JPH04204667A - Production of electrophotograph planographic printing plate and producing device - Google Patents
Production of electrophotograph planographic printing plate and producing deviceInfo
- Publication number
- JPH04204667A JPH04204667A JP33577890A JP33577890A JPH04204667A JP H04204667 A JPH04204667 A JP H04204667A JP 33577890 A JP33577890 A JP 33577890A JP 33577890 A JP33577890 A JP 33577890A JP H04204667 A JPH04204667 A JP H04204667A
- Authority
- JP
- Japan
- Prior art keywords
- printing
- toner
- plate
- fixing
- original plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- DBTMGCOVALSLOR-VPNXCSTESA-N laminarin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)OC1O[C@@H]1[C@@H](O)C(O[C@H]2[C@@H]([C@@H](CO)OC(O)[C@@H]2O)O)O[C@H](CO)[C@H]1O DBTMGCOVALSLOR-VPNXCSTESA-N 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- AIHDCSAXVMAMJH-GFBKWZILSA-N levan Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)OC[C@@H]1[C@@H](O)[C@H](O)[C@](CO)(CO[C@@H]2[C@H]([C@H](O)[C@@](O)(CO)O2)O)O1 AIHDCSAXVMAMJH-GFBKWZILSA-N 0.000 description 1
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 description 1
- 229910052912 lithium silicate Inorganic materials 0.000 description 1
- 235000010420 locust bean gum Nutrition 0.000 description 1
- 239000000711 locust bean gum Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000007726 management method Methods 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 229920003087 methylethyl cellulose Polymers 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- LKKPNUDVOYAOBB-UHFFFAOYSA-N naphthalocyanine Chemical compound N1C(N=C2C3=CC4=CC=CC=C4C=C3C(N=C3C4=CC5=CC=CC=C5C=C4C(=N4)N3)=N2)=C(C=C2C(C=CC=C2)=C2)C2=C1N=C1C2=CC3=CC=CC=C3C=C2C4=N1 LKKPNUDVOYAOBB-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000004866 oxadiazoles Chemical class 0.000 description 1
- 150000003891 oxalate salts Chemical class 0.000 description 1
- 150000007978 oxazole derivatives Chemical class 0.000 description 1
- 235000013808 oxidized starch Nutrition 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- INAAIJLSXJJHOZ-UHFFFAOYSA-N pibenzimol Chemical compound C1CN(C)CCN1C1=CC=C(N=C(N2)C=3C=C4NC(=NC4=CC=3)C=3C=CC(O)=CC=3)C2=C1 INAAIJLSXJJHOZ-UHFFFAOYSA-N 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920003227 poly(N-vinyl carbazole) Polymers 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 239000011698 potassium fluoride Substances 0.000 description 1
- 235000003270 potassium fluoride Nutrition 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 238000012802 pre-warming Methods 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- JEXVQSWXXUJEMA-UHFFFAOYSA-N pyrazol-3-one Chemical class O=C1C=CN=N1 JEXVQSWXXUJEMA-UHFFFAOYSA-N 0.000 description 1
- 150000003219 pyrazolines Chemical class 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical class C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 125000000565 sulfonamide group Chemical group 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- JOUDBUYBGJYFFP-FOCLMDBBSA-N thioindigo Chemical class S\1C2=CC=CC=C2C(=O)C/1=C1/C(=O)C2=CC=CC=C2S1 JOUDBUYBGJYFFP-FOCLMDBBSA-N 0.000 description 1
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229940100445 wheat starch Drugs 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
- 229940075420 xanthine Drugs 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Manufacture Or Reproduction Of Printing Formes (AREA)
- Printing Plates And Materials Therefor (AREA)
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明は光導電層上に、トナー画像を形成した後、トナ
ー画像部以外の非画像部を除去することにより印刷版と
する電子写真式平版印刷版、特に印刷汚れが防止された
平版印刷版を与える電子写真式平版印刷版の製造方法に
関する。Detailed Description of the Invention (Industrial Application Field) The present invention is an electrophotographic method in which a printing plate is produced by forming a toner image on a photoconductive layer and then removing a non-image area other than the toner image area. The present invention relates to a method for producing a lithographic printing plate, particularly an electrophotographic lithographic printing plate that provides a lithographic printing plate in which printing stains are prevented.
(従来の技術)
今日、平版オフセット印刷版としては、ジアゾ化合物と
フェノール樹脂を主成分とするポジ型感光剤やアクリル
系モノマーやプレポリマーを主成分とするネガ型感光剤
を用いる25版などが実用化されているが、これらはす
べて低感度のため、あらかじめ画像記録されたフィルム
原版を密着露光して製版を行なっている。一方、コンピ
ュータ画像処理と大容量データの保存およびデータ通信
技術の進歩によって、近年では、原稿人力、補正、編集
、割り付けから頁組まで一貫してコンピュータ操作され
、高速通信網や衛星通信により即時遠隔地の末端プロッ
タに出力できる電子編集システムが実用化している。特
に、即時性の要求される新聞印刷分野において電子編集
システムの要求度は高い。また、現在オリジナル原稿が
フィルムの形で保存され、これをもとに必要に応じて印
刷版が複製されている分野においても、光ディスクなど
の大容量記録メディアが発達するのにともなって、オリ
ジナルがこれらの記録メディアにデジタルデータとして
保存されるようになると考えられる。(Prior art) Today, as lithographic offset printing plates, there are 25 plates that use positive-working photosensitizers whose main components are diazo compounds and phenolic resins, and negative-working photosensitizers whose main components are acrylic monomers and prepolymers. Although these have been put into practical use, all of them have low sensitivity, so plate making is performed by contact exposure of a film original plate on which an image has been recorded in advance. On the other hand, advances in computer image processing, large-capacity data storage, and data communication technology have meant that in recent years, everything from manipulating manuscripts, corrections, editing, and layout to page composition has become computer-operated, and instant remote control is available through high-speed communication networks and satellite communications. An electronic editing system that can output to a terminal plotter has been put into practical use. In particular, electronic editing systems are in high demand in the field of newspaper printing, which requires immediacy. Furthermore, even in the field where original manuscripts are currently stored in the form of film and printed versions are reproduced as needed based on this, with the development of large-capacity recording media such as optical discs, the original It is thought that data will be stored as digital data on these recording media.
しかしながら、プロッタの出力から直接印刷版を作成す
る直接型印刷版はほとんど実用化されておらず、電子編
集システムの稼働しているところでも出力は銀塩写真フ
ィルムにより行なわれ、これをPS版へ密着露光するこ
とにより印刷版が作成されているのか実情である。これ
は、出力プロッタの光源(例えば、He−Neレーザ、
半導体レーザなと)により実用的な時間内に印刷版を作
成できるだけの高い感度を有する直接型印刷版の開発が
困難であることも1つの原因であった。However, direct printing plates that create printing plates directly from plotter output are hardly ever put into practical use, and even in places where electronic editing systems are in operation, output is done using silver halide photographic film, which is then converted into PS plates. The reality is that printing plates are created by contact exposure. This is the light source of the output plotter (e.g. He-Ne laser,
One of the reasons was that it was difficult to develop a direct printing plate with a sensitivity high enough to make a printing plate within a practical time using a semiconductor laser (such as a semiconductor laser).
