JPH0242841B2 - - Google Patents
Info
- Publication number
- JPH0242841B2 JPH0242841B2 JP11464981A JP11464981A JPH0242841B2 JP H0242841 B2 JPH0242841 B2 JP H0242841B2 JP 11464981 A JP11464981 A JP 11464981A JP 11464981 A JP11464981 A JP 11464981A JP H0242841 B2 JPH0242841 B2 JP H0242841B2
- Authority
- JP
- Japan
- Prior art keywords
- polymer compound
- bis
- photosensitive
- acid
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 claims description 38
- 229920000642 polymer Polymers 0.000 claims description 32
- 239000000178 monomer Substances 0.000 claims description 27
- 239000000539 dimer Substances 0.000 claims description 24
- 229910052757 nitrogen Inorganic materials 0.000 claims description 23
- 150000007513 acids Chemical class 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 239000011342 resin composition Substances 0.000 claims description 8
- 230000008859 change Effects 0.000 claims description 5
- AMSJBNMFXXARTQ-UHFFFAOYSA-N 3406-75-5 Chemical compound OC(=O)CSC1=CC=C([N+]([O-])=O)C=C1 AMSJBNMFXXARTQ-UHFFFAOYSA-N 0.000 claims description 3
- 230000002378 acidificating effect Effects 0.000 claims description 3
- 230000003993 interaction Effects 0.000 claims description 3
- 238000003918 potentiometric titration Methods 0.000 claims description 3
- XWKAVQKJQBISOL-ZETCQYMHSA-N (2s)-2-anilinopropanoic acid Chemical compound OC(=O)[C@H](C)NC1=CC=CC=C1 XWKAVQKJQBISOL-ZETCQYMHSA-N 0.000 claims description 2
- PMUMUYYQHZMXNQ-VIFPVBQESA-N (2s)-5-amino-2-anilino-5-oxopentanoic acid Chemical compound NC(=O)CC[C@@H](C(O)=O)NC1=CC=CC=C1 PMUMUYYQHZMXNQ-VIFPVBQESA-N 0.000 claims description 2
- FNEQUOWQJWSAHK-UHFFFAOYSA-N 2-[carboxy(phenyl)methyl]selanyl-2-phenylacetic acid Chemical compound C=1C=CC=CC=1C(C(=O)O)[Se]C(C(O)=O)C1=CC=CC=C1 FNEQUOWQJWSAHK-UHFFFAOYSA-N 0.000 claims description 2
- 239000012736 aqueous medium Substances 0.000 claims description 2
- 230000003287 optical effect Effects 0.000 claims 1
- -1 3-aminopropyl group Chemical group 0.000 description 30
- 239000000203 mixture Substances 0.000 description 30
- 239000010408 film Substances 0.000 description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 238000000034 method Methods 0.000 description 11
- 125000005907 alkyl ester group Chemical group 0.000 description 10
- 238000006116 polymerization reaction Methods 0.000 description 10
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 9
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 150000004820 halides Chemical class 0.000 description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
- 239000003504 photosensitizing agent Substances 0.000 description 6
- 238000007639 printing Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000012546 transfer Methods 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 150000002430 hydrocarbons Chemical group 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 150000004985 diamines Chemical class 0.000 description 4
- 150000001991 dicarboxylic acids Chemical class 0.000 description 4
- 150000002009 diols Chemical class 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
- 229910052753 mercury Inorganic materials 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000006068 polycondensation reaction Methods 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- 230000000379 polymerizing effect Effects 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- XCVDAQWKJUCVHJ-UHFFFAOYSA-N 2-azaniumyl-2-(4-nitrophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C([N+]([O-])=O)C=C1 XCVDAQWKJUCVHJ-UHFFFAOYSA-N 0.000 description 3
- PPJDSJPSCDUDQR-UHFFFAOYSA-N 3,3,5-triphenyl-1,2-dihydropyrazole Chemical compound C1(=CC=CC=C1)C1(C=C(NN1)C1=CC=CC=C1)C1=CC=CC=C1 PPJDSJPSCDUDQR-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- 239000004952 Polyamide Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 150000002334 glycols Chemical class 0.000 description 3
- 150000002460 imidazoles Chemical class 0.000 description 3
- 125000002883 imidazolyl group Chemical group 0.000 description 3
- 238000007644 letterpress printing Methods 0.000 description 3
- 239000012046 mixed solvent Substances 0.000 description 3
- 229920002647 polyamide Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- SULYEHHGGXARJS-UHFFFAOYSA-N 2',4'-dihydroxyacetophenone Chemical compound CC(=O)C1=CC=C(O)C=C1O SULYEHHGGXARJS-UHFFFAOYSA-N 0.000 description 2
- AVHSSMVTBDPMIP-UHFFFAOYSA-N 2-[2-[carboxymethyl(methyl)amino]ethyl-methylamino]acetic acid Chemical compound OC(=O)CN(C)CCN(C)CC(O)=O AVHSSMVTBDPMIP-UHFFFAOYSA-N 0.000 description 2
- JERMFLFKXHHROS-UHFFFAOYSA-N 2-[4-(carboxymethyl)piperazin-1-yl]acetic acid Chemical compound OC(=O)CN1CCN(CC(O)=O)CC1 JERMFLFKXHHROS-UHFFFAOYSA-N 0.000 description 2
- WRJZKSHNBALIGH-UHFFFAOYSA-N 2-piperazin-1-ium-1-ylacetate Chemical compound OC(=O)CN1CCNCC1 WRJZKSHNBALIGH-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 2
- KFDVPJUYSDEJTH-UHFFFAOYSA-N 4-ethenylpyridine Chemical compound C=CC1=CC=NC=C1 KFDVPJUYSDEJTH-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 229920000298 Cellophane Polymers 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- NPKSPKHJBVJUKB-UHFFFAOYSA-N N-phenylglycine Chemical compound OC(=O)CNC1=CC=CC=C1 NPKSPKHJBVJUKB-UHFFFAOYSA-N 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- AUNGANRZJHBGPY-SCRDCRAPSA-N Riboflavin Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-SCRDCRAPSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- IMUDHTPIFIBORV-UHFFFAOYSA-N aminoethylpiperazine Chemical compound NCCN1CCNCC1 IMUDHTPIFIBORV-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 230000031700 light absorption Effects 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 2
- 238000007645 offset printing Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical group CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
- 150000004053 quinones Chemical class 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 230000004304 visual acuity Effects 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- QSNAVZQFIDCTQI-UHFFFAOYSA-N 1,2,3-trinitro-9h-fluorene Chemical compound C1=CC=C2C(C=C(C(=C3[N+]([O-])=O)[N+]([O-])=O)[N+](=O)[O-])=C3CC2=C1 QSNAVZQFIDCTQI-UHFFFAOYSA-N 0.000 description 1
- PLUFITIFLBGFPN-UHFFFAOYSA-N 1,2-dichloroanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=C(Cl)C(Cl)=CC=C3C(=O)C2=C1 PLUFITIFLBGFPN-UHFFFAOYSA-N 0.000 description 1
- YRSDILSVEAAWQJ-UHFFFAOYSA-N 1,2-dinitro-9h-fluorene Chemical compound C1=CC=C2C3=CC=C([N+](=O)[O-])C([N+]([O-])=O)=C3CC2=C1 YRSDILSVEAAWQJ-UHFFFAOYSA-N 0.000 description 1
- NMNSBFYYVHREEE-UHFFFAOYSA-N 1,2-dinitroanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=C([N+]([O-])=O)C([N+](=O)[O-])=CC=C3C(=O)C2=C1 NMNSBFYYVHREEE-UHFFFAOYSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 1
- FRASJONUBLZVQX-UHFFFAOYSA-N 1,4-dioxonaphthalene Natural products C1=CC=C2C(=O)C=CC(=O)C2=C1 FRASJONUBLZVQX-UHFFFAOYSA-N 0.000 description 1
- BOKGTLAJQHTOKE-UHFFFAOYSA-N 1,5-dihydroxynaphthalene Chemical compound C1=CC=C2C(O)=CC=CC2=C1O BOKGTLAJQHTOKE-UHFFFAOYSA-N 0.000 description 1
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 1
- HMLSBRLVTDLLOI-UHFFFAOYSA-N 1-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)C(C)OC(=O)C(C)=C HMLSBRLVTDLLOI-UHFFFAOYSA-N 0.000 description 1
- CFKSCQPPKNDTED-UHFFFAOYSA-N 1-[4-(2-hydroxy-2-methylnonyl)piperazin-1-yl]-2-methylnonan-2-ol Chemical compound CCCCCCCC(C)(O)CN1CCN(CC(C)(O)CCCCCCC)CC1 CFKSCQPPKNDTED-UHFFFAOYSA-N 0.000 description 1
- 125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 description 1
- AVAGDIXDPQCKCQ-UHFFFAOYSA-N 1-nitro-1,2-dihydroacenaphthylene Chemical compound C1=CC(C([N+](=O)[O-])C2)=C3C2=CC=CC3=C1 AVAGDIXDPQCKCQ-UHFFFAOYSA-N 0.000 description 1
- YIYBRXKMQFDHSM-UHFFFAOYSA-N 2,2'-Dihydroxybenzophenone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1O YIYBRXKMQFDHSM-UHFFFAOYSA-N 0.000 description 1
- FKNIDKXOANSRCS-UHFFFAOYSA-N 2,3,4-trinitrofluoren-1-one Chemical compound C1=CC=C2C3=C([N+](=O)[O-])C([N+]([O-])=O)=C([N+]([O-])=O)C(=O)C3=CC2=C1 FKNIDKXOANSRCS-UHFFFAOYSA-N 0.000 description 1
- USAYMJGCALIGIG-UHFFFAOYSA-N 2,3-dichlorocyclohexa-2,5-diene-1,4-dione Chemical compound ClC1=C(Cl)C(=O)C=CC1=O USAYMJGCALIGIG-UHFFFAOYSA-N 0.000 description 1
- SVPKNMBRVBMTLB-UHFFFAOYSA-N 2,3-dichloronaphthalene-1,4-dione Chemical compound C1=CC=C2C(=O)C(Cl)=C(Cl)C(=O)C2=C1 SVPKNMBRVBMTLB-UHFFFAOYSA-N 0.000 description 1
- RNIPJYFZGXJSDD-UHFFFAOYSA-N 2,4,5-triphenyl-1h-imidazole Chemical compound C1=CC=CC=C1C1=NC(C=2C=CC=CC=2)=C(C=2C=CC=CC=2)N1 RNIPJYFZGXJSDD-UHFFFAOYSA-N 0.000 description 1
