JPH09202721A - Deodorant - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a deodorant effective for an unpleasant odor such as human body odor, foul breath and urine smell, smell of pet animal, feces and urine smell and tobacco smell, by using a specific metal complex compound as a deodorizing component. SOLUTION: This deodorant uses a metal complex compound of phytic acid. A chelate complex formed from phytic acid and one or more metal ions of iron, copper, zinc, aluminum, manganese, calcium, magnesium and cobalt is preferable as the metal complex compound of phytic acid. In the deodorant, the metal complex compound of phytic acid may be directly used or may be used with another component. The deodorant can be formed into powder, granule (granulated material), tablet, film, sheet, stick, various moldings, emulsion composition, etc. The deodorizing component has reducing effect on various unpleasant smells and is safe to a human body.

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to a human or pet animal body odor, fecal odor, containing a metal phytate complex compound,
Alternatively, the present invention relates to a deodorant and a deodorant that are extremely effective against cigarette odor. Its technical fields include deodorant sprays for external use on the human body, cosmetics with a deodorant effect, and other sanitary products, pet products, textile treatment agents for clothing, etc., natural or synthetic polymers used for building materials and fibers. Material,
It belongs to the field of industrial products such as paints. As specific applications of the deodorant component and the metal phytic acid complex compound according to the present invention, for example, those shown in Table 1 are suitable. In other words, for cosmetics and dentifrices with deodorant effects such as antiperspirant sprays, powdered powders, body powders, baby powders and other external sprays, systemic or topical soaps, lotions, creams, shampoos, rinses, foundations, etc. Not to mention the blending of, but also absorbents and deodorants (including sheets) used inside sanitary products such as paper diapers, sanitary products, armpits, breast pads for breasts, and insole sheets for shoes, etc. It can be used after being subjected to treatments such as compounding, encapsulation, mixing, and spraying with sand for absorbing feces and urine of pets, deodorants for preventing urine odors that are thrown into toilet bowls, and the like. Furthermore, clothing (for example, pajamas, shirts, pants, socks, bras, panties, tights, slips, blouses, pants, skirts), diapers, diaper covers, sanitary pants, sheets (beds, duvet covers, cushions) cover,
Pillow covers, cushion covers, etc.), blankets, carpets, carpets, towels, toilet seat covers, etc., and blended with textile treatment agents such as detergents and softeners used for washing various textile products, and other building materials. It can be kneaded with molding raw materials (synthetic or natural polymer materials) such as fibers and various plastic products, and can also be used as an odor adsorbent for sanitary cotton and deodorizing filters.

[Table 1]

[0002]

2. Description of the Related Art Deodorizing etiquette for odors, particularly sweat odor, bad breath, tobacco odor, etc., is increasing year by year. Popularity and needs are increasing rapidly. For example, various products that prevent various unpleasant odors emitted by the human body, such as deodorant sprays for humans, antiperspirants, deodorant soaps, mouthwash and sanitary products with deodorant effects, deodorizing cigarettes, indoors and toilets, automobiles Deodorant products for environmental odors such as deodorant products of the company and germicidal and deodorant agents for air conditioners, and other deodorant agents that prevent pet odors and manure odors.

The deodorizing and deodorizing countermeasures found in these are classified as follows: a method of removing the odor source itself, a method of physically adsorbing and removing the odor component, and a chemical modification of the odor component. Decomposes, masks using other fragrance components, simply removes odorous components, and inhibits the activity of microorganisms that cause odors such as bacteria and bacteria to generate odors. Preventive methods are commonly used.

Although it has been known so far to utilize phytic acid and metal salts of phytic acid as deodorants for oral ingestion, the use of deodorants for metal phytic acid complex compounds was suggested. No publications are found. Kohei
1-275522 is a prior art document relating to an oral deodorant utilizing the above-mentioned phytic acid or phytate, according to which the body odor is obtained by ingesting the compound orally,
It is said that an effect of essentially suppressing the expression of urine odor and halitosis can be obtained, and it is proposed to be applied to foods and drinks and favorite foods.

[0005]

Although various people have different sensitivities to odors, when they feel discomfort, everyone feels depressed. Especially today, as etiquette-oriented and hygiene-oriented are increasing, awareness of odor tends to be relatively hypersensitive, and the bad breath, body odor, cigarette odor, pet odor, excrement odor, etc. of other people are worrisome. There are many people, and this sometimes leads to a situation that even hinders the communication of people. In addition, for the incontinence seen in the elderly and the bedridden illness for a long period of time, these troubles are especially serious problems. Therefore, the solution of such a problem is extremely important and is considered to have great significance.

However, the various deodorants that have been proposed so far have not been sufficiently satisfactory in terms of effect, usability and durability. Also,
In the usage by the oral ingestion method as seen in the prior art documents, it is not always easy for the user to take, such as complexity of taking, delay in time from taking the drug to the onset of efficacy, and persistence of efficacy. It is hard to say, and frequent and irregular dosing may cause extraordinary overdose.

In view of such circumstances, the present inventors have found that there is a particularly high need for human sweat odor, fat odor, halitosis, foot odor, physiological odor, urine odor, cigarette odor, pet odor (fecal odor). The research was started to develop a safe and highly practical deodorant that is highly effective and safe. In the process, a certain metal phytate complex compound, which has been studied as a lipid peroxidation inhibitor for cosmetics for a long time, shows that it has an immediate effect and an excellent deodorizing effect when contacted with those odors. I found it. Then, the present invention was completed by further researching and trying to evaluate other similar compounds and to study various application examples to enhance the utility value of these active ingredients.

[0008]

The present invention provides a metal phytic acid complex compound, preferably phytic acid, and one or more of iron, copper, zinc, aluminum, manganese, calcium, magnesium and cobalt. Deodorant / deodorant for unpleasant odors emitted from humans and pet animals, especially sweat odors, fatty odors, bad breath, foot odors, physiological odors, urine odors, or odors of cigarettes It is applied as.

[0009]

BEST MODE FOR CARRYING OUT THE INVENTION The metal phytic acid complex compound in the present invention means a sparingly water-soluble or water-insoluble complex compound formed by the reaction of phytic acid (inositol hexaphosphate) with a metal ion. It is preferable to use those phytic acid metal complexes formed with one or more metal ions selected from iron, copper, zinc, aluminum, manganese, calcium, magnesium and cobalt.

