JPH07508785A - 新規な革オイリング製剤およびその使用 - Google Patents

新規な革オイリング製剤およびその使用

Info

Publication number: JPH07508785A
Authority: JP; Japan
Prior art keywords: acid; fatty; cooligomer; acids; leather
Prior art date: 1992-07-14
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP6502936A

Other languages

English (en)

Japanese (ja)

Inventor

リッター、ヴォルフガング

ジッツ、ハンス−ディーター

ツァウンス・フーバー、ルドルフ

ルシャインスキー、エミール

Original Assignee

ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチェン

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-07-14

Filing date

1993-07-05

Publication date

1995-09-28

1993-07-05 Application filed by ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチェン filed Critical ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチェン

1995-09-28 Publication of JPH07508785A publication Critical patent/JPH07508785A/ja

Status Pending legal-status Critical Current

Links

239000010985 leather Substances 0.000 title claims description 50
239000000203 mixture Substances 0.000 title claims description 39
238000009472 formulation Methods 0.000 title claims description 18
-1 aromatic sulfonic acids Chemical class 0.000 claims description 32
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 claims description 25
LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 claims description 24
239000006185 dispersion Substances 0.000 claims description 21
150000002148 esters Chemical class 0.000 claims description 21
235000014113 dietary fatty acids Nutrition 0.000 claims description 18
229930195729 fatty acid Natural products 0.000 claims description 18
239000000194 fatty acid Substances 0.000 claims description 18
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 17
239000002253 acid Substances 0.000 claims description 16
125000004432 carbon atom Chemical group C* 0.000 claims description 15
150000002191 fatty alcohols Chemical class 0.000 claims description 14
150000001875 compounds Chemical class 0.000 claims description 12
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 10
239000003795 chemical substances by application Substances 0.000 claims description 10
150000004665 fatty acids Chemical class 0.000 claims description 10
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
125000002947 alkylene group Chemical group 0.000 claims description 9
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 8
150000008064 anhydrides Chemical class 0.000 claims description 7
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 7
238000007334 copolymerization reaction Methods 0.000 claims description 7
239000003995 emulsifying agent Substances 0.000 claims description 7
239000003921 oil Substances 0.000 claims description 7
238000003797 solvolysis reaction Methods 0.000 claims description 7
230000002378 acidificating effect Effects 0.000 claims description 6
239000013543 active substance Substances 0.000 claims description 6
230000000694 effects Effects 0.000 claims description 6
239000000839 emulsion Substances 0.000 claims description 6
238000000034 method Methods 0.000 claims description 6
150000007513 acids Chemical class 0.000 claims description 5
125000002252 acyl group Chemical group 0.000 claims description 5
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 5
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
150000001991 dicarboxylic acids Chemical class 0.000 claims description 4
230000032050 esterification Effects 0.000 claims description 4
238000005886 esterification reaction Methods 0.000 claims description 4
150000002430 hydrocarbons Chemical class 0.000 claims description 4
150000002763 monocarboxylic acids Chemical class 0.000 claims description 4
230000007935 neutral effect Effects 0.000 claims description 4
235000011007 phosphoric acid Nutrition 0.000 claims description 4
239000000126 substance Substances 0.000 claims description 4
239000001993 wax Substances 0.000 claims description 4
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
125000001931 aliphatic group Chemical group 0.000 claims description 3
229930195733 hydrocarbon Natural products 0.000 claims description 3
230000007062 hydrolysis Effects 0.000 claims description 3
238000006460 hydrolysis reaction Methods 0.000 claims description 3
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
239000011976 maleic acid Substances 0.000 claims description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
229920006395 saturated elastomer Polymers 0.000 claims description 3
JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 2
150000001413 amino acids Chemical class 0.000 claims description 2
239000001530 fumaric acid Substances 0.000 claims description 2
239000003607 modifier Substances 0.000 claims description 2
WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
150000003016 phosphoric acids Chemical class 0.000 claims description 2
