JPH0284768A - Manufacture of solid-state image sensing element - Google Patents

Manufacture of solid-state image sensing element

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Publication number
JPH0284768A
JPH0284768A JP63237707A JP23770788A JPH0284768A JP H0284768 A JPH0284768 A JP H0284768A JP 63237707 A JP63237707 A JP 63237707A JP 23770788 A JP23770788 A JP 23770788A JP H0284768 A JPH0284768 A JP H0284768A
Authority
JP
Japan
Prior art keywords
film
silicon
gate insulating
insulating film
charge transfer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP63237707A
Other languages
Japanese (ja)
Other versions
JP3036747B2 (en
Inventor
Yasutaka Nakashiba
康隆 中柴
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Corp
Original Assignee
NEC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Corp filed Critical NEC Corp
Priority to JP63237707A priority Critical patent/JP3036747B2/en
Publication of JPH0284768A publication Critical patent/JPH0284768A/en
Application granted granted Critical
Publication of JP3036747B2 publication Critical patent/JP3036747B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Solid State Image Pick-Up Elements (AREA)

Abstract

PURPOSE:To make it possible to prevent phosphorus subjected to out diffusion through a first poly silicon film and the rear of a p-type semiconductor substrate from adhering on the surface of the substrate at the time of formation of a second gate insulating film by a method wherein the second gate insulating film is formed by oxidizing thermally a silicon insulator film formed by a plasma CVD method. CONSTITUTION:In case a solid-state image sensing element having a photoelectric conversion part of a second conductivity type region (an n-type layer) 6, a first gate insulating film 8, a first poly silicon electrode (a first poly silicon film) 11, a second gate insulating film 9, a second poly silicon electrode (a second poly silicon film) 12, a charge transfer part consisting of the region 6, a transfer gate to perform a charge transfer from the above photoelectric conversion part to the above charge transfer part and a high-concentration first conductivity type channel stop region to electrically isolate each above region, which are provided on one main surface of a first conductivity type (p-type) semiconductor substrate 1, is manufactured, the above film 9 is formed by oxidizing thermally a silicon insulator film formed by a plasma CVD method. For example, the above silicon insulator film is formed of a silicon oxide film or a silicon nitride film.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は固体撮像素子の製造方法に関し、特に2層多結
晶シリコン構造を有する電荷結合素子(COD)の製造
方法に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a method for manufacturing a solid-state imaging device, and particularly to a method for manufacturing a charge-coupled device (COD) having a two-layer polycrystalline silicon structure.

〔従来の技術〕[Conventional technology]

従来、この種の2層多結晶シリコン電極構造の電荷結合
素子を用いた固体撮像素子は、第3図に平面図、第4図
(a)に第3図のI−1層面の断面図、第4図(b)に
第3図のn−n’面の断面図を示した様に、P型半導体
基板1にP−N接合により形成した複数個の光電変換部
2と、信号電荷を転送するN型領域6、ゲート絶縁膜1
0及び2層の多結晶シリコン膜11.12から成る電荷
転送部3と、光電変換部2から電荷転送部3へ信号電荷
を読み出すトランスファゲート部4と隣接した光電変換
部2及び電荷転送部3を電気的に分離するチャンネルス
トップ5とを有していた。
Conventionally, a solid-state imaging device using a charge-coupled device with a two-layer polycrystalline silicon electrode structure of this type has a plan view shown in FIG. 3, a cross-sectional view of the I-1 layer plane in FIG. As shown in FIG. 4(b), which is a cross-sectional view taken along the n-n' plane in FIG. N-type region 6 to be transferred, gate insulating film 1
The photoelectric conversion section 2 and the charge transfer section 3 are adjacent to a transfer gate section 4 that reads signal charges from the photoelectric conversion section 2 to the charge transfer section 3. It had a channel stop 5 for electrically isolating the.

