JPH0364497B2 - - Google Patents
Info
- Publication number
- JPH0364497B2 JPH0364497B2 JP58245012A JP24501283A JPH0364497B2 JP H0364497 B2 JPH0364497 B2 JP H0364497B2 JP 58245012 A JP58245012 A JP 58245012A JP 24501283 A JP24501283 A JP 24501283A JP H0364497 B2 JPH0364497 B2 JP H0364497B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- carbon atoms
- hydrogen
- alkylene
- substituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000004432 carbon atom Chemical group C* 0.000 claims description 94
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 40
- 125000000217 alkyl group Chemical group 0.000 claims description 36
- 125000002947 alkylene group Chemical group 0.000 claims description 28
- 229910052739 hydrogen Inorganic materials 0.000 claims description 28
- 239000001257 hydrogen Substances 0.000 claims description 28
- 150000001875 compounds Chemical class 0.000 claims description 23
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 18
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 17
- 239000002253 acid Substances 0.000 claims description 14
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 13
- 125000001476 phosphono group Chemical group [H]OP(*)(=O)O[H] 0.000 claims description 13
- 150000002431 hydrogen Chemical group 0.000 claims description 12
- -1 alkyl quaternary ammonium salt Chemical class 0.000 claims description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- 229920001774 Perfluoroether Polymers 0.000 claims description 8
- 150000001447 alkali salts Chemical class 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- 125000001424 substituent group Chemical group 0.000 claims description 8
- 125000003545 alkoxy group Chemical group 0.000 claims description 7
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 7
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 6
- 125000003342 alkenyl group Chemical group 0.000 claims description 6
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 6
- 229910052736 halogen Inorganic materials 0.000 claims description 6
- 150000002367 halogens Chemical class 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 239000011593 sulfur Substances 0.000 claims description 6
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000012736 aqueous medium Substances 0.000 claims description 2
- 239000002585 base Substances 0.000 claims description 2
- 239000000080 wetting agent Substances 0.000 claims description 2
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical group OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 claims 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 235000001014 amino acid Nutrition 0.000 description 5
- 229940024606 amino acid Drugs 0.000 description 5
- 150000001413 amino acids Chemical class 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 4
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 3
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 235000003704 aspartic acid Nutrition 0.000 description 3
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 150000002924 oxiranes Chemical class 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- 108010077895 Sarcosine Proteins 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 235000004279 alanine Nutrition 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 125000004106 butoxy group Chemical group [*]OC([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229940043230 sarcosine Drugs 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 2
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical group [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 2
- MTCFGRXMJLQNBG-REOHCLBHSA-N (2S)-2-Amino-3-hydroxypropansÀure Chemical compound OC[C@H](N)C(O)=O MTCFGRXMJLQNBG-REOHCLBHSA-N 0.000 description 1
- OYIFNHCXNCRBQI-UHFFFAOYSA-N 2-aminoadipic acid Chemical compound OC(=O)C(N)CCCC(O)=O OYIFNHCXNCRBQI-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- QKSDVFYLKRDMEA-UHFFFAOYSA-N 2-hydroxysulfonothioyloxyethanamine Chemical compound NCCOS(O)(=O)=S QKSDVFYLKRDMEA-UHFFFAOYSA-N 0.000 description 1
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 description 1
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- SNDPXSYFESPGGJ-BYPYZUCNSA-N L-2-aminopentanoic acid Chemical compound CCC[C@H](N)C(O)=O SNDPXSYFESPGGJ-BYPYZUCNSA-N 0.000 description 1
- ONIBWKKTOPOVIA-BYPYZUCNSA-N L-Proline Chemical compound OC(=O)[C@@H]1CCCN1 ONIBWKKTOPOVIA-BYPYZUCNSA-N 0.000 description 1
- AGPKZVBTJJNPAG-WHFBIAKZSA-N L-isoleucine Chemical compound CC[C@H](C)[C@H](N)C(O)=O AGPKZVBTJJNPAG-WHFBIAKZSA-N 0.000 description 1
- ROHFNLRQFUQHCH-YFKPBYRVSA-N L-leucine Chemical compound CC(C)C[C@H](N)C(O)=O ROHFNLRQFUQHCH-YFKPBYRVSA-N 0.000 description 1
- FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 description 1
- SNDPXSYFESPGGJ-UHFFFAOYSA-N L-norVal-OH Natural products CCCC(N)C(O)=O SNDPXSYFESPGGJ-UHFFFAOYSA-N 0.000 description 1
- COLNVLDHVKWLRT-QMMMGPOBSA-N L-phenylalanine Chemical compound OC(=O)[C@@H](N)CC1=CC=CC=C1 COLNVLDHVKWLRT-QMMMGPOBSA-N 0.000 description 1
- AYFVYJQAPQTCCC-GBXIJSLDSA-N L-threonine Chemical compound C[C@@H](O)[C@H](N)C(O)=O AYFVYJQAPQTCCC-GBXIJSLDSA-N 0.000 description 1
- QIVBCDIJIAJPQS-VIFPVBQESA-N L-tryptophane Chemical compound C1=CC=C2C(C[C@H](N)C(O)=O)=CNC2=C1 QIVBCDIJIAJPQS-VIFPVBQESA-N 0.000 description 1
- OUYCCCASQSFEME-QMMMGPOBSA-N L-tyrosine Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-QMMMGPOBSA-N 0.000 description 1
- KZSNJWFQEVHDMF-BYPYZUCNSA-N L-valine Chemical compound CC(C)[C@H](N)C(O)=O KZSNJWFQEVHDMF-BYPYZUCNSA-N 0.000 description 1
- ROHFNLRQFUQHCH-UHFFFAOYSA-N Leucine Natural products CC(C)CC(N)C(O)=O ROHFNLRQFUQHCH-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 101100123313 Mus musculus H1.8 gene Proteins 0.000 description 1
- YPIGGYHFMKJNKV-UHFFFAOYSA-N N-ethylglycine Chemical compound CC[NH2+]CC([O-])=O YPIGGYHFMKJNKV-UHFFFAOYSA-N 0.000 description 1
- GDFAOVXKHJXLEI-VKHMYHEASA-N N-methyl-L-alanine Chemical compound C[NH2+][C@@H](C)C([O-])=O GDFAOVXKHJXLEI-VKHMYHEASA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- SUHOOTKUPISOBE-UHFFFAOYSA-N O-phosphoethanolamine Chemical compound NCCOP(O)(O)=O SUHOOTKUPISOBE-UHFFFAOYSA-N 0.000 description 1
- 229910004727 OSO3H Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- ONIBWKKTOPOVIA-UHFFFAOYSA-N Proline Natural products OC(=O)C1CCCN1 ONIBWKKTOPOVIA-UHFFFAOYSA-N 0.000 description 1
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 description 1
- AYFVYJQAPQTCCC-UHFFFAOYSA-N Threonine Natural products CC(O)C(N)C(O)=O AYFVYJQAPQTCCC-UHFFFAOYSA-N 0.000 description 1
- 239000004473 Threonine Substances 0.000 description 1
- QIVBCDIJIAJPQS-UHFFFAOYSA-N Tryptophan Natural products C1=CC=C2C(CC(N)C(O)=O)=CNC2=C1 QIVBCDIJIAJPQS-UHFFFAOYSA-N 0.000 description 1
- KZSNJWFQEVHDMF-UHFFFAOYSA-N Valine Natural products CC(C)C(N)C(O)=O KZSNJWFQEVHDMF-UHFFFAOYSA-N 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229960004050 aminobenzoic acid Drugs 0.000 description 1
- 229940124277 aminobutyric acid Drugs 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 125000004369 butenyl group Chemical group C(=CCC)* 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- WSYUEVRAMDSJKL-UHFFFAOYSA-N ethanolamine-o-sulfate Chemical compound NCCOS(O)(=O)=O WSYUEVRAMDSJKL-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- BTCSSZJGUNDROE-UHFFFAOYSA-N gamma-aminobutyric acid Chemical compound NCCCC(O)=O BTCSSZJGUNDROE-UHFFFAOYSA-N 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000006038 hexenyl group Chemical group 0.000 description 1
- 125000003707 hexyloxy group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])O* 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229960000310 isoleucine Drugs 0.000 description 1
- AGPKZVBTJJNPAG-UHFFFAOYSA-N isoleucine Natural products CCC(C)C(N)C(O)=O AGPKZVBTJJNPAG-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229930182817 methionine Natural products 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 125000004115 pentoxy group Chemical group [*]OC([H])([H])C([H])([H])C([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- COLNVLDHVKWLRT-UHFFFAOYSA-N phenylalanine Natural products OC(=O)C(N)CC1=CC=CC=C1 COLNVLDHVKWLRT-UHFFFAOYSA-N 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- BRNULMACUQOKMR-UHFFFAOYSA-N thiomorpholine Chemical group C1CSCCN1 BRNULMACUQOKMR-UHFFFAOYSA-N 0.000 description 1
- RKBCYCFRFCNLTO-UHFFFAOYSA-N triisopropylamine Chemical compound CC(C)N(C(C)C)C(C)C RKBCYCFRFCNLTO-UHFFFAOYSA-N 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004474 valine Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/23—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton
- C07C323/24—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
- C07C323/25—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and nitrogen atoms, not being part of nitro or nitroso groups, bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/004—Surface-active compounds containing F
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Detergent Compositions (AREA)
Description
ãçºæã®è©³çŽ°ãªèª¬æã
æ¬çºæã¯ãçé¢æŽ»æ§å€ãšããŠæçšãªããã«ãã«
ãªãã¢ã«ãã«ã¢ã«ãã¬ã³åºãŸãã¯ããªã¢ã«ãã¬ã³
åºãæããäž¡æ§ååç©ã«é¢ããã
ãªãã¢ã«ãã«ã¢ã«ãã¬ã³åºãŸãã¯ããªã¢ã«ãã¬ã³
åºãæããäž¡æ§ååç©ã«é¢ããã
äž¡æ§çé¢æŽ»æ§å€ã¯å
¬ç¥ã§ãããäŸãã°ãç±³åœç¹
èš±3480666å·ã«ã¯æ°Žé žåºãä¿æãéåŒçŽ ååŠç³»ãš
ããã·ãããèªå°ãããäž¡æ§ã¹ã«ããªã³é žå¡©çé¢
掻æ§å€ãé瀺ãããŠããããŸããç±³åœç¹èš±
4038195å·ã«ã¯äžé£œåã°ãªã·ããšãŒãã«ããèªå°
