JPH0284492A - 鋼の熱間圧延潤滑剤組成物 - Google Patents

鋼の熱間圧延潤滑剤組成物

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Publication number
JPH0284492A
JPH0284492A JP1134323A JP13432389A JPH0284492A JP H0284492 A JPH0284492 A JP H0284492A JP 1134323 A JP1134323 A JP 1134323A JP 13432389 A JP13432389 A JP 13432389A JP H0284492 A JPH0284492 A JP H0284492A
Authority
JP
Japan
Prior art keywords
heat insulating
hot rolling
steel
lubricant composition
insulating agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP1134323A
Other languages
English (en)
Other versions
JPH0813980B2 (ja
Inventor
Masanori Shirata
白田　昌敬
正義 ▲榊▼原
Masayoshi Sakakibara
Hiroshi Kamiyashiki
上屋舗　宏
Takao Kurahashi
隆郎 倉橋
Takahiko Koga
甲賀　孝彦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KYODO YUSHI KK
Kyodo Yushi Co Ltd
Nippon Steel Corp
Original Assignee
KYODO YUSHI KK
Kyodo Yushi Co Ltd
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KYODO YUSHI KK, Kyodo Yushi Co Ltd, Nippon Steel Corp filed Critical KYODO YUSHI KK
Priority to EP89907268A priority Critical patent/EP0453565B1/en
Priority to DE68924075T priority patent/DE68924075T2/de
Priority to AU38334/89A priority patent/AU625675B2/en
Priority to PCT/JP1989/000591 priority patent/WO1989012669A1/ja
Priority to KR1019900700275A priority patent/KR920005534B1/ko
Priority to CA002002036A priority patent/CA2002036A1/en
Publication of JPH0284492A publication Critical patent/JPH0284492A/ja
Priority to US08/266,784 priority patent/US5437802A/en
Publication of JPH0813980B2 publication Critical patent/JPH0813980B2/ja
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C10M141/06—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic nitrogen-containing compound
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Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。

