JPH0576998B2 - - Google Patents

Info

Publication number
JPH0576998B2
JPH0576998B2 JP61034124A JP3412486A JPH0576998B2 JP H0576998 B2 JPH0576998 B2 JP H0576998B2 JP 61034124 A JP61034124 A JP 61034124A JP 3412486 A JP3412486 A JP 3412486A JP H0576998 B2 JPH0576998 B2 JP H0576998B2
Authority
JP
Japan
Prior art keywords
oil
rolling
salts
aluminum
component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP61034124A
Other languages
English (en)
Other versions
JPS62192496A (ja
Inventor
Masaru Akao
Yoshio Okamoto
Akio Manba
Takehiko Ichimoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Corp
Kobe Steel Ltd
Original Assignee
Kao Corp
Kobe Steel Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corp, Kobe Steel Ltd filed Critical Kao Corp
Priority to JP61034124A priority Critical patent/JPS62192496A/ja
Priority to KR1019870000963A priority patent/KR940011836B1/ko
Priority to EP87101936A priority patent/EP0233588B1/en
Priority to CA000529618A priority patent/CA1281708C/en
Priority to DE8787101936T priority patent/DE3764970D1/de
Priority to ES87101936T priority patent/ES2017943B3/es
Priority to US07/014,592 priority patent/US4800034A/en
Publication of JPS62192496A publication Critical patent/JPS62192496A/ja
Publication of JPH0576998B2 publication Critical patent/JPH0576998B2/ja
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21B—ROLLING OF METAL
    • B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
    • B21B45/02—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
    • B21B45/0239—Lubricating
    • B21B45/0242—Lubricants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
    • C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/38—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
    • C10M129/40—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
    • C10M129/56—Acids of unknown or incompletely defined constitution
    • C10M129/60—Tall oil acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/68—Esters
    • C10M129/70—Esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/68—Esters
    • C10M129/76—Esters containing free hydroxy or carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
    • C10M149/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
    • C10M149/12—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M149/14—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds a condensation reaction being involved
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M149/00—Lubricating compositions characterised by the additive being a macromolecular compound containing nitrogen
    • C10M149/12—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M149/14—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds a condensation reaction being involved
    • C10M149/16—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds a condensation reaction being involved between the nitrogen-containing monomer and an aldehyde or ketone
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21B—ROLLING OF METAL
    • B21B3/00—Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
    • B21B2003/001—Aluminium or its alloys
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/18—Tall oil acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/22—Acids obtained from polymerised unsaturated acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/284—Esters of aromatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/286—Esters of polymerised unsaturated acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C10M2207/288—Partial esters containing free carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/287—Partial esters
    • C10M2207/289—Partial esters containing free hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/022—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amino group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/022—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amino group
    • C10M2217/023—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amino group the amino group containing an ester bond
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/024—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/026—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrile group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/028—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/041—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds involving a condensation reaction
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/042—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds between the nitrogen-containing monomer and an aldehyde or ketone
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/043—Mannich bases
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/044—Polyamides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/045—Polyureas; Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/041—Triaryl phosphates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C10M2223/045—Metal containing thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/241—Manufacturing joint-less pipes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/242—Hot working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/243—Cold working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/245—Soft metals, e.g. aluminum
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/246—Iron or steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/247—Stainless steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Lubricants (AREA)