第5図は従来の固体撮像素子の主な製造工程における電
荷転送部の断面図の一例である。P型半導体基板1内に
選択的に光電変換部2と、電荷転送部3の埋込チャンネ
ルとなるN型層6及びチャンネルストップ5となる高濃
度のP型層7を形成した後P型半導体基板1を酸化して
第1のゲート絶縁膜8を形成し、第1の多結晶シリコン
膜11を堆積させ、第1の多結晶シリコン膜の比抵抗を
下げる為及びP型半導体基板lの裏面に高濃度のりんを
入れて結晶欠陥を裏面に意図的に発生させゲッタリング
を行う為に前記第1の多結晶シリコン膜11にリンを拡
散する(第5図(a))。
FIG. 5 is an example of a cross-sectional view of a charge transfer section in the main manufacturing process of a conventional solid-state image sensor. After selectively forming a photoelectric conversion part 2 in a P-type semiconductor substrate 1, an N-type layer 6 which becomes a buried channel of a charge transfer part 3, and a high concentration P-type layer 7 which becomes a channel stop 5, a P-type semiconductor is formed. A first gate insulating film 8 is formed by oxidizing the substrate 1, and a first polycrystalline silicon film 11 is deposited to lower the resistivity of the first polycrystalline silicon film and to reduce the resistivity of the first polycrystalline silicon film and to form a first gate insulating film 8 on the back surface of the P-type semiconductor substrate l. A high concentration of phosphorus is introduced into the first polycrystalline silicon film 11 to intentionally generate crystal defects on the back surface and to perform gettering, phosphorus is diffused into the first polycrystalline silicon film 11 (FIG. 5(a)).

次に写真食刻法及びプラズマエツチング法により第1の
多結晶シリコン膜をパターニングし、前記第1のゲート
絶縁膜8をフッ酸系エツチング液にて基板表面までエツ
チングする(第5図(b))。
Next, the first polycrystalline silicon film is patterned by photolithography and plasma etching, and the first gate insulating film 8 is etched down to the substrate surface using a hydrofluoric acid etching solution (FIG. 5(b)). ).

第2の絶縁膜9をP型半導体基板1及び第1の多結晶シ
リコン膜11を酸化することにより形成する(第5図(
C))。第2の多結晶シリコン膜12を堆積させ、上述
した第1の多結晶シリコン膜11の場合と同様にして、
写真食刻法及びプラズマエツチング法によりパターニン
グして形成する(第5図(d))。しかる後、層間酸化
硅素膜15を常圧CVD法にて形成し、アルミニウム配
線16及び保護酸化硅素膜17を施して第3図、第4図
の固体撮像素子を得る。
A second insulating film 9 is formed by oxidizing the P-type semiconductor substrate 1 and the first polycrystalline silicon film 11 (see FIG.
C)). A second polycrystalline silicon film 12 is deposited in the same manner as in the case of the first polycrystalline silicon film 11 described above.
It is formed by patterning by photolithography and plasma etching (FIG. 5(d)). Thereafter, an interlayer silicon oxide film 15 is formed by atmospheric pressure CVD, and aluminum wiring 16 and a protective silicon oxide film 17 are applied to obtain the solid-state imaging device shown in FIGS. 3 and 4.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

上述した従来の固体撮像素子は第1の多結晶シリコン膜
11をパターニングし第1のゲート絶縁膜8をP型半導
体基板1表面までエツチングした後、P型半導体基板1
及び第1の多結晶シリコン膜11を熱酸化し、第2のゲ
ート絶縁膜9を形成しているため、第2のゲート絶縁膜
9形成時に第1の多結晶シリコン膜11及びP型半導体
基板1の裏面から飛び出した(アウトデイフュージョン
)りんが、基板表面の光電変換部2或は電荷転送部3の
N型層6に付着し、局部的にN+層を形成する為、光電
変換部2に付着した場合には再生画面上点欠陥を生じ、
電荷転送部3のN型層6に付着した場合には、付着した
地点の濃度は他の地点より濃いN+層を形成する為その
点の表面電位は、深くなり転送されて来た電荷はその地
点で一部トラップされる形となり、電荷の転送損失をも
たらすという欠点があった。
The above-described conventional solid-state image sensor is constructed by patterning the first polycrystalline silicon film 11 and etching the first gate insulating film 8 down to the surface of the P-type semiconductor substrate 1.
Since the second gate insulating film 9 is formed by thermally oxidizing the first polycrystalline silicon film 11, the first polycrystalline silicon film 11 and the P-type semiconductor substrate are removed when the second gate insulating film 9 is formed. Phosphorus ejected from the back surface of the substrate (out-diffusion) adheres to the N-type layer 6 of the photoelectric conversion section 2 or charge transfer section 3 on the surface of the substrate, forming an N+ layer locally. If it adheres to the screen, it will cause defects on the top of the playback screen.
When it adheres to the N-type layer 6 of the charge transfer section 3, the concentration at the point where it adheres forms an N+ layer that is higher than other points, so the surface potential at that point becomes deeper and the transferred charges are This has the disadvantage that it becomes partially trapped at certain points, resulting in charge transfer loss.