直接型印刷版を提供し得る高い光感度を有する感光体と
して電子写真感光体が考えられる。電子写真を用いた印
刷版作成の方法としては、トナー画像形成後、非画像部
の光導電層を除去する方法が知られている。例えは、特
公昭37−17162号、同38−fi9B1号、同3
8−7758号、同41−2426号、同46−394
05号、特開昭50−19509号、同50−1951
0号、同52−2437号、同54−145538号、
同54−134832号、同55−IC15254号、
同55−153948号、同55−161250号、同
57−147656号、同57−1518[13号公報
等に記載の電子写真式製版用印刷原版かあげられる。Electrophotographic photoreceptors are considered as photoreceptors with high photosensitivity that can provide direct printing plates. As a method of producing a printing plate using electrophotography, a method is known in which a photoconductive layer in a non-image area is removed after forming a toner image. For example, Special Publication No. 37-17162, No. 38-fi9B1, No. 3
No. 8-7758, No. 41-2426, No. 46-394
No. 05, JP-A No. 50-19509, JP-A No. 50-1951
No. 0, No. 52-2437, No. 54-145538,
No. 54-134832, No. 55-IC15254,
Examples include printing original plates for electrophotographic plate making as described in Publications No. 55-153948, No. 55-161250, No. 57-147656, No. 57-1518 [13].
上記方法ては、電子写真感光体の非画像部をエツチング
で除去し親水性の面を露出させる必要があるため、結合
樹脂としてアルカリ性溶剤に溶解するか、もしくは膨潤
して脱離する結合樹脂を用いることが多い。In the above method, it is necessary to remove the non-image area of the electrophotographic photoreceptor by etching to expose the hydrophilic surface. Often used.
このようにして得られた印刷版を用いて印刷する場合、
通常の枚葉印刷機のように印刷版のサイズよりも小さい
紙に印刷する場合には印刷版の端部に相当する部分か印
刷面とならず、問題はない。When printing using the printing plate obtained in this way,
When printing on paper smaller than the size of the printing plate as in a normal sheet-fed printing press, there is no problem because the printing surface is not the part corresponding to the edge of the printing plate.
しかしながら、新聞印刷のような輪転機を用いてロール
状の紙に印刷する場合には、印刷版端部に相当する場所
に印刷汚れが発生する。この汚れは、反転現像によりト
ナー現像した場合に特に著しい。However, when printing on a roll of paper using a rotary press such as newspaper printing, printing stains occur at locations corresponding to the edges of the printing plate. This stain is particularly noticeable when toner development is performed by reversal development.
(発明が解決しようとする課題)
電子写真式製版用平版印刷原版を反転現像して得られた
平版印刷版による端部汚れ防止として、電子写真式製版
用平版印刷原版の端部(側面)に絶縁性樹脂層を設ける
ことによりトナー付着を防止する方法が提案されている
(特開昭63−178240号)。しかしながら、上記
の手段によっても端部汚れの解消は不十分であった。そ
こで、印刷原版の端部を不感脂化することにより端部汚
れを防止することか特願平1−227398号、同1−
159404号に提案されているが、一般に不感脂化液
は導電性の場合が多く、現像時、特に反転現像において
トナー付着が発生し、端部汚れの解消は不十分であった
。また、特開平1−2616[i0号には現像部と定着
部の間でトナーを除去することが提案されているか、乾
燥したトナーを完全に機械的に除去することは困難であ
ると同時に、除去したトナー粉末による装置、印刷原版
あるいは環境を汚染するという問題があった。(Problems to be Solved by the Invention) In order to prevent edge staining caused by a lithographic printing plate obtained by reversing development of a lithographic printing original plate for electrophotographic platemaking, the edges (side surfaces) of the lithographic printing original plate for electrophotographic platemaking are coated. A method of preventing toner adhesion by providing an insulating resin layer has been proposed (Japanese Patent Laid-Open No. 178240/1983). However, even with the above-mentioned means, the end stains were not sufficiently eliminated. Therefore, it has been proposed to prevent the edges from becoming dirty by desensitizing the edges of the printing plate.
No. 159404 has proposed this method, but desensitizing liquids are generally conductive in many cases, and toner adhesion occurs during development, particularly during reversal development, and the removal of edge stains is insufficient. Furthermore, Japanese Patent Application Laid-Open No. 1-2616 [i0] proposes to remove toner between a developing section and a fixing section, and it is difficult to completely remove dried toner mechanically. There is a problem in that the removed toner powder contaminates the device, the original printing plate, or the environment.
この発明は上述のような事情よりなされたものであり、
この発明の目的は上述した各従来技術の欠点を解決し、
反転現像したときにエツジ部に付着したトナーによる印
刷汚れを確実に防止するようにした電子写真式平版印刷
版の製造方法及び装置を提供することにある。This invention was made due to the circumstances mentioned above,
The purpose of this invention is to solve the drawbacks of the above-mentioned prior art,
It is an object of the present invention to provide a method and apparatus for producing an electrophotographic lithographic printing plate that reliably prevents printing stains caused by toner adhering to the edge portions during reverse development.
(課題を解決するための手段)
本発明者等は前記課題を解決するために鋭意検討した結
果、導電性基板上に光導電層を層設された電子写真式平
版印刷原版に対して少なくとも帯電する帯電工程と、露
光する露光工程と、トナーを用いて現像する現像工程と
、定着する定着工程と、トナー画像以外の前記光導電層
を除去する工程(以下エツチング工程と称す)とにより
電子写真式平版印刷版を製造する方法において、前記現
像工程における前記電子写真式平版印刷原版の所要の部
分のトナーのみを定着するようにしたことによって上記
課題を解決することができた。(Means for Solving the Problems) As a result of intensive studies to solve the above problems, the present inventors have found that an electrophotographic lithographic printing original plate having a photoconductive layer formed on a conductive substrate is at least charged. An electrophotographic process includes a charging process, an exposure process, a developing process using toner, a fixing process, and a process for removing the photoconductive layer other than the toner image (hereinafter referred to as an etching process). In a method for manufacturing a lithographic printing plate, the above problem can be solved by fixing toner only in a required portion of the electrophotographic lithographic printing original plate in the developing step.
(作用)
前記のような新聞印刷において、トナー現像後の電子写
真式平版印刷原版の必要な画像部のみを定着し、端部、
特に側面部に付着したトナーを定−着せずに非画像部の
エツチングを行なうことにより除去するもので、前記の
ように特段のトナー除去手段を設けることなく、端部に
印刷汚れのない平版印刷版を製版することができる。本
発明は新聞印刷の他に、同一の電子写真式平版印刷原版
上に複数のページを設け、製版する場合(多面付け)、
必要な画像部以外に付着したトナ一部分を定着せず、エ
ツチング処理することにより特段のトナー除去手段を設
けることなく、汚れのない平版印刷版を製版することか
できる。(Function) In newspaper printing as described above, only the necessary image areas of the electrophotographic lithographic original plate after toner development are fixed, and the edges,
In particular, toner adhering to the side surfaces is removed by etching the non-image areas without fixing the toner, and as mentioned above, it is possible to perform planographic printing without printing stains on the edges without the need for special toner removal means. Able to make plates. In addition to newspaper printing, the present invention is applicable to cases in which a plurality of pages are provided on the same electrophotographic lithographic original plate for plate making (multi-page printing).
