JPH08510268A - リパーゼを含有する洗浄および清浄製剤 - Google Patents

リパーゼを含有する洗浄および清浄製剤

Info

Publication number: JPH08510268A
Authority: JP; Japan
Prior art keywords: weight; cleaning; alkyl; water; nonionic surfactant
Prior art date: 1993-05-12
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Ceased

Application number

JP6523604A

Other languages

English (en)

Japanese (ja)

Inventor

マイネ、ゲオルグ

ズング、エリック

Original Assignee

ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチェン

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1993-05-12

Filing date

1994-05-03

Publication date

1996-10-29

1994-05-03 Application filed by ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチェン filed Critical ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチェン

1996-10-29 Publication of JPH08510268A publication Critical patent/JPH08510268A/ja

Status Ceased legal-status Critical Current

Links

238000004140 cleaning Methods 0.000 title claims abstract description 111
239000000203 mixture Substances 0.000 title claims abstract description 85
239000004367 Lipase Substances 0.000 title claims abstract description 23
102000004882 Lipase Human genes 0.000 title claims abstract description 23
108090001060 Lipase Proteins 0.000 title claims abstract description 23
235000019421 lipase Nutrition 0.000 title claims abstract description 23
238000009472 formulation Methods 0.000 title abstract description 6
239000002736 nonionic surfactant Substances 0.000 claims abstract description 36
229930182470 glycoside Natural products 0.000 claims abstract description 27
125000000217 alkyl group Chemical group 0.000 claims abstract description 25
102000004190 Enzymes Human genes 0.000 claims abstract description 24
108090000790 Enzymes Proteins 0.000 claims abstract description 24
239000004094 surface-active agent Substances 0.000 claims abstract description 18
150000002338 glycosides Chemical class 0.000 claims abstract description 16
125000003342 alkenyl group Chemical group 0.000 claims abstract description 10
125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 claims abstract description 4
-1 alkenyl sulphates Chemical class 0.000 claims description 33
239000003945 anionic surfactant Substances 0.000 claims description 23
229940088598 enzyme Drugs 0.000 claims description 23
239000007788 liquid Substances 0.000 claims description 16
235000014113 dietary fatty acids Nutrition 0.000 claims description 15
239000000194 fatty acid Substances 0.000 claims description 15
229930195729 fatty acid Natural products 0.000 claims description 15
150000003839 salts Chemical class 0.000 claims description 15
239000007844 bleaching agent Substances 0.000 claims description 14
239000000344 soap Substances 0.000 claims description 13
108091005804 Peptidases Proteins 0.000 claims description 10
239000004365 Protease Substances 0.000 claims description 10
RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
150000004665 fatty acids Chemical class 0.000 claims description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
125000004432 carbon atom Chemical group C* 0.000 claims description 8
102000035195 Peptidases Human genes 0.000 claims description 7
239000012190 activator Substances 0.000 claims description 7
239000002904 solvent Substances 0.000 claims description 7
229910021653 sulphate ion Inorganic materials 0.000 claims description 7
108010065511 Amylases Proteins 0.000 claims description 5
102000013142 Amylases Human genes 0.000 claims description 5
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 5
235000019418 amylase Nutrition 0.000 claims description 5
239000006260 foam Substances 0.000 claims description 5
229940025131 amylases Drugs 0.000 claims description 4
108010084185 Cellulases Proteins 0.000 claims description 3
102000005575 Cellulases Human genes 0.000 claims description 3
229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 3
150000008041 alkali metal carbonates Chemical class 0.000 claims description 3
230000000694 effects Effects 0.000 claims description 3
239000008187 granular material Substances 0.000 claims description 3
238000006384 oligomerization reaction Methods 0.000 claims description 3
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 2
150000003973 alkyl amines Chemical class 0.000 claims description 2
150000002009 diols Chemical group 0.000 claims description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims 1
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230000000087 stabilizing effect Effects 0.000 claims 1
239000004615 ingredient Substances 0.000 abstract description 6
238000003860 storage Methods 0.000 abstract description 4
239000012467 final product Substances 0.000 abstract 1
239000003599 detergent Substances 0.000 description 35
239000002253 acid Substances 0.000 description 23
238000000034 method Methods 0.000 description 16
239000000178 monomer Substances 0.000 description 11
150000007513 acids Chemical class 0.000 description 10
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
239000011734 sodium Substances 0.000 description 8
IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 7
229910052783 alkali metal Inorganic materials 0.000 description 7
150000001732 carboxylic acid derivatives Chemical class 0.000 description 7
150000002191 fatty alcohols Chemical class 0.000 description 7
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 7
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical class C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 6
229920002472 Starch Polymers 0.000 description 6
150000001298 alcohols Chemical class 0.000 description 6
229910052910 alkali metal silicate Inorganic materials 0.000 description 6
239000003795 chemical substances by application Substances 0.000 description 6
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 6
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 6
