JPH08192501A - Protective film for synthetic resin panel - Google Patents

Protective film for synthetic resin panel

Info

Publication number
JPH08192501A
JPH08192501A JP7022343A JP2234395A JPH08192501A JP H08192501 A JPH08192501 A JP H08192501A JP 7022343 A JP7022343 A JP 7022343A JP 2234395 A JP2234395 A JP 2234395A JP H08192501 A JPH08192501 A JP H08192501A
Authority
JP
Japan
Prior art keywords
protective film
synthetic resin
resin plate
film
density polyethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7022343A
Other languages
Japanese (ja)
Inventor
Naoharu Yoshii
直治 吉井
Katsutoshi Kono
勝俊 河野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Chemical Industry Co Ltd filed Critical Asahi Chemical Industry Co Ltd
Priority to JP7022343A priority Critical patent/JPH08192501A/en
Publication of JPH08192501A publication Critical patent/JPH08192501A/en
Pending legal-status Critical Current

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Abstract

PURPOSE: To provide a protective film for a thermal molding synthetic resin panel capable of being thermally molded in such a state that the protective film is bonded. CONSTITUTION: A protective film consists of a low density polyethylene layer with an MI of 5.0-0.1g/10min and density of 0.910-0.935g/cm<3> and an EVA layer with an MI of 5.0-0.1g/10min and vinyl acetate content of 5-15% and the haze thereof is 15% or less.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は加熱成形される合成樹脂
板の保護フィルムに関する。更に詳しくは、本発明は、
合成樹脂板を加熱成形する際に、保護フィルムを貼着し
たままでも保護フィルムが軟化し装置等に粘着すること
なく加熱成形可能であり、かつ加熱成形後に保護フィル
ムを剥離することなく検査可能で、更に容易に剥離可能
な加熱成形用合成樹脂板保護フィルムに関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a protective film for heat-molding synthetic resin plates. More specifically, the present invention provides
When a synthetic resin plate is thermoformed, it can be thermoformed without the protective film softening and sticking to the device even when the protective film is attached, and it can be inspected without peeling off the protective film after thermoforming. The present invention relates to a synthetic resin plate protective film for thermoforming, which can be peeled off more easily.

【0002】[0002]

【従来の技術】合成樹脂板用保護フィルムは、従来より
アクリル板やポリカーボネート板等の表面に取扱の際の
傷付きを防止するために使用されている。
2. Description of the Related Art Protective films for synthetic resin plates have hitherto been used for preventing scratches on the surfaces of acrylic plates, polycarbonate plates and the like during handling.

【0003】[0003]

【発明が解決しようとする課題】しかしながら、保護フ
ィルムを貼着したままの合成樹脂板を加熱成形に供する
と成形作業中に保護フィルムが溶融し作業者の衣服や装
置等に粘着したり、成形を終えたあとで成形品の表面に
保護フィルムが固着したり、粘着層のEVA樹脂が成形
品に付着したり、あるいは成形作業の出来ばえを保護フ
ィルムの外部からは検査できなくなるなどの問題があっ
た。
However, when the synthetic resin plate with the protective film attached is subjected to heat molding, the protective film melts during the molding work and sticks to the worker's clothes or equipment, or is molded. After finishing, there is a problem that the protective film adheres to the surface of the molded product, the EVA resin of the adhesive layer adheres to the molded product, and the quality of the molding work cannot be inspected from the outside of the protective film. It was

【0004】このために、加熱成形される樹脂板が傷付
けられることのないように、加工工程の最終まで合成樹
脂板に貼合され保護する機能を果たし、不用時に容易に
ハクリすることのできる保護フィルムが望まれてきた。
Therefore, in order to prevent the heat-molded resin plate from being damaged, the resin plate is bonded to the synthetic resin plate until the end of the processing step so as to protect the resin plate and can be easily peeled off when not in use. Film has been desired.

