JPH0420535A - ポリクロロプレンの加硫方法 - Google Patents
ポリクロロプレンの加硫方法Info
- Publication number
- JPH0420535A JPH0420535A JP2411696A JP41169690A JPH0420535A JP H0420535 A JPH0420535 A JP H0420535A JP 2411696 A JP2411696 A JP 2411696A JP 41169690 A JP41169690 A JP 41169690A JP H0420535 A JPH0420535 A JP H0420535A
- Authority
- JP
- Japan
- Prior art keywords
- polychloroprene
- vulcanization
- minutes
- sulfur
- amidine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920001084 poly(chloroprene) Polymers 0.000 title claims abstract description 38
- 238000004073 vulcanization Methods 0.000 title claims abstract description 33
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 19
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 18
- -1 amidine compound Chemical class 0.000 claims description 30
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 24
- 238000000034 method Methods 0.000 claims description 16
- 239000000395 magnesium oxide Substances 0.000 claims description 14
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 9
- 239000000178 monomer Substances 0.000 abstract description 11
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 abstract description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 9
- 230000032683 aging Effects 0.000 abstract description 8
- 229910052717 sulfur Inorganic materials 0.000 abstract description 8
- 239000011593 sulfur Substances 0.000 abstract description 8
- 150000001409 amidines Chemical class 0.000 abstract description 7
- 230000006866 deterioration Effects 0.000 abstract description 3
- 230000009477 glass transition Effects 0.000 abstract description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 14
- 239000000203 mixture Substances 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 10
- 238000002156 mixing Methods 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 238000004132 cross linking Methods 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 229920001971 elastomer Polymers 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 7
- 239000011787 zinc oxide Substances 0.000 description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 239000006229 carbon black Substances 0.000 description 6
- 239000004816 latex Substances 0.000 description 6
- 229920000126 latex Polymers 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 125000003710 aryl alkyl group Chemical group 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- PCPYTNCQOSFKGG-ONEGZZNKSA-N (1e)-1-chlorobuta-1,3-diene Chemical compound Cl\C=C\C=C PCPYTNCQOSFKGG-ONEGZZNKSA-N 0.000 description 3
- GQHTUMJGOHRCHB-UHFFFAOYSA-N 2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine Chemical compound C1CCCCN2CCCN=C21 GQHTUMJGOHRCHB-UHFFFAOYSA-N 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 125000000753 cycloalkyl group Chemical group 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 125000000623 heterocyclic group Chemical group 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010077 mastication Methods 0.000 description 2
- 230000018984 mastication Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229950000688 phenothiazine Drugs 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 2
- 125000004434 sulfur atom Chemical group 0.000 description 2
- 238000005987 sulfurization reaction Methods 0.000 description 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 1
- OTPDWCMLUKMQNO-UHFFFAOYSA-N 1,2,3,4-tetrahydropyrimidine Chemical compound C1NCC=CN1 OTPDWCMLUKMQNO-UHFFFAOYSA-N 0.000 description 1
- SGUVLZREKBPKCE-UHFFFAOYSA-N 1,5-diazabicyclo[4.3.0]-non-5-ene Chemical compound C1CCN=C2CCCN21 SGUVLZREKBPKCE-UHFFFAOYSA-N 0.000 description 1
- LIFLRQVHKGGNSG-UHFFFAOYSA-N 2,3-dichlorobuta-1,3-diene Chemical compound ClC(=C)C(Cl)=C LIFLRQVHKGGNSG-UHFFFAOYSA-N 0.000 description 1
- CMBVSYQSELVHQA-UHFFFAOYSA-N 2-benzyl-1,2,3,4-tetrahydropyrimidine Chemical compound C=1C=CC=CC=1CC1NCC=CN1 CMBVSYQSELVHQA-UHFFFAOYSA-N 0.000 description 1
- GVPLALUKJMMFAU-UHFFFAOYSA-N 2-ethyl-1,2,3,4-tetrahydropyrimidine Chemical compound CCC1NCC=CN1 GVPLALUKJMMFAU-UHFFFAOYSA-N 0.000 description 1