〔課題を解決するための手段〕[Means to solve the problem]

本発明の固体撮像素子の製造方法は、第1の導電型の半
導体基板の一主面にそれぞれ設けられた第2導電型領域
の光電変換部と、第1のゲート絶縁膜と第1の多結晶シ
リコン電極とプラズマCvD法で形成した酸化硅素膜或
は窒化硅素膜を熱酸化した第2のゲート絶縁膜と、第2
の多結晶シリコン電極及び第2導電型領域から成る電荷
転送部と、前記光電変換部から前記電荷転送部への電荷
転送を行うトランスファゲートと前記各領域を電気的に
分離する高濃度の第1導電型のチャンネルストップ領域
を有した固体撮像素子の製造方法で、第1の多結晶シリ
コン膜をパターニングし第1のゲート絶縁膜をP型半導
体基板表面までエツチングした後プラズマCVD法によ
り酸化硅素膜或は窒化硅素膜を堆積し、熱酸化を行った
第2のゲート絶縁膜を形成することにより、熱工程にお
いて第1の多結晶シリコン膜及びP型半導体基板の裏面
からアウトデイフュージョンしたりんが前記P型半導体
表面に付着することを防ぐことが出きる。
A method for manufacturing a solid-state image sensor according to the present invention includes a photoelectric conversion section of a second conductivity type region provided on one main surface of a semiconductor substrate of a first conductivity type, a first gate insulating film, and a first multilayer film. a crystalline silicon electrode, a second gate insulating film formed by thermally oxidizing a silicon oxide film or a silicon nitride film formed by a plasma CVD method;
a charge transfer section consisting of a polycrystalline silicon electrode and a second conductivity type region, a transfer gate for transferring charge from the photoelectric conversion section to the charge transfer section, and a highly concentrated first conductivity type region for electrically separating the respective regions. In a method of manufacturing a solid-state image sensor having a conductivity type channel stop region, a first polycrystalline silicon film is patterned, a first gate insulating film is etched to the surface of a P-type semiconductor substrate, and then a silicon oxide film is formed by a plasma CVD method. Alternatively, by forming a second gate insulating film by depositing a silicon nitride film and performing thermal oxidation, phosphorus out-diffused from the back surface of the first polycrystalline silicon film and the P-type semiconductor substrate during the thermal process can be removed. Adhesion to the surface of the P-type semiconductor can be prevented.

〔実施例〕〔Example〕

次に、本発明について図面を参照して説明する。 Next, the present invention will be explained with reference to the drawings.

第1図は本発明の一実施例の主な製造工程における電荷
転送部の断面図である。
FIG. 1 is a sectional view of a charge transfer section in the main manufacturing process of an embodiment of the present invention.

P型半導体基板1内に選択的に光電変換部2と電荷転送
部3の埋込チャンネルとなるN型層6及びチャンネルス
トップ5となる高濃度のP型層7を形成した後P型半導
体基板1を酸化して第1のゲート絶縁膜8を形成し、第
1の多結晶シリコン膜11を堆積させ、第1の多結晶シ
リコン11の比抵抗を下げる為及びP型半導体基板1の
裏面に高濃度のりんを入れて結晶欠陥を裏面に意図的に
発生させゲッタリングを行う為に前記第1の多結晶シリ
コン膜11にりんを拡散する(第1図(a))。
After selectively forming in the P-type semiconductor substrate 1 an N-type layer 6 that will become a buried channel for the photoelectric conversion section 2 and the charge transfer section 3 and a high concentration P-type layer 7 that will become a channel stop 5, the P-type semiconductor substrate 1 is oxidized to form a first gate insulating film 8, and a first polycrystalline silicon film 11 is deposited to lower the specific resistance of the first polycrystalline silicon 11 and on the back surface of the P-type semiconductor substrate 1. Phosphorus is diffused into the first polycrystalline silicon film 11 in order to intentionally generate crystal defects on the back surface and perform gettering by introducing a high concentration of phosphorus (FIG. 1(a)).