Description

【発明の詳細な説明】 （産業上の利用分野） 本発明は、鋼の熱間圧延潤滑剤組成物に関し、基油また
は基グリースに特定の断熱剤を添加することにより、被
圧延材からワークロールへの熱伝達を防止し、ワークロ
ールのサーマルクラウン低減効果を有する改良された潤
滑剤組成物に関するものである。
（従来の技術） 従来、熱間圧延ではロールの保護のため、ロール冷却水
のみが使用されていたが、近年、圧延荷重の低減、ロー
ル摩耗減少のため圧延油が使用され多大な効果を収めて
いる。
（発明が解決しようとする課Ｂ） ところが、今までの熱間圧延潤滑剤は、使用目的がワー
クロール摩耗低減、ロール肌改善が主流であった。これ
は、今まで圧延製品の品質に対する要求が比較的穏やか
なため、ワークロールのサーマルクラウンがあまり重要
視されなかったことによる。しかし、最近、製品の高品
質化が叫ばれ製品の品質に直接影響するワークロールの
サーマルクラウン低減が重要になって来た。
（課題を解決するための手段） 本発明は、基油または基グリースに断熱剤を加えたこと
を特徴とする鋼の熱間圧延潤滑剤組成物に関するもので
、特に、断熱剤として特定の二種類のもの、即ち、（Ａ
）　１２００℃以下の温度で吸熱融解する無機化合物お
よび（Ｂ）　１２００℃以下の温度では融解または分解
せず室温での熱伝導率が０．０１（ｃａ　ｉ　７ｃｍ　
−Ｓ　・℃）以下で摩擦係数が０．７以下である無機粉
体を単独または組合せて組成物中に特定量加えることで
優れた断熱効果が得られワークロールのサーマルクラウ
ン防止に有効であることを知見し、本発明を達成するに
至った。
本発明の第１の発明においては基油に（八）と（Ｂ）と
の性状の異なる断熱剤を組合せて加え、その相剰効果に
より断熱性を高めたものである。
本発明の第２の発明においては基油の代りに基グリース
を用い、基グリースと断熱剤（Ａ）、基グリースと断熱
剤（Ｂ）および基グリースと断熱剤（八）と（Ｂ）との
組合せを加えて断熱性を高めたもので、グリースは油に
較べて高温における流動性が少なく、本来高温における
断熱性が優れているものであるから、断熱剤（Ａ）、　
（Ｂ）単独の添加でもかなりの効果があげる事ができる
。さらに断熱剤（Ａ）と（Ｂ）とを組合せて加えればそ
の相剰効果と相まって最も優れた効果をあげる事ができ
る。
また、本発明においては、基油に断熱剤（Ａ）と（Ｂ）
に加えて極圧剤および／または固体潤滑剤を添加するこ
とにより潤滑性の向上を計ることが出来た。
本発明の潤滑剤組成物には、さらに極圧剤および／また
は固体潤滑剤を添加することにより、基油ベースに比べ
、潤滑性、断熱性、貯蔵安定性、作業性、耐水洗性を向
上させることが出来た。
（作　用） ワークロールは被圧延材と接触することにより、ロール
表面温度が約８００℃まで上昇する。一方、今までの熱
間圧延用潤滑剤の多くは、鉱油、油性剤、極圧添加剤お
よび固体潤滑剤の組み合せで構成されており、潤滑性に
対する考慮はなされていたが、断熱（圧延材からワーク
ロールへの熱伝達を防げる）に対する考慮がなされてい
なかった。
一方、特開昭６０−６２１１号公報には、常圧下での融
点が１２００℃以下、平均粒径が１μｍ以下で、鋳鉄、
鋳鋼を含む鉄鋼およびその他の金属に対する腐食性がな
く、かつ熱の不良導性物質として機能する無機化合物の
微粉末を市販の熱間圧延油（液体）に添加することによ
りロールを保護できることが示されている。
しかし上記公開特許公報に示されている基油は、市販の
熱間圧延油（液体）であり、本発明で使用するグリース
とは異なっている。又使用される粉体は１２００℃以下
の温度で融解する無機化合物粉体であり、融解後は熱伝
達低下性が急減する。
そこで本発明においては、液体、基油を用いた場合は１
２００℃以下の温度で吸熱融解する無機化合物と、１２
００℃以下の温度では融解または分解しない無機粉体と
を組合せて加え、液体、基油より断熱性に優れている半
固体、基グリースを用いた場合は二種の無機粉体を単独
または組合せて加え、これによりさらに断熱性を高めた
ものである。
すなわち、本発明で使用する断熱剤は、（Ａ）１２００
℃以下で吸熱融解する無機化合物および（Ｂ）１２００
℃以下では融解または分解せず酸化に対して安定でかつ
室温での熱伝導率が０．０１　（ｃａ　ｌ　／　ｃｍ・