ãããåŒçŽ åäž¡æ§çé¢æŽ»æ§å€ãé瀺ãããŠããã
èš±3480666å·ã«ã¯æ°Žé žåºãä¿æãéåŒçŽ ååŠç³»ãš
ããã·ãããèªå°ãããäž¡æ§ã¹ã«ããªã³é žå¡©çé¢
掻æ§å€ãé瀺ãããŠããããŸããç±³åœç¹èš±
4038195å·ã«ã¯äžé£œåã°ãªã·ããšãŒãã«ããèªå°
ãããåŒçŽ åäž¡æ§çé¢æŽ»æ§å€ãé瀺ãããŠããã
æ¬çºæã®äžã€ã®ç®çã¯ãäžè¬åŒ(1)
ïŒåŒäžãRfã¯ïŒãªãã12åã®ççŽ ååãæãã
ãã«ãã«ãªãã¢ã«ãã«åºãŸãã¯ïŒãªããïŒåã®ç
çŽ ååãæãããã«ãã«ãªãã¢ã«ã³ãã·åºã«ãã€
ãŠçœ®æããã該ãã«ãã«ãªãã¢ã«ãã«åºã§ããã
R1ã¯ïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã¬
ã³åºãïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã¬
ã³ããªã¢ã«ãã¬ã³åºãïŒãªããïŒåã®ççŽ ååã
æããã¢ã«ãã¬ã³ãªãã·ã¢ã«ãã¬ã³åºããŸãã¯çª
çŽ ååãæ°ŽçŽ ãããã¯äœçŽã¢ã«ãã«åºã第ïŒçœ®æ
åºãšããŠä¿æããïŒãªããïŒåã®ççŽ ååãæã
ãã¢ã«ãã¬ã³ã€ããã¢ã«ãã¬ã³åºã§ãããR2ã
ãã³R3ã¯ç¬ç«ããŠæ°ŽçŽ ããŸãã¯äœçŽã¢ã«ã³ãã·
åºãããã¯ããã²ã³ã«ãã€ãŠçœ®æãããŠãããäœ
çŽã¢ã«ãã«åºãïŒãããã¯ïŒåã®ççŽ ååãæã
ãã·ã¯ãã¢ã«ãã«åºãŸãã¯ïŒåãŸã§ã®ççŽ ååã
æããã¢ã«ã±ãã«åºã§ãããããããã¯R2ãã
ã³R3ã¯äžç·ã«ãªã€ãŠç¡«é»ãŸãã¯é žçŽ ååãæã
ãŠãããïŒåãŸã§ã®ççŽ ååãæããã¢ã«ãã¬ã³
åºã§ãããR4ããã³R5ã¯ç¬ç«ããŠæ°ŽçŽ ãããã
ã¯ã«ã«ããã·åºãã¹ã«ããªåºãã¹ã«ãã¢ãåºãã
ãªã¹ããªãåºãŸãã¯ããªã¹ããªãåºã«ãã€ãŠçœ®æ
ãããããšãããïŒãªãã12åã®ççŽ ååãæã
ãã¢ã«ãã«åºãŸãã¯ããšãã«åºã§ãããã¯ïŒãª
ãã12åã®ççŽ ååãæããã¢ã«ãã¬ã³åºã§ã
ããã¯ã«ã«ããã·åºãã¹ã«ããªåºãã¹ã«ãã¢ã
åºãããªã¹ããªãåºãããªã¹ããªãåºãŸãã¯ããª
ã¹ã«ãã¢ãåºã§ããïŒ ã§ç€ºãããæ°èŠãªãã«ãã«ãªãã¢ã«ãã«äž¡æ§åå
ç©ãããã³åèšäžè¬åŒ(1)ã®ååç©ã®é žä»å ç©ãã¢
ã«ã«ãªå¡©ããŸãã¯ïŒ®âäœçŽã¢ã«ãã«ãããã¯ïŒ®â
ãã³ãžã«ç¬¬åçŽã¢ã³ã¢ããŠã å¡©ãæäŸããããšã§
ããã
ãã«ãã«ãªãã¢ã«ãã«åºãŸãã¯ïŒãªããïŒåã®ç
çŽ ååãæãããã«ãã«ãªãã¢ã«ã³ãã·åºã«ãã€
ãŠçœ®æããã該ãã«ãã«ãªãã¢ã«ãã«åºã§ããã
R1ã¯ïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã¬
ã³åºãïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã¬
ã³ããªã¢ã«ãã¬ã³åºãïŒãªããïŒåã®ççŽ ååã
æããã¢ã«ãã¬ã³ãªãã·ã¢ã«ãã¬ã³åºããŸãã¯çª
çŽ ååãæ°ŽçŽ ãããã¯äœçŽã¢ã«ãã«åºã第ïŒçœ®æ
åºãšããŠä¿æããïŒãªããïŒåã®ççŽ ååãæã
ãã¢ã«ãã¬ã³ã€ããã¢ã«ãã¬ã³åºã§ãããR2ã
ãã³R3ã¯ç¬ç«ããŠæ°ŽçŽ ããŸãã¯äœçŽã¢ã«ã³ãã·
åºãããã¯ããã²ã³ã«ãã€ãŠçœ®æãããŠãããäœ
çŽã¢ã«ãã«åºãïŒãããã¯ïŒåã®ççŽ ååãæã
ãã·ã¯ãã¢ã«ãã«åºãŸãã¯ïŒåãŸã§ã®ççŽ ååã
æããã¢ã«ã±ãã«åºã§ãããããããã¯R2ãã
ã³R3ã¯äžç·ã«ãªã€ãŠç¡«é»ãŸãã¯é žçŽ ååãæã
ãŠãããïŒåãŸã§ã®ççŽ ååãæããã¢ã«ãã¬ã³
åºã§ãããR4ããã³R5ã¯ç¬ç«ããŠæ°ŽçŽ ãããã
ã¯ã«ã«ããã·åºãã¹ã«ããªåºãã¹ã«ãã¢ãåºãã
ãªã¹ããªãåºãŸãã¯ããªã¹ããªãåºã«ãã€ãŠçœ®æ
ãããããšãããïŒãªãã12åã®ççŽ ååãæã
ãã¢ã«ãã«åºãŸãã¯ããšãã«åºã§ãããã¯ïŒãª
ãã12åã®ççŽ ååãæããã¢ã«ãã¬ã³åºã§ã
ããã¯ã«ã«ããã·åºãã¹ã«ããªåºãã¹ã«ãã¢ã
åºãããªã¹ããªãåºãããªã¹ããªãåºãŸãã¯ããª
ã¹ã«ãã¢ãåºã§ããïŒ ã§ç€ºãããæ°èŠãªãã«ãã«ãªãã¢ã«ãã«äž¡æ§åå
ç©ãããã³åèšäžè¬åŒ(1)ã®ååç©ã®é žä»å ç©ãã¢
ã«ã«ãªå¡©ããŸãã¯ïŒ®âäœçŽã¢ã«ãã«ãããã¯ïŒ®â
ãã³ãžã«ç¬¬åçŽã¢ã³ã¢ããŠã å¡©ãæäŸããããšã§
ããã
æ¬çºæã®ããäžã€ã®ç®çã¯ãåèšäžè¬åŒ(1)ã§ç€º
ãããååç©ã®è£œé æ¹æ³ãæäŸããããšã§ããã
ãããååç©ã®è£œé æ¹æ³ãæäŸããããšã§ããã
äžè¬åŒ(1)ã®ååç©ã«ãããŠãRfã¯å¥œãŸããã¯
ïŒãªãã12åã®ççŽ ååãæãããã«ãã«ãªãã¢
ã«ãã«åºã§ãããåŸã€ãŠãã«ãã«ãªãåãããã
ãã·ã«åºããããã«åºããªã¯ãã«åºãããã«åºã
ãã·ã«åºããŠã³ãã·ã«åºããã³ããã·ã«åºã䞊ã³
ã«ãããã®ç°æ§äœã«ãã€ãŠè¡šããããããã®ãã«
ãã«ãªãã¢ã«ãã«åºRfã¯äŸãã°ããã«ããªãå
ããããšããã·åºãããããã·åºããããã·åºã
ãã³ããã·åºããã³ãããœãã·åºã䞊ã³ã«ããã
ã®ç°æ§äœã®ãããªå¥œãŸããã¯ïŒãªããïŒåã®ççŽ
ååãæãããã«ãã«ãªãã¢ã«ã³ãã·åºã«ãã€ãŠ
眮æãããããšãããã
ïŒãªãã12åã®ççŽ ååãæãããã«ãã«ãªãã¢
ã«ãã«åºã§ãããåŸã€ãŠãã«ãã«ãªãåãããã
ãã·ã«åºããããã«åºããªã¯ãã«åºãããã«åºã
ãã·ã«åºããŠã³ãã·ã«åºããã³ããã·ã«åºã䞊ã³
ã«ãããã®ç°æ§äœã«ãã€ãŠè¡šããããããã®ãã«
ãã«ãªãã¢ã«ãã«åºRfã¯äŸãã°ããã«ããªãå
ããããšããã·åºãããããã·åºããããã·åºã
ãã³ããã·åºããã³ãããœãã·åºã䞊ã³ã«ããã
ã®ç°æ§äœã®ãããªå¥œãŸããã¯ïŒãªããïŒåã®ççŽ
ååãæãããã«ãã«ãªãã¢ã«ã³ãã·åºã«ãã€ãŠ
眮æãããããšãããã
ããããªããããã€ãšã奜ãŸããRfã¯çœ®æã
ããªããã«ãã«ãªãã¢ã«ãã«åºã§ããã
ããªããã«ãã«ãªãã¢ã«ãã«åºã§ããã
æ¥ç¶åºR1ã¯ïŒãªããïŒåã®ççŽ ååãæãã
ã¢ã«ãã¬ã³åºã®ãããªã¢ã«ãã¬ã³éšåã§ããããš
ãã¬ã³åºããããã¬ã³åºããã³ããã¬ã³åºãç¹ã«
奜ãŸãããããŸãå ããŠå¥œãŸããã¯äžè¬åŒ âïŒCH2ïŒ1-7ââïŒCH2ïŒ1-7â ïŒåŒäžã®ïŒžã¯ââãââãããã¯ââïŒïŒ²ïŒ
âã§ãããã¯æ°ŽçŽ ãŸãã¯äœçŽã¢ã«ãã«åºã瀺
ããïŒã§ç€ºãããã¢ã«ãã¬ã³ããªã¢ã«ãã¬ã³åºã
ã¢ã«ãã¬ã³ãªãã·ã¢ã«ãã¬ã³åºããã³ã¢ã«ãã¬ã³
ã€ããã¢ã«ãã¬ã³åºãã瀺ããŠããã
ã¢ã«ãã¬ã³åºã®ãããªã¢ã«ãã¬ã³éšåã§ããããš
ãã¬ã³åºããããã¬ã³åºããã³ããã¬ã³åºãç¹ã«
奜ãŸãããããŸãå ããŠå¥œãŸããã¯äžè¬åŒ âïŒCH2ïŒ1-7ââïŒCH2ïŒ1-7â ïŒåŒäžã®ïŒžã¯ââãââãããã¯ââïŒïŒ²ïŒ
âã§ãããã¯æ°ŽçŽ ãŸãã¯äœçŽã¢ã«ãã«åºã瀺
ããïŒã§ç€ºãããã¢ã«ãã¬ã³ããªã¢ã«ãã¬ã³åºã
ã¢ã«ãã¬ã³ãªãã·ã¢ã«ãã¬ã³åºããã³ã¢ã«ãã¬ã³
ã€ããã¢ã«ãã¬ã³åºãã瀺ããŠããã
æ¬æ现æžãéããŠäœçŽã¢ã«ãã«åºãããã¯äœçŽ
ã¢ã«ã³ãã·åºã«ç€ºãããâäœçŽâã¯ïŒãªããïŒ
åã奜ãŸããã¯ïŒãªããïŒåã®ççŽ ååãæãã
ãããã®åºã瀺ããŠãããæŽã«äœçŽã¢ã«ãã«åºã¯
ã¡ãã«åºããã³ãšãã«åºã§ããããšã奜ãŸããã
ã¢ã«ã³ãã·åºã«ç€ºãããâäœçŽâã¯ïŒãªããïŒ
åã奜ãŸããã¯ïŒãªããïŒåã®ççŽ ååãæãã
ãããã®åºã瀺ããŠãããæŽã«äœçŽã¢ã«ãã«åºã¯
ã¡ãã«åºããã³ãšãã«åºã§ããããšã奜ãŸããã
R2ã¯æ°ŽçŽ ãããã¯ã¡ãã«åºããšãã«åºããã
ãã«åºãŸãã¯ããã·ã«åºã®ãããªäœçŽã¢ã«ãã«åº
ã§ããããã®ã¢ã«ãã«åºã¯ã¡ããã·åºããšããã·
åºãŸãã¯ãããã·åºã®ãããªäœçŽã¢ã«ã³ãã·åºã
ãããã¯å¡©çŽ ãŸãã¯èçŽ ã®ãããªããã²ã³ã«ãã€
ãŠçœ®æãããããšããããæŽã«R2ã¯å¥œãŸããã¯
ã·ã¯ããã³ã¿ã³åºãŸãã¯ã·ã¯ããããµã³åºã®ãã
ãªïŒãªããïŒåã®ççŽ ååãæããã·ã¯ãã¢ã«ã
ã«åºããã³ãšããã«åºãããããã«åºããããã«
åºãŸãã¯ããã»ãã«åºã®ãããªïŒåãŸã§ã®ççŽ å
