JPH0379700B2 - - Google Patents
Info
- Publication number
- JPH0379700B2 JPH0379700B2 JP58211668A JP21166883A JPH0379700B2 JP H0379700 B2 JPH0379700 B2 JP H0379700B2 JP 58211668 A JP58211668 A JP 58211668A JP 21166883 A JP21166883 A JP 21166883A JP H0379700 B2 JPH0379700 B2 JP H0379700B2
- Authority
- JP
- Japan
- Prior art keywords
- compound
- dye
- layer
- silver halide
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001875 compounds Chemical class 0.000 claims description 165
- 239000000975 dye Substances 0.000 claims description 110
- -1 silver halide Chemical class 0.000 claims description 106
- 229910052709 silver Inorganic materials 0.000 claims description 79
- 239000004332 silver Substances 0.000 claims description 79
- 239000000839 emulsion Substances 0.000 claims description 63
- 239000000463 material Substances 0.000 claims description 58
- 239000000203 mixture Substances 0.000 claims description 46
- 238000012545 processing Methods 0.000 claims description 42
- 239000007864 aqueous solution Substances 0.000 claims description 15
- 125000003118 aryl group Chemical group 0.000 claims description 14
- 239000000084 colloidal system Substances 0.000 claims description 14
- 125000000217 alkyl group Chemical group 0.000 claims description 13
- 239000001257 hydrogen Substances 0.000 claims description 13
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- 230000002829 reductive effect Effects 0.000 claims description 11
- 125000001424 substituent group Chemical group 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 8
- 150000002431 hydrogen Chemical class 0.000 claims description 6
- 239000000049 pigment Substances 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 239000001043 yellow dye Substances 0.000 claims description 5
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 4
- 238000009877 rendering Methods 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 125000005036 alkoxyphenyl group Chemical group 0.000 claims description 2
- 125000004122 cyclic group Chemical group 0.000 claims 2
- 239000010410 layer Substances 0.000 description 121
- 108010010803 Gelatin Proteins 0.000 description 27
- 229920000159 gelatin Polymers 0.000 description 27
- 239000008273 gelatin Substances 0.000 description 27
- 235000019322 gelatine Nutrition 0.000 description 27
- 235000011852 gelatine desserts Nutrition 0.000 description 27
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 26
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 21
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 21
- 238000009792 diffusion process Methods 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- 238000000034 method Methods 0.000 description 17
- 238000012546 transfer Methods 0.000 description 17
- 239000003795 chemical substances by application Substances 0.000 description 16
- 239000012528 membrane Substances 0.000 description 15
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 14
- 239000006185 dispersion Substances 0.000 description 13
- 239000000047 product Substances 0.000 description 13
- 239000002244 precipitate Substances 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- 238000011161 development Methods 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- 239000007788 liquid Substances 0.000 description 10
- 238000007254 oxidation reaction Methods 0.000 description 10
- 239000002243 precursor Substances 0.000 description 10
- 229910021607 Silver chloride Inorganic materials 0.000 description 9
- 229920000642 polymer Polymers 0.000 description 9
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- 239000011230 binding agent Substances 0.000 description 8
- 230000003647 oxidation Effects 0.000 description 8
- 239000011541 reaction mixture Substances 0.000 description 8
- 125000004429 atom Chemical group 0.000 description 7
- 239000010408 film Substances 0.000 description 7
- 230000007062 hydrolysis Effects 0.000 description 7
- 238000006460 hydrolysis reaction Methods 0.000 description 7
- 230000001603 reducing effect Effects 0.000 description 7
- 230000009467 reduction Effects 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 6
- CLDZVCMRASJQFO-UHFFFAOYSA-N 2,5-bis(2,4,4-trimethylpentan-2-yl)benzene-1,4-diol Chemical compound CC(C)(C)CC(C)(C)C1=CC(O)=C(C(C)(C)CC(C)(C)C)C=C1O CLDZVCMRASJQFO-UHFFFAOYSA-N 0.000 description 6
- ZZEYCGJAYIHIAZ-UHFFFAOYSA-N 4-methyl-1-phenylpyrazolidin-3-one Chemical compound N1C(=O)C(C)CN1C1=CC=CC=C1 ZZEYCGJAYIHIAZ-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000012670 alkaline solution Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000011229 interlayer Substances 0.000 description 5
- 230000003287 optical effect Effects 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 150000002430 hydrocarbons Chemical group 0.000 description 4
- 238000003384 imaging method Methods 0.000 description 4
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 4
- 229940099377 nuox Drugs 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- 238000000967 suction filtration Methods 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 125000002252 acyl group Chemical group 0.000 description 3
- 125000003545 alkoxy group Chemical group 0.000 description 3
- 125000002837 carbocyclic group Chemical group 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000003638 chemical reducing agent Substances 0.000 description 3
- 239000012992 electron transfer agent Substances 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000012264 purified product Substances 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- LWEAHXKXKDCSIE-UHFFFAOYSA-M 2,3-di(propan-2-yl)naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S([O-])(=O)=O)=C(C(C)C)C(C(C)C)=CC2=C1 LWEAHXKXKDCSIE-UHFFFAOYSA-M 0.000 description 2
- SYMYWDHCQHTNJC-UHFFFAOYSA-J 3-oxobutanoate;zirconium(4+) Chemical compound [Zr+4].CC(=O)CC([O-])=O.CC(=O)CC([O-])=O.CC(=O)CC([O-])=O.CC(=O)CC([O-])=O SYMYWDHCQHTNJC-UHFFFAOYSA-J 0.000 description 2
- GVTDRUXHMYZTFF-UHFFFAOYSA-N 5,6,7,8-tetrahydronaphthalene-1,4-diol Chemical compound C1CCCC2=C1C(O)=CC=C2O GVTDRUXHMYZTFF-UHFFFAOYSA-N 0.000 description 2
- LZODMDMDIZUSHT-UHFFFAOYSA-N 5,8-dihydronaphthalene-1,4-diol Chemical compound C1C=CCC2=C1C(O)=CC=C2O LZODMDMDIZUSHT-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 241001274216 Naso Species 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- 239000007868 Raney catalyst Substances 0.000 description 2
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 2
- 229910000564 Raney nickel Inorganic materials 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 description 2
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N benzo-alpha-pyrone Natural products C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 235000001671 coumarin Nutrition 0.000 description 2
- 125000000332 coumarinyl group Chemical class O1C(=O)C(=CC2=CC=CC=C12)* 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 230000000269 nucleophilic effect Effects 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- NDGRWYRVNANFNB-UHFFFAOYSA-N pyrazolidin-3-one Chemical class O=C1CCNN1 NDGRWYRVNANFNB-UHFFFAOYSA-N 0.000 description 2
- 150000004053 quinones Chemical class 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- JRQGFDPXVPTSJU-UHFFFAOYSA-L sodium zirconium(4+) sulfate Chemical compound [Na+].[Zr+4].[O-]S([O-])(=O)=O JRQGFDPXVPTSJU-UHFFFAOYSA-L 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- 150000001629 stilbenes Chemical class 0.000 description 2
- 235000021286 stilbenes Nutrition 0.000 description 2
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 1
- FYADHXFMURLYQI-UHFFFAOYSA-N 1,2,4-triazine Chemical compound C1=CN=NC=N1 FYADHXFMURLYQI-UHFFFAOYSA-N 0.000 description 1
- 150000005206 1,2-dihydroxybenzenes Chemical class 0.000 description 1
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
- DRAHKUIKRMIVIC-UHFFFAOYSA-N 1-(1,4-dihydroxy-5,6,7,8-tetrahydronaphthalen-2-yl)ethanone Chemical compound C1CCCC2=C(O)C(C(=O)C)=CC(O)=C21 DRAHKUIKRMIVIC-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
- JVZZUPJFERSVRN-UHFFFAOYSA-N 2-methyl-2-propylpropane-1,3-diol Chemical compound CCCC(C)(CO)CO JVZZUPJFERSVRN-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- SEBPXHSZHLFWRL-UHFFFAOYSA-N 3,4-dihydro-2,2,5,7,8-pentamethyl-2h-1-benzopyran-6-ol Chemical compound O1C(C)(C)CCC2=C1C(C)=C(C)C(O)=C2C SEBPXHSZHLFWRL-UHFFFAOYSA-N 0.000 description 1
- MWVTWFVJZLCBMC-UHFFFAOYSA-N 4,4'-bipyridine Chemical class C1=NC=CC(C=2C=CN=CC=2)=C1 MWVTWFVJZLCBMC-UHFFFAOYSA-N 0.000 description 1
- KFDVPJUYSDEJTH-UHFFFAOYSA-N 4-ethenylpyridine Chemical compound C=CC1=CC=NC=C1 KFDVPJUYSDEJTH-UHFFFAOYSA-N 0.000 description 1
- 241001479434 Agfa Species 0.000 description 1
- RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Natural products C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
- JGLMVXWAHNTPRF-CMDGGOBGSA-N CCN1N=C(C)C=C1C(=O)NC1=NC2=CC(=CC(OC)=C2N1C\C=C\CN1C(NC(=O)C2=CC(C)=NN2CC)=NC2=CC(=CC(OCCCN3CCOCC3)=C12)C(N)=O)C(N)=O Chemical compound CCN1N=C(C)C=C1C(=O)NC1=NC2=CC(=CC(OC)=C2N1C\C=C\CN1C(NC(=O)C2=CC(C)=NN2CC)=NC2=CC(=CC(OCCCN3CCOCC3)=C12)C(N)=O)C(N)=O JGLMVXWAHNTPRF-CMDGGOBGSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- IEIREBQISNYNTN-UHFFFAOYSA-K [Ag](I)(Br)Cl Chemical compound [Ag](I)(Br)Cl IEIREBQISNYNTN-UHFFFAOYSA-K 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000004442 acylamino group Chemical group 0.000 description 1
- 230000010933 acylation Effects 0.000 description 1
- 238000005917 acylation reaction Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- HFVAFDPGUJEFBQ-UHFFFAOYSA-M alizarin red S Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=C(S([O-])(=O)=O)C(O)=C2O HFVAFDPGUJEFBQ-UHFFFAOYSA-M 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000004414 alkyl thio group Chemical group 0.000 description 1
- 238000005937 allylation reaction Methods 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- HAMNKKUPIHEESI-UHFFFAOYSA-N aminoguanidine Chemical class NNC(N)=N HAMNKKUPIHEESI-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000001000 anthraquinone dye Substances 0.000 description 1
- 125000006615 aromatic heterocyclic group Chemical group 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 125000002619 bicyclic group Chemical group 0.000 description 1
- 150000001649 bromium compounds Chemical class 0.000 description 1
- OIPQUBBCOVJSNS-UHFFFAOYSA-L bromo(iodo)silver Chemical compound Br[Ag]I OIPQUBBCOVJSNS-UHFFFAOYSA-L 0.000 description 1
- 239000000648 calcium alginate Substances 0.000 description 1
- 235000010410 calcium alginate Nutrition 0.000 description 1
- 229960002681 calcium alginate Drugs 0.000 description 1
- OKHHGHGGPDJQHR-YMOPUZKJSA-L calcium;(2s,3s,4s,5s,6r)-6-[(2r,3s,4r,5s,6r)-2-carboxy-6-[(2r,3s,4r,5s,6r)-2-carboxylato-4,5,6-trihydroxyoxan-3-yl]oxy-4,5-dihydroxyoxan-3-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylate Chemical compound [Ca+2].O[C@@H]1[C@H](O)[C@H](O)O[C@@H](C([O-])=O)[C@H]1O[C@H]1[C@@H](O)[C@@H](O)[C@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@H](O2)C([O-])=O)O)[C@H](C(O)=O)O1 OKHHGHGGPDJQHR-YMOPUZKJSA-L 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- RLGQACBPNDBWTB-UHFFFAOYSA-N cetyltrimethylammonium ion Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)C RLGQACBPNDBWTB-UHFFFAOYSA-N 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 150000001907 coumarones Chemical class 0.000 description 1
- 150000001923 cyclic compounds Chemical class 0.000 description 1
- 239000003975 dentin desensitizing agent Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
- FQKWHGOHXVHGMR-UHFFFAOYSA-N hexadecoxybenzene Chemical compound CCCCCCCCCCCCCCCCOC1=CC=CC=C1 FQKWHGOHXVHGMR-UHFFFAOYSA-N 0.000 description 1
- UXMZNEHSMYESLH-UHFFFAOYSA-M hexadecyl(triphenyl)phosphanium;bromide Chemical compound [Br-].C=1C=CC=CC=1[P+](C=1C=CC=CC=1)(CCCCCCCCCCCCCCCC)C1=CC=CC=C1 UXMZNEHSMYESLH-UHFFFAOYSA-M 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 1
- 239000011654 magnesium acetate Substances 0.000 description 1
- 235000011285 magnesium acetate Nutrition 0.000 description 1
- 229940069446 magnesium acetate Drugs 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 239000003094 microcapsule Substances 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- MXWHMTNPTTVWDM-NXOFHUPFSA-N mitoguazone Chemical class NC(N)=N\N=C(/C)\C=N\N=C(N)N MXWHMTNPTTVWDM-NXOFHUPFSA-N 0.000 description 1
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- 150000004714 phosphonium salts Chemical class 0.000 description 1
- 229920013639 polyalphaolefin Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 125000004151 quinonyl group Chemical group 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- ZHUAYNPEJFJKDC-UHFFFAOYSA-M sodium;4,7-bis(2-methylpropyl)naphthalene-2-sulfonate Chemical compound [Na+].CC(C)CC1=CC(S([O-])(=O)=O)=CC2=CC(CC(C)C)=CC=C21 ZHUAYNPEJFJKDC-UHFFFAOYSA-M 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000004173 sunset yellow FCF Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000003419 tautomerization reaction Methods 0.000 description 1