By etching a portion of the toner that has adhered to areas other than the necessary image areas without fixing them, a clean lithographic printing plate can be made without any special toner removal means.
本発明の定着方式としては従来公知の方法を使用するこ
とができる。例えば、赤外線ランプ、キセノンフラッシ
ュ等による輻射伝熱による方法、面状あるいはリボンヒ
ータ等による対流伝熱による方法、加熱ローラあるいは
ベルトの接触による熱伝動による方法、高周波゛による
加熱、圧力、溶剤蒸気等による方法あるいはこれらを組
み合わせることにより定着することができる。As the fixing method of the present invention, conventionally known methods can be used. For example, radiant heat transfer using infrared lamps, xenon flash, etc., convection heat transfer using planar or ribbon heaters, heat transfer via contact with heating rollers or belts, high frequency heating, pressure, solvent vapor, etc. Fixation can be achieved by the following methods or by a combination of these methods.
本発明のように任意の部分を定着するためには輻射伝熱
、接触による熱伝導、高周波、圧力による定着が好まし
く使用できるが、その他の方法も使用可能である。これ
らの定着方法を用いて、任意の部分のみ定着するために
は、例えば、輻射伝熱による場合は反射板あるいはレン
ズ等を用いて必要な画像部のみに熱線を照射するか、あ
るいは不必要なトナ一部に熱線を反射する治具を設ける
ことにより実現することができる。更に必要に応じて不
必要なトナ一部分のみを冷却することにより、より効果
的に本発明を実施することができる。To fix an arbitrary part as in the present invention, radiation heat transfer, heat conduction by contact, high frequency, and pressure fixing are preferably used, but other methods can also be used. In order to fix only a desired area using these fixing methods, for example, in the case of radiation heat transfer, it is necessary to use a reflector or lens to irradiate heat rays only to the necessary image area, or to fix unnecessary areas. This can be realized by providing a jig that reflects heat rays in a part of the toner. Furthermore, the present invention can be carried out more effectively by cooling only a portion of the toner that is unnecessary, if necessary.
また、接触方式による定着の場合には、必要な画像部の
みに定着機を接触させ任意の部分のみを定着することが
可能である。Further, in the case of fixing by a contact method, it is possible to fix only an arbitrary portion by bringing the fixing device into contact with only a necessary image portion.
(実施例)
第1図(A)および(B)は本発明の平版印刷原版の製
造方法の一実施例を示す平面図および側面図である。ト
ナー現像された電子写真印刷原版3は図示せぬ搬送方法
によって定着工程に搬送される。定着工程は少なくとも
赤外線ラインヒータ1、反射板6、遮蔽板2から構成さ
れ、ラインヒータ1で発生した赤外線は反射板6により
平行光線となり印刷原版3の表面に到達する。この赤外
線によって印刷原版上の定着部5のトナー像は加熱定着
されるが、印刷原版端部4は遮蔽板2により赤外線を反
射することによりトナ一定着することなく定着工程を搬
送される。次に、この部分的に定着された印刷原版をエ
ツチングすると、定着部5の部分においてはトナー非画
像部のみが溶比するが、印刷原版端部4の部分において
はトナー像も溶出した。これによって特段の処理工程を
設けることなく端部汚れの全く無い印刷版を製造するこ
とができた。(Example) FIGS. 1A and 1B are a plan view and a side view showing an example of the method for manufacturing a lithographic printing original plate of the present invention. The electrophotographic printing original plate 3 that has been developed with toner is transported to a fixing step by a transport method (not shown). The fixing process is composed of at least an infrared line heater 1, a reflection plate 6, and a shielding plate 2, and the infrared rays generated by the line heater 1 are turned into parallel rays by the reflection plate 6 and reach the surface of the printing original plate 3. The toner image in the fixing unit 5 on the printing original plate is heated and fixed by this infrared rays, but the printing original plate end portion 4 is transported through the fixing step without the toner fixed thereon because the shielding plate 2 reflects the infrared rays. Next, when this partially fixed printing original plate was etched, only the toner non-image area was eluted in the fixing portion 5, but the toner image was also eluted in the printing original plate edge 4 portion. As a result, it was possible to produce a printing plate with no edge stains at all without providing any special processing steps.
第2図(A)および(B)は本発明の平版印刷原版の製
造方法の他の実施例を示す平面図および側面図である。FIGS. 2(A) and 2(B) are a plan view and a side view showing another embodiment of the method for manufacturing a lithographic printing original plate of the present invention.
定着工程は少なくともフラッシュランプ8、反射板6、
遮蔽板2から構成され、フラッシュランプ8で発生した
フラッシュ光9は反射板6により印刷原版3の表面で焦
点を結ぶように到達する。このフラッシュ光を複数回発
光させつつ、印刷原版を搬送することにより印刷原版上
の定着部5のトナー像は加熱定着される。また、印刷原
版端部4は遮蔽板2によってフラッシュ光を反射するこ
とによりトナ一定着することなく定着工程を搬送される
。これによって特段の処理工程を設けることなく端部汚
れの全く無い印刷版を製造することがてきた。The fixing process uses at least a flash lamp 8, a reflector 6,
It is composed of a shielding plate 2, and the flash light 9 generated by the flash lamp 8 reaches the surface of the printing original plate 3 so as to be focused by the reflecting plate 6. By conveying the printing original plate while emitting this flash light multiple times, the toner image in the fixing unit 5 on the printing original plate is heated and fixed. Further, the printing original plate end portion 4 is transported through the fixing process without toner being fixed thereon by reflecting the flash light by the shielding plate 2. As a result, printing plates with no edge stains can be produced without any special processing steps.
第3図(八)および(B)は本発明の平版印刷原版の製
造方法の更に他の実施例を示す平面図および側面図であ
る。定着工程は少なくとも印刷原版3よりも小さい圧力
ローラ10.+1から構成され、定着部5の部分のトナ
ーを圧力により定着しつつ印刷原版3が搬送される。こ
れによって特段の処理工程を設けることなく端部汚れの
全く無い印刷版を製造することができた。FIGS. 3(8) and 3(B) are a plan view and a side view showing still another embodiment of the method for manufacturing a lithographic printing original plate of the present invention. The fixing step is performed using a pressure roller 10, which is at least smaller than the original printing plate 3. +1, and the printing original plate 3 is conveyed while fixing the toner in the fixing section 5 by pressure. As a result, it was possible to produce a printing plate with no edge stains at all without providing any special processing steps.
