°Žã»è±æ°ããïœâãããµã³800mlãšãšãã«ã
å éšãè±æ°Žã»è±æ°ãã1.5ãªãŒãã¯ã¬ãŒãŽã«
å°å ¥ããããã³âïŒ 120ïœmolãä»èŸŒã¿ãå
æž©ã80âã«ä¿ã¡ãæ°ŽçŽ ã1.6KgïŒcm2ã®å§åã§å
å§ãã次ã«ãšãã¬ã³ãå°å ¥ãå šå§ãïŒKgïŒcm2ãš
ããããšãã¬ã³ãè£çµŠããããšã«ãããå šå§ã
4.0KgïŒcm2ã®ã²ãŒãžå§ã«ä¿ã¡ã€ã€ãïŒæééå
ãè¡ããéåäœ167ïœãåŸãã觊åªå¹çã¯ã
1670KgâPEïŒïœâTiãMIã¯0.80ïœïŒ10minã§
ãã€ããéåäœç²æ«ã¯åµ©å¯åºŠã0.48ïœïŒcm3ã§ã
ãã105ã149ÎŒã®ç²æ«ã85ééïŒ ä»¥äžã§ãã€
ãã (5) ãšãã¬ã³ã®éåïŒïŒã (3)ã§åæããåºäœè§ŠåªããïŒmgãšããªãšã
ã«ã¢ã«ãããŠã 0.1ïœmolãšãè±æ°Žã»è±æ°ãã
ã·ã¯ããããµã³800mlãšãšãã«ãå éšãè±æ°ã»
也ç¥ãã1.5ãªãŒãã¯ã¬ãŒãã«å°å ¥ããã次
ã«æ°ŽçŽ ïŒïœmolãšãïŒâãªã¯ãã³800ïœmolã
ä»èŸŒãã åŸããªãŒãã¯ã¬ãŒãŽã180âã«ææž©ãã
ãšãã¬ã³ãå°å ¥ãå šå§ã19KgïŒcm2ã®ã²ãŒãžå§ã«
ä¿ã¡ã€ã€ã20åééåãè¡ãã115ïœã®éåäœ
ãåŸãã 觊åªå¹ç 719KgâPEïŒïœâTi MI 0.76ïœïŒ10min FR 30 å¯ åºŠ 0.924ïœïŒcm3 (6) ãšãã¬ã³ã®éåïŒïŒ 容é50ã®ã¹ãã³ã¬ã¹è£œæµååºãªãŒãã¯ã¬ãŒ
ãŽãçšããŠãæ°çžã§ãšãã¬ã³ãéåããã80â
ã«èª¿ç¯ãããªãŒãã¯ã¬ãŒãŽã«ã(3)ã§åæããåº
äœè§ŠåªæåããTiã«ããŠ30mgãšããªãšãã«ã¢
ã«ãããŠã 15ïœmolãã(4)ã§åŸãããªãšãã¬ã³
50ïœãšãšãã«ä»èŸŒã¿ããšãã¬ã³ïŒããã³âïŒïŒ
æ°ŽçŽ ã®ã¢ã«æ¯ãïŒïŒ0.25ïŒ0.02ã®çµæã®ã¬ã¹ã
15cmïŒsecã®é床ã§ãªãŒãã¯ã¬ãŒãã«å°å ¥ãã€
ã€ã10KgïŒcm2ã®ã²ãŒãžå§ã§ïŒæééåãè¡ãã
嵩å¯åºŠ0.44ïœïŒcm2ã®ç²æ«672ïœãåŸãã 觊åªå¹ç 1040ïœâPEïŒïœâTi MI 1.05ïœïŒ10min å¯ åºŠ 0.923ïœïŒcm3 (7) ãšãã¬ã³ã®éåïŒïŒ æ¹ææ©ä»ãªãŒãã¯ã¬ãŒãåé£ç¶éååå¿åšäž
ã«(3)ã§åæããåºäœè§ŠåªãTiã«ããŠ0.05ïœmol
ãšããªãšãã«ã¢ã«ãããŠã ïŒïœmolããïœâã
ããµã³250mlã«åæ£ãããé«å§ãã³ãã§æ¹ææ©
ä»ãªãŒãã¯ã¬ãŒãã«æ³šå ¥ããè¡šïŒã®æ¡ä»¶ã«ä¿
ã¡ãæ°ŽçŽ ã0.2ã¢ã«ïŒ å«æãããšãã¬ã³ãè£çµŠ
ããŠãè¡šïŒã®æ¡ä»¶ã§éåãè¡ãè¡šïŒã®çµæãåŸ
ãã
ãè¡šã
å®æœäŸ ïŒ
çªçŽ é°å²æ°äžãã¡ãã«ãžã¯ãã«ã·ã©ã³ã®ããã¿
ã³æº¶æ¶²ïŒ1molïŒïŒ300mlããã³ïœâããã¿ã³
200mlããã©ã¹ã³ã«ä»èŸŒã¿ã50âã«ææž©ããã次
