JPH09286902A5 - - Google Patents
Info
- Publication number
- JPH09286902A5 JPH09286902A5 JP1996331209A JP33120996A JPH09286902A5 JP H09286902 A5 JPH09286902 A5 JP H09286902A5 JP 1996331209 A JP1996331209 A JP 1996331209A JP 33120996 A JP33120996 A JP 33120996A JP H09286902 A5 JPH09286902 A5 JP H09286902A5
- Authority
- JP
- Japan
- Prior art keywords
- stabilizer
- aqueous solution
- independently selected
- pyrrole compound
- oxidizing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Claims (4)
- ピロール化合物、酸化剤及びドーパントアニオンの水溶液中でポリピロール化合物を合成する方法において、次の式を有する安定化剤の水溶液の添加を包含することを特徴とする方法。
但し、R1、R2、R3及びR4は、H、OH及びORから独立に選択され、RはC1‐C8アルキルであり、R5及びR6は、H、COOH及びSO3Hから独立に選択され、安定剤に対するピロール化合物の比は、重量で1:100から1:0.01である。 - 安定剤が、ベンゾフェノン、ジヒドロキシベンゾフェノン及びテトラヒドロキシベンゾフェノンからなる群から選択される請求項1に記載の方法。
- 酸化剤、ドーパントアニオン、次の式を有する安定化剤及び織物基質の存在下におけるピロール化合物の水溶液の酸化的重合を包含する方法によって得ることができ、ピロール化合物フィルムが該基質に沈積される伝導性織物材料、
但し、R1、R2、R3及びR4は、H、OH及びORから独立に選択され、RはC1‐C8アルキルであり、R5及びR6は、H、COOH及びSO3Hから独立に選択され、安定剤に対するピロール化合物の比は、重量で1:100から1:0.01である。 - 水溶液が1リットル当り0.01から5グラムのピロール化合物を含有し、酸化剤が塩化鉄(III)であり、安定化剤が2,4-ジヒドロキシベンゾフェノンであり、織物基質が織布又はニット地である請求項3に記載の材料。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/572,997 US5716893A (en) | 1995-12-15 | 1995-12-15 | Method of enhancing the stability of conductive polymers |
| US572997 | 1995-12-15 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JPH09286902A JPH09286902A (ja) | 1997-11-04 |
| JPH09286902A5 true JPH09286902A5 (ja) | 2004-11-04 |
| JP3712805B2 JP3712805B2 (ja) | 2005-11-02 |
Family
ID=24290225
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP33120996A Expired - Fee Related JP3712805B2 (ja) | 1995-12-15 | 1996-12-11 | 伝導性ポリマーの安定性を高める方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US5716893A (ja) |
| EP (1) | EP0783050B1 (ja) |
| JP (1) | JP3712805B2 (ja) |
| CA (1) | CA2191529A1 (ja) |
| DE (1) | DE69602343T2 (ja) |
| ES (1) | ES2133902T3 (ja) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1304534B1 (it) * | 1998-03-26 | 2001-03-19 | Rossi Danilo De | Procedimento per l'ottenimento di film di polimeri elettroconduttoriattraverso trattamento con agenti droganti da polimeri neutri e |
| US6346491B1 (en) * | 1999-05-28 | 2002-02-12 | Milliken & Company | Felt having conductivity gradient |
| US7282261B2 (en) | 2003-02-13 | 2007-10-16 | National University Of Singapore | Method of enhancing the stability of electroactive polymers and redox active materials |
| US6894512B2 (en) | 2003-03-24 | 2005-05-17 | Israel Aircraft Industries Ltd. | Method for detecting hidden corrosion and a sensor for use in the same |
| US7236139B2 (en) * | 2004-12-10 | 2007-06-26 | Bae Systems Information And Electronic Systems Integration Inc. | Low backscatter polymer antenna with graded conductivity |
| US7510745B2 (en) * | 2005-09-09 | 2009-03-31 | The Hong Kong Polytechnic University | Methods for coating conducting polymer |
| US7943066B2 (en) | 2006-10-06 | 2011-05-17 | The University Of New Brunswick | Electrically conductive paper composite |
| US8013776B2 (en) * | 2007-05-07 | 2011-09-06 | Milliken & Company | Radar camouflage fabric |