Ｓ・℃）以下で摩擦係数が０．７以下である無機粉体で
ある。具体的には、（Ａ）　１２００℃以下で吸熱融解
する無機化合物としては、ＫＰＯ３１ＮａＰＯ３＋　Ｋ
ａＰｚＯｔ等の縮合リン酸塩、ケイ酸ナトリウム、　Ｋ
ｚＣｒｔＯｔ等のクロム酸塩、Ｎａ（／！、　ＫＣｊ！
、　ＫＦ、　ＫＢｒ、　Ｋ１等のハロゲン化物等の固体
粉末があり、より好ましくは圧延機や被圧延材に腐食性
を示さない縮合リン酸塩、ケイ酸ナトリウムが良い。
一方、（Ｂ）　１２００℃以下では融解または分解せず
酸化に対して安定でかつ室温での熱伝導率が０．０１（
ｃａｌ　／ｃｔｓ−３・℃）以下で摩擦係数が０．７以
下である無機粉体としては、窒化ホウ素、窒化ケイ素、
無定形炭素、Ｋ３ＰＯ４、Ｃａｓ　（ＰＯａ）　ｚ　、
ベントナイト、Ｓｉｎｇ　、　ＺｎＯ等が利用できる。
なお、ここで規定した摩擦係数は、ピン・オン・ディス
ク法（直径１１ｍｍの円板に直径３ｆｆＩｌＩ＋の先端
平面状の棒を荷重１ｋｇｆで押し付け、速度０．０１（
ｍ／Ｓ）ですべらせる）で求めた。
又、断熱剤の平均粒径としては５０μＩ以下であれば使
用可能であるが、ロールと被圧延材の間隙を考慮すると
平均粒径１μｍ以下がより好ましい。
ここで、（Ａ）　１２００℃以下で吸熱融解する無機化
合物とＣＢ）　１２００℃以下では融解又は分解せず熱
伝導率が０．０１　（ｃａ　ｌ　／ｃＩＩ−Ｓ　・℃）
以下で摩擦係数が０．７以下である無機粉体を併用した
方が良い理由は明確にされた訳ではないが、以下の様に
考えている。すなわち、圧延時ロールバイト内は高温高
圧（６００℃以上、２０００　ｋｇ　ｆ　／　ｃｍ　”
以上）になる。
その際断熱剤（Ａ）は速やかに吸熱融解し被圧延材から
ワークロールへの熱伝達を防げる。しかし、一般に液体
は粉体より熱伝導率が増大することが知られており、断
熱剤（Ａ）の熱伝達低減効果も融解により急激に低下す
ると考える。一方、断熱剤（Ｂ）は高温、高圧下でも融
解又は分解しないためロールバイト中でも粉体で存在し
ワークロールと被圧延材の接触を妨げ、かつ本粉体自身
が潤滑性を有していることよりロールバイト内での摩擦
発熱を低減させるためと考える。
すなわち、断熱剤（Ａ）は断熱性に優れているが、高温
で融解すると断熱性が急激に低下する。一方断熱剤（Ｂ
）は１２００℃以下では融解または分解しないため広い
温度領域にわたり断熱性を有している。
従って、断熱剤（八）と断熱剤（Ｂ）を特定の比率で共
存させることにより両効果が共に優れる潤滑剤を始めて
知り得ることができたのである。
又、断熱剤の添加量は５〜５０重量％が適当であり、よ
り好ましくは１０〜４０重量％である。５重量％未満で
は断熱効果に乏しく、一方５０重量％より多くなると潤
滑剤の粘性が大きくなり給脂性が損なわれてしまう。な
お、断熱剤中の（Ａ）、　（Ｂ）の比は４９：１〜１：
４９が適当であるが、より好ましくは１９：１〜１：４
である。この理由としては、断熱剤（Ａ）の比が小さく
なるとロールバイト内での吸熱による断熱性が低下し、
遂に、断熱剤（８）の比が小さくなると高温断熱性が低
下するためである。
本発明で使用可能な基油としては、スピンドル油、マシ
ン油、ダイナモ油、モーター油、シリンダー油、ブライ
トストック等の中質および重質鉱油、牛脂、ラード、鯨
油、パーム油、ヤシ油、ナタネ油、米ヌカ油、大豆油等
の動植物油脂、８〜２２個の炭素原子を有する脂肪酸と
１価および多価アルコールとのエステル、α−オレフィ
ン、ポリブテン、シリコーン油、フッ素油等の合成油お
よびこれらの混合油があげられる。
本発明で使用可能な基グリースとしては、リチウム石ケ
ングリース、カルシムラ石ケングリース、ナトリウム石
ケングリース、アルミニウム石ケングリース、複合カル
シウム石ケングリース、ウレアグリース、ベントングリ
ース等があげられるが、耐熱性に優れるリチウム石ケン
グリース、複合カルシウム石ケングリース、ウレアグリ
ース、ベントングリースがより好ましい。
本発明で使用可能な固体潤滑剤としては、黒鉛（天然１
人造）、二硫化モリブデン、雲母（天然。
人造）、フッ化黒鉛、窒化ホウ素、軟質金属（金。
銀、銅等）、滑石等の無機系固体潤滑剤および、ＰＴＦ
Ｅ　（四フッ化エチレン）、ＭＣＡ（メラミンとシアヌ
ル酸付加物）、フタロシアニン等の有機系固体潤滑剤の
