JPH07233281A - 加硫可能なハロゲン含有ポリマーの早期硬化の制御 - Google Patents

加硫可能なハロゲン含有ポリマーの早期硬化の制御

Info

Publication number: JPH07233281A
Authority: JP; Japan
Prior art keywords: composition; vulcanizable; cure; halogen; containing polymer
Prior art date: 1993-12-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP31362594A

Other languages

English (en)

Japanese (ja)

Inventor

Jay Bernard Class

ジェイ・バーナード・クラス

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Hercules LLC

Original Assignee

Hercules LLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1993-12-16

Filing date

1994-12-16

Publication date

1995-09-05

1994-12-16 Application filed by Hercules LLC filed Critical Hercules LLC

1995-09-05 Publication of JPH07233281A publication Critical patent/JPH07233281A/ja

Status Pending legal-status Critical Current

Links

229920000642 polymer Polymers 0.000 title claims abstract description 48
238000004073 vulcanization Methods 0.000 title claims abstract description 10
230000002028 premature Effects 0.000 title abstract description 3
229910052736 halogen Inorganic materials 0.000 claims abstract description 37
150000002367 halogens Chemical class 0.000 claims abstract description 37
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
238000000034 method Methods 0.000 claims abstract description 23
238000003860 storage Methods 0.000 claims abstract description 22
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims abstract description 16
239000003431 cross linking reagent Substances 0.000 claims abstract description 12
BIGYLAKFCGVRAN-UHFFFAOYSA-N 1,3,4-thiadiazolidine-2,5-dithione Chemical compound S=C1NNC(=S)S1 BIGYLAKFCGVRAN-UHFFFAOYSA-N 0.000 claims abstract description 8
230000000694 effects Effects 0.000 claims abstract description 8
150000007970 thio esters Chemical class 0.000 claims abstract description 7
239000000203 mixture Substances 0.000 claims description 119
239000004971 Cross linker Substances 0.000 claims description 15
229920001971 elastomer Polymers 0.000 claims description 12
239000005060 rubber Substances 0.000 claims description 12
-1 chloroalkyl acrylate Chemical compound 0.000 claims description 11
150000001875 compounds Chemical class 0.000 claims description 11
BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims description 8
239000004709 Chlorinated polyethylene Substances 0.000 claims description 6
229920001577 copolymer Polymers 0.000 claims description 6
239000000945 filler Substances 0.000 claims description 6
229920001897 terpolymer Polymers 0.000 claims description 5
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 4
239000000843 powder Substances 0.000 claims description 4
229920005557 bromobutyl Polymers 0.000 claims description 3
CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims description 3
229920005556 chlorobutyl Polymers 0.000 claims description 3
229920001328 Polyvinylidene chloride Polymers 0.000 claims description 2
125000005250 alkyl acrylate group Chemical group 0.000 claims description 2
125000002947 alkylene group Chemical group 0.000 claims description 2
229920001903 high density polyethylene Polymers 0.000 claims description 2
239000004700 high-density polyethylene Substances 0.000 claims description 2
229920001519 homopolymer Polymers 0.000 claims description 2
229920002681 hypalon Polymers 0.000 claims description 2
229920001084 poly(chloroprene) Polymers 0.000 claims description 2
229920000915 polyvinyl chloride Polymers 0.000 claims description 2
239000004800 polyvinyl chloride Substances 0.000 claims description 2
229920002620 polyvinyl fluoride Polymers 0.000 claims description 2
238000002156 mixing Methods 0.000 abstract description 5
239000000523 sample Substances 0.000 description 24
238000012360 testing method Methods 0.000 description 24
238000001723 curing Methods 0.000 description 14
238000004132 cross linking Methods 0.000 description 12
239000004615 ingredient Substances 0.000 description 12
239000013068 control sample Substances 0.000 description 10
239000000370 acceptor Substances 0.000 description 8
230000032683 aging Effects 0.000 description 8
239000000047 product Substances 0.000 description 8
239000002253 acid Substances 0.000 description 6
230000007423 decrease Effects 0.000 description 6
239000000654 additive Substances 0.000 description 5
239000011230 binding agent Substances 0.000 description 5
238000004519 manufacturing process Methods 0.000 description 5
239000000463 material Substances 0.000 description 5
230000000704 physical effect Effects 0.000 description 5
239000012141 concentrate Substances 0.000 description 4
239000003381 stabilizer Substances 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
238000010521 absorption reaction Methods 0.000 description 3
125000001931 aliphatic group Chemical group 0.000 description 3
239000007795 chemical reaction product Substances 0.000 description 3
239000000460 chlorine Substances 0.000 description 3
DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 3
238000009472 formulation Methods 0.000 description 3
239000000126 substance Substances 0.000 description 3
150000004867 thiadiazoles Chemical class 0.000 description 3
XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 description 2
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
229920000181 Ethylene propylene rubber Polymers 0.000 description 2
239000004606 Fillers/Extenders Substances 0.000 description 2
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
150000001412 amines Chemical class 0.000 description 2
QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
239000006229 carbon black Substances 0.000 description 2
239000000969 carrier Substances 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
150000002148 esters Chemical class 0.000 description 2
238000010438 heat treatment Methods 0.000 description 2