ã«ææ©ãã°ãã·ãŠã æåã AlMg10ïŒC2H5ïŒ5ïŒïœâC8H17ïŒ7ïŒOC4H9ïŒ11250ïœ
molãå«æããããã¿ã³æº¶æ¶²500mlã50âã§ïŒæ
éãããŠæ»ŽäžããåŸãããã«ïŒæéæ¹æäžåå¿ã
ç¶ãããåå¿ç©ã¹ã©ãªãŒãåŸçã«ããïŒåæŽæ»ã
ãåŸãäžèšåºäœïŒïœãå«æããã¹ã©ãªãŒãããªã
ãšãã«ã·ã©ããŒã«ïŒïœmolãïœâãããµã³100ml
ãšãšãã«æ¹æäžã80âã§ïŒæéåå¿ãããåŸãåŸ
çã«ãããäžæŸã¿ãé€å»ããããã«100mlã®ïœâ
ãããµã³ã§ïŒåæŽæ»ããã ãã®ã¹ã©ãªãŒã50âã«ä¿ã¡ããžãšãã«ã¢ã«ãã
ãŠã ã¯ããªãïŒïœmolããã³ïœâãããµã³100ml
ãæ¹æäžå ããŠã60âã§ïŒæéåå¿ãããåŸçã«
ããäžæŸã¿ãé€å»ãã100mlã®ïœâãããµã³ã§ïŒ
åæŽæ»ãããã€ãã§ããžãšãã«ã¢ã«ãããŠã ã¯ã
ãªãïŒïœmolããã³åå¡©åãã¿ã³ïŒïœmolããã³
ïœâãããµã³100mlãå ã50âã§ïŒæéåå¿ãã
ãåŸãïœâãããµã³100mlã§ïŒåæŽæ»ããŠãåºäœ
觊åªæåãããåŸãã ãã®åºäœè§ŠåªæåãããçšããŠãå®æœäŸïŒâ
(4)ãšåæ§ã«ããŠããšãã¬ã³ã®ã¹ã©ãªãŒéåãè¡
ãã次ã®çµæãåŸãã 觊åªå¹ç 1215ïœâPEïŒïœâTi MI 1.0ïœïŒ10min 嵩å¯åºŠ 0.45ïœïŒcm3 105ã149ÎŒã®æ¯ç 88ïŒ ä»¥äž å®æœäŸ ïŒã11 å®æœäŸïŒã®åºäœè§Šåªã®åæããè¡šïŒã«ç€ºãæå
ãçšããŠè¡ããããããŠåŸãããåºäœè§Šåªæåã
é·ç§»éå±ååã«ããŠã0.002ïœmolãšããªãšãã«
ã¢ã«ãããŠã 0.25ïœmolããè±æ°Žã»è±æ°ããïœâ
ãããµã³800mlãšãšãã«å éšãè±æ°Žã»è±æ°ãã1.5
ãªãŒãã¯ã¬ãŒãã«å°å ¥ãã液åããã³â150ml
ãå°å ¥ããå æž©ã80âã«ä¿ã¡ãæ°ŽçŽ ã1.6KgïŒcm2
ã®å§åã§å å§ãã次ã«ãšãã¬ã³ãå°å ¥ããå šå§ã
ïŒKgïŒcm2ãšããããšãã¬ã³ãè£çµŠããããšã«ã
ããå šå§ãïŒKgïŒcm2ã®ã²ãŒãžå§ã«ä¿ã¡ã€ã€ãïŒæ
ééåãè¡ããè¡šïŒã®çµæãåŸãã
ã³æº¶æ¶²ïŒ1molïŒïŒ300mlããã³ïœâããã¿ã³
200mlããã©ã¹ã³ã«ä»èŸŒã¿ã50âã«ææž©ããã次
ã«ææ©ãã°ãã·ãŠã æåã AlMg10ïŒC2H5ïŒ5ïŒïœâC8H17ïŒ7ïŒOC4H9ïŒ11250ïœ
molãå«æããããã¿ã³æº¶æ¶²500mlã50âã§ïŒæ
éãããŠæ»ŽäžããåŸãããã«ïŒæéæ¹æäžåå¿ã
ç¶ãããåå¿ç©ã¹ã©ãªãŒãåŸçã«ããïŒåæŽæ»ã
ãåŸãäžèšåºäœïŒïœãå«æããã¹ã©ãªãŒãããªã
ãšãã«ã·ã©ããŒã«ïŒïœmolãïœâãããµã³100ml
ãšãšãã«æ¹æäžã80âã§ïŒæéåå¿ãããåŸãåŸ
çã«ãããäžæŸã¿ãé€å»ããããã«100mlã®ïœâ
ãããµã³ã§ïŒåæŽæ»ããã ãã®ã¹ã©ãªãŒã50âã«ä¿ã¡ããžãšãã«ã¢ã«ãã
ãŠã ã¯ããªãïŒïœmolããã³ïœâãããµã³100ml