Description

【発明の詳細な説明】
〔産業上の利用分野〕 本発明は新規な水分散型のアルミニウム及びア
ルミニウム合金用冷間圧延油組成物（以下、「ア
ルミ用冷間圧延油組成物」と称する）、更に詳し
くは、特定の潤滑油成分と分散剤成分を含有する
水分散型アルミ用冷間圧延油組成物に関する。 〔従来の技術〕 通常、金属の圧延加工により薄い金属板を得る
ために熱間圧延、冷間圧延が行われており、それ
ぞれの工程、金属の種類により、種々の圧延潤滑
油が使用されている。 そして、このような金属の圧延潤滑油に要求さ
れる性能として、圧延潤滑性が良好であること、
加工熱の除去性が良いこと、被圧延材の表面に残
留した油分が焼純により汚れを発生しないこと、
圧延潤滑油の液管理が容易であること、寿命が長
いこと、経済的であること、錆を発生させないこ
となどが挙げられる。 たとえば鉄錆の冷間圧延の場合、牛脂やパーム
油のような動植物油脂や鉱油を基油として、脂肪
酸等の油性向上剤を含む潤滑油成分を水中に乳化
した状態で使用している。 一方、アルミニウム及びその合金の冷間圧延で
は、低粘度鉱油を基油として種々の油性向上剤を
含む潤滑油成分をニートで使用している。低粘度
鉱油を基油に用いる理由は、圧延ロールとアルミ
ニウム板が直に接触した境界潤滑領域で圧延加工
することにより、アルミニウム特有の表面光沢を
得るためである。 〔発明が解決しようとする問題点〕 しかしながら、上記の如き従来の圧延油は、低
粘度鉱油を構成している炭化水素の分子量が小さ
いため、沸点が低く引火性が高い性質がある。そ
のため低粘度鉱油の沸点範囲（分留範囲）を狭く
して低沸成分を除去し、低粘度鉱油としては引火
点が高めになるように工夫されてはいるが、火災
の危険を常に抱えながら操業しているのが現象で
ある。 しかも近年アルミニウム及びアルミニウム合金
の冷間圧延がますます高速高圧化に向かう傾向に
あり、それに伴う加工熱の除去の点で上記した低
粘度鉱油を基油とした現行の圧延潤滑油では、そ
の冷却不足が大きな問題となつていた。 〔問題点を解決するための手段〕 本発明者らはこのような現状に鑑み、アルミニ
ウム及びアルミニウム合金の冷間圧延工程におい
て、高速高圧下圧延でも火災の危険がなく、しか
も前述した圧延潤滑油として具備すべき性質を満
足する圧延潤滑油を得るべく鋭意研究を続けた結
果、潤滑油成分を特定の分散剤成分を用いて水中
に乳化分散させれば上記目的を達成できることを
見出した。 更に詳しくは、脂肪族アルコールを含有する潤
滑油成分を、特定の分散剤成分を用いて水中に乳
化分散させることにより、冷却性は勿論のこと、
圧延潤滑性が良好で、かつ該分散剤成分の保護コ
ロイド的作用によつて、潤滑油成分は適度な粒径
に保たれ水中に安定に乳化分散されるので循環安
定性がよく、更に長期循環使用においても粒径が
安定に保たれ液管理が容易であることを見出し、
本発明を完成した。 すなわち、本発明は次の成分(a)及び(b) (a) 脂肪族アルコール又は脂肪族アルコールと鉱
物油、脂肪酸及び脂肪酸エステルより選ばれる
１種若しくは２種以上との混合物からなる潤滑
油成分 (b) 次の(イ)、(ロ)及び(ハ)より選ばれる１種又は２
種
以上の分散剤成分 (イ) 次の一般式（）で表される含窒素単量体
又はその塩若しくは第４級アンモニウム塩の
単独重合物あるいはこれらの２種以上の共重
合物で、その平均分子量が1000〜10000000の
範囲にあるもの、
〔式中、Ａは−Ｏ−又は−NH−を、n1は１〜３の整数を示し、R1はＨ又はCH3を、R2及びR3はＨ、CH3又はC2H5を示す。〕
(ロ) 前記一般式（）で表される含窒素単量体
又はその塩若しくは第４級アンモニウム塩の