- 150000004026 tertiary sulfonium compounds Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 229960000314 zinc acetate Drugs 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C8/00—Diffusion transfer processes or agents therefor; Photosensitive materials for such processes
- G03C8/02—Photosensitive materials characterised by the image-forming section
- G03C8/08—Photosensitive materials characterised by the image-forming section the substances transferred by diffusion consisting of organic compounds
- G03C8/10—Photosensitive materials characterised by the image-forming section the substances transferred by diffusion consisting of organic compounds of dyes or their precursors
- G03C8/12—Photosensitive materials characterised by the image-forming section the substances transferred by diffusion consisting of organic compounds of dyes or their precursors characterised by the releasing mechanism
- G03C8/22—Reduction of the chromogenic substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B43/00—Preparation of azo dyes from other azo compounds
- C09B43/30—Preparation of azo dyes from other azo compounds by esterification of âCOOH or âSO3H groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Description
æ¬çºæã¯éå
ãããç¶æ
ã§å æ°Žå解æ¡ä»¶äžã«ç§»
åæ§ã®åççã«æçšãªååç©ãç¹ã«æ¡æ£è»¢ååç
æ³ã«é©ããæ¡æ£ãåŸãè²çŽ ãçæããå°ããšãäž
ã€ã®éæ¡æ£æ§ç©è³ªãšçµã¿åãããå°ããšãäžã€ã®
æå æ§ããã²ã³åéåèšé²å±€ãå«æããåçææ
ã«é¢ãããã®ã§ãããæ¡æ£è»¢ååçæ³ã¯æ°å¹Žä»¥å
ããç¥ãããŠãããäŸãã°ã¶ ããªãŒã«ã« ãã¬
ã¹ç€Ÿã®ã¯ã«ã ã¢ã€ ãžã€ã³ããœã³ããã³ã©ã«ã
ã€ãŒãžã€ã³ããœã³å ±èãã€ã¡ãŒãžã³ã° ã·ã¹ã
ã ãã«èŠçŽãããŠããã å転ååçæ³ã¯æå æ§åèšé²å±€äžã§ã®å圢æ
ãšãé£æ¥ããååå±€äžã§åã圢æããããã³ïŒã
ããã¯èšé²å±€äžã«åãšããŠååžããç©è³ªãæ®ãå°
ããšãäžã€ã®ç©è³ªãåãšããŠåèšåèšé²å±€ããæ¡
æ£ããããšã«åºã¥ããã®ã§ããã æ¡æ£è»¢åçŽ è²æ³ã«ãããŠã¯ãè²çŽ æäŸç©è³ªãã
ãã²ã³åéä¹³å€ãšçµã¿åããããçè²åã¯ãæå
ã¯éæ¡æ£æ§ã®è²çŽ æäŸç©è³ªãããã²ã³åéçŸåã«
é¢é£ããååŠåå¿ã«ããæ¡æ£åãããã¯æ¡æ£æ§ç
æç©ã«è»¢æããããšã«ãã補é ãããã移åãã
è²çŽ ãããã¯ããããŠè£œé ãããè²çŽ ãã¬ã«ãŒãµ
ãŒã¯å容局ã«æ¡æ£ããŠããã§æçµççè²åãä¿æ
ããããæ®ãã©ã®å Žåã転åãããè²çŽ åã¯åç»
ã®ããžåã§ããã®ã§ãããã²ã³åéææäžã«èšé²
ãããåããã¬ã®å Žåã«ã¯ãè²çŽ æ¡æ£è»¢åæ³ã¯å
å転ããªããšããã°ãªããªãããã®åå転ã¯ãã
ã²ã³åéã®çŸå段éã§ãããã¯æåã¯éæ¡æ£æ§ã®
è²çŽ æäŸç©è³ªããæ¡æ£åè²çŽ (a)ãåãšããŠè£œé ã
ãéã«éæã§ããã䜿çšããããã²ã³åéä¹³å€ã®
ã¿ã€ãã«ããã転åãããããžè²çŽ åã補é ãã
ã«ã¯ç°ã€ãçš®é¡ã®è²çŽ æäŸç³»ãèŠæ±ãããããã
çŽæ¥ããžããã²ã³åéä¹³å€ã䜿çšãããªãã°ãå
ç»ã«å¯ŸããŠããžåãäœãã«ã¯ãè²çŽ æäŸç³»ã¯éé²
å éšã«ãéé²å 床ã«æ£æ¯äŸããçšåºŠã«æ¡æ£æ§è²çŽ
(a)ãçæããªããã°ãªããªãããäžæ¹ãã®æ¡æ£æ§
è²çŽ ã¯é²å éšã«æŸåºãããŠã¯ãªããªããšããããš
ãå¿ èŠã§ããããã®å¿ èŠæ¡ä»¶ãæºãç³»ã®äžã«ã¯ã
äŸãã°ç±³åœç¹èš±ç¬¬3227550å·ã3443940å·ããã³
3751406å·ã«èšèŒãããæè¬æ¡æ£æ§è²çŽ æŸåº
ïŒDDRïŒååç©ããããä»ã®é©åœãªç³»ã§ã¯ãé žå
ãããšåè£ããããã®éå ãããç¶æ ã§ã¯åŠçæ¡
件ã«å®å®ã§ããè²çŽ æŸåºã¬ããã¯ã¹ïŒDRRïŒå
åç©ã䜿çšãããããã®ãããªDRRååç©ã¯çŽ
æ¥ããžã¿ã€ãã®çŸåããã²ã³åéä¹³å€ãšçµã¿åã
ããŠäœ¿çšããå Žåã«ã¯ãéæ¡æ£æ§DRRååç©ãš
é žåãããããã²ã³åéçŸå液ãšã®äº€åé žåã¯é
é²å éšã ãã«ã¢ã«ã«ãªã«äžå®å®ãªé žåçæç©ãåŸ
ã€ãŠæ¡æ£æ§è²çŽ ã®ããžåãšããŠã®ååžãçæã
ããåãšããŠåè£ããDRRååç©ã®äŸã¯ç±³åœç¹
蚱第3628952ãè±åœç¹èš±ç¬¬1405662ã西ãã€ãå ¬é
åºé¡ç¬¬2645656å·ããã³ãªãµãŒã ãžã¹ã¯ããŒãž
ã¢ãŒç¬¬12 832ïŒ1974ïŒã15157ïŒ1976ïŒã«èšèŒãããŠ
ããã ãã¬ããã²ã³åéä¹³å€ãçšããŠåå転ããã«
ã¯ãè²çŽ æäŸç³»ã¯éé²å éšã§åæ§ã«æ¡æ£æ§è²çŽ ã
çæãããããŠé²å 床ã«å¿ããŠé²å éšã§ã®è²çŽ æŸ
åºãé 次劚ããã°ãªããªããæè¬è²çŽ çºè²å€ãã
äŸãã°ç±³åœç¹èš±ç¬¬2983606å·ã«èšèŒããããã®ã
ãã®ç®çã«é©ããŠããããããã®ååç©ã¯ã¢ã«ã«
ãªæ§åŠçæµäœã«å¯æº¶ãåŸã€ãŠæ¡æ£æ§ã§ããããé²
å éšã§ã¯é žåãããããã²ã³åéçŸå液ãšã®äº€å
é žåã«ããäžæº¶æ§éæ¡æ£æ§é žåçæç©ã«å€åã
ãã ããŸäžã€ã®å転æ³ã«åŸãã°ãæè¬IHOïŒé žåã«
ããæå¶ãããå æ°Žå解ïŒååç©ã䜿çšã§ããã
IHOååç©ã¯ãã©ã¹ãåºãæ æãããããå ¥ã
ã芪氎æ§ã³ãã€ãå±€äžã§ã¯æåã¯äžåã§ãããã
ã®ååç©ã®äž»ãªç¹åŸŽã¯ãéå ãããç¶æ ã§ã¯ãé
é²å éšã§æ¡æ£æ§è²çŽ ãæŸåºããããã¢ã«ã«ãªã«äž
å®å®ã§ãããšããããšã§ãããé²å éšã§ã¯ã
IHOååç©ã¯é žåãããããã²ã³åéçŸå液ãš
亀åé žåãããããŠãã®ååç©ã®ã¢ã«ã«ãªã«å®å®
ãªããã©ã¹ãåºãäŸç¶ãšããŠä¿æãããé žåãã
ã察å¿ç©ã«å€ãããããIHOååç©ã®äŸã¯è¥¿ã
ã€ãå ¬éåºé¡ç¬¬2402900å·ã2543902å·ããã³
2654213å·ã«èšèŒãããŠããã ãããIHOååç©ã®ä»£ããšãªããã®ã¯IHRïŒé
å ã«ããå¢å ããå æ°Žå解ïŒååç©ã§ããã åèšIHRååç©ã¯ãã©ã¹ãåºãæã€èæ¡æ£å
ã§äœ¿çšãããé žåãããç¶æ ã«ããIHOååç©
ãšãã€ãŠãå·®æ¯ããªãããããã¯äžè¬çã«ãéå
ããã³å æ°Žå解ã«ããæ¡æ£æ§ã®åççã«æçšãªåº
ïŒPUGïŒãããããæŸåºãããååç©ãšãã€ãŠã
å·®æ¯ããªããIHRååç©ã¯çŽæ¥ã«ãéæ¥ã«ãé ž
åç©è³ªãäŸãã°çŸå液ã®é žåçæç©ãšã¯åå¿ããª
ãã®ã§ãé²å éšã§ã®ãã®ååç©ã®èæ¡æ£æ§ãå€ã
ãããšã¯ã§ããªããããããIHRååç©ã¯éå
æ§ååç©ãšã¯ãäŸãã°ãã¬ã«åãããã²ã³åéä¹³
å€å±€ã®éé²å éšã«æ®çããéé žåã®åççŸå液ãš
ã¯çŽæ¥ãããã¯éæ¥åå¿ã«ããåå¿ããããšãã§
ãããéå ã«ãããå æ°Žå解ã§ããååç©ãåŸã
ãããã®ååç©ããåççã«æçšãªåºã§ãããã
ããã¯ãããå«ãæ¡æ£ç§»åæ§éšåãäŸãã°è²çŽ ã
ããã¯è²çŽ ãã¬ã«ãŒãµãŒãéé¢ãããã®è²çŽ ãã
ãã¯è²çŽ ãã¬ã«ãŒãµãŒã¯ååå±€ã«æ¡æ£ããããšã
ã§ããããã§åºå®ãããã 奜ãŸããæ æ§ã§ã¯ãIHRååç©ã¯ãPUGæŸåº
åå¿ã«å¿ èŠãªé»åãçããé»åäŸäžååç©ïŒED
ååç©ïŒãããã¯é»åäŸäžãã¬ã«ãŒãµãŒååç©
ïŒEDPååç©ïŒãšçµã¿åãããŠäœ¿çšããããåå¿
ã®å¥œãŸããé åºãããããŸãã³ã³ãããŒã«ããã
ãã«ãEDãããã¯EDPååç©ã¯æè¬é»å移åå€
ïŒETAååç©ïŒãšæ··åããŠäœ¿çšããã®ã奜ãŸã
ããäžè¬çã«ã¯ãé»å移åå€ã¯ãé©çšããå å·¥æ¡
件ã®äžã§ã¯é»åäŸäžäœããç§ããããã²ã³åéé
å å€ã§ããååç©ã§ãã€ãŠããã®é»åäŸäžäœãã
ãã²ã³åéãçŸåã§ããªãããããã¯å®è³ªçã«çŸ
åå¹æãæããªãå Žåã«ã¯ããã®ETAååç©ã
ããã²ã³åéãçŸåããæ©èœãæãããŸãé žåã
ããETAååç©ã¯EDååç©ããé»åãåãæã
ãšããçç±ã§ãé žåãããé»åäŸäžäœã®å¯Ÿå¿ãã
äœçšååŒãæäŸããã EDååç©ã¯IHRååç©ãå«ãåããã²ã³åé
ä¹³å€å±€å ã§éæ¡æ£æ§ã®ç¶æ ã§äœ¿çšããã®ã奜ãŸã
ãããããšå察ã«ãETAååç©ã¯æ¡æ£æ§ã®ç¶æ
ã«ããçŸåå€ãšããŠäœ¿çšããã®ã奜ãŸããããã®
ããã«ããŠãå ã¥ç¬¬äžã«ãé²å ããããã²ã³åé
ã«ããETAååç©ã®åãšããŠã®é žåãå§ãŸãã
次ãã§EDååç©ããé žåãããETAååç©ãžã®
è¿ éãªé»å移åãè¡ãªããããããŠãã®EDåå
ç©ã¯å€åããªãå Žåã«ã¯æçµçã«IHRååç©ã
éå ããŠãããå æ°Žå解å¯èœãªããããŠPUGå
åç©ãæ¡æ£æ§ã®ç¶æ ã§æŸåºãããšãã颚ã«ãåå¿
ã¯ãã®æãŸããé åºã«ããããŸãåå²ãããã®ã§
ããã çºè¡ããããšãŒãããç¹èš±åºé¡ç¬¬0004399å·ã«
èšèŒãããçºæã«åŸãã°ããããã€ãååç©ã§ã
ãIHRååç©ãããã²ã³åéãšäœçšããããã«
æ¥è§Šãããç¶æ ã§å«æããã¢ã«ã«ãªééæ§ã³ãã€
ãåªäœäžã§ã¯æåã¯äžåã§ããããããã²ã³åé
çŸåå€ãšã¢ã«ã«ãªæ§ã®éå äœçšã«ãããåççã«
æçšãªç©è³ªãäŸãã°è²çŽ ãè²çŽ ãã¬ã«ãŒãµãŒãçº
è²å€ããã¶ãé²æ¢ååç©ãçŸåæå¶ååç©ããã
ã¯åçå圢æã«ãããŠæŽ»æ§ãªä»ã®çš®å±ãæ¡æ£æ§ã®
ç¶æ ã§ããããåæåé¢å¯èœã§ããããããŠåèš
ãããã€ãååç©ã次ã®äžè¬åŒ(A)ããã³(B)ã®äžã€
ã«çžåœããããã²ã³åéåçææãæäŸãããã ããã§ãïŒNuoxïŒ1ãšïŒNuoxïŒ2ïŒåäžã§ãç°ã€ãŠ
ããŠãããïŒã®åã ã¯ïŒ¯ïŒåºãããã¯HNïŒåºã®
åŠãé žåãããæ±æ žåºãè¡šãããã¯R4ãšR5ã
æã€ççŽ ååã«å¯ŸããŠé»æ°é°æ§çã§ããïŒäŸ¡ã®å
åå ãäŸãã°ã¹ã«ããªãã«åºãè¡šãããã¯ïŒºåº
ãšå ±ã«æŸåºå¯èœãªåççã«æçšãªåºãäŸãã°æ¡æ£
å¯èœãªè²çŽ åºãè¡šãããR1ãR2ããã³R3ã®åã
ã¯ã¢ãååå äŸãã°æ°ŽçŽ ãããã²ã³ååã§ããã
ãããã¯ããªååå äŸãã°ã«ãã«åºãã¢ã«ã³ãã·
åºãã¢ã·ã«åºãèèªå±ãããã¯è³éŠæã«ã«ãã³é ž
ãããã¯ã¹ã«ãã³é žããèªå°ãããã¢ã·ã«ã¢ãã
åºã§ããããããã¯R1ãšR2ã¯ãããããªã³ã°äž
ã®é£æ¥ããäœçœ®ã«ååšããå Žåã«ã¯ããã®ååã®
æ®éšãšèåãããªã³ã°ãäŸãã°ãã³ãŒã³ãªã³ã°ã
äžç·ã«ãªã€ãŠåœ¢æãããããã¯R2ãšR3ã¯äžç·ã«
ãªã€ãŠãã®ååã®æ®éšãšèåãããªã³ã°ãäŸãã°
ãã³ãŒã³ãªã³ã°ã圢æãããããŠR4ããã³R5ïŒå
äžã§ãç°ã€ãŠããŠãããïŒã®åã ã¯æ°ŽçŽ ãããã¯
眮æãããçåæ°ŽçŽ åºãå«ãçåæ°ŽçŽ åºãäŸãã°
ã¢ã«ãã«åºãè¡šããã 眮æåºR1ãR2ãR3ãR4ãããã¯R5ã®å°ãªããš
ãäžã€ã«ã¯ããã©ã¹ãåºïŒžãäŸãã°åçææã®ã¢
ã«ã«ãªééæ§å±€äžã§åèšååç©ãäžåãªãããã
ã®ã«å åãªå€§ããã®ã¢ã«ãã«åºãååšããã äžè¿°ã®ãããã€ãååç©ããåççã«æçšãªç©
質ãæŸåºããéã«åãåå¿æ©æ§ã¯ïŒã€ã®æ®µé(C)ãš
(D)ãšãããªãã ããã§ãâãã©ã¹ãâã¯ãã©ã¹ãåºãæå³ãã
PUGã¯åççã«æçšãªåºãäŸãã°è²çŽ éšåãè¡š
ããããããããã©ã¹ãåºã
åæ§ã®åççã«æçšãªååç©ãç¹ã«æ¡æ£è»¢ååç
æ³ã«é©ããæ¡æ£ãåŸãè²çŽ ãçæããå°ããšãäž
ã€ã®éæ¡æ£æ§ç©è³ªãšçµã¿åãããå°ããšãäžã€ã®
æå æ§ããã²ã³åéåèšé²å±€ãå«æããåçææ
ã«é¢ãããã®ã§ãããæ¡æ£è»¢ååçæ³ã¯æ°å¹Žä»¥å
ããç¥ãããŠãããäŸãã°ã¶ ããªãŒã«ã« ãã¬
ã¹ç€Ÿã®ã¯ã«ã ã¢ã€ ãžã€ã³ããœã³ããã³ã©ã«ã
ã€ãŒãžã€ã³ããœã³å ±èãã€ã¡ãŒãžã³ã° ã·ã¹ã
ã ãã«èŠçŽãããŠããã å転ååçæ³ã¯æå æ§åèšé²å±€äžã§ã®å圢æ
ãšãé£æ¥ããååå±€äžã§åã圢æããããã³ïŒã
ããã¯èšé²å±€äžã«åãšããŠååžããç©è³ªãæ®ãå°
ããšãäžã€ã®ç©è³ªãåãšããŠåèšåèšé²å±€ããæ¡
æ£ããããšã«åºã¥ããã®ã§ããã æ¡æ£è»¢åçŽ è²æ³ã«ãããŠã¯ãè²çŽ æäŸç©è³ªãã
ãã²ã³åéä¹³å€ãšçµã¿åããããçè²åã¯ãæå
ã¯éæ¡æ£æ§ã®è²çŽ æäŸç©è³ªãããã²ã³åéçŸåã«
é¢é£ããååŠåå¿ã«ããæ¡æ£åãããã¯æ¡æ£æ§ç
æç©ã«è»¢æããããšã«ãã補é ãããã移åãã
è²çŽ ãããã¯ããããŠè£œé ãããè²çŽ ãã¬ã«ãŒãµ
ãŒã¯å容局ã«æ¡æ£ããŠããã§æçµççè²åãä¿æ
ããããæ®ãã©ã®å Žåã転åãããè²çŽ åã¯åç»
ã®ããžåã§ããã®ã§ãããã²ã³åéææäžã«èšé²
ãããåããã¬ã®å Žåã«ã¯ãè²çŽ æ¡æ£è»¢åæ³ã¯å
å転ããªããšããã°ãªããªãããã®åå転ã¯ãã
ã²ã³åéã®çŸå段éã§ãããã¯æåã¯éæ¡æ£æ§ã®
è²çŽ æäŸç©è³ªããæ¡æ£åè²çŽ (a)ãåãšããŠè£œé ã
ãéã«éæã§ããã䜿çšããããã²ã³åéä¹³å€ã®
ã¿ã€ãã«ããã転åãããããžè²çŽ åã補é ãã
ã«ã¯ç°ã€ãçš®é¡ã®è²çŽ æäŸç³»ãèŠæ±ãããããã
çŽæ¥ããžããã²ã³åéä¹³å€ã䜿çšãããªãã°ãå
ç»ã«å¯ŸããŠããžåãäœãã«ã¯ãè²çŽ æäŸç³»ã¯éé²
å éšã«ãéé²å 床ã«æ£æ¯äŸããçšåºŠã«æ¡æ£æ§è²çŽ
(a)ãçæããªããã°ãªããªãããäžæ¹ãã®æ¡æ£æ§
è²çŽ ã¯é²å éšã«æŸåºãããŠã¯ãªããªããšããããš
ãå¿ èŠã§ããããã®å¿ èŠæ¡ä»¶ãæºãç³»ã®äžã«ã¯ã
äŸãã°ç±³åœç¹èš±ç¬¬3227550å·ã3443940å·ããã³
3751406å·ã«èšèŒãããæè¬æ¡æ£æ§è²çŽ æŸåº
ïŒDDRïŒååç©ããããä»ã®é©åœãªç³»ã§ã¯ãé žå
ãããšåè£ããããã®éå ãããç¶æ ã§ã¯åŠçæ¡
件ã«å®å®ã§ããè²çŽ æŸåºã¬ããã¯ã¹ïŒDRRïŒå
åç©ã䜿çšãããããã®ãããªDRRååç©ã¯çŽ
æ¥ããžã¿ã€ãã®çŸåããã²ã³åéä¹³å€ãšçµã¿åã
ããŠäœ¿çšããå Žåã«ã¯ãéæ¡æ£æ§DRRååç©ãš
é žåãããããã²ã³åéçŸå液ãšã®äº€åé žåã¯é
é²å éšã ãã«ã¢ã«ã«ãªã«äžå®å®ãªé žåçæç©ãåŸ
ã€ãŠæ¡æ£æ§è²çŽ ã®ããžåãšããŠã®ååžãçæã
ããåãšããŠåè£ããDRRååç©ã®äŸã¯ç±³åœç¹
蚱第3628952ãè±åœç¹èš±ç¬¬1405662ã西ãã€ãå ¬é
åºé¡ç¬¬2645656å·ããã³ãªãµãŒã ãžã¹ã¯ããŒãž
ã¢ãŒç¬¬12 832ïŒ1974ïŒã15157ïŒ1976ïŒã«èšèŒãããŠ
ããã ãã¬ããã²ã³åéä¹³å€ãçšããŠåå転ããã«
ã¯ãè²çŽ æäŸç³»ã¯éé²å éšã§åæ§ã«æ¡æ£æ§è²çŽ ã
çæãããããŠé²å 床ã«å¿ããŠé²å éšã§ã®è²çŽ æŸ
åºãé 次劚ããã°ãªããªããæè¬è²çŽ çºè²å€ãã
äŸãã°ç±³åœç¹èš±ç¬¬2983606å·ã«èšèŒããããã®ã
ãã®ç®çã«é©ããŠããããããã®ååç©ã¯ã¢ã«ã«
ãªæ§åŠçæµäœã«å¯æº¶ãåŸã€ãŠæ¡æ£æ§ã§ããããé²
å éšã§ã¯é žåãããããã²ã³åéçŸå液ãšã®äº€å
é žåã«ããäžæº¶æ§éæ¡æ£æ§é žåçæç©ã«å€åã
ãã ããŸäžã€ã®å転æ³ã«åŸãã°ãæè¬IHOïŒé žåã«
ããæå¶ãããå æ°Žå解ïŒååç©ã䜿çšã§ããã
IHOååç©ã¯ãã©ã¹ãåºãæ æãããããå ¥ã
ã芪氎æ§ã³ãã€ãå±€äžã§ã¯æåã¯äžåã§ãããã
ã®ååç©ã®äž»ãªç¹åŸŽã¯ãéå ãããç¶æ ã§ã¯ãé
é²å éšã§æ¡æ£æ§è²çŽ ãæŸåºããããã¢ã«ã«ãªã«äž
å®å®ã§ãããšããããšã§ãããé²å éšã§ã¯ã
IHOååç©ã¯é žåãããããã²ã³åéçŸå液ãš
亀åé žåãããããŠãã®ååç©ã®ã¢ã«ã«ãªã«å®å®
ãªããã©ã¹ãåºãäŸç¶ãšããŠä¿æãããé žåãã
ã察å¿ç©ã«å€ãããããIHOååç©ã®äŸã¯è¥¿ã
ã€ãå ¬éåºé¡ç¬¬2402900å·ã2543902å·ããã³
2654213å·ã«èšèŒãããŠããã ãããIHOååç©ã®ä»£ããšãªããã®ã¯IHRïŒé
å ã«ããå¢å ããå æ°Žå解ïŒååç©ã§ããã åèšIHRååç©ã¯ãã©ã¹ãåºãæã€èæ¡æ£å
ã§äœ¿çšãããé žåãããç¶æ ã«ããIHOååç©
ãšãã€ãŠãå·®æ¯ããªãããããã¯äžè¬çã«ãéå
ããã³å æ°Žå解ã«ããæ¡æ£æ§ã®åççã«æçšãªåº
ïŒPUGïŒãããããæŸåºãããååç©ãšãã€ãŠã
å·®æ¯ããªããIHRååç©ã¯çŽæ¥ã«ãéæ¥ã«ãé ž
åç©è³ªãäŸãã°çŸå液ã®é žåçæç©ãšã¯åå¿ããª
ãã®ã§ãé²å éšã§ã®ãã®ååç©ã®èæ¡æ£æ§ãå€ã
ãããšã¯ã§ããªããããããIHRååç©ã¯éå
æ§ååç©ãšã¯ãäŸãã°ãã¬ã«åãããã²ã³åéä¹³
å€å±€ã®éé²å éšã«æ®çããéé žåã®åççŸå液ãš
ã¯çŽæ¥ãããã¯éæ¥åå¿ã«ããåå¿ããããšãã§
ãããéå ã«ãããå æ°Žå解ã§ããååç©ãåŸã
ãããã®ååç©ããåççã«æçšãªåºã§ãããã
ããã¯ãããå«ãæ¡æ£ç§»åæ§éšåãäŸãã°è²çŽ ã
ããã¯è²çŽ ãã¬ã«ãŒãµãŒãéé¢ãããã®è²çŽ ãã
ãã¯è²çŽ ãã¬ã«ãŒãµãŒã¯ååå±€ã«æ¡æ£ããããšã
ã§ããããã§åºå®ãããã 奜ãŸããæ æ§ã§ã¯ãIHRååç©ã¯ãPUGæŸåº
åå¿ã«å¿ èŠãªé»åãçããé»åäŸäžååç©ïŒED
ååç©ïŒãããã¯é»åäŸäžãã¬ã«ãŒãµãŒååç©
ïŒEDPååç©ïŒãšçµã¿åãããŠäœ¿çšããããåå¿
ã®å¥œãŸããé åºãããããŸãã³ã³ãããŒã«ããã
ãã«ãEDãããã¯EDPååç©ã¯æè¬é»å移åå€
ïŒETAååç©ïŒãšæ··åããŠäœ¿çšããã®ã奜ãŸã
ããäžè¬çã«ã¯ãé»å移åå€ã¯ãé©çšããå å·¥æ¡
件ã®äžã§ã¯é»åäŸäžäœããç§ããããã²ã³åéé
å å€ã§ããååç©ã§ãã€ãŠããã®é»åäŸäžäœãã
ãã²ã³åéãçŸåã§ããªãããããã¯å®è³ªçã«çŸ
åå¹æãæããªãå Žåã«ã¯ããã®ETAååç©ã
ããã²ã³åéãçŸåããæ©èœãæãããŸãé žåã
ããETAååç©ã¯EDååç©ããé»åãåãæã
ãšããçç±ã§ãé žåãããé»åäŸäžäœã®å¯Ÿå¿ãã
äœçšååŒãæäŸããã EDååç©ã¯IHRååç©ãå«ãåããã²ã³åé
ä¹³å€å±€å ã§éæ¡æ£æ§ã®ç¶æ ã§äœ¿çšããã®ã奜ãŸã
ãããããšå察ã«ãETAååç©ã¯æ¡æ£æ§ã®ç¶æ
ã«ããçŸåå€ãšããŠäœ¿çšããã®ã奜ãŸããããã®
ããã«ããŠãå ã¥ç¬¬äžã«ãé²å ããããã²ã³åé
ã«ããETAååç©ã®åãšããŠã®é žåãå§ãŸãã
次ãã§EDååç©ããé žåãããETAååç©ãžã®
è¿ éãªé»å移åãè¡ãªããããããŠãã®EDåå
ç©ã¯å€åããªãå Žåã«ã¯æçµçã«IHRååç©ã
éå ããŠãããå æ°Žå解å¯èœãªããããŠPUGå
åç©ãæ¡æ£æ§ã®ç¶æ ã§æŸåºãããšãã颚ã«ãåå¿
ã¯ãã®æãŸããé åºã«ããããŸãåå²ãããã®ã§
ããã çºè¡ããããšãŒãããç¹èš±åºé¡ç¬¬0004399å·ã«
èšèŒãããçºæã«åŸãã°ããããã€ãååç©ã§ã
ãIHRååç©ãããã²ã³åéãšäœçšããããã«
æ¥è§Šãããç¶æ ã§å«æããã¢ã«ã«ãªééæ§ã³ãã€
ãåªäœäžã§ã¯æåã¯äžåã§ããããããã²ã³åé
çŸåå€ãšã¢ã«ã«ãªæ§ã®éå äœçšã«ãããåççã«
æçšãªç©è³ªãäŸãã°è²çŽ ãè²çŽ ãã¬ã«ãŒãµãŒãçº
è²å€ããã¶ãé²æ¢ååç©ãçŸåæå¶ååç©ããã
ã¯åçå圢æã«ãããŠæŽ»æ§ãªä»ã®çš®å±ãæ¡æ£æ§ã®
ç¶æ ã§ããããåæåé¢å¯èœã§ããããããŠåèš
ãããã€ãååç©ã次ã®äžè¬åŒ(A)ããã³(B)ã®äžã€
ã«çžåœããããã²ã³åéåçææãæäŸãããã ããã§ãïŒNuoxïŒ1ãšïŒNuoxïŒ2ïŒåäžã§ãç°ã€ãŠ
ããŠãããïŒã®åã ã¯ïŒ¯ïŒåºãããã¯HNïŒåºã®
åŠãé žåãããæ±æ žåºãè¡šãããã¯R4ãšR5ã
æã€ççŽ ååã«å¯ŸããŠé»æ°é°æ§çã§ããïŒäŸ¡ã®å
åå ãäŸãã°ã¹ã«ããªãã«åºãè¡šãããã¯ïŒºåº
ãšå ±ã«æŸåºå¯èœãªåççã«æçšãªåºãäŸãã°æ¡æ£
å¯èœãªè²çŽ åºãè¡šãããR1ãR2ããã³R3ã®åã
ã¯ã¢ãååå äŸãã°æ°ŽçŽ ãããã²ã³ååã§ããã
ãããã¯ããªååå äŸãã°ã«ãã«åºãã¢ã«ã³ãã·
åºãã¢ã·ã«åºãèèªå±ãããã¯è³éŠæã«ã«ãã³é ž
ãããã¯ã¹ã«ãã³é žããèªå°ãããã¢ã·ã«ã¢ãã
åºã§ããããããã¯R1ãšR2ã¯ãããããªã³ã°äž
ã®é£æ¥ããäœçœ®ã«ååšããå Žåã«ã¯ããã®ååã®
æ®éšãšèåãããªã³ã°ãäŸãã°ãã³ãŒã³ãªã³ã°ã
äžç·ã«ãªã€ãŠåœ¢æãããããã¯R2ãšR3ã¯äžç·ã«
ãªã€ãŠãã®ååã®æ®éšãšèåãããªã³ã°ãäŸãã°
ãã³ãŒã³ãªã³ã°ã圢æãããããŠR4ããã³R5ïŒå
äžã§ãç°ã€ãŠããŠãããïŒã®åã ã¯æ°ŽçŽ ãããã¯
眮æãããçåæ°ŽçŽ åºãå«ãçåæ°ŽçŽ åºãäŸãã°
ã¢ã«ãã«åºãè¡šããã 眮æåºR1ãR2ãR3ãR4ãããã¯R5ã®å°ãªããš
ãäžã€ã«ã¯ããã©ã¹ãåºïŒžãäŸãã°åçææã®ã¢
ã«ã«ãªééæ§å±€äžã§åèšååç©ãäžåãªãããã
ã®ã«å åãªå€§ããã®ã¢ã«ãã«åºãååšããã äžè¿°ã®ãããã€ãååç©ããåççã«æçšãªç©
質ãæŸåºããéã«åãåå¿æ©æ§ã¯ïŒã€ã®æ®µé(C)ãš
(D)ãšãããªãã ããã§ãâãã©ã¹ãâã¯ãã©ã¹ãåºãæå³ãã
PUGã¯åççã«æçšãªåºãäŸãã°è²çŽ éšåãè¡š
ããããããããã©ã¹ãåºã
ãåŒãåºã«çµåã
ãŠããå¿
èŠã¯ãªããå®éãããã³æ žäžã®ãã¥ãã®
å Žæãåæ§ã«ãæåã¯èæ¡æ£æ§ã§ãããããã€ã
ååç©ïŒïŒãåŸããšããç®çãæºè¶³ãããã äºå®ãåççã«æçšãªç©è³ªããè¿ éã§ã¯ããã
ãŸãé²å ããããã²ã³åéã®æ¿åºŠã«å®è³ªçã«éæ¯
äŸããŠåæåé¢ãããç³»ã«å¯ŸããèŠæ±ããããæ
èšããã°ããã¬ã¿ã€ãã®åãšããŠé²å ããããã²
ã³åéä¹³å€ãããããã€ãååç©ããã³çŸåå€ãš
äœçšããããã«çµã¿åãããŠå å·¥åŠçããéãå