ãæ¹æäžå ããŠã60âã§ïŒæéåå¿ãããåŸçã«
ããäžæŸã¿ãé€å»ãã100mlã®ïœâãããµã³ã§ïŒ
åæŽæ»ãããã€ãã§ããžãšãã«ã¢ã«ãããŠã ã¯ã
ãªãïŒïœmolããã³åå¡©åãã¿ã³ïŒïœmolããã³
ïœâãããµã³100mlãå ã50âã§ïŒæéåå¿ãã
ãåŸãïœâãããµã³100mlã§ïŒåæŽæ»ããŠãåºäœ
觊åªæåãããåŸãã ãã®åºäœè§ŠåªæåãããçšããŠãå®æœäŸïŒâ
(4)ãšåæ§ã«ããŠããšãã¬ã³ã®ã¹ã©ãªãŒéåãè¡
ãã次ã®çµæãåŸãã 觊åªå¹ç 1215ïœâPEïŒïœâTi MI 1.0ïœïŒ10min 嵩å¯åºŠ 0.45ïœïŒcm3 105ã149ÎŒã®æ¯ç 88ïŒ ä»¥äž å®æœäŸ ïŒã11 å®æœäŸïŒã®åºäœè§Šåªã®åæããè¡šïŒã«ç€ºãæå
ãçšããŠè¡ããããããŠåŸãããåºäœè§Šåªæåã
é·ç§»éå±ååã«ããŠã0.002ïœmolãšããªãšãã«
ã¢ã«ãããŠã 0.25ïœmolããè±æ°Žã»è±æ°ããïœâ
ãããµã³800mlãšãšãã«å éšãè±æ°Žã»è±æ°ãã1.5
ãªãŒãã¯ã¬ãŒãã«å°å ¥ãã液åããã³â150ml
ãå°å ¥ããå æž©ã80âã«ä¿ã¡ãæ°ŽçŽ ã1.6KgïŒcm2
ã®å§åã§å å§ãã次ã«ãšãã¬ã³ãå°å ¥ããå šå§ã
ïŒKgïŒcm2ãšããããšãã¬ã³ãè£çµŠããããšã«ã
ããå šå§ãïŒKgïŒcm2ã®ã²ãŒãžå§ã«ä¿ã¡ã€ã€ãïŒæ
ééåãè¡ããè¡šïŒã®çµæãåŸãã
ãè¡šã
ãè¡šã
å®æœäŸ 12ã17
ææ©MgæåLi0.06MgïŒC2H5ïŒ0.5ïŒïœâC4H9ïŒ0.5
OnâC4H9ïŒ10500mlãšã¡ãã«ãžã¯ãã«ã·ã©ã³250ïœ
molãšããªã¯ãã«ã·ã©ã³250ïœmolã®æ··åç©ãçš
ããŠåºäœç©è³ªãåæããããããªã³ã¢ã«ãããã«
代ããŠããããªã³ã¢ã«ããã250ïœmolããã³ã
ãããªã³ã¢ã«ããããžãšãã«ã¢ã»ã¿ãŒã«50ïœmol
ãçšããä»ã¯ãå šãŠå®æœäŸïŒãšåæ§ã«ããŠåºäœè§Š
åªã®åæãè¡ã€ãã ãã®åºäœãTiã«ããŠ0.20ïœmolãšããªãšãã«ã¢
ã«ãããŠã ïŒïœmolãïœâãããµã³800mlãçšã
ãŠã40âã§ãšãã¬ã³ãïŒïœäºåéåãããŠãåºäœ
觊åªæåããã¿ã³åå0.002ïœmolçžåœåããµã³
ããªã³ã°ããŠã1.5ã®ãªãŒãã¯ã¬ãŒãã«ã€ãœã
ã¿ã³800mlãšãšãã«å°å ¥ããããã«è¡šïŒã«ç€ºãã³
ã¢ãããŒãå°å ¥ãã80âã«ææž©ããæ°ŽçŽ ã9.5
KgïŒcm2ã®å§ã§å å§ãããšãã¬ã³ãå°å ¥ããŠ11.5
KgïŒcm2ã®å§ãšããïŒæééåãè¡ãè¡šïŒã®çµæã
åŸãã
OnâC4H9ïŒ10500mlãšã¡ãã«ãžã¯ãã«ã·ã©ã³250ïœ
molãšããªã¯ãã«ã·ã©ã³250ïœmolã®æ··åç©ãçš
ããŠåºäœç©è³ªãåæããããããªã³ã¢ã«ãããã«
代ããŠããããªã³ã¢ã«ããã250ïœmolããã³ã
ãããªã³ã¢ã«ããããžãšãã«ã¢ã»ã¿ãŒã«50ïœmol
ãçšããä»ã¯ãå šãŠå®æœäŸïŒãšåæ§ã«ããŠåºäœè§Š
