JPH0319304B2 - - Google Patents

Info

Publication number: JPH0319304B2
Authority: JP; Japan
Prior art keywords: exchange membrane; group; fluorine; ion exchange; carboxylic acid
Prior art date: 1982-06-01
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

JP57092120A

Other languages

English (en)

Japanese (ja)

Other versions

JPS58210178A (ja

Inventor

Yoshio Oda

Takeshi Morimoto

Masaru Yoshitake

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

National Institute of Advanced Industrial Science and Technology AIST

Original Assignee

Agency of Industrial Science and Technology

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-06-01

Filing date

1982-06-01

Publication date

1991-03-14

1982-06-01 Application filed by Agency of Industrial Science and Technology filed Critical Agency of Industrial Science and Technology

1982-06-01 Priority to JP57092120A priority Critical patent/JPS58210178A/ja

1983-12-07 Publication of JPS58210178A publication Critical patent/JPS58210178A/ja

1991-03-14 Publication of JPH0319304B2 publication Critical patent/JPH0319304B2/ja

Status Granted legal-status Critical Current

Links

239000012528 membrane Substances 0.000 claims description 21
238000005868 electrolysis reaction Methods 0.000 claims description 19
229910052731 fluorine Inorganic materials 0.000 claims description 16
239000011737 fluorine Substances 0.000 claims description 16
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 15
125000002843 carboxylic acid group Chemical group 0.000 claims description 13
238000005341 cation exchange Methods 0.000 claims description 13
239000001257 hydrogen Substances 0.000 claims description 11
229910052739 hydrogen Inorganic materials 0.000 claims description 11
239000003518 caustics Substances 0.000 claims description 6
238000004519 manufacturing process Methods 0.000 claims description 6
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
229910052700 potassium Inorganic materials 0.000 claims description 5
239000011591 potassium Substances 0.000 claims description 5
239000011347 resin Substances 0.000 claims description 5
229920005989 resin Polymers 0.000 claims description 5
239000007864 aqueous solution Substances 0.000 claims description 4
125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
238000000034 method Methods 0.000 description 23
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 18
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
239000000178 monomer Substances 0.000 description 13
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 12
229920001577 copolymer Polymers 0.000 description 12
239000003014 ion exchange membrane Substances 0.000 description 11
239000000463 material Substances 0.000 description 10
229920000642 polymer Polymers 0.000 description 10
-1 platinum group metals Chemical class 0.000 description 9
229910052751 metal Inorganic materials 0.000 description 7
239000002184 metal Substances 0.000 description 7
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 7
239000000243 solution Substances 0.000 description 7
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000003792 electrolyte Substances 0.000 description 6
125000000524 functional group Chemical group 0.000 description 6
238000005342 ion exchange Methods 0.000 description 6
235000011118 potassium hydroxide Nutrition 0.000 description 6
125000000542 sulfonic acid group Chemical group 0.000 description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
238000000465 moulding Methods 0.000 description 5
229910052759 nickel Inorganic materials 0.000 description 5
230000035699 permeability Effects 0.000 description 5
229920001343 polytetrafluoroethylene Polymers 0.000 description 5
239000004810 polytetrafluoroethylene Substances 0.000 description 5
239000011148 porous material Substances 0.000 description 5
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
239000007868 Raney catalyst Substances 0.000 description 4
229910000564 Raney nickel Inorganic materials 0.000 description 4
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 4
239000002253 acid Substances 0.000 description 4
229910045601 alloy Inorganic materials 0.000 description 4
239000000956 alloy Substances 0.000 description 4
125000004432 carbon atom Chemical group C* 0.000 description 4
239000002245 particle Substances 0.000 description 4
239000000843 powder Substances 0.000 description 4
229910001220 stainless steel Inorganic materials 0.000 description 4
239000010935 stainless steel Substances 0.000 description 4
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 3
239000004063 acid-resistant material Substances 0.000 description 3
239000003513 alkali Substances 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
239000006185 dispersion Substances 0.000 description 3
229910002804 graphite Inorganic materials 0.000 description 3
239000010439 graphite Substances 0.000 description 3
229910052742 iron Inorganic materials 0.000 description 3
150000002739 metals Chemical class 0.000 description 3
239000000203 mixture Substances 0.000 description 3
229910000510 noble metal Inorganic materials 0.000 description 3
229910052697 platinum Inorganic materials 0.000 description 3
238000006116 polymerization reaction Methods 0.000 description 3
229910052707 ruthenium Inorganic materials 0.000 description 3
239000000725 suspension Substances 0.000 description 3
BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 3
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
150000001732 carboxylic acid derivatives Chemical group 0.000 description 2
230000000052 comparative effect Effects 0.000 description 2
229910001882 dioxygen Inorganic materials 0.000 description 2
239000007772 electrode material Substances 0.000 description 2
239000004744 fabric Substances 0.000 description 2
239000011888 foil Substances 0.000 description 2
230000007062 hydrolysis Effects 0.000 description 2
238000006460 hydrolysis reaction Methods 0.000 description 2
229910052741 iridium Inorganic materials 0.000 description 2
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
229920000609 methyl cellulose Polymers 0.000 description 2
239000001923 methylcellulose Substances 0.000 description 2
238000002156 mixing Methods 0.000 description 2
238000006386 neutralization reaction Methods 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
229910052763 palladium Inorganic materials 0.000 description 2
125000005010 perfluoroalkyl group Chemical group 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
235000011121 sodium hydroxide Nutrition 0.000 description 2
229920002554 vinyl polymer Polymers 0.000 description 2
SUTQSIHGGHVXFK-UHFFFAOYSA-N 1,2,2-trifluoroethenylbenzene Chemical compound FC(F)=C(F)C1=CC=CC=C1 SUTQSIHGGHVXFK-UHFFFAOYSA-N 0.000 description 1
CHRJZRDFSQHIFI-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;styrene Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1C=C CHRJZRDFSQHIFI-UHFFFAOYSA-N 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
239000010405 anode material Substances 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
238000005266 casting Methods 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
230000003197 catalytic effect Effects 0.000 description 1
239000000460 chlorine Chemical group 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 1
239000000571 coke Substances 0.000 description 1
239000011231 conductive filler Substances 0.000 description 1
238000007334 copolymerization reaction Methods 0.000 description 1
HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
230000007812 deficiency Effects 0.000 description 1
230000006866 deterioration Effects 0.000 description 1
238000010981 drying operation Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000008151 electrolyte solution Substances 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
125000001153 fluoro group Chemical group F* 0.000 description 1
239000007789 gas Substances 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
150000002431 hydrogen Chemical class 0.000 description 1
125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000007769 metal material Substances 0.000 description 1
239000004745 nonwoven fabric Substances 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
CFQCIHVMOFOCGH-UHFFFAOYSA-N platinum ruthenium Chemical compound [Ru].[Pt] CFQCIHVMOFOCGH-UHFFFAOYSA-N 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
239000010970 precious metal Substances 0.000 description 1
238000003825 pressing Methods 0.000 description 1
125000001453 quaternary ammonium group Chemical group 0.000 description 1
230000005855 radiation Effects 0.000 description 1
239000002994 raw material Substances 0.000 description 1
239000010948 rhodium Substances 0.000 description 1
229910052703 rhodium Inorganic materials 0.000 description 1
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000000758 substrate Substances 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1
238000012719 thermal polymerization Methods 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Landscapes

Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

JP57092120A 1982-06-01 1982-06-01 水素の製造方法 Granted JPS58210178A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP57092120A JPS58210178A (ja)	1982-06-01	1982-06-01	水素の製造方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP57092120A JPS58210178A (ja)	1982-06-01	1982-06-01	水素の製造方法

Publications (2)

Publication Number	Publication Date
JPS58210178A JPS58210178A (ja)	1983-12-07
JPH0319304B2 true JPH0319304B2 (de)	1991-03-14

Family

ID=14045569

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP57092120A Granted JPS58210178A (ja)	1982-06-01	1982-06-01	水素の製造方法

Country Status (1)

Country	Link
JP (1)	JPS58210178A (de)

1982
- 1982-06-01 JP JP57092120A patent/JPS58210178A/ja active Granted

Also Published As

Publication number	Publication date
JPS58210178A (ja)	1983-12-07

Publication	Publication Date	Title
US4319969A (en)	1982-03-16	Aqueous alkali metal chloride electrolytic cell
EP0029751B1 (de)	1985-02-20	Ionenaustauscher-Membranzelle und sie verwendendes elektrolytisches Verfahren
EP0100548A2 (de)	1984-02-15	Material für Gasdiffusionselektrode
EP0045603B2 (de)	1988-07-13	Ionenaustauschermembranzelle und deren Verwendung in elektrolytischen Verfahren
US4465570A (en)	1984-08-14	Process for producing hydrogen
JPH0116630B2 (de)	1989-03-27
JPS6059996B2 (ja)	1985-12-27	塩化アルカリの電解方法
JPS634918B2 (de)	1988-02-01
JPS621652B2 (de)	1987-01-14
JPS6317913B2 (de)	1988-04-15
JPH0319304B2 (de)	1991-03-14
JPS6341990B2 (de)	1988-08-19
JPS6125787B2 (de)	1986-06-17
JPS6120634B2 (de)	1986-05-23
JPS5940231B2 (ja)	1984-09-28	水酸化アルカリの製造方法
JPS6341989B2 (de)	1988-08-19
JPH0219848B2 (de)	1990-05-07
JPS623236B2 (de)	1987-01-23
JPS6221074B2 (de)	1987-05-11
JPS6223076B2 (de)	1987-05-21
EP0020940B1 (de)	1984-10-24	Verfahren zur Herstellung eines Alkalimetallhydroxids durch Elektrolyse einer wässerigen Lösung eines Alkalimetallchlorids
JPS6053756B2 (ja)	1985-11-27	イオン交換膜電解槽
JPS6214036B2 (de)	1987-03-31
JPS6343474B2 (de)	1988-08-30
JPH0377880B2 (de)	1991-12-11