To obtain a poorly water-soluble or water-insoluble metal phytic acid complex compound, a solution of phytic acid is usually adjusted to an optimum pH.
It is obtained by adding a suitable aqueous solution of a water-soluble metal compound to this, and appropriately stirring. The pH value of the phytic acid solution and the mixing molar ratio of the phytic acid and the metal ion when obtaining the target complex compound differ depending on the type of metal, but are usually acidic to neutral (pH 2 to 7). For the phytic acid solution adjusted to
The aqueous solution of the metal compound may be gradually added until no precipitation is observed. Table 2 shows the number of moles of various metal ions required to obtain a metal phytic acid complex compound from 1 mole of phytic acid and the applied pH value in the reaction.

[Table 2] After completion of the reaction, the precipitate formed by centrifugation or the like is recovered, and the precipitate is washed several times with, for example, purified water to remove unreacted phytic acid and excess metal compound to obtain the desired product.

The metal compound used in the present invention includes
Any water-soluble metal compound having the property of forming a water-insoluble or water-insoluble complex compound by reaction with phytic acid can be used, but preferably iron, copper, zinc,
Aluminum, manganese, calcium, magnesium,
A water-soluble metal compound containing one or more elements selected from cobalt is preferable.

Examples of water-soluble iron compounds include iron chloride
(II), iron (II) phosphate, iron (II) sulfate, iron (II) diammonium sulfate, iron (II) fumarate, iron (II) tartrate, iron (II) chloride
I), iron (III) phosphate, iron (III) hydroxide, iron (III) nitrate, iron (III) sulfate, iron (III) sulfate ammonium, iron (II) citrate
I), iron (III) ammonium citrate, iron (III) ammonium oxalate, iron (III) hydroxide hydroxide and the like.

Examples of the water-soluble copper compound include copper chloride, copper ammonium chloride, copper benzoate, copper borofluoride,
Copper citrate, copper sulfate, copper phosphate, dipotassium copper chloride, copper fluoride, copper formate, copper fluorosilicate, copper hydroxide, copper nitrate, copper oxalate, basic copper carbonate, copper acetate, copper amidosulfate, etc. .

Examples of the water-soluble zinc compound include zinc chloride, zinc bromide, zinc nitrate, zinc sulfate, zinc citrate,
Zinc acetate, zinc formate, zinc lactate, zinc oxide, zinc phosphate, zinc selenide, zinc silicate, zinc fluoride, zinc tartrate, etc.

Examples of the water-soluble aluminum compound include aluminum chloride, aluminum nitrate, aluminum sulfate, aluminum lactate, aluminum phosphate, sodium alum, ammonium bromide, ammonium alum, basic aluminum acetate and the like.

As the water-soluble manganese compound, for example,
Manganese chloride, manganese dioxide, manganese oxide, manganese formate, manganese carbonate, manganese bromide, manganese phosphate, manganese benzoate, manganese lactate, manganese sulfate,
Manganese tartrate etc.

Examples of the water-soluble calcium compound include calcium alginate, calcium dihydrogen phosphate,
Calcium borate, calcium chloride, tricalcium citrate, calcium diphosphate, calcium formate, calcium acetate, calcium lactate, tricalcium phosphate, calcium sulfate, calcium hydroxide, etc.

Examples of the water-soluble magnesium compound include magnesium chloride, magnesium bromide, magnesium fluoride, magnesium nitrate, magnesium sulfate, magnesium sulfite, magnesium citrate, magnesium acetate, magnesium formate, magnesium aspartate, magnesium lactate, and shu. Magnesium acid, magnesium phosphate, etc.

As the water-soluble cobalt compound, for example,
Cobalt chloride, cobalt ammonium chloride, cobalt sulfate, cobalt ammonium sulfate, cobalt citrate, cobalt acetate, cobalt amido sulfate, cobalt benzoate,
Cobalt bromide, basic cobalt carbonate, cobalt nitrate, cobalt formate, cobalt phosphate, potassium cobalt nitrite, cobalt selenide, cobalt tartrate, cobalt titanate and the like can be used.

In the deodorant of the present invention, the metal phytic acid complex compound may be used as it is, or may be used in combination with other components depending on the application. Further, the form may be any form such as powder, granule (granulated product), tablet, film sheet, stick, various molded products, emulsified composition, dispersion liquid, gel, etc. depending on the product. Hereinafter, the application products shown in Table 1 will be specifically described.

[1] For external preparations (including external sprays and cosmetics) applied to humans and pets, oral preparations, textile treatment agents for clothes, etc., cleaning agents for toilets or baths, tiles, drains, etc. In application, it may be blended together with various components usually used in the production of those products. The main components are listed below. The amount of the phytic acid metal complex compound, which is the deodorant component according to the present invention, to various products varies depending on the purpose of use, type, frequency of use, etc. of the product and cannot be specified unconditionally. It is preferable that the acid metal complex compound is contained in a proportion of 0.1% by weight or more, preferably 0.5% by weight or more based on the total amount (however, this is not the case when other deodorant components are used in combination).

(1) Various oils and fats Avocado oil, almond oil, fennel oil, perilla oil,
Olive oil, orange oil, orange lafa oil, sesame oil, cocoa butter, chamomile oil, carrot oil, cucumber oil, tallow fatty acid, kukui nut oil, safflower oil, soybean oil, camellia oil, corn oil, rapeseed oil, persic oil , Castor oil, cottonseed oil, peanut oil, turtle oil, mink oil, egg yolk oil, palm oil, palm kernel oil, oak, coconut oil, beef tallow, lard, milk fat, or hydrogenated products of these fats (hardened oil, etc.) Such.

(2) Waxes Beeswax, carnauba wax, whale wax, lanolin, liquid lanolin, reduced lanolin, hard lanolin, candelilla wax,
Montan wax, shellac wax, etc.

(3) Mineral oil Liquid paraffin, petrolatum, paraffin, ozokeride, ceresin, microcristan wax, squalene, squalane, pristane, etc.

(4) Fatty acids Lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, 12-hydroxystearic acid, undecylenic acid, tall oil, natural fatty acids such as lanolin fatty acid, isononanoic acid, caproic acid , 2-ethylbutanoic acid, isopentanoic acid, 2-methylpentanoic acid, 2
-Synthetic fatty acids such as ethylhexanoic acid and isopentanoic acid.