- IAHOUQOWMXVMEH-UHFFFAOYSA-N 2,4,6-trinitroaniline Chemical compound NC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O IAHOUQOWMXVMEH-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- ZEUHFQLWVSUWRF-UHFFFAOYSA-N 2-(2-nitrophenyl)-4,5-diphenyl-1h-imidazole Chemical class [O-][N+](=O)C1=CC=CC=C1C1=NC(C=2C=CC=CC=2)=C(C=2C=CC=CC=2)N1 ZEUHFQLWVSUWRF-UHFFFAOYSA-N 0.000 description 1
- SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- MWSMRYINWRINLC-UHFFFAOYSA-N 2-[(dimethylamino)methyl]-2-methylpropane-1,3-diol Chemical compound CN(C)CC(C)(CO)CO MWSMRYINWRINLC-UHFFFAOYSA-N 0.000 description 1
- ASXVBPCMXXZYHO-UHFFFAOYSA-N 2-[2-[2-hydroxyethyl(methyl)amino]ethyl-methylamino]ethanol Chemical compound OCCN(C)CCN(C)CCO ASXVBPCMXXZYHO-UHFFFAOYSA-N 0.000 description 1
- SDVGDVAQUYLWBY-UHFFFAOYSA-N 2-[4-(2-hydroxycycloheptyl)piperazin-1-yl]cycloheptan-1-ol Chemical compound OC1CCCCCC1N1CCN(C2C(CCCCC2)O)CC1 SDVGDVAQUYLWBY-UHFFFAOYSA-N 0.000 description 1
- LLALCPHRPIWTEO-UHFFFAOYSA-N 2-[4-(aminomethyl)-3-methylpiperazin-1-yl]acetic acid Chemical compound CC1CN(CC(O)=O)CCN1CN LLALCPHRPIWTEO-UHFFFAOYSA-N 0.000 description 1
- WVEYNIYFSLEUCQ-UHFFFAOYSA-N 2-[4-(aminomethyl)piperazin-1-yl]acetic acid Chemical compound NCN1CCN(CC(O)=O)CC1 WVEYNIYFSLEUCQ-UHFFFAOYSA-N 0.000 description 1
- WHXFZAIYFRCDIB-UHFFFAOYSA-N 2-[4-(aminomethyl)piperazin-1-yl]ethanamine Chemical compound NCCN1CCN(CN)CC1 WHXFZAIYFRCDIB-UHFFFAOYSA-N 0.000 description 1
- WRYGFOHQVMVHDM-UHFFFAOYSA-N 2-[4-(carboxymethyl)-3,5-dimethylpiperazin-1-yl]acetic acid Chemical compound CC1CN(CC(O)=O)CC(C)N1CC(O)=O WRYGFOHQVMVHDM-UHFFFAOYSA-N 0.000 description 1
- FSIBLFNJXCMJPX-UHFFFAOYSA-N 2-[[di(propan-2-yl)amino]methyl]-2-methylpropane-1,3-diol Chemical compound CC(C)N(C(C)C)CC(C)(CO)CO FSIBLFNJXCMJPX-UHFFFAOYSA-N 0.000 description 1
- ZOBMEMBAPTUNSO-UHFFFAOYSA-N 2-[aminomethyl(methyl)amino]acetic acid Chemical compound NCN(C)CC(O)=O ZOBMEMBAPTUNSO-UHFFFAOYSA-N 0.000 description 1
- XWSGEVNYFYKXCP-UHFFFAOYSA-N 2-[carboxymethyl(methyl)amino]acetic acid Chemical compound OC(=O)CN(C)CC(O)=O XWSGEVNYFYKXCP-UHFFFAOYSA-N 0.000 description 1
- OWPJOIPLQFYVDK-UHFFFAOYSA-N 2-[cyclohexyl-[6-[cyclohexyl(2-hydroxyethyl)amino]hexyl]amino]ethanol Chemical compound C1CCCCC1N(CCO)CCCCCCN(CCO)C1CCCCC1 OWPJOIPLQFYVDK-UHFFFAOYSA-N 0.000 description 1
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
- MGOUENCSVMAGSE-UHFFFAOYSA-N 2-azaniumyl-2-(3-chlorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=CC(Cl)=C1 MGOUENCSVMAGSE-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- JOMNTHCQHJPVAZ-UHFFFAOYSA-N 2-methylpiperazine Chemical compound CC1CNCCN1 JOMNTHCQHJPVAZ-UHFFFAOYSA-N 0.000 description 1
- OALHHIHQOFIMEF-UHFFFAOYSA-N 3',6'-dihydroxy-2',4',5',7'-tetraiodo-3h-spiro[2-benzofuran-1,9'-xanthene]-3-one Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC(I)=C(O)C(I)=C1OC1=C(I)C(O)=C(I)C=C21 OALHHIHQOFIMEF-UHFFFAOYSA-N 0.000 description 1
- JJZZCEGXLISDMW-UHFFFAOYSA-N 3-(3-methylpiperazin-1-yl)propanoic acid Chemical compound CC1CN(CCC(O)=O)CCN1 JJZZCEGXLISDMW-UHFFFAOYSA-N 0.000 description 1
- VCQPHZSXAHONHF-UHFFFAOYSA-N 3-(dimethylamino)chromen-2-one Chemical compound C1=CC=C2OC(=O)C(N(C)C)=CC2=C1 VCQPHZSXAHONHF-UHFFFAOYSA-N 0.000 description 1
- PCIRIOLCHWHYSX-UHFFFAOYSA-N 3-[4-(carboxymethyl)piperazin-1-yl]propanoic acid Chemical compound OC(=O)CCN1CCN(CC(O)=O)CC1 PCIRIOLCHWHYSX-UHFFFAOYSA-N 0.000 description 1
- ZOHAPDDPDSPUTE-UHFFFAOYSA-N 3-[carboxymethyl(methyl)amino]propanoic acid Chemical compound OC(=O)CN(C)CCC(O)=O ZOHAPDDPDSPUTE-UHFFFAOYSA-N 0.000 description 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
- VVBLNCFGVYUYGU-UHFFFAOYSA-N 4,4'-Bis(dimethylamino)benzophenone Chemical compound C1=CC(N(C)C)=CC=C1C(=O)C1=CC=C(N(C)C)C=C1 VVBLNCFGVYUYGU-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- VWGKEVWFBOUAND-UHFFFAOYSA-N 4,4'-thiodiphenol Chemical compound C1=CC(O)=CC=C1SC1=CC=C(O)C=C1 VWGKEVWFBOUAND-UHFFFAOYSA-N 0.000 description 1
- FSMQOOZWPZDBTR-UHFFFAOYSA-N 4,4,5,5-tetraphenyl-1H-imidazole Chemical compound C1(=CC=CC=C1)C1(C(N=CN1)(C1=CC=CC=C1)C1=CC=CC=C1)C1=CC=CC=C1 FSMQOOZWPZDBTR-UHFFFAOYSA-N 0.000 description 1
- IICCLYANAQEHCI-UHFFFAOYSA-N 4,5,6,7-tetrachloro-3',6'-dihydroxy-2',4',5',7'-tetraiodospiro[2-benzofuran-3,9'-xanthene]-1-one Chemical compound O1C(=O)C(C(=C(Cl)C(Cl)=C2Cl)Cl)=C2C21C1=CC(I)=C(O)C(I)=C1OC1=C(I)C(O)=C(I)C=C21 IICCLYANAQEHCI-UHFFFAOYSA-N 0.000 description 1
- ZPLCXHWYPWVJDL-UHFFFAOYSA-N 4-[(4-hydroxyphenyl)methyl]-1,3-oxazolidin-2-one Chemical compound C1=CC(O)=CC=C1CC1NC(=O)OC1 ZPLCXHWYPWVJDL-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- SHSHMZJKMQRNTC-UHFFFAOYSA-N 4-piperazin-1-ylcyclohexan-1-amine Chemical compound C1CC(N)CCC1N1CCNCC1 SHSHMZJKMQRNTC-UHFFFAOYSA-N 0.000 description 1
- LJQLSPOOOMFPAY-UHFFFAOYSA-N 4-piperazin-1-ylcyclohexane-1-carboxylic acid Chemical compound C1CC(C(=O)O)CCC1N1CCNCC1 LJQLSPOOOMFPAY-UHFFFAOYSA-N 0.000 description 1
- CONKBQPVFMXDOV-QHCPKHFHSA-N 6-[(5S)-5-[[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]methyl]-2-oxo-1,3-oxazolidin-3-yl]-3H-1,3-benzoxazol-2-one Chemical group C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C[C@H]1CN(C(O1)=O)C1=CC2=C(NC(O2)=O)C=C1 CONKBQPVFMXDOV-QHCPKHFHSA-N 0.000 description 1
- YYVYAPXYZVYDHN-UHFFFAOYSA-N 9,10-phenanthroquinone Chemical compound C1=CC=C2C(=O)C(=O)C3=CC=CC=C3C2=C1 YYVYAPXYZVYDHN-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- SDDLEVPIDBLVHC-UHFFFAOYSA-N Bisphenol Z Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCCC1 SDDLEVPIDBLVHC-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- AUNGANRZJHBGPY-UHFFFAOYSA-N D-Lyxoflavin Natural products OCC(O)C(O)C(O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-UHFFFAOYSA-N 0.000 description 1
- GDFCSMCGLZFNFY-UHFFFAOYSA-N Dimethylaminopropyl Methacrylamide Chemical compound CN(C)CCCNC(=O)C(C)=C GDFCSMCGLZFNFY-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- ZGUNAGUHMKGQNY-ZETCQYMHSA-N L-alpha-phenylglycine zwitterion Chemical compound OC(=O)[C@@H](N)C1=CC=CC=C1 ZGUNAGUHMKGQNY-ZETCQYMHSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- CNCOEDDPFOAUMB-UHFFFAOYSA-N N-Methylolacrylamide Chemical compound OCNC(=O)C=C CNCOEDDPFOAUMB-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- XMUZQOKACOLCSS-UHFFFAOYSA-N [2-(hydroxymethyl)phenyl]methanol Chemical compound OCC1=CC=CC=C1CO XMUZQOKACOLCSS-UHFFFAOYSA-N 0.000 description 1
- YWMLORGQOFONNT-UHFFFAOYSA-N [3-(hydroxymethyl)phenyl]methanol Chemical compound OCC1=CC=CC(CO)=C1 YWMLORGQOFONNT-UHFFFAOYSA-N 0.000 description 1
- PCIFXGOJRVVQGH-UHFFFAOYSA-N [4-(aminomethyl)piperazin-1-yl]methanamine Chemical compound NCN1CCN(CN)CC1 PCIFXGOJRVVQGH-UHFFFAOYSA-N 0.000 description 1
- BWVAOONFBYYRHY-UHFFFAOYSA-N [4-(hydroxymethyl)phenyl]methanol Chemical compound OCC1=CC=C(CO)C=C1 BWVAOONFBYYRHY-UHFFFAOYSA-N 0.000 description 1
- NQEQVKVMCQIFFB-UHFFFAOYSA-N [4-(hydroxymethyl)piperazin-1-yl]methanol Chemical compound OCN1CCN(CO)CC1 NQEQVKVMCQIFFB-UHFFFAOYSA-N 0.000 description 1
- PEJLNXHANOHNSU-UHFFFAOYSA-N acridine-3,6-diamine;10-methylacridin-10-ium-3,6-diamine;chloride Chemical compound [Cl-].C1=CC(N)=CC2=NC3=CC(N)=CC=C3C=C21.C1=C(N)C=C2[N+](C)=C(C=C(N)C=C3)C3=CC2=C1 PEJLNXHANOHNSU-UHFFFAOYSA-N 0.000 description 1
- 125000000641 acridinyl group Chemical class C1(=CC=CC2=NC3=CC=CC=C3C=C12)* 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- WPKYZIPODULRBM-UHFFFAOYSA-N azane;prop-2-enoic acid Chemical compound N.OC(=O)C=C WPKYZIPODULRBM-UHFFFAOYSA-N 0.000 description 1
- LHMRXAIRPKSGDE-UHFFFAOYSA-N benzo[a]anthracene-7,12-dione Chemical compound C1=CC2=CC=CC=C2C2=C1C(=O)C1=CC=CC=C1C2=O LHMRXAIRPKSGDE-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- SODJJEXAWOSSON-UHFFFAOYSA-N bis(2-hydroxy-4-methoxyphenyl)methanone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=C(OC)C=C1O SODJJEXAWOSSON-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- UDSAIICHUKSCKT-UHFFFAOYSA-N bromophenol blue Chemical compound C1=C(Br)C(O)=C(Br)C=C1C1(C=2C=C(Br)C(O)=C(Br)C=2)C2=CC=CC=C2S(=O)(=O)O1 UDSAIICHUKSCKT-UHFFFAOYSA-N 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- FLKYBGKDCCEQQM-WYUVZMMLSA-M cefazolin sodium Chemical class [Na+].S1C(C)=NN=C1SCC1=C(C([O-])=O)N2C(=O)[C@@H](NC(=O)CN3N=NN=C3)[C@H]2SC1 FLKYBGKDCCEQQM-WYUVZMMLSA-M 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 150000004775 coumarins Chemical class 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- SEACYXSIPDVVMV-UHFFFAOYSA-L eosin Y Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C([O-])=C(Br)C=C21 SEACYXSIPDVVMV-UHFFFAOYSA-L 0.000 description 1