| US8507102B1 (en) | 2012-08-07 | 2013-08-13 | Fownes Brothers & Co., Inc. | Conductive leather materials and methods for making the same |
| JP6245920B2 (ja) * | 2013-10-07 | 2017-12-13 | 日本バイリーン株式会社 | 電子共役系ポリマーに被覆された多孔性基材の製造方法 |
| JP6460624B2 (ja) * | 2013-10-16 | 2019-01-30 | テイボー株式会社 | ペン先 |
| US10221519B2 (en) | 2014-12-10 | 2019-03-05 | Fownes Brothers & Co., Inc. | Water-repellant conductive fabrics and methods for making the same |
| US10827846B2 (en) | 2016-10-28 | 2020-11-10 | Sleep Number Corporation | Bed with foot warming system |
| US20220227641A1 (en) * | 2019-05-20 | 2022-07-21 | Board Of Regents, The University Of Texas System | 3-d compositions with integrated conductive polymers for water purification and oil separation |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4697001A (en) * | 1984-09-04 | 1987-09-29 | Rockwell International Corporation | Chemical synthesis of conducting polypyrrole |
| US4803096A (en) * | 1987-08-03 | 1989-02-07 | Milliken Research Corporation | Electrically conductive textile materials and method for making same |
| US4975317A (en) * | 1987-08-03 | 1990-12-04 | Milliken Research Corporation | Electrically conductive textile materials and method for making same |
| US4877646A (en) * | 1988-06-27 | 1989-10-31 | Milliken Research Corporation | Method for making electrically conductive textile materials |
| US4981718A (en) * | 1988-06-27 | 1991-01-01 | Milliken Research Corporation | Method for making electrically conductive textile materials |
| US5211810A (en) * | 1990-08-09 | 1993-05-18 | International Paper Company | Electrically conductive polymeric materials and related method of manufacture |
| US5176851A (en) * | 1990-09-04 | 1993-01-05 | Milliken Research Corporation | Method for enhancing polyaniline conductivity |
| FR2672897B1 (fr) * | 1991-02-19 | 1993-04-23 | Thomson Csf | Procede d'obtention de polymeres conducteurs stables thermiquement. |
| US5108829A (en) * | 1991-04-03 | 1992-04-28 | Milliken Research Corporation | Anthraquinone-2-sulfonic acid doped conductive textiles |
| US5198266A (en) * | 1991-04-29 | 1993-03-30 | Rockwell International Corporation | Stabilizing shelf life conductivity of conductive coatings |
| FR2704567B1 (fr) * | 1993-04-30 | 1995-06-23 | Commissariat Energie Atomique | Procede de preparation d'une nappe de materiau poreux revetue d'un polymere conducteur electronique et produit obtenu par ce procede. |
-
1995
- 1995-12-15 US US08/572,997 patent/US5716893A/en not_active Expired - Lifetime
-
1996
- 1996-11-28 CA CA 2191529 patent/CA2191529A1/en not_active Abandoned
- 1996-12-06 ES ES96308864T patent/ES2133902T3/es not_active Expired - Lifetime
- 1996-12-06 EP EP19960308864 patent/EP0783050B1/en not_active Expired - Lifetime
- 1996-12-06 DE DE69602343T patent/DE69602343T2/de not_active Expired - Fee Related
- 1996-12-11 JP JP33120996A patent/JP3712805B2/ja not_active Expired - Fee Related
-
1997
- 1997-05-05 US US08/851,504 patent/US5833884A/en not_active Expired - Lifetime
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