第4図(八)および(B)に示す実施例は、定着工程は
少なくとも赤外線ラインヒータ12、反射板13、アル
ミニウム箔送り出しローラ15、アルミニウム箔押えロ
ーラ1B、アルミニウム箔巻き取りローラ17、アルミ
ニウム箔18から構成され、ラインヒータ12で発生し
た赤外線は反射板13により印刷原版3の表面で焦点を
結ぶように到達する。この赤外線を照射しつつ、印刷原
版を搬送することにより印刷原版上の定着部5のトナ、
−像は加熱定着される。また、印刷原版端部4はアルミ
ニウム箔18によって赤外線を反射すると同時に印刷原
版端部4の部分の放熱を促進し、トナ一定着することな
く定着工程を搬送される。これによって特段の処理工程
を設けることなく端部汚れの全く無い印刷版を製造する
ことができた。In the embodiment shown in FIGS. 4(8) and 4(B), the fixing process includes at least an infrared line heater 12, a reflecting plate 13, an aluminum foil feeding roller 15, an aluminum foil pressing roller 1B, an aluminum foil winding roller 17, an aluminum foil 18, and the infrared rays generated by the line heater 12 reach the surface of the printing original plate 3 by the reflection plate 13 so as to be focused on the surface. By conveying the printing original plate while irradiating this infrared ray, the toner in the fixing section 5 on the printing original plate,
- The image is heat-fixed. Further, the printing original plate end 4 reflects infrared rays by the aluminum foil 18, and at the same time promotes heat dissipation at the printing original plate end 4, so that the fixing process is carried out without the toner sticking to the original plate end 4. As a result, it was possible to produce a printing plate with no edge stains at all without providing any special processing steps.
第5図(A)および(B)は本発明の平版印刷原版の製
造方法の更に他の実施例を示す平面図および側面図であ
る。定着工程は少なくとも赤外線ラインヒータ12、冷
風吹き出し孔19から構成され、ラインヒータ12で発
生した赤外線は反射板13により印刷原版3の表面で焦
点を結ぶように到達する。FIGS. 5(A) and 5(B) are a plan view and a side view showing still another embodiment of the method for manufacturing a lithographic printing original plate of the present invention. The fixing process includes at least an infrared line heater 12 and a cold air blowing hole 19, and the infrared rays generated by the line heater 12 reach the surface of the printing original plate 3 through a reflection plate 13 so as to be focused.
この赤外線を照射しつつ、印刷原版を搬送することによ
り印刷原版上の定着部5のトナー像は加熱定着される。By conveying the printing original plate while irradiating the infrared rays, the toner image in the fixing section 5 on the printing original plate is heated and fixed.
また、印刷原版端部4は冷風吹き出し孔19から吹き出
される冷風20により冷却されトナーを定着することな
く定着工程を搬送される。Further, the printing original plate end portion 4 is cooled by the cold air 20 blown out from the cold air blowing hole 19 and is conveyed through the fixing process without fixing the toner.
これによって特段の処理工程を設けることなく端部汚れ
の全く無い印刷版を製造することができた。As a result, it was possible to produce a printing plate with no edge stains at all without providing any special processing steps.
第6図は第2図(八)に示した実施例を用いて複数頁を
有する印刷原版を製造するときの定着状態を示すもので
ある。FIG. 6 shows the fixing state when a printing original plate having a plurality of pages is manufactured using the embodiment shown in FIG. 2 (8).
本定着部の前工程として、感光体の給版部、帯電部、レ
ーザによる走査露光部あるいは銀塩原稿などを介した面
露光部、トナー現像等か設けられる。トナー現像に当た
っては従来公知の方法、例えは、カスケード現像、磁気
ブラシ現像、パウダークラウド現像、液体現像などの各
種の方法を用いることが出来る。なかでも液体現像は微
細な画像を形成することが可能であり、印刷版を作成す
るために好適である。この時、光導電体の帯電極性とト
ナーの帯電極性の組合せにより正現像、′反転現像何れ
の現像法も可能である。特に、反転現像の場合は印刷原
版の端部に電気的にトナーが付着し印刷汚れとなり易く
、本発明は特に効果的である。As a pre-processing step of the main fixing section, a plate feeding section for the photoreceptor, a charging section, a scanning exposure section using a laser, a surface exposure section via a silver halide original, a toner development, etc. are provided. For toner development, conventionally known methods such as cascade development, magnetic brush development, powder cloud development, liquid development, and various other methods can be used. Among these, liquid development is capable of forming fine images and is suitable for creating printing plates. At this time, either normal development or reverse development is possible depending on the combination of the charge polarity of the photoconductor and the charge polarity of the toner. In particular, in the case of reversal development, toner electrically adheres to the edges of the printing original plate, which tends to cause printing stains, so the present invention is particularly effective.
本定着部の後工程として必要によりエツチング部、水洗
部、不感脂化処理部、乾燥部、ベンダー部等の工程を設
けることができる。As a post-fixing step, steps such as an etching section, a washing section, a desensitizing section, a drying section, a bender section, etc. can be provided as necessary.
次に本発明の装置を使用できる電子写真式印刷原版の構
成について説明する。Next, the structure of an electrophotographic printing original plate that can use the apparatus of the present invention will be explained.
本発明を適用できる電子写真式印刷原版の導電性基板と
しては、各種の支持体を使用することができる。例えば
、導電性表面を有するプラスチックシートまたは特に溶
剤不透過性および導電性にした紙、アルミニウム板、亜
鉛板、または銅−アルミニウム板、銅−ステンレス板、
クロム−銅板等のバイメタル板、またはクロム−銅−ア
ルミニウム板、クロム−鉛−鉄板、クロム−銅−ステン
レス板等のトライメタル板等の親木性表面を有する導電
性基板が用いられ、その厚さは、0.1〜3mmの範囲
のもの、特に0.1〜0.5mmか好ましい。これらの
基板のなかでもアルミニウム板が好適に使用される。本
発明において用いられるアルミニウム板はアルミニウム
を主成分とする純アルミニウムや微量の異原子を含むア
ルミニウム合金などの板状体であり、その組成か特定さ
れるものではな〈従来公知、公用の素材を適宜使用する
ことが出来る。Various supports can be used as the conductive substrate of the electrophotographic printing original plate to which the present invention can be applied. For example, plastic sheets with an electrically conductive surface or papers made especially solvent-impermeable and electrically conductive, aluminum plates, zinc plates, or copper-aluminum plates, copper-stainless steel plates,
A conductive substrate with a wood-loving surface such as a bimetallic plate such as a chromium-copper plate, or a trimetallic plate such as a chromium-copper-aluminum plate, a chromium-lead-iron plate, or a chromium-copper-stainless steel plate is used, and its thickness The thickness is preferably in the range of 0.1 to 3 mm, particularly 0.1 to 0.5 mm. Among these substrates, aluminum plates are preferably used. The aluminum plate used in the present invention is a plate-like material such as pure aluminum whose main component is aluminum or an aluminum alloy containing a small amount of foreign atoms, and its composition is not specified. It can be used as appropriate.