150000005846 sugar alcohols Polymers 0.000 claims description 2
150000003460 sulfonic acids Chemical class 0.000 claims description 2
235000021122 unsaturated fatty acids Nutrition 0.000 claims description 2
150000004670 unsaturated fatty acids Chemical class 0.000 claims description 2
125000004429 atom Chemical group 0.000 claims 1
150000007942 carboxylates Chemical class 0.000 claims 1
238000000354 decomposition reaction Methods 0.000 claims 1
125000001183 hydrocarbyl group Chemical group 0.000 claims 1
150000002688 maleic acid derivatives Chemical class 0.000 claims 1
239000007800 oxidant agent Substances 0.000 claims 1
230000001590 oxidative effect Effects 0.000 claims 1
235000021003 saturated fats Nutrition 0.000 claims 1
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims 1
235000021081 unsaturated fats Nutrition 0.000 claims 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 16
239000008096 xylene Substances 0.000 description 16
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
239000000047 product Substances 0.000 description 11
150000003839 salts Chemical class 0.000 description 11
BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 10
238000005406 washing Methods 0.000 description 10
229920001577 copolymer Polymers 0.000 description 9
238000002360 preparation method Methods 0.000 description 9
238000005108 dry cleaning Methods 0.000 description 8
239000007788 liquid Substances 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 7
229910052500 inorganic mineral Inorganic materials 0.000 description 7
239000011707 mineral Substances 0.000 description 7
235000010755 mineral Nutrition 0.000 description 7
239000000178 monomer Substances 0.000 description 7
150000001298 alcohols Chemical class 0.000 description 6
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
238000012360 testing method Methods 0.000 description 6
OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 5
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
235000019253 formic acid Nutrition 0.000 description 5
230000002209 hydrophobic effect Effects 0.000 description 5
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
238000009835 boiling Methods 0.000 description 4
238000001816 cooling Methods 0.000 description 4
239000003999 initiator Substances 0.000 description 4
229920000642 polymer Polymers 0.000 description 4
239000011541 reaction mixture Substances 0.000 description 4
239000005871 repellent Substances 0.000 description 4
239000000243 solution Substances 0.000 description 4
229910052783 alkali metal Inorganic materials 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
229910052804 chromium Inorganic materials 0.000 description 3
239000011651 chromium Substances 0.000 description 3
238000004140 cleaning Methods 0.000 description 3
239000003925 fat Substances 0.000 description 3
235000019197 fats Nutrition 0.000 description 3
239000000835 fiber Substances 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
238000006116 polymerization reaction Methods 0.000 description 3
238000004078 waterproofing Methods 0.000 description 3
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
239000005642 Oleic acid Substances 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
150000001252 acrylic acid derivatives Chemical class 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
229910000147 aluminium phosphate Inorganic materials 0.000 description 2
150000003863 ammonium salts Chemical class 0.000 description 2
239000002585 base Substances 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
150000001735 carboxylic acids Chemical class 0.000 description 2
239000012986 chain transfer agent Substances 0.000 description 2
239000003599 detergent Substances 0.000 description 2
238000005470 impregnation Methods 0.000 description 2
238000010348 incorporation Methods 0.000 description 2
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
239000000463 material Substances 0.000 description 2
238000003801 milling Methods 0.000 description 2
GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
239000008041 oiling agent Substances 0.000 description 2
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
230000035515 penetration Effects 0.000 description 2
238000012545 processing Methods 0.000 description 2
KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
125000000542 sulfonic acid group Chemical group 0.000 description 2
GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 2
229920001567 vinyl ester resin Polymers 0.000 description 2
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
229910052726 zirconium Inorganic materials 0.000 description 2
OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
RJYOKYDKKOFLBT-UHFFFAOYSA-N 2-[methyl(octadecanoyl)amino]acetic acid Chemical compound CCCCCCCCCCCCCCCCCC(=O)N(C)CC(O)=O RJYOKYDKKOFLBT-UHFFFAOYSA-N 0.000 description 1