１種又は２種以上と、α，β−不飽和カルボ
ン酸又はその塩あるいはその誘導体、スルホ
ン酸基含有ビニル化合物又はその塩から成る
群より選ばれるビニル系単量体の１種又は２
種以上との共重合物で、その平均分子量が
1000〜10000000の範囲にあるもの、 (ハ) エチレンイミンの開環重合物の塩又は第４
級アンモニウム塩で、その平均分子量が1000
〜10000000の範囲にあるもの、 を必須成分として含有することを特徴とする水分
散型アルミニウム及びアルミニウム合金用冷間圧
延油組成物を提供するものである。 本発明の圧延油組成物の(a)成分である潤滑油成
分は、脂肪族アルコール、好ましくは炭素数８〜
22の直鎖若しくは分岐鎖の高級脂肪族アルコール
を必須成分とするものであつて、上記脂肪族アル
コール又は該脂肪族アルコールと鉱物油、脂肪酸
及び脂肪酸エステルより選ばれる１種若しくは２
種以上との混合物からなるものである。ここで、
鉱物油としてはスピンドル油、マシン油、タービ
ン油、シリンダー油、ポリブテン等が、脂肪酸と
しては炭素数８〜22の直鎖若しくは分岐鎖の飽和
若しくは不飽和の高級脂肪酸が、脂肪酸エステル
としては該高級脂肪酸と炭素数１〜８の直鎖若し
くは分岐鎖の１価若しくは多価アルコールとのエ
ステルがそれぞれ挙げられる。 本発明の(b)成分の分散剤成分のうち、(イ)におけ
る含窒素単量体（）の具体例としては、ジメチ
ルアミノエチルアクリレート、ジエチルアミノエ
チルアクリレート、ジメチルアミノエチルメタク
リレート、ジエチルアミノエチルメタクリレー
ト、ジメチルアミノプロピルアクリルアミド、ジ
エチルアミノプロピルアクリルアミド、ジメチル
アミノプロピルメタクリルアミド、ジエチルアミ
ノプロピルメタクリルアミド等が挙げられる。 これら含窒素単量体の単独重合物又は共重合物
のうち、平均分子量が1000〜10000000のものが使
用される。 また、(ロ)におけるビニル系単量体としては、例
えば、アクリル酸、メタクリル酸、マレイン酸又
はこれらの酸のアルカリ金属塩、アンモニウム
塩、アマイド化合物若しくはエステル化物：ビニ
ルスルホン酸、メタクリルスルホン酸、２−アク
リルアミド−２−メチルプロパンスルホン酸、ｐ
−スチレンスルホン酸又はこれらの酸のアルカリ
金属塩若しくはアンモニウム塩等が挙げられる。
そして、当該含窒素単量体とビニル系単量体との
共重合物のうち、平均分子量が1000〜10000000の
ものが使用される。 更に、(ハ)のエチレンイミンの開環重合物の塩又
は第４級アンモニウム塩は、具体的にはその繰り
返し単位が次の一般式（）で評わされ、平均分
子量が1000〜10000000のものが挙げられる。
〔発明の効果〕
かくして得られた本発明のアルミ用冷間圧延油
組成物は安定した粒径分布を与え、高潤滑圧延性
能を有し、経時変化の少ない圧延油を提供すると
ともに、次のような特色を有している。すなわ
ち、圧延後のストリツプ表面に残留した圧延油エ
マルシヨンはエアーパージする事により容易に板
上から除去できることである。この性質は、潤滑
油成分を他の界面活性剤を用いて水中に乳化分散
させた圧延油エマルシヨンではエアパージによる
残留エマルシヨンの除去性が悪く、本発明の組成
物にのみ観察される現象で、圧延後の板面清浄性
に大きく寄与するものである。 〔実施例〕 次に実施例を挙げて本発明を具体的に説明す
る。但し、本発明は本実施例によりなんら制限を
うけるものではない。尚、重量％は単に「％」で
示した。 実施例 本発明に従つて、アルミ用冷間圧延油を以下の
ように調製した。尚、比較のために従来からアル
ミ冷間圧延に使用されているニート油（類似品、
比較品３、４）及び、界面活性剤により潤滑油成
分を乳化したもの（比較品５、６）も調製した。