本発明に用いられる光導電性材料としては従来から知ら
れている数多くの化合物を用いることができる。例えば
、トリアゾール8導体、オキサジアゾール誘導体、イミ
ダゾール誘導体、ポリアリルアルカン誘導体、ピラゾリ
ン誘導体、ピラゾロン誘導体、フェニレンジアミン誘導
体、アリルアミン話導体、アミノ置換カルコン話導体、
N、N −ビカルバジル銹導体、オキサゾール誘導体、
スチリルアントラセン話導体、フルオレノン誘導体、ヒ
ドラゾン誘導体、ベンジジン誘導体、スチルベン誘導体
等の低分子光導電性化合物、ポリビニルカルバゾール及
びその誘導体のような高分子化合物も使用することが出
来る。As the photoconductive material used in the present invention, many conventionally known compounds can be used. For example, triazole 8 conductors, oxadiazole derivatives, imidazole derivatives, polyallylalkane derivatives, pyrazoline derivatives, pyrazolone derivatives, phenylenediamine derivatives, allylamine conductors, amino-substituted chalcone conductors,
N,N-bicalbasil conductor, oxazole derivative,
Low molecular weight photoconductive compounds such as styryl anthracene conductors, fluorenone derivatives, hydrazone derivatives, benzidine derivatives, stilbene derivatives, and high molecular weight compounds such as polyvinyl carbazole and its derivatives can also be used.
また、光導電体の感度の向上、望みの感光波長域を持た
せるため等の目的のために、各種の顔料、増感染料等を
使用することが出来る。顔料の例としては、モノアゾ、
ビスアゾ、トリスアゾ顔料、金属フタロシアニンあるい
は無金属フタロシアニン等のフタロシアニン顔料、ナフ
タロシアニン顔料、ペリレン系顔料、インジゴ、チオイ
ンジゴ誘導体、キナクリドン系顔料、多環キノン系顔料
、ビスベンズイミダゾール系顔料、スクアリウム塩系顔
料、アズレニウム塩系顔料などである。Furthermore, various pigments, sensitizing dyes, and the like can be used for the purpose of improving the sensitivity of the photoconductor and imparting a desired photosensitive wavelength range. Examples of pigments include monoazo,
Bisazo, trisazo pigments, phthalocyanine pigments such as metal phthalocyanine or metal-free phthalocyanine, naphthalocyanine pigments, perylene pigments, indigo, thioindigo derivatives, quinacridone pigments, polycyclic quinone pigments, bisbenzimidazole pigments, squalium salt pigments, These include azulenium salt pigments.
また増感染料としては、[増感剤J No、81987
(講談社)125頁、「電子写真J 12 9 (19
73)、「有機合成化学」圓N0.111010 (1
966)等に記載の公知の化合物を使用することが出来
る。例えば、ビリリウム系染料、トリアリルメタン系染
料、シアニン系染料、スチリル系染料等がある。In addition, as a sensitizing agent, [Sensitizer J No. 81987
(Kodansha) p. 125, “Electronic Photography J 12 9 (19
73), “Organic Synthetic Chemistry” En No. 0.111010 (1
966) and the like can be used. Examples include biryllium dyes, triallylmethane dyes, cyanine dyes, and styryl dyes.
本発明を通用できる電子写真式製版用印刷原版において
使用する結合樹脂としてはトナー現像後非画像部を溶出
除去できれば良く、特定されるものではないが、公害性
あるいは取り扱い性の点からエツチング液として、アル
カリ性水溶液を主体としたエツチング液が好ましく使用
される。従って、結合樹脂としてもアルカリ性水溶液に
よって除去可能な化合物が好ましい。例えば、スチレン
/無水マレイン酸共重合体、スチレン/無水マレイン酸
モノアルキルエステル共重合体、メタクリル酸/メタク
リル酸エステル共重合体、スチレン/メタクリル酸/メ
タクリル酸エステル共重合体、アクリル酸/メタクリル
酸エステル共重合体、スチレン/アクリル酸/メタクリ
ル酸エステル共重合体、酢酸ビニル/クロトン酸共重合
体、酢9ビニル/クロトン酸/メタクリル酸エステル共
重合体等のアクリル酸エステル、メタクリル酸エステル
、スチレン、酢酸ビニルなどのアクリル酸、メタクリル
酸、イタコン酸、クロトン酸、マレイン酸、無水マレイ
ン酸、フマル酸などのカルボン酸含有子ツマ−あるいは
酸無水物基含有子ツマ−との共重合体やメタクリル酸ア
ミド、ビニルピロリドン、フェノール性水酸基、スルホ
ン酸基、スルホンアミド基、スルホンイミド基をもつ単
量体を含有する共重合体、フェノール樹脂、部分ケン化
酢酸ビニル樹脂、キシレン樹脂、ポリビニルブチラール
等のビニルアセタール樹脂をあげることができる。The binding resin used in the printing original plate for electrophotographic plate making that can be used in the present invention may be any resin that can elute and remove the non-image area after toner development, and although it is not specified, it can be used as an etching liquid from the viewpoint of pollution and ease of handling. An etching solution mainly composed of an alkaline aqueous solution is preferably used. Therefore, it is preferable that the binding resin be a compound that can be removed with an alkaline aqueous solution. For example, styrene/maleic anhydride copolymer, styrene/maleic anhydride monoalkyl ester copolymer, methacrylic acid/methacrylic acid ester copolymer, styrene/methacrylic acid/methacrylic acid ester copolymer, acrylic acid/methacrylic acid Acrylic esters such as ester copolymers, styrene/acrylic acid/methacrylic ester copolymers, vinyl acetate/crotonic acid copolymers, 9-vinyl acetate/crotonic acid/methacrylic ester copolymers, methacrylic esters, and styrene. , copolymers with acrylic acids such as vinyl acetate, methacrylic acid, itaconic acid, crotonic acid, maleic acid, maleic anhydride, fumaric acid and other carboxylic acid-containing substances or acid anhydride group-containing substances, and methacrylates. Copolymers containing acid amides, vinylpyrrolidone, monomers with phenolic hydroxyl groups, sulfonic acid groups, sulfonamide groups, sulfonimide groups, phenolic resins, partially saponified vinyl acetate resins, xylene resins, polyvinyl butyral, etc. Examples include vinyl acetal resin.
本発明を適用する電子写真式製版用印刷版は常法に従っ
て光導電層を導電性基板上に塗布することによって得ら
れる。光導電層の作成に当たっては、光導電層を構成す
る成分を同一層中に含有させる方法、°あるいは電荷担
体発生物質と電荷担体輸送物質を異なる層に分離して用
いる方法等が知られており、いづれの方法にても作成す
ることが出来る。The printing plate for electrophotographic platemaking to which the present invention is applied can be obtained by applying a photoconductive layer onto a conductive substrate according to a conventional method. In producing the photoconductive layer, there are known methods such as containing the components constituting the photoconductive layer in the same layer, or separating the charge carrier generating substance and the charge carrier transporting substance into different layers. , it can be created using either method.
本発明が適用できる電子写真式製版用印刷版の光導電層
には光導電性化合物、結合樹脂の他に光導電層の柔軟性
、塗布面性状あ改良等のために、必要゛により可塑剤、
界面活性剤、マ・ント剤その他の各種の添加剤を加える
ことができる。これらの添加剤は光導電層の静電特性、
エツチング性を劣化させない範囲で含有させることがで
きる。In addition to a photoconductive compound and a binding resin, the photoconductive layer of the electrophotographic printing plate to which the present invention can be applied contains a plasticizer, if necessary, to improve the flexibility of the photoconductive layer and the properties of the coated surface. ,
Various additives such as surfactants, management agents, and others can be added. These additives improve the electrostatic properties of the photoconductive layer,
It can be contained within a range that does not deteriorate etching properties.