239000008107 starch Substances 0.000 description 6
235000019698 starch Nutrition 0.000 description 6
229920001897 terpolymer Polymers 0.000 description 6
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
229910000323 aluminium silicate Inorganic materials 0.000 description 5
150000001875 compounds Chemical class 0.000 description 5
239000011976 maleic acid Substances 0.000 description 5
229920000642 polymer Polymers 0.000 description 5
239000002002 slurry Substances 0.000 description 5
229910052708 sodium Inorganic materials 0.000 description 5
239000010457 zeolite Substances 0.000 description 5
241000894006 Bacteria Species 0.000 description 4
241000233866 Fungi Species 0.000 description 4
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 4
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
229910021536 Zeolite Inorganic materials 0.000 description 4
239000007864 aqueous solution Substances 0.000 description 4
230000000052 comparative effect Effects 0.000 description 4
229920001577 copolymer Polymers 0.000 description 4
239000000463 material Substances 0.000 description 4
239000002245 particle Substances 0.000 description 4
150000004760 silicates Chemical class 0.000 description 4
235000000346 sugar Nutrition 0.000 description 4
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 4
MUZDXNQOSGWMJJ-UHFFFAOYSA-N 2-methylprop-2-enoic acid;prop-2-enoic acid Chemical compound OC(=O)C=C.CC(=C)C(O)=O MUZDXNQOSGWMJJ-UHFFFAOYSA-N 0.000 description 3
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
108010059892 Cellulase Proteins 0.000 description 3
SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Chemical group CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 3
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
239000004435 Oxo alcohol Substances 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 3
125000000129 anionic group Chemical group 0.000 description 3
150000001720 carbohydrates Chemical class 0.000 description 3
235000014633 carbohydrates Nutrition 0.000 description 3
239000001768 carboxy methyl cellulose Substances 0.000 description 3
150000001735 carboxylic acids Chemical class 0.000 description 3
229940106157 cellulase Drugs 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
125000005395 methacrylic acid group Chemical group 0.000 description 3
238000002156 mixing Methods 0.000 description 3
125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
239000000843 powder Substances 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 3
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
229920002134 Carboxymethyl cellulose Polymers 0.000 description 2
SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical class CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
239000004115 Sodium Silicate Substances 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
108010056079 Subtilisins Proteins 0.000 description 2
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UYXTWWCETRIEDR-UHFFFAOYSA-N Tributyrin Chemical compound CCCC(=O)OCC(OC(=O)CCC)COC(=O)CCC UYXTWWCETRIEDR-UHFFFAOYSA-N 0.000 description 2
WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
229910052936 alkali metal sulfate Inorganic materials 0.000 description 2
150000001340 alkali metals Chemical group 0.000 description 2
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SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 2
WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
238000004061 bleaching Methods 0.000 description 2
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UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
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125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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WQZGKKKJIJFFOK-VSOAQEOCSA-N L-altropyranose Chemical compound OC[C@@H]1OC(O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-VSOAQEOCSA-N 0.000 description 1
239000005639 Lauric acid Substances 0.000 description 1
239000005642 Oleic acid Substances 0.000 description 1
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
235000021314 Palmitic acid Nutrition 0.000 description 1
LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
WUGQZFFCHPXWKQ-UHFFFAOYSA-N Propanolamine Chemical compound NCCCO WUGQZFFCHPXWKQ-UHFFFAOYSA-N 0.000 description 1
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
PYMYPHUHKUWMLA-LMVFSUKVSA-N Ribose Natural products OC[C@@H](O)[C@@H](O)[C@@H](O)C=O PYMYPHUHKUWMLA-LMVFSUKVSA-N 0.000 description 1
229920000142 Sodium polycarboxylate Polymers 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
241000187392 Streptomyces griseus Species 0.000 description 1
KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
229930006000 Sucrose Natural products 0.000 description 1
CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 1
239000003082 abrasive agent Substances 0.000 description 1
DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
239000013543 active substance Substances 0.000 description 1
239000001361 adipic acid Substances 0.000 description 1
235000011037 adipic acid Nutrition 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001323 aldoses Chemical class 0.000 description 1
229910001413 alkali metal ion Inorganic materials 0.000 description 1
150000004996 alkyl benzenes Chemical group 0.000 description 1
150000008051 alkyl sulfates Chemical class 0.000 description 1
125000005263 alkylenediamine group Polymers 0.000 description 1
HMFHBZSHGGEWLO-UHFFFAOYSA-N alpha-D-Furanose-Ribose Natural products OCC1OC(O)C(O)C1O HMFHBZSHGGEWLO-UHFFFAOYSA-N 0.000 description 1
WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
SRBFZHDQGSBBOR-STGXQOJASA-N alpha-D-lyxopyranose Chemical compound O[C@@H]1CO[C@H](O)[C@@H](O)[C@H]1O SRBFZHDQGSBBOR-STGXQOJASA-N 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
150000001414 amino alcohols Chemical class 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