- GKUYEWXKJWAGHB-UHFFFAOYSA-N 2-ethyl-4-methyl-1,2,3,4-tetrahydropyrimidine Chemical compound CCC1NC=CC(C)N1 GKUYEWXKJWAGHB-UHFFFAOYSA-N 0.000 description 1
- FEJIGNDKURQIRD-UHFFFAOYSA-N 2-methyl-1,2,3,4-tetrahydropyrimidine Chemical compound CC1NCC=CN1 FEJIGNDKURQIRD-UHFFFAOYSA-N 0.000 description 1
- HALGJUKFQIYBHW-UHFFFAOYSA-N 2-phenyl-1,2,3,4-tetrahydropyrimidine Chemical compound N1C=CCNC1C1=CC=CC=C1 HALGJUKFQIYBHW-UHFFFAOYSA-N 0.000 description 1
- FKBYRLPRGMWTIO-UHFFFAOYSA-N 3-benzyliminoazepan-2-one Chemical compound O=C1NCCCCC1=NCC1=CC=CC=C1 FKBYRLPRGMWTIO-UHFFFAOYSA-N 0.000 description 1
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 description 1
- TXLINXBIWJYFNR-UHFFFAOYSA-N 4-phenylpyridine-2-carbonitrile Chemical compound C1=NC(C#N)=CC(C=2C=CC=CC=2)=C1 TXLINXBIWJYFNR-UHFFFAOYSA-N 0.000 description 1
- UFTVMBIIDZCELM-UHFFFAOYSA-N 5-phenylnaphthalen-2-amine Chemical compound C=1C=CC2=CC(N)=CC=C2C=1C1=CC=CC=C1 UFTVMBIIDZCELM-UHFFFAOYSA-N 0.000 description 1
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 description 1
- OQLZINXFSUDMHM-UHFFFAOYSA-N Acetamidine Chemical compound CC(N)=N OQLZINXFSUDMHM-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004604 Blowing Agent Substances 0.000 description 1
- MDJCRRPBYLOXJB-UHFFFAOYSA-N CC(C)(C)N=C1CCCCNC1=O Chemical compound CC(C)(C)N=C1CCCCNC1=O MDJCRRPBYLOXJB-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920001174 Diethylhydroxylamine Polymers 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- PNKUSGQVOMIXLU-UHFFFAOYSA-N Formamidine Chemical compound NC=N PNKUSGQVOMIXLU-UHFFFAOYSA-N 0.000 description 1
- KEQFTVQCIQJIQW-UHFFFAOYSA-N N-Phenyl-2-naphthylamine Chemical compound C=1C=C2C=CC=CC2=CC=1NC1=CC=CC=C1 KEQFTVQCIQJIQW-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 206010063493 Premature ageing Diseases 0.000 description 1
- 208000032038 Premature aging Diseases 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- ALYHFNJJTGKTOG-UHFFFAOYSA-L [O-]OOO[O-].[Mg+2] Chemical compound [O-]OOO[O-].[Mg+2] ALYHFNJJTGKTOG-UHFFFAOYSA-L 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 125000000732 arylene group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- PXXJHWLDUBFPOL-UHFFFAOYSA-N benzamidine Chemical compound NC(=N)C1=CC=CC=C1 PXXJHWLDUBFPOL-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical compound CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 description 1
- 150000002019 disulfides Chemical class 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 150000002681 magnesium compounds Chemical class 0.000 description 1
- ADKOXSOCTOWDOP-UHFFFAOYSA-L magnesium;aluminum;dihydroxide;trihydrate Chemical compound O.O.O.[OH-].[OH-].[Mg+2].[Al] ADKOXSOCTOWDOP-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- SUKZACKQRJZHMT-UHFFFAOYSA-N n'-benzyl-n-ethylbenzenecarboximidamide Chemical compound C=1C=CC=CC=1C(NCC)=NCC1=CC=CC=C1 SUKZACKQRJZHMT-UHFFFAOYSA-N 0.000 description 1
- RIWDLLQJDJLJOW-UHFFFAOYSA-N n'-benzyl-n-tert-butylethanimidamide Chemical compound CC(C)(C)NC(C)=NCC1=CC=CC=C1 RIWDLLQJDJLJOW-UHFFFAOYSA-N 0.000 description 1
- PANBFSGJYKYTNM-UHFFFAOYSA-N n'-phenylethanimidamide Chemical compound CC(N)=NC1=CC=CC=C1 PANBFSGJYKYTNM-UHFFFAOYSA-N 0.000 description 1
- XWRSLEPCXIKCJG-UHFFFAOYSA-N n,n-dibutylbenzenecarboximidamide Chemical compound CCCCN(CCCC)C(=N)C1=CC=CC=C1 XWRSLEPCXIKCJG-UHFFFAOYSA-N 0.000 description 1
- LNIGFYSAOIMZNA-UHFFFAOYSA-N n,n-dimethylbenzenecarboximidamide Chemical compound CN(C)C(=N)C1=CC=CC=C1 LNIGFYSAOIMZNA-UHFFFAOYSA-N 0.000 description 1
- DXFZMBRFLWIORG-UHFFFAOYSA-N n,n-diphenylethanimidamide Chemical compound C=1C=CC=CC=1N(C(=N)C)C1=CC=CC=C1 DXFZMBRFLWIORG-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- HUMLQUKVJARKRN-UHFFFAOYSA-M sodium;n,n-dibutylcarbamodithioate Chemical compound [Na+].CCCCN(C([S-])=S)CCCC HUMLQUKVJARKRN-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 150000005326 tetrahydropyrimidines Chemical class 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- VRXCFPOQRATGDM-UHFFFAOYSA-N zinc ethene oxygen(2-) thiourea Chemical compound NC(=S)N.C=C.[O-2].[Zn+2] VRXCFPOQRATGDM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3942463.4 | 1989-12-22 | ||