(5) Alcohols ethanol, isopropyl alcohol, lauryl alcohol,
Natural alcohols such as cetanol, stearyl alcohol, oleyl alcohol, lanolin alcohol, cholesterol, and phytosterol; and synthetic alcohols such as 2-hexyldecanol, isostearyl alcohol, and 2-octyldodecanol.

(6) Polyhydric alcohol Ethylene oxide, ethylene glycol, diethylene glycol, triethylene glycol, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, polyethylene glycol, propylene oxide, propylene glycol , Polypropylene glycol, 1,3-butylene glycol, glycerin, pentaerythritol, sorbitol, mannitol, etc.

(7) Esters Isopropyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, oleyl oleate, decyl oleate, octyldodecyl myristate, hexyldecyl dimethyloctanoate, cetyl lactate, Myristyl lactate, diethyl phthalate, dibutyl phthalate, lanolin acetate, ethylene glycol monostearate, propylene glycol monostearate, propylene glycol dioleate, etc.

(8) Metal soaps Aluminum stearate, magnesium stearate, zinc stearate, calcium stearate, zinc palmitate, magnesium myristate, zinc laurate, zinc undecylenate, etc.

(9) Gum, sugar and water-soluble polymer compound gum arabic, benzoin gum, dammar gum, guaiac fat, Irish moss, karaya gum, tragacanth gum,
Carob gum, quinseed, agar, casein, lactose,
Fructose, sucrose and its esters, trehalose and its derivatives, dextrin, gelatin, pectin, starch, carrageenan, carboxymethyl chitin or hydroxyalkyl (C ₂ -C ₄ ) oxide to which alkylene (C ₂ -C ₄ ) oxide such as ethylene oxide is added _{2 to} C ₄ ) chitin or chitosan, low molecular weight chitin or chitosan, chitosan salt, sulfated chitin or chitosan, phosphorylated chitin or chitosan, alginic acid and its salt, hyaluronic acid and its salt, chondroitin sulfate and its salt, heparin, ethyl cellulose , Methylcellulose, carboxymethylcellulose, carboxyethylcellulose, sodium carboxyethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, nitrocellulose, crystalline cellulose Polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, polyvinyl methacrylate, polyacrylic acid salts, polyalkylene oxide or crosslinked polymer thereof such as polyethylene oxide or polypropylene oxide, carboxyvinyl polymers, such as polyethyleneimine.

(10) Surfactant Anionic surfactant (alkyl carboxylate, alkyl sulfonate, alkyl sulfate ester salt, alkyl phosphate ester salt), cationic surfactant (alkyl amine salt, alkyl quaternary ammonium salt) ), Amphoteric surfactant:
Carboxylic acid type amphoteric surfactant (amino type, betaine type), sulfate ester type amphoteric surfactant, sulfonic acid type amphoteric surfactant, phosphate type amphoteric surfactant, nonionic surfactant (ether type nonionic) Surfactants, ether ester type nonionic surfactants, ester type nonionic surfactants, block polymer type nonionic surfactants, nitrogen-containing nonionic surfactants), other surfactants (natural surfactants) , Derivatives of protein hydrolysates,
Polymer surfactant, surfactant containing titanium and silicon,
Fluorocarbon surfactants).

(11) Various vitamins Vitamin A group: retinol, retinal (vitamin
A₁), Dehydroretinal (vitamin A_Two), Carochi
Lycopene (Provitamin A), Vitamin B group: Chia
Min hydrochloride, thiamine sulfate (vitamin B₁), Lvov
Rabin (vitamin B_Two ), Pyridoxine (vitamin
B₆), Cyanocobalamin (Vitamin B₁₂), Folic acid,
Nicotinic acid, Pantothenic acid, Biotin, Choline,
Inositols, vitamin C group: ascorbic acid and its
Derivatives of vitamin D group: Ergocalciferol (bi
Tamin D_Two), Cholecalciferol (vitamin D_Three),
Dihydrotaxosterol, Vitamin E group: Tocofellow
And its derivatives, ubiquinones, vitamin K group:
Tonadione (vitamin K₁), Menaquinone (vitamin
K_Two), Menadione (Vitamin K_Three), Menadiol (bi
Tamin K_Four)Such.

(12) Various amino acids Valine, leucine, isoleucine, threonine, methionine, phenylalanine, tryptophan, lysine, glycine, alanine, asparagine, glutamine, serine, cysteine, cystine, tyrosine, proline, hydroxyproline, aspartic acid, glutamic acid , Hydroxylysine, arginine, ornithine, histidine, etc. and their sulfates, phosphates, nitrates, citrates, or amino acid derivatives such as pyrrolidone carboxylic acid.

(13) Various additives derived from plant- or animal-based raw materials These are processes (for example, crushing, milling, washing, hydrolysis, etc.) which are conventionally carried out depending on the product type and form to be added. Fermentation, purification, squeezing, extraction, fractionation, filtration, drying, powderization, granulation, dissolution, sterilization, pH adjustment, deodorization, decolorization, etc. are arbitrarily selected and combined, and various materials are selected. You can select and use it. The solvent used for extraction may be selected in consideration of the purpose and type of the product to be provided, the processing to be performed later, and the like. Usually, water or a water-soluble organic solvent (eg ethanol, propylene glycol) is selected. , 1,3-butylene glycol, etc.)
It is desirable to use one or a mixture of two or more selected from the above. However, when the content of the organic solvent is not preferable depending on the use, only water may be used, or ethanol which is easily removed after extraction may be used, and may be used alone or in an arbitrary mixture with water.

Additives derived from plant or animal raw materials are
When applied to systemic or topical external preparations and cosmetics, including protection of skin and hair, moisturizing, improvement of feel and texture,
Gives flexibility, relieves irritation, relieves stress due to aroma, activates cells (prevents cell aging), suppresses inflammation, improves skin and hair quality, prevents and improves rough skin, hair growth, hair growth, hair loss prevention, gloss Application, cleaning effect, alleviation of fatigue, promotion of blood flow,
In addition to cosmetic effects such as a warm bath effect, effects such as flavoring, deodorizing, thickening, preserving, and buffering can be expected. Furthermore, in addition to these, various cosmetic and pharmaceutical effects of each known raw material are expected, and by combining these, the intended effect can be enhanced or multifunctional. It is also possible to make a product that expects an effect.