- UYMKPFRHYYNDTL-UHFFFAOYSA-N ethenamine Chemical group NC=C UYMKPFRHYYNDTL-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- LIWAQLJGPBVORC-UHFFFAOYSA-N ethylmethylamine Chemical compound CCNC LIWAQLJGPBVORC-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- YLQWCDOCJODRMT-UHFFFAOYSA-N fluoren-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C2=C1 YLQWCDOCJODRMT-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- NIQQIJXGUZVEBB-UHFFFAOYSA-N methanol;propan-2-one Chemical compound OC.CC(C)=O NIQQIJXGUZVEBB-UHFFFAOYSA-N 0.000 description 1
- 238000002715 modification method Methods 0.000 description 1
- COJUXMTZOSXAOW-UHFFFAOYSA-N n'-[2-[3-aminopropyl(methyl)amino]ethyl]-n'-methylpropane-1,3-diamine Chemical compound NCCCN(C)CCN(C)CCCN COJUXMTZOSXAOW-UHFFFAOYSA-N 0.000 description 1
- KFIGICHILYTCJF-UHFFFAOYSA-N n'-methylethane-1,2-diamine Chemical compound CNCCN KFIGICHILYTCJF-UHFFFAOYSA-N 0.000 description 1
- UTSYWKJYFPPRAP-UHFFFAOYSA-N n-(butoxymethyl)prop-2-enamide Chemical compound CCCCOCNC(=O)C=C UTSYWKJYFPPRAP-UHFFFAOYSA-N 0.000 description 1
- VNLHOYZHPQDOMS-UHFFFAOYSA-N n-[3-(diethylamino)propyl]-2-methylprop-2-enamide Chemical compound CCN(CC)CCCNC(=O)C(C)=C VNLHOYZHPQDOMS-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- KLAKIAVEMQMVBT-UHFFFAOYSA-N p-hydroxy-phenacyl alcohol Natural products OCC(=O)C1=CC=C(O)C=C1 KLAKIAVEMQMVBT-UHFFFAOYSA-N 0.000 description 1
- GVKCHTBDSMQENH-UHFFFAOYSA-L phloxine B Chemical compound [Na+].[Na+].[O-]C(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C1=C2C=C(Br)C(=O)C(Br)=C2OC2=C(Br)C([O-])=C(Br)C=C21 GVKCHTBDSMQENH-UHFFFAOYSA-L 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- 150000003219 pyrazolines Chemical class 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000002151 riboflavin Substances 0.000 description 1
- 229960002477 riboflavin Drugs 0.000 description 1
- 235000019192 riboflavin Nutrition 0.000 description 1
- 229930187593 rose bengal Natural products 0.000 description 1
- 229940081623 rose bengal Drugs 0.000 description 1
- STRXNPAVPKGJQR-UHFFFAOYSA-N rose bengal A Natural products O1C(=O)C(C(=CC=C2Cl)Cl)=C2C21C1=CC(I)=C(O)C(I)=C1OC1=C(I)C(O)=C(I)C=C21 STRXNPAVPKGJQR-UHFFFAOYSA-N 0.000 description 1
- 229940047670 sodium acrylate Drugs 0.000 description 1
- MNCGMVDMOKPCSQ-UHFFFAOYSA-M sodium;2-phenylethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 MNCGMVDMOKPCSQ-UHFFFAOYSA-M 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- UGNWTBMOAKPKBL-UHFFFAOYSA-N tetrachloro-1,4-benzoquinone Chemical compound ClC1=C(Cl)C(=O)C(Cl)=C(Cl)C1=O UGNWTBMOAKPKBL-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- PRZSXZWFJHEZBJ-UHFFFAOYSA-N thymol blue Chemical compound C1=C(O)C(C(C)C)=CC(C2(C3=CC=CC=C3S(=O)(=O)O2)C=2C(=CC(O)=C(C(C)C)C=2)C)=C1C PRZSXZWFJHEZBJ-UHFFFAOYSA-N 0.000 description 1
- 150000004961 triphenylmethanes Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 125000001834 xanthenyl group Chemical class C1=CC=CC=2OC3=CC=CC=C3C(C12)* 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
Description
æ¬çºæã¯ãæ°èŠãªæå
æ§æš¹èçµæç©ã«é¢ããæŽ
ã«è©³ããã¯ãé«ååååç©ã®èŠªæ°Žæ§ã®åºŠåãããŸ
ãã¯æ°Žã«å¯Ÿãã溶解床ãå ååŠçã«å€åãããã
æ¹æ³ãçšããæå æ§æš¹èçµæç©ã«é¢ããã è¿å¹Žãæ å ±éã®å¢å ã«äŒŽããçš®ã ã®åéã«ãã
ãŠæå ææã®èŠæ±ãé«ãŸã€ãŠãããããã«å¯Ÿå¿ã
ãæ°ããæå ææã®ç 究ãçãã«è¡ãããŠããã
ãšã¯åšç¥ã®ãšããã§ããããããæ°ããæå ææ
ã«å¯Ÿãã解ååãæå é床ãã·ãšã«ãã©ã€ããã
ãã»ãã·ã³ã°ã®å®¹æããªã©ã®æ§èœèŠæ±ã¯äžæ®µãšå³
ãããªã€ãŠããã æ¬çºæè ãã¯ããã®æ§ãªç¶æ³äžã§éæç 究ãé
ããçµæãç¹éæ55â98744å·å ¬å ±ã«é瀺ããã
ãã«ãåŸæ¥ã®æå ææãšã¯ç°ãªã€ãæ°ããç¹åŸŽã
æããæå æ§æš¹èçµæç©ãåŸãããšã«æåããã
ããããªãããäžèšçµæç©ã§ã¯å åå¿é床ãå®çš
åãåŸãçšå åã§ã¯ãªãã€ãã®ã§ãæ¬çºæè ãã¯
ç 究ãé²ããŠãé«æ床ã®æå æ§æš¹èçµæç©ãèŠåº
ããæ°çµæç©ãææ¡ããããšãããåèšçµæç©ã
ãããäžæ®µãšé«æ床ãèŠæ±ãããæ¬çºæè ãã¯ã
ãã«ç 究ããçµæãæ¬çºæãå®æããã«å°ã€ãã ããªãã¡æ¬çºæã¯ã(1)ããèªäœã§ã¯èŠªæ°Žæ§ãäœ
ããããŸãã¯æ°Žäžæº¶æ§ã§ããããé žæ§ãæããå
åç©ãšã®å ±åäžã§é žå¡©åºçžäºäœçšã«ãã芪氎æ§ã
é«ããªããããŸãã¯æ°Žæº¶æ§ã«ãªãæ§ãªæ§è³ªãæã
ãå¡©åºæ§é«ååååç©ã§ãã€ãŠã該é«ååååç©
ã圢æãåéäœãå¡©åºæ§ã瀺ãåºãæãããã€æ°Ž
溶åªäœã«ãããŠé»äœå·®æ»Žå®ã«ãã枬å®ããŠå¡©åºæ§
åºpka2以äžã瀺ããããã«è©²é«ååååç©äžã®
çªçŽ å«éã0.1ã25åœéïŒKgã§ããå¡©åºæ§é«åå
ååç©ã®å°ãªããšãïŒçš®ã(2)æ¬æ¥é žæ§ã§ãã€ãŠã
å ç §å°ãåããããšã«ããååŠå€åãèµ·ãããŠã
é žæ§ã倱ããããªé žæ§ååç©äžèšäžè¬åŒïŒïŒã§
瀺ãããé žæ§ååç©ãïŒâãããããªããšããã·
é ¢é žãâããšãã«ã¢ã©ãã³ãâããšãã«ã°ã«
ã¿ãã³ãããšãã«ã«ã«ããã·ã¡ãã«ã»ã¬ãããã
ã³ã€ã³ããã·ã«é žã®å°ãªããšãïŒçš®ããã³(3)ããª
ã¢ãªãŒã«ã€ãããŸãªã«äºéäœãå«æããããšãç¹
城ãšããæå æ§æš¹èçµæç©ã§ããã ãåŒäžãR1ã¯ïŒšâãClâãNO2âã瀺ããR2ã¯
ã«è©³ããã¯ãé«ååååç©ã®èŠªæ°Žæ§ã®åºŠåãããŸ
ãã¯æ°Žã«å¯Ÿãã溶解床ãå ååŠçã«å€åãããã
æ¹æ³ãçšããæå æ§æš¹èçµæç©ã«é¢ããã è¿å¹Žãæ å ±éã®å¢å ã«äŒŽããçš®ã ã®åéã«ãã
ãŠæå ææã®èŠæ±ãé«ãŸã€ãŠãããããã«å¯Ÿå¿ã
ãæ°ããæå ææã®ç 究ãçãã«è¡ãããŠããã
ãšã¯åšç¥ã®ãšããã§ããããããæ°ããæå ææ
ã«å¯Ÿãã解ååãæå é床ãã·ãšã«ãã©ã€ããã
ãã»ãã·ã³ã°ã®å®¹æããªã©ã®æ§èœèŠæ±ã¯äžæ®µãšå³
ãããªã€ãŠããã æ¬çºæè ãã¯ããã®æ§ãªç¶æ³äžã§éæç 究ãé
ããçµæãç¹éæ55â98744å·å ¬å ±ã«é瀺ããã
ãã«ãåŸæ¥ã®æå ææãšã¯ç°ãªã€ãæ°ããç¹åŸŽã
æããæå æ§æš¹èçµæç©ãåŸãããšã«æåããã
ããããªãããäžèšçµæç©ã§ã¯å åå¿é床ãå®çš
åãåŸãçšå åã§ã¯ãªãã€ãã®ã§ãæ¬çºæè ãã¯
ç 究ãé²ããŠãé«æ床ã®æå æ§æš¹èçµæç©ãèŠåº
ããæ°çµæç©ãææ¡ããããšãããåèšçµæç©ã
ãããäžæ®µãšé«æ床ãèŠæ±ãããæ¬çºæè ãã¯ã
ãã«ç 究ããçµæãæ¬çºæãå®æããã«å°ã€ãã ããªãã¡æ¬çºæã¯ã(1)ããèªäœã§ã¯èŠªæ°Žæ§ãäœ
ããããŸãã¯æ°Žäžæº¶æ§ã§ããããé žæ§ãæããå
åç©ãšã®å ±åäžã§é žå¡©åºçžäºäœçšã«ãã芪氎æ§ã
é«ããªããããŸãã¯æ°Žæº¶æ§ã«ãªãæ§ãªæ§è³ªãæã
ãå¡©åºæ§é«ååååç©ã§ãã€ãŠã該é«ååååç©
ã圢æãåéäœãå¡©åºæ§ã瀺ãåºãæãããã€æ°Ž
溶åªäœã«ãããŠé»äœå·®æ»Žå®ã«ãã枬å®ããŠå¡©åºæ§
åºpka2以äžã瀺ããããã«è©²é«ååååç©äžã®
çªçŽ å«éã0.1ã25åœéïŒKgã§ããå¡©åºæ§é«åå
ååç©ã®å°ãªããšãïŒçš®ã(2)æ¬æ¥é žæ§ã§ãã€ãŠã
å ç §å°ãåããããšã«ããååŠå€åãèµ·ãããŠã
é žæ§ã倱ããããªé žæ§ååç©äžèšäžè¬åŒïŒïŒã§
瀺ãããé žæ§ååç©ãïŒâãããããªããšããã·
é ¢é žãâããšãã«ã¢ã©ãã³ãâããšãã«ã°ã«
ã¿ãã³ãããšãã«ã«ã«ããã·ã¡ãã«ã»ã¬ãããã
ã³ã€ã³ããã·ã«é žã®å°ãªããšãïŒçš®ããã³(3)ããª
ã¢ãªãŒã«ã€ãããŸãªã«äºéäœãå«æããããšãç¹
城ãšããæå æ§æš¹èçµæç©ã§ããã ãåŒäžãR1ã¯ïŒšâãClâãNO2âã瀺ããR2ã¯
ãåŒãââãââã瀺ããã
æ¬çºæã§çšããå¡©åºæ§é«ååååç©ãšã¯ã該é«
ååååç©ã圢æããåéäœãå¡©åºæ§ã瀺ãåºã
æãããã€æ°Žæº¶åªç³»ã«ãããŠé»äœå·®æ»Žå®ã«ãã枬
å®ããŠå¡©åºæ§åºãpka2以äžã瀺ããã®ããã次
ã«äŸç€ºããæ§ãªååå ã«å¡©åºæ§ã瀺ãåºãæãã
åéäœããã³å¿ èŠãªãã°ä»ã®åéäœãçšããŠéçž®
åãéä»å åå¿ãªã©ã®äžè¬çãªéååå¿ã«ãã€ãŠ
補é ãããé«ååååç©ããŸãã¯åæé«åååå
ç©ãããã¯å€©ç¶é«ååååç©ã«å¯ŸããŠååŠçå€æ§
ã«ããå¡©åºæ§ãä»äžããå€æ§é«ååååç©ãå å«
ããã ãã®æ§ãªéåäœã¯ãã¢ããªããŒã®ã¿ãªãããã©
ã³ãã ã³ããªããŒãŸãã¯ãããã¯ã³ããªããŒã§ã
ã€ãŠãããã æ¬çºæã§çšããå¡©åºæ§é«ååååç©ã®äŸãšããŠ
ã¯å¡©åºæ§çªçŽ ååãæãããã®ãæãããããã
ãã®å Žåãé«ååååç©äžã®çªçŽ å«éã0.1ã25
åœéïŒKgã«0.1ã14åœéïŒKgã§ããããšã奜ãŸã
ãã å¡©åºæ§ãæããããªã¢ãããšããŠã¯ãäžèšäžè¬
åŒïŒïŒãïŒïŒã§ç€ºãããåéäœãéååæãš
ãããã®ãæããããïŒ ãåŒäžããRâ²ã¯æ°ŽçŽ ãŸãã¯ççŽ æ°ïŒã10ã®ç
åæ°ŽçŽ æ®åºïŒRâ³ãã¯ççŽ æ°ïŒã10ã®çåæ°Ž
çŽ æ®åºïŒR15ãR16ãR17ã¯ççŽ æ°ïŒã15ã®ã¢ã«ã
ã¬ã³åºïŒR18ãR19ã¯ççŽ æ°ïŒã10ã®çåæ°ŽçŽ æ®
åºãè¡šãããR19ãšR18ã¯å ±åããŠç°ãŸãã¯ç°ç¯
ç°ã圢æããŠããããR20ã¯ççŽ æ°ïŒãïŒã®äœçŽ
ã¢ã«ãã«åºãŸãã¯
ååååç©ã圢æããåéäœãå¡©åºæ§ã瀺ãåºã
æãããã€æ°Žæº¶åªç³»ã«ãããŠé»äœå·®æ»Žå®ã«ãã枬
å®ããŠå¡©åºæ§åºãpka2以äžã瀺ããã®ããã次
ã«äŸç€ºããæ§ãªååå ã«å¡©åºæ§ã瀺ãåºãæãã
åéäœããã³å¿ èŠãªãã°ä»ã®åéäœãçšããŠéçž®
åãéä»å åå¿ãªã©ã®äžè¬çãªéååå¿ã«ãã€ãŠ
補é ãããé«ååååç©ããŸãã¯åæé«åååå
ç©ãããã¯å€©ç¶é«ååååç©ã«å¯ŸããŠååŠçå€æ§
ã«ããå¡©åºæ§ãä»äžããå€æ§é«ååååç©ãå å«
ããã ãã®æ§ãªéåäœã¯ãã¢ããªããŒã®ã¿ãªãããã©
ã³ãã ã³ããªããŒãŸãã¯ãããã¯ã³ããªããŒã§ã
ã€ãŠãããã æ¬çºæã§çšããå¡©åºæ§é«ååååç©ã®äŸãšããŠ
ã¯å¡©åºæ§çªçŽ ååãæãããã®ãæãããããã
ãã®å Žåãé«ååååç©äžã®çªçŽ å«éã0.1ã25
åœéïŒKgã«0.1ã14åœéïŒKgã§ããããšã奜ãŸã
ãã å¡©åºæ§ãæããããªã¢ãããšããŠã¯ãäžèšäžè¬
åŒïŒïŒãïŒïŒã§ç€ºãããåéäœãéååæãš
ãããã®ãæããããïŒ ãåŒäžããRâ²ã¯æ°ŽçŽ ãŸãã¯ççŽ æ°ïŒã10ã®ç
åæ°ŽçŽ æ®åºïŒRâ³ãã¯ççŽ æ°ïŒã10ã®çåæ°Ž
çŽ æ®åºïŒR15ãR16ãR17ã¯ççŽ æ°ïŒã15ã®ã¢ã«ã
ã¬ã³åºïŒR18ãR19ã¯ççŽ æ°ïŒã10ã®çåæ°ŽçŽ æ®
åºãè¡šãããR19ãšR18ã¯å ±åããŠç°ãŸãã¯ç°ç¯
ç°ã圢æããŠããããR20ã¯ççŽ æ°ïŒãïŒã®äœçŽ
ã¢ã«ãã«åºãŸãã¯
ãåŒãïŒããã§R18ã
R19ã¯åèšãšåæ矩ãïŒãè¡šããããŸãïŒïŒ¢ã¯
âNH2ãâCOOHãâCOORâ²â²â²â²ïŒããã§ïŒ²â²â²â²â²ã¯
ççŽ æ°ïŒã10ã®çåæ°ŽçŽ æ®åºã瀺ããïŒãããªã
矀ããéžã°ããåºãè¡šããããšïŒ¢ã¯åæã«åäž
ãŸãã¯çžç°ãªã€ãŠãããããŸãã¯ïŒâã¢ããã
ããã«åºãè¡šãããã äžèšäžè¬åŒïŒïŒã§ç€ºãããåéäœãšããŠã¯ã
âïŒïŒâã¢ãããšãã«ïŒããã©ãžã³ãâïŒïŒ
âã¢ããã·ã¯ãããã·ã«ïŒããã©ãžã³ãâïŒïŒ
âã¢ãããšãã«ïŒâïŒâã¡ãã«ããã©ãžã³ãªã©ã®
ãžã¢ãã³é¡ãâã«ã«ããã·ã¡ãã«ããã©ãžã³ã
âïŒïŒâã«ã«ããã·ã·ã¯ãããã·ã«ïŒããã©ãž
ã³ãâïŒïŒâã«ã«ããã·ãšãã«ïŒâïŒâã¡ãã«
ããã©ãžã³ãªã©ã®Ïâã¢ããé žãããã¯ãããã®
äœçŽã¢ã«ãã«ãšã¹ãã«ãªã©ãããã äžè¬åŒïŒïŒã§ç€ºãããåéäœãšããŠã¯ãããš
ãã°ïŒ®ïŒNâ²âãã¹ïŒã¢ããã¡ãã«ïŒããã©ãžã³ã
âïŒã¢ããã¡ãã«ïŒâNâ²âïŒïŒâã¢ãããšã
ã«ïŒããã©ãžã³ãªã©ã®ãžã¢ãã³é¡ãïŒNâ²âã
ã¹ïŒã«ã«ããã·ã¡ãã«ïŒããã©ãžã³ãïŒNâ²â
ãã¹ïŒã«ã«ããã·ã¡ãã«ïŒâïŒïŒïŒâãžã¡ãã«ã
ãã©ãžã³ãâïŒïŒâã«ã«ããã·ãšãã«ïŒâ
Nâ²âïŒã«ã«ããã·ã¡ãã«ïŒããã©ãžã³ãªã©ã®ãž
ã«ã«ãã³é žãããã¯ãããã®äœçŽã¢ã«ãã«ãšã¹ã
ã«ãé žããã²ã³åç©ãããã³ïŒ®âïŒã¢ããã¡ã
ã«ïŒâNâ²âïŒã«ã«ããã·ã¡ãã«ïŒããã©ãžã³ã
âïŒã¢ããã¡ãã«ïŒâNâ²âïŒã«ã«ããã·ã¡ã
ã«ïŒâïŒâã¡ãã«ããã©ãžã³ãªã©ã®Ïâã¢ããé ž
é¡ãããã¯ãããã®äœçŽã¢ã«ãã«ãšã¹ãã«é¡ãªã©
ãããã äžè¬åŒïŒïŒã§ç€ºãããåéäœãšããŠã¯ãããš
ãã°ïŒ®ïŒNâ²âãã¹ïŒïŒâã¢ãããšãã«ïŒâã¡ã
ã«ã¢ãã³ãïŒïŒ®âãã¹ïŒïŒâã¢ãããããã«ïŒ
âã·ã¯ãããã·ã«ã¢ãã³ãªã©ã®ãžã¢ãã³é¡ãïŒ
âãã¹ïŒã«ã«ããã·ã¡ãã«ïŒâã¡ãã«ã¢ãã³ã
âã«ã«ããã·ã¡ãã«ââïŒïŒâã«ã«ããã·ãš