本発明を適用する電子写真式製版用印刷原版においては
、必要により前記導電性基板と光導電層の接着性、光導
電層の電気特性、エツチング性、印刷特性等を改良する
目的で中間層を設けることができる。In the printing original plate for electrophotographic platemaking to which the present invention is applied, if necessary, an intermediate layer may be added for the purpose of improving the adhesion between the conductive substrate and the photoconductive layer, the electrical properties of the photoconductive layer, the etching properties, the printing properties, etc. can be provided.
中間層としては例えば、カゼイン、ポリビニルアルコー
ル、エチルセルロτス、ポリアクリル酸、モノエタノー
ルアミン、ジェタノールアミン、トリエタノールアミン
、トリブロノベノールアミン、トリエタノールアミンお
よびそれらの塩酸塩、蓚酸塩、燐酸塩、アラニン等のモ
ノアミノモノカルボン酸等の各種アミノ酸類がある。Examples of the intermediate layer include casein, polyvinyl alcohol, ethylcellulose, polyacrylic acid, monoethanolamine, jetanolamine, triethanolamine, tribronobenolamine, triethanolamine, and their hydrochlorides, oxalates, and phosphoric acids. There are various amino acids such as salts and monoamino monocarboxylic acids such as alanine.
また、光導電層上に必要により光導電層の電気特性、ト
ナー現像時の画像特性、トナーとの接着性等を改良する
目的で、光導電層上・ンチング時に除去てきるオーバー
コート層を設けることができる。このオーバーコート層
は機械的にマ・ント化されたものあるいはマット剤か含
有される樹脂層であっても良い。In addition, an overcoat layer that can be removed during nching is provided on the photoconductive layer, if necessary, for the purpose of improving the electrical properties of the photoconductive layer, image properties during toner development, adhesion with toner, etc. be able to. This overcoat layer may be a mechanically matted layer or a resin layer containing a matting agent.
また、本発明で使用する印刷原版には特開昭63−17
8240号、特開平2−61654号、同2−6656
5号等の様にあらかしめ印刷原版の端部に工・ンチング
液で除去可能な樹脂層を塗設しておくことにより、より
効果的に付着したトナーを除去することかできる。In addition, the printing original plate used in the present invention includes JP-A-63-17
No. 8240, JP 2-61654, JP 2-6656
By applying a resin layer removable with a processing/quenching liquid to the edge of the rough printing original plate, such as No. 5, the attached toner can be removed more effectively.
更に特願平1−159404号、開平1−227398
号、世事2−128587号の様にあらかしめ印刷原版
端部を不感脂化しておくことにより更に効果的に印刷時
の端部t”rれを防止することかできる。Furthermore, Japanese Patent Application No. 1-159404 and Kai-Hyou 1-227398
By desensitizing the edges of the original printing plate by pre-warming as disclosed in Seiji No. 2-128587, it is possible to more effectively prevent the edges from t''r warping during printing.
本発明に使用する前記除去可能な樹脂層あるいは不感脂
化液に用いる高分子としては次の親水性高分子化合物が
有効に使用できる。具体的な親木性高分子としては、例
えは天然高分子には、かんしょ澱粉、はれいしよ澱粉、
タピオカ澱粉、小麦澱粉及びコーンスターチ等の澱粉類
、カラシーチン、ラミナラン、海藻マンナン、ふのり、
アイリュッシュモス、寒天及びアルギン酸ナトリウム等
の藻類から得られるもの、トロロアオイ、マンナン、ク
インスシード、ペクチン、トラガカントガム、カラヤガ
ム、キサンチンガム、グアーピンガム、ローカストピン
カム、アラビアゴム、キャロブガム及びベンゾインカム
等の植物性粘質物、デキストラン、グルカン及びレバン
などのホモ多糖並びにサクシノグルカン及びサンタンガ
ムなどのへテロ多糖等の微生物の発酵などを利用して変
成した粘質物、にかわ、セラチン、カセチン及びコラー
ゲン等のタンパク質などか挙げられる。半天然物(半合
成品)であるアルキン酸プロピレングリコールエステル
の他に、ビスコース、メチルセルロース、エチルセルロ
ース、メチルエチルセルロース、カルボキシメチルセル
ロース、ヒドロキシプロピルセルロース、ヒドロキシプ
ロピルメチルセルロース、ヒドロキシプロピルエチルセ
ルロース及びヒドロキシプロピルメチルセルロースフタ
レート等の繊維素話導体並びに加工澱粉等かあげられる
。加工澱粉には白色デキストリン、黄色デキストリン及
びブリティッシュカムなどの焙焼澱粉、酵素デキストリ
ン及びシャーディンガーデキストリンなどの酵素変性デ
キストリン、可溶化澱粉に示される酸分解澱粉、ジアル
デヒドスターチに示される酸化澱粉、変性アルファ化澱
粉及び無変性アルファ化澱粉等のアルファ化澱粉、リン
酸澱粉、脂肪澱粉、硫酸澱粉、硝酸澱粉、キサントゲン
酸澱粉及びカルバミン酸澱粉などのエステル化澱粉、カ
ルボキシルアルキル澱粉、ヒドロキシアルキル澱粉、ス
ルフォアルキル澱粉、シアノエチル澱粉、アリル澱粉、
ヘンシル澱粉、カルバミルエチル澱粉及びジアルキルア
ミノ澱粉などのエーテル化澱粉、メチロール架橋澱粉、
ヒドロキシアルキル架橋澱粉、リン酸架橋澱粉及びジカ
ルホン酸架橋澱粉などの架橋澱粉、澱粉ポリアクリルア
ミド共重合体、澱粉ポリアクリル酸共重合体、澱粉ポリ
酢酸ビニル共重合体、澱粉ポリアクリロニトリル共重合
体、カチオン性澱粉ポリアクリル酸エステル共重合体、
カチオン性澱粉ビニルポリマー共重合体、澱粉ポリスチ
レンマレイン酸共重合体及び澱粉ポリエチレンオキサイ
ド共重合体などの澱粉グラフト共重合体などがあげられ
る。合成品にはポリビニルアルコールの他、部分アセタ
ール化ポリビニルアルコール、アリル変性ポリビニルア
ルコール、ポリビニルメチルエーテル、ポリビニルエチ
ルエーテル及びポリビニルイソブチルエーテルなどの変
性ポリビニルアルコール、ポリアクリル酸ナトリウム、
ポリアクリル酸エステル部分けん化物、ポリアクリル酸
エステル共重合体部分けん化物、ポリメタアクリル酸塩
及びポリアクリルアマイドなどのポリアクリル酸誘導体
およびポリメタクリル酸誘導体、ポリエチレングリコー
ル、ポリエチレンオキシド、ポリビニルピロリドン、ポ
リビニルピロリドン/ビニルアセテート共重合物、カル
ボキシビニルポリマー、スチロール/マレイン酸共重合
物、スチロール/クロトン酸共重合物等である。As the polymer used in the removable resin layer or desensitizing liquid used in the present invention, the following hydrophilic polymer compounds can be effectively used. Specific wood-loving polymers include, for example, natural polymers such as kansho starch, porphyry starch,
Starches such as tapioca starch, wheat starch and corn starch, chala citin, laminaran, seaweed mannan, funori,
Those obtained from algae, such as Irish moss, agar and sodium alginate; vegetable sources, such as yellow mallow, mannan, quince seed, pectin, gum tragacanth, gum karaya, xanthine gum, guarping gum, locust pinkum, gum arabic, carob gum and benzoincum; Mucilages, homopolysaccharides such as dextran, glucan, and levan, heteropolysaccharides such as succinoglucan and santhan gum, mucilages modified using microbial fermentation, glue, proteins such as seratin, cassetin, and collagen, etc. Can be mentioned. In addition to alkynoic acid propylene glycol ester, which is a semi-natural product (semi-synthetic product), viscose, methylcellulose, ethylcellulose, methylethylcellulose, carboxymethylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxypropylethylcellulose, hydroxypropylmethylcellulose phthalate, etc. Examples include fiber conductors and processed starches. Processed starches include roasted starches such as white dextrin, yellow dextrin, and British cam, enzyme-modified dextrins such as enzyme dextrin and Schardinger dextrin, acid-decomposed starches as shown in solubilized starch, oxidized starches as shown in dialdehyde starch, and modified starches. Pregelatinized starch such as pregelatinized starch and unmodified pregelatinized starch, esterified starch such as phosphate starch, fatty starch, sulfate starch, nitrate starch, xanthate starch and carbamate starch, carboxylalkyl starch, hydroxyalkyl starch, sulfur foralkyl starch, cyanoethyl starch, allyl starch,