èšæ¡æ£æ§ç©è³ªã¯ãåçã«ãšã€ãåç»ãããã¯å æ¯
ã®çœéšããªãã¡éæéšã«å¯Ÿå¿ããŠåå ¥ãã§ããªã
çšåºŠãŸã§éé¢ãããŠã¯ãªããªããããããããã§
ãç¢åŒµããçŸåå€ã¯é«æ¿åºŠã«æ®ã€ãŠããé²å ã®å°
ãªãéšåãããã¯éé²å éšåã§ã¯å åè¿ éã«éé¢
ãããªããã°ãªããªããååç©ïŒïŒã®éå å€ã«
ããéå ãååç©ïŒïŒã®å æ°Žå解ãé²å ããã
ãã²ã³åéã®éå ã«æåã€å Žåã¯ãåççã«æçš
ãªç©è³ªãããããèŠæãããªãé åã§äœãã«ã倧
éã«åæåé¢ããããåççã«æçšãªç©è³ªãè²çŽ
ã§ããå Žåã«ã¯ãæãŸãããªãè²çŽ ãã¶ããå容
ãšã¬ã¡ã³ãäžã§åŸããããããããããã€ãåå
ç©ã®éå å¯èœæ§ãããŸãäœãå Žåã«ã¯ãäŸãã°ã€
ã³ã¹ã¿ã³ãããªãã§é©çšãããã«ã¡ã©å å å·¥ã«èŠ
æ±ããã劥åœãªåŠçæéå ã§ã¯ãåå ¥ãå¯èœãªè²
çŽ å¯åºŠãåŸãããªãã æè¬ãã¶ãã®ã¬ãã«ãšãåççã«æçšãªç©è³ªã
çãåŠçæéå ã«å ååãšããŠæŸåºããããšãã
ããšãšã®éã劥åãããããã«ãããã³æ žã(a)ïŒ
䟡ã®ææ©ãªã³ã°ãããã¯è³éŠå±æ§ãæã€ãªã³ã°ç³»
眮æåºã§çŽæ¥çœ®æããããšããçºè¡ããããšãŒã
ããç¹èš±åºé¡ç¬¬0038092å·ã«ããææ¡ããããã
ã®ããã«çœ®æãããååç©ã«ãããæ¯èŒççãåŠ
çæéäŸãã°ïŒå以äžä»¥å ã§ãåççã«æçšãªç©
質ãåå ¥ããããšã®ã§ããªããããªãã¶ããç¡ã
åãšããŠæŸåºãããã ãããè³éŠæçã«çœ®æããããããã€ãååç©
ã¯äžèšäžè¬åŒ(E)ããã³(F)ã®ãã¡ã®äžã€ã«çžåœã
ãã ããã§ãïŒNuoxïŒ1ãšïŒNuoxïŒ2ïŒåäžã§ãç°ã€ãŠ
ããŠãããïŒã®åã ã¯ïŒ¯ïŒåºãããã¯HNïŒåºã®
åŠãé žåãããæ±æ žåºãè¡šãããZ1ã¯ïŒäŸ¡ã®åå
äŸãã°ââããããã¯R6ãšR7ãæã€ççŽ åå
ã«å¯ŸããŠé»æ°é°æ§çããïŒäŸ¡ã®åºäŸãã°ã¹ã«ããª
ãã«åºãè¡šãããQ1ã¯ãZ1ãšäžç·ã«ãªã€ãŠãæŸ
åºå¯èœãªåççã«æçšãªåºãäŸãã°äžè¿°ããåŠã
æ¡æ£æ§ã®åççã«æçšãªç©è³ªããã矀ãããææ£
æ§ã®è²çŽ ãçããæŸåºå¯èœãªåºãè¡šãããY1ãš
Y2ã¯äžç·ã«ãªã€ãŠã(a)çŽæ¥çµåããïŒäŸ¡ã®ææ©
ãªã³ã°ãããã¯è³éŠå±æ§ãæã€ãªã³ã°ç³»çœ®æåºã§
眮æãããïœâãããã€ããªã³ã°ãéããã®ã«å¿
èŠãªååãè¡šãããY3ã¯(a)çŽæ¥çµåããïŒäŸ¡ã®
ææ©ãªã³ã°ãããã¯è³éŠå±æ§ãæã€ãªã³ã°ç³»çœ®æ
åºã§çœ®æãããïœâãããã€ããªã³ã°ãéããã®
ã«å¿ èŠãªååãè¡šã¯ããR6ãšR7ïŒåäžã§ãç°ã€ãŠ
ããŠãããïŒã®åã ã¯æ°ŽçŽ ã眮æãããçåæ°ŽçŽ
åºãå«ãçåæ°ŽçŽ åºäŸãã°çœ®æãããã¢ã«ãã«åº
ãå«ãã¢ã«ãã«åºããããã¯çœ®æãããã¢ãªãŒã«
åºãå«ãã¢ãªãŒã«åºãè¡šããã奜ãŸããã¯ãã®ã
ã¡ã®äžã€ã¯çœ®æãããããšãã«åºãå«ãããšãã«
åºã§ããããããŠå°ããšãR6ãR7ãããã¯ãã
ãã€ããªã³ã°äžã®çœ®æåºã¯ãã©ã¹ãåºïŒžãäŸãã°
ã¢ã«ã«ãªæ§æ¶²ãåçææã®ã¢ã«ã«ãªééå±€ãéé
ããéåèšååç©ãåèšã¢ã«ã«ãªééå±€å ã§äžå
ã®ãŸãŸä¿æããã®ã«å åãªå€§ãããæã€ã¢ã«ãã«
åºã§ããããããã¯ãããå«æããã äžèšã®ããšãããããã³æ žã®é©åãªçœ®æã«ã
ããååŠåå¿æ§ããã¡ã«éå å¯èœæ§ãã³ã³ãããŒ
ã«ã§ãããšããäºã¯æãã§ãããããããéå ã
ãããããã€ãéšåããªãã¡è²çŽ éšåã«å¯ŸããŠ
âãã€ãªã¢ãŒâéšåãšããŠäœçšãããã€ãããã
ãã€ãéšåã®éå æ§ã®ã¿ãªããå æ°Žå解æ§ãè²çŽ
æŸåºã®é床ã«ãããŠåœ¹å²ãæŒããããšãå®éšçã«
確ç«ãããŠããã å æ°Žå解ã¯ããã€ãããããã€ãååç©åŸã€ãŠ
ãŸããããã€ãååç©ã®èŠªæ°Žæ§ãäœäžãããããš
ã«ããå€å°æå¶ããããšãã§ãããããã¯è²çŽ éš
åïŒã·ã¢ã³ãããžãšã³ã¿ããã³é»è²ïŒã®æ§é ã«ã
ãŸãäŸåããªãè²çŽ æŸåºã«æå©ã§ãããçºè¡ãã
ããšãŒãããç¹èš±åºé¡ç¬¬0049002å·ã®å®æœäŸïŒã
ãåŠã³åŸãåŠãããããã€ãæ žäžã®çœ®æåºã¯ãè²
çŽ éšåã®ç°ã€ãè²çŽ æŸåºååç©ã®è²çŽ æŸåºé床ã
ã§ããã ãè¯å¥œã«åãã¬ãã«ã«ç«ã¡è³ããããã çµæžçãªåŠçæéã§ãã€åäžæ倧å¯åºŠã«å¯ŸããŠ
äžé£åããªãã¶ããçããããšãªãåãå ¥ãå¯èœ
ãªæ倧è²çŽ å¯åºŠãåŸãããã«ãåäžâãã€ãªã¢
ãŒâããäžåè²åçææäžã®äžåè²è²çŽ æŸåºåå
ç©ã«äœ¿çšã§ãããªãã°ãããã¯ç¹ã«æå©ã§ããã æ¬çºæã¯ãã®ãããªææã«çšããã®ã«é©ããã
ããã€ããã€ãªã¢ãŒéšåãæã€ããããŠç¹ã«
DmaxïŒDminã®é¢ä¿ãæ¹è¯ãããIHRè²çŽ æŸåº
ååç©ãæäŸããããªãããã§Dmaxã¯æ倧è²çŽ
å¯åºŠãæå³ããDminã¯æå°è²çŽ å¯åºŠããªãã¡è²
çŽ ãã¶ããæå³ããã æ¬çºæã®ããŸäžã€ã®ç®çã¯ãã·ã¢ã³ãããžãšã³
ã¿ããã³é»è²è²çŽ åãäœãããã®ããã€ãªã¢äžéš
åãåããããç°ã€ãIHRè²çŽ æŸåºååç©ãå«
æããããã²ã³åéè²çŽ æ¡æ£è»¢ååçææãæäŸ
ããããšã§ããããã®ä»ã®ç®çããã³æå©æ§ã¯ä»¥
åŸã®èª¬æããæãã«ãªãã§ãããã æ¬çºæã«åŸãIHRè²çŽ æŸåºååç©ã¯æ¬¡ã®äžè¬
åŒ(G)ã«çžåœãããããã€ãååç©ã§ããã ããã§ãR8ã¯ãããã€ãæ žã®é£æ¥ãã飜åç°
ç¶éšåäžã®ïŒâãããã¯ïŒâäœïŒæå°ã«ãŠç€ºãïŒ
ã«ããæ°ŽçŽ ãããã¯ã¡ãã«ã§ãããR9ã¯ã¢ã«ã
ã«åºäŸãã°ïœâãããã«ããããã¯çœ®æãããã¢
ã«ãã«åºãè³éŠæåºäŸãã°ããšãã«åºããããã¯
眮æãããè³éŠæåºäŸãã°ã¢ã«ã³ãã·ããšãã«åº
ã§ããããã®ãã¡ã¢ã«ã³ãã·ããšãã«åºã奜ãŸã
ããR10ã¯æ°ŽçŽ ãã¢ã«ãã«åºäŸãã°ã¡ãã«ããã
ãã¯ã¢ãªãŒã«åºäŸãã°ããšãã«åºã§ããããããŠ
眮æåºR9ãšR10ã®å°ããšãäžã€ã¯ãã¢ã«ã«ãªæ§æ°Ž
溶液ãã¢ã«ã«ãªééæ§èŠªæ°Žæ§ã³ãã€ãå±€ãééã
ãéåèšååç©ãåèšã³ãã€ãå±€å ã§äžåãªãã
ããã®ã«å åãªå€§ããã®ãã©ã¹ãåºãäŸãã°ã¢ã«
ãã«åºãè¡šããããããã¯ãããå«æããã äžèšäžè¬åŒ(G)ã«åŸãååç©ã¯çŽæ¥è²çŽ ãæŸåºã
ãã®ã§ã¯ãªããŠããã®ããã«ã¯éå ããŠçžåœãã
ãã€ãããããã€ãååç©ãçæããªããŠã¯ãªã
ãªãããã®ååç©ã¯æ¬¡ãã§ã¢ã«ã«ãªæ§æ¡ä»¶äžã§å
æ°Žå解ã«ããåè£ãåãæããããã«ããâSO2
âè²çŽ éšåãã¹ã«ãã€ã³é žã¢ããªã³ãšããŠæ¡æ£æ§
ã®ç¶æ ã§éé¢ããã äžè¬åŒ(G)ã«åŸãååç©ã®è£œé ã«ãããŠããã€ãª
ã¢ãŒéšåã¯äŸãã°æ¬¡ã®åå¿åŒã«åŸã€ãŠãè²çŽ éšå
ãšçµåããã ããã³æ žãã®é£œåããççŽ ç°åŒèåç°ç¶éšã®å°
å ¥ã¯ããã¿ã³ãžãšã³ãããã¯ã€ãœãã¬ã³ãšããã³
ã䜿çšãããžãŒã«ã¹ãŒã¢ã«ããŒåå¿ãçµç±ããŠé²
è¡ããã å ±åœ¹ãžãšã³ãšïœâãã³ãŸããã³ãšã®ãžãŒã«ã¹ãŒ
ã¢ã«ããŒåå¿ã¯ååŠæç®ã«è©³çŽ°ã«èšèŒãããŠã
ããç¹ã«ãã¢ã³ã»ã«ãããã·ãŠãšãŠã€ã«ãœã³ã®å ±
åïŒJ.Chem.Soc.1963ïŒ3012â3028ïŒãšãšã« ãš
ã ãã€ãŒã¶ãŒã®å ±åïŒJ.Amer.Chem.Soc.70ïŒ
3165â317ïŒ1948ïŒïŒãåèã«ããããè¿œå ã®æ å ±
ã¯ããããšãªããïŒorgauic Reacticns5ã136â
192ïŒ1949ïŒïŒããã€ã³ã¬âïŒãšã¹ ãã¿ã€èThe
Chemistry of the quinonoid compoundsïŒç¬¬ïŒ
å·»ïŒ986â1018é ããŠã€ã¬ãŒç€ŸãããŠãŒãšãŒã¯ã
1974幎çºè¡ïŒããã³ãšãã ãŠã«ãªãããšã¢ãŒã«
ãªãã¿ãŒïŒããŒãã³âãŠãšã€ã«å ±è Methoden
der Orgauischen ChewieïŒç¬¬ïŒå·»ïŒ3aãã²ãŒ
ãã€ãšã¡ç€Ÿãã¹ã¿ããã¬ã«ãã1977çºè¡ã80â85
é ïŒã®ç·èª¬ã«èŠåºãããšãã§ããã äžã§å®çŸ©ããã«ã«ãããŒã«ã®åæã«ãŒããäžèš
ã«äŸç€ºããã å¥æ³ã§ã¯ãã¢ã·ã«åãšã¢ãªã«åã«å¯ŸãããžãŒã«
ã¹âã¢ã«ããŒåå¿ã®çžå¯Ÿç段éãéã«ããã ãã¥ãã®ã«ãŒãã®ãžãŒã«ã¹âã¢ã«ããŒåå¿ã«ã
ããŠãããžãšã³ãšããŠã€ãœãã¬ã³ã䜿çšãããªã
ã°ããã®åå¿ããçããçæç©ã¯äºã€ã®å¯èœæ§ã®
ããã¬ãžãªç°æ§äœããã®ãã¡äžæ¹ã¯ïŒäœã«ã¡ãã«
眮æåºãæã¡ãä»æ¹ã¯ïŒäœã«ã¡ãã«çœ®æåºãæã€
ç°æ§äœã®æ··åç©ã§ããããšã«æ³šæããªããã°ãªã
ãªããããã¯åé¢ã§ããããã©ããæ··åç©ã¯åç
çã«ã¯åé¢ãããæåãšåæ§ã«æåããã®ã§ãã
ã®ãããªããšãããå¿ èŠã¯ãªãã äžè¬åŒ(G)ã®ç¯å²å ã«ããååç©ã®åæãããã
ããã·ã¢ã³ãããžãšã³ã¿ïŒ2aïŒ2bïŒããã³é»è²
è²çŽ æŸåºååç©ã«é¢ããè¡šã2aã2bããã³ïŒ
ã®ååç©ã«ã€ããŠããã詳现ã«ããšã«äŸç€ºããã
åæã¯äžèšã®åŒã®äžã€ã«åŸãã
å Žæãåæ§ã«ãæåã¯èæ¡æ£æ§ã§ãããããã€ã
ååç©ïŒïŒãåŸããšããç®çãæºè¶³ãããã äºå®ãåççã«æçšãªç©è³ªããè¿ éã§ã¯ããã
ãŸãé²å ããããã²ã³åéã®æ¿åºŠã«å®è³ªçã«éæ¯
äŸããŠåæåé¢ãããç³»ã«å¯ŸããèŠæ±ããããæ
èšããã°ããã¬ã¿ã€ãã®åãšããŠé²å ããããã²
ã³åéä¹³å€ãããããã€ãååç©ããã³çŸåå€ãš
äœçšããããã«çµã¿åãããŠå å·¥åŠçããéãå
èšæ¡æ£æ§ç©è³ªã¯ãåçã«ãšã€ãåç»ãããã¯å æ¯
ã®çœéšããªãã¡éæéšã«å¯Ÿå¿ããŠåå ¥ãã§ããªã
çšåºŠãŸã§éé¢ãããŠã¯ãªããªããããããããã§
ãç¢åŒµããçŸåå€ã¯é«æ¿åºŠã«æ®ã€ãŠããé²å ã®å°
ãªãéšåãããã¯éé²å éšåã§ã¯å åè¿ éã«éé¢
ãããªããã°ãªããªããååç©ïŒïŒã®éå å€ã«
ããéå ãååç©ïŒïŒã®å æ°Žå解ãé²å ããã
ãã²ã³åéã®éå ã«æåã€å Žåã¯ãåççã«æçš
ãªç©è³ªãããããèŠæãããªãé åã§äœãã«ã倧
éã«åæåé¢ããããåççã«æçšãªç©è³ªãè²çŽ
ã§ããå Žåã«ã¯ãæãŸãããªãè²çŽ ãã¶ããå容
ãšã¬ã¡ã³ãäžã§åŸããããããããããã€ãåå
ç©ã®éå å¯èœæ§ãããŸãäœãå Žåã«ã¯ãäŸãã°ã€
ã³ã¹ã¿ã³ãããªãã§é©çšãããã«ã¡ã©å å å·¥ã«èŠ
æ±ããã劥åœãªåŠçæéå ã§ã¯ãåå ¥ãå¯èœãªè²
çŽ å¯åºŠãåŸãããªãã æè¬ãã¶ãã®ã¬ãã«ãšãåççã«æçšãªç©è³ªã
çãåŠçæéå ã«å ååãšããŠæŸåºããããšãã
ããšãšã®éã劥åãããããã«ãããã³æ žã(a)ïŒ
䟡ã®ææ©ãªã³ã°ãããã¯è³éŠå±æ§ãæã€ãªã³ã°ç³»
眮æåºã§çŽæ¥çœ®æããããšããçºè¡ããããšãŒã
ããç¹èš±åºé¡ç¬¬0038092å·ã«ããææ¡ããããã
ã®ããã«çœ®æãããååç©ã«ãããæ¯èŒççãåŠ
çæéäŸãã°ïŒå以äžä»¥å ã§ãåççã«æçšãªç©
質ãåå ¥ããããšã®ã§ããªããããªãã¶ããç¡ã
åãšããŠæŸåºãããã ãããè³éŠæçã«çœ®æããããããã€ãååç©
ã¯äžèšäžè¬åŒ(E)ããã³(F)ã®ãã¡ã®äžã€ã«çžåœã
ãã ããã§ãïŒNuoxïŒ1ãšïŒNuoxïŒ2ïŒåäžã§ãç°ã€ãŠ
ããŠãããïŒã®åã ã¯ïŒ¯ïŒåºãããã¯HNïŒåºã®
åŠãé žåãããæ±æ žåºãè¡šãããZ1ã¯ïŒäŸ¡ã®åå
äŸãã°ââããããã¯R6ãšR7ãæã€ççŽ åå
ã«å¯ŸããŠé»æ°é°æ§çããïŒäŸ¡ã®åºäŸãã°ã¹ã«ããª
ãã«åºãè¡šãããQ1ã¯ãZ1ãšäžç·ã«ãªã€ãŠãæŸ
åºå¯èœãªåççã«æçšãªåºãäŸãã°äžè¿°ããåŠã
æ¡æ£æ§ã®åççã«æçšãªç©è³ªããã矀ãããææ£
æ§ã®è²çŽ ãçããæŸåºå¯èœãªåºãè¡šãããY1ãš
Y2ã¯äžç·ã«ãªã€ãŠã(a)çŽæ¥çµåããïŒäŸ¡ã®ææ©
ãªã³ã°ãããã¯è³éŠå±æ§ãæã€ãªã³ã°ç³»çœ®æåºã§
眮æãããïœâãããã€ããªã³ã°ãéããã®ã«å¿
èŠãªååãè¡šãããY3ã¯(a)çŽæ¥çµåããïŒäŸ¡ã®
ææ©ãªã³ã°ãããã¯è³éŠå±æ§ãæã€ãªã³ã°ç³»çœ®æ
åºã§çœ®æãããïœâãããã€ããªã³ã°ãéããã®
ã«å¿ èŠãªååãè¡šã¯ããR6ãšR7ïŒåäžã§ãç°ã€ãŠ
ããŠãããïŒã®åã ã¯æ°ŽçŽ ã眮æãããçåæ°ŽçŽ
åºãå«ãçåæ°ŽçŽ åºäŸãã°çœ®æãããã¢ã«ãã«åº
ãå«ãã¢ã«ãã«åºããããã¯çœ®æãããã¢ãªãŒã«
åºãå«ãã¢ãªãŒã«åºãè¡šããã奜ãŸããã¯ãã®ã
ã¡ã®äžã€ã¯çœ®æãããããšãã«åºãå«ãããšãã«
åºã§ããããããŠå°ããšãR6ãR7ãããã¯ãã
ãã€ããªã³ã°äžã®çœ®æåºã¯ãã©ã¹ãåºïŒžãäŸãã°
ã¢ã«ã«ãªæ§æ¶²ãåçææã®ã¢ã«ã«ãªééå±€ãéé
ããéåèšååç©ãåèšã¢ã«ã«ãªééå±€å ã§äžå
ã®ãŸãŸä¿æããã®ã«å åãªå€§ãããæã€ã¢ã«ãã«
åºã§ããããããã¯ãããå«æããã äžèšã®ããšãããããã³æ žã®é©åãªçœ®æã«ã
ããååŠåå¿æ§ããã¡ã«éå å¯èœæ§ãã³ã³ãããŒ
ã«ã§ãããšããäºã¯æãã§ãããããããéå ã
ãããããã€ãéšåããªãã¡è²çŽ éšåã«å¯ŸããŠ
âãã€ãªã¢ãŒâéšåãšããŠäœçšãããã€ãããã
ãã€ãéšåã®éå æ§ã®ã¿ãªããå æ°Žå解æ§ãè²çŽ
æŸåºã®é床ã«ãããŠåœ¹å²ãæŒããããšãå®éšçã«
確ç«ãããŠããã å æ°Žå解ã¯ããã€ãããããã€ãååç©åŸã€ãŠ
ãŸããããã€ãååç©ã®èŠªæ°Žæ§ãäœäžãããããš
ã«ããå€å°æå¶ããããšãã§ãããããã¯è²çŽ éš
åïŒã·ã¢ã³ãããžãšã³ã¿ããã³é»è²ïŒã®æ§é ã«ã
ãŸãäŸåããªãè²çŽ æŸåºã«æå©ã§ãããçºè¡ãã
ããšãŒãããç¹èš±åºé¡ç¬¬0049002å·ã®å®æœäŸïŒã
ãåŠã³åŸãåŠãããããã€ãæ žäžã®çœ®æåºã¯ãè²
çŽ éšåã®ç°ã€ãè²çŽ æŸåºååç©ã®è²çŽ æŸåºé床ã
ã§ããã ãè¯å¥œã«åãã¬ãã«ã«ç«ã¡è³ããããã çµæžçãªåŠçæéã§ãã€åäžæ倧å¯åºŠã«å¯ŸããŠ
äžé£åããªãã¶ããçããããšãªãåãå ¥ãå¯èœ
ãªæ倧è²çŽ å¯åºŠãåŸãããã«ãåäžâãã€ãªã¢
ãŒâããäžåè²åçææäžã®äžåè²è²çŽ æŸåºåå
ç©ã«äœ¿çšã§ãããªãã°ãããã¯ç¹ã«æå©ã§ããã æ¬çºæã¯ãã®ãããªææã«çšããã®ã«é©ããã
ããã€ããã€ãªã¢ãŒéšåãæã€ããããŠç¹ã«
DmaxïŒDminã®é¢ä¿ãæ¹è¯ãããIHRè²çŽ æŸåº
ååç©ãæäŸããããªãããã§Dmaxã¯æ倧è²çŽ
å¯åºŠãæå³ããDminã¯æå°è²çŽ å¯åºŠããªãã¡è²
çŽ ãã¶ããæå³ããã æ¬çºæã®ããŸäžã€ã®ç®çã¯ãã·ã¢ã³ãããžãšã³
ã¿ããã³é»è²è²çŽ åãäœãããã®ããã€ãªã¢äžéš
åãåããããç°ã€ãIHRè²çŽ æŸåºååç©ãå«
æããããã²ã³åéè²çŽ æ¡æ£è»¢ååçææãæäŸ
ããããšã§ããããã®ä»ã®ç®çããã³æå©æ§ã¯ä»¥
åŸã®èª¬æããæãã«ãªãã§ãããã æ¬çºæã«åŸãIHRè²çŽ æŸåºååç©ã¯æ¬¡ã®äžè¬
åŒ(G)ã«çžåœãããããã€ãååç©ã§ããã ããã§ãR8ã¯ãããã€ãæ žã®é£æ¥ãã飜åç°
ç¶éšåäžã®ïŒâãããã¯ïŒâäœïŒæå°ã«ãŠç€ºãïŒ
ã«ããæ°ŽçŽ ãããã¯ã¡ãã«ã§ãããR9ã¯ã¢ã«ã
ã«åºäŸãã°ïœâãããã«ããããã¯çœ®æãããã¢
ã«ãã«åºãè³éŠæåºäŸãã°ããšãã«åºããããã¯
眮æãããè³éŠæåºäŸãã°ã¢ã«ã³ãã·ããšãã«åº
ã§ããããã®ãã¡ã¢ã«ã³ãã·ããšãã«åºã奜ãŸã
ããR10ã¯æ°ŽçŽ ãã¢ã«ãã«åºäŸãã°ã¡ãã«ããã
ãã¯ã¢ãªãŒã«åºäŸãã°ããšãã«åºã§ããããããŠ
眮æåºR9ãšR10ã®å°ããšãäžã€ã¯ãã¢ã«ã«ãªæ§æ°Ž
溶液ãã¢ã«ã«ãªééæ§èŠªæ°Žæ§ã³ãã€ãå±€ãééã
ãéåèšååç©ãåèšã³ãã€ãå±€å ã§äžåãªãã
ããã®ã«å åãªå€§ããã®ãã©ã¹ãåºãäŸãã°ã¢ã«
ãã«åºãè¡šããããããã¯ãããå«æããã äžèšäžè¬åŒ(G)ã«åŸãååç©ã¯çŽæ¥è²çŽ ãæŸåºã
ãã®ã§ã¯ãªããŠããã®ããã«ã¯éå ããŠçžåœãã
ãã€ãããããã€ãååç©ãçæããªããŠã¯ãªã
ãªãããã®ååç©ã¯æ¬¡ãã§ã¢ã«ã«ãªæ§æ¡ä»¶äžã§å
æ°Žå解ã«ããåè£ãåãæããããã«ããâSO2
âè²çŽ éšåãã¹ã«ãã€ã³é žã¢ããªã³ãšããŠæ¡æ£æ§
ã®ç¶æ ã§éé¢ããã äžè¬åŒ(G)ã«åŸãååç©ã®è£œé ã«ãããŠããã€ãª
ã¢ãŒéšåã¯äŸãã°æ¬¡ã®åå¿åŒã«åŸã€ãŠãè²çŽ éšå
ãšçµåããã ããã³æ žãã®é£œåããççŽ ç°åŒèåç°ç¶éšã®å°
å ¥ã¯ããã¿ã³ãžãšã³ãããã¯ã€ãœãã¬ã³ãšããã³
ã䜿çšãããžãŒã«ã¹ãŒã¢ã«ããŒåå¿ãçµç±ããŠé²
è¡ããã å ±åœ¹ãžãšã³ãšïœâãã³ãŸããã³ãšã®ãžãŒã«ã¹ãŒ
ã¢ã«ããŒåå¿ã¯ååŠæç®ã«è©³çŽ°ã«èšèŒãããŠã
ããç¹ã«ãã¢ã³ã»ã«ãããã·ãŠãšãŠã€ã«ãœã³ã®å ±
åïŒJ.Chem.Soc.1963ïŒ3012â3028ïŒãšãšã« ãš
ã ãã€ãŒã¶ãŒã®å ±åïŒJ.Amer.Chem.Soc.70ïŒ
3165â317ïŒ1948ïŒïŒãåèã«ããããè¿œå ã®æ å ±
ã¯ããããšãªããïŒorgauic Reacticns5ã136â
192ïŒ1949ïŒïŒããã€ã³ã¬âïŒãšã¹ ãã¿ã€èThe
Chemistry of the quinonoid compoundsïŒç¬¬ïŒ
å·»ïŒ986â1018é ããŠã€ã¬ãŒç€ŸãããŠãŒãšãŒã¯ã
1974幎çºè¡ïŒããã³ãšãã ãŠã«ãªãããšã¢ãŒã«
ãªãã¿ãŒïŒããŒãã³âãŠãšã€ã«å ±è Methoden
der Orgauischen ChewieïŒç¬¬ïŒå·»ïŒ3aãã²ãŒ
ãã€ãšã¡ç€Ÿãã¹ã¿ããã¬ã«ãã1977çºè¡ã80â85
é ïŒã®ç·èª¬ã«èŠåºãããšãã§ããã äžã§å®çŸ©ããã«ã«ãããŒã«ã®åæã«ãŒããäžèš
ã«äŸç€ºããã å¥æ³ã§ã¯ãã¢ã·ã«åãšã¢ãªã«åã«å¯ŸãããžãŒã«
ã¹âã¢ã«ããŒåå¿ã®çžå¯Ÿç段éãéã«ããã ãã¥ãã®ã«ãŒãã®ãžãŒã«ã¹âã¢ã«ããŒåå¿ã«ã
ããŠãããžãšã³ãšããŠã€ãœãã¬ã³ã䜿çšãããªã
ã°ããã®åå¿ããçããçæç©ã¯äºã€ã®å¯èœæ§ã®
ããã¬ãžãªç°æ§äœããã®ãã¡äžæ¹ã¯ïŒäœã«ã¡ãã«
眮æåºãæã¡ãä»æ¹ã¯ïŒäœã«ã¡ãã«çœ®æåºãæã€
ç°æ§äœã®æ··åç©ã§ããããšã«æ³šæããªããã°ãªã
ãªããããã¯åé¢ã§ããããã©ããæ··åç©ã¯åç
çã«ã¯åé¢ãããæåãšåæ§ã«æåããã®ã§ãã
ã®ãããªããšãããå¿ èŠã¯ãªãã äžè¬åŒ(G)ã®ç¯å²å ã«ããååç©ã®åæãããã
ããã·ã¢ã³ãããžãšã³ã¿ïŒ2aïŒ2bïŒããã³é»è²
è²çŽ æŸåºååç©ã«é¢ããè¡šã2aã2bããã³ïŒ
ã®ååç©ã«ã€ããŠããã詳现ã«ããšã«äŸç€ºããã
åæã¯äžèšã®åŒã®äžã€ã«åŸãã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
ååç©ïŒïŒ15.7ïœãšååç©ïŒïŒ¡ïŒïŒ80éé
ïŒ ã®NasO2å¡©ãNaClãšæ··åããŠå«æããïŒ14.4
ïœãé ¢é ž225mlãšæ°Ž45mläžã§æ¹æãããæ¹æã¯80
âã§ïŒæéé²è¡ãããããã§åå¿æ··åç©ã50âã«
å·åŽãããæ²æŸ±ãåžåŒéã§åé¢ããé žãç¡ããª
ããŸã§ã¡ã¿ããŒã«ïŒæ°ŽïŒå®¹ç©ã§ïŒïŒïŒïŒã®æ··åç©
ã§æŽæ»ãããçæç©ïŒïŒ¡ïŒã颚ãéãããªãŒã
ã³äžã§ä¹Ÿç¥ãããåéã22ïœã ååç©ïŒïŒ¡ïŒ10.97ïœãšïœâãã³ãŸããã³
1.78ïœãç ®æ²žéæµãããŠãããžã¯ãããšã¿ã³120
mläžã§ïŒæéæ¹æããã20âã«å·åŽåŸãçæãã
埮现ãªæ²æŸ±ãåžåŒã«ããåé¢ãå°éã®ãžã¯ãããš
ã¿ã³ã§æŽæ»ããã液ãæ¿çž®ããŠã§ããã ãå€ã
ã®ååç©ïŒ¹ãååãããåéã10.6ïœã ååç©ïŒïŒ15.7ïœãšååç©ïŒïŒ¢ïŒïŒ35éé
ïŒ ã®NaSO2å¡©ãNaClãšæ··åããŠå«æããïŒ37.4
ïœãé ¢é ž300mlãšæ°Ž50mläžã§æ¹æãããæ¹æã¯70
âã§ïŒæéé²è¡ãããããã§åå¿æ··åç©ã50âã«
å·åŽãããæ²æŸ±ãåžåŒéã§åé¢ããé žãç¡ããª
ããŸã§ãã¡ã¿ããŒã«ïŒæ°ŽïŒå®¹ç©ã§ïŒïŒïŒïŒã®æ··å
ç©ã§æŽæ»ãããçæç©ïŒïŒ¢ïŒã颚ãéããŠãªãŒ
ãã³äžã§ä¹Ÿç¥ãããåéã21ïœã ååç©ïŒïŒ¢ïŒ10.12ïœãšïœâãã³ãŸããã³1.3
ïœãšãç ®æ²žéæµãããŠãããžã¯ãããšã¿ã³120ml
äžã§ïŒæéæ¹æããã20âã«å·åŽåŸãçæãã埮
现ãªæ²æŸ±ãåžåŒã«ããåé¢ãå°éã®ãžã¯ãããšã¿
ã³ã§æŽæ»ããã液ãæ¿çž®ããŠã§ããã ãå€ãã®
ååç©ïŒãååãããåéã10ïœã ååç©ïŒïŒ15.7ïœãšååç©ïŒïŒ£ïŒ17.7ïœã
é ¢é ž300mlãšæ°Ž50mläžã§æ¹æãããæ¹æã¯70âã§
ïŒæéé²è¡ãããããã§åå¿æ··åç©ã50âã«å·åŽ
ãããæ²æŸ±ãåžåŒéã§åé¢ããé žãç¡ããªããŸ
ã§ã¡ã¿ããŒã«ïŒæ°ŽïŒå®¹ç©ã§ïŒïŒïŒïŒã®æ··åç©ã§æŽ
æ»ãããçæç©ïŒïŒ£ïŒã颚ãéãããªãŒãã³äž
ã§ä¹Ÿç¥ãããåéã28.5ïœã ååç©ïŒïŒ£ïŒ14.8ïœãšïœâãã³ãŸããã³1.6
ïœãšãç ®æ²žéæµãããŠãããžã¯ãããšã¿ã³150ml
äžã§ïŒæéæ¹æããã20âã«å·åŽåŸãçæãã埮
现ãªæ²æŸ±ãåžåŒã«ããåé¢ãå°éã®ãžã¯ãããšã¿
ã³ã§æŽæ»ããã液ãæ¿çž®ããŠã§ããã ãå€ãã®
ååç©ïŒ£ãååãããåéã9.7ïœã ååç©ïŒ¹ãïŒããã³ïŒ£ã®è£œé ã«ãããäžé
çæç©ã®åæ ïœâãã³ãŸããã³1296ïœãé ¢é ž6.6äžã§æ¹æ
ããã溶液ã10â15âã«å·åŽããããã¿ãžãšã³
780ïœïŒ1250mlïŒãæ¹æããªããæ·»å ãããåå¿
æ··åç©ãïŒæ¥é宀枩ã«ä¿æãã次ãã§ïŒæééæµ
ãããªããç ®æ²žããã宀枩ãŸã§å·åŽåŸãçæãã
æ²æŸ±ãåžåŒéã«ããåé¢ããç²ïŒé ¢é žïŒå®¹ç©ã§
ïŒïŒïŒïŒæ··åç©1200mlã§æŽæ»ã次ãã§æ°ŽïŒã¡ã¿ã
ãŒã«ïŒå®¹ç©ã§ïŒïŒïŒïŒæ··åç©ã§æŽæ»ãããçæç©
ã§ããïŒïŒïŒâãžããããã·âïŒïŒïŒâãžããã
ããã¿ã¬ã³ã颚ãéãããªãŒãã³äžã§ä¹Ÿç¥ããã
åéã1285ïœã ïŒïŒïŒâãžããããã·âïŒïŒïŒâãžããããã
ã¿ã¬ã³36.88ïœãã©ããŒããã±ã«ïŒmlãšæ··åãã
ç¡æ°Žãšã¿ããŒã«ã容ç©250mlã«ãªããŸã§æ·»å ããã
éå ããæ¯çªãªãŒãã¯ã¬ãŒãäž23âã§ã105.3
KgïŒcm2ã®æ°ŽçŽ å§ããåºçºããŠå®æœããã20å以å
ã§ãçè«å€ã®110ïŒ ã«çžåœããæ°ŽçŽ æ¶è²»ãèªããã åå¿æ··åç©ãæ°Ž600mläžã«æ³šå ¥ããæ²æŸ±ãåžåŒ
ã«ããé€ãããæ°Žã§æŽæ»åŸãåŸãããïŒïŒïŒâãž
ããããã·âïŒïŒïŒïŒïŒïŒïŒâããã©ããããã
ã¿ã¬ã³ã也ç¥ãããåéã24.6ïœã ïŒïŒïŒâãžããããã·âïŒïŒïŒïŒïŒïŒïŒâãã