åãæããã¢ã«ã±ãã«åºãã瀺ããŠããã
ãã«åºãŸãã¯ããã·ã«åºã®ãããªäœçŽã¢ã«ãã«åº
ã§ããããã®ã¢ã«ãã«åºã¯ã¡ããã·åºããšããã·
åºãŸãã¯ãããã·åºã®ãããªäœçŽã¢ã«ã³ãã·åºã
ãããã¯å¡©çŽ ãŸãã¯èçŽ ã®ãããªããã²ã³ã«ãã€
ãŠçœ®æãããããšããããæŽã«R2ã¯å¥œãŸããã¯
ã·ã¯ããã³ã¿ã³åºãŸãã¯ã·ã¯ããããµã³åºã®ãã
ãªïŒãªããïŒåã®ççŽ ååãæããã·ã¯ãã¢ã«ã
ã«åºããã³ãšããã«åºãããããã«åºããããã«
åºãŸãã¯ããã»ãã«åºã®ãããªïŒåãŸã§ã®ççŽ å
åãæããã¢ã«ã±ãã«åºãã瀺ããŠããã
R3ã¯R2ãšã¯ç¬ç«ããŠR2ãšåãæå³ããã€ãŠã
ãã
ãã
R2ããã³R3ã¯äžç·ã«ãªã€ãŠïŒåãŸã§ã®ççŽ å
åãæããã¢ã«ãã¬ã³éã圢æããããšãã§ãã
ãã®éã¯ç¡«é»ãçªçŽ ãŸãã¯é žçŽ ã«ãã€ãŠäžæãã
ãŠããããäŸãã°ã¢ã«ããªãªã³ç°ããããªãžã³ç°
ãŸãã¯ããªã¢ã«ããªãªã³ç°ã圢æããã
åãæããã¢ã«ãã¬ã³éã圢æããããšãã§ãã
ãã®éã¯ç¡«é»ãçªçŽ ãŸãã¯é žçŽ ã«ãã€ãŠäžæãã
ãŠããããäŸãã°ã¢ã«ããªãªã³ç°ããããªãžã³ç°
ãŸãã¯ããªã¢ã«ããªãªã³ç°ã圢æããã
R4ã¯æ°ŽçŽ ããããã¯å¥œãŸããã¯ïŒãªãã12å
ã®ççŽ ååãæããã¢ã«ãã«åºã§ãããåŸã€ãŠã
äŸãã°ã¡ãã«åºããšãã«åºããããã«åºãããã«
åºãããã·ã«åºããªã¯ãã«åºããã·ã«åºããã³ã
ãã·ã«åºã®ãããªã¢ã«ãã«åºãšãããã®ç°æ§äœã
é©ããŠããããã®ãã¡ïŒãªããïŒåã®ççŽ ååã
æããã¢ã«ãã«åºã奜ãŸãããæŽã«å¥œãŸããR4
ã¯ã¡ãã«åºã§ããããŸãR4ã¯ããšãã«åºãã瀺
ããŠãããäžèšã®ã¢ã«ãã«åºãšããšãã«åºã¯ã«ã«
ããã·åºïŒâCOOHãâCOO ïŒ ãããã§ïŒ
ã¯éå±ã€ãªã³ã奜ãŸããã¯ã¢ã«ã«ãªéå±ã€ãªã³ã
ããã¯ã¢ã³ã¢ããŠã ã€ãªã³ãè¡šãããïŒãã¹ã«ããª
åºïŒâSO3HãâSO3 ïŒ ãããã§ïŒ ã¯èŠå®ã
ãããã®ãšåäžã§ãããïŒã¹ã«ãã¢ãåºïŒâ
OSO3HâSO3 ïŒ ãããã§ïŒ ã¯äžã«èŠå®ã
ãããã®ãšåäžã§ããïŒããªã¹ããªãåºïŒâ
PO4H2ãâPO4H ïŒ ãâPO4H2 ïŒ ãããã
ã§ïŒ ã¯äžã«èŠå®ããããã®ãšåäžã§ããïŒãã
ãã³ããªã¹ããªãåºïŒâPH3H2ãâPO3H ïŒ ã
âPO3 2 M2 ãããã§ïŒ ã¯äžã«èŠå®ãããã
ã®ãšåäžã§ããïŒã«ãã€ãŠçœ®æããããšãã§ã
ãã奜ãŸãã眮æåºã¯ã«ã«ããã·åºããã³ã¹ã«ã
ãªåºã§ããã
ã®ççŽ ååãæããã¢ã«ãã«åºã§ãããåŸã€ãŠã
äŸãã°ã¡ãã«åºããšãã«åºããããã«åºãããã«
åºãããã·ã«åºããªã¯ãã«åºããã·ã«åºããã³ã
ãã·ã«åºã®ãããªã¢ã«ãã«åºãšãããã®ç°æ§äœã
é©ããŠããããã®ãã¡ïŒãªããïŒåã®ççŽ ååã
æããã¢ã«ãã«åºã奜ãŸãããæŽã«å¥œãŸããR4
ã¯ã¡ãã«åºã§ããããŸãR4ã¯ããšãã«åºãã瀺
ããŠãããäžèšã®ã¢ã«ãã«åºãšããšãã«åºã¯ã«ã«
ããã·åºïŒâCOOHãâCOO ïŒ ãããã§ïŒ
ã¯éå±ã€ãªã³ã奜ãŸããã¯ã¢ã«ã«ãªéå±ã€ãªã³ã
ããã¯ã¢ã³ã¢ããŠã ã€ãªã³ãè¡šãããïŒãã¹ã«ããª
åºïŒâSO3HãâSO3 ïŒ ãããã§ïŒ ã¯èŠå®ã
ãããã®ãšåäžã§ãããïŒã¹ã«ãã¢ãåºïŒâ
OSO3HâSO3 ïŒ ãããã§ïŒ ã¯äžã«èŠå®ã
ãããã®ãšåäžã§ããïŒããªã¹ããªãåºïŒâ
PO4H2ãâPO4H ïŒ ãâPO4H2 ïŒ ãããã
ã§ïŒ ã¯äžã«èŠå®ããããã®ãšåäžã§ããïŒãã
ãã³ããªã¹ããªãåºïŒâPH3H2ãâPO3H ïŒ ã
âPO3 2 M2 ãããã§ïŒ ã¯äžã«èŠå®ãããã
ã®ãšåäžã§ããïŒã«ãã€ãŠçœ®æããããšãã§ã
ãã奜ãŸãã眮æåºã¯ã«ã«ããã·åºããã³ã¹ã«ã
ãªåºã§ããã
R5ã¯R4ãšã¯ç¬ç«ããŠR4ãšåãæå³ããã€ãŠã
ãã
ãã
ã¯å¥œãŸããã¯ïŒãªãã12åã®ççŽ ååãæã
ãã¢ã«ãã¬ã³åºã§ãããR4ãå®çŸ©ããéã«ãã
ãçžåœããã¢ã«ãã«åºããé©åãªåºãéžæã§ã
ããã¯ïŒãªããïŒåã®ççŽ ååãæããã¢ã«ã
ã¬ã³åºã§ããããšãããæãŸãããã¯é žåºã§ã
ããäŸãã°ã«ã«ããã·åºãã¹ã«ããªåºãã¹ã«ãã¢
ãåºãããªã¹ããªãåºãããªã¹ããªãåºïŒããã
ã®åºã®äžè¬åŒã¯R4ã®å®çŸ©ã®éã«èšããŠãïŒãã
ãã¯ããªã¹ã«ãã¢ãåºïŒâS2O3HãâS2O3 ïŒ
ãããã§ïŒ ã¯å ã«èŠå®ããããã®ãšåäžã§ã
ãïŒã瀺ãããã®ãã¡ã«ã«ããã·åºãŸãã¯ã¹ã«ã
ã¢ãåºã奜ãŸããã
ãã¢ã«ãã¬ã³åºã§ãããR4ãå®çŸ©ããéã«ãã
ãçžåœããã¢ã«ãã«åºããé©åãªåºãéžæã§ã
ããã¯ïŒãªããïŒåã®ççŽ ååãæããã¢ã«ã
ã¬ã³åºã§ããããšãããæãŸãããã¯é žåºã§ã
ããäŸãã°ã«ã«ããã·åºãã¹ã«ããªåºãã¹ã«ãã¢
ãåºãããªã¹ããªãåºãããªã¹ããªãåºïŒããã
ã®åºã®äžè¬åŒã¯R4ã®å®çŸ©ã®éã«èšããŠãïŒãã
ãã¯ããªã¹ã«ãã¢ãåºïŒâS2O3HãâS2O3 ïŒ
ãããã§ïŒ ã¯å ã«èŠå®ããããã®ãšåäžã§ã
ãïŒã瀺ãããã®ãã¡ã«ã«ããã·åºãŸãã¯ã¹ã«ã
ã¢ãåºã奜ãŸããã
äžè¬åŒ(1)ååç©ã¯ããŸãã¢ã«ã«ãªå¡©ã®åœ¢ã§ãå
åšãããã¢ã«ã«ãªå¡©ã«ã¯å¥œãŸããã¯ãããªãŠã ã
ãã³ã«ãªãŠã ã®ãããªã¢ã«ã«ãªéå±äžŠã³ã«ãã°ã
ã·ãŠã ãã«ã«ã·ãŠã ããã³ããªãŠã ã®ãããªã¢ã«
ã«ãªåé¡éå±ã®å¡©ãããã
åšãããã¢ã«ã«ãªå¡©ã«ã¯å¥œãŸããã¯ãããªãŠã ã
ãã³ã«ãªãŠã ã®ãããªã¢ã«ã«ãªéå±äžŠã³ã«ãã°ã
ã·ãŠã ãã«ã«ã·ãŠã ããã³ããªãŠã ã®ãããªã¢ã«
ã«ãªåé¡éå±ã®å¡©ãããã
äžè¬åŒ(1)ã®ååç©ã¯ãæŽã«ç¬¬åçŽã¢ã³ã¢ããŠã
å¡©ã奜ãŸããã¯äœçŽã¢ã«ãã«ãäœçŽã¢ã«ã«ããŒã«
ãããã¯ãã³ãžã«ç¬¬åçŽã¢ã³ã¢ããŠã å¡©ã®åœ¢ã§å
åšããã
å¡©ã奜ãŸããã¯äœçŽã¢ã«ãã«ãäœçŽã¢ã«ã«ããŒã«
ãããã¯ãã³ãžã«ç¬¬åçŽã¢ã³ã¢ããŠã å¡©ã®åœ¢ã§å
åšããã
äžè¬åŒ(1)ã®ååç©ã®é
žä»å ç©ã«ã¯ãéåžžã®ç¡æ©
é žã®ä»å ç©ãç¹ã«å¡©é žãèåæ°ŽçŽ é žãç¡«é žãç¡é ž
ããã³çé žã®ä»å ç©ãšäœçŽã¢ã«ã«ãã€ãã¯é žãäœ
çŽã¢ã«ãã«ã¹ã«ããªã³é žãã¢ãªãŒã«ã«ã«ãã³é žç¹
ã«å®æ¯éŠé žãããã³ã¢ãªãŒã«ã¹ã«ããªã³é žç¹ã«ã
ãªã«ã¹ã«ããªã³é žçã®éåžžã®ææ©é žã®ä»å ç©ãã
ãã
é žã®ä»å ç©ãç¹ã«å¡©é žãèåæ°ŽçŽ é žãç¡«é žãç¡é ž
ããã³çé žã®ä»å ç©ãšäœçŽã¢ã«ã«ãã€ãã¯é žãäœ
çŽã¢ã«ãã«ã¹ã«ããªã³é žãã¢ãªãŒã«ã«ã«ãã³é žç¹
ã«å®æ¯éŠé žãããã³ã¢ãªãŒã«ã¹ã«ããªã³é žç¹ã«ã
ãªã«ã¹ã«ããªã³é žçã®éåžžã®ææ©é žã®ä»å ç©ãã
ãã
äžè¬åŒ(1)ã®å¥œãŸããååç©ã¯åŒäžã®RfãïŒãª
ãã12åã®ççŽ ååãæãããã«ãã«ãªãã¢ã«ã
ã«åºãŸãã¯ïŒãªããïŒåã®ççŽ ååãæãããã«
ãã«ãªãã¢ã«ã³ãã·åºã«ãã€ãŠçœ®æããã該ãã«
ãã«ãªãã¢ã«ãã«åºã§ãããR1ãïŒãªããïŒå
ã®ççŽ ååãæããã¢ã«ãã¬ã³åºãïŒãªããïŒå
ã®ççŽ ååãæããã¢ã«ãã¬ã³ããªã¢ã«ãã¬ã³
åºãïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã¬ã³
ãªãã·ã¢ã«ãã¬ã³åºãããã¯çªçŽ ååãæ°ŽçŽ ãŸã
ã¯ïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã«åºã
第ïŒçœ®æåºãšããŠä¿æããŠããïŒãªããïŒåã®ç
çŽ ååãæããã¢ã«ãã¬ã³ã€ããã¢ã«ãã¬ã³åºã§
ãããR2ããã³R3ãæ°ŽçŽ ã§ãããR4ããã³R5ã
æ°ŽçŽ ãã¡ãã«åºãŸãã¯ã«ã«ããã·åºã«ãã€ãŠçœ®æ
ãããïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã«
åºã§ãããã¯ïŒãªããïŒåã®ççŽ ååãæãã
ã¢ã«ãã¬ã³åºã§ããããã«ã«ããã·åºãŸãã¯ã¹
ã«ããªåºã§ããååç©ããããã¯ãããååç©ã®
é žä»å ç©ãã¢ã«ã«ãªå¡©ãŸãã¯ïŒ®âäœçŽã¢ã«ãã«ç¬¬