【0005】[0005]

【課題を解決するための手段】本発明者は上記課題につ
いて種々検討した結果、特定範囲のMI値、密度値を有
する低密度ポリエチレン層と特定範囲の酢酸ビニル含量
値を有するEAV層とを特定範囲のヘイズ値となるよう
に、ポリエチレンのMI、密度;EVAの酢酸ビニル含
量並びに両層の厚み等を選択し・積層することにより、
上記課題が解決されることを見出し、本発明を完成する
に至った。すなわち、本発明は: 、 MI 5.0〜0.1g/10分、密度 0.9
10〜0.935g/cm3 よりなる低密度ポリエチレ
ン層と、MI 5.0〜0.1g/10分、酢酸ビニル
含量 5〜15%よりなるEVA層よりなり、フィルム
ヘイズが15%以下である多層構造の加熱成形用合成樹
脂板保護フィルムに関する。また、 に記載の合成樹脂板保護フィルムを貼着した加熱
成形用アクリル樹脂板に関する。
As a result of various studies on the above problems, the present inventor identified a low density polyethylene layer having an MI value and a density value within a specific range and an EAV layer having a vinyl acetate content value within a specific range. By selecting and laminating the MI of polyethylene, the density; the vinyl acetate content of EVA, the thickness of both layers, etc. so that the haze value in the range is obtained.
The inventors have found that the above problems can be solved and completed the present invention. That is, the present invention is: MI 5.0-0.1 g / 10 minutes, density 0.9
A low-density polyethylene layer composed of 10 to 0.935 g / cm 3 and an EVA layer composed of MI 5.0 to 0.1 g / 10 min and a vinyl acetate content of 5 to 15%, and a film haze of 15% or less. The present invention relates to a synthetic resin plate protective film for multi-layered thermoforming. Further, the present invention relates to an acrylic resin plate for thermoforming, to which the synthetic resin plate protective film described in 1 is attached.

【0006】以下、本発明を具体的に説明する。本発明
に使用される低密度ポリエチレンは、線状低密度ポリエ
チレン(LL)、分岐状低密度ポリエチレン(LD)の
単独またはこれらのブレンド物である。分岐状低密度ポ
リエチレン(LD:いわゆる高圧法ポリエチレン)の使
用が耐熱性の観点から好ましい。線状低密度ポリエチレ
ンとしては、エチレンの単独重合体又はエチレンと炭素
数4〜10の範囲にあるα−オレフィンとの共重合体で
あり、好ましくは炭素数6〜8のα−オレフィンとの共
重合体であり、これらの1種又は2種以上の混合組成で
もよい。
The present invention will be specifically described below. The low density polyethylene used in the present invention is a linear low density polyethylene (LL), a branched low density polyethylene (LD), or a blend thereof. The use of branched low-density polyethylene (LD: so-called high-pressure polyethylene) is preferable from the viewpoint of heat resistance. The linear low-density polyethylene is a homopolymer of ethylene or a copolymer of ethylene and an α-olefin having a carbon number of 4 to 10, preferably a copolymer of an α-olefin having 6 to 8 carbon atoms. It is a polymer and may have a mixed composition of one kind or two or more kinds thereof.

【0007】α−オレフィンの種類としては、1−ブテ
ン、1−ペンテン、1−ヘキセン、4−メチル−1−ペ
ンテン、1−ヘプテン、1−オクテン、1−デセン等が
ある。線状低密度ポリエチレンとしてエチレンと1−ブ
テンとの共重合体、エチレンと1−ヘキセンとの共重合
体の使用が好ましい。
Examples of the α-olefin include 1-butene, 1-pentene, 1-hexene, 4-methyl-1-pentene, 1-heptene, 1-octene, 1-decene and the like. As the linear low density polyethylene, it is preferable to use a copolymer of ethylene and 1-butene, or a copolymer of ethylene and 1-hexene.

【0008】本発明で使用される低密度ポリエチレンは
密度 0.910〜0.935g/c13 、好ましくは
0.915〜0.925g/cm3 、MI 5.0〜
0.1g/10分、好ましくは2.0〜0.2g/10
分、更に好ましくは1.0〜0.3g/10分である。
密度が0.910g/cm3 より低いと加熱成形時にフ
ィルムが軟化し作業者の衣服や、成形装置等に粘着する
場合があり好ましくない。密度が0.935g/cm3
より高い場合は、フィルムの透明性が低下し加熱成形後
の検査が困難な場合があり好ましくない。MIが0.1
g/10分より低い場合はフィルム成形が困難となる場
合があり、MIが5.0g/10分より高い場合は加熱
成形時フィルムが軟化し、成形作業が困難になる場合が
あり好ましくない。
[0008] low-density polyethylene used in the present invention has a density 0.910 to 0.935 g / c1 3, preferably 0.915~0.925g / cm 3, MI 5.0~
0.1 g / 10 minutes, preferably 2.0-0.2 g / 10
Min, more preferably 1.0 to 0.3 g / 10 min.
If the density is lower than 0.910 g / cm 3 , the film may be softened during heat molding and may stick to the clothes of a worker, a molding apparatus or the like, which is not preferable. Density is 0.935 g / cm 3
If it is higher than the above range, the transparency of the film is lowered and the inspection after the heat molding may be difficult, which is not preferable. MI is 0.1
If it is lower than g / 10 minutes, it may be difficult to form the film, and if MI is higher than 5.0 g / 10 minutes, the film may be softened at the time of heat forming and the forming operation may be difficult, which is not preferable.