ãã«ïŒâã¡ãã«ã¢ãã³ãªã©ã®ãžã«ã«ãã³é žé¡ãã
ãã¯ãããã®äœçŽã¢ã«ãã«ãšã¹ãã«ãé žããã²ã³
åç©ãããã³ïŒ®âïŒã¢ããã¡ãã«ïŒââïŒã«ã«
ããã·ã¡ãã«ïŒâã¡ãã«ã¢ãã³ãâïŒã¢ããã¡
ãã«ïŒââïŒïŒâã«ã«ããã·ãšãã«ïŒâã€ãœã
ããã«ã¢ãã³ãªã©ã®Ïâã¢ããé žé¡ãããã¯ãã
ãã®äœçŽã¢ã«ãã«ãšã¹ãã«é¡ãªã©ãããã äžè¬åŒïŒïŒã§ç€ºãããåéäœãšããŠã¯ãããš
ãã°ïŒ®ïŒNâ²âãžã¡ãã«âïŒNâ²âãã¹ïŒïŒâã¢
ãããããã«ïŒãšãã¬ã³ãžã¢ãã³ãïŒNâ²âãž
ã·ã¯ãããã·ã«âïŒNâ²âãã¹ïŒïŒâã¢ããã
ããã«ïŒãããµã¡ãã¬ã³ãžã¢ãã³ãªã©ã®ãžã¢ãã³
é¡ãïŒNâ²âãžã¡ãã«âïŒNâ²âãã¹ïŒã«ã«ã
ãã·ã¡ãã«ïŒãšãã¬ã³ãžã¢ãã³ãïŒNâ²âãžã¡
ãã«âïŒNâ²âãã¹ïŒïŒâã«ã«ããã·ãããã«ïŒ
ãããµã¡ãã¬ã³ãžã¢ãã³ãªã©ã®ãžã«ã«ãã³é žé¡ã
ããã¯ãããã®äœçŽã¢ã«ãã«ãšã¹ãã«ãé žããã²
ã³åç©ãïŒNâ²âãžã¡ãã«ââïŒã¢ããã¡ã
ã«âNâ²âïŒã«ã«ããã·ã¡ãã«ïŒãšãã¬ã³ãžã¢ã
ã³ãïŒNâ²âãžã¡ãã«ââïŒã¢ããã¡ãã«ïŒ
âNâ²âïŒã«ã«ããã·ãšãã«ïŒãããµã¡ãã¬ã³ãž
ã¢ãã³ãªã©ã®Ïâã¢ããé žãããã¯ãããã®äœçŽ
ã¢ã«ãã«ãšã¹ãã«é¡ãªã©ãããã äžè¬åŒïŒïŒã§ç€ºãããåéäœãšããŠã¯ãããš
ãã°ïŒâã¡ãã«âïŒâïŒïŒ®ïŒNâ²âãžã¡ãã«ã¢ã
ãã¡ãã«ïŒâïŒïŒïŒâãžãªããµâïŒïŒ11âãŠã³ã
ã«ã³ãžã¢ãã³ãïŒâãšãã«âïŒâïŒïŒ®ïŒïŒ®âãžã¡
ãã«ã¢ããã¡ãã«âïŒïŒïŒâãžãªããµâïŒïŒ11â
ãŠã³ãã«ã³ãžã¢ãã³ãïŒïŒïŒâãã¹âïŒïŒ®ïŒ
Nâ²âãžã¡ãã«ã¢ããã¡ãã«ïŒâïŒïŒïŒâãžãªããµ
âïŒïŒ11âãŠã³ãã«ã³ãžã¢ãã³ãªã©ã®ãžã¢ãã³é¡
ãããã ãããã®å¡©åºæ§ãæããåéäœã¯ïŒçš®ä»¥äžäœµçš
ããŠãããã æ¬çºæã«çšããããªã¢ããã®éåæåãšããŠã¯
åèšäžè¬åŒïŒïŒãïŒïŒã§ç€ºãããåéäœã®ã»
ãã«ãéåžžã®ããªã¢ããã®éåã«çšããããèèª
æããã³ïŒãŸãã¯è³éŠæã®ãžã«ã«ãã³é žããžã¢ã
ã³ãÏâã¢ããé žãã©ã¯ã¿ã ãªã©ãããã å¡©åºæ§ãæããããªãšã¹ãã«ãšããŠã¯ãäžèšäž
è¬åŒïŒïŒãïŒïŒã§ç€ºãããåéäœãéåå
æãšãããã®ãããïŒ ãåŒäžããRâ²ãRâ³ããR15ãR16ãR17ã
R18ãR19ãR20ã¯åèšãšåæ矩ãAâ²ãBâ²ã¯âOHã
âCOOHãâCOORâ²â²â²â²ïŒããã§ïŒ²â²â²â²â²ã¯ççŽ æ°ïŒ
ã10ã®çåæ°ŽçŽ æ®åºã瀺ããïŒãããªã矀ããéž
ã°ããåºãè¡šãããAâ²ãšBâ²ã¯åæã«åäžãŸãã¯
çžç°ãªã€ãŠããããã äžèšäžè¬åŒïŒïŒã§ç€ºãããåéäœãšããŠã¯ã
å ·äœçã«ã¯ïŒ®ïŒNâ²âãã¹ïŒã«ã«ããã·ã¡ãã«ïŒ
ããã©ãžã³ãïŒNâ²âãã¹ïŒã«ã«ããã·ã¡ãã«ïŒ
âïŒïŒïŒâãžã¡ãã«ããã©ãžã³ãâïŒïŒâã«ã«
ããã·ãšãã«ïŒâNâ²âïŒã«ã«ããã·ã¡ãã«ïŒã
ãã©ãžã³ãªã©ã®ãžã«ã«ãã³é žé¡ãããã¯ãããã®
äœçŽã¢ã«ãã«ãšã¹ãã«ãé žããã²ã³åç©ãïŒ
Nâ²âãã¹ïŒããããã·ã¡ãã«ïŒããã©ãžã³ãïŒ
Nâ²âãã¹ïŒïŒâããããã·ããã«âïŒïŒïŒâãž
ã¡ãã«ããã©ãžã³ãïŒNâ²âãã¹ïŒïŒâããã
ãã·ã·ã¯ããããã«ïŒããã©ãžã³ãïŒNâ²âã
ã¹ïŒïŒâã¡ãã«âïŒâããããã·ããã«ïŒããã©
ãžã³ãªã©ã®ã°ãªã³ãŒã«é¡ãæããããšãã§ããã äžè¬åŒïŒXIïŒã§ç€ºãããåéäœãšããŠã¯ãããš
ãã°ïŒ®ïŒNâ²âãã¹ïŒã«ã«ããã·ã¡ãã«ïŒâã¡ã
ã«ã¢ãã³ãâã«ã«ããã·ã¡ãã«ââïŒïŒâã«
ã«ããã·ãšãã«ïŒâã¡ãã«ã¢ãã³ãªã©ã®ãžã«ã«ã
ã³é žé¡ãããã¯ãããã®äœçŽã¢ã«ãã«ãšã¹ãã«ã
é žããã²ã³åç©ããã³ïŒ®ïŒNâ²âãã¹ïŒïŒâãã
ããã·ãšãã«ïŒã¢ãã³ãïŒNâ²âãã¹ïŒïŒâã
ãããã·ãããã«ïŒâã€ãœãããã«ã¢ãã³ãªã©ã®
ã°ãªã³ãŒã«é¡ã§ããã äžè¬åŒïŒXIIïŒã§ç€ºãããåéäœãšããŠã¯ãããš
ãã°ïŒ®ïŒNâ²âãžã¡ãã«âïŒNâ²âãã¹ïŒã«ã«ã
ãã·ã¡ãã«ïŒãšãã¬ã³ãžã¢ãã³ãïŒNâ²âãžã¡
ãã«âïŒNâ²âãã¹ïŒïŒâã«ã«ããã·ãããã«ïŒ
ãããµã¡ãã¬ã³ãžã¢ãã³ãªã©ã®ãžã«ã«ãã³é žé¡ã
ããã¯ãããã®äœçŽã¢ã«ãã«ãšã¹ãã«ãé žããã²
ã³åç©ãïŒNâ²âãžã¡ãã«âïŒNâ²âãã¹ïŒïŒ
âããããã·ãšãã«ïŒãšãã¬ã³ãžã¢ãã³ãïŒ
Nâ²âãžã·ã¯ãããã·ã«âïŒNâ²âãã¹ïŒïŒâã
ãããã·ãšãã«ïŒãããµã¡ãã¬ã³ãžã¢ãã³ãïŒ
Nâ²âãžã¡ãã«âïŒNâ²âãã¹ïŒïŒâããããã·
ãšãã«ïŒâïŒïŒïŒïŒïŒâããªã¡ãã«âãããµã¡ã
ã¬ã³ãžã¢ãã³ãªã©ã®ã°ãªã³ãŒã«é¡ãããã äžè¬åŒïŒïŒã§ç€ºãããåéäœãšããŠã¯ãã
ãšãã°ïŒâã¡ãã«âïŒâïŒïŒ®ïŒïŒ®âãžã¡ãã«ã¢ã
ãã¡ãã«ïŒâïŒïŒïŒâãããã³ãžãªãŒã«ãïŒâã¡
ãã«âïŒâïŒïŒ®ïŒïŒ®âãžã€ãœãããã«ã¢ããã¡ã
ã«ïŒâïŒïŒïŒâãããã³ãžãªãŒã«ãïŒâã¡ãã«â
ïŒâãããªãžãã¡ãã«âïŒïŒïŒâãããã³ãžãªãŒ
ã«ããã¹ïŒïŒâïŒïŒ®âãžã€ãœãããã«ã¢ããã¡
ãã«ïŒâïŒïŒïŒâãããã³ãžãªãŒã«ãªã©ã®ã°ãªã³
ãŒã«é¡ãæããããã ãããã®å¡©åºæ§ãæããåéäœã¯ïŒçš®ä»¥äžäœµçš
ããŠãããã æ¬çºæã«ãããŠçšããããªãšã¹ãã«ã®éååæ
ãšããŠã¯ãåèšäžè¬åŒïŒïŒãïŒïŒã§ç€ºãã
ãåéäœã®ã»ãã«éåžžã®ããªãšã¹ãã«ã®éåã«çš
ããããèèªæããã³ïŒãŸãã¯è³éŠæã®ãžã«ã«ã
ã³é žãããã¯ãã®äœçŽã¢ã«ãã«ãšã¹ãã«ãã°ãªã³
ãŒã«ããªãã·é žãªã©ã䜵çšããŠãããã å¡©åºæ§ãæããããã«ç³»ããªããŒãšããŠã¯ãïŒ
âããã«ããªãžã³ã®éåäœããŸãã¯äžèšäžè¬åŒ
ïŒïŒïŒ ãåŒäžãRâ²ãRâ³ããR15ã¯åèšãšåæ矩ã
ã¯ãšã¹ãã«çµåãŸãã¯ã¢ããçµåãè¡šãããã ã§ç€ºãããåéäœãéååæãšãããã®ãæãã
ããã äžèšäžè¬åŒïŒïŒã§ç€ºãããåéäœãšããŠ
ã¯ãããšãã°ïŒâïŒïŒ®ïŒNâ²âãžã¡ãã«ã¢ããïŒ
ãšãã«ã¡ã¿ã¯ãªã¬ãŒããïŒâïŒïŒ®ïŒNâ²âãžãšã
ã«ïŒãããã«ã¡ã¿ã¯ãªã¬ãŒããªã©ã®ã¡ã¿ã¯ãªã¬ãŒ
ãé¡ãïŒâïŒïŒ®ïŒNâ²âãžã¡ãã«ã¢ããïŒããã
ã«ã¡ã¿ã¯ãªã«ã¢ãããïŒâïŒïŒ®ïŒNâ²âãžãšãã«
ã¢ããïŒãããã«ã¡ã¿ã¯ãªã«ã¢ãããªã©ã®ã¡ã¿ã¯
ãªã«ã¢ããé¡ãªã©ãããã ãããã®å¡©åºæ§ãæããåéäœã¯ïŒçš®ä»¥äžäœµçš
ããŠãããã æ¬çºæã«ãããŠçšããããããã«ç³»ããªããŒã®
éååæãšããŠã¯ãåèšïŒâããã«ããªãžã³ãŸã
ã¯äžè¬åŒïŒïŒã§ç€ºãããåéäœã®ä»ã«éåžžã®
ããã«ããªããŒã®éåã«çšããããããã«ã¢ãã
ãŒã䜵çšããŠãããã å¡©åºæ§ãæããããªãšãŒãã«ãšããŠã¯ãå¡©åºæ§
ãæãããžãªãŒã«ãããšãã°åèšäžè¬åŒïŒïŒ
ã§è¡šãããããžãªãŒã«ãããã¯ãããã®æ©èœçèª
å°äœããéçž®åã«ããåŸããããã®ããŸãã¯ãã®
ä»ã®ãžãªãŒã«ãããã¯ãããã®æ©èœçèªå°äœãšã
éçž®åããŠåŸããããã®ãããã ãã®ä»ã®ãžãªãŒã«ãããã¯ãã®æ©èœçèªå°äœãš
ããŠã¯ãšãã¬ã³ã°ãªã³ãŒã«ããããã¬ã³ã°ãªã³ãŒ
ã«ãããã©ã¡ãã¬ã³ã°ãªã³ãŒã«ããããµã¡ãã¬ã³
ã°ãªã³ãŒã«ããžãšãã¬ã³ã°ãªã³ãŒã«ãååé200
ã3000ã奜ãŸããã¯200ã1000ã®ããªãšãã¬ã³ã°
ãªã³ãŒã«ãããªããã©ã¡ãã¬ã³ã°ãªã³ãŒã«ããã¹
ïŒïŒâããããã·ããšãã«ïŒã¡ã¿ã³ãïŒïŒïŒâã
ã¹ïŒïŒâããããã·ããšãã«ïŒã·ã¯ããããµã³ã
ãã¹ïŒïŒâããããã·ããšãã«ïŒããªãšãŒãã«ã
ãã¹ïŒïŒâããããã·ããšãã«ïŒã¹ã«ãã³ãïŒïŒ
2â²âãžããããã·ãã³ãŸããšãã³ãïŒïŒ2â²âãžã
ãããã·âïŒïŒ4â²âãžã¡ããã·ãã³ãŸããšãã³ã
ã¯ã¬ãŸãŒã«ãã¬ãŸã«ã·ã³ããããããã³ãïŒïŒïŒ
âãžããããã·ã¢ã»ãããšãã³ãïŒïŒïŒâãžãã
ããã·ããã¿ã¬ã³ãïœâãïœâãŸãã¯ïœâãã·ãª
ã¬ã³ã°ãªã³ãŒã«ãªã©ãæããããšãã§ããã äžèšããªãšãŒãã«ã¯éåžžã®æ¹æ³ã«åŸãéçž®åã
ãŠè£œé ããããã®ã§ããã å€æ§é«ååååç©ã®äŸãšããŠã¯ããšãã¬ã³ã¢ã
ã³ã«ãã€ãŠå€æ§ãããã»ã«ããŒã¹èªå°äœãããšã
ã°ã¢ãããšãã«ã»ã«ããŒã¹ããŸãã¯é«ååååç©
ã®äžè¬çãªå€æ§æ³ãšããŠç¥ãããŠããã°ã©ããå
å¿ã«ããå¡©åºæ§ãä»äžãããå€æ§é«ååååç©ãª
ã©ãæããããã ããã«ãæ¬çºæã®çµæç©ã«ãããŠã¯ãå¡©åºæ§ã
æããé«ååååç©ã«å ããä»çš®ã®é«ååååç©
ã䜵çšããããšãå¯èœã§ããã 該塩åºæ§é«ååååç©ãšåèšé žæ§ååç©ãšã®çµ
æç©ã«ãããæ··åéããã³æ··åå²åã¯ãäž¡è ã®çµ
åãããçš®é¡ã«ãã€ãŠç°ãªãããŸãå®é䜿çšãã
æã«èŠæ±ãããç¹æ§ïŒããšãã°å ç §å°ååŸã«ãã
ã芪氎æ§ãŸãã¯æ°Žæº¶æ§ã®å·®ãååŠçæ§è³ªãåå¿é
床ãªã©ïŒã«ããéžæãããããå šçµæç©äžã«å å
å¿æ§ååç©ã0.4ã700ïœïŒKgã®å²åã§å«æãããŠ
ãããäž¡è ã®é åå²åã¯ãé žæ§ååç©ã®é žæ§åºãš
å¡©åºæ§é«ååååç©ã«å«ãŸããå¡©åºæ§çªçŽ ã®åœé
æ¯ã0.02ãïŒã«ãªãããã«ããã®ã奜ãŸããã æ¬çºæã«ãããŠããªã¢ãªãŒã«ã€ãããŸãªã«äºé
äœã¯äžèšäžè¬åŒïŒïŒã§ç€ºããã該äºéäœã¯å
ç §å°ãåããããšã«ããéé¢åºãçºçããé žæ§å
åç©ã®é žæ§åºŠãäœäžããååŠå€åãæ¹èµ·ãããã¯
ä¿é²ãããããã«ãã€ãŠæ床ãèããåäžããã åŒäžãArãArâ²ãArâ³ã¯ããããçæåºãæã
ããæããªãã¢ãªãŒã«åºã瀺ãã ãªãæ¬çºæã«ãããŠãArãããšãã«åºã®å Žå
ã«ã¯ãããšãã«åºã®ãªã«ãäœã«çœ®æåºãæããã
ã®ããŸãArãïŒâãããã«åºã®å Žåã«ã¯ãïŒâ
ãããã«åºã®ïŒäœã«çœ®æåºãæãããã®ã奜ãŸã
ãã å ·äœçã«ãããšãã°ïŒâïŒïœâã¯ãã«ããšã
ã«ïŒâïŒïŒïŒâãžããšãã«ã€ãããŸãªã«äºéäœã
ïŒâïŒïœâã¯ãã«ããšãã«ïŒâïŒïŒïŒâïŒïœâãž
ã¯ãã«ããšãã«ïŒã€ãããŸãªã«äºéäœãïŒâïŒïœ
âã¯ãã«ããšãã«ïŒâïŒïŒïŒâïŒïœâãžã¢ãã·
ã«ïŒã€ãããŸãªã«äºéäœãïŒâïŒïœâãã«ãªãã
ãšãã«ïŒâïŒïŒïŒâãžããšãã«ã€ãããŸãªã«äºé
äœãïŒâïŒïœâã¡ããã·ããšãã«ïŒâïŒïŒïŒâãž
ããšãã«ã€ãããŸãªã«äºéäœãïŒâïŒïœâããã
ããšãã«ïŒâïŒïŒïŒâãžããšãã«ã€ãããŸãªã«äº
éäœãïŒâïŒïœâãããããšãã«ïŒâïŒïŒïŒâãž
ããšãã«ã€ãããŸãªã«äºéäœãïŒâïŒïœâããã¢
ããšãã«ïŒâïŒïŒïŒâãžããšãã«ã€ãããŸãªã«äº
éäœãïŒâïŒïŒâãããã«ïŒâïŒïŒïŒâãžããšã
ã«ã€ãããŸãªã«äºéäœãïŒâïŒïŒâã¯ãã«âïŒâ
ãããã«ïŒâïŒïŒïŒâãžããšãã«ã€ãããŸãªã«äº
éäœãªã©ãæããããšãã§ããããªããåèšäºé
äœã¯åäžã®ããã€ã³ã®äºéäœã瀺ããŠããããå¿
è«ç°ãªãããã€ã³ã®äºéäœãå«ãŸããããšãã°ïŒ
âããšãã«ã2â²âïŒïœâã¯ãã«ããšãã«ãïŒïŒ
4â²ïŒïŒïŒ5â²âããã©ããšãã«ïŒãã€ãããŸãŒã«ã
ïŒâïŒïœâã¯ãã«ããšãã«ïŒâ2â²âããšãã«ã
ïŒïŒïŒâïŒãžïœã¢ãã·ã«ïŒâïŒïŒ5â²âãžããšãã«
ãã€ãããŸãŒã«ãªã©ãããã ãªããåèšããªã¢ãªãŒã«ã€ãããŸãªã«äºéäœ
ã¯ãå šçµæç©ã«å¯ŸããŠïŒééïŒ ã50ééïŒ ã奜ãŸ
ããã¯ïŒã20ééïŒ å«æãããåèšé žæ§ååç©ã«
察ãã該äºéäœã®åœéæ¯ã0.1ã2.0ã«ãªãããã«
ããã®ã奜ãŸããã æ¬çºæçµæç©ã«ãããŠãããã«å å¢æå€ãæ·»å
ããããšã«ãã€ãŠæ床ãäžããããšãã§ããã æ¬çºæã«çšããããå å¢æå€ãšããŠã¯ãããšã
ã°ïŒïŒ4â²âãã¹ãžã¡ãã«ã¢ãããã³ãŸããšãã³ã
ããªããµã³ãã³ããã«ãªã¬ãã³ãããªããããã«
ãªã¬ãã³ãªã©ã®è³éŠæã±ãã³ç³»ååç©ãïŒïŒ4â²â
ãã¹ãžã¡ãã«ã¢ããããªãã³ãŸããšãã³ãªã©ã®è³
éŠæããªã±ãã³ååç©ããã³ãŸããã³ããžã¯ãã«
ãã³ãŸããã³ãããã©ã¯ãã«ãã³ãŸããã³ããžã¯
ãã«ãããããã³ãããšãã³ãã¬ã³ããã³ããžã¯
ãã«ã¢ã³ãã©ããã³ããžãããã¢ã³ãã©ããã³ã
ã¢ãªã¶ãªã³ããã³ãºã¢ã³ãã©ããã³ãªã©ã®ããã³
ç³»ååç©ããžããããã«ãªã¬ã³ãããã©ãããã
ã«ãªã¬ã³ãããªããããã«ãªã¬ã³ããããã¢ã»ã
ããã³ãïŒïŒïŒïŒïŒâããªãããã¢ããªã³ãªã©ã®
è³éŠæãããååç©ãããªããšãã«ãã©ãŸãªã³ãª
ã©ã®ããªã¢ãªãŒã«ãã©ãŸãªã³ç³»ååç©ãããã©ã
ãšãã«ã€ãããŸãŒã«ãããªããšãã«ã€ãããŸãŒã«
ãªã©ã®ã¢ãã€ãããŸãŒã«ç³»ååç©ããã«ãªã¬ã»ã€
ã³ããšãªã·ã³ïŒ¹ãããŒãºãã³ã¬ã«ããšãªããã·ã³
ããããã·ã³ãªã©ã®ããµã³ãã³ç³»ååç©ãã¢ã¯
ãªãã©ãã³ããªããã©ãã³ãªã©ã®ã¢ã¯ãªãžã³ç³»å
åç©ãïŒââãžã¡ãã«ã¢ããã¯ããªã³ãªã©ã®ã¯
ããªã³ç³»ååç©ããã¢ãŒã«ãã«ãŒãããã ãã¢ãŒ
ã«ãã«ãŒãããã ã ã¯ã¬ãŸãŒã«ã°ãªãŒã³ãªã©ã®ã
ãªããšãã«ã¡ã¿ã³ç³»ååç©ãªã©ããããäžã§ãè³
éŠæã±ãã³ç³»ååç©ãããã³ç³»ååç©ãè³éŠæã
ããååç©ãããªã¢ãªãŒã«ãã©ãŸãªã³ç³»ååç©ã
ã¯ããªã³ç³»ååç©ã奜ãŸããã ãªãåèšå å¢æå€ã¯ã å šçµæç©ã«å¯ŸããŠ0.1ã10ééïŒ ã奜ãŸããã¯
0.1ã5.0ééïŒ æ·»å ããŠãããã æ¬çºæã®çµæç©ã«ã¯ãå¿ èŠãªãã°å 掻æ§ååç©
ã®å ±åäžã§ãå ç §å°ãåããŠååãšããŠé žæ§ã倱
ããªãæ§ãªé žæ§ååç©ã䜵çšããŠãå ç §å°ååŸã®
芪氎æ§ãŸãã¯æ°Žæº¶æ§ã®å·®ãå¶åŸ¡ããããšãå¯èœã§
ããã ãŸããåæ§ã®ç®çããã³ååŠçæ§è³ªã®å¶åŸ¡ã®ã
ãã«ãåŸæ¥ããç¥ãããŠããå äžæº¶åå€ã䜵çšã
ãããšãå¿è«å¯èœã§ããã 䜵çšã§ããå äžæº¶åå€ãšããŠã¯ãããšãã°ã¢ã¯
ãªã«é žãã¡ã¿ã¯ãªã«é žãã¡ãã«ã¢ã¯ãªã¬ãŒããã¡
ãã«ã¡ã¿ã¯ãªã¬ãŒããã·ã¯ãããã·ã«ã¢ã¯ãªã¬ãŒ
ããã¢ã¯ãªã«ã¢ãããã¡ã¿ã¯ãªã«ã¢ãããâã¡
ãããŒã«ã¢ã¯ãªã«ã¢ãããïœâãããã·ã¡ãã«ã¢
ã¯ãªã«ã¢ããããããªãŠã ã¢ã¯ãªã¬ãŒããã¢ã³ã¢
ããŠã ã¢ã¯ãªã¬ãŒããã¢ã¯ãªããããªã«ãã¹ãã¬
ã³ãã¹ãã¬ã³ã¹ã«ãã³é žãœãŒããããã«ããªãžã³
çã®äžé£œåäºéçµåãïŒåæããåéäœãããã
ã¯ã°ãªã·ãžã¡ã¿ã¯ãªã¬ãŒããã¢ãªã«ã¡ã¿ã¯ãªã¬ãŒ
ãããšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãããšãã¬
ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒâããã
ã³ãžãªãŒã«ã¢ã¯ãªã¬ãŒããïŒïŒïŒâãããã³ãžãª
ãŒã«ã¡ã¿ã¯ãªã¬ãŒããããªã¡ãããŒã«ãããã³ã
ãªã¢ã¯ãªã¬ãŒããããªã¡ãããŒã«ãããã³ããªã¡
ã¿ã¯ãªã¬ãŒããããªã¢ã¯ãªãã€ã«ãªãã·ãšãã«ã
ã¹ããšã€ããã¡ãã¬ã³ãã¹ã¢ã¯ãªã¢ãããã¡ãã¬
ã³ãã¹ã¡ã¿ã¯ãªã¢ããçã®äžé£œåäºéçµåãïŒå
以äžæããåéäœãããã æ¬çºæã®çµæç©ã®èª¿è£œã«ããã€ãŠã¯ãå¡©åºæ§é«
ååååç©ãšé žæ§ååç©ãããªã¢ãªãŒã«ã€ãããŸ
ãªã«äºéäœããã³å¿ èŠãªãã°å å¢æå€ãé©åœãªæº¶
åªã«æº¶è§£ããŠåäžã«æ··åããå¡©åºæ§é«ååååç©
ãšé žæ§ååç©ãšã®éã§é žå¡©åºå¯Ÿã圢æãããæ¹æ³
ãæ¡çšããããé©åœãªæº¶åªãšããŠã¯ã¡ã¿ããŒã«ã
ãšã¿ããŒã«ãã€ãœãããããŒã«ã®ãããªäœçŽã¢ã«
ã³ãŒã«ãã¢ã»ãã³ãã¡ãã«ãšãã«ã±ãã³ã®ãããª
ã±ãã³é¡ãã¡ãã«ã»ããœã«ãããšãã«ã»ããœã«ã
ãªã©ã®ãšã¹ãã«é¡ããã«ãšã³ããã·ã¬ã³ãªã©ã®è³
éŠæååç©ãŸãã¯ãããã®ïŒçš®ä»¥äžã®æ··åç©ãçš
ããããšãã§ãããããããçšããå¡©åºæ§é«åå
ååç©ãåžžæž©ã§æ¶²äœã§ãããããŸãã¯ãã®èç¹ã
è»åç¹ãæµåç¹ãæ¯èŒçäœãå Žåã«ã¯ã溶åªã䜿
çšããããšãªãçŽæ¥äž¡è ãæ··åããæ¹æ³ãæ¡çšã
ããã ãã®æ§ã«ããŠèª¿è£œãããæ¬çºæã®çµæç©ã¯ãã
ãšãã°æº¶æ¶²æµå»¶æ³ãç±ãã¬ã¹æ³ã泚åæ³ã溶èæŒ
ãåºãæ³ãªã©ã«ããææã®åã¿ã®èããã€ã«ã ã
ã·ãŒãç¶ç©ãšæãããšãããããŸããããããæ¥
çå±€ãä»ããŠãŸãä»ããã«æ¯æäœã«ç©å±€ããããš
ãã§ãããæ¯æäœãšããŠã¯ã¹ããŒã«ãã¢ã«ãããŠ
ã ããã©ã¹ããã¯ãã€ã«ã ãã¬ã©ã¹ãªã©ä»»æã®ã
ã®ã䜿çšã§ããã æ¬çºæã®çµæç©ã«å¯Ÿããæå å æºãšããŠã¯ãã
ãšãã°å皮氎éç¯ãççŽ ã¢ãŒã¯ç¯ããã»ãã³ã©ã³
ãã玫å€ç·è¢å ç¯ãªã©400mΌ以äžã®æ³¢é·ã®å ç·ã«
å¯ããã®ã奜ãŸããã ãããã®å æºããã®æ¬çºæã®çµæç©ã«å¯Ÿããå
ç §æ¹æ³ãšããŠã¯ãå éééšåããã³é®å éšåãã
æãææã®ç»åãŸãã¯ãã¿ãŒã³åãæããããã
ããã¬ãã€ã«ã ãŸãã¯ããžãã€ã«ã ãéããŠè¡ã
ããããããã¯ããã®æ§ãªå æºããã®å ããŒã ã«
ããæ¬çºæã®çµæç©ã®ç»äžããææã®ç»åãŸãã¯
ãã¿ãŒã³åãè»è·¡ãšããŠèµ°æ»ããããšã«ããè¡ã
ããã å ç §å°ã«ããæ¬çºæã®çµæç©ã®é¢äžã«å ã圢æ
ãããæœåã¯ãå ç §å°ãåããªãã€ãéšåãšæ¯èŒ
ããŠèŠªæ°Žæ§ãäœäžããŠããããæ®ãã©çæ°Žæ§ã«å€
åããŠããããã®ããšã¯å ç §å°éšåã®æ¥µæ§ãéç §
å°éšåã®ãããããäœäžããŠãããšè¡šçŸããããš
ãã§ããã äžã€ã®é¢äžã«åŸããã極æ§ã®ç°ãªãç»åæœåãŸ
ãã¯ãã¿ãŒã³æœåã¯ãäœãã®è¿œå çåŠçããè¡ã
ãã«ãã®ãŸãŸå©çšããããšãã§ãããŸãäœããã®
çŸååŠçãæœãããŠå©çšããããšãã§ããã çŸååŠçã溶åªãå¿ èŠãšããå Žåã溶åªã®éžæ
ã¯ãå ç §å°éšåãšéç §å°éšåã®æ¥µæ§ã®å·®ã«å¯Ÿå¿ã
ãŠä»»æã«è¡ããåŸããäžè¬çã«ã¯æ°Žã®å©çšãæã
䟿å©ã§ããããã€å¥œãŸããããæ¬çºæã®çµæç©ã«
é¢ããŠã¯æ°ŽçŸåã®æ¡çšãå¯èœã§ããããã®å Žåã
PH5.5ã7.5ã®æ°Žã®äœ¿çšã奜ãŸããã æ¬çºæã®çµæç©ã®å¹æçå©çšã¯ãåè¿°ã®æ§ã«ã
äž»ãšããŠèç¶ããã€ã«ã ç¶ãŸãã¯ã·ãŒãç¶ãªã©ã®
æ¯èŒçèãå±€ã«ãã€ãŠãªããããã€å€ãã®å Žåã¯
é©åœãªæ¯æäœãšã®ç©å±€ç©ãšããŠå©çšããããå ·äœ
çå©çšã«åœã€ãŠã¯ãç©ç¶ç©ã®é¢äžã«å ç §å°ãè¡ã€
ãŠåŸãã極æ§ãŸãã¯èŠªæ°Žæ§ã®å·®ãå±€ç¶ç©ã®åœ¢æ ã
å€ããããšãªãå©çšããå Žåãšãæ°Žã«ãããšãã
ã³ã°ãŸãã¯ãŠãªãã·ãŠã¢ãŠãæäœãå ããŠå©çšã
ãå Žåããããåè ã®å©çšäŸã¯ã極æ§ã®å·®ããå¿
ç¶çã«çºçããå°é»æ§ã®å·®ãå©çšããé»ååççš
éãéé»å°å·çšéããããããã«æè²æ§ã®å·®ãå©
çšããç»åèšé²ææãšããŠãçšãããããäžæ¹ã
åŸè ã®å©çšäŸã¯ãåçš®ãã¬åã¬ãžã¹ããšããŠããŸ
ããªãã»ããå°å·ççšãšããŠã®çšéãããããã
ã«ã¬ãªãŒããšããŠã¯åžçå°å·çšæš¹èçãããŒã ã
ã¬ãŒããé³åçšæš¹èåããšã³ãã¹å å·¥çšæš¹èåãª
ã©ã®å©çšãæããããã æ¬çºæã®çµæç©ã¯ãå以ã€ãŠææãŸãã¯é¡æã
æ··ããç³»ã§ãå©çšããããã¿ãŒã³é®å çšåçš®ãã¹
ãã³ã°çšéã«ãæå¹ãªææãæäŸããã 以äžãããæ§æãããªãæ¬çºæçµæç©ã®ç¹é·ãš
ãããšããã¯ããã®äž»æåã§ããïŒçš®ã®ååç©
ïŒå¡©åºæ§é«ååååç©ãé žæ§ååç©ããã³ããªã¢
ãªãŒã«ã€ãããŸãªã«äºéäœïŒã®åã ã®éžæçš®ãã
ã³çžäºã®éæ¯ãåºãç¯å²ã«ãããçµã¿åãããã
ãšã«ãããå ç §å°ã«ãã極ãããããªèŠªæ°Žæ§ã®å€
åãããæ°Žäžæº¶æ§ä¹è³æ°Žæº¶æ§ãšãã倧ããªå€åã«
ãããææã®æ§èœå€åãçºçŸããåŸãããšã§ã
ãããŸããæ¬çºæã®çµæç©ã®å åå¿ã¯é£éåå¿ã«
äŸã€ãŠé²è¡ãããã®ã§ã¯ãªãã®ã§ã解ååã極ã
ãŠé«ããæèšããã°ãæ¬çºæã®çµæç©ã¯æš¹èã®ïŒ
次å åå¿ãšç°ãªããå ç §å°åŸã®äœç©åçž®ãããªã
ã¡åã®å šã䌎ãããåŸã€ãŠé«ã解ååãä¿æãã
ããšãã§ãããå ããŠãïŒæ¬¡å åããŠããªãé«å
åååç©ã¯æ¬è³ªçã«æº¶åªå¯æº¶ã§ããããšãããæ¬
çºæã®ååç©ã«ãããããšãã°ã¬ãžã¹ãåãã¬ãª
ãŒãåã補é ããå Žåã«ãäžæŠåŸãããåã®ä¿®æ£
çæ¶å»ãå¯èœãšãªããæŽã«æ¬çºæã®çµæç©ã®å å
å¿ã¯ãå éååå¿ã®ããšãé žçŽ ã«ãã€ãŠåŠšå®³ãã
ãããšã¯ãªãã®ã§ã空æ°äžããã®é žçŽ ååã®æ¡æ£
ãèµ·ãæãèèç¶æ ã§ã®åå¿é床ã«ãäœãã®æ¯é
ãçããªããããããŠç±çãªå®å®æ§ãé«ããæ¬çº
æã®çµæç©ã§ã¯æ¥µããŠæ°žãã·ãšã«ãã©ã€ããä¿èšŒ
ãããã æ¬çºæã®çµæç©ã®ä»äžã€ã®ç¹é·ã¯ãã¬ãžã¹ãå
ãã¬ãªãŒãåãåŸãå Žåã®ãšããã³ã°ãŸãã¯ãŠãª
ãã·ãŠã¢ãŠãã«éããŠãåãªãæ°Žãæ¡çšã§ããç¹
ã§ããããã®ããšã¯å®å šæ§ã®é¢ã§ç¹ã«å¥œãŸããäœ
æ¥ç°å¢ãšæäœæ§ãçŽæããããšã«ãªããããã«æ¬
çºæçµæç©ã¯ãå åå¿é床ã極ããŠéããããå
åã«å®çšãåŸããã®ã§ããã 次ã«å®æœäŸã瀺ããæ¬çºæãæŽã«å ·äœçã«èª¬æ
ããããªããå®æœäŸäžãéšãšããã¯ç¹èšããªãé
ãéééšãè¡šããã å®æœäŸ ïŒ ïŒâã¡ãã«âïŒâïŒïŒ®ïŒNâ²âãžã¡ãã«ã¢ããïŒ
ã¡ãã«âïŒïŒïŒâãããã³ãžãªãŒã«ãšãã¬ãã¿ã«
é žããçŽæ¥éåæ³ã«ããåŸãããããªãšã¹ãã«ïŒ
éšãâããšãã«ã°ãªã·ã³0.4éšãïŒâïŒïœâã¯
ãã«ããšãã«ïŒâïŒïŒïŒâãžããšãã«ã€ãããŸãª
ã«äºéäœ0.15éšãã¡ãã«ãšãã«ã±ãã³ïŒéšã«æº¶è§£
ããã åŸããã溶液ãããããããè¡šé¢ã«å°é»åŠçå€
ïŒåæšåïŒDow ECR34ãããŠã±ãã«ã«ç€Ÿè£œïŒã
å¡åžä¹Ÿç¥ããã¢ãŒãçŽäžã«å¡åžããç±é¢šä¹Ÿç¥åšã«
ãã70âã§ïŒåé也ç¥ãè¡ã€ãŠåã6ÎŒã®ããã
å±€ãæããæå çŽãåŸãã ãã®æå çŽã«ãã¬ãã€ãã»ãªãªãžãã«ãã€ã«ã
ãéãã±ãã«ã«ã©ã³ãïŒ20WÃ10æ¬ãã©ã³ãâæ
å çŽéè·é¢45mmïŒã§2.5åéé²å ãããé²å æžã®
æå çŽãé»åè€åæ©ïŒåæšåïŒã³ãã¹ã¿ãŒ211ã
äžç°å·¥æ¥æ ªåŒäŒç€Ÿè£œïŒã«éãããšãããé²å éšã®
ã¿ã«ãããŒãä»çããããžç»åãåŸãããã網ç¹
解åæ§ã¯150lineïŒinchã§ãã€ãã å®æœäŸ ïŒ å®æœäŸïŒã§åŸãé²å æžã®æå çŽãéé»è»¢åè£ çœ®
ïŒåæšåïŒãŒããã¯ã¹1385ãã©ã³ã¯ãŒããã¯ã¹ç€Ÿ
補ïŒã«ã»ããããéé»è»¢åãã«ã¹ã±ãŒãæ³ã«ãã
ã¢ãŒãçŽã«å¯ŸããŠè¡ã€ããšãããã¢ãŒãçŽã«ã¯é®®
æãªãããŒåã圢æãããã 転ååŸã®æå çŽãè±è綿ã§ã¯ãªãŒãã³ã°ããå
床éé»è»¢åè£ çœ®ã«ã»ãããããšããå·¥çšã«ãã転
åãç¹°ãè¿ãããšãããåäžã®è€åç©ãå€æ°æåŸ
ããã30åã®è©Šè¡åŸãç»åã¯å šãåäžã§ãã€ãã ã¡ãªã¿ã«ããããæå çŽã®åž¯é»é»å§ããã³ãã®
çµæå€åãã¹ã¿ãã€ãã¯ãªãã¹ãã¡ãŒã¿ãŒïŒåæš
åïŒæ ªåŒäŒç€Ÿç©ŽæžåäŒè£œïŒã«ãããâ15KVæŸé»
ã§æªé²å éšããã³é²å éšã«ã€ããŠæž¬å®ãããé²å
æããã³é²å åŸïŒã±æã®åž¯é»é»å§ã¯ãæªé²å éšã§
ã¯å ±ã«300Vãé²å éšã§ã¯å ±ã«15Vã§ãã€ãã ãã®æ§ãªæ§èœã¯ãæ¬çºæã®çµæç©ããã¬ããžã¿
ã€ãã®éé»å°å·åçã«å¥œé©ã§ããããšã瀺ããŠã
ãã å®æœäŸ ïŒ å®æœäŸïŒã®çµæç©æº¶æ¶²ããéœæ¥µé žååŠçããå
ã200ÎŒã®ã¢ã«ãæ¿äžã«ãåã2ÎŒã«åäžã«ã³ãŒã
ãã50âã§ïŒåé枩颚也ç¥ããã該æå æ¿ã«ãã¬
ãã€ããªãªãžããã€ã«ã ãå¯çããé«å§æ°Žéç¯
ïŒãªããŒç€ŸããªããŒããªã³ã¿ãŒ3000ïŒã§2.5åéé²
å ãããé²å åŸã該æå æ¿ã20âã®PHïŒïŒã®æ°Žã«
浞挬ãããŠãªãã·ã€ãŒïŒå€§æ¥æ¬ã¹ã¯ãªãŒã³ç€Ÿè£œïŒ
ã§ãã©ãã·ã³ã°ãè¡ãªããæ°ŽæŽãæ°ŽåãåŸã60â
ã§10åé枩颚也ç¥åšã§ä¹Ÿç¥ãã次ãã§ã¬ã 液ïŒå¯
åãã€ã«ã 瀟補GUïŒã§ã¬ã åŒããè¡ãªã€ãã宀
æž©ã§é¢šä¹Ÿç¥åŸããªãã»ããå°å·æ©ïŒãªãšãŠã瀟補
KR480åïŒã§å°å·ãã¹ããè¡ã€ãçµæãè¯å¥œãª
å°å·ãµã³ãã«ãåŸãããã æ¯èŒäŸ ïŒ å®æœäŸïŒã«ãããŠãïŒâïŒïœâã¯ãã«ããšã
ã«ïŒâ4.5âãžããšãã«ã€ãããŸãªã«äºéäœãé
åããªãã€ã以å€ã¯ãã¹ãŠå®æœäŸïŒãšåæ§ã«ããŠ
æå çŽïŒ¢ãåŸãã åŸãããæå çŽïŒ¢ãããããå®æœäŸïŒãšåæ§ã«
ããŠé²å éšã®ã¿ã«ãããŒãä»çããããžç»åãåŸ
ãããšããããå®æœäŸïŒãšåæ§ã®ç¶²ç¹è§£åæ§ãåŸ
ãããã«ã¯æå çŽïŒ¢ã¯ïŒåã®é²å æéãå¿ èŠã§ã
ã€ãã å®æœäŸ ïŒ åŒïŒ ã§ç€ºãããã¢ããã¢ã«ãã«ã¡ã¿ã¯ãªã¬ãŒã50éšãª
ãã³ã«ã¡ã¿ã¯ãªã«é žã¡ãã«50éšãéåããŠåŸãã
ãé«ååååç©ïŒéšãããšãã«ã°ãªã·ã³0.35éšã
ïŒâïŒïœâã¯ãã«ããšãã«âïŒïŒïŒâïŒïœâãžã¢
ãã·ã«ïŒã€ãããŸãªã«äºéäœ0.2éšãããªããšã
ã«ãã©ãŸãªã³0.05éšãããã«ã«ãŒãã³ãã©ãã¯
0.15éšãããã³ããã©ãã€ãããã©ã³ïŒéšãããª
ãçµæç©ãåã100ÎŒã®ããªãšãã¬ã³ãã¬ãã¿ã¬
ãŒãã®ïŒè»žå»¶äŒžãã€ã«ã äžã«å¡åžãã也ç¥ããŠå
ã3ÎŒã®æå æ§ç©å±€äœãåŸããåå å 床èšãçšã
ãŠ300ã400mÎŒã®æ³¢é·ç¯å²ã®æŽ»æ§å ç·åžåçã枬
å®ãããšããã99.9ïŒ ä»¥äžã§ãã€ãããã®æå æ§
ç©å±€äœã«å®æœäŸïŒããã³ïŒã§çšããç»åãã¬ãã€
ã«ã ãå¯çãããŠ3KWã®è¶ é«å§æ°Žéç¯ãçšãã
50cmã®è·é¢ã§ïŒåéé²å ãè¡ã€ãããã®åŸãã¹ã
ã¬ã€ããºã«ããïŒKgïŒcm2ã®æ°Žå§ã®æ°Žéæ°ŽãçŽ0.5
åéåŽãã€ããå³åº§ã«ä¹Ÿç¥ãè¡ã€ãçµæã網ç¹æ¿
床ïŒïŒ ãã90ïŒ ã®ç¯å²ã§æ¥µããŠå¿ å®ãªçœé»ç»åã
åŸãããããã®çœé»ç»åãæããããžãã€ã«ã ã
åè¿°ã®æªé²å æå æ§ç©å±€äœäžã«å¯çããããŠåæ§
ã®åŠçãè¡ããšã網ç¹ãå¿ å®ã«åçŸããå転çœé»
ãã¬ç»åãåŸãããã æŽã«ããã®ãã¬ãã€ã«ã ãæå æ§æš¹èçãæ±æŽ
玡ããªã³ã¿ã€ãRFâ95ã«å¯çãããŠå®æœäŸïŒã§
çšããé²å æ©ã§4.5åéé²å ããæ±æŽçŽ¡ããªã³ã¿
ã€ãçšæŽåºãæ©ã§2.5åéæ°ŽæŽãè¡ãªã€ãŠéåžžã«
è¯å¥œãªåžçå°å·çšã¬ãªãŒãçãåŸãã å®æœäŸ ïŒ ãžãšãã«ã¢ãããšãã«ã¡ã¿ã¯ãªã¬ãŒã30éšãšãš
ãã¬ã³70éšãéåããŠåŸãé«ååååç©ïŒéšãïŒ
âïŒïœâã¯ãã«ããšãã«ïŒâïŒïŒïŒâïŒïœâãžã¢
ãã·ã«ïŒã€ãããŸãŒã«äºéäœ0.1éšãïŒâã¯ãã«
ããšãã«ã°ãªã·ã³0.3éšãã¡ãã«ãšãã«ã±ãã³ïŒ
ãã«ãšã³ïŒå®¹éæ¯5.5ïŒ4.5ïŒæ··å溶åªã«æº¶è§£ã
ããåŸããã溶液ãããªãããã¬ã³ãã€ã«ã ïŒå
ã60ÎŒãåæšåïŒæ±æŽçŽ¡ãã€ã¬ã³ãã€ã«ã P1120
ïŒ60ãæ±æŽåæå·¥æ¥æ ªåŒäŒç€Ÿè£œïŒã«ã¯ã€ã€ãŒããŒ
ã§è¢«èŠãã70âã§ïŒåé也ç¥ãè¡ãåã5ÎŒã®æ
å å±€ãæããæå ãã€ã«ã ãåŸãã ãã®æå ãã€ã«ã ã«ãã¬ãã€ãã»ãªãªãžãã«ã
ã€ã«ã ãéããã±ãã«ã«ã©ã³ãïŒ20WÃ10æ¬ãã©
ã³ããŒæå çŽéè·é¢45mmïŒã§1.5åéé²å ããã ããã ããšããŒã«ãã«ãŒ0.005éšãæ°ŽïŒã¡ã¿ã
ãŒã«ïŒå®¹éæ¯ïŒïŒïŒïŒæ··å溶åª10éšã«æº¶è§£ããçŸ
å液ã«ãé²å åŸã®ãã€ã«ã ã30ç§é浞挬ããŠæ·±é
è²ã®ããžç»åããã網ç¹è§£åæ§ã¯150lineïŒinch
以äžã§ãã€ãã å®æœäŸ ïŒ ïŒ®âïŒÎ²âã¢ãããšãã«ïŒããã©ãžã³40éšãã¢
ãžãã³é ž50éšããã³Îµâã«ããã©ã¯ã¿ã 38éšãé
åããŠåŸãããããªã¢ãã100ãšïŒâãããããš
ãã«ã°ãªã·ã³50éšãïŒâïŒ2â²âã¯ãã«â1â²âãã
ãã«ïŒâïŒïŒïŒâïŒïœâãžã¢ãã·ã«ïŒã€ãããŸãŒ
ã«äºéäœ20éšããã³ïŒââãžã¡ãã«ã¢ããã¯ã
ãªã³ïŒéšãã¡ã¿ããŒã«ã«æº¶è§£åŸã該溶液ãæµå»¶ã
ãŠ28mmã®éæ¿ã«è²Œãåãããããã®æ§ã«ããŠåŸã
æå æ§åæ¿ã«150lineïŒinchã®ç¶²å解ã§äœããã
ç»åãã¬ãå¯çããç §åºŠ200WïŒcm2ã®ã±ãã«ã«ã©
ã³ãã§ïŒåéé²å ãè¡ãªã€ãããã®åŸãPH7.5ã®
æ°Žéæ°Žäžã«æµžæŒ¬ããç¶æ ã§ïŒåéãã©ãã·ã³ã°ã
è¡ãã次ãã§60âã®æž©é¢šã§10åé也ç¥ããã åŸãããã¬ãªãŒãçã¯ç»åãã¬ã«å¿ å®ãªå¯Ÿå¿ã
瀺ããŠããããŸãã¬ãªãŒãæé¢ã®ã·ãšã«ããŒè§åºŠ
ã¯çŽ70床ã§ãã€ãã ãã®ã¬ãªãŒãçãçšããŠãèªååžçæ ¡æ£æ©ïŒæ¯
å©è£œäœæ補ïŒã«ããå°å·ãã¹ããè¡ãªã€ãçµæã
åå³ç»åãè¯å¥œã«åçŸããå°å·ãµã³ãã«ãåŸãã
ãã ããã«ããã®ã¬ãªãŒãçã®ç»åã®äžéšãæ®ããŠ
ã»ããã¢ã³ããŒãã§çé¢ã被èŠããåŸãPH4.0ã®
æ°Žã§0.5åéã¹ãã¬ãŒæŽãåºããè¡ã€ããã»ãã
ã¢ã³ããŒããå¥ãããŠä¹Ÿç¥ããåŸãäžèšãšåæ§ã®
å°å·ãã¹ããè¡ã€ããšããã被èŠãæœããªãã€ã
éšåã®ã¿ã®ç¶²ç»åãä»ã®éšåã«æ¯ã¹éåžžã«æãã
ãå°å·ç©ãåŸãããã å®æœäŸ ïŒ ããªïŒâããã«ããªãžã³ïŒåºæ ååŠæ ªåŒäŒç€Ÿ
補ïŒ50éšãïŒâãããããªããšããã·é ¢é žïŒéšã
ïŒâïŒïœâãããããšãã«ïŒâïŒïŒïŒâãžããšã
ã«ã€ãããŸãŒã«äºéäœ10éšããã³ãã«ãªã¬ã»ã€ã³
ïŒéšãã¢ã»ãã³âã¡ã¿ããŒã«æ··å溶åªã«æº¶è§£ããŠ