本発明品１〜５及び比較品５、６は、潤滑油成分
を９重量倍の水に乳化分散させたものである。 発明品No.１ 鉱油（40℃、9.5cSt） 87.0％ ラウリルアルコール 10.0％ 分散剤成分(A) 3.0％ Ａ：ジメチルアミノプロピルメタクリルアミドの
メチルクロリドによる第４級アンモニウム塩
の重合物（MW＝80万） 比較品No.１ 鉱油（40℃、9.5cSt） 77.0％ ステアリン酸ブチルエステル 20.0％ 分散剤成分(B) 3.0％ Ｂ：ジメチルアミノエチルメタクリレートのグリ
コール酸中和物／アクリル酸ソーダ＝６／１
の共重合物（MW＝50万） 比較品No.２ 鉱油（40℃、4.0cSt） 96.0％ オレイン酸 2.0％ 酸化防止剤 1.0％ 分散剤成分(C) 1.0％ Ｃ：ジメチルアミノエチルメタクリレートのグル
コン酸中和物／２−アクリルアミド−２−メ
チルプロパンスルホン酸ソーダ＝４／１の共
重合物 発明品No.２ ステアリン酸メチルエステル 40.0％ ミリスチルアルコール 55.0％ 分散剤成分(D) 5.0％ Ｄ：ポリエチレンイミンのリン酸中和物（MW＝
７万） 発明品No.３ 鉱油（40℃、3.5cSt） 46.0％ ミリスチン酸イソプロピルエステル 35.0％ ラウリルアルコール 10.0％ オレイン酸 4.0％ リン酸エステル系極圧剤 1.0％ 分散剤成分(B) 2.0％ 分散剤成分(D) 2.0％ 発明品No.４ 鉱油（40℃、3.5cSt） 62.0％ C10〜C16の脂肪族アルコール 30.0％ 牛脂脂肪酸 5.0％ 分散剤成分(E) 3.0％ Ｅ：エピクロルヒドリンのトリメチルアミン第４
級化物の開環重合物（MW＝3500） 発明品No.５ 鉱油（40℃、9.5cSt） 60.0％ ラウリルアルコール 25.0％ C18ゲルベ脂肪酸 10.0％ 分散剤成分(F) 5.0％ Ｆ：ジメチルアミノエチルメタクリレート／ラウ
リルメタクリレート＝３／１の共重合物
（MW＝５万） 比較品No.３ 鉱油（40℃、3.5cSt） 95.0％ ラウリルアルコール 5.0％ 比較品No.４ 鉱油（40℃、3.5cSt） 60.0％ C12〜C15のオキソアルコール 20.0％ ステアリン酸ブチル 20.0％ 比較品No.５ 鉱油（40℃、3.5cSt） 50.0％ ラウリルアルコール 45.0％ ポリオキシエチレンノニルフエニルエーテル
（HLB＝10.5） 5.0％ 比較品No.６ 鉱油（40℃、9.5cSt） 52.0％ ステアリン酸−２−エチルヘキシル 35.0％ ミリスチン酸 10.0％ ポリオキシエチレンノニルフエニルエーテル
（HLB＝10.5） 2.0％ ポリオキシエチレンノニルフエニルエーテル
（HLB＝13.0） 1.0％ １ 圧延試験 本発明品１〜５及び比較品１〜６を使用して圧
延機による圧延試験を行つた。圧延は、ロール間
の間〓を各パス毎に一定量ずつ小さくし、その時
の圧延荷重と圧下率を測定する事により圧延潤滑
性を比較した。 圧延機の仕様 ワークロール径 200mm ワークロール幅 200mm ロール材質 SUJ−2Hs95 圧延速度 100ｍ／min 被圧延材 純アルミニウム板 A1050H材 板 幅 80mm 板 厚 ３mm 長 さ 300mm 圧延油 圧延油は表−１に示す条件でスプレーから供給
した（流量600ml／min）。
【表】 ２ エアーパージ試験 アルミニウム板（60mm×80mm）に本発明品１〜
５および比較品１、２、５、６のエマルシヨンを
スプレー塗布する。その後EDMドライヤー
（Wingo Seiki社製）でエアーパージし、その時
のエマルシヨンの除去性を比較した。 ３ 結果 表−２のとおりである。
【表】
【表】