PYMYPHUHKUWMLA-WDCZJNDASA-N arabinose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C=O PYMYPHUHKUWMLA-WDCZJNDASA-N 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
230000001580 bacterial effect Effects 0.000 description 1
239000002585 base Substances 0.000 description 1
229940116226 behenic acid Drugs 0.000 description 1
KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
239000011575 calcium Substances 0.000 description 1
159000000007 calcium salts Chemical class 0.000 description 1
150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
150000001733 carboxylic acid esters Chemical class 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
229920003086 cellulose ether Polymers 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000000084 colloidal system Substances 0.000 description 1
239000004064 cosurfactant Substances 0.000 description 1
239000013078 crystal Substances 0.000 description 1
230000001461 cytolytic effect Effects 0.000 description 1
125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
150000001991 dicarboxylic acids Chemical class 0.000 description 1
238000002845 discoloration Methods 0.000 description 1
238000001035 drying Methods 0.000 description 1
239000000975 dye Substances 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
230000009969 flowable effect Effects 0.000 description 1
235000019253 formic acid Nutrition 0.000 description 1
239000003205 fragrance Substances 0.000 description 1
230000002538 fungal effect Effects 0.000 description 1
229930182830 galactose Natural products 0.000 description 1
229920000159 gelatin Polymers 0.000 description 1
235000019322 gelatine Nutrition 0.000 description 1
235000011852 gelatine desserts Nutrition 0.000 description 1
239000003292 glue Substances 0.000 description 1
150000004676 glycans Chemical class 0.000 description 1
150000002334 glycols Chemical class 0.000 description 1
125000001046 glycoluril group Chemical class [H]C12N(*)C(=O)N(*)C1([H])N(*)C(=O)N2* 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
WJRBRSLFGCUECM-UHFFFAOYSA-N hydantoin Chemical compound O=C1CNC(=O)N1 WJRBRSLFGCUECM-UHFFFAOYSA-N 0.000 description 1
229940091173 hydantoin Drugs 0.000 description 1
125000002951 idosyl group Chemical class C1([C@@H](O)[C@H](O)[C@@H](O)[C@H](O1)CO)* 0.000 description 1
230000002779 inactivation Effects 0.000 description 1
238000003780 insertion Methods 0.000 description 1
230000037431 insertion Effects 0.000 description 1
ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
150000002584 ketoses Chemical class 0.000 description 1
235000019626 lipase activity Nutrition 0.000 description 1
159000000003 magnesium salts Chemical class 0.000 description 1
238000005259 measurement Methods 0.000 description 1
108010003855 mesentericopeptidase Proteins 0.000 description 1
229920000609 methyl cellulose Polymers 0.000 description 1
XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
239000001923 methylcellulose Substances 0.000 description 1
108010020132 microbial serine proteinases Proteins 0.000 description 1
239000004200 microcrystalline wax Substances 0.000 description 1
235000019808 microcrystalline wax Nutrition 0.000 description 1
150000002763 monocarboxylic acids Chemical class 0.000 description 1
150000004682 monohydrates Chemical class 0.000 description 1
WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
239000003346 palm kernel oil Substances 0.000 description 1
235000019865 palm kernel oil Nutrition 0.000 description 1
BXRNXXXXHLBUKK-UHFFFAOYSA-N piperazine-2,5-dione Chemical compound O=C1CNC(=O)CN1 BXRNXXXXHLBUKK-UHFFFAOYSA-N 0.000 description 1
229920001521 polyalkylene glycol ether Polymers 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920001282 polysaccharide Polymers 0.000 description 1
239000005017 polysaccharide Substances 0.000 description 1
239000001267 polyvinylpyrrolidone Substances 0.000 description 1
229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
230000002028 premature Effects 0.000 description 1
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical class CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
238000007127 saponification reaction Methods 0.000 description 1
150000004671 saturated fatty acids Chemical class 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
SZHIIIPPJJXYRY-UHFFFAOYSA-M sodium;2-methylprop-2-ene-1-sulfonate Chemical compound [Na+].CC(=C)CS([O-])(=O)=O SZHIIIPPJJXYRY-UHFFFAOYSA-M 0.000 description 1
239000007921 spray Substances 0.000 description 1
238000005507 spraying Methods 0.000 description 1
230000006641 stabilisation Effects 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
239000005720 sucrose Substances 0.000 description 1
NVBFHJWHLNUMCV-UHFFFAOYSA-N sulfamide Chemical compound NS(N)(=O)=O NVBFHJWHLNUMCV-UHFFFAOYSA-N 0.000 description 1
230000001180 sulfating effect Effects 0.000 description 1
239000011593 sulfur Substances 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
XTHPWXDJESJLNJ-UHFFFAOYSA-N sulfurochloridic acid Chemical compound OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
239000003760 tallow Substances 0.000 description 1
108010075550 termamyl Proteins 0.000 description 1
TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical class CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
150000004685 tetrahydrates Chemical class 0.000 description 1
150000003852 triazoles Chemical class 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000001993 wax Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38627—Preparations containing enzymes, e.g. protease or amylase containing lipase
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38663—Stabilised liquid enzyme compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Molecular Biology (AREA)
Detergent Compositions (AREA)
Enzymes And Modification Thereof (AREA)