Etherified starches such as Hensyl starch, carbamylethyl starch and dialkylamino starch, methylol cross-linked starches,
Crosslinked starch such as hydroxyalkyl crosslinked starch, phosphoric acid crosslinked starch and dicarphonic acid crosslinked starch, starch polyacrylamide copolymer, starch polyacrylic acid copolymer, starch polyvinyl acetate copolymer, starch polyacrylonitrile copolymer, cationic starch polyacrylate copolymer,
Examples include starch graft copolymers such as cationic starch vinyl polymer copolymers, starch polystyrene maleic acid copolymers, and starch polyethylene oxide copolymers. In addition to polyvinyl alcohol, synthetic products include partially acetalized polyvinyl alcohol, allyl-modified polyvinyl alcohol, modified polyvinyl alcohol such as polyvinyl methyl ether, polyvinylethyl ether, and polyvinyl isobutyl ether, sodium polyacrylate,
Partially saponified polyacrylic esters, partially saponified polyacrylic ester copolymers, polyacrylic acid derivatives and polymethacrylic acid derivatives such as polymethacrylates and polyacrylamides, polyethylene glycol, polyethylene oxide, polyvinylpyrrolidone, polyvinyl These include pyrrolidone/vinyl acetate copolymer, carboxyvinyl polymer, styrene/maleic acid copolymer, and styrene/crotonic acid copolymer.
本発明で使用する不感脂化液には、更に強酸の釦属塩を
含有させておくことが好ましく、これにとり不感脂化作
用を更に高めることができる。真木的な強酸の金属塩と
しては、硝酸、硫酸またはクロム酸等のナトリウム、カ
リウム、マグネシウム、カルシウム、または亜鉛等の塩
、フッ化ナトリウムおよびフッ化カリウム等を挙げるこ
とがで薫る。強酸の金属塩を用いる場合はp)11から
5、上り好ましくは2から465の範囲で使用するのが
仔ましい。It is preferable that the desensitizing liquid used in the present invention further contains a strong acid potassium salt, which can further enhance the desensitizing effect. Examples of metal salts of strong acids include salts of sodium, potassium, magnesium, calcium, or zinc such as nitric acid, sulfuric acid, or chromic acid, sodium fluoride, and potassium fluoride. When using a metal salt of a strong acid, it is recommended to use p) in the range of 11 to 5, preferably 2 to 465.
また前記強酸の金属塩に替えて、一般式+SiO2/n
M2O(M:アルカル金属原子、m/n −0,5〜1
.5)で表される珪酸塩を不感脂化液中に含有させでも
不感脂化作用を高めることができる。具体的シ珪酸塩と
しては珪酸ナトリウム、珪酸カリウム、珪酸リチウム等
を使用することができる。本発明で使用する珪酸塩は全
不惑脂化液中の約0.4重量%から約40重量%、好ま
しくは約0.8重量%う)ら約25重量%で使用するの
が好ましい。Also, instead of the metal salt of the strong acid, the general formula +SiO2/n
M2O (M: alkal metal atom, m/n -0,5~1
.. The desensitizing effect can also be enhanced by including the silicate represented by 5) in the desensitizing liquid. As specific silicates, sodium silicate, potassium silicate, lithium silicate, etc. can be used. The silicate used in the present invention is preferably used in an amount of about 0.4% to about 40% by weight, preferably about 0.8% to about 25% by weight, based on the total fat-fading liquid.
本発明に使用される不感脂化液に珪酸塩を用いる場合は
pH8から14、より好ましくは9から13の範囲で使
用するのが好ましい。本発明に使用される不感脂化液に
は必要に応じて界面活性剤、湿潤剤などの各種添加剤を
用いることができる。When a silicate is used in the desensitizing liquid used in the present invention, it is preferably used within a pH range of 8 to 14, more preferably 9 to 13. Various additives such as a surfactant and a wetting agent may be used in the desensitizing liquid used in the present invention, if necessary.
本発明に使用される不感脂化液は上述の如き親水性高分
子化合物の水溶液からなるものであるが1、例えば米国
特許第4,253,999号、同第4.268,613
号、同第4.348,954号等明細書に記載の乳化型
不感脂化液も使用することがてきる。不感脂化液の印刷
原版端面への塗布量は約50から150g/m2の範囲
が好ましい。The desensitizing liquid used in the present invention consists of an aqueous solution of a hydrophilic polymer compound as described above1, for example, U.S. Pat. No. 4,253,999 and U.S. Pat.
It is also possible to use the emulsified desensitizing liquids described in the specifications of No. 4,348,954 and the like. The amount of desensitizing liquid applied to the end surface of the original printing plate is preferably in the range of about 50 to 150 g/m<2>.
前記各種樹脂あるいは不感脂化液の印刷原版への塗布方
法としては例えは、刷毛、スポンジ、ローラなどで塗布
したり、スプレー塗布など従来より良く知られている方
法で行なえば良い。また塗布すべき端面は、印刷版の使
用形態により異なり、印刷版の一端面のみが印刷面とな
る場合にはその一端面のみ不感脂化液を塗布しておけは
良いが、種々の使用形態を想定して、好ましくは対向す
る二つの端面、最も好ましくは全外周端面(即ち、四辺
全端面)に塗布される。The various resins or desensitizing liquids may be applied to the printing original plate by, for example, a brush, a sponge, a roller, etc., or by a well-known method such as spray coating. The edge surface to be coated varies depending on the usage pattern of the printing plate. If only one end surface of the printing plate is to be printed, it is fine to apply the desensitizing liquid to only that end surface, but depending on the usage pattern Assuming that, the coating is preferably applied to two opposing end surfaces, most preferably to the entire outer circumferential end surface (that is, all four side end surfaces).