239000000049 pigment Substances 0.000 description 2
239000004014 plasticizer Substances 0.000 description 2
229920000058 polyacrylate Polymers 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
150000003839 salts Chemical class 0.000 description 2
229920003048 styrene butadiene rubber Polymers 0.000 description 2
MGAXYKDBRBNWKT-UHFFFAOYSA-N (5-oxooxolan-2-yl)methyl 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)OCC1OC(=O)CC1 MGAXYKDBRBNWKT-UHFFFAOYSA-N 0.000 description 1
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
MBIZXFATKUQOOA-UHFFFAOYSA-N 1,3,4-thiadiazole Chemical compound C1=NN=CS1 MBIZXFATKUQOOA-UHFFFAOYSA-N 0.000 description 1
YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 1
YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
VETPHHXZEJAYOB-UHFFFAOYSA-N 1-n,4-n-dinaphthalen-2-ylbenzene-1,4-diamine Chemical compound C1=CC=CC2=CC(NC=3C=CC(NC=4C=C5C=CC=CC5=CC=4)=CC=3)=CC=C21 VETPHHXZEJAYOB-UHFFFAOYSA-N 0.000 description 1
ZNRLMGFXSPUZNR-UHFFFAOYSA-N 2,2,4-trimethyl-1h-quinoline Chemical compound C1=CC=C2C(C)=CC(C)(C)NC2=C1 ZNRLMGFXSPUZNR-UHFFFAOYSA-N 0.000 description 1
TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 description 1
JYDRKKMKDMWVQQ-UHFFFAOYSA-N 4-(6-methylheptylamino)phenol Chemical compound CC(C)CCCCCNC1=CC=C(O)C=C1 JYDRKKMKDMWVQQ-UHFFFAOYSA-N 0.000 description 1
RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
244000043261 Hevea brasiliensis Species 0.000 description 1
239000013032 Hydrocarbon resin Substances 0.000 description 1
KEQFTVQCIQJIQW-UHFFFAOYSA-N N-Phenyl-2-naphthylamine Chemical compound C=1C=C2C=CC=CC2=CC=1NC1=CC=CC=C1 KEQFTVQCIQJIQW-UHFFFAOYSA-N 0.000 description 1
229920000459 Nitrile rubber Polymers 0.000 description 1
229920002367 Polyisobutene Polymers 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
229930006000 Sucrose Natural products 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
239000012190 activator Substances 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000004982 aromatic amines Chemical class 0.000 description 1
AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
229910001038 basic metal oxide Inorganic materials 0.000 description 1
238000005452 bending Methods 0.000 description 1
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
239000000920 calcium hydroxide Substances 0.000 description 1
229910001861 calcium hydroxide Inorganic materials 0.000 description 1
BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
239000000292 calcium oxide Substances 0.000 description 1
ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
239000004927 clay Substances 0.000 description 1
238000013329 compounding Methods 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
MLUCVPSAIODCQM-NSCUHMNNSA-N crotonaldehyde Chemical compound C\C=C\C=O MLUCVPSAIODCQM-NSCUHMNNSA-N 0.000 description 1
MLUCVPSAIODCQM-UHFFFAOYSA-N crotonaldehyde Natural products CC=CC=O MLUCVPSAIODCQM-UHFFFAOYSA-N 0.000 description 1
230000007547 defect Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
239000003814 drug Substances 0.000 description 1
229940079593 drug Drugs 0.000 description 1
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
239000013020 final formulation Substances 0.000 description 1
235000011187 glycerol Nutrition 0.000 description 1
229920006270 hydrocarbon resin Polymers 0.000 description 1
150000004679 hydroxides Chemical class 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000003999 initiator Substances 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
229910000464 lead oxide Inorganic materials 0.000 description 1
239000007788 liquid Substances 0.000 description 1
229920001684 low density polyethylene Polymers 0.000 description 1
239000004702 low-density polyethylene Substances 0.000 description 1
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
239000000347 magnesium hydroxide Substances 0.000 description 1
229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910000000 metal hydroxide Inorganic materials 0.000 description 1
239000004200 microcrystalline wax Substances 0.000 description 1
235000019808 microcrystalline wax Nutrition 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 1
BLCKKNLGFULNRC-UHFFFAOYSA-L n,n-dimethylcarbamodithioate;nickel(2+) Chemical compound [Ni+2].CN(C)C([S-])=S.CN(C)C([S-])=S BLCKKNLGFULNRC-UHFFFAOYSA-L 0.000 description 1
229920003052 natural elastomer Polymers 0.000 description 1
229920001194 natural rubber Polymers 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
235000019809 paraffin wax Nutrition 0.000 description 1
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
235000019271 petrolatum Nutrition 0.000 description 1
150000004714 phosphonium salts Chemical group 0.000 description 1
229920002959 polymer blend Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229920000166 polytrimethylene carbonate Polymers 0.000 description 1
238000012545 processing Methods 0.000 description 1
235000013772 propylene glycol Nutrition 0.000 description 1
150000003242 quaternary ammonium salts Chemical class 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
230000000630 rising effect Effects 0.000 description 1
238000013040 rubber vulcanization Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000001632 sodium acetate Substances 0.000 description 1
235000017281 sodium acetate Nutrition 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
239000005720 sucrose Substances 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 description 1
KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 1
239000001993 wax Substances 0.000 description 1
150000003751 zinc Chemical class 0.000 description 1
BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/45—Heterocyclic compounds having sulfur in the ring
- C08K5/46—Heterocyclic compounds having sulfur in the ring with oxygen or nitrogen in the ring