JP6523604A 1993-05-12 1994-05-03 リパーゼを含有する洗浄および清浄製剤 Ceased JPH08510268A (ja)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
DE4315854A DE4315854A1 (de)	1993-05-12	1993-05-12	Lipasehaltige Wasch- und Reinigungsmittel
DE4315854.4		1993-05-12
PCT/EP1994/001400 WO1994026861A1 (de)	1993-05-12	1994-05-03	Lipasehaltige wasch- und reinigungsmittel

Publications (1)

Publication Number	Publication Date
JPH08510268A true JPH08510268A (ja)	1996-10-29

Family

ID=6487905

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP6523604A Ceased JPH08510268A (ja)	1993-05-12	1994-05-03	リパーゼを含有する洗浄および清浄製剤

Country Status (6)

Country	Link
EP (1)	EP0698079B1 (de)
JP (1)	JPH08510268A (de)
AT (1)	ATE157698T1 (de)
DE (2)	DE4315854A1 (de)
ES (1)	ES2108456T3 (de)
WO (1)	WO1994026861A1 (de)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2016535811A (ja) *	2013-09-30	2016-11-17	エンサバイオテックアクチエボラグＥｎｚａＢｉｏｔｅｃｈＡｂ	界面活性剤組成物
JP2017071664A (ja) *	2015-10-05	2017-04-13	花王株式会社	衣料用液体洗浄剤組成物
JP2021507971A (ja) *	2017-12-20	2021-02-25	ビーエイエスエフ・ソシエタス・エウロパエアＢａｓｆＳｅ	繊維製品に付着した、融解温度が３０℃超のである脂肪化合物を除去するための洗濯用配合物