いずれでも使用可能であるが、耐熱性及び高温での酸化
安定性に優れかつ、被圧延材への影響が少ない黒鉛（天
然９人造）、雲母（天然１人造）、窒化ホウ素、滑石等
がより好ましい。固体潤滑剤の添加量は０〜４０重量％
が適当であり、より好ましくは５〜１５重量％である。
なお、４０重重量を超えると潤滑剤の粘性が大きくなり
給脂性が低下する。
本発明で使用可能な極圧添加剤としては、硫黄系化合物
、リン系化合物、塩素系化合物、有機金属化合物等があ
げられるが、発錆等の影響が少ない硫黄系化合物、リン
系化合物、有機金属化合物がより好ましい。極圧添加剤
の添加量は０〜２０重量％が適当であり、より好ましく
は０．５〜１０重量％である。添加量が２０重重量を超
えると、腐食性が現われるとかグリースのミセル構造が
不安定になる等の副作用を生じる。
（実施例） 次に、本発明を実施例及び比較例により説明する。
１１〜２６．　　　六　１〜５ 基油、基グリース、断熱剤および極圧添加剤、固体潤滑
剤を第１表に示す配合率で配合して実施例１〜２６、比
較例１〜５の潤滑剤を作った。これ等の組成物につき、
次に示す試験方法で性能を評価し、得た結果を第１表に
併記する。
（性能試験方法） Ａ）　Ｅ−１２による 試験 Ｅ−１２型熱間潤滑性能試験機の原理は、両端を固定後
誘導加熱した試験片を給油しながらロールではさみスリ
ップ潤滑し、各種潤滑剤の摩擦係数と耐焼付き性能を調
べ潤滑性の評価を行なうものである。
（Ｔ：軸トルク、Ｒ：ロール半径、Ｗ：負荷荷重）なお
、試験機の概要及び試験条件は下記の通りである。
イ）型式：２段式すべり潤滑試験機 口）ロール寸法：直径１２４ｍｍｘ長さ８０ｍｍハ）ロ
ール材質：ハイクロムロール （Ｈ３＝７０〜７５） 二）試験片材質：　　５Ｓ−４１ （縦２０×横２０×長さ５８０胴） ホ）試験片温度：　　４００．６００．８００℃（自動
温度調節） へ）速度：　　２０Ｏｒｐｍ ト）圧下荷重：５００〜３０００ｋｇｆ（５００ｋｇｆ
毎に荷重を増大） チ）潤滑剤供給方法：ハケ塗り Ｂ）肱跣血跋験 イ）Ａ）、で用いた試験片を２０　Ｘ　２０　Ｘ　１０
０　（舗）の試験片に切断加工する。
口）イ）の試験片を軒下につるし、２週間放置後の錆発
生の有無、を調べる。
発錆なし　　発錆大 Ｏ× Ｃ）■水洗性跋験 イ）ＨＨｔｌ済みのｌ板（ＳＰＣＣ−５Ｄ、　１００　
Ｘ　１００Ｘ０．８（Ｍ）　）に潤滑剤３０±３（■）
を均一に塗布する。
口）イ）の鋼板を下記条件にて水洗し、水洗後の重量を
求め、残油率を求める。
イ）ノズル型番：　　１／４　ＫＢＦＯ８６５０）吐出
量：　　６．４ｊ！／ｍ１ｎ （吐出圧：　　２．Ｏｋｇｆ／ｃｍ２）ハ）水洗時間：
５秒（水温：２５℃） 二）鋼板とノズルの距離：　　２００ｍｍイ）試験片材
質：　　ＷＴ−６０（直径２５ｍｍＸ長さ５０ｎｖｎ）
口）温度：高温材　７８０℃ 低温材　２２〜３０℃ ハ）熱電対二　Ｃ＾（０，５ｍｍ）　シース（取付位置
　１．５．３．０ｍｍ） 二）断熱材：カオウール ホ）圧縮カニ　　５００ｋｇｆ／ｃｍ”へ）試料の充填
方法及び厚さ： 第１図に示すように試料１を塗り付けた低温材２に高温
材３を押し付け、接触後の両試料の温度の時間的変化か
ら、各試料の接触界面温度と熱流速を逆算し、ニュート
ン（Ｎｅ＋５ｔｏｎ）の冷却法則を拡大適用し、金属間
熱伝達係数を求め、更に、その係数を試料なしの場合と
比較し熱伝達比とする。
尚、第１図において４は断熱材、５は熱電対を示す。
Ｅ）　　　　　でのロール Ｆ５スタンド（６スタンドミル）入側上ワークロールに
エアスプレーノズル８個（２０ｆｆＩ！！、７分・ノズ
ル）を取り付け、ニッケルグレンロールを用い一般材、
約３００トンを圧延しロール摩耗量を測定し、現用油剤
との摩耗量比較を行う。
（発明の効果） 本発明の効果を要約すれば以下の通りである。
基油または基グリースに断熱剤（Ａ）および／または断
熱剤（Ｂ）を添加したことより、被圧延材からワークロ
ールへの熱伝達を抑制出来る。従って、熱によるワーク
ロールの損傷およびワークロールのサーマルクラウンを
減少出来る。
【図面の簡単な説明】
第１図は、金属間接触熱伝達化の測定方法の説明図であ
る。 １・・・試料　　　　　　　２・・・低温材３・・・高
温材　　　　　　４・・・断熱剤５・・・熱電対 第１