åäžãªæš¹èçµæç©ã®æº¶æ¶²ã調補ããããã®æº¶æ¶²ã
åã0.3mmã®çŽé¢ã«ããŒã³ãŒã¿ãçšããŠå¡åžãã
åŸã颚也ç¥ããŠçŽ5ÎŒã®åã¿ã®æš¹èçµæç©ã被èŠ
ãããæå çŽãåŸããåŸãããæå çŽã®æš¹èã³ãŒ
ãé¢äžã«ãå®æœäŸïŒã§çšãããã¬ãã€ã«ã ãå¯ç
ãããå®æœäŸïŒãšåãé²å æ©ã§çŽïŒåéé²å ãè¡
ã€ããé²å ããæå çŽããã¢ãã¯ã¹ãªãã»ããæ©
ïŒãªã³ãŒæ ªåŒäŒç€Ÿè£œïŒã«åä»ããŠå°å·ãã¹ããè¡
ã€ãçµæãè¯å¥œãªå°å·ãµã³ãã«ãåŸãããã å®æœäŸ ïŒã17 å®æœäŸïŒã«ãããŠãâããšãã«ã°ãªã·ã³ã®ä»£
ãã«ç¬¬ïŒè¡šã«ç€ºãé žæ§ååç©ãæå®éããã³å å¢
æå€ãé åããããé åããã«å®æœäŸïŒãšåæ§ã«
ããŠåã3ÎŒã®ãããå±€ãæããæå çŽãåŸãã
åŸãããæå çŽããããããã¬ãã€ããªãªãžãã«
ãã€ã«ã ãéããŠå®æœäŸïŒãšåæ§ã«ããŠãåæé
ã ãæå ãé»åè€åæ©ã«éããŠããžç»åãåŸãã
åã ã®ç¶²ç¹è§£åæ§ã第ïŒè¡šã«äœµèšããã
âNH2ãâCOOHãâCOORâ²â²â²â²ïŒããã§ïŒ²â²â²â²â²ã¯
ççŽ æ°ïŒã10ã®çåæ°ŽçŽ æ®åºã瀺ããïŒãããªã
矀ããéžã°ããåºãè¡šããããšïŒ¢ã¯åæã«åäž
ãŸãã¯çžç°ãªã€ãŠãããããŸãã¯ïŒâã¢ããã
ããã«åºãè¡šãããã äžèšäžè¬åŒïŒïŒã§ç€ºãããåéäœãšããŠã¯ã
âïŒïŒâã¢ãããšãã«ïŒããã©ãžã³ãâïŒïŒ
âã¢ããã·ã¯ãããã·ã«ïŒããã©ãžã³ãâïŒïŒ
âã¢ãããšãã«ïŒâïŒâã¡ãã«ããã©ãžã³ãªã©ã®
ãžã¢ãã³é¡ãâã«ã«ããã·ã¡ãã«ããã©ãžã³ã
âïŒïŒâã«ã«ããã·ã·ã¯ãããã·ã«ïŒããã©ãž
ã³ãâïŒïŒâã«ã«ããã·ãšãã«ïŒâïŒâã¡ãã«
ããã©ãžã³ãªã©ã®Ïâã¢ããé žãããã¯ãããã®
äœçŽã¢ã«ãã«ãšã¹ãã«ãªã©ãããã äžè¬åŒïŒïŒã§ç€ºãããåéäœãšããŠã¯ãããš
ãã°ïŒ®ïŒNâ²âãã¹ïŒã¢ããã¡ãã«ïŒããã©ãžã³ã
âïŒã¢ããã¡ãã«ïŒâNâ²âïŒïŒâã¢ãããšã
ã«ïŒããã©ãžã³ãªã©ã®ãžã¢ãã³é¡ãïŒNâ²âã
ã¹ïŒã«ã«ããã·ã¡ãã«ïŒããã©ãžã³ãïŒNâ²â
ãã¹ïŒã«ã«ããã·ã¡ãã«ïŒâïŒïŒïŒâãžã¡ãã«ã
ãã©ãžã³ãâïŒïŒâã«ã«ããã·ãšãã«ïŒâ
Nâ²âïŒã«ã«ããã·ã¡ãã«ïŒããã©ãžã³ãªã©ã®ãž
ã«ã«ãã³é žãããã¯ãããã®äœçŽã¢ã«ãã«ãšã¹ã
ã«ãé žããã²ã³åç©ãããã³ïŒ®âïŒã¢ããã¡ã
ã«ïŒâNâ²âïŒã«ã«ããã·ã¡ãã«ïŒããã©ãžã³ã
âïŒã¢ããã¡ãã«ïŒâNâ²âïŒã«ã«ããã·ã¡ã
ã«ïŒâïŒâã¡ãã«ããã©ãžã³ãªã©ã®Ïâã¢ããé ž
é¡ãããã¯ãããã®äœçŽã¢ã«ãã«ãšã¹ãã«é¡ãªã©
ãããã äžè¬åŒïŒïŒã§ç€ºãããåéäœãšããŠã¯ãããš
ãã°ïŒ®ïŒNâ²âãã¹ïŒïŒâã¢ãããšãã«ïŒâã¡ã
ã«ã¢ãã³ãïŒïŒ®âãã¹ïŒïŒâã¢ãããããã«ïŒ
âã·ã¯ãããã·ã«ã¢ãã³ãªã©ã®ãžã¢ãã³é¡ãïŒ
âãã¹ïŒã«ã«ããã·ã¡ãã«ïŒâã¡ãã«ã¢ãã³ã
âã«ã«ããã·ã¡ãã«ââïŒïŒâã«ã«ããã·ãš
ãã«ïŒâã¡ãã«ã¢ãã³ãªã©ã®ãžã«ã«ãã³é žé¡ãã
ãã¯ãããã®äœçŽã¢ã«ãã«ãšã¹ãã«ãé žããã²ã³
åç©ãããã³ïŒ®âïŒã¢ããã¡ãã«ïŒââïŒã«ã«
ããã·ã¡ãã«ïŒâã¡ãã«ã¢ãã³ãâïŒã¢ããã¡
ãã«ïŒââïŒïŒâã«ã«ããã·ãšãã«ïŒâã€ãœã
ããã«ã¢ãã³ãªã©ã®Ïâã¢ããé žé¡ãããã¯ãã
ãã®äœçŽã¢ã«ãã«ãšã¹ãã«é¡ãªã©ãããã äžè¬åŒïŒïŒã§ç€ºãããåéäœãšããŠã¯ãããš
ãã°ïŒ®ïŒNâ²âãžã¡ãã«âïŒNâ²âãã¹ïŒïŒâã¢
ãããããã«ïŒãšãã¬ã³ãžã¢ãã³ãïŒNâ²âãž
ã·ã¯ãããã·ã«âïŒNâ²âãã¹ïŒïŒâã¢ããã
ããã«ïŒãããµã¡ãã¬ã³ãžã¢ãã³ãªã©ã®ãžã¢ãã³
é¡ãïŒNâ²âãžã¡ãã«âïŒNâ²âãã¹ïŒã«ã«ã
ãã·ã¡ãã«ïŒãšãã¬ã³ãžã¢ãã³ãïŒNâ²âãžã¡
ãã«âïŒNâ²âãã¹ïŒïŒâã«ã«ããã·ãããã«ïŒ
ãããµã¡ãã¬ã³ãžã¢ãã³ãªã©ã®ãžã«ã«ãã³é žé¡ã
ããã¯ãããã®äœçŽã¢ã«ãã«ãšã¹ãã«ãé žããã²
ã³åç©ãïŒNâ²âãžã¡ãã«ââïŒã¢ããã¡ã
ã«âNâ²âïŒã«ã«ããã·ã¡ãã«ïŒãšãã¬ã³ãžã¢ã
ã³ãïŒNâ²âãžã¡ãã«ââïŒã¢ããã¡ãã«ïŒ
âNâ²âïŒã«ã«ããã·ãšãã«ïŒãããµã¡ãã¬ã³ãž
ã¢ãã³ãªã©ã®Ïâã¢ããé žãããã¯ãããã®äœçŽ
ã¢ã«ãã«ãšã¹ãã«é¡ãªã©ãããã äžè¬åŒïŒïŒã§ç€ºãããåéäœãšããŠã¯ãããš
ãã°ïŒâã¡ãã«âïŒâïŒïŒ®ïŒNâ²âãžã¡ãã«ã¢ã
ãã¡ãã«ïŒâïŒïŒïŒâãžãªããµâïŒïŒ11âãŠã³ã
ã«ã³ãžã¢ãã³ãïŒâãšãã«âïŒâïŒïŒ®ïŒïŒ®âãžã¡
ãã«ã¢ããã¡ãã«âïŒïŒïŒâãžãªããµâïŒïŒ11â
ãŠã³ãã«ã³ãžã¢ãã³ãïŒïŒïŒâãã¹âïŒïŒ®ïŒ
Nâ²âãžã¡ãã«ã¢ããã¡ãã«ïŒâïŒïŒïŒâãžãªããµ
âïŒïŒ11âãŠã³ãã«ã³ãžã¢ãã³ãªã©ã®ãžã¢ãã³é¡
ãããã ãããã®å¡©åºæ§ãæããåéäœã¯ïŒçš®ä»¥äžäœµçš
ããŠãããã æ¬çºæã«çšããããªã¢ããã®éåæåãšããŠã¯
åèšäžè¬åŒïŒïŒãïŒïŒã§ç€ºãããåéäœã®ã»
ãã«ãéåžžã®ããªã¢ããã®éåã«çšããããèèª
æããã³ïŒãŸãã¯è³éŠæã®ãžã«ã«ãã³é žããžã¢ã
ã³ãÏâã¢ããé žãã©ã¯ã¿ã ãªã©ãããã å¡©åºæ§ãæããããªãšã¹ãã«ãšããŠã¯ãäžèšäž
è¬åŒïŒïŒãïŒïŒã§ç€ºãããåéäœãéåå
æãšãããã®ãããïŒ ãåŒäžããRâ²ãRâ³ããR15ãR16ãR17ã
R18ãR19ãR20ã¯åèšãšåæ矩ãAâ²ãBâ²ã¯âOHã
âCOOHãâCOORâ²â²â²â²ïŒããã§ïŒ²â²â²â²â²ã¯ççŽ æ°ïŒ
ã10ã®çåæ°ŽçŽ æ®åºã瀺ããïŒãããªã矀ããéž
ã°ããåºãè¡šãããAâ²ãšBâ²ã¯åæã«åäžãŸãã¯
çžç°ãªã€ãŠããããã äžèšäžè¬åŒïŒïŒã§ç€ºãããåéäœãšããŠã¯ã
å ·äœçã«ã¯ïŒ®ïŒNâ²âãã¹ïŒã«ã«ããã·ã¡ãã«ïŒ
ããã©ãžã³ãïŒNâ²âãã¹ïŒã«ã«ããã·ã¡ãã«ïŒ
âïŒïŒïŒâãžã¡ãã«ããã©ãžã³ãâïŒïŒâã«ã«
ããã·ãšãã«ïŒâNâ²âïŒã«ã«ããã·ã¡ãã«ïŒã
ãã©ãžã³ãªã©ã®ãžã«ã«ãã³é žé¡ãããã¯ãããã®
äœçŽã¢ã«ãã«ãšã¹ãã«ãé žããã²ã³åç©ãïŒ
Nâ²âãã¹ïŒããããã·ã¡ãã«ïŒããã©ãžã³ãïŒ
Nâ²âãã¹ïŒïŒâããããã·ããã«âïŒïŒïŒâãž
ã¡ãã«ããã©ãžã³ãïŒNâ²âãã¹ïŒïŒâããã
ãã·ã·ã¯ããããã«ïŒããã©ãžã³ãïŒNâ²âã
ã¹ïŒïŒâã¡ãã«âïŒâããããã·ããã«ïŒããã©
ãžã³ãªã©ã®ã°ãªã³ãŒã«é¡ãæããããšãã§ããã äžè¬åŒïŒXIïŒã§ç€ºãããåéäœãšããŠã¯ãããš
ãã°ïŒ®ïŒNâ²âãã¹ïŒã«ã«ããã·ã¡ãã«ïŒâã¡ã
ã«ã¢ãã³ãâã«ã«ããã·ã¡ãã«ââïŒïŒâã«
ã«ããã·ãšãã«ïŒâã¡ãã«ã¢ãã³ãªã©ã®ãžã«ã«ã
ã³é žé¡ãããã¯ãããã®äœçŽã¢ã«ãã«ãšã¹ãã«ã
é žããã²ã³åç©ããã³ïŒ®ïŒNâ²âãã¹ïŒïŒâãã
ããã·ãšãã«ïŒã¢ãã³ãïŒNâ²âãã¹ïŒïŒâã
ãããã·ãããã«ïŒâã€ãœãããã«ã¢ãã³ãªã©ã®
ã°ãªã³ãŒã«é¡ã§ããã äžè¬åŒïŒXIIïŒã§ç€ºãããåéäœãšããŠã¯ãããš
ãã°ïŒ®ïŒNâ²âãžã¡ãã«âïŒNâ²âãã¹ïŒã«ã«ã
ãã·ã¡ãã«ïŒãšãã¬ã³ãžã¢ãã³ãïŒNâ²âãžã¡
ãã«âïŒNâ²âãã¹ïŒïŒâã«ã«ããã·ãããã«ïŒ
ãããµã¡ãã¬ã³ãžã¢ãã³ãªã©ã®ãžã«ã«ãã³é žé¡ã
ããã¯ãããã®äœçŽã¢ã«ãã«ãšã¹ãã«ãé žããã²
ã³åç©ãïŒNâ²âãžã¡ãã«âïŒNâ²âãã¹ïŒïŒ
âããããã·ãšãã«ïŒãšãã¬ã³ãžã¢ãã³ãïŒ
Nâ²âãžã·ã¯ãããã·ã«âïŒNâ²âãã¹ïŒïŒâã
ãããã·ãšãã«ïŒãããµã¡ãã¬ã³ãžã¢ãã³ãïŒ
Nâ²âãžã¡ãã«âïŒNâ²âãã¹ïŒïŒâããããã·
ãšãã«ïŒâïŒïŒïŒïŒïŒâããªã¡ãã«âãããµã¡ã
ã¬ã³ãžã¢ãã³ãªã©ã®ã°ãªã³ãŒã«é¡ãããã äžè¬åŒïŒïŒã§ç€ºãããåéäœãšããŠã¯ãã
ãšãã°ïŒâã¡ãã«âïŒâïŒïŒ®ïŒïŒ®âãžã¡ãã«ã¢ã
ãã¡ãã«ïŒâïŒïŒïŒâãããã³ãžãªãŒã«ãïŒâã¡
ãã«âïŒâïŒïŒ®ïŒïŒ®âãžã€ãœãããã«ã¢ããã¡ã
ã«ïŒâïŒïŒïŒâãããã³ãžãªãŒã«ãïŒâã¡ãã«â
ïŒâãããªãžãã¡ãã«âïŒïŒïŒâãããã³ãžãªãŒ
ã«ããã¹ïŒïŒâïŒïŒ®âãžã€ãœãããã«ã¢ããã¡
ãã«ïŒâïŒïŒïŒâãããã³ãžãªãŒã«ãªã©ã®ã°ãªã³
ãŒã«é¡ãæããããã ãããã®å¡©åºæ§ãæããåéäœã¯ïŒçš®ä»¥äžäœµçš
ããŠãããã æ¬çºæã«ãããŠçšããããªãšã¹ãã«ã®éååæ
ãšããŠã¯ãåèšäžè¬åŒïŒïŒãïŒïŒã§ç€ºãã
ãåéäœã®ã»ãã«éåžžã®ããªãšã¹ãã«ã®éåã«çš
ããããèèªæããã³ïŒãŸãã¯è³éŠæã®ãžã«ã«ã
ã³é žãããã¯ãã®äœçŽã¢ã«ãã«ãšã¹ãã«ãã°ãªã³
ãŒã«ããªãã·é žãªã©ã䜵çšããŠãããã å¡©åºæ§ãæããããã«ç³»ããªããŒãšããŠã¯ãïŒ
âããã«ããªãžã³ã®éåäœããŸãã¯äžèšäžè¬åŒ
ïŒïŒïŒ ãåŒäžãRâ²ãRâ³ããR15ã¯åèšãšåæ矩ã
ã¯ãšã¹ãã«çµåãŸãã¯ã¢ããçµåãè¡šãããã ã§ç€ºãããåéäœãéååæãšãããã®ãæãã
ããã äžèšäžè¬åŒïŒïŒã§ç€ºãããåéäœãšããŠ
ã¯ãããšãã°ïŒâïŒïŒ®ïŒNâ²âãžã¡ãã«ã¢ããïŒ
ãšãã«ã¡ã¿ã¯ãªã¬ãŒããïŒâïŒïŒ®ïŒNâ²âãžãšã
ã«ïŒãããã«ã¡ã¿ã¯ãªã¬ãŒããªã©ã®ã¡ã¿ã¯ãªã¬ãŒ
ãé¡ãïŒâïŒïŒ®ïŒNâ²âãžã¡ãã«ã¢ããïŒããã
ã«ã¡ã¿ã¯ãªã«ã¢ãããïŒâïŒïŒ®ïŒNâ²âãžãšãã«
ã¢ããïŒãããã«ã¡ã¿ã¯ãªã«ã¢ãããªã©ã®ã¡ã¿ã¯
ãªã«ã¢ããé¡ãªã©ãããã ãããã®å¡©åºæ§ãæããåéäœã¯ïŒçš®ä»¥äžäœµçš
ããŠãããã æ¬çºæã«ãããŠçšããããããã«ç³»ããªããŒã®
éååæãšããŠã¯ãåèšïŒâããã«ããªãžã³ãŸã
ã¯äžè¬åŒïŒïŒã§ç€ºãããåéäœã®ä»ã«éåžžã®
ããã«ããªããŒã®éåã«çšããããããã«ã¢ãã
ãŒã䜵çšããŠãããã å¡©åºæ§ãæããããªãšãŒãã«ãšããŠã¯ãå¡©åºæ§
ãæãããžãªãŒã«ãããšãã°åèšäžè¬åŒïŒïŒ
ã§è¡šãããããžãªãŒã«ãããã¯ãããã®æ©èœçèª
å°äœããéçž®åã«ããåŸããããã®ããŸãã¯ãã®
ä»ã®ãžãªãŒã«ãããã¯ãããã®æ©èœçèªå°äœãšã
éçž®åããŠåŸããããã®ãããã ãã®ä»ã®ãžãªãŒã«ãããã¯ãã®æ©èœçèªå°äœãš
ããŠã¯ãšãã¬ã³ã°ãªã³ãŒã«ããããã¬ã³ã°ãªã³ãŒ
ã«ãããã©ã¡ãã¬ã³ã°ãªã³ãŒã«ããããµã¡ãã¬ã³
ã°ãªã³ãŒã«ããžãšãã¬ã³ã°ãªã³ãŒã«ãååé200
ã3000ã奜ãŸããã¯200ã1000ã®ããªãšãã¬ã³ã°
ãªã³ãŒã«ãããªããã©ã¡ãã¬ã³ã°ãªã³ãŒã«ããã¹
ïŒïŒâããããã·ããšãã«ïŒã¡ã¿ã³ãïŒïŒïŒâã
ã¹ïŒïŒâããããã·ããšãã«ïŒã·ã¯ããããµã³ã
ãã¹ïŒïŒâããããã·ããšãã«ïŒããªãšãŒãã«ã
ãã¹ïŒïŒâããããã·ããšãã«ïŒã¹ã«ãã³ãïŒïŒ
2â²âãžããããã·ãã³ãŸããšãã³ãïŒïŒ2â²âãžã
ãããã·âïŒïŒ4â²âãžã¡ããã·ãã³ãŸããšãã³ã
ã¯ã¬ãŸãŒã«ãã¬ãŸã«ã·ã³ããããããã³ãïŒïŒïŒ
âãžããããã·ã¢ã»ãããšãã³ãïŒïŒïŒâãžãã
ããã·ããã¿ã¬ã³ãïœâãïœâãŸãã¯ïœâãã·ãª
ã¬ã³ã°ãªã³ãŒã«ãªã©ãæããããšãã§ããã äžèšããªãšãŒãã«ã¯éåžžã®æ¹æ³ã«åŸãéçž®åã
ãŠè£œé ããããã®ã§ããã å€æ§é«ååååç©ã®äŸãšããŠã¯ããšãã¬ã³ã¢ã
ã³ã«ãã€ãŠå€æ§ãããã»ã«ããŒã¹èªå°äœãããšã
ã°ã¢ãããšãã«ã»ã«ããŒã¹ããŸãã¯é«ååååç©
ã®äžè¬çãªå€æ§æ³ãšããŠç¥ãããŠããã°ã©ããå
å¿ã«ããå¡©åºæ§ãä»äžãããå€æ§é«ååååç©ãª
ã©ãæããããã ããã«ãæ¬çºæã®çµæç©ã«ãããŠã¯ãå¡©åºæ§ã
æããé«ååååç©ã«å ããä»çš®ã®é«ååååç©
ã䜵çšããããšãå¯èœã§ããã 該塩åºæ§é«ååååç©ãšåèšé žæ§ååç©ãšã®çµ
æç©ã«ãããæ··åéããã³æ··åå²åã¯ãäž¡è ã®çµ
åãããçš®é¡ã«ãã€ãŠç°ãªãããŸãå®é䜿çšãã
æã«èŠæ±ãããç¹æ§ïŒããšãã°å ç §å°ååŸã«ãã
ã芪氎æ§ãŸãã¯æ°Žæº¶æ§ã®å·®ãååŠçæ§è³ªãåå¿é
床ãªã©ïŒã«ããéžæãããããå šçµæç©äžã«å å
å¿æ§ååç©ã0.4ã700ïœïŒKgã®å²åã§å«æãããŠ
ãããäž¡è ã®é åå²åã¯ãé žæ§ååç©ã®é žæ§åºãš
å¡©åºæ§é«ååååç©ã«å«ãŸããå¡©åºæ§çªçŽ ã®åœé
æ¯ã0.02ãïŒã«ãªãããã«ããã®ã奜ãŸããã æ¬çºæã«ãããŠããªã¢ãªãŒã«ã€ãããŸãªã«äºé
äœã¯äžèšäžè¬åŒïŒïŒã§ç€ºããã該äºéäœã¯å
ç §å°ãåããããšã«ããéé¢åºãçºçããé žæ§å
åç©ã®é žæ§åºŠãäœäžããååŠå€åãæ¹èµ·ãããã¯
ä¿é²ãããããã«ãã€ãŠæ床ãèããåäžããã åŒäžãArãArâ²ãArâ³ã¯ããããçæåºãæã
ããæããªãã¢ãªãŒã«åºã瀺ãã ãªãæ¬çºæã«ãããŠãArãããšãã«åºã®å Žå
ã«ã¯ãããšãã«åºã®ãªã«ãäœã«çœ®æåºãæããã
ã®ããŸãArãïŒâãããã«åºã®å Žåã«ã¯ãïŒâ
ãããã«åºã®ïŒäœã«çœ®æåºãæãããã®ã奜ãŸã
ãã å ·äœçã«ãããšãã°ïŒâïŒïœâã¯ãã«ããšã
ã«ïŒâïŒïŒïŒâãžããšãã«ã€ãããŸãªã«äºéäœã
ïŒâïŒïœâã¯ãã«ããšãã«ïŒâïŒïŒïŒâïŒïœâãž
ã¯ãã«ããšãã«ïŒã€ãããŸãªã«äºéäœãïŒâïŒïœ
âã¯ãã«ããšãã«ïŒâïŒïŒïŒâïŒïœâãžã¢ãã·
ã«ïŒã€ãããŸãªã«äºéäœãïŒâïŒïœâãã«ãªãã
ãšãã«ïŒâïŒïŒïŒâãžããšãã«ã€ãããŸãªã«äºé
äœãïŒâïŒïœâã¡ããã·ããšãã«ïŒâïŒïŒïŒâãž
ããšãã«ã€ãããŸãªã«äºéäœãïŒâïŒïœâããã
ããšãã«ïŒâïŒïŒïŒâãžããšãã«ã€ãããŸãªã«äº
éäœãïŒâïŒïœâãããããšãã«ïŒâïŒïŒïŒâãž
ããšãã«ã€ãããŸãªã«äºéäœãïŒâïŒïœâããã¢
ããšãã«ïŒâïŒïŒïŒâãžããšãã«ã€ãããŸãªã«äº
éäœãïŒâïŒïŒâãããã«ïŒâïŒïŒïŒâãžããšã
ã«ã€ãããŸãªã«äºéäœãïŒâïŒïŒâã¯ãã«âïŒâ
ãããã«ïŒâïŒïŒïŒâãžããšãã«ã€ãããŸãªã«äº
éäœãªã©ãæããããšãã§ããããªããåèšäºé
äœã¯åäžã®ããã€ã³ã®äºéäœã瀺ããŠããããå¿
è«ç°ãªãããã€ã³ã®äºéäœãå«ãŸããããšãã°ïŒ
âããšãã«ã2â²âïŒïœâã¯ãã«ããšãã«ãïŒïŒ
4â²ïŒïŒïŒ5â²âããã©ããšãã«ïŒãã€ãããŸãŒã«ã
ïŒâïŒïœâã¯ãã«ããšãã«ïŒâ2â²âããšãã«ã
ïŒïŒïŒâïŒãžïœã¢ãã·ã«ïŒâïŒïŒ5â²âãžããšãã«
ãã€ãããŸãŒã«ãªã©ãããã ãªããåèšããªã¢ãªãŒã«ã€ãããŸãªã«äºéäœ
ã¯ãå šçµæç©ã«å¯ŸããŠïŒééïŒ ã50ééïŒ ã奜ãŸ
ããã¯ïŒã20ééïŒ å«æãããåèšé žæ§ååç©ã«
察ãã該äºéäœã®åœéæ¯ã0.1ã2.0ã«ãªãããã«
ããã®ã奜ãŸããã æ¬çºæçµæç©ã«ãããŠãããã«å å¢æå€ãæ·»å