ã©ãããããã¿ã¬ã³410ïœãæ¿é ¢é ž520mläžã§æ¹æ
ããã80âã§BR3ã¬ã¹ãïŒæéå°å ¥ãæ¹æãç¶ç¶
ãããåå¿ãã¹ã¯æž©åºŠã100âãŸã§äžæãããšæ¥
æ¿ã«åºåãããåå¿æ··åç©ãå·åŽããæ°Ž2.4ã«
溶ãããé ¢é žãœãŒã600ïœã®æº¶æ¶²ã«æå ¥ãããã
ã¹å šäœãæ¹æããŠåŸ®çŽ°ãªæ²æŸ±ãçæãããããã
åžåŒéã«ããåé¢ããä»åºŠã¯ã¡ã¿ããŒã«1.2
äžã§å床æ¹æããããã«æ°ŽïŒãæ·»å ããã粟補
ããçæç©ãåžåŒéã«ããåé¢ãã颚ãéãã
ãªãŒãã³äžã§50âã§ä¹Ÿç¥ãããåéãïŒïŒïŒâãž
ããããã·âïŒâã¢ã»ãã«âïŒïŒïŒïŒïŒïŒïŒâã
ãã©ãããããã¿ã¬ã³495ïœãèç¹ã199âã ïŒïŒïŒâãžããããã·âïŒâã¢ã»ãã«âïŒïŒ
ïŒïŒïŒïŒïŒâããã©ãããããã¿ã¬ã³51.5ïœãšã»
ãã«ãªãã·ãã³ãŒã³79.5ïœãå¡©åã¡ãã¬ã³200ml
ãšäžåŒåé ¢é ž125mlã®æ··åç©äžã§æ¹æãããåå¿
æ··åç©ãïŒâãŸã§å·åŽãããïœâããã«ãããªã«
115mlãïŒâã§ïŒæé以å ã§æ»Žäžãããåå¿æ··å
ç©ã«ã¡ã¿ããŒã«500mlãæ·»å ãããæ²æŸ±ãåžåŒ
éã«ããåé¢ããã¡ã¿ããŒã«80mlã§æŽæ»ã次ãã§
颚ãéãããªãŒãã³äžã§ä¹Ÿç¥ãããåéãç²ïŒïŒ
ïŒâãžããããã·âïŒâã¢ã»ãã«âïŒâïœâã»ã
ã«ãªãã·ããšãã«âïŒïŒïŒïŒïŒïŒïŒâããã©ãã
ãããã¿ã¬ã³105ïœãé ¢é žãšãã«ããåçµæ¶ããŠ
粟補ç©97ïœãåŸãã åèšç²Ÿè£œç©60ïœãšå°éã®ãããªãŠã ã¡ãã©ãŒã
ã«ãšãã¬ã³ã°ãªã³ãŒã« ã¢ãã¡ãã« ãšãŒãã«ã®
å åãªéãå ããŠå šå®¹ç©ã500mlãšãããæ°ŽçŽ ã¬
ã¹ã«ããéå ããæ¯çªãªãŒãã¯ã¬ãŒããçšã90â
95âã§ã105KgïŒcm2ã®æ°ŽçŽ å§ããåºçºããŠå®æœã
ãã ïŒæéã®æ¯çªåŸãçè«éã®90ïŒ ã®æ°ŽçŽ ã䜿çšã
ãããã©ããŒããã±ã«ãéã«ããé€ããéã«
ã¡ã¿ããŒã«300mlãšæ°ŽïŒå®¹ç©ã§ïŒïŒïŒïŒã®æ··åç©
ãæ·»å ããŠæ²æŸ±ãããç²å€§ã«ãªãããã«ãããæ²
柱ãåžåŒéã«ããåé¢ãã颚ãéãããªãŒãã³
äžã§ä¹Ÿç¥ãããåéãïŒïŒïŒâãžããããã·âïŒ
âïŒ1â²âããããã·ãšãã«ïŒâïŒâïœâã»ãã«ãªã
ã·ããšãã«âïŒïŒïŒïŒïŒïŒïŒâããã©ããããã
ã¿ã¬ã³55ïœããã®ãã®ã¯ååç©ïŒ¹ãïŒããã³
ã®è£œé ã«ãããŠãããã䜿çšãããçæç©
ïŒïŒã§ããã æ¬çºæã«åŸãããã²ã³åéåçææã¯ãã¢ã«ã«
ãªééæ§ã³ãã€ãåªäœäžã§ã¢ã«ã«ãªæ§æ¶²ãšæ¥è§Šã
ããšäžåã§ããããã€è²çŽ éšåãšãã©ã¹ãåºãæ
ã€äžè¬åŒ(G)ã«åŸããããã€ãååç©ãå«ãå°ããš
ãäžã€ã®ã¢ã«ã«ãªééæ§èŠªæ°Žæ§ããã²ã³åéã³ã
ã€ãä¹³å€å±€ãæ æããæ¯æäœãããªãããããŠå
èšååç©ã¯ããã²ã³åéçŸåå€ã«ãããåçææ
äžã®åãšããŠçŸåå¯èœãªããã²ã³åéãããé ã
é床ã§éå å¯èœã§ããããŸãéå å¯èœã§ã¢ã«ã«ãª
æ§æ¡ä»¶äžåèšè²çŽ éšåãæŸåºã§ããã å€è²åãäœãæ æ§ã«ãããŠã¯ãæ¬çºæã¯(1)ã¢ã«
ã«ãªééæ§ã³ãã€ãåªäœäžã§ã¯æåã¯äžåã§ã
ãããããŠããã²ã³åéçŸåå€ãšã¢ã«ã«ãªæ§ã®é
å äœçšã«ããã·ã¢ã³è²çŽ ãããããæ¡æ£æ§ã®ç¶æ
ã§åæåé¢ããåèšãããã€ãååç©ãšäœçšãã
ããã«çµåãããèµ€ææ§ããã²ã³åéä¹³å€å±€ã(2)
ããžãšã³ã¿è²çŽ ãæ¡æ£æ§ã®ç¶æ ã§åæåé¢ããã
ç¹ãç°ãªã€ãŠãã(1)ã®åèšååç©ãšäœçšãããã
ã«çµåãããç·ææ§ããã²ã³åéãšãã«ãžãšã³
å±€ãããã³(3)é»è²è²çŽ ãæ¡æ£æ§ã®ç¶æ ã§åæåé¢
ãããç¹ãç°ãªã€ãŠãã(1)ã®åèšååç©ãšäœçšã
ãããã«çµã¿åãããéææ§ããã²ã³åéä¹³å€å±€
ãæ æããæ¯æäœãããªãåçææã«é¢ããã åè²çŽ æäŸéšåã¯å®æããè²çŽ ã§ãè²çŽ ã«å€å
ãããã®ã§ãããããã®ã¿ã€ãã®è²çŽ ææã¯åœè©²
æè¡ã§å ¬ç¥ã§ãããã¢ãŸè²çŽ ãã¢ãŸã¡ãã³ïŒã€ã
ã³ïŒè²çŽ ãã¢ã³ãã©ããã³è²çŽ ãã¢ãªã¶ãªã³è²
çŽ ãã¡ãã·ã¢ãã³è²çŽ ããããªã³è²çŽ ãã·ã¢ã³è²
çŽ ãªã©ãæãããããè²çŽ ã«å€åãããã®ã«ã¯ã
PHã®å€åã®åŠãç°ãªãç°å¢ã«åããšãè€å¡©ãçæ
ããææãšåå¿ãããšãäºå€ç°æ§ãåãããšãå
åç©ã®pKaãå€ããåå¿ãåãããšããŸãçºè²å
ã®ååã«çµåããåºäŸãã°å æ°Žå解å¯èœãªã¢ã·ã«
åºãé€å»ãããšããã®å åžåç¹æ§ãæµ è²çã«ãã
ãã¯æ·±è²çã«å€åããååç©ãæããããããã
ãååç©ã¯äŸãã°ã1966幎ïŒæ12æ¥ã«çºè¡ããã
ãŠãªã«ã¿ãŒ ãžãšãŒ ãŠãšã€ã¢ãŒããšãŠã€ã«ããŒ
ãšã ãµã«ããã³ã®ç±³åœç¹èš±æ现æžç¬¬3260597
å·ã«èšèŒãããŠãããããæ æ§ã«ãããŠã¯ãè²çŽ
ã«å€åãããã®ãç¹ã«çºè²å ã®å ±åæ§é ã«åœ±é¿ã
ãååã«å æ°Žå解å¯èœãªåºãæã€ãã®ã極ããŠå¥œ
ãŸããããã®çç±ã¯ãã®ååç©ã¯ããã²ã³åéä¹³
å€å±€ã«çŽæ¥æ··å ¥ããããšãã§ãããããããã¯ã
ã®å±€ã®é²å åŽã«ã§ããããã²ã³åéã®é²å ã«å¹æ
çãªå ãå®è³ªçã«æžå°ãããããšãªããæ··å ¥ãã
ããšãã§ããããã§ãããé²å åŸããã®è²çŽ ã¯äŸ
ãã°ã¢ã·ã«åºãå æ°Žå解ã§é€ããŠããããã®åè²
çŽ ãçæãããããšã«ããé©åœãªè²ã«è»¢æããã
ããšãã§ããã æ¬çºæã®äžè¬åŒ(G)ã«åŸã1HRååç©ã¯ãé£æ¥
å±€ãããã¯å容ãšã¬ã¡ã³ãã«è²çŽ å®äœã転åãã
ãããšãæãŸããæ¡æ£è»¢åæ³ã«ãããŠç¹ã«äœ¿çšã
ããã æ¬çºæã«åŸãçšéã«çšãã1HRååç©ã¯ãé
åžžã®æ¹æ³ã®äžã€ã«ãããåçææã®å±€ã«çšããå¡
åžæ¶²äžã«æ··åãããå¡åžæ¶²ïŒåœãã«çšãããã®
ååç©ã®éã¯ãäŸãã°åæåé¢ããããšã«ãªã€ãŠ
ããåççã«æçšãªåºã«ãããæ¯èŒçåºç¯å²å ã«
å€åãããããŠæãé©åœãªæ¿åºŠã¯ç°¡åã®ãã¹ãã«
ãã€ãŠèŠåºãããšãã§ãããäŸãã°ã0.01ãªãã
10ïœã奜ãŸããã¯0.1ãªãã0.5ïœã®1HRååç©ã
m2åœã䜿çšã§ãããå¡åžæ¶²äŸãã°ããã²ã³åéãš
ãã«ãžãšã³äžã«æ··ãããã«ã¯ããµã³ããã«ã«ãŠäœ
ã€ãåæ£æ¶²ãããã¯è¶ é³æ³¢ãçšããŠãããã ä»ã®æ¹æ³ã«åŸãã°ã1HRååç©ããããã²ã³
åéãšããŠéæã«ã¯çŸåå€ç©è³ªãšãäžç·ã«ããŠæ
è¬ãã€ã¯ãã«ãã»ã«ã®åœ¢ã«ããŠèŠªæ°Žæ§ã³ãã€ãå±€
äžã«ãŸã蟌ãããšãèŠæãããããã®å ŽåãäŸã
ã°1955幎ïŒæïŒæ¥ã«çºè¡ãããã¬ãªãã«ã ãŽã
ããŠã€ã¹ããŒã®ç±³åœç¹èš±æ现æžç¬¬2698794ã«èšèŒ
ãããŠããåŠããäºã€ä»¥äžã®æãæ¹ã®ç°ãªããã
ã²ã³åéä¹³å€ãšé©åœãªèæ¡æ£æ§ååç©ãšãæè¬æ··
åãã±ããä¹³å€ã®åœ¢ã§äžã€ã®å±€å ã§äžç·ã«ããŠã
ããã1HRååç©ãã¢ã«ã«ãªæ§æ°Žæº¶æ¶²ãã芪氎
æ§ãã€ã³ããŒäžã«ãŸã蟌ãå å«æ¹æ³ãããã®åå
ç©ã®å æ°Žå解ã®å±éºãç¡ããšããçç±ã§çšããŠã
ããã ç¹å¥ã®æ æ§ã§ã¯ãåèšãããã€ãååç©ã¯ãã
ã²ã³åéä¹³å€å±€ã«é£æ¥ãã芪氎æ§ã³ãã€ãå±€å ã«
ååšãããã®é£æ¥å±€ã¯é²å äžã®å ¥å°å ã®æ¹åãã
èŠãŠããã²ã³åéä¹³å€å±€ã®èåŸã«äœçœ®ããã®ã奜
ãŸããã æ¬çºæã«åŸãç¹å®ã®æ æ§ã«ãããŠã¯ãã«ã¡ã©å
åŠççšã«èšèšããã«ã¡ã©ã®å Žåã«èªããããåŠ
ããäžå¯Ÿã®äžŠãã å å§éšæã®éã«éããŠåŠçãã
ã®ã«é©ããèãã€ã«ã ãŠãããã§ããåçææã
æäŸãããããã®ãŠãããã¯(1)åãã¯ã¢ã«ã«ãªé
éæ§ã³ãã€ãåªäœäžã§äžåã§ããããããŠããã²
ã³åéçŸåå€ãšã¢ã«ã«ãªæ§ã®éå äœçšã«ããè²çŽ
ãããããæ¡æ£æ§ã®ç¶æ ã§åæåé¢ããåèšãã
ãã€ãååç©ãçµåãããŠæã€ããã²ã³åéä¹³å€
å±€ãå«ãæå æ§ãšã¬ã¡ã³ãã(2)åè²çŽ å容局ã(3)
ã¢ã«ã«ãªæ§åŠççµæç©ãèãŠãããå éšã§æåºã
ãæ段äŸãã°ç Žè£å¯èœãªå®¹åšã§ãã€ãŠããã®å®¹åš
ã¯å å§éšæã«ãã€ãŠãã®å®¹åšã«ãããå§çž®åã§å®¹
åšã®å 容ç©ãèå éšã«æåºããããããèã®å å·¥
äžã«ååšããã®ã«é©ãããã®ã§ãããããã³(4)å
èšèãŠãããå éšã«ååšããã¢ã«ã«ãªæ§åŠççµæ
ç©ã«å¯å®¹æ§ã§ããããã²ã³åéçŸåå€ãããªãã æ¬çºæã®åçææã¯ã(1)å°ããšãäžã€ã®ããã²
ã³åéä¹³å€å±€ãšãã¢ã«ã«ãªééæ§ã³ãã€ãå±€äžã§
æåã¯äžåã§ããåèšãããã€ãååç©ãããªã
å°ããšãäžã€ã®ã¢ã«ã«ãªééæ§å±€ïŒãã®å±€ã¯ãã
ã²ã³åéãå«æããå±€ãšåäžå±€ã§ãã€ãŠãããïŒ
ãšãæ æããæ¯æäœãããªãåãšããŠé²å ããã
åçææã«ã¢ã«ã«ãªæ§åŠççµæç©ãé©çšãããªã
ããã«ãããŠåèšååç©ã¯ããã²ã³åéçŸåå€ã«
ãããææäžã®åãšããŠçŸåå¯èœãªããã²ã³åé
ãããé ãé床ã§éå å¯èœã§ããããŸãéå ãã
ãç¶æ ã§ã¢ã«ã«ãªæ§æ¡ä»¶äžè²çŽ ãæŸåºããããšã
ã§ãããã®ã§ããã(2)åçææäžã®åèšããã²ã³
åéã®åãšããŠã®çŸåã«åæ¯äŸããŠãåèšè²çŽ ã
åãšããŠæŸåºãããæ¡ä»¶ã®äžã§åèšã¢ã«ã«ãªæ§åŠ
ççµæç©ã䜿çšããéçšã§åèšåçææçšçŸåå€
ãæäŸãããããŠ(3)æåã«è²çŽ ããŸã蟌ãŸããŠã
ã€ãå±€ããè²çŽ ãåèšã¢ã«ã«ãªæ§åŠççµæç©ãšå ±
ã«æ¡æ£ãããŠãè²çŽ ãããŸäžã€ã®å±€ã«åãšããŠç§»
è¡ãããããšãããªãæ¹æ³ã«ãããŠæçšã§ããã è²çŽ åãäœãæ æ§ã«ãããŠã¯ãæ¬çºæã¯ã ïœïŒ æ¬çºæã«åŸãåçãšã¬ã¡ã³ãããé²å ãã
ããã²ã³åéä¹³å€å±€ã®åã ãçŸåããããã²ã³
åéçŸåå€ã®ååšäžã§ãã¢ã«ã«ãªæ§åŠççµæç©
ãçšããŠåŠçããŠããã®çŸåå€ãåãšããŠé žå
ãããããŠåãšããŠã®ããã²ã³åéã®çŸåã®é
ã®æ©èœãšããŠãéå ãããç¶æ ã§(a)è²çŽ ãæŸåº
ã§ããåèšäžåæ§ãããã€ãååç©ãéå ãã ïœïŒ éå ãããäžåæ§ååç©ããæ¡æ£æ§ã®ç¶æ
ã§åèšè²çŽ ãæŸåºãããã«å åãªæéã®éãå
èšåçææãåŠççµæç©ã®ã¢ã«ã«ãªæ§åªäœäžã«
ä¿æãããã㊠ïœïŒ åèšè²çŽ ã®å°ããšãäžéšãå容局ãšããŠäœ
çšããéæå å±€ã«è»¢åããããšãããªãæ¡æ£è»¢
åçè²åçæ³ã«é¢ããã ã«ã¡ã©å åŠçã«å¯ŸããŠã¯ãæå æ§ææã¯ãæå
æ§ããã²ã³åéä¹³å€å±€ããã¬ã«åãããã€æå å±€
ãšãã¢ã«ã«ãªééæ§ã§å ãåå°ããå容局ãšãã
ã²ã³åéä¹³å€å±€ã®éã«äœçœ®ãã奜ãŸããã¯äžéæ
å±€ãæã€éæå å±€å容ãšã¬ã¡ã³ããšã®äžäœççµå
ãçæããããã«ãåèšæå æ§ããã²ã³åéä¹³å€
å±€ãå容局ãšåãæ¯æäœã«å¡åžãããããã«æ§æ
ãããããšã奜ãŸããããã®ãããªææãçšãã
æ¹æ³ã§ã¯ãã¢ã«ã«ãªæ§åŠççµæç©ã¯åçãšã¬ã¡ã³
ãã®æå å€å±€ãšãéæã§é²å åã«éããããã«ã
ãŒã·ãŒããšã®éã«æ¿å ¥ããŠãããã æ¬çºæã®ãããã€ãååç©ãçšããŠæ¡æ£è»¢åç
è²æ³ãå®æœããã«ã¯ããã®ååç©ãšãå°ããšãäž
ã€ãé»åäŸäžäœïŒEDååç©ïŒãšåŒã°ããååç©
ã§ããããŸãå°ããšãäžã€ãé»å移åå€ïŒETA
ååç©ïŒãšåŒã°ããååç©ã§ããéå å€ã®æ··åç©
ãšãçµåããŠäœ¿çšããŠå®æœããã®ã奜ãŸããã EDååç©ã¯ããã®ååç©ããã®é»åãããã
ã€ãååç©ã«ç§»è¡ãããªããã°ãªããªãå±€ãŠãã
ãå éšã«ãšã©ãŸãããã«ãäŸãã°ãã©ã¹ãåºãæ
ã€éæ¡æ£æ§ã§ããããšã奜ãŸããã EDååç©ã¯ãç°ãªã€ãéæ¡æ£æ§è²çŽ ãããã¯
è²çŽ ãã¬ã«ãŒãµãŒãå«æãããã¬ã«åãããã²ã³
åéä¹³å€åå±€ã«éæ¡æ£æ§ã®ç¶æ ã§ååšããããšã
奜ãŸããããã®ãããªEDååç©ã®äŸã«ã¯ãã¢ã«
ã³ã«ãã«ããã«ãããŒããšïŒïŒïŒâãã¹ïŒ1â²ïŒ
1â²ïŒ3â²ïŒ3â²âããã©ã¡ãã«ããã«ïŒâãã€ãããã
ã³ãããããã®ä»ã®EDååç©ã¯ç±³åœç¹èš±ç¬¬
4139379å·ããã³çºè¡ããããã€ãç¹èš±åºé¡ç¬¬
2947425å·ã«èšèŒãããŠãããEDååç©ã®ä»£ã
ã«ãçºè¡ããããã€ãç¹èš±åºé¡ç¬¬2809716å·ãšç±³
åœç¹èš±ç¬¬4278750å·ã«èšèŒãããåŠããé»åäŸäž
äœãã¬ã«ãŒãµãŒååç©ãåçææã«äœ¿çšã§ããã
æ¬çºæã®HRååç©ãšçµã¿åãããããã®ç¹ã«
æçšãªEDãã¬ã«ãŒãµãŒååç©ã¯çºè¡ããããã€
ãç¹èš±åºé¡ç¬¬3006268å·ã«é瀺ããããã³ãŸãã©
ã³ååç©ã§ãããã¯æ¬¡ã®äžè¬åŒã«çžåœããã ããã§R11ã¯ççŽ ç°åŒãããã¯ç°ç¯ç°åŒè³éŠæ
ç°ãè¡šãããR12ãR13ããã³R14ïŒåäžã§ãç°ã€
ãŠããŠãããïŒã¯æ°ŽçŽ ãã¢ã«ãã«ãã¢ã«ã±ãã«ã
ã¢ãªãŒã«ãã¢ã«ã³ãã·ãã¢ã«ãã«ããªãã¢ããã
è¡šããããããã¯R13ãšR14ã¯äžç·ã«ãªã€ãŠé£æ¥
ç°äŸãã°ççŽ ç°åŒç°ãè¡šããããããŠãã®å Žå
R11ãR12ãR13ããã³R14ã®å°ããšãäžã€ã¯10ãª
ãã22ã®ççŽ ååãæã€ãã©ã¹ãåºãè¡šããã ETAååç©ã¯æ¡æ£æ§ã®ç¶æ ã«ããçŸåå€ãšã
ãŠäœ¿çšããã®ã奜ãŸããããŸãäŸãã°ãäžã€ä»¥äž
ã®ããã²ã³åéä¹³å€å±€ã«é£æ¥ã芪氎æ§ã³ãã€ãå±€
ã«åãæã圢ã§ãŸã蟌ãŸãããããããã¯è²çŽ æ¡
æ£è»¢åçšåŠç液ããæ·»å ãããã å žåçã«æçšãªETAååç©ã«ã¯ãäŸãã°ç±³åœ
ç¹èš±æ现æžç¬¬4139379å·ã«èšèŒãããåŠãããã€
ããããã³ååç©ãã¢ããããšããŒã«ååç©ãã«
ãã³ãŒã«ååç©ãããšãã¬ã³ãžã¢ãã³é¡ããã³ïŒ
âãã©ãŸãªãžãã³ååç©äŸãã°ïŒâã¢ãªãŒã«âïŒ
âãã©ãŸãªãžãã³ãããã ç±³åœç¹èš±æ现æžç¬¬3039869å·ã«é瀺ãããåŠã
ç°ã€ãETAååç©ã®çµåããã䜿çšã§ãããã
ã®ãããªçŸåå€ã¯æ¶²ç¶åŠççµæç©ã§äœ¿çšã§ãã
ãããããã¯å°ããªããšãäžéšããåçãšã¬ã¡ã³
ããããã¯èãŠãããã®ãããªãå±€ã«ãäŸãã°ã
ãã²ã³åéä¹³å€å±€ãè²çŽ åæäŸææå±€ãäžéå±€ã
åå容局ãªã©ã«å å«ãããŠããŠããããéžæãã
ãç¹å¥ã®ETAã¯å¿è«ãã®æ¹æ³ã§äœ¿çšããç¹å¥ã®
é»åäŸäžäœãšãããã€ãååç©ã«ããŸãç¹å¥ã®å
çãšã¬ã¡ã³ãçšã®åŠçæ¡ä»¶ã«äŸåããã åçææäžã®EDååç©ãããã¯EDãã¬ã«ãŒãµ
ãŒååç©ã®æ¿åºŠã¯åºç¯å²ã«å€æŽã§ããããäŸãã°
ãããã€ãååç©ã«å¯ŸããŠïŒïŒïŒãªããïŒïŒïŒã®
ã¢ã«ç¯å²ã«ãããETAååç©ã¯çŸå段éã§äœ¿çš
ããã¢ã«ã«ãªæ§æ°Žæº¶æ¶²äžã«ååšããŠãããããå°
ããªããšãäžã€ã®ããã²ã³åéä¹³å€å±€ã«é£æ¥ãã
éæå æ§èŠªæ°Žæ§ã³ãã€ãå±€å ã§æ¡æ£æ§ã®åœ¢ã§äœ¿çš
ããã®ã奜ãŸããã äŸãã°ETAååç©ãšããŠäœçšããéé žåã®çŸ
åå€ã®ãã€ã°ã¬ãŒã·ãšã³ã¯éåãšããŠé²è¡ããã
ããŠäœã€ãçŸåå€ããã¬ã«åãä¹³å€å±€ã®é²å éšã«
é žåãããã«ãšã©ãŸãå Žåã«ã¯æ£ç¢ºãªæŒè²ã«æªåœ±
é¿ãåãŒããã®ã§ãããåŸã€ãŠãæ¬çºæã®å¥œãŸã
ãæ æ§ã«åŸãã°ãå€åããªãçŸåå€ïŒETAåå
ç©ïŒã¯ãã¯ãçŽæ¥ã«ãããã¯äœ¿çšããEDååç©
ãéããŠãããã€ãååç©ãšåå¿ãããã®ã«ã¯åœ¹
ç«ããªãã§ããããšæãããé²å åå ã«ãããã€
ã°ã¬ãŒãããçŸåå€ã®äžåïŒããªãã¡ç©çççŸå
ã«ããé žåïŒãå©ããããã«ãããã²ã³åé溶åª
äŸãã°ããªãµã«ããšãŒãã䜿çšããŠè€éãªåœ¢ãã
ãæªé²å ããã²ã³åéãåé€ãããã®ç®çã«ãã
ã²ã³åé溶åªã䜿çšããããšã¯çºè¡ããããšãŒã
ããç¹èš±åºé¡ç¬¬0049002å·ã«èšèŒãããã ããæ£ç¢ºãªæŒè²ãåŸãããã«ã¯ãé žåããã
ETAååç©ãéäžã§æããŠããããEDååç©ã®
æãŸãããªãé žåãåŒèµ·ãããšããã°ã§ããã§ã
ããé£æ¥ããå圢æå±€ãžãã€ã°ã¬ãŒãããã®ãé²
æ¢ããããšãæå©ã§ãããåèšæç²ã«ã¯ãéæ¡æ£
ç¶æ ã§åçææäžã«ãäŸãã°å圢æå±€ã®éã®äžé
å±€ã«ãŸã蟌ãŸããæè¬é€å»å€ã䜿çšããããã®ç®
çã«çšããé©åœãªé€å»å€ã¯äŸãã°ç±³åœç¹èš±ç¬¬
4205987å·ããã³ãšãŒãããç¹èš±ç¬¬29546å·ã«èšèŒ
ãããŠããã æ¬çºæã«åŸãåçãšã¬ã¡ã³ãã§äºã€ä»¥äžã®ãã
ã²ã³åéä¹³å€å±€ãå«ããã®ã§ã¯ãè²çŽ åæäŸææ
ãå«ãããããã¯è²çŽ åæäŸææãå°ç¶ãã®å±€ã
ãªããŠååšããåããã²ã³åéä¹³å€å±€ããèãŠã
ããäžã®ä»ã®ããã²ã³åéä¹³å€å±€ããäžéå±€ã«ã
ãåé¢ããŠããããããã§äžéå±€ã¯äŸãã°ã²ã©ã
ã³ãã¢ã«ã®ã³é žã«ã«ã·ãŠã ããããã¯1968幎ïŒæ
21æ¥çºè¡ã®ãªãã€ãŒã ãããªãŠãŒ ããã«ãŒã®
ç±³åœç¹èš±æ现æžç¬¬3384483å·ã«é瀺ãããã³ãã€
ãé¡ã1969幎æ14æ¥çºè¡ã®ãã€ã ã㌠ããŒã©
ãŒã®ç±³åœç¹èš±æ现æžç¬¬3421892å·ã«èšèŒãããã
ãªããã«ã¢ããã®åŠãããªããŒææã®ãã¥ãã
ãããããã¯ãã©ãã€ã瀟ã«ãã1970幎ïŒæ13æ¥
ã«åºé¡ããããã©ã³ã¹ç¹èš±æ现æžç¬¬2028236å·ã
ãããã¯1961幎ïŒæ11æ¥çºè¡ã®ãã¯ãŒã ã·ãŒ
ããŒã¹ã®ç±³åœç¹èš±æ现æžç¬¬2992104å·ãããã³
1969幎ïŒæ11æ¥çºè¡ã®ãããã ããŒã«ãŒã«ãœã³
ãšãžãšãã ãšã« ã¬ã€ãã®ç±³åœç¹èš±æ现æžç¬¬
3427158å·ã«é瀺ããããã®ã®ãã¥ãããå«æã
ãã æ¬çºæã«åŸãå€è²æ¡æ£è»¢åææã®è£œé ã«ããã
æ æ§ã«åŸãã°ãé»è²éæ¡æ£è²çŽ ãããã¯ã«ãŒã¬ã€
ãªãŒ ã·ã«ããŒã§æããæ°Žééæ§ã³ãã€ãäžé
å±€ãé»è²è²çŽ æŸåºååç©ãå«ãéææ§ããã²ã³å
éä¹³å€å±€ã®äžã«ã€ããã æ¬çºæã®ããæ æ§ã§ç¹ã«äžäœåèãŠããããæ
ã€ãã®ã§ã¯ãäžéæåå€ãåŠççµæç©ããå ãã
ããšãã§ãããäžéæåå€ã®äŸãšããŠã¯ãã«ãŒã
ã³ãã©ãã¯ãç¡«é žããªãŠã ãé žåäºéãã¹ãã¢ãª
ã³é žããªãŠã ãç¡ é žé¡ãã¢ã«ãããé žåãžã«ã³ã
ãŠã ãã¢ã»ãã«é ¢é žãžã«ã³ããŠã ãç¡«é žãããªãŠ
ã ãžã«ã³ããŠã ãã«ãªãªã³ããã€ã«ãäºé žåãã¿
ããŠã ãæ瀺è¬è²çŽ ããã°ãã·ã³ã®åŠãææ©è²çŽ
ãããã¯ãããã®æ··åç©ãæãããããã®éã¯æ
æã®äžéæ床ã«å¿ããŠåºç¯å²ã«å€åãããäžè¬
ã«ãäžéæåå€ã®æ¿åºŠã¯ãæ¯æäœãéããŠçŽæ¥å
ãããŠããšããããã¯ãšã¬ã¡ã³ãã®ç«¯ããå·®ã蟌
ãå ã®ããã«ãåŠççµæç©ã®å±€ãéã倧æ°ã®ååŠ
ç·ã«ããèãŠãããã®ããã²ã³åä¹³å€ãããã«é²
å ããã®ãé²ãã«å åãªãã®ã§ãªããã°ãªããª
ããäŸãã°ãã«ãŒãã³ãã©ãã¯ãããã¯äºé žåã
ã¿ããŠã ã¯äžè¬ã«ããããåŠç溶液äžã«çŽïŒãªã
ã40ééïŒ ã®éã§ååšããå Žåã«ã¯ãå åãªäžé
æãæäŸãããåŠç溶液ãšäžéæåå€ãèãŠãã
ãå ã«ååžããåŸã¯ãåŠçãååŠç·ã®ååšäžã«ã¡
ã©ã®å€ã§è¡ãªã€ãŠãããããããã¯ããã®ã©ãã
ãŒãã®ãã²ã³åä¹³å€ããäžã€ã®äž»èŠé¢ã§ã¯äžéæ
ã®åŠççµæç©ã«ãããŸãæ®ãã®äž»èŠé¢ã§ã¯ã¢ã«ã«
ãªæ§æº¶æ¶²ãééãããäžéæå±€ã«ããå ¥å°å ã«å¯Ÿ
ããŠé©åã«ä¿è·ãããŠãããšããäºå®ãèæ ®ããŠ
ã®ããšã§ãããããæ æ§ã§ã¯ããã©ã¹ãåºã®ã€ã
ãæ瀺è¬è²çŽ ãããã¯è²çŽ ãã¬ã«ãŒãµãŒãæå å±€
ã®é²å åŽäžã®å±€äžã«ãŸã蟌ãããšãã§ãããããŠ
ãã®æ瀺è¬è²çŽ ã¯é²å äžã¯éæã§ãããåŠççµæ
ç©ãšæ¥è§Šãããšäžéæã«ãªãããšã奜ãŸãããã
ãã²ã³åéä¹³å€ã«æå°ããååŠç·ããšããžéšã§æŒ
ããã®ãé²æ¢ããã®ã«äžéæãªçµåããŒããçšã
ãããšãã§ããã äºé žåãã¿ããŠã ãããã¯ä»ã®çœè²é¡æãåŠç
çµæç©ã®äžéæåå€ãšããŠäœ¿çšããå Žåã«ã¯ãã
ããšååã§ãã¿ã¬ã€ã³è²çŽ ã®åŠãPHã«æããäžé
æåè²çŽ ã䜿çšããããšããŸã奜ãŸããããã®ã
ããªè²çŽ ã¯å圢æãè¡ãªãããPHã§ã¯åžå æ§ã§ã
ãããããã¯çè²ããŠãããããäœãPHã§ã¯ç¡è²
ããããã¯éåžå æ§ã§ããããããäžéæåè²çŽ
ã«é¢ãããã®ä»ã®è©³çŽ°ã¯ããã©ãã€ã瀟ã1969幎
12æ22æ¥ã«åºé¡ãããã©ã³ã¹ç¹èš±æ现æžç¬¬
2026927å·ã«èšèŒãããŠããã æ¬çºæã®äžäœçå容èãŠãããäžã®ã¢ã«ã«ãªæ§
溶液ãééãããå®è³ªçã«äžéæãªå åå°å±€ã¯ã
ãããææã®æ§è³ªãæã€éããã€ã³ããŒäžã«åæ£
ãããããªãäžéæåå€ããã§ãéåžžãªãåŸãã
ç¹ã«æãŸããã®ã¯çœè²å åå°å±€ã§ãã€ãŠãããã¯
ãã®å±€ã審çŸçã«å¿«ããã®äžã§è»¢åãããè²çŽ å
ãçºããèæ¯ã瀺ããšå ±ã«ãŸãå ¥å°å ç·ã®åå°ã«
æãŸããå åŠçæ§è³ªãæã€ããã§ãããé©åœãªäž
éæåå€ã«ã¯ãåŠççµæç©ã«é¢ããŠæ¢ã«è¿°ã¹ãåŠ
ããäºé žåãã¿ããŠã ãç¡«é žããªãŠã ãé žåäº
éãã¹ãã¢ãªã³é žããªãŠã ãèéçãç¡ é žå¡©é¡ã
ã¢ã«ãããé žåãžã«ã³ããŠã ãã¢ã»ãã«é ¢é žãžã«
ã³ããŠã ãç¡«é žãããªãŠã ãžã«ã³ããŠã ãã«ãªãª
ã³ããã€ã«ãããã¯ãããã®æ··åç©ãæãããã
ãã®éã¯ææã®éæå床ã«å¿ããŠåºç¯å²ã«å€ãã
ãããäžéæåå€ã¯ãããªããã€ã³ããŒã«åæ£ã
ããŠãããããã®ãã€ã³ããŒã«ã¯äŸãã°ã²ã©ã
ã³ãããªããã«ã¢ã«ã³ãŒã«çã®åŠãã¢ã«ã«ãªæ§æº¶
液ééæ§ããªããŒãããªãã¯ããããã¹ãã«ã
ã³ãã¯ããªã³ãããªã¢ãžã³ã€ãªããµãŸãŒã«ã®åŠã
è¢å å¢çœå€ããææãªãã°å åå°å±€ã«æ·»å ããŠã
ãããå åå°å±€ã®äžéæåèœåãé«ããããšãæ
ãå Žåã«ã¯ãäŸãã°ã«ãŒãã³ãã©ãã¯ããã°ãã·
ã³è²çŽ ãªã©ã®åŠãæè²äžéæåå€ããã®å±€ã«å ã
ãŠããããå åå°å±€ã®äžéæåèœåãé«ããããŸ
äžã€ã®æ¹æ³ã¯ãã¢ã«ã«ãªæ§æ°Žæº¶æ¶²ãééãããã
ãªããŒãããªãã¯ã¹ãäŸãã°ã²ã©ãã³ãããªãã
ã«ã¢ã«ã³ãŒã«çã«äŸãã°ã«ãŒãã³ãã©ãã¯ããã°
ãã·ã³è²çŽ çãåæ£ãããå¥ã®äžéæå±€ããå å
å°å±€ã®çäžã«é 眮ããããšã§ããããã®ãããªäž
éæå±€ã¯éåžžå¯åºŠãå°ããšãïŒå¥œãŸããã¯ïŒãã
倧ããããã€ååŠç·ã«å¯ŸããŠå®è³ªçã«äžéæã§ã
ãã®ããããäžéæå±€ã¯ãããäžã€ã§ååšãããª