Claims (1)

  1. 【特許請求の範囲】 １ 次の成分(a)及び(b) (a) 脂肪族アルコール又は脂肪族アルコールと鉱
    物油、脂肪酸及び脂肪酸エステルより選ばれる
    １種若しくは２種以上との混合物からなる潤滑
    油成分 (b) 次の(イ)、(ロ)及び(ハ)より選ばれる１種又は２
    種
    以上の分散剤成分 (イ) 次の一般式（）で表される含窒素単量体
    又はその塩若しくは第４級アンモニウム塩の
    単独重合物あるいはこれらの２種以上の共重
    合物で、その平均分子量が1000〜10000000の
    範囲にあるもの、 【化】 〔式中、Ａは−Ｏ−又は−NH−を、n1は１
    〜３の整数を示し、R1はＨ又はCH3を、R2
    及びR3はＨ、CH3又はC2H5を示す。〕 (ロ) 前記一般式（）で表される含窒素単量体
    又はその塩若しくは第４級アンモニウム塩の
    １種又は２種以上と、α，β−不飽和カルボ
    ン酸又はその塩あるいはその誘導体、スルホ
    ン酸基含有ビニル化合物又はその塩から成る
    群より選ばれるビニル系単量体の１種又は２
    種以上との共重合物で、その平均分子量が
    1000〜10000000の範囲にあるもの、 (ハ) エチレンイミンの開環重合物の塩又は第４
    級アンモニウム塩で、その平均分子量が1000
    〜10000000の範囲にあるもの、 を必須成分として含有することを特徴とする水分
    散型アルミニウム及びアルミニウム合金用冷間圧
    延油組成物。 ２ (b)成分の分散剤成分が全組成中の0.1〜10重
    量％である特許請求の範囲第１項記載の水分散型
    アルミニウム及びアルミニウム合金用冷間圧延油
    組成物。
JP61034124A 1986-02-19 1986-02-19 アルミ用冷間圧延油組成物 Granted JPS62192496A (ja)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP61034124A JPS62192496A (ja) 1986-02-19 1986-02-19 アルミ用冷間圧延油組成物
KR1019870000963A KR940011836B1 (ko) 1986-02-19 1987-02-06 알루미늄 및 알루미늄 합금용 냉간 압연 오일 조성물
EP87101936A EP0233588B1 (en) 1986-02-19 1987-02-12 A cold rolling oil composition for aluminium and aluminium-containing alloys
CA000529618A CA1281708C (en) 1986-02-19 1987-02-12 Cold rolling oil composition for aluminum and aluminum-containingalloys
DE8787101936T DE3764970D1 (de) 1986-02-19 1987-02-12 Kaltwalzoel-zusammensetzung fuer aluminium und aluminium enthaltende legierungen.
ES87101936T ES2017943B3 (es) 1986-02-19 1987-02-12 Un compuesto para laminacion en frio de aluminio y de aleaciones que contienen aluminio.
US07/014,592 US4800034A (en) 1986-02-19 1987-02-13 Cold rolling oil composition for aluminum and aluminum-containing alloys

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61034124A JPS62192496A (ja) 1986-02-19 1986-02-19 アルミ用冷間圧延油組成物

Publications (2)

Publication Number Publication Date
JPS62192496A JPS62192496A (ja) 1987-08-24
JPH0576998B2 true JPH0576998B2 (ja) 1993-10-25