As a concrete plant (crude drug) used as a raw material,
For example, Ai (Aiba), Aokazura (Seifu Fuji), Aotsu-Juraji (Kibo), Acacia, Akasugi fruit, Akagrape, Akamegashiwa (Akabu Kashiwa), Akane (Akane grass root), Akayajiou (Jihuang), Agi (Awei), Akinire (Roasted skin), akebi
(Kidori), Asa (Jin Asako), Asagao (Toshiko), Ashitaba
(Tomorrow's leaf), Adzuki (red azuki bean), Asenyaku (Asenyaku), Acerola, Anise fruit, Abemaki fruit, Avocado, Ama, Amacha (Amacha), Amadokoro (Tamatake), Amigasa lily (Shellfish), Almond, Altea, Arnica , Aloe (log), aloe vera, apricot (almond jelly), ansokkou (benzuka), Igakozolina (biliary head), knotweed (tiger cane root), strawberry, fig (non-flower fruit) or its leaves, strawberry (winter aoiko),
Itohimehagi (Enshi), carob, rice seed or seed coat,
Inondo seeds, nettle, ylang-ylang, ginkgo (gingko leaves, ginkgo), Ibuki-yakosou, fennel (fenka), ukiyagara (sanryou), turmeric fruit, turmeric
(Utsubane), Usbania Oyster, Usbenita Oyster, Usubasaishin (spicy), Utsubogusa (summer hay), Udo or Shishiudo (Qang activity, independence, Tang Dynasty activity), Ume (Umebai) or its pulp, Vladigashi, Uwaurushi, Unshurikan ( Chen), Estragon, Eleuthero (Ezo Goka), Enoki, Ebisugusa (Keiko), Elderberry fruit, Elemi, Enju
(Gossip, Gossip rice), ogre (Astragalus radiata), Ouren (Orchid), Ookarasuri (Karonin), Ootsu-la-Fuji (self-defense), Psyllium (Carmae, Carmaegrass), Toucan (Haruko), Obananaokera ( White ajutsu), fruit beetle fruit, hawthorn
(Yamako), barley (barley), ogurma (turning over), okra fruit, okera (white jujube), panax ginseng (carrot), hypericum (brother's cut grass), odorikosou (intermittent), onamimi (blue ears),
Origurumi, Oninoyagara (Tianma), Oniyuri (Yuri), Oninos, Halibut (Hihayu), Ominaeshi (defeated), Dutch strawberry, Dutch garashi, Dutch parsley, Dutch honeyspot, olive, oregano, orange fruit or peel,
Kaikei (ripe yellow), seaweed [green algae, brown algae, red algae],
Cacao seeds, oysters or their leaves (persimmon), kagi kazura (chou hooks), cassia, casino ki fruit (pepper fruit), gajutsu (shadoju),
Kashiwa (Shaju, Shayo), Cascarilla, Kanixa (Kin Sato),
Valerian (valerian root), squash, capokunoki seed, kahokusansho (pepper), cattail (kamaki), chamomile, kamiyatsude (passing grass), karasuri (flower), oak grass, rasabisaku (midsummer), guarana seeds, karaya, Karin (Gourd Gourd), Kawayanagi, Kawatake Mushroom, Kawamuragi (Inchinko), Kansui (Kansu), Licorice (Licorice), Candelilla, Kanto,
Canna, raspberry, kiwi fruit, kikarasuri (uryu root), kikyo (bellflower, bellflower root), chrysanthemum (chrysanthemum flower), catalpa
(Azumi), Rumex (Yotei root), Kizuta, Kidachi aloe, Kidachi mint, Kinoki, Yellowfin (yellow), Yellowtail
(Astragalus), Gymnema Sylvesta, Kiraja Saponaria, Kiraya, Cabbage, Cabbage Immature Fruit, Cucumber, Kumquat Fruit, Betel, Kinmizuki (Senakurushi), Guayule, Quercus Infectoria (Gallery), Kukuinuts, Kuko (Garium, Gugiko, gugi leaf, ground bone bark), cedar japonicus (tenmon winter), kuzu (kuzukon), camphor tree, gooseberry fruit, gardenia (garden garden), kunugi (bokuso), kumazasa,
Japanese black bean (Coleoptera), Clara (Bittersweet), Cranberry fruit, Chestnut or its astringent skin, Curculigo latifolia fruit, Grapefruit fruit, Buckthorn buckthorn, Black grape mochi (Needs rescue), Kurobana cypress (Enmeisou), Chlorella, Mulberry (Mulberry leaf, Mulberry fruit, mulberry fruit, mussels (thorns, stalks), celosia (cow flower, rooster), keirin saishin (spicy), laurel, gentian, gennoshoko
(Old tomato grass), Cilantro fruit, Koshinbara (Monthly flower), Kosui mint, Kozo fruit, Black tea, Kouhone (Raw bone), Kouhon (Straw and Kara straw), Koulyan, Kokemomo (Koshibachi),
Koganebana (Yellow Gon), Kogomeba Hypericum, Coconut Fruit, Goshuyu (Goshuyu), Goshostrawberry (covered bonko), Pepper (pepper), Copaiba Balsam, Coffee Beans, Kobushi
Burdock, burdock, burdock, sesame
(Sesame seeds), sesame seeds (brown ginseng), wheat (wheat), rice or rice bran (red bran, white bran), cola acuminata seeds, cola vera seeds, fenugreek fruit, colombo, condullango, kelp, comfrey ), Konjac, Sakisima button d'zuru (weird sen), cherry blossoms, leaves, fruits, bark (cherry bark),
Pomegranate, sasa, lily of the valley, lily of the valley, sasanqua, sardines of the sardines (sawashatsu), sweet potato, sugarcane, sugar beet,
Jujube jujube (acid jujube), saffron (ban safflower, western safflower),
Pomelo fruit, Soapwort, Salmonberry fruit, Sarashina-sho (Masahima), Salvia, Sawagikyo (Yamakona),
Sawagurumi leaves, Sankirai (Yamakoi), Hawthorn (Yamako), Sanshin ginseng (Sanjin ginseng), Sanshuyu (sanshuyu), Sansho (sansho), Sandscon (Yamazone), Cyanoki fruit, Shiitake mushroom, Jio (Jiro), Shion (Shi-en), Digitalis, Shikunshi (Kimiko), Shishiudo (Independent, Tang-do),
Perilla, Aojiso, Chirimenzo, Catamendiso (Shiyo leaf, Shiso), Weeping birch (white birch bark), Rosewood, Linden tree, Chinese beetle (Forestry), Shimakaniku (Chrysanthemum flower), Shimotsukesou, Potato, Peony (Shakuyaku), Shajin
(Sasan), Scotch beetle (Wheat gate winter), Shirakashi seed, Shirogoshi butterfly seed, Shirobanairisu, Shirobanatsuta flower, Shirominanten (South Tenmi), Juzudama, Palm fruit, Ginger (Ginger), Shoubu (Iris, Iris root) , Shozuku fruit, Birch, Cinconas sacyl bra, Cinnamon, Watermelon