次に写真食刻法及びプラズマエツチング法により、第1
の多結晶シリコン膜11をパターニングし前記第1のゲ
ート絶縁膜8をフッ酸系エツチング液にて基板表面まで
エツチングする(第1図(b))。
Next, by photolithography and plasma etching, the first
The polycrystalline silicon film 11 is patterned, and the first gate insulating film 8 is etched to the substrate surface using a hydrofluoric acid etching solution (FIG. 1(b)).

プラズマCVD法を用いて酸化硅素膜13を約10nm
から50nm堆積させる(第1 (c)図)。
Silicon oxide film 13 is approximately 10 nm thick using plasma CVD method.
(FIG. 1(c)).

プラズマCVD法にて堆積させた酸化硅素膜13に熱酸
化を施し第2のゲート絶縁膜9を形成する(第1図(d
))。
The silicon oxide film 13 deposited by plasma CVD is thermally oxidized to form a second gate insulating film 9 (see FIG. 1(d)).
)).

第2の多結晶シリコン膜12を堆積させ上述した第1の
多結晶シリコン膜11の場合と同様にして写真食刻法及
びプラズマエツチング法によりパターニングする(第1
図(e))。
A second polycrystalline silicon film 12 is deposited and patterned by photolithography and plasma etching in the same manner as in the case of the first polycrystalline silicon film 11 described above.
Figure (e)).

しかる後、層間酸化膜層を常圧CVD法にて形成しアル
ミニウム配線及び保護酸化膜を施して固体撮像素子を得
る。
Thereafter, an interlayer oxide film layer is formed by atmospheric pressure CVD, and aluminum wiring and a protective oxide film are applied to obtain a solid-state image sensor.

第2図は本発明の他の実施例の主な製造工程における電
荷転送部の断面図である。
FIG. 2 is a sectional view of a charge transfer section in the main manufacturing process of another embodiment of the present invention.

第2図(C)においてプラズマCVD法において窒化硅
素膜14を約10nmから30nm堆積させている以外
は第1図に示した実施例と同一である。
The embodiment is the same as the embodiment shown in FIG. 1, except that in FIG. 2(C), a silicon nitride film 14 is deposited to a thickness of approximately 10 nm to 30 nm using the plasma CVD method.

第2図(e)において第2の多結晶シリコン膜12のパ
ターニング終了後、層間酸化膜層を常圧CVD法にて形
成し、アルミニウム配線及び保護酸化膜を施して固体撮
像素子を得る。
In FIG. 2(e), after patterning the second polycrystalline silicon film 12, an interlayer oxide film layer is formed by atmospheric pressure CVD, and aluminum wiring and a protective oxide film are applied to obtain a solid-state image sensor.

〔発明の効果〕〔Effect of the invention〕

以上説明した様に、本発明によれば固体撮像素子の製造
工程において、第2のゲート絶縁膜をプラズマCVD法
で形成した酸化硅素膜或は窒化硅素膜を熱酸化し、形成
することにより、第2のゲート絶縁膜形成時に第1の多
結晶シリコン膜及びP型半導体基板の裏面からアウトデ
イフュージョンしたりんが基板表面の光電変換部或は電
荷転送部のN型層に付着し、局部的なN+層を形成する
のを抑制することが出来、テレビジョンカメラシステム
として使用した場合前記局部的なN+層に起因する再生
画面上の点欠陥及び電荷の転送損傷による棒状欠陥を抑
制することが出来るという効果がある。
As explained above, according to the present invention, in the manufacturing process of a solid-state image sensor, the second gate insulating film is formed by thermally oxidizing a silicon oxide film or a silicon nitride film formed by a plasma CVD method. During the formation of the second gate insulating film, phosphorus outdiffused from the first polycrystalline silicon film and the back surface of the P-type semiconductor substrate adheres to the N-type layer of the photoelectric conversion section or charge transfer section on the substrate surface, causing local damage. When used as a television camera system, point defects on the playback screen caused by the localized N+ layer and rod-like defects due to charge transfer damage can be suppressed. There is an effect that it can be done.