Family

ID=12405491

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61034124A Granted JPS62192496A (ja) 1986-02-19 1986-02-19 アルミ用冷間圧延油組成物

Country Status (7)

Country Link
US (1) US4800034A (ja)
EP (1) EP0233588B1 (ja)
JP (1) JPS62192496A (ja)
KR (1) KR940011836B1 (ja)
CA (1) CA1281708C (ja)
DE (1) DE3764970D1 (ja)
ES (1) ES2017943B3 (ja)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE464306B (sv) * 1988-02-15 1991-04-08 Nynaes Ind Ab Saett vid bearbetning av aluminium och anvaendning av en dikarboxylsyra vid saettet
JPH02305894A (ja) * 1989-05-19 1990-12-19 Nkk Corp 鋼板用冷間圧延油
DE3929071A1 (de) * 1989-09-01 1991-03-07 Henkel Kgaa Universalschmiermittel auf der basis einer syntheseoelloesung
US5286300A (en) * 1991-02-13 1994-02-15 Man-Gill Chemical Company Rinse aid and lubricant
JP2840526B2 (ja) * 1993-06-24 1998-12-24 出光興産株式会社 潤滑油組成物
US5549836A (en) * 1995-06-27 1996-08-27 Moses; David L. Versatile mineral oil-free aqueous lubricant compositions
JPH10324887A (ja) * 1997-05-26 1998-12-08 Kyodo Yushi Kk 水溶性油剤組成物
US6068957A (en) * 1998-06-29 2000-05-30 Eastman Kodak Company Lubricating layer in photographic elements
FR2820431B1 (fr) * 2001-02-06 2007-04-27 Rhodia Chimie Sa Procede de deformation de metaux mettant en oeuvre un lubrifiant aqueux additive permettant d'augmenter la productivite
US6586375B1 (en) * 2002-04-15 2003-07-01 The Lubrizol Corporation Phosphorus salts of nitrogen containing copolymers and lubricants containing the same
JP2005200610A (ja) * 2004-01-19 2005-07-28 Kyodo Yushi Co Ltd 冷間圧延油組成物及び冷間圧延方法
US20060135380A1 (en) * 2004-12-20 2006-06-22 The Lubrizol Corporation Method of fatigue control
DE102008033449B3 (de) * 2008-07-16 2009-11-19 BRÜNDERMANN, Georg Verfahren zur Herstellung von Rippenrohren
CN101781780B (zh) * 2010-04-06 2011-10-05 中南大学 一种提高锌电解用阴极铝板耐腐蚀性能的方法
CA2834607C (en) * 2011-06-02 2020-01-14 Rohm And Haas Company Amphoteric polymer composition
JP7125833B2 (ja) * 2016-12-06 2022-08-25 Ｅｎｅｏｓ株式会社 金属加工油組成物及び金属加工油組成物のろ過性の低下を抑制する方法
CN109433799B (zh) * 2018-11-14 2021-07-13 蓝思科技（长沙）有限公司 一种用于分离玻璃-金属组装件的分离剂及分离工艺
CN111849599B (zh) * 2020-07-03 2022-11-08 浙江物得宝尔新材料有限公司 一种水溶性润滑液及铝冷轧的加工方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4036769A (en) * 1971-04-05 1977-07-19 Werner G. Smith, Inc. Sperm oil substitute from blend of alcohol-carboxylic acid esters with liquid fat
GB1486197A (en) * 1973-09-29 1977-09-21 Nippon Light Metal Res Labor Water-soluble metal working lubricating composition
US4191658A (en) * 1974-10-10 1980-03-04 The Lubrizol Corporation Hot melt metal working lubricants and methods for their application
US4178260A (en) * 1974-10-31 1979-12-11 Exxon Research & Engineering Co. Ester based metal working lubricants
CH615696A5 (ja) * 1975-08-05 1980-02-15 Alusuisse
US4191801A (en) * 1977-02-08 1980-03-04 The Lubrizol Corporation Hot melt metal working lubricants
US4096078A (en) * 1977-06-28 1978-06-20 Texaco Inc. Synthetic aircraft turbine oil
DE2909517A1 (de) * 1979-03-10 1980-09-18 Bayer Ag Metallbearbeitungs-schmieroele
JPS58104999A (ja) * 1981-12-18 1983-06-22 Kao Corp 水分散型金属圧延油組成物
US4566983A (en) * 1982-08-09 1986-01-28 The Lubrizol Corporation Combination of carboxylic acylating agents substituted with olefin polymers of high and low molecular weight mono-olefins, derivatives thereof, and fuels and lubricants containing same
DE3247426A1 (de) * 1982-12-22 1984-06-28 Merck Patent Gmbh, 6100 Darmstadt Schneidoel fuer die spangebende bearbeitung von buntmetallen
JPS59227985A (ja) * 1983-06-10 1984-12-21 Kao Corp 金属加工油組成物
GB2142931B (en) * 1983-06-14 1986-07-30 Kao Corp Metal-working compositions
JPH0240119B2 (ja) * 1983-06-16 1990-09-10 Kao Kk Reikanatsuenyu
JPS601292A (ja) * 1983-06-17 1985-01-07 Nippon Kokan Kk <Nkk> 鋼板用冷間圧延油