åçŽã¢ã³ã¢ããŠã å¡©ã§ããã
ãã12åã®ççŽ ååãæãããã«ãã«ãªãã¢ã«ã
ã«åºãŸãã¯ïŒãªããïŒåã®ççŽ ååãæãããã«
ãã«ãªãã¢ã«ã³ãã·åºã«ãã€ãŠçœ®æããã該ãã«
ãã«ãªãã¢ã«ãã«åºã§ãããR1ãïŒãªããïŒå
ã®ççŽ ååãæããã¢ã«ãã¬ã³åºãïŒãªããïŒå
ã®ççŽ ååãæããã¢ã«ãã¬ã³ããªã¢ã«ãã¬ã³
åºãïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã¬ã³
ãªãã·ã¢ã«ãã¬ã³åºãããã¯çªçŽ ååãæ°ŽçŽ ãŸã
ã¯ïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã«åºã
第ïŒçœ®æåºãšããŠä¿æããŠããïŒãªããïŒåã®ç
çŽ ååãæããã¢ã«ãã¬ã³ã€ããã¢ã«ãã¬ã³åºã§
ãããR2ããã³R3ãæ°ŽçŽ ã§ãããR4ããã³R5ã
æ°ŽçŽ ãã¡ãã«åºãŸãã¯ã«ã«ããã·åºã«ãã€ãŠçœ®æ
ãããïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã«
åºã§ãããã¯ïŒãªããïŒåã®ççŽ ååãæãã
ã¢ã«ãã¬ã³åºã§ããããã«ã«ããã·åºãŸãã¯ã¹
ã«ããªåºã§ããååç©ããããã¯ãããååç©ã®
é žä»å ç©ãã¢ã«ã«ãªå¡©ãŸãã¯ïŒ®âäœçŽã¢ã«ãã«ç¬¬
åçŽã¢ã³ã¢ããŠã å¡©ã§ããã
ç¹ã«å¥œãŸããååç©ã¯ãRfãïŒãªãã12åã®
ççŽ ååãæãããã«ãã«ãªãã¢ã«ãã«åºã§ã
ããR1ãïŒãªããïŒåã®ççŽ ååãæããã¢ã«
ãã¬ã³åºã§ãããR2ããã³R3ãæ°ŽçŽ ãR4ããã³
R5ãæ°ŽçŽ ãã¡ãã«åºããŸãã¯ã«ã«ããã·åºã«ã
ã€ãŠçœ®æãããäœçŽã¢ã«ãã«åºãã¯ïŒãªããïŒ
åã®ççŽ ååãæããã¢ã«ãã¬ã³åºãã¯ã«ã«ã
ãã·åºãŸãã¯ã¹ã«ããªåºã§ããååç©ããããã¯
ãããååç©ã®é žä»å ç©ãã¢ã«ã«ãªå¡©ãŸãã¯ïŒ®â
äœçŽã¢ã«ãã«ç¬¬åçŽã¢ã³ã¢ããŠã å¡©ã§ããã
ççŽ ååãæãããã«ãã«ãªãã¢ã«ãã«åºã§ã
ããR1ãïŒãªããïŒåã®ççŽ ååãæããã¢ã«
ãã¬ã³åºã§ãããR2ããã³R3ãæ°ŽçŽ ãR4ããã³
R5ãæ°ŽçŽ ãã¡ãã«åºããŸãã¯ã«ã«ããã·åºã«ã
ã€ãŠçœ®æãããäœçŽã¢ã«ãã«åºãã¯ïŒãªããïŒ
åã®ççŽ ååãæããã¢ã«ãã¬ã³åºãã¯ã«ã«ã
ãã·åºãŸãã¯ã¹ã«ããªåºã§ããååç©ããããã¯
ãããååç©ã®é žä»å ç©ãã¢ã«ã«ãªå¡©ãŸãã¯ïŒ®â
äœçŽã¢ã«ãã«ç¬¬åçŽã¢ã³ã¢ããŠã å¡©ã§ããã
ãã®æ°èŠãªRfâäž¡æ§ååç©ã¯äžè¬åŒ(2)
ã®Rfâãšããã·ããäžè¬åŒ(3)
NR4R5Z (3)
ã§è¡šããããã¢ããé
žã«ä»å ããããšã«ãã€ãŠåŸ
ãããïŒäž¡åŒäžãRfãR1ãR2ãR3ãR4ãR5ãã
ã³ïŒºã¯åèšã«èŠå®ããããã®ãšåäžã§ããïŒã
ãããïŒäž¡åŒäžãRfãR1ãR2ãR3ãR4ãR5ãã
ã³ïŒºã¯åèšã«èŠå®ããããã®ãšåäžã§ããïŒã
æ¬çºæã«çšããããã¢ããé
žã«ã¯éåžžã®ã«ã«ã
ãã·åºããã³ã¹ã«ããªåºã®çœ®æåºã®ã¿ãªããã¹ã«
ãã¢ãåºãããªã¹ããªãåºããã³ããªã¹ããªãåº
ããä¿æãã倩ç¶ããã³åæã¢ããé žãå«ãŸã
ãããããã®äžã«ã¯äŸãã°ã°ãªã·ã³ãã¢ã©ãã³ã
ããªã³ããã€ã·ã³ãã€ãœãã€ã·ã³ãããšãã«ã¢ã©
ãã³ããããªã³ãã¡ããªãã³ãã»ãªã³ããã¬ãªã
ã³ãã·ã¹ããªã³ãããã·ã³ãããªãããã¢ã³ãã¢
ããã¢ãžãã³é žãã¢ã©ãã³ãã¡ãã«ã¢ã©ãã³ãã¢
ããé ªé žããšãã«ã°ãªã·ã³ããã«ããªã³ãã¢ã¹ã
ã©ã®ã³é žããµã«ã³ã·ã³ãã€ããäºé ¢é žãã¢ããå®
æ¯éŠé žãïŒâã¢ãããšãã«æ°ŽçŽ ç¡«é žãšã¹ãã«ãïŒ
âã¢ãããšãã«ããªç¡«é žãïŒâã¢ãããšãã«æ°ŽçŽ
çé žãšã¹ãã«ãã¿ãŠãªã³ãã¡ãã«ã¿ãŠãªã³ãã
ãã
ãã·åºããã³ã¹ã«ããªåºã®çœ®æåºã®ã¿ãªããã¹ã«
ãã¢ãåºãããªã¹ããªãåºããã³ããªã¹ããªãåº
ããä¿æãã倩ç¶ããã³åæã¢ããé žãå«ãŸã
ãããããã®äžã«ã¯äŸãã°ã°ãªã·ã³ãã¢ã©ãã³ã
ããªã³ããã€ã·ã³ãã€ãœãã€ã·ã³ãããšãã«ã¢ã©
ãã³ããããªã³ãã¡ããªãã³ãã»ãªã³ããã¬ãªã
ã³ãã·ã¹ããªã³ãããã·ã³ãããªãããã¢ã³ãã¢
ããã¢ãžãã³é žãã¢ã©ãã³ãã¡ãã«ã¢ã©ãã³ãã¢
ããé ªé žããšãã«ã°ãªã·ã³ããã«ããªã³ãã¢ã¹ã
ã©ã®ã³é žããµã«ã³ã·ã³ãã€ããäºé ¢é žãã¢ããå®
æ¯éŠé žãïŒâã¢ãããšãã«æ°ŽçŽ ç¡«é žãšã¹ãã«ãïŒ
âã¢ãããšãã«ããªç¡«é žãïŒâã¢ãããšãã«æ°ŽçŽ
çé žãšã¹ãã«ãã¿ãŠãªã³ãã¡ãã«ã¿ãŠãªã³ãã
ãã
ãšããã·ãã®ã¢ããé
žãžã®ä»å ã¯ãåäžçžäžã§
ãã€ãšã容æã«çããå¡©åºæ§æ¥è§Šåå¿ã§ãããã
ã®åå¿ã¯äžè¬ã«ãã¡ã¿ããŒã«ãã€ãœãããããŒ
ã«ããããã·ãšã¿ããŒã«çã®ãããªæ°Žãšçžæº¶æ§ã®
ããé©åœãªæº¶åªãéžãã§ã€ãã€ãæ°Žæ§åªè³ªæ··åç©
äžã§è¡ããããåå¿ã¯äžè¬ã«25âãã200âã奜
ããŸããã¯50âãã130âã®éã®æž©åºŠã§è¡ãããã
ãã€ãšã容æã«çããå¡©åºæ§æ¥è§Šåå¿ã§ãããã
ã®åå¿ã¯äžè¬ã«ãã¡ã¿ããŒã«ãã€ãœãããããŒ
ã«ããããã·ãšã¿ããŒã«çã®ãããªæ°Žãšçžæº¶æ§ã®
ããé©åœãªæº¶åªãéžãã§ã€ãã€ãæ°Žæ§åªè³ªæ··åç©
äžã§è¡ããããåå¿ã¯äžè¬ã«25âãã200âã奜
ããŸããã¯50âãã130âã®éã®æž©åºŠã§è¡ãããã
ãããåå¿çš®ãååã«å¡©åºæ§ã§ãããªãã°ãã
ããã¯æ°Žé žåã¢ã«ã«ãªãã€ãªã³äº€æ觊åªãããã¯
ããªã€ãœãããã«ã¢ãã³ã®ãããªéåå¿æ§å¡©åºã«
ãã€ãŠããããããã¢ã«ã«ãªæ§PHå€ã«ãããªã
ã°ãåå¿ã¯é觊åªçã«ãããããã
ããã¯æ°Žé žåã¢ã«ã«ãªãã€ãªã³äº€æ觊åªãããã¯
ããªã€ãœãããã«ã¢ãã³ã®ãããªéåå¿æ§å¡©åºã«
ãã€ãŠããããããã¢ã«ã«ãªæ§PHå€ã«ãããªã
ã°ãåå¿ã¯é觊åªçã«ãããããã
çæç©ã¯äžè¬ã«åé¢ããªããŠãæçšã§ãããã
PHå€ã«ãã€ãŠé žã®åœ¢ã§ãçé»åäžæ§å¡©ãšããŠãã
ãã¯ã¢ã«ã«ãªéå±ãããã¯ã¢ã³ã¢ããŠã å¡©ãšããŠ
åé¢ããããšãã§ãããâäœçŽã¢ã«ãã«ããã
ã¯ïŒ®âãã³ãžã«ç¬¬åçŽå®èœåºããã€ãå®å šã«åçŽ
åãããèªå°äœã¯ãäžè¬ã«äžæ§ã®äž¡æ§ã€ãªã³åå
ç©ãŸãã¯å¡©é žå¡©ã®ãããªé žä»å ç©ãšããŠåé¢ãã
ãã
PHå€ã«ãã€ãŠé žã®åœ¢ã§ãçé»åäžæ§å¡©ãšããŠãã
ãã¯ã¢ã«ã«ãªéå±ãããã¯ã¢ã³ã¢ããŠã å¡©ãšããŠ
åé¢ããããšãã§ãããâäœçŽã¢ã«ãã«ããã
ã¯ïŒ®âãã³ãžã«ç¬¬åçŽå®èœåºããã€ãå®å šã«åçŽ
åãããèªå°äœã¯ãäžè¬ã«äžæ§ã®äž¡æ§ã€ãªã³åå
ç©ãŸãã¯å¡©é žå¡©ã®ãããªé žä»å ç©ãšããŠåé¢ãã
ãã
æ¬çºæã®äž¡æ§ååç©ã¯å æ°Žå解ã«å¯ŸããŠéåžžã«
å®å šã§çé¢æŽ»æ§å€ããã³æ¹¿æœ€å€ãšããŠå€ãã®çšé
ãããããããã®ååç©ã¯å®¹æã«å ¥æã§ããã¢ã
ãé žãšå®¹æã«å ¥æå¯èœãªåŒçŽ åãšããã·ãããèª
å°ãããã®ã§ç¹ã«æçšãªçµæãæ§æããŠããã
å®å šã§çé¢æŽ»æ§å€ããã³æ¹¿æœ€å€ãšããŠå€ãã®çšé
ãããããããã®ååç©ã¯å®¹æã«å ¥æã§ããã¢ã
ãé žãšå®¹æã«å ¥æå¯èœãªåŒçŽ åãšããã·ãããèª
å°ãããã®ã§ç¹ã«æçšãªçµæãæ§æããŠããã
以äžãæ¬çºæãå®æœäŸã«ãã€ãŠèª¬æããã
å®æœäŸ ïŒ
C8F14CH2CH2SCH2CHOHCH2
NHïŒCH3ïŒ
CH2CO2 50mlã®ãã©ã¹ã³ã«ïŒâïŒïŒïŒïŒïŒïŒïŒïŒâãã
ã©ããããã«ãã«ãªããã«ã³ããªïŒâïŒïŒïŒâãš
ããã·ãããã³ïŒ5.4ïœïŒ10ããªã¢ã«ïŒããµã«ã³ã·
ã³ïŒ1.0ïœïŒ10.5ããªã¢ã«ïŒã50ïŒ æ°Žé žåãããªãŠ
ã 氎溶液ïŒ0.9ïœïŒ11ããªã¢ã«ïŒãã€ãœãããããŒ
ã«ïŒ18ïœïŒããã³ååãªæ°ŽïŒïŒïœïŒãå ¥ãæž æŸãª
溶液ãåŸãããã®æº¶æ¶²ãïŒæéã77âã«å ç±ã
ããå·åŽåŸã溶åªãèžçºããŠé€ãåååºäœãæ°Žã«
å溶解ãããäžæº¶ç©ãéããéã72æééæ
ã«ãããçæç©ãèžçºã«ããååããã
