JPH09286902A5 - - Google Patents

Info

Publication number
JPH09286902A5
JPH09286902A5 JP1996331209A JP33120996A JPH09286902A5 JP H09286902 A5 JPH09286902 A5 JP H09286902A5 JP 1996331209 A JP1996331209 A JP 1996331209A JP 33120996 A JP33120996 A JP 33120996A JP H09286902 A5 JPH09286902 A5 JP H09286902A5
Authority
JP
Japan
Prior art keywords
stabilizer
aqueous solution
independently selected
pyrrole compound
oxidizing agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP1996331209A
Other languages
English (en)
Other versions
JP3712805B2 (ja
JPH09286902A (ja
Filing date
Publication date
Priority claimed from US08/572,997 external-priority patent/US5716893A/en
Application filed filed Critical
Publication of JPH09286902A publication Critical patent/JPH09286902A/ja
Publication of JPH09286902A5 publication Critical patent/JPH09286902A5/ja
Application granted granted Critical
Publication of JP3712805B2 publication Critical patent/JP3712805B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Claims (4)

  1. ピロール化合物、酸化剤及びドーパントアニオンの水溶液中でポリピロール化合物を合成する方法において、次の式を有する安定化剤の水溶液の添加を包含することを特徴とする方法。
    但し、R、R、R及びRは、H、OH及びORから独立に選択され、RはC‐Cアルキルであり、R及びRは、H、COOH及びSOHから独立に選択され、安定剤に対するピロール化合物の比は、重量で1:100から1:0.01である。
  2. 安定剤が、ベンゾフェノン、ジヒドロキシベンゾフェノン及びテトラヒドロキシベンゾフェノンからなる群から選択される請求項1に記載の方法。
  3. 酸化剤、ドーパントアニオン、次の式を有する安定化剤及び織物基質の存在下におけるピロール化合物の水溶液の酸化的重合を包含する方法によって得ることができ、ピロール化合物フィルムが該基質に沈積される伝導性織物材料、
    但し、R、R、R及びRは、H、OH及びORから独立に選択され、RはC‐Cアルキルであり、R及びRは、H、COOH及びSOHから独立に選択され、安定剤に対するピロール化合物の比は、重量で1:100から1:0.01である。
  4. 水溶液が1リットル当り0.01から5グラムのピロール化合物を含有し、酸化剤が塩化鉄(III)であり、安定化剤が2,4-ジヒドロキシベンゾフェノンであり、織物基質が織布又はニット地である請求項3に記載の材料。
JP33120996A 1995-12-15 1996-12-11 伝導性ポリマーの安定性を高める方法 Expired - Fee Related JP3712805B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/572,997 US5716893A (en) 1995-12-15 1995-12-15 Method of enhancing the stability of conductive polymers
US572997 1995-12-15

Publications (3)

Publication Number Publication Date
JPH09286902A JPH09286902A (ja) 1997-11-04
JPH09286902A5 true JPH09286902A5 (ja) 2004-11-04
JP3712805B2 JP3712805B2 (ja) 2005-11-02

Family

ID=24290225

Family Applications (1)

Application Number Title Priority Date Filing Date
JP33120996A Expired - Fee Related JP3712805B2 (ja) 1995-12-15 1996-12-11 伝導性ポリマーの安定性を高める方法

Country Status (6)

Country Link
US (2) US5716893A (ja)
EP (1) EP0783050B1 (ja)
JP (1) JP3712805B2 (ja)
CA (1) CA2191529A1 (ja)
DE (1) DE69602343T2 (ja)
ES (1) ES2133902T3 (ja)

Families Citing this family (14)

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Publication number Priority date Publication date Assignee Title
IT1304534B1 (it) * 1998-03-26 2001-03-19 Rossi Danilo De Procedimento per l'ottenimento di film di polimeri elettroconduttoriattraverso trattamento con agenti droganti da polimeri neutri e
US6346491B1 (en) * 1999-05-28 2002-02-12 Milliken & Company Felt having conductivity gradient
US7282261B2 (en) 2003-02-13 2007-10-16 National University Of Singapore Method of enhancing the stability of electroactive polymers and redox active materials
US6894512B2 (en) 2003-03-24 2005-05-17 Israel Aircraft Industries Ltd. Method for detecting hidden corrosion and a sensor for use in the same
US7236139B2 (en) * 2004-12-10 2007-06-26 Bae Systems Information And Electronic Systems Integration Inc. Low backscatter polymer antenna with graded conductivity
US7510745B2 (en) * 2005-09-09 2009-03-31 The Hong Kong Polytechnic University Methods for coating conducting polymer
US7943066B2 (en) 2006-10-06 2011-05-17 The University Of New Brunswick Electrically conductive paper composite
US8013776B2 (en) * 2007-05-07 2011-09-06 Milliken & Company Radar camouflage fabric
US8507102B1 (en) 2012-08-07 2013-08-13 Fownes Brothers & Co., Inc. Conductive leather materials and methods for making the same
JP6245920B2 (ja) * 2013-10-07 2017-12-13 日本バイリーン株式会社 電子共役系ポリマーに被覆された多孔性基材の製造方法
JP6460624B2 (ja) * 2013-10-16 2019-01-30 テイボー株式会社 ペン先
US10221519B2 (en) 2014-12-10 2019-03-05 Fownes Brothers & Co., Inc. Water-repellant conductive fabrics and methods for making the same
US10827846B2 (en) 2016-10-28 2020-11-10 Sleep Number Corporation Bed with foot warming system
US20220227641A1 (en) * 2019-05-20 2022-07-21 Board Of Regents, The University Of Texas System 3-d compositions with integrated conductive polymers for water purification and oil separation

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4697001A (en) * 1984-09-04 1987-09-29 Rockwell International Corporation Chemical synthesis of conducting polypyrrole
US4803096A (en) * 1987-08-03 1989-02-07 Milliken Research Corporation Electrically conductive textile materials and method for making same
US4975317A (en) * 1987-08-03 1990-12-04 Milliken Research Corporation Electrically conductive textile materials and method for making same
US4877646A (en) * 1988-06-27 1989-10-31 Milliken Research Corporation Method for making electrically conductive textile materials
US4981718A (en) * 1988-06-27 1991-01-01 Milliken Research Corporation Method for making electrically conductive textile materials
US5211810A (en) * 1990-08-09 1993-05-18 International Paper Company Electrically conductive polymeric materials and related method of manufacture
US5176851A (en) * 1990-09-04 1993-01-05 Milliken Research Corporation Method for enhancing polyaniline conductivity
FR2672897B1 (fr) * 1991-02-19 1993-04-23 Thomson Csf Procede d'obtention de polymeres conducteurs stables thermiquement.
US5108829A (en) * 1991-04-03 1992-04-28 Milliken Research Corporation Anthraquinone-2-sulfonic acid doped conductive textiles
US5198266A (en) * 1991-04-29 1993-03-30 Rockwell International Corporation Stabilizing shelf life conductivity of conductive coatings
FR2704567B1 (fr) * 1993-04-30 1995-06-23 Commissariat Energie Atomique Procede de preparation d'une nappe de materiau poreux revetue d'un polymere conducteur electronique et produit obtenu par ce procede.

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