ãã°ãçŸåè¬é€å»å±€ãšäžç·ã«ããŠããããå åå°
å±€ãšäžéæå±€ã¯éåžžåã¿ã0.025ãªãã0.15mmã§
ãããã䜿çšããäžéæåå€ãèŠæããäžéæ床
çã«å¿ããŠå€ããããšãã§ããã æ¬çºæã«äœ¿çšããæå æ§ç©è³ªã¯ããã²ã³åéä¹³
å€ã§ããããšãæãŸããããŸãå¡©åéãèåéã
èåæ²åéãå¡©åèåæ²åéçããããã¯ããã
ã®æ··åç©ãããªã€ãŠããããä¹³å€ã¯ç²å€§ã§ã埮ç²
ã§ãããããããªãå ¬ç¥æ¹æ³ã§äœãããšãã§ã
ããäŸãã°ãžã³ã°ã«ãžãšããä¹³å€ããªãããã³ä¹³
å€ã®åŠãããã«ãžãšããä¹³å€ãã¢ã³ã¢ãã¢æ§ä¹³
å€ãäžèšç±³åœç¹èš±æ现æžã«èšèŒãããåŠãããªã·
ã¢ããŒããããã¯ããªãšãŒãã«çæä¹³å€ãããã
ç±³åœç¹èš±ã«ã¯1940幎11æïŒæ¥çºè¡ã®ã¢ãã«ã ãš
ãã ããŒããšãã¬ããªã㯠ãžãšãŒ ã©ãã»ã«
ã®ç¬¬2222264å·ã1967幎ïŒæ16æ¥çºè¡ã®ããŒããŒ
ããã€ãŒ ã€ãªã³ã°ã¹ã¢ãŠãŒã¹ã®ç¬¬3320069å·ã
ãã³1966幎ïŒæïŒæ¥çºè¡ã®ã¯ã©ã¬ã³ã¹ ã€ãŒ ã
ãã¯ãã©ã€ãã®ç¬¬3271157å·ããããè¡šé¢åä¹³å€
ã䜿çšããŠãããããããã¯äžèšç±³åœç¹èš±æ现æž
ã«èšèŒãããåŠãå éšåä¹³å€ã䜿çšããŠãããã
ç±³åœç¹èš±æ现æžã«ã¯ã1952幎ïŒæïŒæ¥çºè¡ã®ãšã
ã¯ãŒã ãã€ãªãã ããŒããŒãšãšãã¯ãŒã ã
ãšã¹ ãããã®ç¬¬2592250å·ã1965幎ïŒæ14æ¥çº
è¡ã®ãã³ãªãŒ ãã€ãŒ ããŒã¿ãŒãããŒãã¹ ãš
ãã ãžãšãŒã ã¹ããã³ãŠãšãºã¬ãŒ ãžãŒ ããŒ
ãŠãšã®ç¬¬3206313å·ããã³1969幎ïŒæïŒæ¥çºè¡ã®
ãããŒã ã€ãŒ ããŒã³ã³ããã³ãžãŒã³ ãšã
ããŒãã¢ãŒã®ç¬¬3447927å·ããããä¹³å€ã¯ãã¯ã¬
ã€ã³ãšã¢ã€ã¶ãŒããžã€ãŒãã« ãªã 㶠ããªã
ã°ã©ãã€ã㯠ãµã€ãšã³ã¹12å·»ãïŒå·ïŒæïŒ10æ
å·ã242â251é ã1964幎ã«èšèŒããã¿ã€ãã®åŠã
ç²åã®æŽã®ã€ãä¹³å€ã§ããããææãããã°ã
1961幎ïŒæ15æ¥çºè¡ã®ãžãšãŒãž ãããªãŠãŒ ã©
ãããŒãšãžãšãŒã³ ã·ãŒ ãããã®ç±³åœç¹èš±æ现
æžç¬¬2996382ã«èšèŒãããåŠããè¡šé¢åä¹³å€ãšå
éšåä¹³å€ã®æ··åç©ã䜿çšããŠãããã æ®éã¯ãã¬ã¿ã€ãã䜿çšãããããŠåå転ã®å¿
èŠããªãæã¯ãäžèšç±³åœç¹èš±æ现æžãè±çŽ°ç¹èš±æ
现æžã«èšèŒãããåŠãçŽæ¥ããžä¹³å€ãåæ§ã«äœ¿çš
ããŠããããç±³åœç¹èš±æ现æžã«ã¯ã1939幎12æ19
æ¥çºè¡ã®ãžãšã³ ãšãŒ ãªãŒã«ã¡ãŒã«ãŒã¹ã®ç¬¬
2184013å·ã1951幎ïŒæ13æ¥çºè¡ã®ãŠã€ãªã¢ã ã
㌠ã±ã³ãã«ãšãžãšãŒãž ãã€ãŒ ãã«ã®ç¬¬
2541472å·ã1968幎ïŒæïŒæ¥çºè¡ã®ãããŒã ã
ããªãŠãŒ ããªãŒãã³ã®ç¬¬3367778å·ã1970幎ïŒ
æ17æ¥çºè¡ã®ããŒããŒã ãã€ãŒ ã€ãªã³ã°ã¹ãŠ
ã¯ãŒã¹ã®ç¬¬3501307å·ã1951幎ïŒæïŒæ¥ä»¥è¡ã®ã
ã€ãŒã«ã¹ ãšã ã¢ã€ãã¹ã®ç¬¬2563785å·ã1948
幎12æ21æ¥çºè¡ã®ãšãã¯ãŒã ããšã¹ ããããš
ã¬ã€ãŠã€ãªã¢ã ã¹ ãŠã€ãªã¹ã®ç¬¬2456953å·ã
1958幎11æ25æ¥çºè¡ã®ãšããŠã€ã³ ãšãã ã©ã³
ãã®ç¬¬2861885å·ã1973幎ïŒæ25æ¥çºè¡ã®ãã©ã³
ã·ã¹ ãžãšã³ãšãã³ã¹ã®ç¬¬3761276å·ã1973幎ïŒ
æ25æ¥çºè¡ã®ãã«ã〠ããããšã« ãã«ãã³ã®
第3761266å·ã1973幎ïŒæ29æ¥çºè¡ã®ã¹ãŒã¶ã³
ã¹ã¿ãŒ ã³ãªã¢ãŒãšããŒã« ããªãŠã¹ã¿ãŒ ã®ã«
ãã³ ãžãã¢ãŒã®ç¬¬3736140å·ããã³1973幎ïŒæ
ïŒæ¥çºè¡ã®ããŒã« ããªãŠã¹ã¿ãŒ ã®ã«ãã³ ãž
ãã¢ãŒãããã«ã ãžãšãŒãž ã©ã¬ãŒããã³ãµã
ã¹ ããã«ã ã³ã¹ãŒã«ã¯ã®ç¬¬3730723å·ãããã
ãŸãè±åœç¹èš±æ现æžã«ã¯N.V.ã²ããŒã ããªã
ãããã¯ã·ãšã³ã1952幎ïŒæïŒæ¥ã«åºé¡ãã第
723019å·ãããã æã ã®çºæã§æçšãªããã²ã³åéä¹³å€ã¯åœè©²æ
è¡ã®çç·Žè ã«ã¯å ¬ç¥ã§ããããã®çµæã補æ³ãã
ã³å¡è£ ã«é¢ãããã詳现ãªããšã¯ãäŸãã°ããªã
ã¯ã ã©ã€ã»ã³ã·ã³ã° ã€ã³ããã¯ã¹92å·»ã1971
幎12æããããªã±ãŒã·ãšã³9232ã107â109é ã«èš
èŒãããŠããã äžã€ã®æ æ§ã«åŸãã°ãæ¬çºæã®ããã²ã³åéä¹³
å€å±€ã¯ã²ã©ãã³ã«åæ£ãããæå æ§ããã²ã³åé
ãããªããåã¿ã¯çŽ0.2ãªãã2ÎŒmã§ãããè²çŽ
åæäŸææã¯ã¢ã«ã«ãªæ§æº¶æ¶²ãééãããããªã
ãŒãã€ã³ããŒäŸãã°ã²ã©ãã³ã«åæ£ãããŠåã¿çŽ
ïŒãªãã7ÎŒmã®å¥ã®å±€ã圢æãããã®å±€ã¯ãåã¿
çŽïŒãªãã5ÎŒmã®ã¢ã«ã«ãªæ§æº¶æ¶²ãééãããã
ãªããŒäžéå±€äŸãã°ãŒã©ãã³ãšçµã¿åãããŠã
ããå¿è«ããããã®åã¿ã¯ããããã®ãã®ã«éã
ããæèŠã®è£œåã«åŸã€ãŠå€æŽããŠãããã æ¬çºæã®åçãšã¬ã¡ã³ãçšæ¯æäœã¯ããããè
ãŠãããã®åççæ§è³ªã«æªåœ±é¿ãåãŒãããŸã寞
æ³çã«å®å®ã§ããéãããããªãææã§ãã€ãŠã
ãããå žåçãªæè»æ§ã®ããã·ãŒãç¶ææã¯ãäŸ
ãã°çé¢ãããã¯äž¡é¢ã«Î±âãªã¬ãã€ã³ããªããŒ
äŸãã°ããªãšãã¬ã³ãå¡åžããçŽæ¯æäœã§ããã
ãã®ææã«ã¯ããããã»ã«ããŒãº ãã€ã«ã ãé ¢
é žã»ã«ããŒãºãã€ã«ã ãããªïŒããã«ã¢ã»ã¿ãŒ
ã«ïŒãã€ã«ã ãããªã¹ãã¬ã³ ãã€ã«ã ãããª
ïŒãšãã¬ã³ ãã¬ãã¿ã©ãŒãïŒãã€ã«ã ãããªã«
ãŒãããŒã ãã€ã«ã ãããªãšãã¬ã³ããã³ããª
ãããã¬ã³ ãã€ã«ã ã®åŠãããªÎ±âãªã¬ãã€ã³
ããã³é¢é£ãã€ã«ã ãããã¯æš¹èææãæããã
ããæ¯æäœã¯éåžžåã¿ãçŽ0.05ãªãã0.15mmã§ã
ãã è²åœ©åçã§ã®äœ¿çšã«ã¯ãææã®åªææ©èœããã
ã¯ããã§ãªããã°æ¡æ£ããè²çŽ ã®åºçãåŸããã
éããåå容局ãšããŠãããªãææã䜿çšããã
ãšãã§ãããéžã°ããç¹å¥ãªææã¯å¿è«åªæãã
è²çŽ ã«äŸåãããé žæ§è²çŽ ã¯åªæããããšã«ãªã€
ãŠãããªãã°ãåå容局ã¯æ¬¡ã®ååç©ããæãåŸ
ãããããã¯ãããå«æãåŸãããã®ãããªåå
ç©ãšããŠã¯ãå¡©åºæ§ããªããŒåªæå€äŸãã°1959幎
ïŒæ14æ¥çºè¡ã®ãã€ã¹ ãšã ãã³ã¹ã¯ã®ç±³åœç¹
èš±æ现æžç¬¬2882156å·ã«èšèŒãããããã« ã¡ã
ã« ã±ãã³ã®ã¢ããã°ã¢ããžã³èªå°äœã®ããªã
ãŒãããã³å¡©åºæ§ããªããŒåªæå€ãšèªå°äœäŸãã°
ããªâïŒâããã«ããªãžã³ãããªâïŒâããã«ã
ãªãžã³ ã¡ãâïœâãã«ãšã³ ã¹ã«ããªããŒãã
ãã³1949幎10æ11æ¥çºè¡ã®ãããŒã ãšãã ã¹
ãã©ãŒã°ãšã¬ã¹ãªãŒ ãžãŒ ãã«ãã«ãŒã®ç±³åœç¹
èš±æ现æžç¬¬2484430å·ã«èšèŒã®é¡äŒŒååç©ãã¢ã¯
ãã¢ãŒã²ããŒã A.G.ã1971幎ïŒæ11æ¥ã«åºé¡
ãããã€ãç¹èš±åºé¡å ¬å第2200063å·ã«èšèŒã®å
åç©ãæãããããé©åœãªåªæãã€ã³ããŒã«ã¯ã
ã¢ã·ã«ã¹ãã¬ã³ããªããŒã®ã°ã¢ãã«ããã©ãŸã³èª
å°äœãæãããããã®ååç©ã¯äŸãã°ã¢ã¯ãã¢ãŒ
ã²ããŒãA.G.ã1970幎ïŒæ28ç®ã«åºé¡ããå ¬å
ãã€ãç¹èš±æ现æžç¬¬2009498å·ã«èšèŒãããŠããã
ãããäžè¬ã«ã¯ãä»ã®ãã€ã³ããŒäŸãã°ãŒã©ãã³
ãäžèšåªæãã€ã³ããŒã«å ããã®ããããå¹æç
ãªåªæçµæç©ã¯ã»ãã«ããªã¡ãã«ã¢ã³ã¢ããŠã
ãããã€ããšãé·é第ïŒçŽã¢ã³ã¢ããŠã ããã
ã¯ããã¹ãããŠã ååç©ãããã¯ç¬¬ïŒçŽã¹ã«ãã
ãŠã ååç©ã§ãã€ãŠãåŸè ã®äºã€ã®ååç©ã¯äŸã
ã°å ±ã«1966幎ïŒæïŒæ¥çºè¡ã®ãããããŠãªã«ã¿ãŒ
ãšã ããã·ãŠãšã±ãŒã¹ ã€ãŒ ãŠã€ããã¢ã¢
ãŒã®ç±³åœç¹èš±æ现æžç¬¬3271147å·ãšç¬¬3271148å·ãš
ã«èšèŒãããŠãããããéå±å¡©ãããã³é žæ§è²çŽ
ãšé£æº¶æ§ååç©ãçæãããã®æ°Žé žåç©ã䜿çšã
ãŠããããè²çŽ åªæå€ã¯åå容局äžã®æ®éã®èŠªæ°Ž
æ§ãã€ã³ããŒã®äžã€äŸãã°ãŒã©ãã³ãããªããã«
ãããªãã³ãããã¯éšåçãããã¯å®å šã«å æ°Žå
解ããã»ã«ããŒãºãšã¹ãã«äžã«åæ£ãããã äžè¬ã«è¯å¥œãªçµæãåŸãããã®ã¯ã奜ãŸããã¯
ã¢ã«ã«ãªæ§æº¶æ¶²ãééãããåå容局ãéæã§çŽ
ïŒãªããçŽ10ÎŒmã®åã¿ãæã€å Žåã§ããããã®
åã¿ã¯å¿è«ææã®çµæã«å¿ããŠå€æŽããããšãã§
ãããåå容局ã¯ãåªæãããè²çŽ åãéè²ãã
ä¿è·ãã玫å€ç·åžåæãã¹ãã«ãã³ãã¯ããªã³ã
ããªã¢ãžã³ããªããµãŸãŒã«ã®åŠãè¢å å¢çœå€ãã¯
ããããŒã«ãã¢ã«ãã«ããšããŒã«ã®åŠãè²çŽ å®å®
å€çãå«æããŠãããã æ¬çºæã«åŸãèãŠãããã®è²çŽ åå容ãšã¬ã¡ã³
ãäžã«PHäœäžå€ã䜿çšãããšãé垞転åãããå
ã®å®å®æ§ãå¢å ãããäžè¬ã«ãPHäœäžå€ã¯ãæå¶
åŸçæéå ã«åå±€ã®PHãçŽ13ãããã¯14ããå°ã
ãšã11ãžã奜ãŸããã¯ïŒãªããïŒãžäœäžãããã
ã®ã§ãããäŸãã°ã1968幎ïŒæïŒæ¥çºè¡ã®ãšããŠ
ã€ã³ ãšãã ã©ã³ãã®ç±³åœç¹èš±æ现æžç¬¬
3362819å·ã«é瀺ãããããªããŒé žãåºäœé žãã
ããã¯1952幎ïŒæ29æ¥çºè¡ã®ãšããŠã€ã³ ãšãã
ã©ã³ãã®ç±³åœç¹èš±æ现æžç¬¬2584030å·ã«é瀺ã
ããéå±å¡©äŸãã°é ¢é žäºéãç¡«é žäºéãé ¢é žãã°
ãã·ãŠã çã䜿çšã§ãè¯å¥œãªçµæãäžããããã®
ãããªPHäœäžå€ã¯çŸååŸèãŠãããã®PHãæžå°ã
ããŠçŸåãçµçµããããã以äžã®è²çŽ ã®è»¢åãå®
質çã«æžå°ãããããããŠè²çŽ åãå®å®ã«ããã å®éã«ã¯ãäžæŽ»æ§ãªæé調ç¯å±€ããªãã¡ã¹ããŒ
ãµãŒå±€ãPHäœäžå±€ã®äžã«éããŠãããããã®å±€ã¯
äžæŽ»æ§ãªã¹ããŒãµãŒå±€ãéãã¢ã«ã«ãªã®æ¡æ£é床
ã«å¿ããŠPHæžå°ã®æéã調ç¯ããªãã¡ã³ã³ãããŒ
ã«ãããã®ã§ããããã®ãããªæé調ç¯å±€ã®äŸãš
ããŠã¯ããŒã©ãã³ãããªããã«ã¢ã«ã³ãŒã«ããã
ã¯1969幎ïŒæ15æ¥çºè¡ã®ã¬ãªããŒã ã·ãŒ ãã¢
ãŒããŒããã¯ãŒã ãžãŒ ããžã€ãŒã¹ããã³ãªã
ã€ãŒã ãããªãŠãŒã€ã³ã°ã®ç±³åœç¹èš±æ现æžç¬¬
3455686å·ã«èšèŒãããã³ãã€ãã®ãã¹ãŠãæã
ããããæé調ç¯å±€ã¯ãåºã枩床ç¯å²ã«äºã€ãŠ
çš®ã ã®åå¿é床ããªããã®ã«å¹æçã§ãããäŸã
ã°æå¶ã宀枩以äžã®æž©åºŠäŸãã°35ãªãã37âã§å®
æœããå Žåãæ©ãããPHäœäžãé²æ¢ãããæé調
ç¯å±€ã¯éåžžåã¿ãçŽ2.5ÎŒmãªããçŽ18ÎŒmã§ããã
ç¹ã«è¯å¥œãªçµæãåŸãããã®ã¯ãæé調ç¯å±€ãåŠ
ççµæç©ã«ãããã€ããå æ°Žå解ããå æ°Žå解æ§
ããªããŒãããã¯ãã®ãããªããªããŒã®æ··åç©ã
ããªãå Žåã§ããããã®ãããªå æ°Žå解æ§ããªã
ãŒã®äŸãšããŠã¯ãããªããã«ã¢ã»ããŒããããªã¢
ãããã»ã«ããŒãºãšã¹ãã«çãæããããã æ¬çºæã§äœ¿çšãããã¢ã«ã«ãªæ§åŠççµæç©ã¯ã¢
ã«ã«ãªæ§ææäŸãã°æ°Žé žåãããªãŠã ãçé žãã
ãªãŠã ãããã¯ãžãšãã«ã¢ãã³ã®åŠãã¢ãã³ã®å¥œ
ãŸããã¯11以äžã®PHãæã€åŸæ¥ã®æ°Žæº¶æ¶²ã§ããåŸ
ãã äžã€ã®æ æ§ã«åŸãã°ãã¢ã«ã«ãªæ§åŠç液ã¯ãã
ã²ã³åéã®éå ãéè¡ããæ¡æ£æ§çŸåå€äŸãã°ã¢
ã¹ã³ã«ãã³é žããããã¯ïŒâãã©ãŸãªãžãã³ç³»çŸ
åå€äŸãã°ïŒâããšãã«âïŒâã¡ãã«âïŒâãã©
ãŸãªãžãã³ãå«æããã æ¬çºæã§äœ¿çšããã¢ã«ã«ãªæ§åŠççµæç©ã¯ãæ
å æ§ãšã¬ã¡ã³ããå å·¥ã®ããã«ã¡ã©ããååºãã
åŸã¯ãã®ãšã¬ã¡ã³ãããã以äžã¯ç¢ºå®ã«é²å ããª
ãããã«ãããããæžæå€äŸãã°ã¡ãã¬ã³ãã«
ãŒãããã眮æããç°ç¯ç°åŒååç©ãïŒïŒ4â²âã
ããªãžããŠã å¡©çãå«ãã§ãããã ãã®æº¶æ¶²ãé«ååéããªããŒã®åŠãå¢ç²æ§åå
ç©ãäŸãã°ããããã·ãšãã«ã»ã«ããŒãºã®åŠãã¢
ã«ã«ãªæ§æº¶æ¶²ã«äžæŽ»æ§ãªæ°Žæº¶æ§ãšãŒãã«ãããã¯
ã«ã«ããã·ã¡ãã«ã»ã«ããŒãºãããªãŠã ã®åŠãã«
ã«ããã·ã¡ãã«ã»ã«ããŒãºã®ã¢ã«ã«ãªéå±å¡©ãå«
æããã®ã奜ãŸãããå¢ç²æ§ååç©ã®æ¿åºŠã¯ãåŠ
ççµæç©ã®çŽïŒãªããçŽïŒééïŒ ã§ããããšã奜
ãŸããããã®æ¿åºŠãªãåŠççµæç©ã«çŽ100ãªãã
çŽ200000mPa.sã®ç²åºŠãä»äžããã åŠçã¯ååšããç¿çŸåãŠãããäžã§ãäŸãã°é
åžžã®éè€å¡©æ¡æ£è»¢åïŒDTRïŒè£ 眮å ã§é²è¡ãã
ãã®è£ 眮å ã§ã¯åçææãåŠç液ãå ååžåãã
åŸãå¥ã ã®è²çŽ åå容ææãšã®æ¥è§Šãè¡ãªãã
ãããã®ç®çã«é©ããè£ çœ®ã¯DTRçŸåè£ çœ®ã§ã
ãCOPYPROOF CP38ïŒåååïŒã§ããã
COPYPROOFã¯ã¢ã³ããã«ãã³ïŒã¬ããŒã¯ãŒã»
ã³ ã¢ã°ãã¢ãŒã²ããŒãã®åååã§ããã å容局ãæå å±€ãšäžäœã§ãããã®ä»ã®æ æ§ã«åŸ
ãã°ãåŠç液ã¯ç Žè£å¯èœãªå®¹åšããå ããããã
ãããã¯ã¹ãã¬ãŒã§å ããããã æ¬çºæã§äœ¿çšã§ããç Žè£å¯èœãªå®¹åšã¯äžèšç±³åœ
ç¹èš±æ现æžã«é瀺ãããã¿ã€ãã®ãã®ã§ãããç±³
åœç¹èš±æ现æžãšããŠã¯ã1951幎ïŒæ27çºè¡ã®ãšã
ãŠã€ã³ ãšãã ã©ã³ãã®ç¬¬2543181å·ã1953幎
ïŒæ30æ¥çºè¡ã®ãŠã«ãªãã ãšã« ãž ã®ãªãã®
第2643886å·ã1953幎ïŒæ29æ¥çºè¡ã®ãšããŠã€ã³
ãšãã ã©ã³ã第2653732å· 1955幎11æïŒæ¥
çºè¡ã®ãŠã€ãªã¢ã ãžãšãŒ ããã¯ããŠãŒã³ ãž
ãã¢ãŒã®ç¬¬2723051å·ã1962幎10æïŒæ¥çºè¡ã®å ±
ã«ãžãšã³ ã€ãŒ ãã€ã³ããã«ã®ç¹èš±ã§ãã第
3056492å·ãšç¬¬3056491å·ãããã³1964幎10æ13æ¥
çºè¡ã®ãšããŠã€ã³ ãšãã ã©ã³ãã®ç¬¬3152515
å·ãæãããããäžè¬ã«ããã®ãããªå®¹åšã¯ã液
äœã空æ°ãéããªãææã®é·æ¹åœ¢ã·ãŒãã瞊æ¹å
ã«æãéããŠäºã€ã®å£ãäœãããã®å£ããã®çžŠãš
æ«ç«¯ã®ãµã¡ã«æ²¿ã€ãŠçžäºã«ã·ãŒã«ããŠåŠç液ãå ¥
ãã空ã©ãã圢æããããã®ã§ããã æ¬çºæã§äœ¿çšããã¢ã«ã«ãªæ§åŠççµæç©ã¯æ¢è¿°
ããåŠãç Žè£å¯èœãªå®¹åšäžã§äœ¿çšããŠåŠççµæç©
ãèãŠãããäžã«å ¥ããã®ã䟿å®çã«å®¹æããã
ããšãã§ããããåŠççµæç©ãèãŠãããå éšã§
æåºããä»ã®æ段ãçšããããšãã§ããããã®æ
段ãšããŠã¯äŸãã°ã1967幎11æ14æ¥çºè¡ã®ããã«
ã ãšã ããŒããŒã®ç±³åœç¹èš±æ现æžç¬¬3352674
å·ã«èšèŒãããŠããåŠããç®äžæ³šå°éã«äŒŒããã¥
ããã«ã¡ã©ã®ã«ãŒããªããžã«åä»ããé£ééšæã
çšããŠåŠç溶液ãæ³šå ¥ããæ段ãããã 次ã®æ¯èŒäŸãçšããŠæ¬çºæãããã«èª¬æããã
ãã¹ãŠã®ããŒã»ã³ãããžãšæ¯ã¯å¥ã«èšåããªãé
ãééã«ãããã®ã§ããã å®æœäŸ ïŒ è©ŠéšçïŒâ15ã®çšæ äž¡é¢ã15ïœïŒm2ã®ããªãšãã¬ã³å±€ãå¡åžãã
110ïœïŒm2ã®çŽã·ãŒããããªãäžå¡ãããèæ°Žæ§
çŽæ¯æäœãã³ããæŸé»ã§åŠçãããã®äžã«äžèšé
åºã§æ¬¡ã®å±€ãå¡åžããã ïŒïŒ 也ç¥ç¡¬ååŸå¹³æ¹ïœåœãäžèšååç©ãå«ãã¢
ã«ã«ãªééæ§ã³ãã€ãå±€ïŒ ãŒã©ãã³ 1.5ïœ ã·ã¢ã³è²çŽ æäŸãããã€ãååç©ïŒè¡šïŒåç §ïŒ
ïŒåŸè¿°ã®åŠãããŠçšæããåæ£æ¶²ããå ããïŒ
0.26ããªã¢ã« å¡©åéïŒèµ€ææ§ãŒã©ãã³å¡©åéä¹³å€ããå ã
ãïŒ 0.498ïœ ïŒïŒïŒâãã¹ïŒ1â²ïŒ1â²ïŒ3â²ïŒ3â²âããã©ã¡ãã«
ããã«ïŒãã€ããããã³ 0.102ïœ ïŒïŒ å¹³æ¹ïœåœã次ã®ååç©ãå«ãäžéå±€ïŒ ãŒã©ãã³ 1.155ïœ ïŒâããšãã«âïŒâã¡ãã«âïŒâãã©ãŸãªãžã
ã³ïŒåŸè¿°ã®åŠãããŠçšæããåæ£æ¶²ããå ã
ãïŒ 0.084ïœ ïŒâã¢ã»ãã«âïŒâãªã¯ããã·ã«(2)âãã€ãã
ããã³ 0.096ïœ ããžãšã³ã¿ããã€ã«ã¿ãŒããè²çŽ ãšããŠãã°ã¡
ã³ãã¬ãã146ïŒC.I.11000ïŒ 0.910ïœ ïŒïŒ å¹³æ¹ïœåœã次ã®ååç©ãå«ãã¢ã«ã«ãªéé
æ§ã³ãã€ãå±€ïŒ ãŒã©ãã³ 1.285ïœ ããžãšã³ã¿è²çŽ æäŸãããã€ãååç©ïŒè¡šïŒå
ç §ïŒïŒåŸè¿°ã®åŠãããŠçšæããåæ£æ¶²ããå ã
ãïŒ 0.31ããªã¢ã« ïŒïŒïŒâãã¹ïŒ1â²ïŒ1â²ïŒ3â²ïŒ3â²âããã©ã¡ãã«
ããã«ïŒãã€ããããã³ 0.104ïœ å¡©åéïŒç·ææ§ãŒã©ãã³å¡©åéä¹³å€ããå ã
ãïŒ 0.553ïœ ïŒïŒ å¹³æ¹ïœåœã次ã®ååç©ãå«ãäžéå±€ïŒ ãŒã©ãã³ 1.155ïœ ïŒâã¢ã»ãã«âïŒâãªã¯ã¿ãã·ã«(2)âãã€ãã
ããã³ 0.096ïœ ïŒâããšãã«âïŒâã¡ãã«âïŒâãã©ãŸãªãžã
ã³ 0.084ïœ ãšããŒããã€ã«ã¿ãŒããè²çŽ ãšããŠãã°ã¡ã³ã
ãšããŒ83ïŒC.I.20000ïŒ 1.085ïœ ïŒïŒ å¹³æ¹ïœåœã次ã®ååç©ãå«ãã¢ã«ã«ãªéé
æ§ã³ãã€ãå±€ïŒ ãŒã©ãã³ 2.046ïœ é»è²è²çŽ æäŸãããã€ãååç©Y1ïŒåŸè¿°ã®åŠã
ããŠçšæããåæ£æ¶²ããå ããïŒ 0.56ããªã¢ã« ïŒïŒïŒâãã¹ïŒ1â²ïŒ1â²ïŒ3â²ïŒ3â²âããã©ã¡ãã«
ããã«ïŒãã€ããããã³ 0.187ïœ å¡©åéïŒéææ§ãŒã©ãã³å¡©åéä¹³å€ããå ã
ãïŒ 0.500ïœ ïŒïŒ å¹³æ¹ïœåœã次ã®ååç©ãå«ãä¿è·å±€ïŒ ãŒã©ãã³ 0.112ïœ ïŒâããšãã«âïŒâã¡ãã«âïŒâãã©ãŸãªãžã
ã³ã®åæ£æ¶²ã®äœè£œ äœè£œã¯æ¬¡ã®æåããµã³ããã«ã«ãããããšã«
ããè¡ãªãããã ãŒã©ãã³ 40ïœ ïŒâããšãã«âïŒâã¡ãã«âïŒâãã©ãŸãªãžã
ã³LOMAR ïŒåååïŒã®40ïŒ æ°Žæº¶æ¶² 10ml èžæºæ°Ž 850ml ïŒLOMAR ã¯çž®ååå¿ã«ãã«ã ã¢ã«ãã
ãã䜿çšããããã¿ã¬ã³ã¹ã«ãããŒãçž®åç©ã«
察ããç±³åœN.J.ãã¯ãŒã¯ ããã³ååŠäŒç€Ÿã®å
ååã§ããïŒã ïŒïŒïŒâãã¹ïŒ1â²ïŒ1â²ïŒ3â²ïŒ3â²âããã©ã¡ã
ã«ããã«ïŒãã€ããããã³ã®åæ£æ¶²ã®äœè£œ ïŒïŒïŒâãã¹ïŒ1â²ïŒ1â²ïŒ3â²ïŒ3â²âãã©ã«ã¡ã
ã«ããã«ïŒãã€ããããã³500ïœãé ¢é žãšãã«
ïŒãšããªã¯ã¬ã·ã«ãã¹ããšãŒã500ïœã«æº¶è§£
ãããããŠ70âã§NEKAL BX38.5ïœãå ãã
ïŒNEKAL BXã¯ïŒïŒïŒâãžâã€ãœããã«ãã
ã¿ã¬ã³âïŒâã¹ã«ãã³é žãããªãŠã ã«å¯Ÿãã西
ãã€ãBASF瀟ã®åååã§ããïŒã溶液ã55â
ãŸã§æŸå·ãã次ãã§å åæ¹æããªããã ãŒã©ãã³ 250ïœ è±å¡©æ°Ž 2.2 é ¢é žãšãã« 500ml ãå«ã溶液ïŒ55âã«ä¿æž©ïŒã«å ããã ããããŠåŸãããäºååæ£æ¶²ã次ãã§ããã«
é«å§ãã¢ãžãã€ã¶ãŒäžã§åŠçããããã§é ¢é žãš
ãã«ãæžå§äžèžçºã«ããé€ãã é»è²è²çŽ æäŸååç©Y1ã®åæ£æ¶²ã®äœè£œ ãšãŒãããç¹èš±åºé¡ç¬¬0038092å·ã«èšèŒãã
ãåŠãåæããã次ã®æ§é åŒïŒ ãæã€ååç©Y1ã®åæ£æ¶²ã次ã®æåãçšããŠ
äœè£œããã ååç©Y1 50ïœ ãŒã©ãã³ 75ïœ MARLON â396ïŒåååïŒã®10ïŒ æ°Žæº¶æ¶²
50ml èžæºæ°Ž 625ïœ ååç©Y1ããŸãé ¢é žãšãã«ã«æº¶è§£ãã次ã
ã§MARLON â396ïŒåååïŒã®æ°Žæº¶æ¶²ãäº
ãæ·»å ããæ瀺éã®æ°Žã«æº¶è§£ãããŒã©ãã³ã«æ¿
ããæ¹æããªããæ·»å ãããããã§é ¢é žãšãã«
ãæžå§äžèžçºã«ããé€ããã MARLON â396ã¯æ¬¡ã®åŒïŒ ããã§ïŒ²ã¯C10âC13nâã¢ã«ãã«ã§ãããã
æã€æ¹¿æœ€å€ã«å¯Ÿãã西ãã€ã AGããŒã«ïŒãŠ
ãšã¹ããã¢ãŒã¬ã³ ååŠäŒç€Ÿãã«ãºã®åååã§
ããã ããžãšã³ã¿ãããã¯ã·ã¢ã³è²çŽ æäŸååç©ã®å
æ£æ¶²ã®äœè£œ äœè£œã¯æ¬¡ã®æåã䜿çšãã以å€ã¯ååç©Y1
ã®åæ£æ¶²ã®äœè£œãšåæ§ã«è¡ãªãããã è²çŽ æäŸååç© 17ïœ ãŒã©ãã³ 25ïœ MARLON â396ïŒåååïŒã®10ïŒ æ°Žæº¶æ¶²
10ml èžæºæ°Žãå ã㊠300ïœ ãŸã§ã«ããã ããžãšã³ã¿ãããã¯ã·ã¢ã³æäŸååç©ã®é ¢é ž
ãšãã«ã«å¯Ÿãã溶解床ãäžå åãªå Žåã«ã¯ãäž
èšæåããµã³ããã«ã«ãããããšã«ããåæ£æ¶²
ãäœè£œããã äžè¿°ã®æäœã«åŸã€ãŠãããžãšã³ã¿ãããã¯ã·ã¢
ã³è²çŽ æäŸååç©ïŒè¡šïŒïŒã®éžæãçžäºã«ç°ãªã
ããããã®è©ŠéšçïŒïŒâ15ïŒãäœè£œãããæ°çµã®
æ¯èŒè©Šéšã§çšããååç©ã®æ§é ãè¡šïŒâïŒã«ç€º
ãã é²å ãšåŠç è©ŠéšçïŒâïŒã®åã ãã·ã¢ã³ïŒããªãã¡èµ€è²å
ç·ãåžåããïŒãã€ã«ã¿ãŒãéããŠé²å ããŠé»æ
ããã³ç·æå±€ãå åé²å ããã次ãã§åäžè©Šéšç
ãå®æ°0.15ã®å åŠæ¥ãéããŠçœè²å ã«é²å ããã
è©ŠéšéšçïŒâ15ã®åã ãããžãšã³ã¿ïŒããªãªãã¡
ç·è²å ç·ãåžåããïŒãã€ã«ã¿ãŒãéããŠé²å ã
ãŠé»æããã³èµ€æå±€ãå åé²å ããã次ãã§åäž
è©Šéšçãå®æ°0.15ã®å åŠæ¥ãéããŠçœè²å ã«é²å
ããã é²å ããè©Šéšçããæ¡æ£è»¢ååŠçè£ ã§ãã®ç¿ã®
äžã«åœã次ã®ååç©ãããªã氎溶液ãå«ã
COPYPROOF CP 38ïŒåååïŒäžã§ïŒåéå容
ææïŒåŸè¿°ããåŠãçµæç©ïŒãšæ¥è§ŠãããŠåŠçã
ãã ããªç¡«é žãããªãŠã ïŒïœ æ°Žé žåãããªãŠã 15ïœ ïŒïŒïŒâãã¹âããããã·ã¡ãã«âã·ã¯ããã
ãµã³ 12.5ïœ ïŒâã¡ãã«âïŒâãããã«âïŒïŒïŒâãããã³
ãžãªãŒã« 12.5ïœ èåã«ãªãŠã ïŒïœ èžæºæ°Žãå ã㊠1000ml ãŸã§ã«ããã å容ææã®çµæ äžèšæå æ§ææã«å¯ŸããŠèšèŒãããšåãæ¯æäœ
ã«å¹³è¡ïœåœã次ã®çµæãæã€å¡åžæ¶²ãå¡åžããã ãŒã©ãã³ ïŒïœ ããªããšãã«âïœâãããµãã·ã«ãã¹ãããŠã
ãããã€ã ïŒïœ
ïŒ ã®NasO2å¡©ãNaClãšæ··åããŠå«æããïŒ14.4
ïœãé ¢é ž225mlãšæ°Ž45mläžã§æ¹æãããæ¹æã¯80
âã§ïŒæéé²è¡ãããããã§åå¿æ··åç©ã50âã«
å·åŽãããæ²æŸ±ãåžåŒéã§åé¢ããé žãç¡ããª
ããŸã§ã¡ã¿ããŒã«ïŒæ°ŽïŒå®¹ç©ã§ïŒïŒïŒïŒã®æ··åç©
ã§æŽæ»ãããçæç©ïŒïŒ¡ïŒã颚ãéãããªãŒã
ã³äžã§ä¹Ÿç¥ãããåéã22ïœã ååç©ïŒïŒ¡ïŒ10.97ïœãšïœâãã³ãŸããã³