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE4344154A1 (de) *	1993-12-23	1995-06-29	Henkel Kgaa	Enzymhaltiges Flüssigwaschmittel
DE4411349A1 (de) *	1994-03-31	1995-10-05	Henkel Kgaa	Lipasehaltiges Textilwaschmittel
WO1997043375A1 (en) *	1996-05-15	1997-11-20	The Procter & Gamble Company	Detergent compositions comprising specific lipolytic enzyme and a specific surfactant system
WO1997043377A1 (en) *	1996-05-15	1997-11-20	The Procter & Gamble Company	Detergent compositions comprising specific lipolytic enzyme and alkyl poly glucoside surfactant
DE19928922A1 (de) *	1999-06-24	2000-12-28	Cognis Deutschland Gmbh	Schaumkontrollierte feste Waschmittel
US20120315689A1 (en) *	2009-12-21	2012-12-13	Danisco Us Inc.	Surfactants that improve the cleaning of lipid-based stains treated with lipases
EP4438707A4 (de) *	2021-11-24	2025-11-19	SkyLab AG	Biologisch abbaubare waschmittelzusammensetzung auf lipasebasis

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO1986005187A1 (en) *	1985-03-07	1986-09-12	A.E. Staley Manufacturing Company	Detergent composition containing an enzyme and a glycoside surfactant
US4959179A (en) *	1989-01-30	1990-09-25	Lever Brothers Company	Stabilized enzymes liquid detergent composition containing lipase and protease
DE4034840A1 (de) *	1990-11-02	1992-05-07	Henkel Kgaa	Enzymatisches fluessigwaschmittel

1993
- 1993-05-12 DE DE4315854A patent/DE4315854A1/de not_active Withdrawn
1994
- 1994-05-03 WO PCT/EP1994/001400 patent/WO1994026861A1/de not_active Ceased
- 1994-05-03 EP EP94916185A patent/EP0698079B1/de not_active Expired - Lifetime
- 1994-05-03 ES ES94916185T patent/ES2108456T3/es not_active Expired - Lifetime
- 1994-05-03 JP JP6523604A patent/JPH08510268A/ja not_active Ceased
- 1994-05-03 DE DE59403971T patent/DE59403971D1/de not_active Expired - Fee Related
- 1994-05-03 AT AT94916185T patent/ATE157698T1/de not_active IP Right Cessation

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2016535811A (ja) *	2013-09-30	2016-11-17	エンサバイオテックアクチエボラグＥｎｚａＢｉｏｔｅｃｈＡｂ	界面活性剤組成物
US10188736B2 (en)	2013-09-30	2019-01-29	Enza Biotech Ab	Surfactant composition
JP2020041146A (ja) *	2013-09-30	2020-03-19	エンサバイオテックアクチエボラグＥｎｚａＢｉｏｔｅｃｈＡｂ	界面活性剤組成物
JP2022060263A (ja) *	2013-09-30	2022-04-14	エンサバイオテックアクチエボラグ	界面活性剤組成物
JP2017071664A (ja) *	2015-10-05	2017-04-13	花王株式会社	衣料用液体洗浄剤組成物
WO2017061283A1 (ja) *	2015-10-05	2017-04-13	花王株式会社	衣料用液体洗浄剤組成物
JP2021507971A (ja) *	2017-12-20	2021-02-25	ビーエイエスエフ・ソシエタス・エウロパエアＢａｓｆＳｅ	繊維製品に付着した、融解温度が３０℃超のである脂肪化合物を除去するための洗濯用配合物

Also Published As

Publication number	Publication date
WO1994026861A1 (de)	1994-11-24
DE59403971D1 (de)	1997-10-09
ATE157698T1 (de)	1997-09-15
ES2108456T3 (es)	1997-12-16
DE4315854A1 (de)	1994-11-17
EP0698079A1 (de)	1996-02-28
EP0698079B1 (de)	1997-09-03

Legal Events

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2004-06-10

A313

Final decision of rejection without a dissenting response from the applicant

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Effective date: 20040524

2004-06-29

A02

Decision of refusal

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Effective date: 20040629

Publication	Publication Date	Title
US5972668A (en)	1999-10-26	Production of multi-enzyme granules
US7431739B2 (en)	2008-10-07	Boosting the cleaning performance of laundry detergents by polymer of styrene/methyl methacrylate/methyl polyethylene glycol
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