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

JP31362594A 1993-12-16 1994-12-16 加硫可能なハロゲン含有ポリマーの早期硬化の制御 Pending JPH07233281A (ja)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date
US16869493A	1993-12-16	1993-12-16
US168694		1993-12-16
US18471394A	1994-01-21	1994-01-21
US184713		1994-01-21

Publications (1)

Publication Number	Publication Date
JPH07233281A true JPH07233281A (ja)	1995-09-05

Family

ID=26864364

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP31362594A Pending JPH07233281A (ja)	1993-12-16	1994-12-16	加硫可能なハロゲン含有ポリマーの早期硬化の制御

Country Status (7)

Country	Link
EP (1)	EP0658590B1 (fr)
JP (1)	JPH07233281A (fr)
CA (1)	CA2138002C (fr)
DE (1)	DE69425227T2 (fr)
DK (1)	DK0658590T3 (fr)
ES (1)	ES2147766T3 (fr)
GR (1)	GR3034419T3 (fr)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1536593A (en) *	1976-06-28	1978-12-20	Hercules Inc	Vulcanizing halogen-containing polymers
US4482681A (en) *	1981-10-22	1984-11-13	Hercules Incorporated	Crosslinking halogen-containing polymers
US4745147A (en) *	1986-10-24	1988-05-17	E. I. Du Pont De Nemours And Company	Vulcanizable chlorinated polyethylene compositions

1994
- 1994-12-13 CA CA 2138002 patent/CA2138002C/fr not_active Expired - Fee Related
- 1994-12-15 EP EP94119831A patent/EP0658590B1/fr not_active Expired - Lifetime
- 1994-12-15 ES ES94119831T patent/ES2147766T3/es not_active Expired - Lifetime
- 1994-12-15 DK DK94119831T patent/DK0658590T3/da active
- 1994-12-15 DE DE1994625227 patent/DE69425227T2/de not_active Expired - Fee Related
- 1994-12-16 JP JP31362594A patent/JPH07233281A/ja active Pending
2000
- 2000-09-18 GR GR20000402107T patent/GR3034419T3/el not_active IP Right Cessation

Also Published As

Publication number	Publication date
EP0658590B1 (fr)	2000-07-12
DE69425227T2 (de)	2000-12-21
ES2147766T3 (es)	2000-10-01
CA2138002A1 (fr)	1995-06-17
CA2138002C (fr)	1998-11-24
DK0658590T3 (da)	2000-10-16
EP0658590A1 (fr)	1995-06-21
HK1005692A1 (en)	1999-01-22
DE69425227D1 (de)	2000-08-17
GR3034419T3 (en)	2000-12-29

Publication	Publication Date	Title
US4288576A (en)	1981-09-08	2,5-Dimercapto-1,3,4-thiadiazole as a cross-linker for saturated, halogen-containing polymers
EP0214361A2 (fr)	1987-03-18	Composition réticulable résistant au roussissement contenant un mélange de dithiocarbamates de cuivre et d'autres métaux
EP0658591B1 (fr)	2000-10-18	Contrôle de durcissement prématuré des polymères vulcanisables contenant des halogènes
JPH04505034A (ja)	1992-09-03	塩素化もしくはクロロスルホン化ポリエチレンおよび結晶性オレフィンポリマーを基材とする熱可塑性エラストマー
JPH11503483A (ja)	1999-03-26	フリーラジカル硬化エラストマーの早期硬化防止
US5665830A (en)	1997-09-09	Controlling premature curing of vulcanizable halogen-containing polymers
US7964110B2 (en)	2011-06-21	Cure system for halogenated elastomer compositions, a curable halogenated elastomer composition, and a method for curing halogenated elastomer compositions
JP2807005B2 (ja)	1998-09-30	臭素またはヨウ素を含むフルオロエラストマーのペルオキシドによる硬化用添加剤
EP0078155A1 (fr)	1983-05-04	Réticulation des polymères halogénés
JPH07233281A (ja)	1995-09-05	加硫可能なハロゲン含有ポリマーの早期硬化の制御
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