CH2CO2 50mlã®ãã©ã¹ã³ã«ïŒâïŒïŒïŒïŒïŒïŒïŒïŒâãã
ã©ããããã«ãã«ãªããã«ã³ããªïŒâïŒïŒïŒâãš
ããã·ãããã³ïŒ5.4ïœïŒ10ããªã¢ã«ïŒããµã«ã³ã·
ã³ïŒ1.0ïœïŒ10.5ããªã¢ã«ïŒã50ïŒ æ°Žé žåãããªãŠ
ã 氎溶液ïŒ0.9ïœïŒ11ããªã¢ã«ïŒãã€ãœãããããŒ
ã«ïŒ18ïœïŒããã³ååãªæ°ŽïŒïŒïœïŒãå ¥ãæž æŸãª
溶液ãåŸãããã®æº¶æ¶²ãïŒæéã77âã«å ç±ã
ããå·åŽåŸã溶åªãèžçºããŠé€ãåååºäœãæ°Žã«
å溶解ãããäžæº¶ç©ãéããéã72æééæ
ã«ãããçæç©ãèžçºã«ããååããã
åæïŒC16H16F17NO3ãšããŠèšç®ïŒ
C30.8ïŒH2.4ïŒN2.2 å®æœå€ C30.0ïŒH2.3ïŒN2.8 å®æœäŸ ïŒ C6F13CH2CH2SCH2CHOHCH2 NHCHïŒCO2
ïŒCH2CO2Na 50mlã®ãã©ã¹ã³ã«ïŒâïŒïŒïŒïŒïŒïŒïŒïŒâãã
ã©ããããã«ãã«ãªããã«ã³ããªïŒâïŒïŒïŒâãš
ããã·ãããã³ïŒ3.0ïœïŒ6.9ããªã¢ã«ïŒãã¢ã¹ã
ã©ã®ã³é žïŒ1.0ïœã7.2ããªã¢ã«ïŒã50ïŒ æ°Žé žåã
ããªãŠã 氎溶液ïŒ0.6ïœã7.5ããªã¢ã«ïŒãã€ãœã
ããããŒã«ïŒ12.6ïœïŒããã³ååãªæ°ŽïŒ19.2ïœïŒ
ãå ¥ãæž æŸãªæº¶æ¶²ãåŸãããã®æº¶æ¶²ã24æé70â
ã«å ç±ãããå·åŽåŸã溶åªãèžçºããŠé€ããåå
ãããåºäœãæ°Žã«å溶解ãããäžæº¶ç©ãéãã
éã72æééæã«ãããçæç©ãèžçºã«ããå
åããã
C30.8ïŒH2.4ïŒN2.2 å®æœå€ C30.0ïŒH2.3ïŒN2.8 å®æœäŸ ïŒ C6F13CH2CH2SCH2CHOHCH2 NHCHïŒCO2
ïŒCH2CO2Na 50mlã®ãã©ã¹ã³ã«ïŒâïŒïŒïŒïŒïŒïŒïŒïŒâãã
ã©ããããã«ãã«ãªããã«ã³ããªïŒâïŒïŒïŒâãš
ããã·ãããã³ïŒ3.0ïœïŒ6.9ããªã¢ã«ïŒãã¢ã¹ã
ã©ã®ã³é žïŒ1.0ïœã7.2ããªã¢ã«ïŒã50ïŒ æ°Žé žåã
ããªãŠã 氎溶液ïŒ0.6ïœã7.5ããªã¢ã«ïŒãã€ãœã
ããããŒã«ïŒ12.6ïœïŒããã³ååãªæ°ŽïŒ19.2ïœïŒ
ãå ¥ãæž æŸãªæº¶æ¶²ãåŸãããã®æº¶æ¶²ã24æé70â
ã«å ç±ãããå·åŽåŸã溶åªãèžçºããŠé€ããåå
ãããåºäœãæ°Žã«å溶解ãããäžæº¶ç©ãéãã
éã72æééæã«ãããçæç©ãèžçºã«ããå
åããã
åæïŒC15H14F13NNaO5SãšããŠèšç®ïŒ
C28.1ïŒH2.5ïŒN2.5 å®æž¬å€ C29.7ïŒH2.6ïŒN2.0 ãã®ååç©ã®è¡šé¢åŒµåæå¶å¹æãïŒ10æ°Žé žå
ãããªãŠã 溶液ã§å®èšŒããã0.01ããã³0.001ïŒ
ã®éã§çšããå Žåã枬å®ãããè¡šé¢åŒµåå€ã¯ãã
ãã17.8ããã³34.5ãã€ã³ïŒcmã§ãã€ãã
C28.1ïŒH2.5ïŒN2.5 å®æž¬å€ C29.7ïŒH2.6ïŒN2.0 ãã®ååç©ã®è¡šé¢åŒµåæå¶å¹æãïŒ10æ°Žé žå
ãããªãŠã 溶液ã§å®èšŒããã0.01ããã³0.001ïŒ
ã®éã§çšããå Žåã枬å®ãããè¡šé¢åŒµåå€ã¯ãã
ãã17.8ããã³34.5ãã€ã³ïŒcmã§ãã€ãã
å®æœäŸ ïŒ
C10F21CH2CH2SCH2CHOHCH2NïŒCH3ïŒ
CH2CH2SO3Na 50mlã®ãã©ã¹ã³ã«ïŒâïŒïŒïŒïŒïŒïŒïŒïŒâãã
ã©ããããã«ãã«ãªãããã«ã³ããªïŒâïŒïŒïŒâ
ãšããã·ãããã³ïŒ6.30ïœïŒ10ããªã¢ã«ïŒãâ
ã¡ãã«ã¿ãŠãªã³ïŒ6.21ïœïŒ15ããªã¢ã«ïŒã25ïŒ æ°Ž
é žåãããªãŠã 氎溶液ïŒ0.10ïœïŒ20ããªã¢ã«ïŒã
ãã³20ïœã®ã¡ã¿ããŒã«ãå ¥ããã溶液ã16æé75
âã«å ç±ãããå·åŽåŸã100mlã®æ°Žãš400mlã®ã¡ã¿
ããŒã«ãå ãã溶液ã72âã§éããïŒâ10âã«
å·åŽããåã³éã70âã§ç空也ç¥ããã
CH2CH2SO3Na 50mlã®ãã©ã¹ã³ã«ïŒâïŒïŒïŒïŒïŒïŒïŒïŒâãã
ã©ããããã«ãã«ãªãããã«ã³ããªïŒâïŒïŒïŒâ
ãšããã·ãããã³ïŒ6.30ïœïŒ10ããªã¢ã«ïŒãâ
ã¡ãã«ã¿ãŠãªã³ïŒ6.21ïœïŒ15ããªã¢ã«ïŒã25ïŒ æ°Ž
é žåãããªãŠã 氎溶液ïŒ0.10ïœïŒ20ããªã¢ã«ïŒã
ãã³20ïœã®ã¡ã¿ããŒã«ãå ¥ããã溶液ã16æé75
âã«å ç±ãããå·åŽåŸã100mlã®æ°Žãš400mlã®ã¡ã¿
ããŒã«ãå ãã溶液ã72âã§éããïŒâ10âã«
å·åŽããåã³éã70âã§ç空也ç¥ããã
åæïŒC8H17F21NNaO4S2ãšããŠèšç®ïŒ
C27.1ïŒH2.2ïŒN1.8ïŒF50.5ïŒS8.0 å®æž¬å€ C27.2ïŒH2.2ïŒN1.3ïŒF52.3ïŒS7.5 å®æœäŸ ïŒ C10F21CH2CH2SCH2CHOHCH2 NH
ïŒCH2CO2HïŒCH2CO2 50mlã®ãã©ã¹ã³ã«ïŒâïŒïŒïŒïŒïŒïŒïŒïŒâãã
ã©ããããã«ãã«ãªããã«ã³ããªïŒâïŒïŒïŒâãš
ããã·ãããã³ïŒ6.30ïœïŒ10ããªã¢ã«ïŒãã€ãã
äºé ¢é žïŒ2.93ïœïŒ15ããªã¢ã«ïŒã25ïŒ æ°Žé žåãã
ãªãŠã 氎溶液ïŒ3.20ïœïŒ20ããªã¢ã«ïŒããã³20ïœ
ã®ã¡ã¿ããŒã«ãå ¥ããããã®åå¿æ··åç©ã16æé
75âã«å ç±ãããå·åŽåŸãå¡©é žã§é žæ§åãéã
ã¡ã¿ããŒã«ã§æŽæ»ã70âã§ç空也ç¥ããã
C27.1ïŒH2.2ïŒN1.8ïŒF50.5ïŒS8.0 å®æž¬å€ C27.2ïŒH2.2ïŒN1.3ïŒF52.3ïŒS7.5 å®æœäŸ ïŒ C10F21CH2CH2SCH2CHOHCH2 NH
ïŒCH2CO2HïŒCH2CO2 50mlã®ãã©ã¹ã³ã«ïŒâïŒïŒïŒïŒïŒïŒïŒïŒâãã
ã©ããããã«ãã«ãªããã«ã³ããªïŒâïŒïŒïŒâãš
ããã·ãããã³ïŒ6.30ïœïŒ10ããªã¢ã«ïŒãã€ãã
äºé ¢é žïŒ2.93ïœïŒ15ããªã¢ã«ïŒã25ïŒ æ°Žé žåãã
ãªãŠã 氎溶液ïŒ3.20ïœïŒ20ããªã¢ã«ïŒããã³20ïœ
ã®ã¡ã¿ããŒã«ãå ¥ããããã®åå¿æ··åç©ã16æé
75âã«å ç±ãããå·åŽåŸãå¡©é žã§é žæ§åãéã
ã¡ã¿ããŒã«ã§æŽæ»ã70âã§ç空也ç¥ããã
åæïŒC19H16F21NO5SãšããŠèšç®ïŒ C29.7ïŒH2.1
枬å®å€ C28.7ïŒH2.1
ïŒçªçŽ åæã¯äžèŽããªãã€ãïŒ
1HâNMRâã¹ãã¯ãã«ã¯äžèšã®ååç©ã®äºæ³
æ§é ãšäžèŽããã
æ§é ãšäžèŽããã
ÎŽ2.35ïŒ2HãïœïŒCF2CH2ïŒÎŽ2.72ïŒ4HãïœïŒ
CF2CH2CH2SCH2ïŒ ÎŽ3.36ïŒ2HãïŒNHCH2CO2 ïŒÎŽ3.43ïŒ2Hã
ïŒNHCH2CO2HïŒ ÎŽ3.49ïŒ2HïŒCHOHCH2NHïŒÎŽ3.27ïŒ1Hã
QuintetïŒCHOH å®æœäŸ ïŒ C10F12CH2CH2SCH2CHOHCH2 NH2CH
ïŒCO2HïŒCH2CO2 50mlã®ãã©ã¹ã³ã«ïŒâïŒïŒïŒïŒïŒïŒïŒïŒâãã
ã©ããããã«ãã«ãªãããã«ã³ããªïŒâïŒïŒïŒâ
ãšããã·ãããã³ïŒ6.30ïœïŒ10ããªã¢ã«ïŒãã¢ã¹
ãã©ã®ã³é žïŒ2.0ïœïŒ15ããªã¢ã«ïŒã25ïŒ æ°Žé žåã
ããªãŠã 氎溶液ïŒ3.2ïœïŒ20ããªã¢ã«ïŒããã³20
ïœã®ã¡ã¿ããŒã«ãå ¥ããããã®åå¿æ··åç©ã16æ
éã75âã«å ç±ãããå·åŽåŸãå¡©é žã§é žæ§åãã
éããïŒâ10âã«å·åŽããåéåŸä¹Ÿç¥ããã
CF2CH2CH2SCH2ïŒ ÎŽ3.36ïŒ2HãïŒNHCH2CO2 ïŒÎŽ3.43ïŒ2Hã
ïŒNHCH2CO2HïŒ ÎŽ3.49ïŒ2HïŒCHOHCH2NHïŒÎŽ3.27ïŒ1Hã
QuintetïŒCHOH å®æœäŸ ïŒ C10F12CH2CH2SCH2CHOHCH2 NH2CH
ïŒCO2HïŒCH2CO2 50mlã®ãã©ã¹ã³ã«ïŒâïŒïŒïŒïŒïŒïŒïŒïŒâãã
ã©ããããã«ãã«ãªãããã«ã³ããªïŒâïŒïŒïŒâ
ãšããã·ãããã³ïŒ6.30ïœïŒ10ããªã¢ã«ïŒãã¢ã¹
ãã©ã®ã³é žïŒ2.0ïœïŒ15ããªã¢ã«ïŒã25ïŒ æ°Žé žåã
ããªãŠã 氎溶液ïŒ3.2ïœïŒ20ããªã¢ã«ïŒããã³20
ïœã®ã¡ã¿ããŒã«ãå ¥ããããã®åå¿æ··åç©ã16æ
éã75âã«å ç±ãããå·åŽåŸãå¡©é žã§é žæ§åãã
éããïŒâ10âã«å·åŽããåéåŸä¹Ÿç¥ããã
åæïŒC19H16F21NO5SãšããŠèšç®
C29.7ïŒH2.1ïŒN1.8 å®æž¬å€ C28.7ïŒH1.8ïŒN1.1 1HâNMRâã¹ãã¯ãã«ã¯äžèšååç©ã®äºæ³æ§
é ãšäžèŽããã
C29.7ïŒH2.1ïŒN1.8 å®æž¬å€ C28.7ïŒH1.8ïŒN1.1 1HâNMRâã¹ãã¯ãã«ã¯äžèšååç©ã®äºæ³æ§
é ãšäžèŽããã
ÎŽ2.34ïŒ2HãïœïŒCF2CH2ïŒÎŽ2.71ïŒ6HãïœïŒCH3
ââCH2ãCH3CO2HïŒ ÎŽ3.53ïŒ5HãïœïŒCH2â âCH2ãCHOH.