ããããšã«ãã€ãŠæ床ãäžããããšãã§ããã æ¬çºæã«çšããããå å¢æå€ãšããŠã¯ãããšã
ã°ïŒïŒ4â²âãã¹ãžã¡ãã«ã¢ãããã³ãŸããšãã³ã
ããªããµã³ãã³ããã«ãªã¬ãã³ãããªããããã«
ãªã¬ãã³ãªã©ã®è³éŠæã±ãã³ç³»ååç©ãïŒïŒ4â²â
ãã¹ãžã¡ãã«ã¢ããããªãã³ãŸããšãã³ãªã©ã®è³
éŠæããªã±ãã³ååç©ããã³ãŸããã³ããžã¯ãã«
ãã³ãŸããã³ãããã©ã¯ãã«ãã³ãŸããã³ããžã¯
ãã«ãããããã³ãããšãã³ãã¬ã³ããã³ããžã¯
ãã«ã¢ã³ãã©ããã³ããžãããã¢ã³ãã©ããã³ã
ã¢ãªã¶ãªã³ããã³ãºã¢ã³ãã©ããã³ãªã©ã®ããã³
ç³»ååç©ããžããããã«ãªã¬ã³ãããã©ãããã
ã«ãªã¬ã³ãããªããããã«ãªã¬ã³ããããã¢ã»ã
ããã³ãïŒïŒïŒïŒïŒâããªãããã¢ããªã³ãªã©ã®
è³éŠæãããååç©ãããªããšãã«ãã©ãŸãªã³ãª
ã©ã®ããªã¢ãªãŒã«ãã©ãŸãªã³ç³»ååç©ãããã©ã
ãšãã«ã€ãããŸãŒã«ãããªããšãã«ã€ãããŸãŒã«
ãªã©ã®ã¢ãã€ãããŸãŒã«ç³»ååç©ããã«ãªã¬ã»ã€
ã³ããšãªã·ã³ïŒ¹ãããŒãºãã³ã¬ã«ããšãªããã·ã³
ããããã·ã³ãªã©ã®ããµã³ãã³ç³»ååç©ãã¢ã¯
ãªãã©ãã³ããªããã©ãã³ãªã©ã®ã¢ã¯ãªãžã³ç³»å
åç©ãïŒââãžã¡ãã«ã¢ããã¯ããªã³ãªã©ã®ã¯
ããªã³ç³»ååç©ããã¢ãŒã«ãã«ãŒãããã ãã¢ãŒ
ã«ãã«ãŒãããã ã ã¯ã¬ãŸãŒã«ã°ãªãŒã³ãªã©ã®ã
ãªããšãã«ã¡ã¿ã³ç³»ååç©ãªã©ããããäžã§ãè³
éŠæã±ãã³ç³»ååç©ãããã³ç³»ååç©ãè³éŠæã
ããååç©ãããªã¢ãªãŒã«ãã©ãŸãªã³ç³»ååç©ã
ã¯ããªã³ç³»ååç©ã奜ãŸããã ãªãåèšå å¢æå€ã¯ã å šçµæç©ã«å¯ŸããŠ0.1ã10ééïŒ ã奜ãŸããã¯
0.1ã5.0ééïŒ æ·»å ããŠãããã æ¬çºæã®çµæç©ã«ã¯ãå¿ èŠãªãã°å 掻æ§ååç©
ã®å ±åäžã§ãå ç §å°ãåããŠååãšããŠé žæ§ã倱
ããªãæ§ãªé žæ§ååç©ã䜵çšããŠãå ç §å°ååŸã®
芪氎æ§ãŸãã¯æ°Žæº¶æ§ã®å·®ãå¶åŸ¡ããããšãå¯èœã§
ããã ãŸããåæ§ã®ç®çããã³ååŠçæ§è³ªã®å¶åŸ¡ã®ã
ãã«ãåŸæ¥ããç¥ãããŠããå äžæº¶åå€ã䜵çšã
ãããšãå¿è«å¯èœã§ããã 䜵çšã§ããå äžæº¶åå€ãšããŠã¯ãããšãã°ã¢ã¯
ãªã«é žãã¡ã¿ã¯ãªã«é žãã¡ãã«ã¢ã¯ãªã¬ãŒããã¡
ãã«ã¡ã¿ã¯ãªã¬ãŒããã·ã¯ãããã·ã«ã¢ã¯ãªã¬ãŒ
ããã¢ã¯ãªã«ã¢ãããã¡ã¿ã¯ãªã«ã¢ãããâã¡
ãããŒã«ã¢ã¯ãªã«ã¢ãããïœâãããã·ã¡ãã«ã¢
ã¯ãªã«ã¢ããããããªãŠã ã¢ã¯ãªã¬ãŒããã¢ã³ã¢
ããŠã ã¢ã¯ãªã¬ãŒããã¢ã¯ãªããããªã«ãã¹ãã¬
ã³ãã¹ãã¬ã³ã¹ã«ãã³é žãœãŒããããã«ããªãžã³
çã®äžé£œåäºéçµåãïŒåæããåéäœãããã
ã¯ã°ãªã·ãžã¡ã¿ã¯ãªã¬ãŒããã¢ãªã«ã¡ã¿ã¯ãªã¬ãŒ
ãããšãã¬ã³ã°ãªã³ãŒã«ãžã¢ã¯ãªã¬ãŒãããšãã¬
ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒããïŒïŒïŒâããã
ã³ãžãªãŒã«ã¢ã¯ãªã¬ãŒããïŒïŒïŒâãããã³ãžãª
ãŒã«ã¡ã¿ã¯ãªã¬ãŒããããªã¡ãããŒã«ãããã³ã
ãªã¢ã¯ãªã¬ãŒããããªã¡ãããŒã«ãããã³ããªã¡
ã¿ã¯ãªã¬ãŒããããªã¢ã¯ãªãã€ã«ãªãã·ãšãã«ã
ã¹ããšã€ããã¡ãã¬ã³ãã¹ã¢ã¯ãªã¢ãããã¡ãã¬
ã³ãã¹ã¡ã¿ã¯ãªã¢ããçã®äžé£œåäºéçµåãïŒå
以äžæããåéäœãããã æ¬çºæã®çµæç©ã®èª¿è£œã«ããã€ãŠã¯ãå¡©åºæ§é«
ååååç©ãšé žæ§ååç©ãããªã¢ãªãŒã«ã€ãããŸ
ãªã«äºéäœããã³å¿ èŠãªãã°å å¢æå€ãé©åœãªæº¶
åªã«æº¶è§£ããŠåäžã«æ··åããå¡©åºæ§é«ååååç©
ãšé žæ§ååç©ãšã®éã§é žå¡©åºå¯Ÿã圢æãããæ¹æ³
ãæ¡çšããããé©åœãªæº¶åªãšããŠã¯ã¡ã¿ããŒã«ã
ãšã¿ããŒã«ãã€ãœãããããŒã«ã®ãããªäœçŽã¢ã«
ã³ãŒã«ãã¢ã»ãã³ãã¡ãã«ãšãã«ã±ãã³ã®ãããª
ã±ãã³é¡ãã¡ãã«ã»ããœã«ãããšãã«ã»ããœã«ã
ãªã©ã®ãšã¹ãã«é¡ããã«ãšã³ããã·ã¬ã³ãªã©ã®è³
éŠæååç©ãŸãã¯ãããã®ïŒçš®ä»¥äžã®æ··åç©ãçš
ããããšãã§ãããããããçšããå¡©åºæ§é«åå
ååç©ãåžžæž©ã§æ¶²äœã§ãããããŸãã¯ãã®èç¹ã
è»åç¹ãæµåç¹ãæ¯èŒçäœãå Žåã«ã¯ã溶åªã䜿
çšããããšãªãçŽæ¥äž¡è ãæ··åããæ¹æ³ãæ¡çšã
ããã ãã®æ§ã«ããŠèª¿è£œãããæ¬çºæã®çµæç©ã¯ãã
ãšãã°æº¶æ¶²æµå»¶æ³ãç±ãã¬ã¹æ³ã泚åæ³ã溶èæŒ
ãåºãæ³ãªã©ã«ããææã®åã¿ã®èããã€ã«ã ã
ã·ãŒãç¶ç©ãšæãããšãããããŸããããããæ¥
çå±€ãä»ããŠãŸãä»ããã«æ¯æäœã«ç©å±€ããããš
ãã§ãããæ¯æäœãšããŠã¯ã¹ããŒã«ãã¢ã«ãããŠ
ã ããã©ã¹ããã¯ãã€ã«ã ãã¬ã©ã¹ãªã©ä»»æã®ã
ã®ã䜿çšã§ããã æ¬çºæã®çµæç©ã«å¯Ÿããæå å æºãšããŠã¯ãã
ãšãã°å皮氎éç¯ãççŽ ã¢ãŒã¯ç¯ããã»ãã³ã©ã³
ãã玫å€ç·è¢å ç¯ãªã©400mΌ以äžã®æ³¢é·ã®å ç·ã«
å¯ããã®ã奜ãŸããã ãããã®å æºããã®æ¬çºæã®çµæç©ã«å¯Ÿããå
ç §æ¹æ³ãšããŠã¯ãå éééšåããã³é®å éšåãã
æãææã®ç»åãŸãã¯ãã¿ãŒã³åãæããããã
ããã¬ãã€ã«ã ãŸãã¯ããžãã€ã«ã ãéããŠè¡ã
ããããããã¯ããã®æ§ãªå æºããã®å ããŒã ã«
ããæ¬çºæã®çµæç©ã®ç»äžããææã®ç»åãŸãã¯
ãã¿ãŒã³åãè»è·¡ãšããŠèµ°æ»ããããšã«ããè¡ã
ããã å ç §å°ã«ããæ¬çºæã®çµæç©ã®é¢äžã«å ã圢æ
ãããæœåã¯ãå ç §å°ãåããªãã€ãéšåãšæ¯èŒ
ããŠèŠªæ°Žæ§ãäœäžããŠããããæ®ãã©çæ°Žæ§ã«å€
åããŠããããã®ããšã¯å ç §å°éšåã®æ¥µæ§ãéç §
å°éšåã®ãããããäœäžããŠãããšè¡šçŸããããš
ãã§ããã äžã€ã®é¢äžã«åŸããã極æ§ã®ç°ãªãç»åæœåãŸ
ãã¯ãã¿ãŒã³æœåã¯ãäœãã®è¿œå çåŠçããè¡ã
ãã«ãã®ãŸãŸå©çšããããšãã§ãããŸãäœããã®
çŸååŠçãæœãããŠå©çšããããšãã§ããã çŸååŠçã溶åªãå¿ èŠãšããå Žåã溶åªã®éžæ
ã¯ãå ç §å°éšåãšéç §å°éšåã®æ¥µæ§ã®å·®ã«å¯Ÿå¿ã
ãŠä»»æã«è¡ããåŸããäžè¬çã«ã¯æ°Žã®å©çšãæã
䟿å©ã§ããããã€å¥œãŸããããæ¬çºæã®çµæç©ã«
é¢ããŠã¯æ°ŽçŸåã®æ¡çšãå¯èœã§ããããã®å Žåã
PH5.5ã7.5ã®æ°Žã®äœ¿çšã奜ãŸããã æ¬çºæã®çµæç©ã®å¹æçå©çšã¯ãåè¿°ã®æ§ã«ã
äž»ãšããŠèç¶ããã€ã«ã ç¶ãŸãã¯ã·ãŒãç¶ãªã©ã®
æ¯èŒçèãå±€ã«ãã€ãŠãªããããã€å€ãã®å Žåã¯
é©åœãªæ¯æäœãšã®ç©å±€ç©ãšããŠå©çšããããå ·äœ
çå©çšã«åœã€ãŠã¯ãç©ç¶ç©ã®é¢äžã«å ç §å°ãè¡ã€
ãŠåŸãã極æ§ãŸãã¯èŠªæ°Žæ§ã®å·®ãå±€ç¶ç©ã®åœ¢æ ã
å€ããããšãªãå©çšããå Žåãšãæ°Žã«ãããšãã
ã³ã°ãŸãã¯ãŠãªãã·ãŠã¢ãŠãæäœãå ããŠå©çšã
ãå Žåããããåè ã®å©çšäŸã¯ã極æ§ã®å·®ããå¿
ç¶çã«çºçããå°é»æ§ã®å·®ãå©çšããé»ååççš
éãéé»å°å·çšéããããããã«æè²æ§ã®å·®ãå©
çšããç»åèšé²ææãšããŠãçšãããããäžæ¹ã
åŸè ã®å©çšäŸã¯ãåçš®ãã¬åã¬ãžã¹ããšããŠããŸ
ããªãã»ããå°å·ççšãšããŠã®çšéãããããã
ã«ã¬ãªãŒããšããŠã¯åžçå°å·çšæš¹èçãããŒã ã
ã¬ãŒããé³åçšæš¹èåããšã³ãã¹å å·¥çšæš¹èåãª
ã©ã®å©çšãæããããã æ¬çºæã®çµæç©ã¯ãå以ã€ãŠææãŸãã¯é¡æã
æ··ããç³»ã§ãå©çšããããã¿ãŒã³é®å çšåçš®ãã¹
ãã³ã°çšéã«ãæå¹ãªææãæäŸããã 以äžãããæ§æãããªãæ¬çºæçµæç©ã®ç¹é·ãš
ãããšããã¯ããã®äž»æåã§ããïŒçš®ã®ååç©
ïŒå¡©åºæ§é«ååååç©ãé žæ§ååç©ããã³ããªã¢
ãªãŒã«ã€ãããŸãªã«äºéäœïŒã®åã ã®éžæçš®ãã
ã³çžäºã®éæ¯ãåºãç¯å²ã«ãããçµã¿åãããã
ãšã«ãããå ç §å°ã«ãã極ãããããªèŠªæ°Žæ§ã®å€
åãããæ°Žäžæº¶æ§ä¹è³æ°Žæº¶æ§ãšãã倧ããªå€åã«
ãããææã®æ§èœå€åãçºçŸããåŸãããšã§ã
ãããŸããæ¬çºæã®çµæç©ã®å åå¿ã¯é£éåå¿ã«
äŸã€ãŠé²è¡ãããã®ã§ã¯ãªãã®ã§ã解ååã極ã
ãŠé«ããæèšããã°ãæ¬çºæã®çµæç©ã¯æš¹èã®ïŒ
次å åå¿ãšç°ãªããå ç §å°åŸã®äœç©åçž®ãããªã
ã¡åã®å šã䌎ãããåŸã€ãŠé«ã解ååãä¿æãã
ããšãã§ãããå ããŠãïŒæ¬¡å åããŠããªãé«å
åååç©ã¯æ¬è³ªçã«æº¶åªå¯æº¶ã§ããããšãããæ¬
çºæã®ååç©ã«ãããããšãã°ã¬ãžã¹ãåãã¬ãª
ãŒãåã補é ããå Žåã«ãäžæŠåŸãããåã®ä¿®æ£
çæ¶å»ãå¯èœãšãªããæŽã«æ¬çºæã®çµæç©ã®å å
å¿ã¯ãå éååå¿ã®ããšãé žçŽ ã«ãã€ãŠåŠšå®³ãã
ãããšã¯ãªãã®ã§ã空æ°äžããã®é žçŽ ååã®æ¡æ£
ãèµ·ãæãèèç¶æ ã§ã®åå¿é床ã«ãäœãã®æ¯é
ãçããªããããããŠç±çãªå®å®æ§ãé«ããæ¬çº
æã®çµæç©ã§ã¯æ¥µããŠæ°žãã·ãšã«ãã©ã€ããä¿èšŒ
ãããã æ¬çºæã®çµæç©ã®ä»äžã€ã®ç¹é·ã¯ãã¬ãžã¹ãå
ãã¬ãªãŒãåãåŸãå Žåã®ãšããã³ã°ãŸãã¯ãŠãª
ãã·ãŠã¢ãŠãã«éããŠãåãªãæ°Žãæ¡çšã§ããç¹
ã§ããããã®ããšã¯å®å šæ§ã®é¢ã§ç¹ã«å¥œãŸããäœ
æ¥ç°å¢ãšæäœæ§ãçŽæããããšã«ãªããããã«æ¬
çºæçµæç©ã¯ãå åå¿é床ã極ããŠéããããå
åã«å®çšãåŸããã®ã§ããã 次ã«å®æœäŸã瀺ããæ¬çºæãæŽã«å ·äœçã«èª¬æ
ããããªããå®æœäŸäžãéšãšããã¯ç¹èšããªãé
ãéééšãè¡šããã å®æœäŸ ïŒ ïŒâã¡ãã«âïŒâïŒïŒ®ïŒNâ²âãžã¡ãã«ã¢ããïŒ
ã¡ãã«âïŒïŒïŒâãããã³ãžãªãŒã«ãšãã¬ãã¿ã«
é žããçŽæ¥éåæ³ã«ããåŸãããããªãšã¹ãã«ïŒ
éšãâããšãã«ã°ãªã·ã³0.4éšãïŒâïŒïœâã¯
ãã«ããšãã«ïŒâïŒïŒïŒâãžããšãã«ã€ãããŸãª
ã«äºéäœ0.15éšãã¡ãã«ãšãã«ã±ãã³ïŒéšã«æº¶è§£
ããã åŸããã溶液ãããããããè¡šé¢ã«å°é»åŠçå€
ïŒåæšåïŒDow ECR34ãããŠã±ãã«ã«ç€Ÿè£œïŒã
å¡åžä¹Ÿç¥ããã¢ãŒãçŽäžã«å¡åžããç±é¢šä¹Ÿç¥åšã«
ãã70âã§ïŒåé也ç¥ãè¡ã€ãŠåã6ÎŒã®ããã
å±€ãæããæå çŽãåŸãã ãã®æå çŽã«ãã¬ãã€ãã»ãªãªãžãã«ãã€ã«ã
ãéãã±ãã«ã«ã©ã³ãïŒ20WÃ10æ¬ãã©ã³ãâæ
å çŽéè·é¢45mmïŒã§2.5åéé²å ãããé²å æžã®
æå çŽãé»åè€åæ©ïŒåæšåïŒã³ãã¹ã¿ãŒ211ã
äžç°å·¥æ¥æ ªåŒäŒç€Ÿè£œïŒã«éãããšãããé²å éšã®
ã¿ã«ãããŒãä»çããããžç»åãåŸãããã網ç¹
解åæ§ã¯150lineïŒinchã§ãã€ãã å®æœäŸ ïŒ å®æœäŸïŒã§åŸãé²å æžã®æå çŽãéé»è»¢åè£ çœ®
ïŒåæšåïŒãŒããã¯ã¹1385ãã©ã³ã¯ãŒããã¯ã¹ç€Ÿ
補ïŒã«ã»ããããéé»è»¢åãã«ã¹ã±ãŒãæ³ã«ãã
ã¢ãŒãçŽã«å¯ŸããŠè¡ã€ããšãããã¢ãŒãçŽã«ã¯é®®
æãªãããŒåã圢æãããã 転ååŸã®æå çŽãè±è綿ã§ã¯ãªãŒãã³ã°ããå
床éé»è»¢åè£ çœ®ã«ã»ãããããšããå·¥çšã«ãã転
åãç¹°ãè¿ãããšãããåäžã®è€åç©ãå€æ°æåŸ
ããã30åã®è©Šè¡åŸãç»åã¯å šãåäžã§ãã€ãã ã¡ãªã¿ã«ããããæå çŽã®åž¯é»é»å§ããã³ãã®
çµæå€åãã¹ã¿ãã€ãã¯ãªãã¹ãã¡ãŒã¿ãŒïŒåæš
åïŒæ ªåŒäŒç€Ÿç©ŽæžåäŒè£œïŒã«ãããâ15KVæŸé»
ã§æªé²å éšããã³é²å éšã«ã€ããŠæž¬å®ãããé²å
æããã³é²å åŸïŒã±æã®åž¯é»é»å§ã¯ãæªé²å éšã§
ã¯å ±ã«300Vãé²å éšã§ã¯å ±ã«15Vã§ãã€ãã ãã®æ§ãªæ§èœã¯ãæ¬çºæã®çµæç©ããã¬ããžã¿
ã€ãã®éé»å°å·åçã«å¥œé©ã§ããããšã瀺ããŠã
ãã å®æœäŸ ïŒ å®æœäŸïŒã®çµæç©æº¶æ¶²ããéœæ¥µé žååŠçããå
ã200ÎŒã®ã¢ã«ãæ¿äžã«ãåã2ÎŒã«åäžã«ã³ãŒã
ãã50âã§ïŒåé枩颚也ç¥ããã該æå æ¿ã«ãã¬
ãã€ããªãªãžããã€ã«ã ãå¯çããé«å§æ°Žéç¯
ïŒãªããŒç€ŸããªããŒããªã³ã¿ãŒ3000ïŒã§2.5åéé²
å ãããé²å åŸã該æå æ¿ã20âã®PHïŒïŒã®æ°Žã«
浞挬ãããŠãªãã·ã€ãŒïŒå€§æ¥æ¬ã¹ã¯ãªãŒã³ç€Ÿè£œïŒ
ã§ãã©ãã·ã³ã°ãè¡ãªããæ°ŽæŽãæ°ŽåãåŸã60â
ã§10åé枩颚也ç¥åšã§ä¹Ÿç¥ãã次ãã§ã¬ã 液ïŒå¯
åãã€ã«ã 瀟補GUïŒã§ã¬ã åŒããè¡ãªã€ãã宀
æž©ã§é¢šä¹Ÿç¥åŸããªãã»ããå°å·æ©ïŒãªãšãŠã瀟補
KR480åïŒã§å°å·ãã¹ããè¡ã€ãçµæãè¯å¥œãª
å°å·ãµã³ãã«ãåŸãããã æ¯èŒäŸ ïŒ å®æœäŸïŒã«ãããŠãïŒâïŒïœâã¯ãã«ããšã
ã«ïŒâ4.5âãžããšãã«ã€ãããŸãªã«äºéäœãé
åããªãã€ã以å€ã¯ãã¹ãŠå®æœäŸïŒãšåæ§ã«ããŠ
æå çŽïŒ¢ãåŸãã åŸãããæå çŽïŒ¢ãããããå®æœäŸïŒãšåæ§ã«
ããŠé²å éšã®ã¿ã«ãããŒãä»çããããžç»åãåŸ
ãããšããããå®æœäŸïŒãšåæ§ã®ç¶²ç¹è§£åæ§ãåŸ
ãããã«ã¯æå çŽïŒ¢ã¯ïŒåã®é²å æéãå¿ èŠã§ã
ã€ãã å®æœäŸ ïŒ åŒïŒ ã§ç€ºãããã¢ããã¢ã«ãã«ã¡ã¿ã¯ãªã¬ãŒã50éšãª
ãã³ã«ã¡ã¿ã¯ãªã«é žã¡ãã«50éšãéåããŠåŸãã
ãé«ååååç©ïŒéšãããšãã«ã°ãªã·ã³0.35éšã
ïŒâïŒïœâã¯ãã«ããšãã«âïŒïŒïŒâïŒïœâãžã¢
ãã·ã«ïŒã€ãããŸãªã«äºéäœ0.2éšãããªããšã
ã«ãã©ãŸãªã³0.05éšãããã«ã«ãŒãã³ãã©ãã¯
0.15éšãããã³ããã©ãã€ãããã©ã³ïŒéšãããª
ãçµæç©ãåã100ÎŒã®ããªãšãã¬ã³ãã¬ãã¿ã¬
ãŒãã®ïŒè»žå»¶äŒžãã€ã«ã äžã«å¡åžãã也ç¥ããŠå
ã3ÎŒã®æå æ§ç©å±€äœãåŸããåå å 床èšãçšã
ãŠ300ã400mÎŒã®æ³¢é·ç¯å²ã®æŽ»æ§å ç·åžåçã枬
å®ãããšããã99.9ïŒ ä»¥äžã§ãã€ãããã®æå æ§
ç©å±€äœã«å®æœäŸïŒããã³ïŒã§çšããç»åãã¬ãã€
ã«ã ãå¯çãããŠ3KWã®è¶ é«å§æ°Žéç¯ãçšãã
50cmã®è·é¢ã§ïŒåéé²å ãè¡ã€ãããã®åŸãã¹ã
ã¬ã€ããºã«ããïŒKgïŒcm2ã®æ°Žå§ã®æ°Žéæ°ŽãçŽ0.5
åéåŽãã€ããå³åº§ã«ä¹Ÿç¥ãè¡ã€ãçµæã網ç¹æ¿
床ïŒïŒ ãã90ïŒ ã®ç¯å²ã§æ¥µããŠå¿ å®ãªçœé»ç»åã
åŸãããããã®çœé»ç»åãæããããžãã€ã«ã ã
åè¿°ã®æªé²å æå æ§ç©å±€äœäžã«å¯çããããŠåæ§
ã®åŠçãè¡ããšã網ç¹ãå¿ å®ã«åçŸããå転çœé»
ãã¬ç»åãåŸãããã æŽã«ããã®ãã¬ãã€ã«ã ãæå æ§æš¹èçãæ±æŽ
玡ããªã³ã¿ã€ãRFâ95ã«å¯çãããŠå®æœäŸïŒã§
çšããé²å æ©ã§4.5åéé²å ããæ±æŽçŽ¡ããªã³ã¿
ã€ãçšæŽåºãæ©ã§2.5åéæ°ŽæŽãè¡ãªã€ãŠéåžžã«
è¯å¥œãªåžçå°å·çšã¬ãªãŒãçãåŸãã å®æœäŸ ïŒ ãžãšãã«ã¢ãããšãã«ã¡ã¿ã¯ãªã¬ãŒã30éšãšãš