1.78ïœãç ®æ²žéæµãããŠãããžã¯ãããšã¿ã³120
mläžã§ïŒæéæ¹æããã20âã«å·åŽåŸãçæãã
埮现ãªæ²æŸ±ãåžåŒã«ããåé¢ãå°éã®ãžã¯ãããš
ã¿ã³ã§æŽæ»ããã液ãæ¿çž®ããŠã§ããã ãå€ã
ã®ååç©ïŒ¹ãååãããåéã10.6ïœã ååç©ïŒïŒ15.7ïœãšååç©ïŒïŒ¢ïŒïŒ35éé
ïŒ ã®NaSO2å¡©ãNaClãšæ··åããŠå«æããïŒ37.4
ïœãé ¢é ž300mlãšæ°Ž50mläžã§æ¹æãããæ¹æã¯70
âã§ïŒæéé²è¡ãããããã§åå¿æ··åç©ã50âã«
å·åŽãããæ²æŸ±ãåžåŒéã§åé¢ããé žãç¡ããª
ããŸã§ãã¡ã¿ããŒã«ïŒæ°ŽïŒå®¹ç©ã§ïŒïŒïŒïŒã®æ··å
ç©ã§æŽæ»ãããçæç©ïŒïŒ¢ïŒã颚ãéããŠãªãŒ
ãã³äžã§ä¹Ÿç¥ãããåéã21ïœã ååç©ïŒïŒ¢ïŒ10.12ïœãšïœâãã³ãŸããã³1.3
ïœãšãç ®æ²žéæµãããŠãããžã¯ãããšã¿ã³120ml
äžã§ïŒæéæ¹æããã20âã«å·åŽåŸãçæãã埮
现ãªæ²æŸ±ãåžåŒã«ããåé¢ãå°éã®ãžã¯ãããšã¿
ã³ã§æŽæ»ããã液ãæ¿çž®ããŠã§ããã ãå€ãã®
ååç©ïŒãååãããåéã10ïœã ååç©ïŒïŒ15.7ïœãšååç©ïŒïŒ£ïŒ17.7ïœã
é ¢é ž300mlãšæ°Ž50mläžã§æ¹æãããæ¹æã¯70âã§
ïŒæéé²è¡ãããããã§åå¿æ··åç©ã50âã«å·åŽ
ãããæ²æŸ±ãåžåŒéã§åé¢ããé žãç¡ããªããŸ
ã§ã¡ã¿ããŒã«ïŒæ°ŽïŒå®¹ç©ã§ïŒïŒïŒïŒã®æ··åç©ã§æŽ
æ»ãããçæç©ïŒïŒ£ïŒã颚ãéãããªãŒãã³äž
ã§ä¹Ÿç¥ãããåéã28.5ïœã ååç©ïŒïŒ£ïŒ14.8ïœãšïœâãã³ãŸããã³1.6
ïœãšãç ®æ²žéæµãããŠãããžã¯ãããšã¿ã³150ml
äžã§ïŒæéæ¹æããã20âã«å·åŽåŸãçæãã埮
现ãªæ²æŸ±ãåžåŒã«ããåé¢ãå°éã®ãžã¯ãããšã¿
ã³ã§æŽæ»ããã液ãæ¿çž®ããŠã§ããã ãå€ãã®
ååç©ïŒ£ãååãããåéã9.7ïœã ååç©ïŒ¹ãïŒããã³ïŒ£ã®è£œé ã«ãããäžé
çæç©ã®åæ ïœâãã³ãŸããã³1296ïœãé ¢é ž6.6äžã§æ¹æ
ããã溶液ã10â15âã«å·åŽããããã¿ãžãšã³
780ïœïŒ1250mlïŒãæ¹æããªããæ·»å ãããåå¿
æ··åç©ãïŒæ¥é宀枩ã«ä¿æãã次ãã§ïŒæééæµ
ãããªããç ®æ²žããã宀枩ãŸã§å·åŽåŸãçæãã
æ²æŸ±ãåžåŒéã«ããåé¢ããç²ïŒé ¢é žïŒå®¹ç©ã§
ïŒïŒïŒïŒæ··åç©1200mlã§æŽæ»ã次ãã§æ°ŽïŒã¡ã¿ã
ãŒã«ïŒå®¹ç©ã§ïŒïŒïŒïŒæ··åç©ã§æŽæ»ãããçæç©
ã§ããïŒïŒïŒâãžããããã·âïŒïŒïŒâãžããã
ããã¿ã¬ã³ã颚ãéãããªãŒãã³äžã§ä¹Ÿç¥ããã
åéã1285ïœã ïŒïŒïŒâãžããããã·âïŒïŒïŒâãžããããã
ã¿ã¬ã³36.88ïœãã©ããŒããã±ã«ïŒmlãšæ··åãã
ç¡æ°Žãšã¿ããŒã«ã容ç©250mlã«ãªããŸã§æ·»å ããã
éå ããæ¯çªãªãŒãã¯ã¬ãŒãäž23âã§ã105.3
KgïŒcm2ã®æ°ŽçŽ å§ããåºçºããŠå®æœããã20å以å
ã§ãçè«å€ã®110ïŒ ã«çžåœããæ°ŽçŽ æ¶è²»ãèªããã åå¿æ··åç©ãæ°Ž600mläžã«æ³šå ¥ããæ²æŸ±ãåžåŒ
ã«ããé€ãããæ°Žã§æŽæ»åŸãåŸãããïŒïŒïŒâãž
ããããã·âïŒïŒïŒïŒïŒïŒïŒâããã©ããããã
ã¿ã¬ã³ã也ç¥ãããåéã24.6ïœã ïŒïŒïŒâãžããããã·âïŒïŒïŒïŒïŒïŒïŒâãã
ã©ãããããã¿ã¬ã³410ïœãæ¿é ¢é ž520mläžã§æ¹æ
ããã80âã§BR3ã¬ã¹ãïŒæéå°å ¥ãæ¹æãç¶ç¶
ãããåå¿ãã¹ã¯æž©åºŠã100âãŸã§äžæãããšæ¥
æ¿ã«åºåãããåå¿æ··åç©ãå·åŽããæ°Ž2.4ã«
溶ãããé ¢é žãœãŒã600ïœã®æº¶æ¶²ã«æå ¥ãããã
ã¹å šäœãæ¹æããŠåŸ®çŽ°ãªæ²æŸ±ãçæãããããã
åžåŒéã«ããåé¢ããä»åºŠã¯ã¡ã¿ããŒã«1.2
äžã§å床æ¹æããããã«æ°ŽïŒãæ·»å ããã粟補
ããçæç©ãåžåŒéã«ããåé¢ãã颚ãéãã
ãªãŒãã³äžã§50âã§ä¹Ÿç¥ãããåéãïŒïŒïŒâãž
ããããã·âïŒâã¢ã»ãã«âïŒïŒïŒïŒïŒïŒïŒâã
ãã©ãããããã¿ã¬ã³495ïœãèç¹ã199âã ïŒïŒïŒâãžããããã·âïŒâã¢ã»ãã«âïŒïŒ
ïŒïŒïŒïŒïŒâããã©ãããããã¿ã¬ã³51.5ïœãšã»
ãã«ãªãã·ãã³ãŒã³79.5ïœãå¡©åã¡ãã¬ã³200ml
ãšäžåŒåé ¢é ž125mlã®æ··åç©äžã§æ¹æãããåå¿
æ··åç©ãïŒâãŸã§å·åŽãããïœâããã«ãããªã«
115mlãïŒâã§ïŒæé以å ã§æ»Žäžãããåå¿æ··å
ç©ã«ã¡ã¿ããŒã«500mlãæ·»å ãããæ²æŸ±ãåžåŒ
éã«ããåé¢ããã¡ã¿ããŒã«80mlã§æŽæ»ã次ãã§
颚ãéãããªãŒãã³äžã§ä¹Ÿç¥ãããåéãç²ïŒïŒ
ïŒâãžããããã·âïŒâã¢ã»ãã«âïŒâïœâã»ã
ã«ãªãã·ããšãã«âïŒïŒïŒïŒïŒïŒïŒâããã©ãã
ãããã¿ã¬ã³105ïœãé ¢é žãšãã«ããåçµæ¶ããŠ
粟補ç©97ïœãåŸãã åèšç²Ÿè£œç©60ïœãšå°éã®ãããªãŠã ã¡ãã©ãŒã
ã«ãšãã¬ã³ã°ãªã³ãŒã« ã¢ãã¡ãã« ãšãŒãã«ã®
å åãªéãå ããŠå šå®¹ç©ã500mlãšãããæ°ŽçŽ ã¬
ã¹ã«ããéå ããæ¯çªãªãŒãã¯ã¬ãŒããçšã90â
95âã§ã105KgïŒcm2ã®æ°ŽçŽ å§ããåºçºããŠå®æœã
ãã ïŒæéã®æ¯çªåŸãçè«éã®90ïŒ ã®æ°ŽçŽ ã䜿çšã
ãããã©ããŒããã±ã«ãéã«ããé€ããéã«
ã¡ã¿ããŒã«300mlãšæ°ŽïŒå®¹ç©ã§ïŒïŒïŒïŒã®æ··åç©
ãæ·»å ããŠæ²æŸ±ãããç²å€§ã«ãªãããã«ãããæ²
柱ãåžåŒéã«ããåé¢ãã颚ãéãããªãŒãã³
äžã§ä¹Ÿç¥ãããåéãïŒïŒïŒâãžããããã·âïŒ
âïŒ1â²âããããã·ãšãã«ïŒâïŒâïœâã»ãã«ãªã
ã·ããšãã«âïŒïŒïŒïŒïŒïŒïŒâããã©ããããã
ã¿ã¬ã³55ïœããã®ãã®ã¯ååç©ïŒ¹ãïŒããã³
ã®è£œé ã«ãããŠãããã䜿çšãããçæç©
ïŒïŒã§ããã æ¬çºæã«åŸãããã²ã³åéåçææã¯ãã¢ã«ã«
ãªééæ§ã³ãã€ãåªäœäžã§ã¢ã«ã«ãªæ§æ¶²ãšæ¥è§Šã
ããšäžåã§ããããã€è²çŽ éšåãšãã©ã¹ãåºãæ
ã€äžè¬åŒ(G)ã«åŸããããã€ãååç©ãå«ãå°ããš
ãäžã€ã®ã¢ã«ã«ãªééæ§èŠªæ°Žæ§ããã²ã³åéã³ã
ã€ãä¹³å€å±€ãæ æããæ¯æäœãããªãããããŠå
èšååç©ã¯ããã²ã³åéçŸåå€ã«ãããåçææ
äžã®åãšããŠçŸåå¯èœãªããã²ã³åéãããé ã
é床ã§éå å¯èœã§ããããŸãéå å¯èœã§ã¢ã«ã«ãª
æ§æ¡ä»¶äžåèšè²çŽ éšåãæŸåºã§ããã å€è²åãäœãæ æ§ã«ãããŠã¯ãæ¬çºæã¯(1)ã¢ã«
ã«ãªééæ§ã³ãã€ãåªäœäžã§ã¯æåã¯äžåã§ã
ãããããŠããã²ã³åéçŸåå€ãšã¢ã«ã«ãªæ§ã®é
å äœçšã«ããã·ã¢ã³è²çŽ ãããããæ¡æ£æ§ã®ç¶æ
ã§åæåé¢ããåèšãããã€ãååç©ãšäœçšãã
ããã«çµåãããèµ€ææ§ããã²ã³åéä¹³å€å±€ã(2)
ããžãšã³ã¿è²çŽ ãæ¡æ£æ§ã®ç¶æ ã§åæåé¢ããã
ç¹ãç°ãªã€ãŠãã(1)ã®åèšååç©ãšäœçšãããã
ã«çµåãããç·ææ§ããã²ã³åéãšãã«ãžãšã³
å±€ãããã³(3)é»è²è²çŽ ãæ¡æ£æ§ã®ç¶æ ã§åæåé¢
ãããç¹ãç°ãªã€ãŠãã(1)ã®åèšååç©ãšäœçšã
ãããã«çµã¿åãããéææ§ããã²ã³åéä¹³å€å±€
ãæ æããæ¯æäœãããªãåçææã«é¢ããã åè²çŽ æäŸéšåã¯å®æããè²çŽ ã§ãè²çŽ ã«å€å
ãããã®ã§ãããããã®ã¿ã€ãã®è²çŽ ææã¯åœè©²
æè¡ã§å ¬ç¥ã§ãããã¢ãŸè²çŽ ãã¢ãŸã¡ãã³ïŒã€ã
ã³ïŒè²çŽ ãã¢ã³ãã©ããã³è²çŽ ãã¢ãªã¶ãªã³è²
çŽ ãã¡ãã·ã¢ãã³è²çŽ ããããªã³è²çŽ ãã·ã¢ã³è²
çŽ ãªã©ãæãããããè²çŽ ã«å€åãããã®ã«ã¯ã
PHã®å€åã®åŠãç°ãªãç°å¢ã«åããšãè€å¡©ãçæ
ããææãšåå¿ãããšãäºå€ç°æ§ãåãããšãå
åç©ã®pKaãå€ããåå¿ãåãããšããŸãçºè²å
ã®ååã«çµåããåºäŸãã°å æ°Žå解å¯èœãªã¢ã·ã«
åºãé€å»ãããšããã®å åžåç¹æ§ãæµ è²çã«ãã
ãã¯æ·±è²çã«å€åããååç©ãæããããããã
ãååç©ã¯äŸãã°ã1966幎ïŒæ12æ¥ã«çºè¡ããã
ãŠãªã«ã¿ãŒ ãžãšãŒ ãŠãšã€ã¢ãŒããšãŠã€ã«ããŒ
ãšã ãµã«ããã³ã®ç±³åœç¹èš±æ现æžç¬¬3260597
å·ã«èšèŒãããŠãããããæ æ§ã«ãããŠã¯ãè²çŽ
ã«å€åãããã®ãç¹ã«çºè²å ã®å ±åæ§é ã«åœ±é¿ã
ãååã«å æ°Žå解å¯èœãªåºãæã€ãã®ã極ããŠå¥œ
ãŸããããã®çç±ã¯ãã®ååç©ã¯ããã²ã³åéä¹³
å€å±€ã«çŽæ¥æ··å ¥ããããšãã§ãããããããã¯ã
ã®å±€ã®é²å åŽã«ã§ããããã²ã³åéã®é²å ã«å¹æ
çãªå ãå®è³ªçã«æžå°ãããããšãªããæ··å ¥ãã
ããšãã§ããããã§ãããé²å åŸããã®è²çŽ ã¯äŸ
ãã°ã¢ã·ã«åºãå æ°Žå解ã§é€ããŠããããã®åè²
çŽ ãçæãããããšã«ããé©åœãªè²ã«è»¢æããã
ããšãã§ããã æ¬çºæã®äžè¬åŒ(G)ã«åŸã1HRååç©ã¯ãé£æ¥
å±€ãããã¯å容ãšã¬ã¡ã³ãã«è²çŽ å®äœã転åãã
ãããšãæãŸããæ¡æ£è»¢åæ³ã«ãããŠç¹ã«äœ¿çšã
ããã æ¬çºæã«åŸãçšéã«çšãã1HRååç©ã¯ãé
åžžã®æ¹æ³ã®äžã€ã«ãããåçææã®å±€ã«çšããå¡
åžæ¶²äžã«æ··åãããå¡åžæ¶²ïŒåœãã«çšãããã®
ååç©ã®éã¯ãäŸãã°åæåé¢ããããšã«ãªã€ãŠ
ããåççã«æçšãªåºã«ãããæ¯èŒçåºç¯å²å ã«
å€åãããããŠæãé©åœãªæ¿åºŠã¯ç°¡åã®ãã¹ãã«
ãã€ãŠèŠåºãããšãã§ãããäŸãã°ã0.01ãªãã
10ïœã奜ãŸããã¯0.1ãªãã0.5ïœã®1HRååç©ã
m2åœã䜿çšã§ãããå¡åžæ¶²äŸãã°ããã²ã³åéãš
ãã«ãžãšã³äžã«æ··ãããã«ã¯ããµã³ããã«ã«ãŠäœ
ã€ãåæ£æ¶²ãããã¯è¶ é³æ³¢ãçšããŠãããã ä»ã®æ¹æ³ã«åŸãã°ã1HRååç©ããããã²ã³
åéãšããŠéæã«ã¯çŸåå€ç©è³ªãšãäžç·ã«ããŠæ
è¬ãã€ã¯ãã«ãã»ã«ã®åœ¢ã«ããŠèŠªæ°Žæ§ã³ãã€ãå±€
äžã«ãŸã蟌ãããšãèŠæãããããã®å ŽåãäŸã
ã°1955幎ïŒæïŒæ¥ã«çºè¡ãããã¬ãªãã«ã ãŽã
ããŠã€ã¹ããŒã®ç±³åœç¹èš±æ现æžç¬¬2698794ã«èšèŒ
ãããŠããåŠããäºã€ä»¥äžã®æãæ¹ã®ç°ãªããã
ã²ã³åéä¹³å€ãšé©åœãªèæ¡æ£æ§ååç©ãšãæè¬æ··
åãã±ããä¹³å€ã®åœ¢ã§äžã€ã®å±€å ã§äžç·ã«ããŠã
ããã1HRååç©ãã¢ã«ã«ãªæ§æ°Žæº¶æ¶²ãã芪氎
æ§ãã€ã³ããŒäžã«ãŸã蟌ãå å«æ¹æ³ãããã®åå
ç©ã®å æ°Žå解ã®å±éºãç¡ããšããçç±ã§çšããŠã
ããã ç¹å¥ã®æ æ§ã§ã¯ãåèšãããã€ãååç©ã¯ãã
ã²ã³åéä¹³å€å±€ã«é£æ¥ãã芪氎æ§ã³ãã€ãå±€å ã«
ååšãããã®é£æ¥å±€ã¯é²å äžã®å ¥å°å ã®æ¹åãã
èŠãŠããã²ã³åéä¹³å€å±€ã®èåŸã«äœçœ®ããã®ã奜
ãŸããã æ¬çºæã«åŸãç¹å®ã®æ æ§ã«ãããŠã¯ãã«ã¡ã©å
åŠççšã«èšèšããã«ã¡ã©ã®å Žåã«èªããããåŠ
ããäžå¯Ÿã®äžŠãã å å§éšæã®éã«éããŠåŠçãã
ã®ã«é©ããèãã€ã«ã ãŠãããã§ããåçææã
æäŸãããããã®ãŠãããã¯(1)åãã¯ã¢ã«ã«ãªé
éæ§ã³ãã€ãåªäœäžã§äžåã§ããããããŠããã²
ã³åéçŸåå€ãšã¢ã«ã«ãªæ§ã®éå äœçšã«ããè²çŽ
ãããããæ¡æ£æ§ã®ç¶æ ã§åæåé¢ããåèšãã
ãã€ãååç©ãçµåãããŠæã€ããã²ã³åéä¹³å€
å±€ãå«ãæå æ§ãšã¬ã¡ã³ãã(2)åè²çŽ å容局ã(3)
ã¢ã«ã«ãªæ§åŠççµæç©ãèãŠãããå éšã§æåºã
ãæ段äŸãã°ç Žè£å¯èœãªå®¹åšã§ãã€ãŠããã®å®¹åš
ã¯å å§éšæã«ãã€ãŠãã®å®¹åšã«ãããå§çž®åã§å®¹
åšã®å 容ç©ãèå éšã«æåºããããããèã®å å·¥
äžã«ååšããã®ã«é©ãããã®ã§ãããããã³(4)å
èšèãŠãããå éšã«ååšããã¢ã«ã«ãªæ§åŠççµæ
ç©ã«å¯å®¹æ§ã§ããããã²ã³åéçŸåå€ãããªãã æ¬çºæã®åçææã¯ã(1)å°ããšãäžã€ã®ããã²
ã³åéä¹³å€å±€ãšãã¢ã«ã«ãªééæ§ã³ãã€ãå±€äžã§
æåã¯äžåã§ããåèšãããã€ãååç©ãããªã
å°ããšãäžã€ã®ã¢ã«ã«ãªééæ§å±€ïŒãã®å±€ã¯ãã
ã²ã³åéãå«æããå±€ãšåäžå±€ã§ãã€ãŠãããïŒ
ãšãæ æããæ¯æäœãããªãåãšããŠé²å ããã
åçææã«ã¢ã«ã«ãªæ§åŠççµæç©ãé©çšãããªã
ããã«ãããŠåèšååç©ã¯ããã²ã³åéçŸåå€ã«
ãããææäžã®åãšããŠçŸåå¯èœãªããã²ã³åé
ãããé ãé床ã§éå å¯èœã§ããããŸãéå ãã
ãç¶æ ã§ã¢ã«ã«ãªæ§æ¡ä»¶äžè²çŽ ãæŸåºããããšã
ã§ãããã®ã§ããã(2)åçææäžã®åèšããã²ã³
åéã®åãšããŠã®çŸåã«åæ¯äŸããŠãåèšè²çŽ ã
åãšããŠæŸåºãããæ¡ä»¶ã®äžã§åèšã¢ã«ã«ãªæ§åŠ
ççµæç©ã䜿çšããéçšã§åèšåçææçšçŸåå€
ãæäŸãããããŠ(3)æåã«è²çŽ ããŸã蟌ãŸããŠã
ã€ãå±€ããè²çŽ ãåèšã¢ã«ã«ãªæ§åŠççµæç©ãšå ±
ã«æ¡æ£ãããŠãè²çŽ ãããŸäžã€ã®å±€ã«åãšããŠç§»
è¡ãããããšãããªãæ¹æ³ã«ãããŠæçšã§ããã è²çŽ åãäœãæ æ§ã«ãããŠã¯ãæ¬çºæã¯ã ïœïŒ æ¬çºæã«åŸãåçãšã¬ã¡ã³ãããé²å ãã
ããã²ã³åéä¹³å€å±€ã®åã ãçŸåããããã²ã³
åéçŸåå€ã®ååšäžã§ãã¢ã«ã«ãªæ§åŠççµæç©
ãçšããŠåŠçããŠããã®çŸåå€ãåãšããŠé žå
ãããããŠåãšããŠã®ããã²ã³åéã®çŸåã®é
ã®æ©èœãšããŠãéå ãããç¶æ ã§(a)è²çŽ ãæŸåº
ã§ããåèšäžåæ§ãããã€ãååç©ãéå ãã ïœïŒ éå ãããäžåæ§ååç©ããæ¡æ£æ§ã®ç¶æ
ã§åèšè²çŽ ãæŸåºãããã«å åãªæéã®éãå
èšåçææãåŠççµæç©ã®ã¢ã«ã«ãªæ§åªäœäžã«
ä¿æãããã㊠ïœïŒ åèšè²çŽ ã®å°ããšãäžéšãå容局ãšããŠäœ
çšããéæå å±€ã«è»¢åããããšãããªãæ¡æ£è»¢
åçè²åçæ³ã«é¢ããã ã«ã¡ã©å åŠçã«å¯ŸããŠã¯ãæå æ§ææã¯ãæå
æ§ããã²ã³åéä¹³å€å±€ããã¬ã«åãããã€æå å±€
ãšãã¢ã«ã«ãªééæ§ã§å ãåå°ããå容局ãšãã
ã²ã³åéä¹³å€å±€ã®éã«äœçœ®ãã奜ãŸããã¯äžéæ
å±€ãæã€éæå å±€å容ãšã¬ã¡ã³ããšã®äžäœççµå
ãçæããããã«ãåèšæå æ§ããã²ã³åéä¹³å€
å±€ãå容局ãšåãæ¯æäœã«å¡åžãããããã«æ§æ
ãããããšã奜ãŸããããã®ãããªææãçšãã
æ¹æ³ã§ã¯ãã¢ã«ã«ãªæ§åŠççµæç©ã¯åçãšã¬ã¡ã³
ãã®æå å€å±€ãšãéæã§é²å åã«éããããã«ã
ãŒã·ãŒããšã®éã«æ¿å ¥ããŠãããã æ¬çºæã®ãããã€ãååç©ãçšããŠæ¡æ£è»¢åç
è²æ³ãå®æœããã«ã¯ããã®ååç©ãšãå°ããšãäž
ã€ãé»åäŸäžäœïŒEDååç©ïŒãšåŒã°ããååç©
ã§ããããŸãå°ããšãäžã€ãé»å移åå€ïŒETA
ååç©ïŒãšåŒã°ããååç©ã§ããéå å€ã®æ··åç©
ãšãçµåããŠäœ¿çšããŠå®æœããã®ã奜ãŸããã EDååç©ã¯ããã®ååç©ããã®é»åãããã
ã€ãååç©ã«ç§»è¡ãããªããã°ãªããªãå±€ãŠãã
ãå éšã«ãšã©ãŸãããã«ãäŸãã°ãã©ã¹ãåºãæ
ã€éæ¡æ£æ§ã§ããããšã奜ãŸããã EDååç©ã¯ãç°ãªã€ãéæ¡æ£æ§è²çŽ ãããã¯
è²çŽ ãã¬ã«ãŒãµãŒãå«æãããã¬ã«åãããã²ã³
åéä¹³å€åå±€ã«éæ¡æ£æ§ã®ç¶æ ã§ååšããããšã
奜ãŸããããã®ãããªEDååç©ã®äŸã«ã¯ãã¢ã«
ã³ã«ãã«ããã«ãããŒããšïŒïŒïŒâãã¹ïŒ1â²ïŒ
1â²ïŒ3â²ïŒ3â²âããã©ã¡ãã«ããã«ïŒâãã€ãããã
ã³ãããããã®ä»ã®EDååç©ã¯ç±³åœç¹èš±ç¬¬
4139379å·ããã³çºè¡ããããã€ãç¹èš±åºé¡ç¬¬
2947425å·ã«èšèŒãããŠãããEDååç©ã®ä»£ã
ã«ãçºè¡ããããã€ãç¹èš±åºé¡ç¬¬2809716å·ãšç±³
åœç¹èš±ç¬¬4278750å·ã«èšèŒãããåŠããé»åäŸäž
äœãã¬ã«ãŒãµãŒååç©ãåçææã«äœ¿çšã§ããã
æ¬çºæã®HRååç©ãšçµã¿åãããããã®ç¹ã«
æçšãªEDãã¬ã«ãŒãµãŒååç©ã¯çºè¡ããããã€
ãç¹èš±åºé¡ç¬¬3006268å·ã«é瀺ããããã³ãŸãã©
ã³ååç©ã§ãããã¯æ¬¡ã®äžè¬åŒã«çžåœããã ããã§R11ã¯ççŽ ç°åŒãããã¯ç°ç¯ç°åŒè³éŠæ
ç°ãè¡šãããR12ãR13ããã³R14ïŒåäžã§ãç°ã€
ãŠããŠãããïŒã¯æ°ŽçŽ ãã¢ã«ãã«ãã¢ã«ã±ãã«ã
ã¢ãªãŒã«ãã¢ã«ã³ãã·ãã¢ã«ãã«ããªãã¢ããã
è¡šããããããã¯R13ãšR14ã¯äžç·ã«ãªã€ãŠé£æ¥
ç°äŸãã°ççŽ ç°åŒç°ãè¡šããããããŠãã®å Žå
R11ãR12ãR13ããã³R14ã®å°ããšãäžã€ã¯10ãª
ãã22ã®ççŽ ååãæã€ãã©ã¹ãåºãè¡šããã ETAååç©ã¯æ¡æ£æ§ã®ç¶æ ã«ããçŸåå€ãšã
ãŠäœ¿çšããã®ã奜ãŸããããŸãäŸãã°ãäžã€ä»¥äž
ã®ããã²ã³åéä¹³å€å±€ã«é£æ¥ã芪氎æ§ã³ãã€ãå±€
ã«åãæã圢ã§ãŸã蟌ãŸãããããããã¯è²çŽ æ¡
æ£è»¢åçšåŠç液ããæ·»å ãããã å žåçã«æçšãªETAååç©ã«ã¯ãäŸãã°ç±³åœ
ç¹èš±æ现æžç¬¬4139379å·ã«èšèŒãããåŠãããã€
ããããã³ååç©ãã¢ããããšããŒã«ååç©ãã«
ãã³ãŒã«ååç©ãããšãã¬ã³ãžã¢ãã³é¡ããã³ïŒ
âãã©ãŸãªãžãã³ååç©äŸãã°ïŒâã¢ãªãŒã«âïŒ
âãã©ãŸãªãžãã³ãããã ç±³åœç¹èš±æ现æžç¬¬3039869å·ã«é瀺ãããåŠã
ç°ã€ãETAååç©ã®çµåããã䜿çšã§ãããã
ã®ãããªçŸåå€ã¯æ¶²ç¶åŠççµæç©ã§äœ¿çšã§ãã
ãããããã¯å°ããªããšãäžéšããåçãšã¬ã¡ã³
ããããã¯èãŠãããã®ãããªãå±€ã«ãäŸãã°ã
ãã²ã³åéä¹³å€å±€ãè²çŽ åæäŸææå±€ãäžéå±€ã
åå容局ãªã©ã«å å«ãããŠããŠããããéžæãã
ãç¹å¥ã®ETAã¯å¿è«ãã®æ¹æ³ã§äœ¿çšããç¹å¥ã®
é»åäŸäžäœãšãããã€ãååç©ã«ããŸãç¹å¥ã®å
çãšã¬ã¡ã³ãçšã®åŠçæ¡ä»¶ã«äŸåããã åçææäžã®EDååç©ãããã¯EDãã¬ã«ãŒãµ
ãŒååç©ã®æ¿åºŠã¯åºç¯å²ã«å€æŽã§ããããäŸãã°
ãããã€ãååç©ã«å¯ŸããŠïŒïŒïŒãªããïŒïŒïŒã®
ã¢ã«ç¯å²ã«ãããETAååç©ã¯çŸå段éã§äœ¿çš
ããã¢ã«ã«ãªæ§æ°Žæº¶æ¶²äžã«ååšããŠãããããå°
ããªããšãäžã€ã®ããã²ã³åéä¹³å€å±€ã«é£æ¥ãã
éæå æ§èŠªæ°Žæ§ã³ãã€ãå±€å ã§æ¡æ£æ§ã®åœ¢ã§äœ¿çš
ããã®ã奜ãŸããã äŸãã°ETAååç©ãšããŠäœçšããéé žåã®çŸ
åå€ã®ãã€ã°ã¬ãŒã·ãšã³ã¯éåãšããŠé²è¡ããã
ããŠäœã€ãçŸåå€ããã¬ã«åãä¹³å€å±€ã®é²å éšã«
é žåãããã«ãšã©ãŸãå Žåã«ã¯æ£ç¢ºãªæŒè²ã«æªåœ±
é¿ãåãŒããã®ã§ãããåŸã€ãŠãæ¬çºæã®å¥œãŸã
ãæ æ§ã«åŸãã°ãå€åããªãçŸåå€ïŒETAåå
ç©ïŒã¯ãã¯ãçŽæ¥ã«ãããã¯äœ¿çšããEDååç©
ãéããŠãããã€ãååç©ãšåå¿ãããã®ã«ã¯åœ¹
ç«ããªãã§ããããšæãããé²å åå ã«ãããã€
ã°ã¬ãŒãããçŸåå€ã®äžåïŒããªãã¡ç©çççŸå
ã«ããé žåïŒãå©ããããã«ãããã²ã³åé溶åª
äŸãã°ããªãµã«ããšãŒãã䜿çšããŠè€éãªåœ¢ãã
ãæªé²å ããã²ã³åéãåé€ãããã®ç®çã«ãã
ã²ã³åé溶åªã䜿çšããããšã¯çºè¡ããããšãŒã
ããç¹èš±åºé¡ç¬¬0049002å·ã«èšèŒãããã ããæ£ç¢ºãªæŒè²ãåŸãããã«ã¯ãé žåããã
ETAååç©ãéäžã§æããŠããããEDååç©ã®
æãŸãããªãé žåãåŒèµ·ãããšããã°ã§ããã§ã
ããé£æ¥ããå圢æå±€ãžãã€ã°ã¬ãŒãããã®ãé²
æ¢ããããšãæå©ã§ãããåèšæç²ã«ã¯ãéæ¡æ£
ç¶æ ã§åçææäžã«ãäŸãã°å圢æå±€ã®éã®äžé
å±€ã«ãŸã蟌ãŸããæè¬é€å»å€ã䜿çšããããã®ç®
çã«çšããé©åœãªé€å»å€ã¯äŸãã°ç±³åœç¹èš±ç¬¬
4205987å·ããã³ãšãŒãããç¹èš±ç¬¬29546å·ã«èšèŒ
ãããŠããã æ¬çºæã«åŸãåçãšã¬ã¡ã³ãã§äºã€ä»¥äžã®ãã
ã²ã³åéä¹³å€å±€ãå«ããã®ã§ã¯ãè²çŽ åæäŸææ
ãå«ãããããã¯è²çŽ åæäŸææãå°ç¶ãã®å±€ã
ãªããŠååšããåããã²ã³åéä¹³å€å±€ããèãŠã
ããäžã®ä»ã®ããã²ã³åéä¹³å€å±€ããäžéå±€ã«ã
ãåé¢ããŠããããããã§äžéå±€ã¯äŸãã°ã²ã©ã
ã³ãã¢ã«ã®ã³é žã«ã«ã·ãŠã ããããã¯1968幎ïŒæ
21æ¥çºè¡ã®ãªãã€ãŒã ãããªãŠãŒ ããã«ãŒã®
ç±³åœç¹èš±æ现æžç¬¬3384483å·ã«é瀺ãããã³ãã€
ãé¡ã1969幎æ14æ¥çºè¡ã®ãã€ã ã㌠ããŒã©
ãŒã®ç±³åœç¹èš±æ现æžç¬¬3421892å·ã«èšèŒãããã
ãªããã«ã¢ããã®åŠãããªããŒææã®ãã¥ãã
ãããããã¯ãã©ãã€ã瀟ã«ãã1970幎ïŒæ13æ¥
ã«åºé¡ããããã©ã³ã¹ç¹èš±æ现æžç¬¬2028236å·ã
ãããã¯1961幎ïŒæ11æ¥çºè¡ã®ãã¯ãŒã ã·ãŒ
ããŒã¹ã®ç±³åœç¹èš±æ现æžç¬¬2992104å·ãããã³
1969幎ïŒæ11æ¥çºè¡ã®ãããã ããŒã«ãŒã«ãœã³
ãšãžãšãã ãšã« ã¬ã€ãã®ç±³åœç¹èš±æ现æžç¬¬
3427158å·ã«é瀺ããããã®ã®ãã¥ãããå«æã
ãã æ¬çºæã«åŸãå€è²æ¡æ£è»¢åææã®è£œé ã«ããã
æ æ§ã«åŸãã°ãé»è²éæ¡æ£è²çŽ ãããã¯ã«ãŒã¬ã€
ãªãŒ ã·ã«ããŒã§æããæ°Žééæ§ã³ãã€ãäžé
å±€ãé»è²è²çŽ æŸåºååç©ãå«ãéææ§ããã²ã³å
éä¹³å€å±€ã®äžã«ã€ããã æ¬çºæã®ããæ æ§ã§ç¹ã«äžäœåèãŠããããæ
ã€ãã®ã§ã¯ãäžéæåå€ãåŠççµæç©ããå ãã
ããšãã§ãããäžéæåå€ã®äŸãšããŠã¯ãã«ãŒã
ã³ãã©ãã¯ãç¡«é žããªãŠã ãé žåäºéãã¹ãã¢ãª
ã³é žããªãŠã ãç¡ é žé¡ãã¢ã«ãããé žåãžã«ã³ã
ãŠã ãã¢ã»ãã«é ¢é žãžã«ã³ããŠã ãç¡«é žãããªãŠ
ã ãžã«ã³ããŠã ãã«ãªãªã³ããã€ã«ãäºé žåãã¿
ããŠã ãæ瀺è¬è²çŽ ããã°ãã·ã³ã®åŠãææ©è²çŽ
ãããã¯ãããã®æ··åç©ãæãããããã®éã¯æ
æã®äžéæ床ã«å¿ããŠåºç¯å²ã«å€åãããäžè¬
ã«ãäžéæåå€ã®æ¿åºŠã¯ãæ¯æäœãéããŠçŽæ¥å
ãããŠããšããããã¯ãšã¬ã¡ã³ãã®ç«¯ããå·®ã蟌
ãå ã®ããã«ãåŠççµæç©ã®å±€ãéã倧æ°ã®ååŠ
ç·ã«ããèãŠãããã®ããã²ã³åä¹³å€ãããã«é²
å ããã®ãé²ãã«å åãªãã®ã§ãªããã°ãªããª
ããäŸãã°ãã«ãŒãã³ãã©ãã¯ãããã¯äºé žåã
ã¿ããŠã ã¯äžè¬ã«ããããåŠç溶液äžã«çŽïŒãªã
ã40ééïŒ ã®éã§ååšããå Žåã«ã¯ãå åãªäžé
æãæäŸãããåŠç溶液ãšäžéæåå€ãèãŠãã
ãå ã«ååžããåŸã¯ãåŠçãååŠç·ã®ååšäžã«ã¡
ã©ã®å€ã§è¡ãªã€ãŠãããããããã¯ããã®ã©ãã
ãŒãã®ãã²ã³åä¹³å€ããäžã€ã®äž»èŠé¢ã§ã¯äžéæ
ã®åŠççµæç©ã«ãããŸãæ®ãã®äž»èŠé¢ã§ã¯ã¢ã«ã«