| DE3942463A DE3942463A1 (de) | 1989-12-22 | 1989-12-22 | Verfahren zur vulkanisation von polychloropren |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0420535A true JPH0420535A (ja) | 1992-01-24 |
Family
ID=6396129
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2411696A Pending JPH0420535A (ja) | 1989-12-22 | 1990-12-19 | ポリクロロプレンの加硫方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US5210152A (de) |
| EP (1) | EP0433808A3 (de) |
| JP (1) | JPH0420535A (de) |
| CA (1) | CA2032860A1 (de) |
| DE (1) | DE3942463A1 (de) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001261889A (ja) * | 2000-03-15 | 2001-09-26 | Denki Kagaku Kogyo Kk | クロロプレン系ゴム組成物 |
| JP2002338746A (ja) * | 2001-05-22 | 2002-11-27 | Denki Kagaku Kogyo Kk | ラテックス組成物 |
| JP2007217668A (ja) * | 2006-01-14 | 2007-08-30 | Bayer Materialscience Ag | 水性分散液 |
| JP2009197127A (ja) * | 2008-02-21 | 2009-09-03 | Denki Kagaku Kogyo Kk | クロロプレンゴム組成物及び該クロロプレン組成物からなるクロロプレンゴム成形体。 |
| WO2013076989A1 (ja) * | 2011-11-22 | 2013-05-30 | 株式会社ブリヂストン | ホース用ゴム組成物及びホース |
| JP2013129684A (ja) * | 2011-11-22 | 2013-07-04 | Bridgestone Corp | ホース用ゴム組成物及びホース |
| JP2013129683A (ja) * | 2011-11-22 | 2013-07-04 | Bridgestone Corp | ホース用ゴム組成物及びホース |
| JP2023527888A (ja) * | 2020-06-02 | 2023-06-30 | アランセオ・ドイチュランド・ゲーエムベーハー | ニトロソアミンフリーの硫黄変性ポリクロロプレン加硫物を形成するための加硫性組成物 |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5406764A (en) * | 1991-01-03 | 1995-04-18 | Van Auken; Richard H. | Mesh roof facing system |
| US5549832A (en) | 1994-12-22 | 1996-08-27 | Century Manufacturing Company | Vehicle coolant recycling |
| DE19618571A1 (de) * | 1996-05-09 | 1997-11-13 | Bayer Ag | Polymercompounds und ihre Verwendung für die Vulkanisation halogenhaltiger Kautschuke |
| JP2001139728A (ja) | 1999-11-17 | 2001-05-22 | Bridgestone Corp | ゴム組成物 |
| TW584650B (en) * | 2001-04-20 | 2004-04-21 | Denki Kagaku Kogyo Kk | Latex composition |
| US20110207891A1 (en) * | 2010-01-29 | 2011-08-25 | Parent J Scott | Delayed Curing of Halogenated Elastomers |
| EP3184559A1 (de) * | 2015-12-23 | 2017-06-28 | ARLANXEO Deutschland GmbH | Bei niedriger temperatur vernetzbare polychloroprenzusammensetzungen |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2943078A (en) * | 1957-02-26 | 1960-06-28 | Vanderbilt Co R T | Chloroprene polymers containing a thio pyrimidine accelerator |
-
1989
- 1989-12-22 DE DE3942463A patent/DE3942463A1/de not_active Withdrawn
-
1990
- 1990-12-08 EP EP19900123610 patent/EP0433808A3/de not_active Withdrawn
- 1990-12-10 US US07/624,967 patent/US5210152A/en not_active Expired - Fee Related
- 1990-12-19 JP JP2411696A patent/JPH0420535A/ja active Pending
- 1990-12-20 CA CA002032860A patent/CA2032860A1/en not_active Abandoned
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001261889A (ja) * | 2000-03-15 | 2001-09-26 | Denki Kagaku Kogyo Kk | クロロプレン系ゴム組成物 |
| JP2002338746A (ja) * | 2001-05-22 | 2002-11-27 | Denki Kagaku Kogyo Kk | ラテックス組成物 |
| JP2007217668A (ja) * | 2006-01-14 | 2007-08-30 | Bayer Materialscience Ag | 水性分散液 |
| JP2009197127A (ja) * | 2008-02-21 | 2009-09-03 | Denki Kagaku Kogyo Kk | クロロプレンゴム組成物及び該クロロプレン組成物からなるクロロプレンゴム成形体。 |
| WO2013076989A1 (ja) * | 2011-11-22 | 2013-05-30 | 株式会社ブリヂストン | ホース用ゴム組成物及びホース |
| JP2013129684A (ja) * | 2011-11-22 | 2013-07-04 | Bridgestone Corp | ホース用ゴム組成物及びホース |
| JP2013129683A (ja) * | 2011-11-22 | 2013-07-04 | Bridgestone Corp | ホース用ゴム組成物及びホース |
| JP2023527888A (ja) * | 2020-06-02 | 2023-06-30 | アランセオ・ドイチュランド・ゲーエムベーハー | ニトロソアミンフリーの硫黄変性ポリクロロプレン加硫物を形成するための加硫性組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0433808A3 (en) | 1991-12-11 |
| EP0433808A2 (de) | 1991-06-26 |
| DE3942463A1 (de) | 1991-06-27 |
| US5210152A (en) | 1993-05-11 |
| CA2032860A1 (en) | 1991-06-23 |
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