åªã®åæãè¡ã€ãã ãã®åºäœãTiã«ããŠ0.20ïœmolãšããªãšãã«ã¢
ã«ãããŠã ïŒïœmolãïœâãããµã³800mlãçšã
ãŠã40âã§ãšãã¬ã³ãïŒïœäºåéåãããŠãåºäœ
觊åªæåããã¿ã³åå0.002ïœmolçžåœåããµã³
ããªã³ã°ããŠã1.5ã®ãªãŒãã¯ã¬ãŒãã«ã€ãœã
ã¿ã³800mlãšãšãã«å°å ¥ããããã«è¡šïŒã«ç€ºãã³
ã¢ãããŒãå°å ¥ãã80âã«ææž©ããæ°ŽçŽ ã9.5
KgïŒcm2ã®å§ã§å å§ãããšãã¬ã³ãå°å ¥ããŠ11.5
KgïŒcm2ã®å§ãšããïŒæééåãè¡ãè¡šïŒã®çµæã
åŸãã
ãè¡šã
å®æœäŸ 18ã19
N2æ°æµäž200âã§ïŒæé也ç¥ããã·ãªã«ïŒå¯å£«
ãããªã³ååŠã952ïŒæ¯è¡šé¢ç©300m2ïŒïœãå容ç©
1.65c.c.ïŒïœïŒ20ïœãšAlMg6Et3nâBu9ïŒOnBuïŒ36
ïœmolïŒãããµã³æº¶æ¶²ïŒ100mlïŒããã©ã¹ã³ã«ç§€å
ãã枩床ã65âã«ä¿ã¡ãªãããããªã¯ãã«ã·ã©ã³
ïŒïœmolïŒãããµã³æº¶æ¶²ïŒ100mlïŒãïŒæéãããŠ
滎äžããããã«65âã§ïŒæéãæ¹æäžåå¿ãç¶ã
ãã åå¿çµäºåŸãåŸçã«ããäžæŸæ¶²ãé€å»ããåºäœ
ç©è³ªãåŸãããã®åºäœç©è³ªãšè¡šïŒã«ç€ºãååç©ã
çšããä»ã¯å šãŠãå®æœäŸïŒâ(3)ãšåæ§ã«ããŠåºäœ
觊åªæåã®åæãè¡ãããšãã¬ã³ã®ãããµã³äžã§
ã®éåãè¡ããè¡šïŒã®çµæãåŸãã
ãããªã³ååŠã952ïŒæ¯è¡šé¢ç©300m2ïŒïœãå容ç©
1.65c.c.ïŒïœïŒ20ïœãšAlMg6Et3nâBu9ïŒOnBuïŒ36
ïœmolïŒãããµã³æº¶æ¶²ïŒ100mlïŒããã©ã¹ã³ã«ç§€å
ãã枩床ã65âã«ä¿ã¡ãªãããããªã¯ãã«ã·ã©ã³
ïŒïœmolïŒãããµã³æº¶æ¶²ïŒ100mlïŒãïŒæéãããŠ
滎äžããããã«65âã§ïŒæéãæ¹æäžåå¿ãç¶ã
ãã åå¿çµäºåŸãåŸçã«ããäžæŸæ¶²ãé€å»ããåºäœ
ç©è³ªãåŸãããã®åºäœç©è³ªãšè¡šïŒã«ç€ºãååç©ã
çšããä»ã¯å šãŠãå®æœäŸïŒâ(3)ãšåæ§ã«ããŠåºäœ
觊åªæåã®åæãè¡ãããšãã¬ã³ã®ãããµã³äžã§
ã®éåãè¡ããè¡šïŒã®çµæãåŸãã
ãè¡šã
å®æœäŸ 20ã22
å®æœäŸïŒã§åæããåºäœè§Šåªãåæ§ã«åæãã
è¡šïŒã«ç€ºãææ©éå±ååç©ãšåãããŠãè¡šïŒã«ç€º
ããªã¬ãã€ã³ã®éåãè¡ããè¡šïŒã®çµæãåŸãã
è¡šïŒã«ç€ºãææ©éå±ååç©ãšåãããŠãè¡šïŒã«ç€º
ããªã¬ãã€ã³ã®éåãè¡ããè¡šïŒã®çµæãåŸãã
第ïŒå³ã¯æ¬çºæã«ããã觊åªã®èª¿è£œå·¥çšã瀺ã
ãããŒãã€ãŒãå³ã§ããã
ãããŒãã€ãŒãå³ã§ããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ãAã(1)(i) (a)äžè¬åŒMαMgβR1 pR2 qXrYsïŒåŒäž
ã
ïŒã¯AlïŒZnïŒïŒ¢ïŒBeïŒLiååãR1ïŒR2ã¯