ãªæ§æº¶æ¶²ãééãããäžéæå±€ã«ããå ¥å°å ã«å¯Ÿ
ããŠé©åã«ä¿è·ãããŠãããšããäºå®ãèæ ®ããŠ
ã®ããšã§ãããããæ æ§ã§ã¯ããã©ã¹ãåºã®ã€ã
ãæ瀺è¬è²çŽ ãããã¯è²çŽ ãã¬ã«ãŒãµãŒãæå å±€
ã®é²å åŽäžã®å±€äžã«ãŸã蟌ãããšãã§ãããããŠ
ãã®æ瀺è¬è²çŽ ã¯é²å äžã¯éæã§ãããåŠççµæ
ç©ãšæ¥è§Šãããšäžéæã«ãªãããšã奜ãŸãããã
ãã²ã³åéä¹³å€ã«æå°ããååŠç·ããšããžéšã§æŒ
ããã®ãé²æ¢ããã®ã«äžéæãªçµåããŒããçšã
ãããšãã§ããã äºé žåãã¿ããŠã ãããã¯ä»ã®çœè²é¡æãåŠç
çµæç©ã®äžéæåå€ãšããŠäœ¿çšããå Žåã«ã¯ãã
ããšååã§ãã¿ã¬ã€ã³è²çŽ ã®åŠãPHã«æããäžé
æåè²çŽ ã䜿çšããããšããŸã奜ãŸããããã®ã
ããªè²çŽ ã¯å圢æãè¡ãªãããPHã§ã¯åžå æ§ã§ã
ãããããã¯çè²ããŠãããããäœãPHã§ã¯ç¡è²
ããããã¯éåžå æ§ã§ããããããäžéæåè²çŽ
ã«é¢ãããã®ä»ã®è©³çŽ°ã¯ããã©ãã€ã瀟ã1969幎
12æ22æ¥ã«åºé¡ãããã©ã³ã¹ç¹èš±æ现æžç¬¬
2026927å·ã«èšèŒãããŠããã æ¬çºæã®äžäœçå容èãŠãããäžã®ã¢ã«ã«ãªæ§
溶液ãééãããå®è³ªçã«äžéæãªå åå°å±€ã¯ã
ãããææã®æ§è³ªãæã€éããã€ã³ããŒäžã«åæ£
ãããããªãäžéæåå€ããã§ãéåžžãªãåŸãã
ç¹ã«æãŸããã®ã¯çœè²å åå°å±€ã§ãã€ãŠãããã¯
ãã®å±€ã審çŸçã«å¿«ããã®äžã§è»¢åãããè²çŽ å
ãçºããèæ¯ã瀺ããšå ±ã«ãŸãå ¥å°å ç·ã®åå°ã«
æãŸããå åŠçæ§è³ªãæã€ããã§ãããé©åœãªäž
éæåå€ã«ã¯ãåŠççµæç©ã«é¢ããŠæ¢ã«è¿°ã¹ãåŠ
ããäºé žåãã¿ããŠã ãç¡«é žããªãŠã ãé žåäº
éãã¹ãã¢ãªã³é žããªãŠã ãèéçãç¡ é žå¡©é¡ã
ã¢ã«ãããé žåãžã«ã³ããŠã ãã¢ã»ãã«é ¢é žãžã«
ã³ããŠã ãç¡«é žãããªãŠã ãžã«ã³ããŠã ãã«ãªãª
ã³ããã€ã«ãããã¯ãããã®æ··åç©ãæãããã
ãã®éã¯ææã®éæå床ã«å¿ããŠåºç¯å²ã«å€ãã
ãããäžéæåå€ã¯ãããªããã€ã³ããŒã«åæ£ã
ããŠãããããã®ãã€ã³ããŒã«ã¯äŸãã°ã²ã©ã
ã³ãããªããã«ã¢ã«ã³ãŒã«çã®åŠãã¢ã«ã«ãªæ§æº¶
液ééæ§ããªããŒãããªãã¯ããããã¹ãã«ã
ã³ãã¯ããªã³ãããªã¢ãžã³ã€ãªããµãŸãŒã«ã®åŠã
è¢å å¢çœå€ããææãªãã°å åå°å±€ã«æ·»å ããŠã
ãããå åå°å±€ã®äžéæåèœåãé«ããããšãæ
ãå Žåã«ã¯ãäŸãã°ã«ãŒãã³ãã©ãã¯ããã°ãã·
ã³è²çŽ ãªã©ã®åŠãæè²äžéæåå€ããã®å±€ã«å ã
ãŠããããå åå°å±€ã®äžéæåèœåãé«ããããŸ
äžã€ã®æ¹æ³ã¯ãã¢ã«ã«ãªæ§æ°Žæº¶æ¶²ãééãããã
ãªããŒãããªãã¯ã¹ãäŸãã°ã²ã©ãã³ãããªãã
ã«ã¢ã«ã³ãŒã«çã«äŸãã°ã«ãŒãã³ãã©ãã¯ããã°
ãã·ã³è²çŽ çãåæ£ãããå¥ã®äžéæå±€ããå å
å°å±€ã®çäžã«é 眮ããããšã§ããããã®ãããªäž
éæå±€ã¯éåžžå¯åºŠãå°ããšãïŒå¥œãŸããã¯ïŒãã
倧ããããã€ååŠç·ã«å¯ŸããŠå®è³ªçã«äžéæã§ã
ãã®ããããäžéæå±€ã¯ãããäžã€ã§ååšãããª
ãã°ãçŸåè¬é€å»å±€ãšäžç·ã«ããŠããããå åå°
å±€ãšäžéæå±€ã¯éåžžåã¿ã0.025ãªãã0.15mmã§
ãããã䜿çšããäžéæåå€ãèŠæããäžéæ床
çã«å¿ããŠå€ããããšãã§ããã æ¬çºæã«äœ¿çšããæå æ§ç©è³ªã¯ããã²ã³åéä¹³
å€ã§ããããšãæãŸããããŸãå¡©åéãèåéã
èåæ²åéãå¡©åèåæ²åéçããããã¯ããã
ã®æ··åç©ãããªã€ãŠããããä¹³å€ã¯ç²å€§ã§ã埮ç²
ã§ãããããããªãå ¬ç¥æ¹æ³ã§äœãããšãã§ã
ããäŸãã°ãžã³ã°ã«ãžãšããä¹³å€ããªãããã³ä¹³
å€ã®åŠãããã«ãžãšããä¹³å€ãã¢ã³ã¢ãã¢æ§ä¹³
å€ãäžèšç±³åœç¹èš±æ现æžã«èšèŒãããåŠãããªã·
ã¢ããŒããããã¯ããªãšãŒãã«çæä¹³å€ãããã
ç±³åœç¹èš±ã«ã¯1940幎11æïŒæ¥çºè¡ã®ã¢ãã«ã ãš
ãã ããŒããšãã¬ããªã㯠ãžãšãŒ ã©ãã»ã«
ã®ç¬¬2222264å·ã1967幎ïŒæ16æ¥çºè¡ã®ããŒããŒ
ããã€ãŒ ã€ãªã³ã°ã¹ã¢ãŠãŒã¹ã®ç¬¬3320069å·ã
ãã³1966幎ïŒæïŒæ¥çºè¡ã®ã¯ã©ã¬ã³ã¹ ã€ãŒ ã
ãã¯ãã©ã€ãã®ç¬¬3271157å·ããããè¡šé¢åä¹³å€
ã䜿çšããŠãããããããã¯äžèšç±³åœç¹èš±æ现æž
ã«èšèŒãããåŠãå éšåä¹³å€ã䜿çšããŠãããã
ç±³åœç¹èš±æ现æžã«ã¯ã1952幎ïŒæïŒæ¥çºè¡ã®ãšã
ã¯ãŒã ãã€ãªãã ããŒããŒãšãšãã¯ãŒã ã
ãšã¹ ãããã®ç¬¬2592250å·ã1965幎ïŒæ14æ¥çº
è¡ã®ãã³ãªãŒ ãã€ãŒ ããŒã¿ãŒãããŒãã¹ ãš
ãã ãžãšãŒã ã¹ããã³ãŠãšãºã¬ãŒ ãžãŒ ããŒ
ãŠãšã®ç¬¬3206313å·ããã³1969幎ïŒæïŒæ¥çºè¡ã®
ãããŒã ã€ãŒ ããŒã³ã³ããã³ãžãŒã³ ãšã
ããŒãã¢ãŒã®ç¬¬3447927å·ããããä¹³å€ã¯ãã¯ã¬
ã€ã³ãšã¢ã€ã¶ãŒããžã€ãŒãã« ãªã 㶠ããªã
ã°ã©ãã€ã㯠ãµã€ãšã³ã¹12å·»ãïŒå·ïŒæïŒ10æ
å·ã242â251é ã1964幎ã«èšèŒããã¿ã€ãã®åŠã
ç²åã®æŽã®ã€ãä¹³å€ã§ããããææãããã°ã
1961幎ïŒæ15æ¥çºè¡ã®ãžãšãŒãž ãããªãŠãŒ ã©
ãããŒãšãžãšãŒã³ ã·ãŒ ãããã®ç±³åœç¹èš±æ现
æžç¬¬2996382ã«èšèŒãããåŠããè¡šé¢åä¹³å€ãšå
éšåä¹³å€ã®æ··åç©ã䜿çšããŠãããã æ®éã¯ãã¬ã¿ã€ãã䜿çšãããããŠåå転ã®å¿
èŠããªãæã¯ãäžèšç±³åœç¹èš±æ现æžãè±çŽ°ç¹èš±æ
现æžã«èšèŒãããåŠãçŽæ¥ããžä¹³å€ãåæ§ã«äœ¿çš
ããŠããããç±³åœç¹èš±æ现æžã«ã¯ã1939幎12æ19
æ¥çºè¡ã®ãžãšã³ ãšãŒ ãªãŒã«ã¡ãŒã«ãŒã¹ã®ç¬¬
2184013å·ã1951幎ïŒæ13æ¥çºè¡ã®ãŠã€ãªã¢ã ã
㌠ã±ã³ãã«ãšãžãšãŒãž ãã€ãŒ ãã«ã®ç¬¬
2541472å·ã1968幎ïŒæïŒæ¥çºè¡ã®ãããŒã ã
ããªãŠãŒ ããªãŒãã³ã®ç¬¬3367778å·ã1970幎ïŒ
æ17æ¥çºè¡ã®ããŒããŒã ãã€ãŒ ã€ãªã³ã°ã¹ãŠ
ã¯ãŒã¹ã®ç¬¬3501307å·ã1951幎ïŒæïŒæ¥ä»¥è¡ã®ã
ã€ãŒã«ã¹ ãšã ã¢ã€ãã¹ã®ç¬¬2563785å·ã1948
幎12æ21æ¥çºè¡ã®ãšãã¯ãŒã ããšã¹ ããããš
ã¬ã€ãŠã€ãªã¢ã ã¹ ãŠã€ãªã¹ã®ç¬¬2456953å·ã
1958幎11æ25æ¥çºè¡ã®ãšããŠã€ã³ ãšãã ã©ã³
ãã®ç¬¬2861885å·ã1973幎ïŒæ25æ¥çºè¡ã®ãã©ã³
ã·ã¹ ãžãšã³ãšãã³ã¹ã®ç¬¬3761276å·ã1973幎ïŒ
æ25æ¥çºè¡ã®ãã«ã〠ããããšã« ãã«ãã³ã®
第3761266å·ã1973幎ïŒæ29æ¥çºè¡ã®ã¹ãŒã¶ã³
ã¹ã¿ãŒ ã³ãªã¢ãŒãšããŒã« ããªãŠã¹ã¿ãŒ ã®ã«
ãã³ ãžãã¢ãŒã®ç¬¬3736140å·ããã³1973幎ïŒæ
ïŒæ¥çºè¡ã®ããŒã« ããªãŠã¹ã¿ãŒ ã®ã«ãã³ ãž
ãã¢ãŒãããã«ã ãžãšãŒãž ã©ã¬ãŒããã³ãµã
ã¹ ããã«ã ã³ã¹ãŒã«ã¯ã®ç¬¬3730723å·ãããã
ãŸãè±åœç¹èš±æ现æžã«ã¯N.V.ã²ããŒã ããªã
ãããã¯ã·ãšã³ã1952幎ïŒæïŒæ¥ã«åºé¡ãã第
723019å·ãããã æã ã®çºæã§æçšãªããã²ã³åéä¹³å€ã¯åœè©²æ
è¡ã®çç·Žè ã«ã¯å ¬ç¥ã§ããããã®çµæã補æ³ãã
ã³å¡è£ ã«é¢ãããã詳现ãªããšã¯ãäŸãã°ããªã
ã¯ã ã©ã€ã»ã³ã·ã³ã° ã€ã³ããã¯ã¹92å·»ã1971
幎12æããããªã±ãŒã·ãšã³9232ã107â109é ã«èš
èŒãããŠããã äžã€ã®æ æ§ã«åŸãã°ãæ¬çºæã®ããã²ã³åéä¹³
å€å±€ã¯ã²ã©ãã³ã«åæ£ãããæå æ§ããã²ã³åé
ãããªããåã¿ã¯çŽ0.2ãªãã2ÎŒmã§ãããè²çŽ
åæäŸææã¯ã¢ã«ã«ãªæ§æº¶æ¶²ãééãããããªã
ãŒãã€ã³ããŒäŸãã°ã²ã©ãã³ã«åæ£ãããŠåã¿çŽ
ïŒãªãã7ÎŒmã®å¥ã®å±€ã圢æãããã®å±€ã¯ãåã¿
çŽïŒãªãã5ÎŒmã®ã¢ã«ã«ãªæ§æº¶æ¶²ãééãããã
ãªããŒäžéå±€äŸãã°ãŒã©ãã³ãšçµã¿åãããŠã
ããå¿è«ããããã®åã¿ã¯ããããã®ãã®ã«éã
ããæèŠã®è£œåã«åŸã€ãŠå€æŽããŠãããã æ¬çºæã®åçãšã¬ã¡ã³ãçšæ¯æäœã¯ããããè
ãŠãããã®åççæ§è³ªã«æªåœ±é¿ãåãŒãããŸã寞
æ³çã«å®å®ã§ããéãããããªãææã§ãã€ãŠã
ãããå žåçãªæè»æ§ã®ããã·ãŒãç¶ææã¯ãäŸ
ãã°çé¢ãããã¯äž¡é¢ã«Î±âãªã¬ãã€ã³ããªããŒ
äŸãã°ããªãšãã¬ã³ãå¡åžããçŽæ¯æäœã§ããã
ãã®ææã«ã¯ããããã»ã«ããŒãº ãã€ã«ã ãé ¢
é žã»ã«ããŒãºãã€ã«ã ãããªïŒããã«ã¢ã»ã¿ãŒ
ã«ïŒãã€ã«ã ãããªã¹ãã¬ã³ ãã€ã«ã ãããª
ïŒãšãã¬ã³ ãã¬ãã¿ã©ãŒãïŒãã€ã«ã ãããªã«
ãŒãããŒã ãã€ã«ã ãããªãšãã¬ã³ããã³ããª
ãããã¬ã³ ãã€ã«ã ã®åŠãããªÎ±âãªã¬ãã€ã³
ããã³é¢é£ãã€ã«ã ãããã¯æš¹èææãæããã
ããæ¯æäœã¯éåžžåã¿ãçŽ0.05ãªãã0.15mmã§ã
ãã è²åœ©åçã§ã®äœ¿çšã«ã¯ãææã®åªææ©èœããã
ã¯ããã§ãªããã°æ¡æ£ããè²çŽ ã®åºçãåŸããã
éããåå容局ãšããŠãããªãææã䜿çšããã
ãšãã§ãããéžã°ããç¹å¥ãªææã¯å¿è«åªæãã
è²çŽ ã«äŸåãããé žæ§è²çŽ ã¯åªæããããšã«ãªã€
ãŠãããªãã°ãåå容局ã¯æ¬¡ã®ååç©ããæãåŸ
ãããããã¯ãããå«æãåŸãããã®ãããªåå
ç©ãšããŠã¯ãå¡©åºæ§ããªããŒåªæå€äŸãã°1959幎
ïŒæ14æ¥çºè¡ã®ãã€ã¹ ãšã ãã³ã¹ã¯ã®ç±³åœç¹
èš±æ现æžç¬¬2882156å·ã«èšèŒãããããã« ã¡ã
ã« ã±ãã³ã®ã¢ããã°ã¢ããžã³èªå°äœã®ããªã
ãŒãããã³å¡©åºæ§ããªããŒåªæå€ãšèªå°äœäŸãã°
ããªâïŒâããã«ããªãžã³ãããªâïŒâããã«ã
ãªãžã³ ã¡ãâïœâãã«ãšã³ ã¹ã«ããªããŒãã
ãã³1949幎10æ11æ¥çºè¡ã®ãããŒã ãšãã ã¹
ãã©ãŒã°ãšã¬ã¹ãªãŒ ãžãŒ ãã«ãã«ãŒã®ç±³åœç¹
èš±æ现æžç¬¬2484430å·ã«èšèŒã®é¡äŒŒååç©ãã¢ã¯
ãã¢ãŒã²ããŒã A.G.ã1971幎ïŒæ11æ¥ã«åºé¡
ãããã€ãç¹èš±åºé¡å ¬å第2200063å·ã«èšèŒã®å
åç©ãæãããããé©åœãªåªæãã€ã³ããŒã«ã¯ã
ã¢ã·ã«ã¹ãã¬ã³ããªããŒã®ã°ã¢ãã«ããã©ãŸã³èª
å°äœãæãããããã®ååç©ã¯äŸãã°ã¢ã¯ãã¢ãŒ
ã²ããŒãA.G.ã1970幎ïŒæ28ç®ã«åºé¡ããå ¬å
ãã€ãç¹èš±æ现æžç¬¬2009498å·ã«èšèŒãããŠããã
ãããäžè¬ã«ã¯ãä»ã®ãã€ã³ããŒäŸãã°ãŒã©ãã³
ãäžèšåªæãã€ã³ããŒã«å ããã®ããããå¹æç
ãªåªæçµæç©ã¯ã»ãã«ããªã¡ãã«ã¢ã³ã¢ããŠã
ãããã€ããšãé·é第ïŒçŽã¢ã³ã¢ããŠã ããã
ã¯ããã¹ãããŠã ååç©ãããã¯ç¬¬ïŒçŽã¹ã«ãã
ãŠã ååç©ã§ãã€ãŠãåŸè ã®äºã€ã®ååç©ã¯äŸã
ã°å ±ã«1966幎ïŒæïŒæ¥çºè¡ã®ãããããŠãªã«ã¿ãŒ
ãšã ããã·ãŠãšã±ãŒã¹ ã€ãŒ ãŠã€ããã¢ã¢
ãŒã®ç±³åœç¹èš±æ现æžç¬¬3271147å·ãšç¬¬3271148å·ãš
ã«èšèŒãããŠãããããéå±å¡©ãããã³é žæ§è²çŽ
ãšé£æº¶æ§ååç©ãçæãããã®æ°Žé žåç©ã䜿çšã
ãŠããããè²çŽ åªæå€ã¯åå容局äžã®æ®éã®èŠªæ°Ž
æ§ãã€ã³ããŒã®äžã€äŸãã°ãŒã©ãã³ãããªããã«
ãããªãã³ãããã¯éšåçãããã¯å®å šã«å æ°Žå
解ããã»ã«ããŒãºãšã¹ãã«äžã«åæ£ãããã äžè¬ã«è¯å¥œãªçµæãåŸãããã®ã¯ã奜ãŸããã¯
ã¢ã«ã«ãªæ§æº¶æ¶²ãééãããåå容局ãéæã§çŽ
ïŒãªããçŽ10ÎŒmã®åã¿ãæã€å Žåã§ããããã®
åã¿ã¯å¿è«ææã®çµæã«å¿ããŠå€æŽããããšãã§
ãããåå容局ã¯ãåªæãããè²çŽ åãéè²ãã
ä¿è·ãã玫å€ç·åžåæãã¹ãã«ãã³ãã¯ããªã³ã
ããªã¢ãžã³ããªããµãŸãŒã«ã®åŠãè¢å å¢çœå€ãã¯
ããããŒã«ãã¢ã«ãã«ããšããŒã«ã®åŠãè²çŽ å®å®
å€çãå«æããŠãããã æ¬çºæã«åŸãèãŠãããã®è²çŽ åå容ãšã¬ã¡ã³
ãäžã«PHäœäžå€ã䜿çšãããšãé垞転åãããå
ã®å®å®æ§ãå¢å ãããäžè¬ã«ãPHäœäžå€ã¯ãæå¶
åŸçæéå ã«åå±€ã®PHãçŽ13ãããã¯14ããå°ã
ãšã11ãžã奜ãŸããã¯ïŒãªããïŒãžäœäžãããã
ã®ã§ãããäŸãã°ã1968幎ïŒæïŒæ¥çºè¡ã®ãšããŠ
ã€ã³ ãšãã ã©ã³ãã®ç±³åœç¹èš±æ现æžç¬¬
3362819å·ã«é瀺ãããããªããŒé žãåºäœé žãã
ããã¯1952幎ïŒæ29æ¥çºè¡ã®ãšããŠã€ã³ ãšãã
ã©ã³ãã®ç±³åœç¹èš±æ现æžç¬¬2584030å·ã«é瀺ã
ããéå±å¡©äŸãã°é ¢é žäºéãç¡«é žäºéãé ¢é žãã°
ãã·ãŠã çã䜿çšã§ãè¯å¥œãªçµæãäžããããã®
ãããªPHäœäžå€ã¯çŸååŸèãŠãããã®PHãæžå°ã
ããŠçŸåãçµçµããããã以äžã®è²çŽ ã®è»¢åãå®
質çã«æžå°ãããããããŠè²çŽ åãå®å®ã«ããã å®éã«ã¯ãäžæŽ»æ§ãªæé調ç¯å±€ããªãã¡ã¹ããŒ
ãµãŒå±€ãPHäœäžå±€ã®äžã«éããŠãããããã®å±€ã¯
äžæŽ»æ§ãªã¹ããŒãµãŒå±€ãéãã¢ã«ã«ãªã®æ¡æ£é床
ã«å¿ããŠPHæžå°ã®æéã調ç¯ããªãã¡ã³ã³ãããŒ
ã«ãããã®ã§ããããã®ãããªæé調ç¯å±€ã®äŸãš
ããŠã¯ããŒã©ãã³ãããªããã«ã¢ã«ã³ãŒã«ããã
ã¯1969幎ïŒæ15æ¥çºè¡ã®ã¬ãªããŒã ã·ãŒ ãã¢
ãŒããŒããã¯ãŒã ãžãŒ ããžã€ãŒã¹ããã³ãªã
ã€ãŒã ãããªãŠãŒã€ã³ã°ã®ç±³åœç¹èš±æ现æžç¬¬
3455686å·ã«èšèŒãããã³ãã€ãã®ãã¹ãŠãæã
ããããæé調ç¯å±€ã¯ãåºã枩床ç¯å²ã«äºã€ãŠ
çš®ã ã®åå¿é床ããªããã®ã«å¹æçã§ãããäŸã
ã°æå¶ã宀枩以äžã®æž©åºŠäŸãã°35ãªãã37âã§å®
æœããå Žåãæ©ãããPHäœäžãé²æ¢ãããæé調
ç¯å±€ã¯éåžžåã¿ãçŽ2.5ÎŒmãªããçŽ18ÎŒmã§ããã
ç¹ã«è¯å¥œãªçµæãåŸãããã®ã¯ãæé調ç¯å±€ãåŠ
ççµæç©ã«ãããã€ããå æ°Žå解ããå æ°Žå解æ§
ããªããŒãããã¯ãã®ãããªããªããŒã®æ··åç©ã
ããªãå Žåã§ããããã®ãããªå æ°Žå解æ§ããªã
ãŒã®äŸãšããŠã¯ãããªããã«ã¢ã»ããŒããããªã¢
ãããã»ã«ããŒãºãšã¹ãã«çãæããããã æ¬çºæã§äœ¿çšãããã¢ã«ã«ãªæ§åŠççµæç©ã¯ã¢
ã«ã«ãªæ§ææäŸãã°æ°Žé žåãããªãŠã ãçé žãã
ãªãŠã ãããã¯ãžãšãã«ã¢ãã³ã®åŠãã¢ãã³ã®å¥œ
ãŸããã¯11以äžã®PHãæã€åŸæ¥ã®æ°Žæº¶æ¶²ã§ããåŸ
ãã äžã€ã®æ æ§ã«åŸãã°ãã¢ã«ã«ãªæ§åŠç液ã¯ãã
ã²ã³åéã®éå ãéè¡ããæ¡æ£æ§çŸåå€äŸãã°ã¢
ã¹ã³ã«ãã³é žããããã¯ïŒâãã©ãŸãªãžãã³ç³»çŸ
åå€äŸãã°ïŒâããšãã«âïŒâã¡ãã«âïŒâãã©
ãŸãªãžãã³ãå«æããã æ¬çºæã§äœ¿çšããã¢ã«ã«ãªæ§åŠççµæç©ã¯ãæ
å æ§ãšã¬ã¡ã³ããå å·¥ã®ããã«ã¡ã©ããååºãã
åŸã¯ãã®ãšã¬ã¡ã³ãããã以äžã¯ç¢ºå®ã«é²å ããª
ãããã«ãããããæžæå€äŸãã°ã¡ãã¬ã³ãã«
ãŒãããã眮æããç°ç¯ç°åŒååç©ãïŒïŒ4â²âã
ããªãžããŠã å¡©çãå«ãã§ãããã ãã®æº¶æ¶²ãé«ååéããªããŒã®åŠãå¢ç²æ§åå
ç©ãäŸãã°ããããã·ãšãã«ã»ã«ããŒãºã®åŠãã¢
ã«ã«ãªæ§æº¶æ¶²ã«äžæŽ»æ§ãªæ°Žæº¶æ§ãšãŒãã«ãããã¯
ã«ã«ããã·ã¡ãã«ã»ã«ããŒãºãããªãŠã ã®åŠãã«
ã«ããã·ã¡ãã«ã»ã«ããŒãºã®ã¢ã«ã«ãªéå±å¡©ãå«
æããã®ã奜ãŸãããå¢ç²æ§ååç©ã®æ¿åºŠã¯ãåŠ
ççµæç©ã®çŽïŒãªããçŽïŒééïŒ ã§ããããšã奜
ãŸããããã®æ¿åºŠãªãåŠççµæç©ã«çŽ100ãªãã
çŽ200000mPa.sã®ç²åºŠãä»äžããã åŠçã¯ååšããç¿çŸåãŠãããäžã§ãäŸãã°é
åžžã®éè€å¡©æ¡æ£è»¢åïŒDTRïŒè£ 眮å ã§é²è¡ãã
ãã®è£ 眮å ã§ã¯åçææãåŠç液ãå ååžåãã
åŸãå¥ã ã®è²çŽ åå容ææãšã®æ¥è§Šãè¡ãªãã
ãããã®ç®çã«é©ããè£ çœ®ã¯DTRçŸåè£ çœ®ã§ã
ãCOPYPROOF CP38ïŒåååïŒã§ããã
COPYPROOFã¯ã¢ã³ããã«ãã³ïŒã¬ããŒã¯ãŒã»
ã³ ã¢ã°ãã¢ãŒã²ããŒãã®åååã§ããã å容局ãæå å±€ãšäžäœã§ãããã®ä»ã®æ æ§ã«åŸ
ãã°ãåŠç液ã¯ç Žè£å¯èœãªå®¹åšããå ããããã
ãããã¯ã¹ãã¬ãŒã§å ããããã æ¬çºæã§äœ¿çšã§ããç Žè£å¯èœãªå®¹åšã¯äžèšç±³åœ
ç¹èš±æ现æžã«é瀺ãããã¿ã€ãã®ãã®ã§ãããç±³
åœç¹èš±æ现æžãšããŠã¯ã1951幎ïŒæ27çºè¡ã®ãšã
ãŠã€ã³ ãšãã ã©ã³ãã®ç¬¬2543181å·ã1953幎
ïŒæ30æ¥çºè¡ã®ãŠã«ãªãã ãšã« ãž ã®ãªãã®
第2643886å·ã1953幎ïŒæ29æ¥çºè¡ã®ãšããŠã€ã³
ãšãã ã©ã³ã第2653732å· 1955幎11æïŒæ¥
çºè¡ã®ãŠã€ãªã¢ã ãžãšãŒ ããã¯ããŠãŒã³ ãž
ãã¢ãŒã®ç¬¬2723051å·ã1962幎10æïŒæ¥çºè¡ã®å ±
ã«ãžãšã³ ã€ãŒ ãã€ã³ããã«ã®ç¹èš±ã§ãã第
3056492å·ãšç¬¬3056491å·ãããã³1964幎10æ13æ¥
çºè¡ã®ãšããŠã€ã³ ãšãã ã©ã³ãã®ç¬¬3152515
å·ãæãããããäžè¬ã«ããã®ãããªå®¹åšã¯ã液
äœã空æ°ãéããªãææã®é·æ¹åœ¢ã·ãŒãã瞊æ¹å
ã«æãéããŠäºã€ã®å£ãäœãããã®å£ããã®çžŠãš
æ«ç«¯ã®ãµã¡ã«æ²¿ã€ãŠçžäºã«ã·ãŒã«ããŠåŠç液ãå ¥
ãã空ã©ãã圢æããããã®ã§ããã æ¬çºæã§äœ¿çšããã¢ã«ã«ãªæ§åŠççµæç©ã¯æ¢è¿°
ããåŠãç Žè£å¯èœãªå®¹åšäžã§äœ¿çšããŠåŠççµæç©
ãèãŠãããäžã«å ¥ããã®ã䟿å®çã«å®¹æããã
ããšãã§ããããåŠççµæç©ãèãŠãããå éšã§
æåºããä»ã®æ段ãçšããããšãã§ããããã®æ
段ãšããŠã¯äŸãã°ã1967幎11æ14æ¥çºè¡ã®ããã«
ã ãšã ããŒããŒã®ç±³åœç¹èš±æ现æžç¬¬3352674
å·ã«èšèŒãããŠããåŠããç®äžæ³šå°éã«äŒŒããã¥
ããã«ã¡ã©ã®ã«ãŒããªããžã«åä»ããé£ééšæã
çšããŠåŠç溶液ãæ³šå ¥ããæ段ãããã 次ã®æ¯èŒäŸãçšããŠæ¬çºæãããã«èª¬æããã
ãã¹ãŠã®ããŒã»ã³ãããžãšæ¯ã¯å¥ã«èšåããªãé
ãééã«ãããã®ã§ããã å®æœäŸ ïŒ è©ŠéšçïŒâ15ã®çšæ äž¡é¢ã15ïœïŒm2ã®ããªãšãã¬ã³å±€ãå¡åžãã
110ïœïŒm2ã®çŽã·ãŒããããªãäžå¡ãããèæ°Žæ§
çŽæ¯æäœãã³ããæŸé»ã§åŠçãããã®äžã«äžèšé
åºã§æ¬¡ã®å±€ãå¡åžããã ïŒïŒ 也ç¥ç¡¬ååŸå¹³æ¹ïœåœãäžèšååç©ãå«ãã¢
ã«ã«ãªééæ§ã³ãã€ãå±€ïŒ ãŒã©ãã³ 1.5ïœ ã·ã¢ã³è²çŽ æäŸãããã€ãååç©ïŒè¡šïŒåç §ïŒ
ïŒåŸè¿°ã®åŠãããŠçšæããåæ£æ¶²ããå ããïŒ
0.26ããªã¢ã« å¡©åéïŒèµ€ææ§ãŒã©ãã³å¡©åéä¹³å€ããå ã
ãïŒ 0.498ïœ ïŒïŒïŒâãã¹ïŒ1â²ïŒ1â²ïŒ3â²ïŒ3â²âããã©ã¡ãã«
ããã«ïŒãã€ããããã³ 0.102ïœ ïŒïŒ å¹³æ¹ïœåœã次ã®ååç©ãå«ãäžéå±€ïŒ ãŒã©ãã³ 1.155ïœ ïŒâããšãã«âïŒâã¡ãã«âïŒâãã©ãŸãªãžã
ã³ïŒåŸè¿°ã®åŠãããŠçšæããåæ£æ¶²ããå ã
ãïŒ 0.084ïœ ïŒâã¢ã»ãã«âïŒâãªã¯ããã·ã«(2)âãã€ãã
ããã³ 0.096ïœ ããžãšã³ã¿ããã€ã«ã¿ãŒããè²çŽ ãšããŠãã°ã¡
ã³ãã¬ãã146ïŒC.I.11000ïŒ 0.910ïœ ïŒïŒ å¹³æ¹ïœåœã次ã®ååç©ãå«ãã¢ã«ã«ãªéé
æ§ã³ãã€ãå±€ïŒ ãŒã©ãã³ 1.285ïœ ããžãšã³ã¿è²çŽ æäŸãããã€ãååç©ïŒè¡šïŒå
ç §ïŒïŒåŸè¿°ã®åŠãããŠçšæããåæ£æ¶²ããå ã
ãïŒ 0.31ããªã¢ã« ïŒïŒïŒâãã¹ïŒ1â²ïŒ1â²ïŒ3â²ïŒ3â²âããã©ã¡ãã«
ããã«ïŒãã€ããããã³ 0.104ïœ å¡©åéïŒç·ææ§ãŒã©ãã³å¡©åéä¹³å€ããå ã
ãïŒ 0.553ïœ ïŒïŒ å¹³æ¹ïœåœã次ã®ååç©ãå«ãäžéå±€ïŒ ãŒã©ãã³ 1.155ïœ ïŒâã¢ã»ãã«âïŒâãªã¯ã¿ãã·ã«(2)âãã€ãã
ããã³ 0.096ïœ ïŒâããšãã«âïŒâã¡ãã«âïŒâãã©ãŸãªãžã
ã³ 0.084ïœ ãšããŒããã€ã«ã¿ãŒããè²çŽ ãšããŠãã°ã¡ã³ã
ãšããŒ83ïŒC.I.20000ïŒ 1.085ïœ ïŒïŒ å¹³æ¹ïœåœã次ã®ååç©ãå«ãã¢ã«ã«ãªéé
æ§ã³ãã€ãå±€ïŒ ãŒã©ãã³ 2.046ïœ é»è²è²çŽ æäŸãããã€ãååç©Y1ïŒåŸè¿°ã®åŠã
ããŠçšæããåæ£æ¶²ããå ããïŒ 0.56ããªã¢ã« ïŒïŒïŒâãã¹ïŒ1â²ïŒ1â²ïŒ3â²ïŒ3â²âããã©ã¡ãã«
ããã«ïŒãã€ããããã³ 0.187ïœ å¡©åéïŒéææ§ãŒã©ãã³å¡©åéä¹³å€ããå ã
ãïŒ 0.500ïœ ïŒïŒ å¹³æ¹ïœåœã次ã®ååç©ãå«ãä¿è·å±€ïŒ ãŒã©ãã³ 0.112ïœ ïŒâããšãã«âïŒâã¡ãã«âïŒâãã©ãŸãªãžã
ã³ã®åæ£æ¶²ã®äœè£œ äœè£œã¯æ¬¡ã®æåããµã³ããã«ã«ãããããšã«
ããè¡ãªãããã ãŒã©ãã³ 40ïœ ïŒâããšãã«âïŒâã¡ãã«âïŒâãã©ãŸãªãžã
ã³LOMAR ïŒåååïŒã®40ïŒ æ°Žæº¶æ¶² 10ml èžæºæ°Ž 850ml ïŒLOMAR ã¯çž®ååå¿ã«ãã«ã ã¢ã«ãã
ãã䜿çšããããã¿ã¬ã³ã¹ã«ãããŒãçž®åç©ã«
察ããç±³åœN.J.ãã¯ãŒã¯ ããã³ååŠäŒç€Ÿã®å
ååã§ããïŒã ïŒïŒïŒâãã¹ïŒ1â²ïŒ1â²ïŒ3â²ïŒ3â²âããã©ã¡ã
ã«ããã«ïŒãã€ããããã³ã®åæ£æ¶²ã®äœè£œ ïŒïŒïŒâãã¹ïŒ1â²ïŒ1â²ïŒ3â²ïŒ3â²âãã©ã«ã¡ã
ã«ããã«ïŒãã€ããããã³500ïœãé ¢é žãšãã«
ïŒãšããªã¯ã¬ã·ã«ãã¹ããšãŒã500ïœã«æº¶è§£
ãããããŠ70âã§NEKAL BX38.5ïœãå ãã
ïŒNEKAL BXã¯ïŒïŒïŒâãžâã€ãœããã«ãã
ã¿ã¬ã³âïŒâã¹ã«ãã³é žãããªãŠã ã«å¯Ÿãã西
ãã€ãBASF瀟ã®åååã§ããïŒã溶液ã55â
ãŸã§æŸå·ãã次ãã§å åæ¹æããªããã ãŒã©ãã³ 250ïœ è±å¡©æ°Ž 2.2 é ¢é žãšãã« 500ml ãå«ã溶液ïŒ55âã«ä¿æž©ïŒã«å ããã ããããŠåŸãããäºååæ£æ¶²ã次ãã§ããã«
é«å§ãã¢ãžãã€ã¶ãŒäžã§åŠçããããã§é ¢é žãš
ãã«ãæžå§äžèžçºã«ããé€ãã é»è²è²çŽ æäŸååç©Y1ã®åæ£æ¶²ã®äœè£œ ãšãŒãããç¹èš±åºé¡ç¬¬0038092å·ã«èšèŒãã
ãåŠãåæããã次ã®æ§é åŒïŒ ãæã€ååç©Y1ã®åæ£æ¶²ã次ã®æåãçšããŠ
äœè£œããã ååç©Y1 50ïœ ãŒã©ãã³ 75ïœ MARLON â396ïŒåååïŒã®10ïŒ æ°Žæº¶æ¶²