ââCH2ãCH3CO2HïŒ ÎŽ3.53ïŒ5HãïœïŒCH2â âCH2ãCHOH.
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ äžè¬åŒ(1) ïŒåŒäžãRfã¯ïŒãªãã12åã®ççŽ ååãæãã
ãã«ãã«ãªãã¢ã«ãã«åºãŸãã¯ïŒãªããïŒåã®ç
çŽ ååãæãããã«ãã«ãªãã¢ã«ã³ãã·åºã«ãã€
ãŠçœ®æããã該ãã«ãã«ãªãã¢ã«ãã«åºã§ããã
R1ã¯ïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã¬
ã³åºãïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã¬
ã³ããªã¢ã«ãã¬ã³åºãïŒãªããïŒåã®ççŽ ååã
æããã¢ã«ãã¬ã³ãªãã·ã¢ã«ãã¬ã³åºããŸãã¯çª
çŽ ååãæ°ŽçŽ ãããã¯äœçŽã¢ã«ãã«åºã第ïŒçœ®æ
åºãšããŠä¿æããïŒãªããïŒåã®ççŽ ååãæã
ãã¢ã«ãã¬ã³ã€ããã¢ã«ãã¬ã³åºã§ãããR2ã
ãã³R3ã¯ç¬ç«ããŠæ°ŽçŽ ããŸãã¯äœçŽã¢ã«ã³ãã·
åºãããã¯ããã²ã³ã«ãã€ãŠçœ®æãããŠãããäœ
çŽã¢ã«ãã«åºãïŒãããã¯ïŒåã®ççŽ ååãæã
ãã·ã¯ãã¢ã«ãã«åºãŸãã¯ïŒåãŸã§ã®ççŽ ååã
æããã¢ã«ã±ãã«åºã§ãããããããã¯R2ãã
ã³R3ã¯äžç·ã«ãªã€ãŠç¡«é»ãŸãã¯é žçŽ ååãæã
ãŠãããïŒåãŸã§ã®ççŽ ååãæããã¢ã«ãã¬ã³
åºã§ãããR4ããã³R5ã¯ç¬ç«ããŠæ°ŽçŽ ãããã
ã¯ã«ã«ããã·åºãã¹ã«ããªåºãã¹ã«ãã¢ãåºãã
ãªã¹ããªãåºãŸãã¯ããªã¹ããªãåºã«ãã€ãŠçœ®æ
ãããŠãããïŒãªãã12åã®ççŽ ååãæããã¢
ã«ãã«åºãŸãã¯ããšãã«åºã§ãããã¯ïŒãªãã
12åã®ççŽ ååãæããã¢ã«ãã¬ã³åºã§ããã
ã¯ã«ã«ããã·åºãã¹ã«ããªåºãã¹ã«ãã¢ãåºãã
ãªã¹ããªãåºãããªã¹ããªãåºãŸãã¯ããªã¹ã«ã
ã¢ãåºã§ããïŒ ã§ç€ºããããã«ãã«ãªãã¢ã«ãã«ããªã¢ã«ãã¬ã³
äž¡æ§ååç©ãããã³åèšäžè¬åŒ(1)ã®ååç©ã®é žä»
å ç©ãã¢ã«ã«ãªå¡©ããŸãã¯ïŒ®âäœçŽã¢ã«ãã«ãã
ãã¯ïŒ®âãã³ãžã«ç¬¬åçŽã¢ã³ã¢ããŠã å¡©ã ïŒ RfãïŒãªãã12åã®ççŽ ååãæãããã«
ãã«ãªãã¢ã«ãã«åºãããã¯ïŒãªããïŒåã®ççŽ
ååãæãããã«ãã«ãªãã¢ã«ã³ãã·åºã«ãã€ãŠ
眮æããã該ãã«ãã«ãªãã¢ã«ãã«åºã§ããã
R1ãïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã¬
ã³åºãïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã¬
ã³ããªã¢ã«ãã¬ã³åºãïŒãªããïŒåã®ççŽ ååã
æããã¢ã«ãã¬ã³ãªãã·ã¢ã«ãã¬ã³åºããããã¯
çªçŽ ååãæ°ŽçŽ ãŸãã¯ïŒãªããïŒåã®ççŽ ååã
æããã¢ã«ãã«åºã第ïŒçœ®æåºãšããŠä¿æããïŒ
ãªããïŒåã®ççŽ ååãæããã¢ã«ãã¬ã³ã€ãã
ã¢ã«ãã¬ã³åºã§ãããR2ããã³R3ãæ°ŽçŽ ã§ããã
R4ããã³R5ãæ°ŽçŽ ãã¡ãã«åºããŸãã¯ã«ã«ãã
ã·åºã«ãã€ãŠçœ®æãããã¢ã«ãã«åºã§ãããã¯
ïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã¬ã³åºã§
ãããã¯ã«ã«ããã·åºãŸãã¯ã¹ã«ããªåºã§ãã
äžè¬åŒ(1)ã®ååç©ãããã³è©²äžè¬åŒ(1)ã®ååç©ã®
é žä»å ç©ãã¢ã«ã«ãªå¡©ããŸãã¯ïŒ®âäœçŽã¢ã«ãã«
第åçŽã¢ã³ã¢ããŠã å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒ
é èšèŒã®ååç©ã ïŒ RfãïŒãªãã12åã®ççŽ ååãæãããã«
ãã«ãªãã¢ã«ãã«åºã§ãããR1ãïŒãªããïŒå
ã®ççŽ ååãæããã¢ã«ãã¬ã³åºã§ãããR2ã
ãã³R3ãæ°ŽçŽ ã§ãããR4ããã³R5ãæ°ŽçŽ ãã¡ã
ã«åºããããã¯ã«ã«ããã·åºã«ãã€ãŠçœ®æããã
äœçŽã¢ã«ãã«åºã§ãããã¯ïŒãªããïŒåã®ççŽ
ååãæããã¢ã«ãã¬ã³åºã§ãããã¯ã«ã«ãã
ã·åºãŸãã¯ã¹ã«ããªåºã§ããäžè¬åŒ(1)ã®ååç©ã
ããã³äžè¬åŒ(1)ã®ååç©ã®é žä»å ç©ãã¢ã«ã«ãª
å¡©ããŸãã¯ïŒ®âäœçŽã¢ã«ãã«ç¬¬åçŽã¢ã³ã¢ããŠã
å¡©ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ååç©ã ïŒ äžè¬åŒ(2) ã®ååç©ãšäžè¬åŒ(3) NR4R5Z (3) ã®ååç©ã ïŒåŒäžãRfã¯ïŒãªãã12åã®ççŽ ååãæãã
ãã«ãã«ãªãã¢ã«ãã«åºãŸãã¯ïŒãªããïŒåã®ç
çŽ ååãæãããã«ãã«ãªãã¢ã«ã³ãã·åºã«ãã€
ãŠçœ®æããã該ãã«ãã«ãªãã¢ã«ãã«åºã§ããã
R1ã¯ïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã¬
ã³åºãïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã¬
ã³ããªã¢ã«ãã¬ã³åºãïŒãªããïŒåã®ççŽ ååã
æããã¢ã«ãã¬ã³ãªãã·ã¢ã«ãã¬ã³åºããŸãã¯çª
çŽ ååãæ°ŽçŽ ãããã¯äœçŽã¢ã«ãã«åºã第ïŒçœ®æ
åºãšããŠä¿æããïŒãªããïŒåã®ççŽ ååãæã
ãã¢ã«ãã¬ã³ã€ããã¢ã«ãã¬ã³åºã§ãããR2ã
ãã³R3ã¯ç¬ç«ããŠæ°ŽçŽ ããŸãã¯äœçŽã¢ã«ã³ãã·
åºãããã¯ããã²ã³ã«ãã€ãŠçœ®æãããŠãããäœ
çŽã¢ã«ãã«åºãïŒãããã¯ïŒåã®ççŽ ååãæã
ãã·ã¯ãã¢ã«ãã«åºãŸãã¯ïŒåãŸã§ã®ççŽ ååã
æããã¢ã«ã±ãã«åºã§ãããããããã¯R2ãã
ã³R3ã¯äžç·ã«ãªã€ãŠç¡«é»ãŸãã¯é žçŽ ååãæã
ãŠãããïŒåãŸã§ã®ççŽ ååãæããã¢ã«ãã¬ã³
åºã§ãããR4ããã³R5ã¯ç¬ç«ããŠæ°ŽçŽ ãããã
ã¯ã«ã«ããã·åºãã¹ã«ããªåºãã¹ã«ãã¢ãåºãã
ãªã¹ããªãåºãŸãã¯ããªã¹ããªãåºã«ãã€ãŠçœ®æ
ãããŠãããïŒãªãã12åã®ççŽ ååãæããã¢
ã«ãã«åºãŸãã¯ããšãã«åºã§ãããã¯ïŒãªãã
12åã®ççŽ ååãæããã¢ã«ãã¬ã³åºã§ããã
ã¯ã«ã«ããã·åºãã¹ã«ããªåºãã¹ã«ãã¢ãåºãã
ãªã¹ããªãåºãããªã¹ããªãåºãŸãã¯ããªã¹ã«ã
ã¢ãåºã§ããïŒ æ°Žæ§åªè³ªæ··åç©äžã§ãææã«ããå¡©åºã®ååšäž
ã§ãåå¿ãããããšãç¹åŸŽãšããäžè¬åŒ(1) ïŒåŒäžãRfã¯ïŒãªãã12åã®ççŽ ååãæãã
ãã«ãã«ãªãã¢ã«ãã«åºãŸãã¯ïŒãªããïŒåã®ç
çŽ ååãæãããã«ãã«ãªãã¢ã«ã³ãã·åºã«ãã€
ãŠçœ®æããã該ãã«ãã«ãªãã¢ã«ãã«åºã§ããã
R1ã¯ïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã¬
ã³åºãïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã¬
ã³ããªã¢ã«ãã¬ã³åºãïŒãªããïŒåã®ççŽ ååã
æããã¢ã«ãã¬ã³ãªãã·ã¢ã«ãã¬ã³åºããŸãã¯çª
çŽ ååãæ°ŽçŽ ãããã¯äœçŽã¢ã«ãã«åºã第ïŒçœ®æ
åºãšããŠä¿æããïŒãªããïŒåã®ççŽ ååãæã
ãã¢ã«ãã¬ã³ã€ããã¢ã«ãã¬ã³åºã§ãããR2ã
ãã³R3ã¯ç¬ç«ããŠæ°ŽçŽ ããŸãã¯äœçŽã¢ã«ã³ãã·
åºãããã¯ããã²ã³ã«ãã€ãŠçœ®æãããŠãããäœ
çŽã¢ã«ãã«åºãïŒãããã¯ïŒåã®ççŽ ååãæã
ãã·ã¯ãã¢ã«ãã«åºãŸãã¯ïŒåãŸã§ã®ççŽ ååã
æããã¢ã«ã±ãã«åºã§ãããããããã¯R2ãã
ã³R3ã¯äžç·ã«ãªã€ãŠç¡«é»ãŸãã¯é žçŽ ååãæã
ãŠãããïŒåãŸã§ã®ççŽ ååãæããã¢ã«ãã¬ã³
åºã§ãããR4ããã³R5ã¯ç¬ç«ããŠæ°ŽçŽ ãããã
ã¯ã«ã«ããã·åºãã¹ã«ããªåºãã¹ã«ãã¢ãåºãã
ãªã¹ããªãåºãŸãã¯ããªã¹ããªãåºã«ãã€ãŠçœ®æ
ãããŠãããïŒãªãã12åã®ççŽ ååãæããã¢
ã«ãã«åºãŸãã¯ããšãã«åºã§ãããã¯ïŒãªãã
12åã®ççŽ ååãæããã¢ã«ãã¬ã³åºã§ããã
ã¯ã«ã«ããã·åºãã¹ã«ããªåºãã¹ã«ãã¢ãåºãã
ãªã¹ããªãåºãããªã¹ããªãåºãŸãã¯ããªã¹ã«ã
ã¢ãåºã§ããïŒ ã®ååç©ã®è£œé æ¹æ³ã ïŒ äžè¬åŒ(1) ïŒåŒäžãRfã¯ïŒãªãã12åã®ççŽ ååãæãã
ãã«ãã«ãªãã¢ã«ãã«åºãŸãã¯ïŒãªããïŒåã®ç
çŽ ååãæãããã«ãã«ãªãã¢ã«ã³ãã·åºã«ãã€
ãŠçœ®æããã該ãã«ãã«ãªãã¢ã«ãã«åºã§ããã
R1ã¯ïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã¬
ã³åºãïŒãªããïŒåã®ççŽ ååãæããã¢ã«ãã¬
ã³ããªã¢ã«ãã¬ã³åºãïŒãªããïŒåã®ççŽ ååã
æããã¢ã«ãã¬ã³ãªãã·ã¢ã«ãã¬ã³åºããŸãã¯çª
çŽ ååãæ°ŽçŽ ãããã¯äœçŽã¢ã«ãã«åºã第ïŒçœ®æ