Also Published As

Publication number Publication date
JPS62192496A (ja) 1987-08-24
ES2017943B3 (es) 1991-03-16
KR870008011A (ko) 1987-09-23
EP0233588A1 (en) 1987-08-26
KR940011836B1 (ko) 1994-12-26
DE3764970D1 (de) 1990-10-25
CA1281708C (en) 1991-03-19
EP0233588B1 (en) 1990-09-19
US4800034A (en) 1989-01-24

Similar Documents

Publication Publication Date Title
JPH0576998B2 (ja)
JP2004263087A (ja) アルミニウム板用熱間圧延油用潤滑油
CN102264882A (zh) 热轧油用润滑油及热轧板的制造方法
JPS6214599B2 (ja)
CN1332001C (zh) 钢板冷轧油
JPH0240111B2 (ja)
JPH10231494A (ja) 水分散型鋼板冷間圧延油用潤滑油及び鋼板冷間圧延方法
US5583100A (en) Oil compositions for hot rolling aluminum and aluminum alloys
JP4463632B2 (ja) アルミニウム及びアルミニウム合金板用熱間圧延油
JP2919206B2 (ja) アルミニウム及びアルミニウム合金の冷間圧延油及びそれを用いる冷間圧延方法
JP6273521B2 (ja) 冷間圧延油組成物及び冷間圧延方法
CN1093875C (zh) 用于钢板水分散冷轧油的润滑油
JP2779506B2 (ja) アルミニウム及びアルミニウム合金用熱間圧延油組成物
JP3386927B2 (ja) 金属加工油剤原液組成物および金属加工油剤組成物
JPH108077A (ja) 金属塑性加工用潤滑油剤
JP3370880B2 (ja) アルミニウム及びアルミニウム合金板の圧延方法
JPH0314880B2 (ja)
JP3096289B2 (ja) 水分散型鋼板冷間圧延油
JP3370873B2 (ja) アルミニウム又はアルミニウム合金板の圧延方法
US3563895A (en) Lubricant-coolant
JPH0741785A (ja) チタン板用冷間圧延油組成物
JP3370872B2 (ja) アルミニウム又はアルミニウム合金板の圧延方法
JP3370879B2 (ja) アルミニウム又はアルミニウム合金板の圧延方法及び装置
JP2869850B2 (ja) アルミニウム及びアルミニウム合金用熱間圧延油組成物
JP3370878B2 (ja) アルミニウム又はアルミニウム合金板の圧延方法

Legal Events

Date Code Title Description
LAPS Cancellation because of no payment of annual fees