トナー画像形成後のトナー非画像部の光導電性絶縁層を
除去するエツチング液としては、光導電性絶縁層を除去
できるものなら任意の溶剤が使用可能であり、特に限定
されるものではないが、好ましくは、アルカリ性溶剤が
使用される。ここで言うアルカリ性溶剤とは、アルカリ
性化合物を含有する水溶液、アルカリ性化合物を含有す
る有機溶剤もしくは、アルカリ性化合物を含有する水溶
液と有機溶剤との混合物である。As the etching solution for removing the photoconductive insulating layer in the toner non-image area after the toner image is formed, any solvent can be used as long as it can remove the photoconductive insulating layer, and the etching solution is not particularly limited. , preferably alkaline solvents are used. The alkaline solvent referred to herein is an aqueous solution containing an alkaline compound, an organic solvent containing an alkaline compound, or a mixture of an aqueous solution containing an alkaline compound and an organic solvent.
アルカリ性化合物としては、水酸化ナトリウム、水酸化
カリウム、炭酸ナトリウム、ケイ酸ナトリウム、ケイ酸
カリウム、メタケイ酸ナトリウム、メタケイ酸カリウム
、リン酸ナトリウム、リン酸カリウム、アンモニア、お
よびモノエタノールアミン、ジェタノールアミン、トリ
エタノールアミン等のアミノアルコール類等の有機およ
び無機の任意のアルカリ性の化合物を挙げることが出来
る。エツチング液の溶媒としては前述のように、水もし
くは多くの有機溶剤を使用することが出来るが、臭気、
公害性の点から水を主体としたエツチング液か好ましく
使用される。Alkaline compounds include sodium hydroxide, potassium hydroxide, sodium carbonate, sodium silicate, potassium silicate, sodium metasilicate, potassium metasilicate, sodium phosphate, potassium phosphate, ammonia, and monoethanolamine and jetanolamine. , amino alcohols such as triethanolamine, and any organic and inorganic alkaline compounds. As mentioned above, water or many organic solvents can be used as the solvent for the etching solution;
From the viewpoint of pollution, an etching solution mainly containing water is preferably used.
また、エツチング液には必要に応じて界面活性剤、消泡
剤、その他各種の添加剤を含有したものが使用される。Further, the etching liquid may contain a surfactant, an antifoaming agent, and various other additives as required.
(発明の効果)
本発明の電子写真式平版印刷版の製造方法および装置に
よれば、トナー現像後の定着工程において印刷原版端部
のトナー汚れ部分の定着を簡単な方法で抑止することに
より次のエツチング工程でトナー汚れは容易に除去する
ことかでき、機械的な除去手段を用いて除去する必要を
なくした。(Effects of the Invention) According to the method and apparatus for manufacturing an electrophotographic lithographic printing plate of the present invention, in the fixing step after toner development, fixation of toner-stained portions at the edges of printing original plates can be prevented by a simple method, thereby achieving the following: Toner stains can be easily removed during the etching process, eliminating the need for mechanical removal means.
第1図(A)および(B)は本発明の一実施例を示す平
面図および側面図、第2図(八)および(B)乃至第5
図(A)および(B)は本発明の他の実施例を示す平面
図および側面図、第6図は本発明を用いた多面付は製版
の例である。
1・・・赤外線ラインヒータ、2・・・遮蔽板、3・・
・電子写真式平版印刷原版、4・・・印刷原版端部、5
・・・定着部、6・・・反射板、7・・・赤外線、8・
−・フラッシュランプ、9・・・フラッシュ光、10.
11・・・圧力ローラ、12・・・赤外線ラインヒータ
、13・・・反射板、14・・・赤外線、15・・・ア
ルミニウム箔送り出しローラ、16・・・アルミニウム
箔押えローラ、17・・・アルミニウム箔巻き取りロー
ラ、18・・・アルミニウム箔、19・・・冷風吹き出
し孔、20・・・冷風。
出願人代理人 安 形 雄 三
ぐコ
骨20
/l−311]FIGS. 1(A) and (B) are a plan view and a side view showing one embodiment of the present invention, and FIGS. 2(8) and (B) to 5
Figures (A) and (B) are a plan view and a side view showing another embodiment of the present invention, and Fig. 6 is an example of plate making for multi-sided printing using the present invention. 1... Infrared line heater, 2... Shielding plate, 3...
・Electrophotographic lithographic printing original plate, 4...Printing original plate edge, 5
...Fixing section, 6.Reflector, 7.Infrared rays, 8.
-・Flash lamp, 9...Flash light, 10.
DESCRIPTION OF SYMBOLS 11... Pressure roller, 12... Infrared line heater, 13... Reflector, 14... Infrared rays, 15... Aluminum foil delivery roller, 16... Aluminum foil pressing roller, 17... Aluminum foil winding roller, 18... Aluminum foil, 19... Cold air outlet, 20... Cold air. Applicant's agent Yu Yasugata Migukotsu 20/l-311]
Claims (1)
版印刷原版に対して少なくとも帯電する帯電工程と、露
光する露光工程と、トナーを用いて現像する現像工程と
、定着する定着工程と、トナー画像以外の前記光導電層
を除去するエッチング工程とにより電子写真式平版印刷
版を製造する方法において、前記電子写真式平版印刷原
版の所要部分のトナーを定着するようにしたことを特徴
とする電子写真式平版印刷版の製造方法。 2、少なくとも前記帯電工程と、前記露光工程と、前記
定着工程と、前記エッチング工程とを含む前記電子写真
式平版印刷版の製造装置において、定着部内に印刷原版
端部の定着を抑止する手段を設けたことを特徴とする電
子写真式平版印刷版の製造装置。[Scope of Claims] 1. A charging step of at least charging an electrophotographic lithographic printing original plate having a photoconductive layer layered on a conductive substrate, an exposure step of exposing it to light, and a development step of developing with toner. A method for manufacturing an electrophotographic lithographic printing plate by a step of fixing the toner image, a fixing step of fixing the toner image, and an etching step of removing the photoconductive layer other than the toner image. A method for producing an electrophotographic lithographic printing plate, characterized in that: 2. In the electrophotographic planographic printing plate manufacturing apparatus including at least the charging step, the exposure step, the fixing step, and the etching step, a means for suppressing fixing of the edge of the printing original plate is provided in the fixing section. An apparatus for manufacturing an electrophotographic lithographic printing plate, characterized in that:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33577890A JPH04204667A (en) | 1990-11-30 | 1990-11-30 | Production of electrophotograph planographic printing plate and producing device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33577890A JPH04204667A (en) | 1990-11-30 | 1990-11-30 | Production of electrophotograph planographic printing plate and producing device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04204667A true JPH04204667A (en) | 1992-07-27 |
Family
ID=18292344
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP33577890A Pending JPH04204667A (en) | 1990-11-30 | 1990-11-30 | Production of electrophotograph planographic printing plate and producing device |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04204667A (en) |
-
1990
- 1990-11-30 JP JP33577890A patent/JPH04204667A/en active Pending
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