【図面の簡単な説明】[Brief explanation of the drawing]

(e)は本発明の他の実施例の主な製造工程における電
荷転送部の断面図である。 第3図は従来技術の一例である2層多結晶シリコン電極
構造の電荷結合素子を用いた固体撮像素子の平面図、第
4図(a)は第3図I−1’面の断面図、第4図(b)
は第3図n−n’面の断面図、第5図は従来の固体撮像
素子の主な製造工程における電荷転送部の断面図である
。 1・・・・・・P型半導体基板、2・・・・・・光電変
換部、3・・・・・・電荷転送部、4・・・・・・トラ
ンスファゲート部、5・・・・・・チャンネルストップ
、6・・・・・・N型層、7・・・・・・P型層、8・
・・・・・第1のゲート絶縁膜、9・・・・・・第2ゲ
ート絶縁膜、10・・・・・・ゲート絶縁膜、11・・
・・・・第1の多結晶シリコン膜、12・・・・・・第
2の多結晶シリコン膜、13・・・・・・プラズマCV
D酸化硅素膜、14・・・・・・プラズマCVD窒化硅
素膜、15・・・・・・常圧CVD層間酸化硅素膜、1
6・・・・・・アルミニウム配線、17・・・・・・保
護酸化硅素膜。 代理人 弁理士  内 原   晋 窟1図(し) 肩1図(の 第1回(め 77M1め9′米吉晶シリ]〕万吟 7扁z図((L) // 第1圓(脚 りrデ2−Lン■to4ノ 片3図 /2.j152f)zダt4h閣iシリL15に!し冒
刀(C) ′!J4図r幻 菊4図Cらジ 第5図(71) 筋5図(#)) 刻5回(d)
(e) is a cross-sectional view of the charge transfer section in the main manufacturing process of another embodiment of the present invention. FIG. 3 is a plan view of a solid-state imaging device using a charge-coupled device with a two-layer polycrystalline silicon electrode structure, which is an example of the conventional technology, and FIG. 4(a) is a cross-sectional view taken along plane I-1' in FIG. Figure 4(b)
3 is a cross-sectional view taken along line nn' in FIG. 3, and FIG. 5 is a cross-sectional view of a charge transfer section in the main manufacturing process of a conventional solid-state image sensor. DESCRIPTION OF SYMBOLS 1... P-type semiconductor substrate, 2... Photoelectric conversion section, 3... Charge transfer section, 4... Transfer gate section, 5... ...Channel stop, 6...N type layer, 7...P type layer, 8...
...First gate insulating film, 9... Second gate insulating film, 10... Gate insulating film, 11...
...First polycrystalline silicon film, 12... Second polycrystalline silicon film, 13... Plasma CV
D silicon oxide film, 14... plasma CVD silicon nitride film, 15... normal pressure CVD interlayer silicon oxide film, 1
6... Aluminum wiring, 17... Protective silicon oxide film. Agent Patent Attorney Shinku Uchihara 1st drawing (shi) Shoulder 1st drawing (1st (Me77M1me9' Akira Yoneyoshi)) Mangin 7th z drawing ((L) // 1st round (legs) r de 2-L n ■to4 no piece 3 figure/2.j152f) z da t4h cabinet i Shiri L15!Shi Sword (C) '!J4 figure r Genkiku 4 figure C raji figure 5 (71) 5 lines (#)) 5 times (d)

Claims (1)

