JPH0631331B2 - 熱分解ガソリン中のジエンの選択的水素化方法 - Google Patents
熱分解ガソリン中のジエンの選択的水素化方法Info
- Publication number
- JPH0631331B2 JPH0631331B2 JP58219632A JP21963283A JPH0631331B2 JP H0631331 B2 JPH0631331 B2 JP H0631331B2 JP 58219632 A JP58219632 A JP 58219632A JP 21963283 A JP21963283 A JP 21963283A JP H0631331 B2 JPH0631331 B2 JP H0631331B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- stage
- hydrogen
- range
- pyrolysis gasoline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 18
- 238000000197 pyrolysis Methods 0.000 title claims description 15
- 238000005984 hydrogenation reaction Methods 0.000 title claims description 14
- 150000001993 dienes Chemical class 0.000 title claims description 12
- 239000003054 catalyst Substances 0.000 claims description 64
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 25
- 229910052739 hydrogen Inorganic materials 0.000 claims description 25
- 239000001257 hydrogen Substances 0.000 claims description 25
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 18
- 239000002245 particle Substances 0.000 claims description 11
- 229910052759 nickel Inorganic materials 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000007789 gas Substances 0.000 description 9
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 5
- 239000012263 liquid product Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 150000005673 monoalkenes Chemical class 0.000 description 5
- 239000002184 metal Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000007791 liquid phase Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- 239000012798 spherical particle Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 238000001833 catalytic reforming Methods 0.000 description 1
- 238000001193 catalytic steam reforming Methods 0.000 description 1
- 230000005465 channeling Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- VLXBWPOEOIIREY-UHFFFAOYSA-N dimethyl diselenide Natural products C[Se][Se]C VLXBWPOEOIIREY-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- -1 of dienes Chemical class 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
- C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
- C10G45/36—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
- C10G65/06—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps at least one step being a selective hydrogenation of the diolefins
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB08233746A GB2131043B (en) | 1982-11-26 | 1982-11-26 | Selective hydrogenation of dienes in pyrolysis gasoline |
| GB8233746 | 1982-11-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59105083A JPS59105083A (ja) | 1984-06-18 |
| JPH0631331B2 true JPH0631331B2 (ja) | 1994-04-27 |
Family
ID=10534541
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58219632A Expired - Lifetime JPH0631331B2 (ja) | 1982-11-26 | 1983-11-24 | 熱分解ガソリン中のジエンの選択的水素化方法 |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPH0631331B2 (it) |
| KR (1) | KR910004883B1 (it) |
| AU (1) | AU559246B2 (it) |
| BE (1) | BE898299A (it) |
| CA (1) | CA1216311A (it) |
| DE (1) | DE3342521A1 (it) |
| FR (1) | FR2536759B1 (it) |
| GB (1) | GB2131043B (it) |
| IT (1) | IT1168974B (it) |
| NL (1) | NL8303740A (it) |
| ZA (1) | ZA838762B (it) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19608241A1 (de) * | 1996-03-04 | 1997-09-18 | Basf Ag | Verfahren zur selektiven Hydrierung von Dienen |
| FR2790000B1 (fr) * | 1999-02-24 | 2001-04-13 | Inst Francais Du Petrole | Procede de production d'essences a faible teneur en soufre |
| US7038097B2 (en) * | 2003-03-04 | 2006-05-02 | Exxonmobil Chemical Patents Inc. | Dual bed process using two different catalysts for selective hydrogenation of acetylene and dienes |
| US7153807B2 (en) | 2003-03-04 | 2006-12-26 | Exxon Mobil Chemical Patents Inc. | Catalysts for selective hydrogenation of alkynes and alkadienes |
| CN101081998B (zh) * | 2006-05-31 | 2010-05-12 | 中国石油化工股份有限公司 | 一种c4馏分的加氢方法 |
| SG10201402426UA (en) | 2009-06-11 | 2014-10-30 | Shell Int Research | A process for the selective hydrogenation and hydrodesulferization of a pyrolysis gasoline feedstock |
| CN112691671B (zh) * | 2019-10-23 | 2024-07-02 | 中国石油化工股份有限公司 | 镍催化剂及其制备方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB942493A (en) * | 1961-05-10 | 1963-11-20 | British Petroleum Co | Improvements relating to the hydrogenation of petroleum hydrocarbons |
| US3388056A (en) * | 1966-08-19 | 1968-06-11 | Exxon Research Engineering Co | Process for the hydrogenation of steam cracked naphtha |
| NL161807C (nl) * | 1969-03-03 | 1980-08-15 | Shell Int Research | Werkwijze voor het winnen van aromatische koolwater- stoffen uit pyrolysebenzine. |
| GB1346778A (en) * | 1971-02-11 | 1974-02-13 | British Petroleum Co | Selective hydrogenation of gasolines |
| GB1380962A (en) * | 1972-01-19 | 1975-01-22 | British Petroleum Co | Selective hydrogenation of unsaturated gasolines |
| US4113603A (en) * | 1977-10-19 | 1978-09-12 | The Lummus Company | Two-stage hydrotreating of pyrolysis gasoline to remove mercaptan sulfur and dienes |
| FR2410038A1 (fr) * | 1977-11-29 | 1979-06-22 | Inst Francais Du Petrole | Procede d'hydrogenation selective d'essences contenant a la fois des composes generateurs de gommes et des composes indesirables du soufre |
-
1982
- 1982-11-26 GB GB08233746A patent/GB2131043B/en not_active Expired
-
1983
- 1983-10-31 NL NL8303740A patent/NL8303740A/nl not_active Application Discontinuation
- 1983-11-01 CA CA000440192A patent/CA1216311A/en not_active Expired
- 1983-11-24 AU AU21653/83A patent/AU559246B2/en not_active Ceased
- 1983-11-24 DE DE19833342521 patent/DE3342521A1/de not_active Withdrawn
- 1983-11-24 IT IT23879/83A patent/IT1168974B/it active
- 1983-11-24 JP JP58219632A patent/JPH0631331B2/ja not_active Expired - Lifetime
- 1983-11-24 BE BE0/211927A patent/BE898299A/nl not_active IP Right Cessation
- 1983-11-24 ZA ZA838762A patent/ZA838762B/xx unknown
- 1983-11-24 KR KR1019830005559A patent/KR910004883B1/ko not_active Expired
- 1983-11-24 FR FR838318726A patent/FR2536759B1/fr not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| FR2536759B1 (fr) | 1990-02-09 |
| AU559246B2 (en) | 1987-03-05 |
| IT8323879A0 (it) | 1983-11-24 |
| JPS59105083A (ja) | 1984-06-18 |
| GB2131043B (en) | 1986-09-10 |
| KR840007433A (ko) | 1984-12-07 |
| IT1168974B (it) | 1987-05-20 |
| DE3342521A1 (de) | 1984-05-30 |
| CA1216311A (en) | 1987-01-06 |
| FR2536759A1 (fr) | 1984-06-01 |
| KR910004883B1 (ko) | 1991-07-15 |
| GB2131043A (en) | 1984-06-13 |
| NL8303740A (nl) | 1984-06-18 |
| ZA838762B (en) | 1984-07-25 |
| BE898299A (nl) | 1984-05-24 |
| AU2165383A (en) | 1984-05-31 |
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