ãã¬ã³70éšãéåããŠåŸãé«ååååç©ïŒéšãïŒ
âïŒïœâã¯ãã«ããšãã«ïŒâïŒïŒïŒâïŒïœâãžã¢
ãã·ã«ïŒã€ãããŸãŒã«äºéäœ0.1éšãïŒâã¯ãã«
ããšãã«ã°ãªã·ã³0.3éšãã¡ãã«ãšãã«ã±ãã³ïŒ
ãã«ãšã³ïŒå®¹éæ¯5.5ïŒ4.5ïŒæ··å溶åªã«æº¶è§£ã
ããåŸããã溶液ãããªãããã¬ã³ãã€ã«ã ïŒå
ã60ÎŒãåæšåïŒæ±æŽçŽ¡ãã€ã¬ã³ãã€ã«ã P1120
ïŒ60ãæ±æŽåæå·¥æ¥æ ªåŒäŒç€Ÿè£œïŒã«ã¯ã€ã€ãŒããŒ
ã§è¢«èŠãã70âã§ïŒåé也ç¥ãè¡ãåã5ÎŒã®æ
å å±€ãæããæå ãã€ã«ã ãåŸãã ãã®æå ãã€ã«ã ã«ãã¬ãã€ãã»ãªãªãžãã«ã
ã€ã«ã ãéããã±ãã«ã«ã©ã³ãïŒ20WÃ10æ¬ãã©
ã³ããŒæå çŽéè·é¢45mmïŒã§1.5åéé²å ããã ããã ããšããŒã«ãã«ãŒ0.005éšãæ°ŽïŒã¡ã¿ã
ãŒã«ïŒå®¹éæ¯ïŒïŒïŒïŒæ··å溶åª10éšã«æº¶è§£ããçŸ
å液ã«ãé²å åŸã®ãã€ã«ã ã30ç§é浞挬ããŠæ·±é
è²ã®ããžç»åããã網ç¹è§£åæ§ã¯150lineïŒinch
以äžã§ãã€ãã å®æœäŸ ïŒ ïŒ®âïŒÎ²âã¢ãããšãã«ïŒããã©ãžã³40éšãã¢
ãžãã³é ž50éšããã³Îµâã«ããã©ã¯ã¿ã 38éšãé
åããŠåŸãããããªã¢ãã100ãšïŒâãããããš
ãã«ã°ãªã·ã³50éšãïŒâïŒ2â²âã¯ãã«â1â²âãã
ãã«ïŒâïŒïŒïŒâïŒïœâãžã¢ãã·ã«ïŒã€ãããŸãŒ
ã«äºéäœ20éšããã³ïŒââãžã¡ãã«ã¢ããã¯ã
ãªã³ïŒéšãã¡ã¿ããŒã«ã«æº¶è§£åŸã該溶液ãæµå»¶ã
ãŠ28mmã®éæ¿ã«è²Œãåãããããã®æ§ã«ããŠåŸã
æå æ§åæ¿ã«150lineïŒinchã®ç¶²å解ã§äœããã
ç»åãã¬ãå¯çããç §åºŠ200WïŒcm2ã®ã±ãã«ã«ã©
ã³ãã§ïŒåéé²å ãè¡ãªã€ãããã®åŸãPH7.5ã®
æ°Žéæ°Žäžã«æµžæŒ¬ããç¶æ ã§ïŒåéãã©ãã·ã³ã°ã
è¡ãã次ãã§60âã®æž©é¢šã§10åé也ç¥ããã åŸãããã¬ãªãŒãçã¯ç»åãã¬ã«å¿ å®ãªå¯Ÿå¿ã
瀺ããŠããããŸãã¬ãªãŒãæé¢ã®ã·ãšã«ããŒè§åºŠ
ã¯çŽ70床ã§ãã€ãã ãã®ã¬ãªãŒãçãçšããŠãèªååžçæ ¡æ£æ©ïŒæ¯
å©è£œäœæ補ïŒã«ããå°å·ãã¹ããè¡ãªã€ãçµæã
åå³ç»åãè¯å¥œã«åçŸããå°å·ãµã³ãã«ãåŸãã
ãã ããã«ããã®ã¬ãªãŒãçã®ç»åã®äžéšãæ®ããŠ
ã»ããã¢ã³ããŒãã§çé¢ã被èŠããåŸãPH4.0ã®
æ°Žã§0.5åéã¹ãã¬ãŒæŽãåºããè¡ã€ããã»ãã
ã¢ã³ããŒããå¥ãããŠä¹Ÿç¥ããåŸãäžèšãšåæ§ã®
å°å·ãã¹ããè¡ã€ããšããã被èŠãæœããªãã€ã
éšåã®ã¿ã®ç¶²ç»åãä»ã®éšåã«æ¯ã¹éåžžã«æãã
ãå°å·ç©ãåŸãããã å®æœäŸ ïŒ ããªïŒâããã«ããªãžã³ïŒåºæ ååŠæ ªåŒäŒç€Ÿ
補ïŒ50éšãïŒâãããããªããšããã·é ¢é žïŒéšã
ïŒâïŒïœâãããããšãã«ïŒâïŒïŒïŒâãžããšã
ã«ã€ãããŸãŒã«äºéäœ10éšããã³ãã«ãªã¬ã»ã€ã³
ïŒéšãã¢ã»ãã³âã¡ã¿ããŒã«æ··å溶åªã«æº¶è§£ããŠ
åäžãªæš¹èçµæç©ã®æº¶æ¶²ã調補ããããã®æº¶æ¶²ã
åã0.3mmã®çŽé¢ã«ããŒã³ãŒã¿ãçšããŠå¡åžãã
åŸã颚也ç¥ããŠçŽ5ÎŒã®åã¿ã®æš¹èçµæç©ã被èŠ
ãããæå çŽãåŸããåŸãããæå çŽã®æš¹èã³ãŒ
ãé¢äžã«ãå®æœäŸïŒã§çšãããã¬ãã€ã«ã ãå¯ç
ãããå®æœäŸïŒãšåãé²å æ©ã§çŽïŒåéé²å ãè¡
ã€ããé²å ããæå çŽããã¢ãã¯ã¹ãªãã»ããæ©
ïŒãªã³ãŒæ ªåŒäŒç€Ÿè£œïŒã«åä»ããŠå°å·ãã¹ããè¡
ã€ãçµæãè¯å¥œãªå°å·ãµã³ãã«ãåŸãããã å®æœäŸ ïŒã17 å®æœäŸïŒã«ãããŠãâããšãã«ã°ãªã·ã³ã®ä»£
ãã«ç¬¬ïŒè¡šã«ç€ºãé žæ§ååç©ãæå®éããã³å å¢
æå€ãé åããããé åããã«å®æœäŸïŒãšåæ§ã«
ããŠåã3ÎŒã®ãããå±€ãæããæå çŽãåŸãã
åŸãããæå çŽããããããã¬ãã€ããªãªãžãã«
ãã€ã«ã ãéããŠå®æœäŸïŒãšåæ§ã«ããŠãåæé
ã ãæå ãé»åè€åæ©ã«éããŠããžç»åãåŸãã
åã ã®ç¶²ç¹è§£åæ§ã第ïŒè¡šã«äœµèšããã
ãè¡šã
ãè¡šã
å®æœäŸ 18
âãžã¡ãã«ã¢ãããšãã«ã¡ã¿ã¯ãªã¬ãŒã56éš
ããã³ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã44éšãéåããŠåŸã
ããé«ååååç©ïŒéšãïŒâïŒïŒ¯âã¯ãã«ããšã
ã«ïŒâïŒïŒïŒâïŒïœâãžã¢ãã·ã«ïŒã€ãããŸãŒã«
äºéäœ0.24éšãïŒâãããããšãã«ã°ãªã·ã³0.4
éšããã³ããªããšãã«ãã©ãŸãªã³0.05éšãããã«
ã«ãŒãã³ãã©ãã¯0.15éšããã³ããã©ãã€ããã³
10éšãããªãçµæç©ãåã100ÎŒã®ããªãšãã¬ã³
ãã¬ãã¿ã¬ãŒãã®ïŒè»žå»¶äŒžãã€ã«ã äžã«å¡åžãã
也ç¥ããŠåã3ÎŒã®æå æ§ç©å±€äœãåŸããåå å
床èšãçšããŠ300ã400mÎŒã®æ³¢é·ç¯å²ã®æŽ»æ§å ç·
åžåçã枬å®ãããšããã99.9ïŒ ä»¥äžã§ãã€ãã
ãã®æå æ§ç©å±€äœã«å®æœäŸïŒããã³ïŒã§çšããç»
åãã¬ãã€ã«ã ãå¯çãããŠ3KWã®è¶ é«å§æ°Žé
ç¯ãçšãã50cmã®è·é¢ã§ïŒåéé²å ãè¡ãªã€ãã
ã®åŸã¹ãã¬ãŒããºã«ããïŒKgïŒcm2ã®æ°Žå§ã®æ°Žéæ°Ž
ãçŽ0.5åéåŽãã€ããå³åº§ã«ä¹Ÿç¥ãè¡ãªã€ãçµ
æã網ç¹æ¿åºŠïŒïŒ ãã90ïŒ ã®ç¯å²ã§æ¥µããŠå¿ å®ãª
çœé»ç»åãåŸãããããã®çœé»ç»åãæããããž
ãã€ã«ã ãåè¿°ã®æªé²å æå æ§ç©å±€äœäžã«å¯çã
ãããŠåæ§ã®åŠçãè¡ãªããšç¶²ç¹ãå¿ å®ã«åçŸã
ãå転çœé»ãã¬ç»åãåŸããããæŽã«ããã®ãã¬
ãã€ã«ã ãæå æ§æš¹èçãæ±æŽçŽ¡ããªã³ã¿ã€ã³ã
RFâ95ã«å¯çãããŠå®æœäŸïŒã§çšããé²å æ©ã§
4.5åéé²å ããæ±æŽçŽ¡ããªã³ã¿ã€ãçšæŽãåºã
æ©ã§2.5åéæ°ŽæŽãè¡ãªã€ãŠéåžžã«è¯å¥œãªåžçå°
å·çšã¬ãªãŒãçãåŸãã å®æœäŸ 19 å®æœäŸ18ã§ææ©é žååç©ïŒâãããããšãã«ã°
ãªã·ã³ã®æ¿ãã«ãâïœâããã«ããªé ¢é ž0.3éš
ãçšãã以äžå®æœäŸ18ãšåæ§ã«å®æœããåæ§ãªçµ
æãåŸãã
ããã³ã¡ãã«ã¡ã¿ã¯ãªã¬ãŒã44éšãéåããŠåŸã
ããé«ååååç©ïŒéšãïŒâïŒïŒ¯âã¯ãã«ããšã
ã«ïŒâïŒïŒïŒâïŒïœâãžã¢ãã·ã«ïŒã€ãããŸãŒã«
äºéäœ0.24éšãïŒâãããããšãã«ã°ãªã·ã³0.4
éšããã³ããªããšãã«ãã©ãŸãªã³0.05éšãããã«
ã«ãŒãã³ãã©ãã¯0.15éšããã³ããã©ãã€ããã³
10éšãããªãçµæç©ãåã100ÎŒã®ããªãšãã¬ã³
ãã¬ãã¿ã¬ãŒãã®ïŒè»žå»¶äŒžãã€ã«ã äžã«å¡åžãã
也ç¥ããŠåã3ÎŒã®æå æ§ç©å±€äœãåŸããåå å
床èšãçšããŠ300ã400mÎŒã®æ³¢é·ç¯å²ã®æŽ»æ§å ç·
åžåçã枬å®ãããšããã99.9ïŒ ä»¥äžã§ãã€ãã
ãã®æå æ§ç©å±€äœã«å®æœäŸïŒããã³ïŒã§çšããç»
åãã¬ãã€ã«ã ãå¯çãããŠ3KWã®è¶ é«å§æ°Žé
ç¯ãçšãã50cmã®è·é¢ã§ïŒåéé²å ãè¡ãªã€ãã
ã®åŸã¹ãã¬ãŒããºã«ããïŒKgïŒcm2ã®æ°Žå§ã®æ°Žéæ°Ž
ãçŽ0.5åéåŽãã€ããå³åº§ã«ä¹Ÿç¥ãè¡ãªã€ãçµ
æã網ç¹æ¿åºŠïŒïŒ ãã90ïŒ ã®ç¯å²ã§æ¥µããŠå¿ å®ãª
çœé»ç»åãåŸãããããã®çœé»ç»åãæããããž
ãã€ã«ã ãåè¿°ã®æªé²å æå æ§ç©å±€äœäžã«å¯çã
ãããŠåæ§ã®åŠçãè¡ãªããšç¶²ç¹ãå¿ å®ã«åçŸã
ãå転çœé»ãã¬ç»åãåŸããããæŽã«ããã®ãã¬
ãã€ã«ã ãæå æ§æš¹èçãæ±æŽçŽ¡ããªã³ã¿ã€ã³ã
RFâ95ã«å¯çãããŠå®æœäŸïŒã§çšããé²å æ©ã§
4.5åéé²å ããæ±æŽçŽ¡ããªã³ã¿ã€ãçšæŽãåºã
æ©ã§2.5åéæ°ŽæŽãè¡ãªã€ãŠéåžžã«è¯å¥œãªåžçå°
å·çšã¬ãªãŒãçãåŸãã å®æœäŸ 19 å®æœäŸ18ã§ææ©é žååç©ïŒâãããããšãã«ã°
ãªã·ã³ã®æ¿ãã«ãâïœâããã«ããªé ¢é ž0.3éš
ãçšãã以äžå®æœäŸ18ãšåæ§ã«å®æœããåæ§ãªçµ
æãåŸãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ (1)ããèªäœã§ã¯èŠªæ°Žæ§ãäœããããŸãã¯æ°Žäž
溶æ§ã§ããããé žæ§ãæããååç©ãšã®å ±åäžã§
é žå¡©åºçžäºäœçšã«ãã芪氎æ§ãé«ããªããããŸã
ã¯æ°Žæº¶æ§ã«ãªãæ§ãªæ§è³ªãæããå¡©åºæ§é«ååå
åç©ã§ãã€ãŠã該é«ååååç©ã圢æããåéäœ
ãå¡©åºæ§ã瀺ãåºãæãããã€æ°Žæº¶åªäœã«ãããŠ
é»äœå·®æ»Žå®ã«ãã枬å®ããŠå¡©åºæ§åºãpka2以äž
ã瀺ããããã«è©²é«ååååç©äžã®çªçŽ å«éã
0.1ã25åœéïŒKgã§ããå¡©åºæ§é«ååååç©ã®å°
ãªããšãïŒçš®ã(2)æ¬æ¥é žæ§ã§ãããå ç §å°ãåã
ãããšã«ããå åŠå€åãèµ·ãããŠé žæ§ã倱ããã
ãªé žæ§ååç©ã§ãã€ãŠãäžèšäžè¬åŒïŒïŒã§ç€ºã
ããé žæ§ååç©ãïŒâãããããªããšããã·é ¢
é žãâããšãã«ã¢ã©ãã³ãâããšãã«ã°ã«ã¿
ãã³ãããšãã«ã«ã«ããã·ã¡ãã«ã»ã¬ããããã³
ã€ã³ããã·ã«é žããéžæãããå°ãªããšãïŒçš®ã
ãã³(3)ããªã¢ãªãŒã«ã€ãããŸãªã«äºéäœãå«æã
ãããšãç¹åŸŽãšããæå æ§æš¹èçµæç©ã ãåŒäžãR1ã¯ïŒšâãClâãNO2âã瀺ããR2ã¯
ãåŒãââãââã瀺ããã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11464981A JPS5815531A (ja) | 1981-07-21 | 1981-07-21 | æå æ§æš¹èçµæç© |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11464981A JPS5815531A (ja) | 1981-07-21 | 1981-07-21 | æå æ§æš¹èçµæç© |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5815531A JPS5815531A (ja) | 1983-01-28 |
| JPH0242841B2 true JPH0242841B2 (ja) | 1990-09-26 |
Family
ID=14643086
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11464981A Granted JPS5815531A (ja) | 1981-07-21 | 1981-07-21 | æå æ§æš¹èçµæç© |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5815531A (ja) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59230003A (ja) * | 1983-06-13 | 1984-12-24 | Daicel Chem Ind Ltd | å éåéå§å€ |
-
1981
- 1981-07-21 JP JP11464981A patent/JPS5815531A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5815531A (ja) | 1983-01-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4464456A (en) | Photosensitive polymer compositions comprising polyether-ester amides | |
| US4245031A (en) | Photopolymerizable compositions based on salt-forming polymers and polyhydroxy polyethers | |
| US4264708A (en) | Radiation sensitive element having a thin photopolymerizable layer | |
| US4337307A (en) | Light-sensitive diazo composition and material with branched polyurethane resin | |
| US4405705A (en) | Photosensitive resin composition containing basic polymeric compounds and organic carboxylic acids | |
| AU611721B2 (en) | Improved composition | |
| US4369249A (en) | Process for producing polymeric image and photosensitive element therefor | |
| US4292394A (en) | Process for preparing multicolor toned images on a single photosensitive layer | |
| US5229244A (en) | Dry processible photosensitive composition including photo-acid generator and optically clear polymer (co-polymer) blend that becomes tacky upon exposure to actinic radiation | |
| US3770435A (en) | Production of gravure printing plates based on plastics materials | |
| US4291115A (en) | Elements and method which use photopolymerizable compositions based on salt-forming polymers and polyhydroxy polyethers | |
| US4308338A (en) | Methods of imaging photopolymerizable materials containing diester polyether | |
| US4906551A (en) | Process for the post-treatment of developed relief printing forms for use in flexographic printing | |
| US3787211A (en) | Makeready foil for relief printing | |
| AU596101B2 (en) | Photosensitive elastomeric polymer composition for flexographic printing plate | |
| GB1587476A (en) | Photopolymerizable compositions and elements and methods of imaging | |
| JPH0119573B2 (ja) | ||
| JPS6341048B2 (ja) | ||
| JPS5830755A (ja) | é²å æ¹æ³ | |
| JPS5815531A (ja) | æå æ§æš¹èçµæç© | |
| US5286595A (en) | Process for creating a tacky tonable image surface through exposure of a substrate coated with a polymer blend, including a photo-acid generator, to actinic radiation | |
| GB2035591A (en) | Process for preparing multicolor toned images on a single photosensitive layer | |
| WO1998058296A1 (en) | Photosensitive polymer composition and element containing photosensitive polyamide and mixture of acrylates | |
| JPS6367176B2 (ja) | ||
| EP0058737B1 (en) | Flexographic printing plates containing blended adhesives |