XEEYSDHEOQHCDA-UHFFFAOYSA-N 2-methylprop-2-ene-1-sulfonic acid Chemical compound CC(=C)CS(O)(=O)=O XEEYSDHEOQHCDA-UHFFFAOYSA-N 0.000 description 1
AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical group C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
235000011468 Albizia julibrissin Nutrition 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
239000004215 Carbon black (E152) Substances 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
240000005852 Mimosa quadrivalvis Species 0.000 description 1
BACYUWVYYTXETD-UHFFFAOYSA-N N-Lauroylsarcosine Chemical compound CCCCCCCCCCCC(=O)N(C)CC(O)=O BACYUWVYYTXETD-UHFFFAOYSA-N 0.000 description 1
AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
FSYKKLYZXJSNPZ-UHFFFAOYSA-N N-methylaminoacetic acid Natural products C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
DIOYAVUHUXAUPX-KHPPLWFESA-N Oleoyl sarcosine Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CC(O)=O DIOYAVUHUXAUPX-KHPPLWFESA-N 0.000 description 1
241000282320 Panthera leo Species 0.000 description 1
CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
108010081873 Persil Proteins 0.000 description 1
229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
108010077895 Sarcosine Proteins 0.000 description 1
244000000231 Sesamum indicum Species 0.000 description 1
235000003434 Sesamum indicum Nutrition 0.000 description 1
239000004280 Sodium formate Substances 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000004480 active ingredient Substances 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000003545 alkoxy group Chemical group 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
125000003277 amino group Chemical group 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
230000000386 athletic effect Effects 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
MKUWVMRNQOOSAT-UHFFFAOYSA-N but-3-en-2-ol Chemical compound CC(O)C=C MKUWVMRNQOOSAT-UHFFFAOYSA-N 0.000 description 1
150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
125000002843 carboxylic acid group Chemical group 0.000 description 1
238000007906 compression Methods 0.000 description 1
230000006835 compression Effects 0.000 description 1
230000001143 conditioned effect Effects 0.000 description 1
239000000470 constituent Substances 0.000 description 1
ZFTFAPZRGNKQPU-UHFFFAOYSA-N dicarbonic acid Chemical compound OC(=O)OC(O)=O ZFTFAPZRGNKQPU-UHFFFAOYSA-N 0.000 description 1
RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 1
238000004043 dyeing Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
150000004676 glycans Chemical class 0.000 description 1
159000000011 group IA salts Chemical class 0.000 description 1
229910052739 hydrogen Inorganic materials 0.000 description 1
239000001257 hydrogen Substances 0.000 description 1
150000002433 hydrophilic molecules Chemical class 0.000 description 1
XXROGKLTLUQVRX-UHFFFAOYSA-N hydroxymethylethylene Natural products OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
230000003993 interaction Effects 0.000 description 1
LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
150000005673 monoalkenes Chemical class 0.000 description 1
150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
238000006386 neutralization reaction Methods 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
150000007530 organic bases Chemical class 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
230000020477 pH reduction Effects 0.000 description 1
230000000149 penetrating effect Effects 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
UIIIBRHUICCMAI-UHFFFAOYSA-N prop-2-ene-1-sulfonic acid Chemical compound OS(=O)(=O)CC=C UIIIBRHUICCMAI-UHFFFAOYSA-N 0.000 description 1
238000013102 re-test Methods 0.000 description 1
238000011160 research Methods 0.000 description 1
229940043230 sarcosine Drugs 0.000 description 1
108700004121 sarkosyl Proteins 0.000 description 1
150000004671 saturated fatty acids Chemical class 0.000 description 1
235000003441 saturated fatty acids Nutrition 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 1
235000019254 sodium formate Nutrition 0.000 description 1
239000007787 solid Substances 0.000 description 1
235000002316 solid fats Nutrition 0.000 description 1
235000020354 squash Nutrition 0.000 description 1
238000010186 staining Methods 0.000 description 1
239000012086 standard solution Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
239000001384 succinic acid Substances 0.000 description 1
229950011008 tetrachloroethylene Drugs 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
235000013311 vegetables Nutrition 0.000 description 1
NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical class OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
150000003754 zirconium Chemical class 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/14—Esterification