(Watermelon), honeysuckle (gold and silver flowers, shintofu), sorrel (acidic pattern), swimberry fruit, strawberry fruit, horsetail (infestation), stevia, plum fruit, pine cone, pine larch, euphorbia edulis, edible walnut, Pear fruit, snowy pear, oilseed meadow, oilseed americanum, oilseed walnut, oilseed smelt, mint, euphoria melanogaster, euphoria dolphini, edible mackerel, euphorbia, saccharomyces, sacrum Kawakyu), Senna fruit or leaves, Senninsou (large tate), Japanese cabbage (medicine), Soka (grass), buckwheat seeds, Somei potato, Daio (Ohio), Radish, soybean, Daidai (orange peel, Kikomi), Thyme , Takatodai (Daigei), Takawarabi (Inu), Dark Sweet Ferry fruit, Thymus vulgaris (HyakuRika), Tachibana (Tachibanakawa), Tachiyanagi, tamarind seeds, onions, Magnolia salicifolia (fist), Aralia elata or the root bark, Danshen (Dan Shen), dammar, cherry fruit,
Chigaya or its roots (Chiyone), chicory, cloves (cloves, cloves), daffodil (gomiko), daffodil
(Ohta), Korean ginseng (Wuyi), Korean ginseng
(Ginseng), Artemisia (Aiba), Choreimaitake
(Irei), Tsukimiso, Camellia, Camellia, Tsumekusa (lacquer lacustrine), Tsurukusa (duckling grass), Tsuruazuki (red azuki bean), Tsurudukudami (Hanshukara), Tsuruna (Kankyo), Tsurujinjin (Four leaf ginseng), Tsuwabuki, Deiko , Teuchigurumi, Duberry fruit, Tengusa, Tendaiyaku (crow medicine), Touga (Winter melon), Pepper (Pan pepper), Touki (Toki), Toukinsenka, Maize or Maize hair (Nanban hair), Tosumi Mochi (Female Sadako) , Tourindo (dragon gall), dokudami (jujutsu), radish (tomato), tochiban ginseng (bamboo ginseng), eucommia (tochu, tochuha), tomato, tragacanth, triacanthos seed, tormentilla, dronoki, troloi, nigeriaberry fruit , Potatoes (herbal medicine), nagi-kida, naginatakoju, nazuna, jujube, jujube (daijutsu),
Naniwaibara (Kanekurako), Narco Lily (Yoshisei), Peanut (Peanut), Nanten (Namitenmi), Nigaki (Makiki), Nigayomogi (Gakui), Nikuzuku, Nikkei (Kisushi), Leek (Nirako),
Elderberry (bone grafted), carrot, garlic (garlic), nurde
(Five-fold child), leek, thistle (daiji), noibara (fruit), yarrow, nodake (maehu), nobara, peach, palm,
Hibiscus (Bussouge, Furin-Bussouge, Roselle), Pineapple fruit, Hakata lily (Yuri), Hakaumauraboshi (Bone crushing supplement), Hakusen (White moss bark), Huckleberry fruit, Hakobe (Resurrection), Hazelnut (Haruko), Hashidokoro (Roth root) , Basil, lotus (lotus meat, lotus root), parsley, batata, wasp (bamboo-boiled), patchouli, mint (light load, light load leaf), barley (yokuinin), hanasuge (chimomo), banana, hanahakka, vanilla bins, papaya, Stilt
(Mouse malt grass), hub grass, paprika, hamago (vine thorns), hamasuge (kosuke), hamabishi (situriko), hamanas (my rose flower), hamabafu (beach storm), hamamelis, rose (rose), parietalia , Harunile (Yu, YuYi, Yuba),
Breadfruit, Hiougi (sun-dried), Lycopodium carrot (party party), pecan nut, giganbana (stone garlic, mulberry flower),
Hikiokoshi (prolonged life grass), Hishi (Hishimi), pistachio, beet, Hitotsuba (stone reed), Hinata Kozuchi (cow knee), Hiba,
Castor, Sunflower, Bell Pepper, Himegama (Incense Bulb), Himematsutake, Pimenta Fruit, Hiyu Fruit, Below Oyster, Hiroha Kinagusa (Hakuto Okina), Hiroha Senega (Senega), Loquat
(Loquat, loquat leaf), betel nut (large belly skin, betel roe), sprouts (southern wisteria), butterbur (winter winter flowers), and coltsfoot (winter winter flowers,
Subsidiary winter leaves), Fujibakamama (orchid), Fuji beans (bean beans), butcher bloom, grape peel or fruit, beech, Fuyumushinatsukutake mushroom (Cordyceps sinensis), Brazilian liquorice, black currant fruit, blackberry fruit, plum fruit, furcellaria, blueberry Fruit, prune, blond psyllium, bundou (mung bean), loofah, safflower (safflower), belladonna, berry fruit, boysenberry fruit, boufu
(Windbreak), spinach, physalis (Torone), honoki
(Thick, Japanese Thick), Bokeh (Gourd), Hosobaokera (Sojutsu), Hosobabarengiku, Bodaiju, Button (peony bark), Hop, Jojoba, Whiteberry Berry Fruit, Honganzu (Apricot Jin), Hongshimeji, Meisultennanshaw ( Tiannan star),
Ephedra (maoh), macadamia nuts, macri (sea grass), maguwa (mulberry leaves, mulberry bark), madatake (bamboo boiled), matabi (mokuten tate), matsukasa, matsuhodo (bukuryo), marigold, malvanozadine (apricot) ), Mulberry fruit, quince, horse chestnut, mango, mangosteen, mansugurumi,
Mandarin fruit, mannentake (reishi), mannenrow,
Citrus fruit (Colourful), Mishima Psycho (Saiko), Mizokakushi (Harenbei lotus), Misohagi (Sengansai), Mitsugashiwa, Mitsuba, Mitsubahamago (vine vine), Midorihakka, Mimosa,
Ginger, miracle fruit fruit, myrrh, myrobaran, mugwort (Moon Geese), mukunoki, mukuroji, murasaki (purple root), murasaki maize, mehajiki (benefit mother grass), mebuki, melaleuca, melissa, melilot, melon fruit, mokoyomikoku, mokurenposhi ), Mokko (Kinko), Maple Butterfly, Peach Fruit, Seed (Peach) or Leaf (Peach), Sprouts, Morero Cherry Fruit, Moroheiya, Yakawamurasakiimo, Yakuchi (Masuchi), Cornflower, Cornflower, Cornflower Mint, yashabushi (arrow wheel), yachiyanagi, yatsude (octagonal gold plate), mistletoe (parasitic willow), willow leaf, yabugarashi, yabukouji (purple gold beef), pokeweed (land), yamanoimo (yakuyaku), yamahanoki (yamaharu) ), Bayberry (Yumebai skin), Eucalyptus, Yucca Brevifolia, Yukinoshita (Tiger ear grass), Yuzu Real, lily,
Artemisia (Aiba), yogurusa, lime fruit, peanut, lakanka fruit, raspberry fruit, lavender, longan
(Dragon meat), green tea, apple fruit, Rubus suabicimus
(Sweet), lettuce, red currant fruit, lemon fruit,
There are lemongrass, forsythia (forsythia), forsythia, wax palm, loganberry fruit, rosehip, rosemary, Roman chamomile, wakame, wasabi, waremoko (earthworm).