åäžãŸãã¯ç°ãªã€ãC1ãC10ã®çåæ°ŽçŽ åºã
ïŒïŒ¹ã¯åäžãŸãã¯ç°ãªã€ãOR3ïŒ
OSiR4R5R6ïŒNR7R8ïŒSR9ïŒããã²ã³ãª
ãåºãè¡šãããR3ïŒR4ïŒR5ïŒR6ïŒR7ïŒR8
ã¯æ°ŽçŽ ååãŸãã¯C1ãC10ã®çåæ°ŽçŽ åºã§
ãããR9ã¯C1ãC10ã®çåæ°ŽçŽ åºã§ããã
αâ§ïŒãβïŒïŒãïœïŒïœïŒïœïŒïœâ§ïŒãïœ
ã¯ïŒã®åå䟡ãïœïŒïœïŒïœïŒïœïŒmαïŒ
2βãïŒâŠïŒïœïŒïœïŒïŒïŒÎ±ïŒÎ²ïŒâŠïŒã®é¢
ä¿ã«ãããïŒã§ç€ºãããææ©ãã°ãã·ãŠã
ïŒã¢ã«ãšãæãã¯(a)ãš(b)ãšãŒãã«ãããªãš
ãŒãã«ãã±ãã³ãã¢ã«ããããã«ã«ãã³é ž
ãŸãã¯ãã®èªå°äœãããã¯ã¢ã«ã³ãŒã«ãã
ãªã¢ã«ã³ãŒã«ãã¢ãã³ããéžã°ããé»åäŸ
äžäœãšåå¿ãããæåïŒã¢ã«ãšã (ii) äžè¬åŒHaSiClbR10 4-(a+b)ïŒåŒäžãïœïŒïœã¯
ïŒãã倧ããæ°ã§ïœïŒïœâŠïŒãïŒïŒïœâŠ
ïŒãR10ã¯ççŽ æ°ïŒã10ã®çåæ°ŽçŽ åºãè¡š
ããïŒã§ç€ºãããâSiçµåå«æã¯ãã«ã·
ã©ã³ååç©0.01ã100ã¢ã«ã次ããéžã°ã
ãç¡æ©æ äœã®ååšäžæãã¯éåšäžã« (i) ç¡æ©é žåç© (ii) ç¡æ©çé žå¡©ãçªé žå¡©ãç¡«é žå¡© (iii) ç¡æ©æ°Žé žåç© (iv) (i)ã(iii)ãããªãè€å¡©ãåºæº¶äœãªããæ··å
ç©ã åå¿ãããŠãªãåºäœäžã«å«ãŸããâMg
çµåïŒã¢ã«ã«å¯ŸããŠã (2) 次ããéžã°ããååç©ã0.05ã20ã¢ã«åå¿
ãããŠåŸãããåºäœã (i) ã¢ã«ããã (ii) ã·ã©ããŒã« (iii) ãã€ãããžãšã³ã·ãããµã³ (3) ãã¿ããŠã ååç©ããããžãŠã ååç©ããž
ã«ã³ããŠã ååç©ãããããŠã ååç©ããã³
ãããã®æ··åç©ãªããåå¿ç©ããéžã°ããïŒ
皮以äžã®æåã åå¿ãããŠåŸãããåºäœè§Šåªæåãæãã¯ãã
ã« (4) åããã²ã³åãã¿ããŠã ååç©ãã¢ã«ãã
ãŠã ã®ããã²ã³åç©ãçªçŽ ã®ããã²ã³åç©é«
ã®ããã²ã³åç©ããéžã°ããæå ã«ããåŠçããŠåŸãããåºäœè§Šåªæå ãBã ææ©éå±ååç©æå ã§ãã€ãŠããããšãããããªã觊åªããªã¬ã
ã€ã³ãšæ¥è§Šããããªã¬ãã€ã³éåæ¹æ³ã ïŒ ãã(1)ã®åºäœäžã®ïŒ£âMgçµåïŒã¢ã«ã«å¯Ÿ
ããŠãæå(2)ã0.1ã10ã¢ã«ã§ããç¹èš±è«æ±ã®ç¯
å²ç¬¬ïŒé èšèŒã®ãªã¬ãã€ã³éåæ¹æ³ã ïŒ ãã(1)ã®åºäœäžã®ïŒ£âMgçµåïŒã¢ã«ã«å¯Ÿ
ããŠãæå(2)ã0.2ãïŒã¢ã«ã§ããç¹èš±è«æ±ã®ç¯
å²ç¬¬ïŒé èšèŒã®ãªã¬ãã€ã³éåæ¹æ³ã ïŒ äžè¬åŒMãMgãR1 pR2 qXrYsã§è¡šããããææ©ã
ã°ãã·ãŠã æåã«ãããŠãïŒãAlïŒïŒ¢ïŒZnãŸã
ã¯Beã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒé ãŸã
ã¯ç¬¬ïŒé ã®ããããã«èšèŒã®ãªã¬ãã€ã³éåæ¹