【0009】本発明で使用されるEVAはMI 5.0
〜0.1g/10分、好ましくは2.0〜0.2g/1
0分、更に好ましくは1.0〜0.3g/10分、酢酸
ビニル含有量3〜15%、好ましくは、5〜13%であ
る。MIが0.1g/10分より低い場合はフィルム成
形が困難となる場合があり、MIが5.0g/10分よ
り高い場合は加熱成形後の保護フィルムのハクリが困難
になる場合があり好ましくない。酢酸ビニル含量が3%
より低い場合は合成樹脂板との粘着性が不十分な場合が
あり、15%より高い場合は合成樹脂板よりのハクリが
困難な場合があり好ましくない。
The EVA used in the present invention is MI 5.0.
~ 0.1 g / 10 minutes, preferably 2.0-0.2 g / 1
0 minutes, more preferably 1.0 to 0.3 g / 10 minutes, and the vinyl acetate content is 3 to 15%, preferably 5 to 13%. When the MI is lower than 0.1 g / 10 minutes, it may be difficult to form the film, and when the MI is higher than 5.0 g / 10 minutes, peeling of the protective film after heat molding may be difficult, which is preferable. Absent. Vinyl acetate content is 3%
If it is lower, the adhesiveness to the synthetic resin plate may be insufficient, and if it is higher than 15%, peeling from the synthetic resin plate may be difficult, which is not preferable.

【0010】低密度ポリエチレン層とEVA層の厚み
は、特に制限されないが、作業性等の点より低密度ポリ
エチレン層は20〜100μ、EVA層は5〜20μが
好ましい。本発明の多層フィルムのヘイズは15%以
下、好ましくは10%以下である。ヘイズが15%より
大きいと、加熱成形後の樹脂板の検査を保護フィルムと
貼合したままでは困難な場合があり好ましくない。
The thicknesses of the low-density polyethylene layer and the EVA layer are not particularly limited, but from the viewpoint of workability, the low-density polyethylene layer is preferably 20-100 μm, and the EVA layer is preferably 5-20 μm. The haze of the multilayer film of the present invention is 15% or less, preferably 10% or less. If the haze is more than 15%, it may be difficult to inspect the resin plate after the thermoforming with the protective film attached, which is not preferable.

【0011】なお、本発明においては、低密度ポリエチ
レンの密度、MI等;EVAの酢酸ビニル含量等;両層
の厚み等のパラメータを種々選択して、両層を積層した
場合にヘイズ値が15%以下の特定値なるようにするこ
とが重要である。本発明の複合フィルムを製造するに
は、両フィルムを共押出してラミネートしても良いし、
また両フィルムを公知の接着剤を介して積層するなど公
知の積層法を適用できる。
In the present invention, various parameters such as the density of low-density polyethylene, MI, etc .; vinyl acetate content of EVA, etc .; thickness of both layers are selected to obtain a haze value of 15 when both layers are laminated. It is important to have a specific value below%. To produce the composite film of the present invention, both films may be coextruded and laminated,
Further, a known laminating method such as laminating both films via a known adhesive can be applied.

【0012】本発明で使用する低密度ポリエチレン及び
EVAには、酸化防止剤、滑剤、アンチブロッキング
剤、紫外線吸収剤、帯電防止剤、防曇剤、顔料等の添加
剤を使用しても良い。本発明で云う加熱成形とは雰囲気
温度100℃以上での加工を云う。雰囲気温度が100
℃より低い場合は特に大きな問題とはならない。
The low density polyethylene and EVA used in the present invention may contain additives such as an antioxidant, a lubricant, an antiblocking agent, an ultraviolet absorber, an antistatic agent, an antifogging agent and a pigment. The thermoforming referred to in the present invention means processing at an ambient temperature of 100 ° C. or higher. Ambient temperature is 100
If it is lower than ℃, it does not cause a big problem.