åºãšããŠä¿æããïŒãªããïŒåã®ççŽ ååãæã
ãã¢ã«ãã¬ã³ã€ããã¢ã«ãã¬ã³åºã§ãããR2ã
ãã³R3ã¯ç¬ç«ããŠæ°ŽçŽ ããŸãã¯äœçŽã¢ã«ã³ãã·
åºãããã¯ããã²ã³ã«ãã€ãŠçœ®æãããŠãããäœ
çŽã¢ã«ãã«åºãïŒãããã¯ïŒåã®ççŽ ååãæã
ãã·ã¯ãã¢ã«ãã«åºãŸãã¯ïŒåãŸã§ã®ççŽ ååã
æããã¢ã«ã±ãã«åºã§ãããããããã¯R2ãã
ã³R3ã¯äžç·ã«ãªã€ãŠç¡«é»ãŸãã¯é žçŽ ååãæã
ãŠãããïŒåãŸã§ã®ççŽ ååãæããã¢ã«ãã¬ã³
åºã§ãããR4ããã³R5ã¯ç¬ç«ããŠæ°ŽçŽ ãããã
ã¯ã«ã«ããã·åºãã¹ã«ããªåºãã¹ã«ãã¢ãåºãã
ãªã¹ããªãåºãŸãã¯ããªã¹ããªãåºã«ãã€ãŠçœ®æ
ãããŠãããïŒãªãã12åã®ççŽ ååãæããã¢
ã«ãã«åºãŸãã¯ããšãã«åºã§ãããã¯ïŒãªãã
12åã®ççŽ ååãæããã¢ã«ãã¬ã³åºã§ããã
ã¯ã«ã«ããã·åºãã¹ã«ããªåºãã¹ã«ãã¢ãåºãã
ãªã¹ããªãåºãããªã¹ããªãåºãŸãã¯ããªã¹ã«ã
ã¢ãåºã§ããïŒ ã®çé¢æŽ»æ§å€ãŸãã¯æ¹¿æœ€å€ãšããŠäœ¿çšããæ¹æ³ã
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/454,211 US4490304A (en) | 1982-12-29 | 1982-12-29 | Perfluoroalkyl thioalkylene amphoteric compounds |
| US454211 | 1982-12-29 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59130858A JPS59130858A (ja) | 1984-07-27 |
| JPH0364497B2 true JPH0364497B2 (ja) | 1991-10-07 |
Family
ID=23803750
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58245012A Granted JPS59130858A (ja) | 1982-12-29 | 1983-12-27 | ãã«ãã«ãªãã¢ã«ãã«äž¡æ§ååç© |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4490304A (ja) |
| EP (1) | EP0115251B1 (ja) |
| JP (1) | JPS59130858A (ja) |
| CA (1) | CA1206482A (ja) |
| DE (1) | DE3363552D1 (ja) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2002331258A1 (en) * | 2001-07-25 | 2003-02-17 | Ciba Specialty Chemicals Holding Inc. | Perfluoroalkyl-substituted amines, acids, amino acids and thioether acids |
| CN100357017C (zh) * | 2004-10-15 | 2007-12-26 | åäº¬å€§åŠ | äžç§å€é åè¡šé¢æŽ»æ§ååå ¶å¶å€æ¹æ³äžåºçš |
| CN1323747C (zh) * | 2005-03-18 | 2007-07-04 | äžæµ·çæ£ç§ææéå ¬åž | äžç§å šæ°äž€æ§è¡šé¢æŽ»æ§åçåææ¹æ³åå ¶çšé |
| US7553985B2 (en) * | 2005-11-02 | 2009-06-30 | E.I. Du Pont De Nemours And Company | Fluorinated surfactants |
| US8153846B2 (en) * | 2007-12-03 | 2012-04-10 | E.I. Du Pont De Nemours And Company | Sulfur containing fluoroalkyl amines and isocyanates |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2018461A1 (de) * | 1969-05-20 | 1971-11-04 | Walter Bloechl | Fluoralkyldi- und -polyamine mit grenzflÀchenaktiven Eigenschaften, uhre Herstellung und Anwendung |
| US3948887A (en) * | 1972-08-25 | 1976-04-06 | Pennwalt Corporation | Fluorine and sulfur-containing compositions |
| US4126633A (en) * | 1973-09-12 | 1978-11-21 | Pennwalt Corporation | Fluorinated aliphatic sulfides |
| US4098811A (en) * | 1976-12-02 | 1978-07-04 | Ciba-Geigy Corporation | Perfluoroalkylthioamido amine and ammonium compounds |
| US4102916A (en) * | 1976-12-02 | 1978-07-25 | Ciba-Geigy Corporation | Perfluoroalkylthioaminimide derivatives |
-
1982
- 1982-12-29 US US06/454,211 patent/US4490304A/en not_active Expired - Fee Related
-
1983
- 1983-12-22 DE DE8383810609T patent/DE3363552D1/de not_active Expired
- 1983-12-22 EP EP83810609A patent/EP0115251B1/en not_active Expired
- 1983-12-23 CA CA000444243A patent/CA1206482A/en not_active Expired
- 1983-12-27 JP JP58245012A patent/JPS59130858A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| CA1206482A (en) | 1986-06-24 |
| US4490304A (en) | 1984-12-25 |
| EP0115251A1 (en) | 1984-08-08 |
| EP0115251B1 (en) | 1986-05-14 |
| JPS59130858A (ja) | 1984-07-27 |
| DE3363552D1 (en) | 1986-06-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1535260B (zh) | å šæ°ç·åºå代çèºãé žãæ°šåºé žåç¡«éé ž | |
| US8796489B2 (en) | Ketobenzofuran derivatives, method for synthesizing same, and intermediates | |
| JPS6221778B2 (ja) | ||
| JPH0364497B2 (ja) | ||
| US7199258B2 (en) | Process for preparing nitrooxyderivatives of naproxen | |
| US4431595A (en) | Fluorine-containing aminosulfonate | |
| US4429162A (en) | Perfluoroalkyl phenols and naphthols | |
| JPH03169839A (ja) | 第åã¢ã³ã¢ããŠã ååç©ã®è£œé æ¹æ³ | |
| CA1280443C (fr) | Composes polyfluoroalkylthio-methyliques, leurs procedes de preparation et leurs applications comme agents tensio-actifs ou precurseurs de ces derniers | |
| JPH0480898B2 (ja) | ||
| EP0073863A1 (en) | Fluorine-containing aminosulfonate | |
| CA2033312A1 (en) | Surface-active compounds having a perfluoroalkyl group and a nitrogen-containing aliphatic radical, a process for their preparation and their use | |
| JPS6089458A (ja) | äž¡æ§çé¢æŽ»æ§ãã¿ã€ã³ååç©ããã³ãã®è£œæ³ | |
| WO2002053518A2 (en) | HALOGENATED-α,β-UNSATURATED-β-(SUBSTITUTED-AMINO) CARBOXYLATE ESTERS | |
| JPH0157160B2 (ja) | ||
| JPS6233222B2 (ja) | ||
| JPH0250900B2 (ja) | ||
| JP3747483B2 (ja) | ã·ã¯ãããããã³ã¢ã»ã¿ãŒã«èªå°äœ | |
| JPH039099B2 (ja) | ||
| JP2538335B2 (ja) | è³éŠæã¢ãã³é¡ã®è£œæ³ | |
| JPH09316426A (ja) | ã¢ã¹ãã©ã®ã³é žèªå°äœåã³ãããäž»æåãšãããã¬ãŒãå€ | |
| JPS6042234B2 (ja) | å«ããçŽ ååç©ã®è£œé æ³ | |
| JPH11322668A (ja) | ïŒïŒïŒââããããã«âïŒïŒïŒââãžã«ã«ãã³é žã®å åŠåå²æ¹æ³ | |
| JPH07157457A (ja) | ã¢ã³ãã©ãã«é žèªå°äœ | |
| JPH0317053A (ja) | ã¢ã«ãã«ã¢ããã®è£œé æ¹æ³ |