æ³ã ïŒ äžè¬åŒMãMgãR1 pR2 qXrYsã§è¡šããããææ©ã
ã°ãã·ãŠã æåã«ãããŠãαïŒïŒïŒ0.5âŠÎ²ïŒÎ±
âŠ10ïŒïŒâŠïŒïœïŒïœïŒïŒïŒÎ±ïŒÎ²ïŒâŠ0.8ã§ããç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒé ã第ïŒé ãŸãã¯ç¬¬ïŒ
é ã®ããããã«èšèŒã®ãªã¬ãã€ã³éåæ¹æ³ã ïŒ åºäœãšãã¿ã³ååç©ããããžãŠã ååç©ããž
ã«ã³ããŠã ååç©ãããããŠã ååç©ããéžã°ã
ãæåãšã®åå¿ããææ©éå±ååç©ã®ååšäžã«è¡
ãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒé ã第ïŒé ã第ïŒ
é ãŸãã¯ç¬¬ïŒé ã®ããããã«èšèŒã®ãªã¬ãã€ã³é
åæ¹æ³ã ïŒ ãã¿ã³ååç©ããããžãŠã ååç©ããžã«ã³ã
ãŠã ååç©ãããããŠã ååç©ãŸãã¯ãããã®æ··
åç©ãåå¿ç©ããéžã°ããæå(3)ãããã¿ã³åå
ç©ã§ãããããŸãã¯ãã¿ã³ååç©ãå«æããæå
ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒé ã第ïŒé ã
第ïŒé ã第ïŒé ãŸãã¯ç¬¬ïŒé ã®ããããã«èšèŒã®
ãªã¬ãã€ã³éåæ¹æ³ã
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11011083A JPS604505A (ja) | 1983-06-21 | 1983-06-21 | ãªã¬ãã€ã³éåæ¹æ³ |
| EP19840304043 EP0132288B1 (en) | 1983-06-21 | 1984-06-15 | A method of polymerizing an olefin |
| DE8484304043T DE3481422D1 (de) | 1983-06-21 | 1984-06-15 | Verfahren zur polymerisation von olefinen. |
| CA000456963A CA1219997A (en) | 1983-06-21 | 1984-06-20 | Method of polymerizing an olefin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11011083A JPS604505A (ja) | 1983-06-21 | 1983-06-21 | ãªã¬ãã€ã³éåæ¹æ³ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS604505A JPS604505A (ja) | 1985-01-11 |
| JPH0242365B2 true JPH0242365B2 (ja) | 1990-09-21 |
Family
ID=14527294
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11011083A Granted JPS604505A (ja) | 1983-06-21 | 1983-06-21 | ãªã¬ãã€ã³éåæ¹æ³ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS604505A (ja) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5358611A (en) * | 1993-05-17 | 1994-10-25 | Rohm And Haas Company | Method of reducing impurities in aqueous monomer solutions |