【0013】[0013]

【実施例】以下、実施例及び比較例によって本発明を詳
細に説明するが、これらは本発明の範囲を制限しない。 (実施例1)口径100mmφのダイス内接着タイプの
二層共押出フィルム用ダイスの外層となる供給口には、
口径50mmφ、L/D=26の押出機を接続し、内層
となる供給口には、口径50mmφ、L/D=28の押
出機を接続し、表1に示した分岐状低密度ポリエチレン
とEVAを使用して、分岐状低密度ポリエチレン層の厚
さが50μ、EVA層の厚さを10μにして複合フィル
ムを製膜した。フィルムのヘイズは、(株)村上色彩技
研所製HM100型のヘイズメーターで測定した。その
測定結果を表1に示した。
The present invention will be described in detail below with reference to Examples and Comparative Examples, but these do not limit the scope of the present invention. (Example 1) A supply port serving as an outer layer of a die for a two-layer coextrusion film of an adhesive type in a die having a diameter of 100 mmφ,
An extruder with a diameter of 50 mmφ and L / D = 26 was connected, and an extruder with a diameter of 50 mmφ and L / D = 28 was connected to the inner layer supply port. The branched low-density polyethylene and EVA shown in Table 1 Was used to form a composite film with the branched low-density polyethylene layer having a thickness of 50 μ and the EVA layer having a thickness of 10 μ. The haze of the film was measured by a HM100 type haze meter manufactured by Murakami Color Research Laboratory. The measurement results are shown in Table 1.

【0014】次に、このフィルムを、アクリル樹脂押出
板に貼着した。このアクリル板を180℃に加熱した熱
風循環炉にて3分加熱後、プレス型により絞り部の直径
が200mm、深さが50mmのシルクハット状の成形
品を作成した。次にこの成形品の曲げ加工状態を目視で
検査し、冷却後保護フィルムを剥離した。この結果を表
1に示した。
Next, this film was attached to an acrylic resin extruded plate. This acrylic plate was heated for 3 minutes in a hot-air circulating furnace heated to 180 ° C., and then a top hat-shaped molded product having a diameter of the drawn portion of 200 mm and a depth of 50 mm was prepared by a press die. Next, the bent state of this molded product was visually inspected, and after cooling, the protective film was peeled off. The results are shown in Table 1.

【0015】(実施例2〜6)表1に示す樹脂を使用し
た以外は実施例1と同様に行った。 (実施例7)分岐状低密度ポリエチレンをエチレンと1
−ブテンとの共重合体に代えた以外は実施例1と同様に
行った。 (実施例8)分岐状低密度ポリエチレンをエチレンと1
−ヘキセンの共重合体に代えた以外は実施例1と同様に
行った。 (比較例1〜5)表1に示す樹脂を使用した以外は実施
例1と同様に行った。複合フィルムのヘイズ値は、AS
TM規格D−1003に基いて設計された(株)村上色
彩技術研究所製 HM−100型により測定した。測定
はフィルムよりサンプル(40mm×40mm)を5サ
ンプル採取し、5サンプルの測定値の平均値を該フィル
ムのヘイズとした。
(Examples 2 to 6) The same procedure as in Example 1 was carried out except that the resins shown in Table 1 were used. (Example 7) A branched low-density polyethylene was mixed with ethylene and 1
-The same procedure as in Example 1 was repeated except that the copolymer with butene was used instead. (Example 8) Branched low-density polyethylene was mixed with ethylene and 1
-A procedure similar to that of Example 1 was performed except that a hexene copolymer was used. (Comparative Examples 1 to 5) The same procedure as in Example 1 was carried out except that the resins shown in Table 1 were used. The haze value of the composite film is AS
It was measured by HM-100 model manufactured by Murakami Color Research Laboratory Co., Ltd. designed based on TM standard D-1003. For the measurement, 5 samples (40 mm × 40 mm) were taken from the film, and the average value of the measured values of the 5 samples was taken as the haze of the film.

【0016】[0016]

【表1】 [Table 1]

【0017】(註) ※1 ○:粘着性なし、×:粘着性あり。 ※2 ○:容易に剥離、×:成形品に固着。 ※3 ○:検査可能、 ×:検査不可。 ※4 ○:粘着性あり、×:粘着せず。(Note) * 1 ○: No tackiness, ×: There is tackiness. * 2 ○: Easy peeling, ×: Sticking to the molded product. * 3 ○: Inspection is possible, ×: Inspection is not possible. * 4 ○: Adhesive, ×: Not adhered.