Materials derived from animal-derived raw materials include poultry extract, cow / human placenta extract, pig / cow stomach, duodenum or intestinal extract or its decomposition product, pig / cow spleen extract. Or its decomposition products, extracts of brain tissue of pigs and cows,
Water-soluble collagen, collagen derivative such as acylated collagen, collagen hydrolyzate, elastin, elastin hydrolyzate, water-soluble elastin derivative, keratin and its degradation product or their derivatives, silk protein and its degradation product or their derivatives, Pig / Bovine blood cell proteolysis product (globin peptide), Pig / cow hemoglobin degradation product (hemin, hematin, heme, protoheme, heme iron, etc.), milk,
Casein and its degradation products or their derivatives, skim milk powder and its degradation products or their derivatives, lactoferrin or its degradation products, chicken egg components, fish meat degradation products, etc.

(14) Microorganism culture metabolites Yeast metabolites, yeast extract, rice fermentation extract, rice bran fermentation extract, Euglena extract, lactic acid fermented product of skim milk powder, etc.

(15) α-Hydroxycarboxylic acid An α-hydroxycarboxylic acid having 2 or more carbon atoms such as glycolic acid, citric acid, malic acid, tartaric acid and lactic acid.

(16) Inorganic pigments Silicic anhydride, magnesium silicate, talc, kaolin,
Bentonite, mica, titanium mica, bismuth oxychloride, zirconium oxide, magnesium oxide, zinc oxide,
Titanium oxide, calcium carbonate, magnesium carbonate, yellow iron oxide, red iron oxide, black iron oxide, gunjou, chromium oxide,
Chromium hydroxide, carbon black, calamine, etc.

(17) Ultraviolet absorber p-aminobenzoic acid derivative, salicylic acid derivative, anthranilic acid derivative, coumarin derivative, amino acid compound,
Benzotriazole derivatives, tetrazole derivatives, imidazoline derivatives, pyrimidine derivatives, dioxane derivatives, camphor derivatives, furan derivatives, pyrone derivatives,
Nucleic acid derivatives, allantoin derivatives, nicotinic acid derivatives,
Vitamin B ₆ derivatives, oxybenzone, benzophenone, guaiazulene, shikonin, baicalin, baicalein, berberine and the like.

(18) Astringents Lactic acid, tartaric acid, succinic acid, citric acid, allantoin, zinc chloride, zinc sulfate, zinc oxide, calamine, zinc p-phenolsulfonate, potassium aluminum sulfate, resorcin, ferric chloride, tannin Acids (including catechin compounds) etc.

(19) Antioxidant Ascorbic acid and its salt, stearic acid ester, tocopherol and its ester derivative, nordihydroguaselethenoic acid, butylhydroxytoluene (BHT),
Butylhydroxyanisole (BHA), hydroxytyrosol, parahydroxyanisole, propyl gallate, sesamol, sesamolin, gossypol and the like.

(20) Anti-inflammatory agent Ictamol, indomethacin, kaolin, salicylic acid, sodium salicylate, methyl salicylate, acetylsalicylic acid, diphenhydramine hydrochloride, d or dl-
Camphor, hydrocortisone, guaiazulene, camazulene, chlorpheniramine maleate, glycyrrhizic acid and its salts, glycyrrhetinic acid and its salts and the like.

(21) Bactericidal / Disinfectant Acrinol, sulfur, benzalkonium chloride, benzethonium chloride, methylrosaniline chloride, cresol, calcium gluconate, chlorhexidine gluconate, sulfamine, mercurochrome, lactoferrin or its hydrolyzate.

(22) Fragrances Natural animal fragrances such as musk, civet, castorium and ambergris, anise essential oils, angelica essential oils, ylang-ylang essential oils, iris essential oils, fennel essential oils, orange essential oils, cananga essential oils, caraway essential oils, cardamom essential oils, Guayakwood essential oil, cumin essential oil, black character essential oil, cinnamon essential oil, cinnamon essential oil, geranium essential oil, copaiba balsam essential oil, coriandel essential oil, perilla essential oil, cedarwood essential oil, citronella essential oil, jasmine essential oil, gingergrass essential oil, cedar essential oil, spearmint essential oil, western Mint essential oil, large scented essential oil, tuberose essential oil, Choji essential oil, orange essential oil, winter green essential oil, true balsam essential oil, butchery essential oil, rose essential oil, palmarosa essential oil, cypress essential oil, hiba essential oil,
Sandalwood essential oil, Petitgren essential oil, Bay essential oil, Vetiva essential oil, Bergamot essential oil, Peruvian balsam essential oil, Boad rose essential oil, Camphor essential oil, Mandarin essential oil, Eucalyptus essential oil, Lime essential oil, Lavender essential oil, Linaloe essential oil, Lemongrass essential oil, Lemon essential oil, Rosemary Vegetable flavors such as essential oils and Japanese peppermint essential oils, and other synthetic flavors.