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
General Chemical & Material Sciences (AREA)
Treatment And Processing Of Natural Fur Or Leather (AREA)
Lubricants (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

JP6502936A 1992-07-14 1993-07-05 新規な革オイリング製剤およびその使用 Pending JPH07508785A (ja)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
DE4223111A DE4223111A1 (de)	1992-07-14	1992-07-14	Neue Lederfettungsmittel und ihre Verwendung
DE4223111.6		1992-07-14
PCT/EP1993/001730 WO1994001587A1 (de)	1992-07-14	1993-07-05	Neue lederfettungsmittel und ihre verwendung

Publications (1)

Publication Number	Publication Date
JPH07508785A true JPH07508785A (ja)	1995-09-28

Family

ID=6463169

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP6502936A Pending JPH07508785A (ja)	1992-07-14	1993-07-05	新規な革オイリング製剤およびその使用

Country Status (7)

Country	Link
US (2)	US5567343A (de)
EP (1)	EP0650530B1 (de)
JP (1)	JPH07508785A (de)
AT (1)	ATE142278T1 (de)
DE (2)	DE4223111A1 (de)
ES (1)	ES2091623T3 (de)
WO (1)	WO1994001587A1 (de)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE4400507A1 (de) *	1994-01-12	1995-07-13	Henkel Kgaa	Mittel zur fettenden Ausrüstung von Leder
DE4405205A1 (de) *	1994-02-18	1995-08-24	Henkel Kgaa	Neue Lederfettungsmittel und ihre Verwendung
DE4432361A1 (de) *	1994-09-12	1996-03-14	Henkel Kgaa	Verwendung von massepolymerisierten Co-Oligomeren zur fettenden Ausrüstung von Leder
DE19625984C2 (de) *	1996-06-28	1999-07-29	Stockhausen Chem Fab Gmbh	Wäßrige Polymerdispersionen, Verfahren zu ihrer Herstellung und ihre Verwendung in der Lederherstellung
US6294103B1 (en)	1996-11-07	2001-09-25	3M Innovative Properties Company	Use of amphiphilic copolymers containing a fluorinated monomer to impart waterproofness to leather
ES2143125T3 (es)	1996-11-07	2000-05-01	Minnesota Mining & Mfg	Uso de copolimeros anfifilicos que contienen un monomero fluorado para impartir impermeabilidad al cuero.
DE19708501A1 (de) *	1997-03-03	1998-09-10	Henkel Kgaa	Verwendung von Polymeren zur fettenden Ausrüstung von Leder
US7049379B2 (en)	1999-05-11	2006-05-23	3M Innovative Properties Company	Alkylated fluorochemical oligomers and use thereof in the treatment of fibrous substrates
US6525127B1 (en)	1999-05-11	2003-02-25	3M Innovative Properties Company	Alkylated fluorochemical oligomers and use thereof in the treatment of fibrous substrates
DE19942681B4 (de) *	1999-09-07	2006-04-27	Dr. Th. Böhme KG Chem. Fabrik GmbH & Co	Copolymer zur Behandlung von Leder und Pelzfellen
US6753369B2 (en)	2001-10-16	2004-06-22	Buckman Laboratories International, Inc.	Leather waterproofing formulation and leather goods waterproofed therewith
EP2045276A1 (de) *	2007-10-05	2009-04-08	E.I. Du Pont De Nemours And Company	Fluorpolymer

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE1669347A1 (de) *	1967-03-25	1971-05-06	Henkel & Cie Gmbh	Verfahren zum Fetten von Leder
DE3507241A1 (de) *	1985-03-01	1986-09-04	Henkel KGaA, 4000 Düsseldorf	Verfahren zur herstellung wasserdichter leder oder pelze
DE3529869A1 (de) *	1985-08-21	1987-02-26	Basf Ag	Verfahren zum hydrophobieren von leder und pelzen
DE3816103A1 (de) *	1988-05-11	1989-11-23	Henkel Kgaa	Verbesserter haftgrund fuer lederzurichtungen
JPH02149509A (ja) *	1988-12-01	1990-06-08	Nippon Oil & Fats Co Ltd	化粧用微粒子粉体
TNSN89128A1 (fr) *	1988-12-02	1991-02-04	Rohn And Haas Company Independance Mall West	Traitement du cuir avec des copolymeres amphiphites choisis
DE3926167A1 (de) *	1989-08-08	1991-02-14	Basf Ag	Verwendung von copolymerisaten auf basis von langkettigen olefinen und ethylenisch ungesaettigten dicarbonsaeureanhydriden zum hydrophobieren von leder und pelzfellen
DE3931039A1 (de) *	1989-09-16	1991-03-28	Basf Ag	Verwendung von copolymerisaten auf basis von langkettigen ungesaettigten estern und ethylenisch ungesaettigten carbonsaeuren zum hydrophobieren von leder und pelzfellen
DE4129244A1 (de) *	1991-09-03	1993-03-04	Henkel Kgaa	Waessrige dispersionen von neuen amphiphilen co-oligomeren fuer die wasch- und reinigungsbestaendige fettende ausruestung von leder und pelzfellen sowie ihre verwendung