【0018】[0018]

【発明の効果】本発明のフィルムは、合成樹脂板を加熱
成形する際に、保護フィルムを貼着したまま加工、検査
が可能であり、かつ不用時には容易にハクリ可能な加熱
成形用合成樹脂板の保護フィルムを提供することにあ
る。
INDUSTRIAL APPLICABILITY The film of the present invention can be processed and inspected while the protective film is still attached when the synthetic resin plate is thermoformed, and can be easily peeled off when not in use. Is to provide a protective film.

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 MI 5.0〜0.1g/10分、密度
0.910〜0.935g/cm3 よりなる低密度ポ
リエチレン層と、MI 5.0〜0.1g/10分、酢
酸ビニル含量 5〜15%よりなるエチレン−酢酸ビニ
ル系共重合体(以下、EVAと略称する)層よりなり、
フィルムヘイズ値が15%以下であることを特徴とす
る、多層構造の加熱成形用合成樹脂板保護フィルム。
1. A low-density polyethylene layer having an MI of 5.0 to 0.1 g / 10 min and a density of 0.910 to 0.935 g / cm 3 , and an MI of 5.0 to 0.1 g / 10 min, vinyl acetate. An ethylene-vinyl acetate copolymer (hereinafter referred to as EVA) layer having a content of 5 to 15%,
A heat-moldable synthetic resin plate protective film having a multilayer structure, which has a film haze value of 15% or less.
【請求項2】 請求項1に記載の合成樹脂板保護フィル
ムを貼着した加熱成形用アクリル樹脂板。
2. An acrylic resin plate for thermoforming, to which the synthetic resin plate protective film according to claim 1 is adhered.
JP7022343A 1995-01-18 1995-01-18 Protective film for synthetic resin panel Pending JPH08192501A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7022343A JPH08192501A (en) 1995-01-18 1995-01-18 Protective film for synthetic resin panel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7022343A JPH08192501A (en) 1995-01-18 1995-01-18 Protective film for synthetic resin panel

Publications (1)

Publication Number Publication Date
JPH08192501A true JPH08192501A (en) 1996-07-30

Family

ID=12080045

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7022343A Pending JPH08192501A (en) 1995-01-18 1995-01-18 Protective film for synthetic resin panel

Country Status (1)

Country Link
JP (1) JPH08192501A (en)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5181885A (en) * 1975-01-13 1976-07-17 Nippon Unicar Co Ltd
JPS54133578A (en) * 1978-04-10 1979-10-17 Showa Denko Kk Laminated film
JPH0174248U (en) * 1987-11-06 1989-05-19
JPH05229082A (en) * 1992-02-25 1993-09-07 Toray Gosei Film Kk Surface protective film
JPH06145616A (en) * 1992-11-10 1994-05-27 Sekisui Chem Co Ltd Surface-protection film
JPH06155686A (en) * 1992-11-20 1994-06-03 Mitsubishi Plastics Ind Ltd Protective film for thermoplastic resin sheet
JPH06279742A (en) * 1993-03-26 1994-10-04 Sekisui Chem Co Ltd Surface protection film
JPH06328632A (en) * 1993-05-24 1994-11-29 Nippon Unicar Co Ltd Co-extruded adhesive film

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5181885A (en) * 1975-01-13 1976-07-17 Nippon Unicar Co Ltd
JPS54133578A (en) * 1978-04-10 1979-10-17 Showa Denko Kk Laminated film
JPH0174248U (en) * 1987-11-06 1989-05-19
JPH05229082A (en) * 1992-02-25 1993-09-07 Toray Gosei Film Kk Surface protective film
JPH06145616A (en) * 1992-11-10 1994-05-27 Sekisui Chem Co Ltd Surface-protection film
JPH06155686A (en) * 1992-11-20 1994-06-03 Mitsubishi Plastics Ind Ltd Protective film for thermoplastic resin sheet
JPH06279742A (en) * 1993-03-26 1994-10-04 Sekisui Chem Co Ltd Surface protection film
JPH06328632A (en) * 1993-05-24 1994-11-29 Nippon Unicar Co Ltd Co-extruded adhesive film

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