Claims (1)

  1. 【特許請求の範囲】 １、基油に、断熱剤を加えた鋼の熱間圧延潤滑剤組成物
    において、断熱剤として（Ａ）１２００℃以下の温度で
    吸熱融解する無機化合物および（Ｂ）１２００℃以下の
    温度では融解または分解せず、かつ室温での熱伝導率が
    ０．０１（ｃａｌ／ｃｍ・Ｓ・℃）以下で摩擦係数が０
    ．７以下である無機粉体を用いたことを特徴とする鋼の
    熱間圧延潤滑剤組成物。 ２、基油に、請求項１記載の断熱剤ＡおよびＢを加え、
    更に極圧添加剤および／または固体潤滑剤を加えたこと
    を特徴とする請求項１記載の鋼の熱間圧延潤滑剤組成物
    。 ３、基グリースに断熱剤を加えた鋼の熱間圧延潤滑剤組
    成物において、断熱剤として（Ａ）１２００℃以下の温
    度で吸熱融解する無機化合物および／または（Ｂ）１２
    ００℃以下の温度では融解または分解せず、かつ室温で
    の熱伝導率が０．０１（ｃａｌ／ｃｍ・Ｓ・℃）以下で
    摩擦係数が０．７以下である無機粉体を用いたことを特
    徴とする鋼の熱間圧延潤滑剤組成物。 ４、基グリースに請求項３記載の断熱剤Ａおよび／また
    はＢを加え、更に極圧添加剤および／または固体潤滑剤
    を加えたことを特徴とする請求項３記載の鋼の熱間圧延
    潤滑剤組成物。 ５、断熱剤の添加量が５〜５０重量％であることを特徴
    とする請求項１または請求項３記載の鋼の熱間圧延潤滑
    剤組成物。
JP1134323A 1988-06-14 1989-05-26 鋼の熱間圧延潤滑剤組成物 Expired - Lifetime JPH0813980B2 (ja)

Priority Applications (7)

Application Number Priority Date Filing Date Title
EP89907268A EP0453565B1 (en) 1988-06-14 1989-06-13 Lubricant composition for hot-rolling of steel
DE68924075T DE68924075T2 (de) 1988-06-14 1989-06-13 Schmiermittelzubereitung für heizwalzen von stahl.
AU38334/89A AU625675B2 (en) 1988-06-14 1989-06-13 Lubricant composition for hot-rolling of steel
PCT/JP1989/000591 WO1989012669A1 (fr) 1988-06-14 1989-06-13 Compose lubrifiant pour le laminage a chaud de l'acier
KR1019900700275A KR920005534B1 (ko) 1988-06-14 1989-06-13 강의 열간압연 윤활제 조성물
CA002002036A CA2002036A1 (en) 1989-05-26 1989-11-01 Lubricating composition for hot-rolling steel
US08/266,784 US5437802A (en) 1988-06-14 1994-06-28 Lubricating composition for hot-rolling steel

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP14458888 1988-06-14
JP63-144588 1988-06-14

Publications (2)

Publication Number Publication Date
JPH0284492A true JPH0284492A (ja) 1990-03-26
JPH0813980B2 JPH0813980B2 (ja) 1996-02-14