【特許請求の範囲】 1、第1導電型の半導体基板の一主面にそれぞれ設けら
れた第2導電型領域の光電変換部と、第1のゲート絶縁
膜と第1の多結晶シリコン電極と第2のゲート絶縁膜と
第2の多結晶シリコン電極及び第2導電型領域から成る
電荷転送部と、前記光電変換部から前記電荷転送部への
電荷転送を行うトランスファゲートと、前記各領域を電
気的に分離する高濃度の第1導電型のチャンネルストッ
プ領域とを有する固体撮像素子の製造方法において、前
記第2のゲート絶縁膜がプラズマCVD法で形成した硅
素の絶縁物膜を熱酸化して形成されることを特徴とする
固体撮像素子の製造方法 2、前記硅素の絶縁物膜は酸化硅素膜である請求項1記
載の固体撮像素子の製造方法 3、前記硅素の絶縁物膜は窒化硅素膜である請求項1記
載の固体撮像素子の製造方法
[Claims] 1. A photoelectric conversion section of a second conductivity type region provided on one main surface of a semiconductor substrate of a first conductivity type, a first gate insulating film, and a first polycrystalline silicon electrode. a charge transfer section including a second gate insulating film, a second polycrystalline silicon electrode, and a second conductivity type region; a transfer gate that transfers charge from the photoelectric conversion section to the charge transfer section; In the method for manufacturing a solid-state imaging device having a highly concentrated first conductivity type channel stop region that is electrically isolated, the second gate insulating film is formed by thermally oxidizing a silicon insulating film formed by a plasma CVD method. 2. A method 3 for manufacturing a solid-state image sensor according to claim 1, wherein the silicon insulator film is a silicon oxide film. The silicon insulator film is a nitride film. The method for manufacturing a solid-state imaging device according to claim 1, which is a silicon film.
JP63237707A 1988-09-21 1988-09-21 Method for manufacturing solid-state imaging device Expired - Lifetime JP3036747B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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KR100269549B1 (en) * 1996-04-19 2000-10-16 가네꼬 히사시 Two phase clock type charge coupled device having electrodes with side walls and method for producing the same
CN103400847A (en) * 2013-08-14 2013-11-20 中国电子科技集团公司第四十四研究所 Technology for manufacturing CCD secondary or more than secondary polycrystalline silicon
CN109256441A (en) * 2018-09-20 2019-01-22 北方电子研究院安徽有限公司 A kind of EMCCD device mul-tiple layers of polysilicon grid structure production method

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JPS5448484A (en) * 1977-08-30 1979-04-17 Toshiba Corp Forming method of insulation film
JPS5851673A (en) * 1981-09-22 1983-03-26 Sharp Corp solid state imaging device
JPS60263437A (en) * 1984-06-12 1985-12-26 Ise Electronics Corp Manufacturing method of thin film transistor
JPS61156885A (en) * 1984-12-28 1986-07-16 Fujitsu Ltd Polycrystalline semiconductor device and manufacture thereof
JPS61214463A (en) * 1985-03-19 1986-09-24 Nec Corp Solid-state imaging device and its driving method

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JPS5448484A (en) * 1977-08-30 1979-04-17 Toshiba Corp Forming method of insulation film
JPS5851673A (en) * 1981-09-22 1983-03-26 Sharp Corp solid state imaging device
JPS60263437A (en) * 1984-06-12 1985-12-26 Ise Electronics Corp Manufacturing method of thin film transistor
JPS61156885A (en) * 1984-12-28 1986-07-16 Fujitsu Ltd Polycrystalline semiconductor device and manufacture thereof
JPS61214463A (en) * 1985-03-19 1986-09-24 Nec Corp Solid-state imaging device and its driving method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100269549B1 (en) * 1996-04-19 2000-10-16 가네꼬 히사시 Two phase clock type charge coupled device having electrodes with side walls and method for producing the same
CN103400847A (en) * 2013-08-14 2013-11-20 中国电子科技集团公司第四十四研究所 Technology for manufacturing CCD secondary or more than secondary polycrystalline silicon
CN109256441A (en) * 2018-09-20 2019-01-22 北方电子研究院安徽有限公司 A kind of EMCCD device mul-tiple layers of polysilicon grid structure production method

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