50ml èžæºæ°Ž 625ïœ ååç©Y1ããŸãé ¢é žãšãã«ã«æº¶è§£ãã次ã
ã§MARLON â396ïŒåååïŒã®æ°Žæº¶æ¶²ãäº
ãæ·»å ããæ瀺éã®æ°Žã«æº¶è§£ãããŒã©ãã³ã«æ¿
ããæ¹æããªããæ·»å ãããããã§é ¢é žãšãã«
ãæžå§äžèžçºã«ããé€ããã MARLON â396ã¯æ¬¡ã®åŒïŒ ããã§ïŒ²ã¯C10âC13nâã¢ã«ãã«ã§ãããã
æã€æ¹¿æœ€å€ã«å¯Ÿãã西ãã€ã AGããŒã«ïŒãŠ
ãšã¹ããã¢ãŒã¬ã³ ååŠäŒç€Ÿãã«ãºã®åååã§
ããã ããžãšã³ã¿ãããã¯ã·ã¢ã³è²çŽ æäŸååç©ã®å
æ£æ¶²ã®äœè£œ äœè£œã¯æ¬¡ã®æåã䜿çšãã以å€ã¯ååç©Y1
ã®åæ£æ¶²ã®äœè£œãšåæ§ã«è¡ãªãããã è²çŽ æäŸååç© 17ïœ ãŒã©ãã³ 25ïœ MARLON â396ïŒåååïŒã®10ïŒ æ°Žæº¶æ¶²
10ml èžæºæ°Žãå ã㊠300ïœ ãŸã§ã«ããã ããžãšã³ã¿ãããã¯ã·ã¢ã³æäŸååç©ã®é ¢é ž
ãšãã«ã«å¯Ÿãã溶解床ãäžå åãªå Žåã«ã¯ãäž
èšæåããµã³ããã«ã«ãããããšã«ããåæ£æ¶²
ãäœè£œããã äžè¿°ã®æäœã«åŸã€ãŠãããžãšã³ã¿ãããã¯ã·ã¢
ã³è²çŽ æäŸååç©ïŒè¡šïŒïŒã®éžæãçžäºã«ç°ãªã
ããããã®è©ŠéšçïŒïŒâ15ïŒãäœè£œãããæ°çµã®
æ¯èŒè©Šéšã§çšããååç©ã®æ§é ãè¡šïŒâïŒã«ç€º
ãã é²å ãšåŠç è©ŠéšçïŒâïŒã®åã ãã·ã¢ã³ïŒããªãã¡èµ€è²å
ç·ãåžåããïŒãã€ã«ã¿ãŒãéããŠé²å ããŠé»æ
ããã³ç·æå±€ãå åé²å ããã次ãã§åäžè©Šéšç
ãå®æ°0.15ã®å åŠæ¥ãéããŠçœè²å ã«é²å ããã
è©ŠéšéšçïŒâ15ã®åã ãããžãšã³ã¿ïŒããªãªãã¡
ç·è²å ç·ãåžåããïŒãã€ã«ã¿ãŒãéããŠé²å ã
ãŠé»æããã³èµ€æå±€ãå åé²å ããã次ãã§åäž
è©Šéšçãå®æ°0.15ã®å åŠæ¥ãéããŠçœè²å ã«é²å
ããã é²å ããè©Šéšçããæ¡æ£è»¢ååŠçè£ ã§ãã®ç¿ã®
äžã«åœã次ã®ååç©ãããªã氎溶液ãå«ã
COPYPROOF CP 38ïŒåååïŒäžã§ïŒåéå容
ææïŒåŸè¿°ããåŠãçµæç©ïŒãšæ¥è§ŠãããŠåŠçã
ãã ããªç¡«é žãããªãŠã ïŒïœ æ°Žé žåãããªãŠã 15ïœ ïŒïŒïŒâãã¹âããããã·ã¡ãã«âã·ã¯ããã
ãµã³ 12.5ïœ ïŒâã¡ãã«âïŒâãããã«âïŒïŒïŒâãããã³
ãžãªãŒã« 12.5ïœ èåã«ãªãŠã ïŒïœ èžæºæ°Žãå ã㊠1000ml ãŸã§ã«ããã å容ææã®çµæ äžèšæå æ§ææã«å¯ŸããŠèšèŒãããšåãæ¯æäœ
ã«å¹³è¡ïœåœã次ã®çµæãæã€å¡åžæ¶²ãå¡åžããã ãŒã©ãã³ ïŒïœ ããªããšãã«âïœâãããµãã·ã«ãã¹ãããŠã
ãããã€ã ïŒïœ
ãè¡šã
ãè¡šã
ãè¡šã
ãè¡šã
è¡šïŒã§ã¯ãè©ŠéšçïŒãšïŒãè©ŠéšïŒãšããŸãè©Šéš
çïŒãšïŒãè©ŠéšçïŒãšæ¯èŒããããšã«ããããã®
æ¯èŒã®çµæãããæ¬çºæã«åŸãã·ã¢ã³è²çŽ æäŸå
åç©ã¯ããæå©ãªDmaxïŒDminã®é¢ä¿ãçãã
ããšããŸãåäžDmaxã«ä¿®æ£åŸã§èæ ®ãããšçã
ãè²çŽ ãã¶ããäœãããšããããã è¡šïŒã§ã¯ãè©ŠéšçïŒïŒïŒããã³10ãè©Šéšç12ã
ãã³13ãšãäžæ¹è©ŠéšçïŒããã³11ãè©Šéšç14ãã
ã³15ãšæ¯èŒããªããã°ãªããªããããŒã¿ãŒããã
ãã€ãªã¢ãŒéšåïŒè©ŠéšçïŒãšïŒãåç §ïŒã®ïŒïŒïŒ
âãžã¡ãã«çœ®æã¯äœãDmaxå€ãçããã®ã«ãã
ã€ãªã¢ãŒéšåïŒè©Šéšç10ãš11åç §ïŒã®èåããµã€
ã¯ãªãã¯æ§é ã¯åäžDmaxã«å¯ŸããŠããé«ããã¶
ãå€ãçããçµæã«ãªãããšãããããæ¬çºæã«
åŸãããžãšã³ã¿è²çŽ æäŸååç©ã¯ãå ¬åãšãŒãã
ãç¹èš±åºé¡ç¬¬0004399ããã³0038092å·ã®æ¯èŒã§ã
ãåŸæ¥æè¡ååç©ãšæ¯èŒããŠãè²çŽ ãã¶ãã®ãã
äœãããšãç¹åŸŽã§ããããŸãããé«ãDmaxè²çŽ
å¯åºŠã«åçã§ããã å®æœäŸ ïŒ è©Šéšçã®äœè£œ äž¡é¢ã15ïœïŒm2ã®ããªãšãã¬ã³å±€ãå¡åžã
E110ïœïŒm2ã®çŽã·ãŒããããªãäžå¡ãããèæ°Ž
æ§çŽæ¯æäœãã³ããæŸé»ã§åŠçãããã®äžã«äžèš
é åºã§æ¬¡ã®å±€ãå¡åžããã ïŒïŒ 也ç¥ç¡¬ååŸå¹³æ¹ïœåœãäžèšååç©ãå«ãã¢
ã«ã«ãªééæ§ã³ãã€ãå±€ïŒ ãŒã©ãã³ 1.285ïœ ããžãšã³ã¿ãããã¯ãšããŒè²çŽ æäŸãããã€ã
ååç©ïŒè¡šïŒåç §ïŒïŒå®æœäŸïŒã§èšèŒããåŠã
äœè£œããåæ£æ¶²ããå ããïŒ 0.31ããªã¢ã« ïŒïŒïŒâãã¹ïŒ1â²ïŒ1â²ïŒ3â²ïŒ3â²âããã©ã¡ãã«
ããã«ïŒãã€ããããã³ 0.104ïœ å¡©åéïŒç·ææ§ãŒã©ãã³å¡©åéä¹³å€ããå ã
ãïŒ 0.553ïœ ïŒïŒ å¹³æ¹ïœåœã次ã®ååç©ãå«ãä¿è·å±€ïŒä¹Ÿç¥
硬ååŸïŒïŒ ãŒã©ããã³ ïŒïœ äžè¿°ã®æäœã«åŸã€ãŠãããžãšã³ã¿ãããã¯ãšã
ãŒè²çŽ æäŸååç©ïŒè¡šïŒåç §ïŒã®éžæãçžäºã«ç°
ãªãããããã®è©Šéšçãäœè£œããã
çïŒãšïŒãè©ŠéšçïŒãšæ¯èŒããããšã«ããããã®
æ¯èŒã®çµæãããæ¬çºæã«åŸãã·ã¢ã³è²çŽ æäŸå
åç©ã¯ããæå©ãªDmaxïŒDminã®é¢ä¿ãçãã
ããšããŸãåäžDmaxã«ä¿®æ£åŸã§èæ ®ãããšçã
ãè²çŽ ãã¶ããäœãããšããããã è¡šïŒã§ã¯ãè©ŠéšçïŒïŒïŒããã³10ãè©Šéšç12ã
ãã³13ãšãäžæ¹è©ŠéšçïŒããã³11ãè©Šéšç14ãã
ã³15ãšæ¯èŒããªããã°ãªããªããããŒã¿ãŒããã
ãã€ãªã¢ãŒéšåïŒè©ŠéšçïŒãšïŒãåç §ïŒã®ïŒïŒïŒ
âãžã¡ãã«çœ®æã¯äœãDmaxå€ãçããã®ã«ãã
ã€ãªã¢ãŒéšåïŒè©Šéšç10ãš11åç §ïŒã®èåããµã€
ã¯ãªãã¯æ§é ã¯åäžDmaxã«å¯ŸããŠããé«ããã¶
ãå€ãçããçµæã«ãªãããšãããããæ¬çºæã«
åŸãããžãšã³ã¿è²çŽ æäŸååç©ã¯ãå ¬åãšãŒãã
ãç¹èš±åºé¡ç¬¬0004399ããã³0038092å·ã®æ¯èŒã§ã
ãåŸæ¥æè¡ååç©ãšæ¯èŒããŠãè²çŽ ãã¶ãã®ãã
äœãããšãç¹åŸŽã§ããããŸãããé«ãDmaxè²çŽ
å¯åºŠã«åçã§ããã å®æœäŸ ïŒ è©Šéšçã®äœè£œ äž¡é¢ã15ïœïŒm2ã®ããªãšãã¬ã³å±€ãå¡åžã
E110ïœïŒm2ã®çŽã·ãŒããããªãäžå¡ãããèæ°Ž
æ§çŽæ¯æäœãã³ããæŸé»ã§åŠçãããã®äžã«äžèš
é åºã§æ¬¡ã®å±€ãå¡åžããã ïŒïŒ 也ç¥ç¡¬ååŸå¹³æ¹ïœåœãäžèšååç©ãå«ãã¢
ã«ã«ãªééæ§ã³ãã€ãå±€ïŒ ãŒã©ãã³ 1.285ïœ ããžãšã³ã¿ãããã¯ãšããŒè²çŽ æäŸãããã€ã
ååç©ïŒè¡šïŒåç §ïŒïŒå®æœäŸïŒã§èšèŒããåŠã
äœè£œããåæ£æ¶²ããå ããïŒ 0.31ããªã¢ã« ïŒïŒïŒâãã¹ïŒ1â²ïŒ1â²ïŒ3â²ïŒ3â²âããã©ã¡ãã«
ããã«ïŒãã€ããããã³ 0.104ïœ å¡©åéïŒç·ææ§ãŒã©ãã³å¡©åéä¹³å€ããå ã
ãïŒ 0.553ïœ ïŒïŒ å¹³æ¹ïœåœã次ã®ååç©ãå«ãä¿è·å±€ïŒä¹Ÿç¥
硬ååŸïŒïŒ ãŒã©ããã³ ïŒïœ äžè¿°ã®æäœã«åŸã€ãŠãããžãšã³ã¿ãããã¯ãšã
ãŒè²çŽ æäŸååç©ïŒè¡šïŒåç §ïŒã®éžæãçžäºã«ç°
ãªãããããã®è©Šéšçãäœè£œããã
ãè¡šã
é²å
ãšåŠç
è©Šéšç16â24ã®åã
ããå®æ°0.15ã®å
åŠæ¥ã§ã«
ããŒãããç·è²å ééãã€ã«ã¿ãŒãéããŠé²å ã
ããè©Šéšç25â26ã®åã ããå®æ°0.15ã®å åŠæ¥ã§
ã«ããŒãããé»è²å ééãã€ã«ã¿ãŒãéããŠé²å
ãããé²å ããè©Šéšçã®åŠçãå®æœäŸïŒã«èšèŒã
ãåŠãæ£ç¢ºã«å®æœãããããžãšã³ã¿è²çŽ æäŸåå
ç©ã«ã€ããŠåŸãããçµæã«é¢ããè¡š10ã§ã¯ãè©Šéš
ç16ïŒ17ããã³19ã¯è©Šéšç21ããã³22ãšããŸãè©Š
éšç18ãš20ã¯è©Šéšç23ããã³24ãšæ¯èŒããããšãš
ãããåŸãããããŒã¿ãŒãããæ¬çºæã®ããžãšã³
ã¿è²çŽ æŸåºååç©ã¯åäžDmaxã«å¯ŸããŠè²çŽ ãã¶
ãïŒDminïŒãå®è³ªçã«ããäœãããšãç¹åŸŽã§ã
ãããšãããã³è²çŽ ãã¶ãã¯æ¥è§Šæéãšå ±ã«èã
ãå¢å ããªãããšããããã
ããŒãããç·è²å ééãã€ã«ã¿ãŒãéããŠé²å ã
ããè©Šéšç25â26ã®åã ããå®æ°0.15ã®å åŠæ¥ã§
ã«ããŒãããé»è²å ééãã€ã«ã¿ãŒãéããŠé²å
ãããé²å ããè©Šéšçã®åŠçãå®æœäŸïŒã«èšèŒã
ãåŠãæ£ç¢ºã«å®æœãããããžãšã³ã¿è²çŽ æäŸåå
ç©ã«ã€ããŠåŸãããçµæã«é¢ããè¡š10ã§ã¯ãè©Šéš
ç16ïŒ17ããã³19ã¯è©Šéšç21ããã³22ãšããŸãè©Š
éšç18ãš20ã¯è©Šéšç23ããã³24ãšæ¯èŒããããšãš
ãããåŸãããããŒã¿ãŒãããæ¬çºæã®ããžãšã³
ã¿è²çŽ æŸåºååç©ã¯åäžDmaxã«å¯ŸããŠè²çŽ ãã¶
ãïŒDminïŒãå®è³ªçã«ããäœãããšãç¹åŸŽã§ã
ãããšãããã³è²çŽ ãã¶ãã¯æ¥è§Šæéãšå ±ã«èã
ãå¢å ããªãããšããããã
ãè¡šã
ãšããŒè²çŽ æäŸååç©ã«ã€ããŠåŸãããçµæã«
é¢ããè¡š11ã§ã¯ãè©Šéšç25ã¯è©Šéšç26ãšæ¯èŒãã
ããšãšãããåŸãããããŒã¿ãŒãããæ¬çºæã«åŸ
ããšããŒè²çŽ æäŸååç©ã§ã¯ãããäœãDmin
ïŒãã¶ãïŒãšåãå€ã«å¯ŸããŠããé«ãDmaxå€ã
åŸãããããšããããã
é¢ããè¡š11ã§ã¯ãè©Šéšç25ã¯è©Šéšç26ãšæ¯èŒãã
ããšãšãããåŸãããããŒã¿ãŒãããæ¬çºæã«åŸ
ããšããŒè²çŽ æäŸååç©ã§ã¯ãããäœãDmin
ïŒãã¶ãïŒãšåãå€ã«å¯ŸããŠããé«ãDmaxå€ã
åŸãããããšããããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ ã¢ã«ã«ãªæ§æ°Žæº¶æ¶²ã§ã¢ã«ã«ãªééæ§ã³ãã€ã
åªäœãééããæãã¢ã«ã«ãªééæ§åªäœäžã§äžå
æ§ã§ããããã€è²çŽ éšåãšãã©ã¹ãåºãå«æãã
ãããã€ãååç©ãå«ãå°ããšãïŒã€ã®ã¢ã«ã«ãª
ééæ§ããã²ã³åé芪氎æ§ã³ãã€ãä¹³å€å±€ãæ æ
ããæ¯æäœãå«ã¿ãåèšååç©ãããã²ã³åéçŸ
åå€ã«ãããåçææäžã®åã«åŸã€ãŠçŸåå¯èœãª
ããã²ã³åéã®é床ãããé ãé床ã§éå å¯èœã§
ãããéå ç¶æ ã§ã¢ã«ã«ãªæ§æ¡ä»¶äžã§åèšè²çŽ éš
åãæŸåºå¯èœã§ããããã²ã³åéåçææã«ãã
ãŠãåèšãããã€ãååç©ãäžèšäžè¬åŒïŒ ãããã§R3ã¯ãããã€ãæ žã®é£œåé£æ¥ç°ç¶éš
åäžã®ïŒâãããã¯ïŒâäœïŒæå°ã«ãŠç€ºãïŒã«ã
ãæ°ŽçŽ ãŸãã¯ã¡ãã«åºã§ãããR9ã¯ã¢ã«ãã«åºã
眮æã¢ã«ãã«åºãè³éŠæåºãŸãã¯çœ®æè³éŠæåºã§
ãããR10ã¯æ°ŽçŽ ãã¢ã«ãã«åºãŸãã¯ã¢ãªãŒã«åº
ã§ããã眮æåºR9ãšR10ã®å°ããšãïŒã€ã¯ãã¢ã«
ã«ãªééæ§èŠªæ°Žæ§ã³ãã€ãå±€ãã¢ã«ã«ãªæ§æ°Žæº¶æ¶²
ã§ééããæåèšååç©ãåèšå±€äžã§äžåæ§ãšã
ãã«å åãªå€§ããã®ãã©ã¹ãåºãè¡šãããããã
ã¯ãããå å«ãããã«çžåœããããšããç¹åŸŽãšã
ãããã²ã³åéåçææã ïŒ R9ãã¢ã«ã³ãã·çœ®æããšãã«åºã§ããç¹èš±
è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®åçææã ïŒ èµ€ãç·ããã³éã®å ã«æå ããããã²ã³åé
ä¹³å€å±€ãæ æããæ¯æäœãå«ã¿ãåèšä¹³å€å±€ã®
åã ã¯ããããã·ã¢ã³ãããŒã³ã¿ããã³é»è²è²çŽ
ãæŸåºã§ããåèšãããã€ãååç©ãå«ãç¹èš±è«
æ±ã®ç¯å²ç¬¬ïŒé ãŸãã¯ç¬¬ïŒé èšèŒã®åçææã ïŒ ïŒã€ä»¥äžã®ãã¬äœçšæ§æå æ§ããã²ã³åéä¹³
å€å±€ãæ¯æãããå容局ããã³åèšä¹³å€å±€ãšåèš
æ¯æãããå容局ã®éã®ã¢ã«ã«ãªééæ§å åå°æ§
äžéæå±€ãå«ãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ãªãã第ïŒ
é ã®ããããã«èšèŒã®åçææã ïŒ åçææããäžå¯Ÿã®äžŠãã å å§éšæã®éã«ã
ã€ã«ã ãŠããããéããŠåŠçããã®ã«é©ãããã€
ã«ã ãŠãããã§ãããåèšãŠãããã(1)åãã¯ã¢
ã«ã«ãªééæ§ã³ãã€ãåªäœäžã§äžåæ§ã§ãããã
ããŠã¢ã«ã«ãªåºŠããã³ããã²ã³åéçŸåå€ã®éå
äœçšã«ããè²çŽ ãæ¡æ£æ§ç¶æ ã§åé¢ããåèšãã
ãã€ãååç©ãçµåãããŠæããããã²ã³åéä¹³
å€å±€ãå«ãæå æ§ãšã¬ã¡ã³ãã(2)åè²çŽ å容局ã
(3)ã¢ã«ã«ãªæ§åŠççµæç©ããã€ã«ã ãŠãããå éš
ã§æŸåºããæ段ïŒãã®æ段ã¯ç Žè£å¯èœãªå®¹åšã§ã
ã€ãŠããã®å®¹åšã¯å å§éšæã«ãã€ãŠå®¹åšã«ããã
å§çž®åã§ãã€ã«ã å ã§å®¹åšã®å 容ç©ã®æŸåºãè¡ã
ããã«ãã€ã«ã ã®åŠçäžã«ååšããããã«ãªãã
ãŠããïŒãããã³(4)åèšãã€ã«ã ãŠãããå ã«å
åšããã¢ã«ã«ãªæ§åŠççµæç©ã«å¯æº¶æ§ã§ãããã
ã²ã³åéçŸåå€ãå«æããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé
èšèŒã®åçææã ïŒ éå ãããç¶æ ã§ããã³ã¢ã«ã«ãªæ§æ¡ä»¶äžã§
è²çŽ éšåãæŸåºå¯èœã§ãããã¢ã«ã«ãªæ§æ°Žæº¶æ¶²ã§
ã¢ã«ã«ãªééæ§ã³ãã€ãåªäœãééããæåèšåª
äœäžã§ååç©ãäžåæ§ãªããããããã®ãã©ã¹ã
åºãå«ããããã€ãååç©ã«ãããŠãåèšããã
ã€ãååç©ãäžèšäžè¬åŒïŒ ãããã§R8ã¯ãããã€ãæ žã®é£œåé£æ¥ç°ç¶éš
åäžã®ïŒâãããã¯ïŒâäœïŒæå°ã«ãŠç€ºãïŒã«ã
ãæ°ŽçŽ ãŸãã¯ã¡ãã«åºã§ãããR9ã¯ã¢ã«ãã«åºã
眮æã¢ã«ãã«åºãè³éŠæåºãŸãã¯çœ®æè³éŠæåºã§
ãããR10ã¯æ°ŽçŽ ãã¢ã«ãã«åºãŸãã¯ã¢ãªãŒã«åº
ã§ããã眮æåºR9ãšR10ã®å°ããšãïŒã€ã¯ãã¢ã«
ã«ãªééæ§èŠªæ°Žæ§ã³ãã€ãå±€ãã¢ã«ã«ãªæ§æ°Žæº¶æ¶²
ã§ééããæåèšååç©ãåèšå±€äžã§äžåæ§ãšã
ãã«å åãªå€§ããã®ãã©ã¹ãåºãè¡šãããããã
ã¯ãããå å«ãããã«çžåœããããšãç¹åŸŽãšãã
ãããã€ãååç©ã ïŒ R9ãã¢ã«ã³ãã·ããšãã«åºã§ããç¹èš±è«æ±
ã®ç¯å²ç¬¬ïŒé èšèŒã®ãããã€ãååç©ã
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8232448 | 1982-11-12 | ||
| GB8232448 | 1982-11-12 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59101649A JPS59101649A (ja) | 1984-06-12 |
| JPH0379700B2 true JPH0379700B2 (ja) | 1991-12-19 |
Family
ID=10534240
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58211668A Granted JPS59101649A (ja) | 1982-11-12 | 1983-11-10 | æ¡æ£è»¢åææããã³æ¹æ³ |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4477554A (ja) |
| EP (1) | EP0109701B1 (ja) |
| JP (1) | JPS59101649A (ja) |
| CA (1) | CA1214352A (ja) |
| DE (1) | DE3368470D1 (ja) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3464288D1 (en) * | 1983-03-15 | 1987-07-23 | Agfa Gevaert Nv | Photographic silver halide material containing a ballasted electron-donor precursor compound |
| JPS6083031A (ja) * | 1983-10-13 | 1985-05-11 | Fuji Photo Film Co Ltd | åçæå ææ |
| EP0208022B1 (en) * | 1985-07-09 | 1989-05-17 | Agfa-Gevaert N.V. | Yellow dye-releasing azo compounds for use in the production of diffusion transfer colour images |
| JPH07120009B2 (ja) * | 1986-06-06 | 1995-12-20 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ç»å圢ææ¹æ³ |
| US4746592A (en) * | 1986-08-27 | 1988-05-24 | Eastman Kodak Company | Color correction in negative images using positive imaging chemistry |
| JPH07119986B2 (ja) * | 1987-05-15 | 1995-12-20 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | ããã²ã³åéæå ææ |
| DE3778363D1 (de) | 1987-09-11 | 1992-05-21 | Agfa Gevaert Nv | Polymerisches phosphoniumbeizmittel und photographisches element, das dieses enthaelt. |
| US5336761A (en) | 1991-03-05 | 1994-08-09 | Fuji Photo Film Co., Ltd. | Heat-developable diffusion transfer color photographic material |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4139379A (en) * | 1977-03-07 | 1979-02-13 | Eastman Kodak Company | Photographic elements containing ballasted electron-accepting nucleophilic displacement compounds |
| DE2962762D1 (en) * | 1978-03-22 | 1982-07-01 | Agfa Gevaert Nv | Photographic material suited for use in diffusion transfer photography and method of diffusion transfer photography using such material |
| DE3162464D1 (en) * | 1980-04-14 | 1984-04-12 | Agfa Gevaert Nv | Photographic material suited for use in diffusion transfer photography |
-
1983
- 1983-10-20 EP EP83201506A patent/EP0109701B1/en not_active Expired
- 1983-10-20 DE DE8383201506T patent/DE3368470D1/de not_active Expired
- 1983-10-26 US US06/545,434 patent/US4477554A/en not_active Expired - Fee Related
- 1983-10-28 CA CA000439954A patent/CA1214352A/en not_active Expired
- 1983-11-10 JP JP58211668A patent/JPS59101649A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59101649A (ja) | 1984-06-12 |
| CA1214352A (en) | 1986-11-25 |
| US4477554A (en) | 1984-10-16 |
| EP0109701B1 (en) | 1986-12-17 |
| EP0109701A1 (en) | 1984-05-30 |
| DE3368470D1 (en) | 1987-01-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS6217217B2 (ja) | ||
| CA1159451A (en) | Photographic material suited for use in diffusion transfer photography | |
| JPS6187155A (ja) | åçèŠçŽ | |
| US4619884A (en) | Photographic products employing nondiffusible N',N'-diaromatic carbocyclic--or diaromatic heterocyclic--sulfonohydrazide compounds capable of releasing photographically useful groups | |
| JPS6314345B2 (ja) | ||
| JPS602654B2 (ja) | åççµäœ | |
| US4871654A (en) | Photographic element incorporating redox compounds for use in a dye diffusion transfer process | |
| EP0059269A2 (en) | Photographic elements containing blocked dyes or blocked dye releasing compounds and processes for using them | |
| US4450223A (en) | Diffusion transfer material and process | |
| US4663273A (en) | Non-diffusing compounds capable of releasing a diffusible dye or dye precursor compound with multiple dye units | |
| JPS5914739B2 (ja) | ã«ã©âæ¡æ£è»¢åæ³ | |
| US4369243A (en) | Photographic recording material for diffusion processes and useful non-diffusing sulfilimine compounds | |
| JPS59101649A (ja) | æ¡æ£è»¢åææããã³æ¹æ³ | |
| JPH0223856B2 (ja) | ||
| GB1568855A (en) | Photographic silmer halide elements for the colour diffusion-transfer process | |
| US4149892A (en) | Color diffusion transfer photographic elements | |
| JPS6161099B2 (ja) | ||
| US4139383A (en) | Dye diffusion transfer employing pyridine azo dye | |
| US4537853A (en) | Photographic silver halide material containing a ballasted electron-donor precursor compound | |
| US4496645A (en) | Process for the production of a photographic color image by image-wise dye diffusion transfer | |
| US4777124A (en) | Azo dye compounds for use in a dye diffusion transfer process and photographic elements incorporating them | |
| JPS5944618B2 (ja) | ã«ã©âæ¡æ£è»¢åæ³ | |
| JPS6155650A (ja) | ããŒã³ã¿æææŸåºæ§éæ¡æ£æ§ååç©ãçšãæ¡æ£è»¢ååã補é ããæ¹æ³ | |
| JPS5945140B2 (ja) | ã«ã©âåçæå ææ | |
| JPH0229646A (ja) | ããŒã³ã¿æææŸåºæ§ååç© |