(23) Dyes / colorants Red cabbage dye, red rice dye, madder dye, anato dye, squid dye, turmeric dye, endu dye, krill dye, persimmon dye, caramel, gold, silver, gardenia dye, corn dye , Onion pigment, tamarind pigment, spirulina pigment, whole buckwheat pigment, cherry pigment, laver pigment, hibiscus pigment, grape juice pigment, marigold pigment, purple potato pigment, purple yam pigment, lac pigment, rutin, etc.

(24) Other moisturizers, hormones, sequestering agents, pH adjusters,
Chelating agents, antiseptic / antifungal agents, cooling agents, stabilizers, emulsifiers, animal / vegetable protein and its degradation products, animal / vegetable polysaccharides and its degradation products, animal / vegetable glycoprotein and its degradation products, Blood flow promoters, anti-inflammatory agents / anti-allergic agents, cell activating agents, keratolytic agents, wound healing agents, foaming agents, thickening agents, oral agents, deodorizing / deodorizing agents, enzymes, etc. When used in combination, additive and synergistic effects can be expected.

[2] In application to sanitary products, it is usually mixed with a polymer absorber (mainly mainly polyacrylate type polymer) used internally, or absorbent paper for preventing reversion, It is considered that the lowest cost method is to use by spreading or encapsulating on an absorbent sheet or cotton-like pulp material, but in addition to this, a thin sheet using the deodorant according to the present invention is separately prepared. Alternatively, they may be layered and commercialized. The amount of the metal phytic acid complex compound used is preferably 0.1 g or more, more preferably 0.5 g or more.

[3] For application to synthetic or natural polymer materials (plastics, rubbers, etc.) as raw materials for industrial products such as building materials, containers, fibers, packaging materials, filters, etc. Treatments such as impregnation and spraying can be performed. The applied amount is 0.01% by weight or more, preferably 0.1
It is better to use more than weight%.

[4] The deodorant of the present invention may be directly molded with an excipient for use as a deodorant to be thrown in the toilet bowl of a toilet or sand for absorbing excrement of pet animals, or , It is usually mixed with the raw materials applied to those products (for example, paradichlorobenzene and naphthalene for toilet deodorant, and zeolite, bentonite, silica gel, pulp for pet manure absorbent). Can be converted. Of course, it is also possible to impregnate an existing product or attach it to the surface before use.

[5] Others, paints, sundries (for example,
The same can be applied to use in a bath or tile, a cleaning agent for a sink, a drain, etc.).

[0053]

[Example] Production example of metal phytic acid complex compound 13.2 g of phytic acid (C ₁₆ H ₁₈ O ₂₄ P ₆ = 660.04) was dissolved in purified water, and the pH was adjusted to around 4 with 1N-sodium hydroxide solution. Then, make up to 200 mL with purified water to prepare a 0.1 M phytate solution. Separately, a water-soluble metal compound prepared with purified water to an appropriate concentration (usually, a metal ion concentration of about 0.5 mol / L is preferable) is prepared. The amount to be prepared may be based on the value of the number of moles of each metal ion required for 1M phytic acid (Table 2). Add the metal compound solution to the phytic acid solution until precipitation does not occur, and stir sufficiently (around 30 minutes). Then 5,
Centrifuge at 000 rpm for 10 minutes, add an appropriate amount of purified water to the obtained precipitate, and centrifuge again. By performing this operation several times, unreacted phytic acid and the metal compound are removed by washing. The washed product thus obtained is dried and powdered to obtain a metal phytic acid complex compound.

[0054]

Example Urine odor prevention effect The phytin metal complex compound produced according to the production example was dispersed in water, the towel cloth was dipped in this dispersion, squeezed well, and further dried. In addition, as a comparative control, one treated by the same treatment using an aqueous solution of phytate is prepared. 50 mL of urine collected from each of the in-house volunteers (5 adult males) was absorbed into this, and the deodorizing effect for 2 days on the same day (after 10 minutes) and the next day (after 30 hours) was sensory-evaluated. Table 3 shows the results.

[Table 3]

[0055]

[Examples] Preventive effect on pet manure odor Using dried pellets made of 100% recycled pulp commercially available as cattle toilet manure absorbing sand, 1 kg of pellets
On the other hand, for the sample A, 50 g of metal phytate complex compound (iron phytate complex compound, zinc phytate complex compound, aluminum phytate complex compound of equal amount mixture) was mixed,
For sample B, the same amount of the dried product of the same metal salt of phytic acid (equal amount mixture) was mixed, and these were transferred to regular toilet pads, and two cats (2 days before the test to the same feed during the test). Were given free stool for 2 days each,
Feces and urine odors of the collected pellets were compared by sensory evaluation (total of 10 persons, 8 males and 2 females who did not know the content of the sample). The results are shown in Table 4.

[Table 4]

[0056]

[Example] Suppressing effect of tobacco odor attached to fibers Disperse phytin metal complex compound (mixture of zinc phytate complex compound, magnesium phytate complex compound, copper phytate complex compound) produced according to the production example in water, Soak a towel cloth (15 x 15 cm) in this dispersion and squeeze it well. As a comparative control, a water-treated product is prepared. Next, put these into a 5 L Mayel, have the volunteer smoke a regular cigarette, and inhale the gas into the bottom of Mayel through a glass tube. Confirm that the inside of Mayel has become white with smoke, and quickly plug it. do. Shake the sealed towel so that the entire towel cloth is in contact with smoke, and leave it for 30 minutes. After that, the towel cloth was taken out and naturally dried, and then sensory evaluation was performed on the deodorant effect against tobacco odor and the feel of the towel cloth (man 6
/ Total of 10 women (4 women). The results are shown in Table 5.

[Table 5]

[0057]

[Example] Deodorizing effect of foot odor Non-woven fabric (polyester fiber) cut into a shoe insole sheet size is prepared on each side, of which 5% is for the right foot
Phytic acid metal complex compound (iron phytate complex compound, manganese phytate complex compound, aluminum phytate complex compound equal amount mixture) soak in dispersion liquid, and for left foot, same metal salt of phytic acid (equal amount mixture) ) Soak in an aqueous solution,
dry. Volunteers (five men) were asked to perform a usage test as an insole for one month, and after the test was completed, the odors of the taken out insole sheets were compared by sensory evaluation. The results are shown in Table 6.

