JPH0332532B2 - - Google Patents

Info

Publication number: JPH0332532B2
Authority: JP; Japan
Prior art keywords: meth; methyl; acrylate; hydrazine; column
Prior art date: 1982-04-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP6507482A

Other languages

English (en)

Japanese (ja)

Other versions

JPS58183633A (ja

Inventor

Atsushi Aoshima

Yoshio Suzuki

Makoto Nyukai

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Asahi Chemical Industry Co Ltd

Original Assignee

Asahi Chemical Industry Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-04-19

Filing date

1982-04-19

Publication date

1991-05-13

1982-04-19 Application filed by Asahi Chemical Industry Co Ltd filed Critical Asahi Chemical Industry Co Ltd

1982-04-19 Priority to JP6507482A priority Critical patent/JPS58183633A/ja

1983-10-26 Publication of JPS58183633A publication Critical patent/JPS58183633A/ja

1991-05-13 Publication of JPH0332532B2 publication Critical patent/JPH0332532B2/ja

Status Granted legal-status Critical Current

Links

OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 50
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 claims description 38
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 29
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 28
239000012535 impurity Substances 0.000 claims description 18
238000000034 method Methods 0.000 claims description 13
239000002994 raw material Substances 0.000 claims description 11
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 9
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 6
238000004821 distillation Methods 0.000 description 27
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
150000001728 carbonyl compounds Chemical class 0.000 description 14
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 11
239000007788 liquid Substances 0.000 description 9
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 6
FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 6
DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 4
STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 description 4
238000009835 boiling Methods 0.000 description 4
NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 3
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
150000001299 aldehydes Chemical class 0.000 description 3
230000000694 effects Effects 0.000 description 3
IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 3
238000006116 polymerization reaction Methods 0.000 description 3
239000004471 Glycine Substances 0.000 description 2
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 2
239000002253 acid Substances 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
239000003112 inhibitor Substances 0.000 description 2
230000001590 oxidative effect Effects 0.000 description 2
238000000746 purification Methods 0.000 description 2
238000011084 recovery Methods 0.000 description 2
238000010992 reflux Methods 0.000 description 2
238000000926 separation method Methods 0.000 description 2
229940079827 sodium hydrogen sulfite Drugs 0.000 description 2
235000010267 sodium hydrogen sulphite Nutrition 0.000 description 2
-1 0.9% high boilers Chemical compound 0.000 description 1
WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 1
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical class CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
DXORWOXMIMWULJ-UHFFFAOYSA-N benzene-1,4-diol;methyl 2-methylprop-2-enoate Chemical compound COC(=O)C(C)=C.OC1=CC=C(O)C=C1 DXORWOXMIMWULJ-UHFFFAOYSA-N 0.000 description 1
239000012267 brine Substances 0.000 description 1
150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
150000003840 hydrochlorides Chemical class 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000000203 mixture Substances 0.000 description 1
239000000178 monomer Substances 0.000 description 1
239000013307 optical fiber Substances 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
229950000688 phenothiazine Drugs 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
238000004064 recycling Methods 0.000 description 1
150000003349 semicarbazides Chemical class 0.000 description 1
238000007086 side reaction Methods 0.000 description 1
HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
125000000542 sulfonic acid group Chemical group 0.000 description 1

Landscapes

Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

JP6507482A 1982-04-19 1982-04-19 （メタ）アクロレインの回収及び（メタ）アクリル酸メチルの精製方法 Granted JPS58183633A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP6507482A JPS58183633A (ja)	1982-04-19	1982-04-19	（メタ）アクロレインの回収及び（メタ）アクリル酸メチルの精製方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP6507482A JPS58183633A (ja)	1982-04-19	1982-04-19	（メタ）アクロレインの回収及び（メタ）アクリル酸メチルの精製方法

Publications (2)

Publication Number	Publication Date
JPS58183633A JPS58183633A (ja)	1983-10-26
JPH0332532B2 true JPH0332532B2 (de)	1991-05-13

Family

ID=13276435

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP6507482A Granted JPS58183633A (ja)	1982-04-19	1982-04-19	（メタ）アクロレインの回収及び（メタ）アクリル酸メチルの精製方法

Country Status (1)

Country	Link
JP (1)	JPS58183633A (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0323624A3 (de) *	1988-01-06	1991-01-02	BASF Corporation	Reinigung von Carbonsäureestern durch Anwendung von ausgewählten Reduktionsmitteln
TWI796324B (zh) *	2017-03-09	2023-03-21	日商東亞合成股份有限公司	(甲基)丙烯酸酯的製造方法

1982
- 1982-04-19 JP JP6507482A patent/JPS58183633A/ja active Granted

Also Published As

Publication number	Publication date
JPS58183633A (ja)	1983-10-26

Publication	Publication Date	Title
RU2102379C1 (ru)	1998-01-20	Способ получения уксусной кислоты
CN100522916C (zh)	2009-08-05	从甲醇羰基化工艺流中去除还原高锰酸盐的化合物
US8859804B2 (en)	2014-10-14	Method for producing a (meth)acrylate
US4199410A (en)	1980-04-22	Purification of crude acrylic acid
KR840001899B1 (ko)	1984-10-24	메틸 메타아크릴레이트의 정제방법
WO2006062216A1 (en)	2006-06-15	Distillation process
US4039428A (en)	1977-08-02	Purification of propionic acid
JPS58159442A (ja)	1983-09-21	アクリル酸エステル又はメタクリル酸エステルの製造方法
JP4256887B2 (ja)	2009-04-22	（メタ）アクリル酸の製造方法
JPH0332532B2 (de)	1991-05-13
JPH0244296B2 (de)	1990-10-03
JPH0147454B2 (de)	1989-10-13
JP2022533439A (ja)	2022-07-22	高純度アルキルアクリレートを製造するための改良された方法
JP2924563B2 (ja)	1999-07-26	酢酸エチルの精製方法
JP4942878B2 (ja)	2012-05-30	（メタ）アクリル酸エステルの精製方法
JP4601120B2 (ja)	2010-12-22	アクリル酸の製造方法
JP2003321419A (ja)	2003-11-11	高純度（メタ）アクリル酸の製造方法
JP2001288147A (ja)	2001-10-16	メタクリル酸メチルの精製方法
JPH1135523A (ja)	1999-02-09	メタクリル酸メチルの精製方法
JP4299432B2 (ja)	2009-07-22	（メタ）アクリル酸の精製方法
JPS5929633A (ja)	1984-02-16	酢酸塩水溶液から酢酸を回収する方法
JP2003160530A (ja)	2003-06-03	（メタ）アクリル酸の精製方法
JP4204097B2 (ja)	2009-01-07	メタクリル酸メチルの製造方法
JP7750140B2 (ja)	2025-10-07	（メタ）アクリル酸エステルの製造方法
JPH0159261B2 (de)	1989-12-15