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Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7767631B2 (en) * 1995-06-07 2010-08-03 Lee County Mosquito Control District Lubricant compositions and methods
ES2198490T3 (es) * 1995-06-07 2004-02-01 Lee County Mosquito Control District Composiciones lubricantes y metodos.
US20020198114A1 (en) * 1995-06-07 2002-12-26 Lee County Mosquito Control District Lubricant compositions and methods
EP0829528B1 (de) * 1996-09-17 2003-06-18 Chemische Fabrik Budenheim KG Graphitfreier Dornstangenschmierstoff
JP2911113B2 (ja) * 1997-06-02 1999-06-23 工業技術院長 高性能潤滑油
US6589918B2 (en) 2000-06-22 2003-07-08 Nsk Ltd. Conductive grease and rolling apparatus packed with the same
WO2004018594A1 (ja) * 2002-08-21 2004-03-04 Citizen Watch Co., Ltd. 精密機器用グリース組成物およびこれを用いた時計
WO2004046285A1 (ja) * 2002-11-21 2004-06-03 Oiles Corporation 固体潤滑剤および摺動部材
US20050049350A1 (en) * 2003-08-25 2005-03-03 Sandeep Tonapi Thin bond-line silicone adhesive composition and method for preparing the same
KR100679242B1 (ko) * 2005-04-22 2007-02-05 한국마그네슘기술연구조합 마그네슘합금 압출용 윤활제 및 그 제조방법
CN101218331B (zh) * 2005-04-26 2013-04-24 可再生润滑油有限公司 含氮化硼的高温生物润滑剂组合物
CN100389184C (zh) * 2005-08-31 2008-05-21 中国石油化工股份有限公司 含有机硅抗磨防滑剂的热轧油组合物
CN100395322C (zh) * 2005-08-31 2008-06-18 中国石油化工股份有限公司 含纳米抗磨剂的热轧油组合物
DE102005042020A1 (de) * 2005-09-02 2007-03-08 Sms Demag Ag Verfahren zum Schmieren und Kühlen von Walzen und Metallband beim Walzen, insbesondere beim Kaltwalzen, von Metallbändern
KR100721602B1 (ko) 2006-08-30 2007-05-23 주식회사 한국하우톤 바이오디젤 생산시 생성되는 증류 잔유물을 이용한 수용성절삭유 조성물
US8283296B2 (en) * 2006-10-11 2012-10-09 Henkel Ag & Co., Kgaa Lubricant for hot forging applications
SG154349A1 (en) * 2008-01-11 2009-08-28 Cheng Kit Yew Composition and process of manufacturing of biodiesel grease by gelling biodiesel, anti-wear additives, extreme pressure additives, water repellent additives and anti-oxidant additives.
US7998572B2 (en) * 2008-08-12 2011-08-16 Caterpillar Inc. Self-lubricating coatings
US20130196887A1 (en) * 2011-08-04 2013-08-01 Greengold Lubricants Llc Lubricant composition and methods of manufacture thereof
KR102008879B1 (ko) * 2018-09-12 2019-08-08 (주)케미우스코리아 콘크리트 압송배관의 윤활층 활성화 조성물

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4932861A (ja) * 1972-07-19 1974-03-26
JPS51147448A (en) * 1975-06-12 1976-12-17 Nippon Kokuen Kogyo Kk Method and device for lubricating roll in rolling mill
JPS5981394A (ja) * 1982-10-30 1984-05-11 Kobe Steel Ltd 金属のプレス加工用潤滑剤
JPS61223096A (ja) * 1985-03-28 1986-10-03 Sumitomo Metal Ind Ltd 鋼材の熱間加工用潤滑剤

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2176879A (en) * 1937-11-20 1939-10-24 Acheson Colloids Corp Method of disintegrating, dispersing and stabilizing graphite and product
US3801503A (en) * 1970-07-24 1974-04-02 Chevron Res Pneumatic tool lubricant
US3931020A (en) * 1974-08-22 1976-01-06 Gulf & Western Industries, Inc. Smokeless forging lubricant
US4039337A (en) * 1974-10-23 1977-08-02 Ball Brothers Research Corporation Release coating for glass manufacture
JPS52101363A (en) * 1977-01-27 1977-08-25 Origin Electric Coatng for lubricating
US4107058A (en) * 1977-08-19 1978-08-15 Exxon Research & Engineering Co. Pressure grease composition
US4155859A (en) * 1978-01-19 1979-05-22 The Lubrizol Corporation Forging lubricants and method of use thereof
DE2850244A1 (de) * 1978-11-20 1980-05-29 Hoechst Ag Additiv fuer die metallbearbeitung
JPS581796A (ja) * 1981-06-25 1983-01-07 Kobe Steel Ltd 熱間圧延用潤滑剤
JPS606211A (ja) * 1983-06-27 1985-01-12 Nippon Steel Corp ロ−ルの保護方法
US4612127A (en) * 1983-09-28 1986-09-16 Hitachi, Ltd. Lubricant for metal forming and process for metal forming
CH670106A5 (ja) * 1984-07-23 1989-05-12 Lonza Ag
US4715972A (en) * 1986-04-16 1987-12-29 Pacholke Paula J Solid lubricant additive for gear oils
US4758358A (en) * 1987-06-08 1988-07-19 Van Straaten Corporation Environmentally acceptable forging lubricants

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4932861A (ja) * 1972-07-19 1974-03-26
JPS51147448A (en) * 1975-06-12 1976-12-17 Nippon Kokuen Kogyo Kk Method and device for lubricating roll in rolling mill
JPS5981394A (ja) * 1982-10-30 1984-05-11 Kobe Steel Ltd 金属のプレス加工用潤滑剤
JPS61223096A (ja) * 1985-03-28 1986-10-03 Sumitomo Metal Ind Ltd 鋼材の熱間加工用潤滑剤

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KR900701979A (ko) 1990-12-05
KR920005534B1 (ko) 1992-07-06
US5437802A (en) 1995-08-01

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