[Table 6]

[0058]

[Example] Production of various products using the deodorant component of the present invention [1] Cleansing cream (% by weight) 1. Stearic acid 10 2. Palmitic acid 10 3. Lauric acid 4 4. Myristic acid 12 5. Oleyl alcohol 1.5 6. Glycerin 18 7. Metal phytate complex compound 0.5 8. Comfrey extract 4 9. Potassium hydroxide 6 10. Purified water 34 Add alkali to purified water and heat to around 70 ℃ While adding more glycerin. To this, the oil phase, which had been previously mixed with other components except the metal phytate complex compound and heated and melted, was added gradually with stirring, kept at about 70 ° C for a while to saponify, and then with stirring, around 50 ° C. After the temperature is lowered to, phytic acid metal complex compound is added and further cooled to 25 ° C.

[2] Peel-off pack (% by weight) 1. Polyvinyl alcohol 15 2. Sodium carboxymethyl cellulose 5 3.4% hydroxyethyl chitosan solution 5 4. Propylene glycol 3 5. Ethanol 10 6. Phytic acid metal complex compound 0. 5 7 Aloe extract 3 10. Purified water 58.5 Propylene glycol is added to dissolved in purified water, and polyvinyl alcohol and carboxymethyl cellulose moistened with a part of alcohol are added thereto, and the mixture is heated to about 70 ° C and completely stirred. Dissolve. Next, the temperature is gradually lowered, and at about 40 ° C, the remaining alcohol, hydroxyethyl chitosan solution, phytic acid metal complex compound and aloe extract are added and mixed, and further cooled to about 25 ° C.

[3] Hair rinse (% by weight) 1. Stearyl trimethyl ammonium chloride 1.5 2. Cetanol 2 3.4% hydroxypropyl chitosan solution 3 4.2-octyldodecanol 1 5. Cationized cellulose 0.5 6. Polyoxyethylene cetyl ether 1 7.1 1,3-butylene glycol 5 8 Metal phytic acid complex compound 0.5 9. Chlorella extract 3 10. Purified water Residue According to a conventional method, a hair rinse agent is prepared with the above-mentioned formulation. .

[4] Dusting powder (powder used after bathing, etc.) (% by weight) 1. Talc 95 2. Light magnesium carbonate 1 3. Metal phytic acid complex compound 2 4. Perfume 2 5. Sterilizing preservatives After stirring and mixing the pigment components excluding the fragrance with a blender, the fragrance is sprayed and uniformly mixed.

[5] Antiperspirant / deodorant powder (% by weight) 1. Aluminum hydroxychloride 2 2. Triclosan 0.1 3. Metal phytate complex compound 2 4. Talc 89.9 5. Zinc oxide 3 Blender by conventional method Stir to mix.

[6] Toothpaste (wt%) 1. Calcium hydrogen phosphate 40 2. Hydroxyapatasit 5 3. Metal phytic acid complex compound 2 4. Glycerin 20 5. Carrageenan 1 6. Sodium lauryl sulfate 1.5 7. Saccharin sodium 1 8. Perfume / preservative appropriate amount 9. Purified water Residue Make a toothpaste according to the above formula by the conventional method.

[7] Deodorant for Toilet Toilet Metal phytate complex compound (10 g) was added to p-dichlorobenzene (90 g), heated and melted in a warm bath, and then poured into a suitable cooled mold to solidify. It was

[8] Aerosol deodorant (% by weight) 1. Triclosan 0.1 2. Metal phytic acid complex compound 5 3.1, 3-Butylene glycol 2 4. Absolute ethanol 55 5. Propellant (gas) residue 1 4 to 4 are mixed by a conventional method and filled in a can, and after the valve is mounted, the propellant is filled.

[0066]

[Example] Usage test Panelists (10 male / five female / five females in total) used the antiperspirant / deodorant powder of the above [5] and evaluated the feeling of use. For comparison, an equivalent product containing no metal phytate complex compound was tested. The result is
The results are shown in Table 7.

[Table 7]

[0067]

[Examples] Safety test [1] Primary skin irritation test Various metal phytate metal complex compounds obtained according to the production examples were prepared with purified water to about 20% by weight, and the back was shaved Japanese white It was applied to the skin of a rabbit (female, 3 animals per group, weighing about 2.8 kg). The judgment was made 24, 48, and 72 hours after application by the primary irritation scoring method using erythema and edema as indices. As a result, in all the samples, there was no animal in which erythema and edema were recognized, and it was judged as negative.

[2] Skin Cumulative Irritation Test Various types of metal phytate complex compounds obtained according to the production examples were prepared with purified water so as to be about 20% by weight, and Hartley guinea pigs (female) with the flanks shaved , 3 animals per group,
0.5 ml / animal was applied to the skin having a body weight of about 310 g) once a day, 5 times a week. Application was performed over two weeks and shaving was performed on the last application day of each week. Judgment was made on the day of each application and on the day after the last application using the primary irritancy scoring method using erythema and edema as indices. As a result, in all the samples, there was no animal in which erythema and edema were observed over 2 weeks, and it was determined to be negative.

[3] Acute toxicity test Various phytic acid metal complex compounds obtained according to the production examples were 2,000 to ddy mice (male and female, 5 mice per group, 5 weeks old) fasted for 4 hours before the test. Oral administration of mg / kg was performed, and the onset and extent of toxic symptoms were observed over time. As a result, no abnormalities were observed in all the mice for 14 days, and no abnormalities were observed in the dissection results. Therefore, LD ₅₀
It was determined to be 2,000 mg / kg or more.

[0070]

INDUSTRIAL APPLICABILITY The present invention relates to a deodorant / deodorant effective against unpleasant odors such as human body odor, bad breath, urine odor, pet animal odor, excrement odor, and cigarette odor. Phytic acid metal complex compound, which is a deodorant component, has the effect of reducing various unpleasant odors such as the one described above.
Moreover, it is safe for the human body. Therefore, it can be applied to a great many industrial products,
It is also practical for the user to prevent unpleasant odors through everyday items that are very common.

Claims (2)

[Claims] 1. A deodorant containing a metal phytic acid complex compound.
Deodorant. 2. A phytic acid metal complex compound is a chelate complex formed by phytic acid and one or more metal ions selected from iron, copper, zinc, aluminum, manganese, calcium, magnesium and cobalt. The deodorant / deodorant according to claim 1.