-
1983
- 1983-06-21 JP JP11011083A patent/JPS604505A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS604505A (ja) | 1985-01-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5767034A (en) | Olefin polymerization catalyst with additive comprising aluminum-silicon composition, calixarene derivatives or cyclodextrin derivatives | |
| US4245071A (en) | Low pressure polymerization of olefins | |
| CA1163617A (en) | Catalyst for polymerization of olefins and polymerization process employing such catalyst | |
| US6218331B1 (en) | Polymer-supported catalyst for olefin polymerization | |
| JPH04306203A (ja) | æ¹è¯ããããªã¬ãã£ã³éåçšä¹Ÿç¥è§Šåª | |
| JP3049569B2 (ja) | ããªãªã¬ãã£ã³ã®è£œé æ¹æ³ | |
| EP0052471B1 (en) | Process and catalyst for polymerization of olefins | |
| JPH11507086A (ja) | ãªã¬ãã£ã³éåçšããªããŒæ æè§Šåª | |
| CN102060945A (zh) | äžç§ä¹ç¯èååºäœéå¬ååç»åçå¶å€ååºçš | |
| EP0132288B1 (en) | A method of polymerizing an olefin | |
| JPH0242365B2 (ja) | ||
| JPH04261408A (ja) | ããªãªã¬ãã£ã³ã®è£œé æ¹æ³ | |
| JPH0617400B2 (ja) | ãªã¬ãã€ã³ã®éåæ¹æ³ | |
| JPH0242366B2 (ja) | ||
| JPH0822890B2 (ja) | ãããã¬ã³éåäœã®è£œé æ³ | |
| JP3247448B2 (ja) | αâãªã¬ãã£ã³ã®éåæ¹æ³ | |
| JPH0335004A (ja) | ããªãªã¬ãã£ã³ã®è£œé æ¹æ³ | |
| JPS643210B2 (ja) | ||
| JPS6142511A (ja) | ãªã¬ãã€ã³ã®éåæ¹æ³ | |
| JPH04216804A (ja) | αâãªã¬ãã£ã³ã®éåæ¹æ³ | |
| JPH07109306A (ja) | ãªã¬ãã£ã³éåçšè§Šåª | |
| JPS643209B2 (ja) | ||
| JPS64966B2 (ja) | ||
| JPH06102694B2 (ja) | αâãªã¬ãã€ã³éåäœè£œé æ¹æ³ | |
| JPS6142510A (ja) | ãªã¬ãã€ã³éåæ¹æ³ |