1992
- 1992-07-14 DE DE4223111A patent/DE4223111A1/de not_active Withdrawn
1993
- 1993-07-05 WO PCT/EP1993/001730 patent/WO1994001587A1/de not_active Ceased
- 1993-07-05 AT AT93915795T patent/ATE142278T1/de active
- 1993-07-05 DE DE59303678T patent/DE59303678D1/de not_active Expired - Fee Related
- 1993-07-05 US US08/367,268 patent/US5567343A/en not_active Expired - Fee Related
- 1993-07-05 ES ES93915795T patent/ES2091623T3/es not_active Expired - Lifetime
- 1993-07-05 JP JP6502936A patent/JPH07508785A/ja active Pending
- 1993-07-05 EP EP93915795A patent/EP0650530B1/de not_active Expired - Lifetime
1996
- 1996-06-28 US US08/672,753 patent/US5741434A/en not_active Expired - Fee Related

Also Published As

Publication number	Publication date
ES2091623T3 (es)	1996-11-01
DE4223111A1 (de)	1994-01-20
EP0650530B1 (de)	1996-09-04
WO1994001587A1 (de)	1994-01-20
US5741434A (en)	1998-04-21
EP0650530A1 (de)	1995-05-03
DE59303678D1 (de)	1996-10-10
US5567343A (en)	1996-10-22
ATE142278T1 (de)	1996-09-15

Publication	Publication Date	Title
US5316860A (en)	1994-05-31	Leather treatment selected amphiphilic copolymers
JPH07508785A (ja)	1995-09-28	新規な革オイリング製剤およびその使用
JP3295080B2 (ja)	2002-06-24	革および皮の耐洗濯および耐クリーニング性オイリング用の新規な両親和性コオリゴマーの水性分散体およびその使用
JPH0376800A (ja)	1991-04-02	皮革及び原皮の撥水加工法
JPH0841130A (ja)	1996-02-13	エチレン性不飽和ジカルボン酸無水物、長鎖オレフィンおよびフルオロオレフィンを構成成分として有するコポリマー
JP2000507628A (ja)	2000-06-20	エチレン系不飽和ジカルボン酸又はジカルボン酸無水物、低級オレフィン及び疎水性コモノマーをベースとするコポリマーの、皮革及び毛皮の後なめし、加脂又は疎水性化のための使用
KR0154106B1 (ko)	1998-11-16	폴리실록산 단위를 포함하는 공중합체를 사용하여 가죽 및 모피를 처리하는 방법
US5728313A (en)	1998-03-17	Leather oiling compositions and their use
US5330537A (en)	1994-07-19	Leather treatment selected amphiphilic copolymer
JPH07508784A (ja)	1995-09-28	新規な革オイリング製剤およびその使用（２）
JP3907702B2 (ja)	2007-04-18	水性ポリマー分散液、その調製方法及び革の製造にそれを使用する方法
KR100292208B1 (ko)	2001-10-24	에틸렌계불포화카복실산과에틸렌계불포화지방산유도체의공중합체의염,이의제조방법,및이를포함하는가지제및이의제조방법
US5683611A (en)	1997-11-04	Preparations for the oiling of leather
JPH09510490A (ja)	1997-10-21	ダイマーおよび／またはトリマーアミノプロピオン酸の革類のオイリング仕上げへの使用
CN115181216B (zh)	2023-09-26	一种复鞣剂及其制备方法
JPH09510491A (ja)	1997-10-21	革類をオイリング仕上げするためのアルキレンジアミノテトラプロピオン酸の使用
CN1276017A (zh)	2000-12-06	两性全氟烷基改性的聚二烯及其在皮革处理中的应用
JP2000501444A (ja)	2000-02-08	革加脂用のケイ素含有ターポリマーの使用
WO1996020962A1 (en)	1996-07-11	Copolymer of vinyl sulfonic acid and method for treating leather
KR20080021113A (ko)	2008-03-06	가죽의 제조 방법