JPH05504226A - 再充電可能な電池の二酸化マンガン陰極及び同陰極を含む電池 - Google Patents

再充電可能な電池の二酸化マンガン陰極及び同陰極を含む電池

Info

Publication number: JPH05504226A
Authority: JP; Japan
Prior art keywords: cathode; rechargeable; electrochemical cell; battery; anode
Prior art date: 1990-02-15
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP2514684A

Other languages

English (en)

Japanese (ja)

Inventor

トマンチュガー、クラウス

ミカロウスキー、クリストファー

Original Assignee

バッテリー・テクノロジーズ・インコーポレーテッド

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-02-15

Filing date

1990-11-02

Publication date

1993-07-01

1990-11-02 Application filed by バッテリー・テクノロジーズ・インコーポレーテッド filed Critical バッテリー・テクノロジーズ・インコーポレーテッド

1993-07-01 Publication of JPH05504226A publication Critical patent/JPH05504226A/ja

Status Pending legal-status Critical Current

Links

NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 title claims description 96
239000000835 fiber Substances 0.000 claims description 71
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 58
239000000203 mixture Substances 0.000 claims description 55
239000003792 electrolyte Substances 0.000 claims description 48
239000010439 graphite Substances 0.000 claims description 46
229910002804 graphite Inorganic materials 0.000 claims description 46
238000009472 formulation Methods 0.000 claims description 41
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 38
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 37
239000011701 zinc Substances 0.000 claims description 37
229910052725 zinc Inorganic materials 0.000 claims description 34
239000000654 additive Substances 0.000 claims description 26
229920000049 Carbon (fiber) Polymers 0.000 claims description 25
239000004917 carbon fiber Substances 0.000 claims description 24
239000011787 zinc oxide Substances 0.000 claims description 19
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 17
239000010949 copper Substances 0.000 claims description 17
229910052802 copper Inorganic materials 0.000 claims description 17
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 14
238000000034 method Methods 0.000 claims description 14
230000000996 additive effect Effects 0.000 claims description 13
229910052751 metal Inorganic materials 0.000 claims description 13
239000002184 metal Substances 0.000 claims description 13
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
229910052799 carbon Inorganic materials 0.000 claims description 12
239000008188 pellet Substances 0.000 claims description 11
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 11
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 10
229910052753 mercury Inorganic materials 0.000 claims description 10
239000000463 material Substances 0.000 claims description 8
229910052793 cadmium Inorganic materials 0.000 claims description 7
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 7
239000007789 gas Substances 0.000 claims description 7
229910052797 bismuth Inorganic materials 0.000 claims description 6
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 6
229910052739 hydrogen Inorganic materials 0.000 claims description 6
239000001257 hydrogen Substances 0.000 claims description 6
229910052742 iron Inorganic materials 0.000 claims description 6
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 5
229910052744 lithium Inorganic materials 0.000 claims description 5
230000002093 peripheral effect Effects 0.000 claims description 4
238000012216 screening Methods 0.000 claims description 4
239000000126 substance Substances 0.000 claims description 4
238000002156 mixing Methods 0.000 claims description 3
239000006229 carbon black Substances 0.000 claims description 2
239000003292 glue Substances 0.000 claims description 2
238000009434 installation Methods 0.000 claims description 2
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical group [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims 22
230000002452 interceptive effect Effects 0.000 claims 5
229910052782 aluminium Inorganic materials 0.000 claims 4
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 4
125000004435 hydrogen atom Chemical class [H]* 0.000 claims 4
229940072033 potash Drugs 0.000 claims 4
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims 4
235000015320 potassium carbonate Nutrition 0.000 claims 4
239000003513 alkali Substances 0.000 claims 2
240000002834 Paulownia tomentosa Species 0.000 claims 1
239000002253 acid Substances 0.000 claims 1
239000003610 charcoal Substances 0.000 claims 1
238000007789 sealing Methods 0.000 claims 1
208000028659 discharge Diseases 0.000 description 38
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 11
239000011230 binding agent Substances 0.000 description 11
238000012360 testing method Methods 0.000 description 10
238000007792 addition Methods 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 8
239000011572 manganese Substances 0.000 description 7
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 5
229910052759 nickel Inorganic materials 0.000 description 5
229910052709 silver Inorganic materials 0.000 description 5
239000004332 silver Substances 0.000 description 5
NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 5
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
238000013459 approach Methods 0.000 description 4
239000004568 cement Substances 0.000 description 4
230000008859 change Effects 0.000 description 4
230000007797 corrosion Effects 0.000 description 4
238000005260 corrosion Methods 0.000 description 4
238000007599 discharging Methods 0.000 description 4
239000003349 gelling agent Substances 0.000 description 4
AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 4
229910000831 Steel Inorganic materials 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
230000001351 cycling effect Effects 0.000 description 3
230000006378 damage Effects 0.000 description 3
230000000694 effects Effects 0.000 description 3
239000010410 layer Substances 0.000 description 3
230000005012 migration Effects 0.000 description 3
238000013508 migration Methods 0.000 description 3
239000002245 particle Substances 0.000 description 3
239000010959 steel Substances 0.000 description 3
239000011800 void material Substances 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 2
239000004480 active ingredient Substances 0.000 description 2
230000000903 blocking effect Effects 0.000 description 2
229910002092 carbon dioxide Inorganic materials 0.000 description 2
239000001569 carbon dioxide Substances 0.000 description 2
239000003575 carbonaceous material Substances 0.000 description 2
230000015556 catabolic process Effects 0.000 description 2
238000000354 decomposition reaction Methods 0.000 description 2
238000006731 degradation reaction Methods 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
239000003112 inhibitor Substances 0.000 description 2
230000002427 irreversible effect Effects 0.000 description 2
WJZHMLNIAZSFDO-UHFFFAOYSA-N manganese zinc Chemical compound [Mn].[Zn] WJZHMLNIAZSFDO-UHFFFAOYSA-N 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
230000007246 mechanism Effects 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
230000035515 penetration Effects 0.000 description 2
238000007747 plating Methods 0.000 description 2
238000003860 storage Methods 0.000 description 2
238000012546 transfer Methods 0.000 description 2
229940007718 zinc hydroxide Drugs 0.000 description 2
229910021511 zinc hydroxide Inorganic materials 0.000 description 2
SZKTYYIADWRVSA-UHFFFAOYSA-N zinc manganese(2+) oxygen(2-) Chemical compound [O--].[O--].[Mn++].[Zn++] SZKTYYIADWRVSA-UHFFFAOYSA-N 0.000 description 2
229910001369 Brass Inorganic materials 0.000 description 1
229910000906 Bronze Inorganic materials 0.000 description 1
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical class [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
206010011878 Deafness Diseases 0.000 description 1
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 1
229910018654 Mn Ox Inorganic materials 0.000 description 1
229910003174 MnOOH Inorganic materials 0.000 description 1
229910016978 MnOx Inorganic materials 0.000 description 1
-1 Zincate ion Chemical class 0.000 description 1
238000009825 accumulation Methods 0.000 description 1
239000012670 alkaline solution Substances 0.000 description 1
238000005267 amalgamation Methods 0.000 description 1
229940069428 antacid Drugs 0.000 description 1
239000003159 antacid agent Substances 0.000 description 1
230000001458 anti-acid effect Effects 0.000 description 1
239000010951 brass Substances 0.000 description 1
239000010974 bronze Substances 0.000 description 1
OJIJEKBXJYRIBZ-UHFFFAOYSA-N cadmium nickel Chemical compound [Ni].[Cd] OJIJEKBXJYRIBZ-UHFFFAOYSA-N 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000002482 conductive additive Substances 0.000 description 1
230000008602 contraction Effects 0.000 description 1
KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
238000005336 cracking Methods 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
238000013016 damping Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000007547 defect Effects 0.000 description 1
230000005611 electricity Effects 0.000 description 1
238000005868 electrolysis reaction Methods 0.000 description 1
229910052733 gallium Inorganic materials 0.000 description 1
229910052738 indium Inorganic materials 0.000 description 1
APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000004816 latex Substances 0.000 description 1
229920000126 latex Polymers 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
IPJKJLXEVHOKSE-UHFFFAOYSA-L manganese dihydroxide Chemical compound [OH-].[OH-].[Mn+2] IPJKJLXEVHOKSE-UHFFFAOYSA-L 0.000 description 1
229910001437 manganese ion Inorganic materials 0.000 description 1
239000007769 metal material Substances 0.000 description 1
238000003801 milling Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
239000011255 nonaqueous electrolyte Substances 0.000 description 1
238000002161 passivation Methods 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
231100000572 poisoning Toxicity 0.000 description 1
230000000607 poisoning effect Effects 0.000 description 1
229920002492 poly(sulfone) Polymers 0.000 description 1
239000004810 polytetrafluoroethylene Substances 0.000 description 1
229920001343 polytetrafluoroethylene Polymers 0.000 description 1
239000011148 porous material Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
230000008569 process Effects 0.000 description 1
230000009467 reduction Effects 0.000 description 1
230000002787 reinforcement Effects 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000002356 single layer Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
230000003068 static effect Effects 0.000 description 1
239000004753 textile Substances 0.000 description 1
229910052716 thallium Inorganic materials 0.000 description 1
BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
210000002268 wool Anatomy 0.000 description 1
UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
VDNOULUYFBNMFR-UHFFFAOYSA-J zinc manganese(2+) tetrachloride Chemical compound [Mn+2].[Cl-].[Zn+2].[Cl-].[Cl-].[Cl-] VDNOULUYFBNMFR-UHFFFAOYSA-J 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies

Landscapes

Battery Electrode And Active Subsutance (AREA)
Supercharger (AREA)
Exhaust-Gas Circulating Devices (AREA)
Output Control And Ontrol Of Special Type Engine (AREA)

JP2514684A 1990-02-15 1990-11-02 再充電可能な電池の二酸化マンガン陰極及び同陰極を含む電池 Pending JPH05504226A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
CA010,142		1990-02-15
CA002010142A CA2010142C (fr)	1990-02-15	1990-02-15	Cathode en dioxyde de manganese pour une pile alcaline rechargeable et pile renfermant cette cathode

Publications (1)

Publication Number	Publication Date
JPH05504226A true JPH05504226A (ja)	1993-07-01

Family

ID=4144306

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP2514684A Pending JPH05504226A (ja)	1990-02-15	1990-11-02	再充電可能な電池の二酸化マンガン陰極及び同陰極を含む電池

Country Status (4)

Country	Link
JP (1)	JPH05504226A (fr)
CA (1)	CA2010142C (fr)
DE (1)	DE69029866T2 (fr)
HU (1)	HUT69279A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2016520969A (ja) *	2014-04-03	2016-07-14	グラジュエートスクールアットシェンチェン、ツィングワユニバーシティー	亜鉛イオン二次電池及びその製造方法

1990
- 1990-02-15 CA CA002010142A patent/CA2010142C/fr not_active Expired - Lifetime
- 1990-11-02 JP JP2514684A patent/JPH05504226A/ja active Pending
- 1990-11-02 DE DE69029866T patent/DE69029866T2/de not_active Expired - Fee Related
- 1990-11-02 HU HU9202646A patent/HUT69279A/hu unknown

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2016520969A (ja) *	2014-04-03	2016-07-14	グラジュエートスクールアットシェンチェン、ツィングワユニバーシティー	亜鉛イオン二次電池及びその製造方法

Also Published As

Publication number	Publication date
DE69029866D1 (de)	1997-03-13
CA2010142C (fr)	1997-02-04
DE69029866T2 (de)	1997-09-18
HUT69279A (en)	1995-09-28
CA2010142A1 (fr)	1991-08-15

Publication	Publication Date	Title
US5108852A (en)	1992-04-28	Manganese dioxide cathode for a rechargeable alkaline cell, and cell containing the same
EP0695465B1 (fr)	2000-01-05	Piles rechargeables zinc-dioxyde de manganese
CA1099334A (fr)	1981-04-14	Pile alcaline rechargeable, au zinc - mn0.sub.2
US5340666A (en)	1994-08-23	Rechargeable alkaline manganese cell having improved capacity and improved energy density
CA1310362C (fr)	1992-11-17	Cellule electrochimique rechargeable a electrolyte alkakin et cathode zinc-dioxyde de manganese, a capacite amelioree
EP1632003A2 (fr)	2006-03-08	Accumulateur utilisant un batonnet electrode qui contient une electrode interieure incorporee
EP0617845B1 (fr)	1996-02-07	Cathodes destinees aux cellules dioxyde de manganese-zinc comportant des additifs a base de barium
US7754386B2 (en)	2010-07-13	Rechargeable alkaline manganese cell having reduced capacity fade and improved cycle life
US20100062347A1 (en)	2010-03-11	Rechargeable zinc cell with longitudinally-folded separator
US3288642A (en)	1966-11-29	Rechargeable dry cell having gelled electrolyte
US3671319A (en)	1972-06-20	Battery electrode and battery embodying same
JPH05504226A (ja)	1993-07-01	再充電可能な電池の二酸化マンガン陰極及び同陰極を含む電池
EP0520990B1 (fr)	1997-01-29	Cathode en bioxyde de manganese pour piles rechargeables et piles contenant cette cathode
US6399245B1 (en)	2002-06-04	Electrochemical cell with an anode containing sulfur
US6740449B2 (en)	2004-05-25	Nickel electrode for alkaline storage battery and method of manufacturing the same
JP2008532256A (ja)	2008-08-14	電池
WO1993018557A1 (fr)	1993-09-16	Batterie rechargeable a haute capacite ayant une electrode en bioxyde de manganese
JP2001216947A (ja)	2001-08-10	有機溶媒電池

JPH05504226A - 再充電可能な電池の二酸化マンガン陰極及び同陰極を含む電池 - Google Patents

Info

Links

Classifications

Landscapes

Applications Claiming Priority (2)

Publications (1)

Family

ID=4144306

Family Applications (1)

Country Status (4)

Cited By (1)

Cited By (1)

Also Published As

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