JPH1121579A - メインテナンスフリーのジョイント軸用潤滑剤 - Google Patents

メインテナンスフリーのジョイント軸用潤滑剤

Info

Publication number
JPH1121579A
JPH1121579A JP10188073A JP18807398A JPH1121579A JP H1121579 A JPH1121579 A JP H1121579A JP 10188073 A JP10188073 A JP 10188073A JP 18807398 A JP18807398 A JP 18807398A JP H1121579 A JPH1121579 A JP H1121579A
Authority
JP
Japan
Prior art keywords
oil
lubricant
acid
weight
lithium salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10188073A
Other languages
English (en)
Inventor
Wilfried Hermann Dresel
ヘルマン ドレ−ゼル ヴィルフリート
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FUCHS MINERALOELWERKE GmbH
GKN Gelenkwellenbau GmbH
Original Assignee
FUCHS MINERALOELWERKE GmbH
GKN Gelenkwellenbau GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19817055A external-priority patent/DE19817055A1/de
Application filed by FUCHS MINERALOELWERKE GmbH, GKN Gelenkwellenbau GmbH filed Critical FUCHS MINERALOELWERKE GmbH
Publication of JPH1121579A publication Critical patent/JPH1121579A/ja
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
    • C10M101/02—Petroleum fractions
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/32—Esters
    • C10M105/38—Esters of polyhydroxy compounds
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    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
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    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
    • C10M107/08—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation containing butene
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    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/50—Lubricating compositions characterised by the base-material being a macromolecular compound containing silicon
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    • C10M117/00—Lubricating compositions characterised by the thickener being a non-macromolecular carboxylic acid or salt thereof
    • C10M117/02—Lubricating compositions characterised by the thickener being a non-macromolecular carboxylic acid or salt thereof having only one carboxyl group bound to an acyclic carbon atom, cycloaliphatic carbon atom or hydrogen
    • C10M117/04—Lubricating compositions characterised by the thickener being a non-macromolecular carboxylic acid or salt thereof having only one carboxyl group bound to an acyclic carbon atom, cycloaliphatic carbon atom or hydrogen containing hydroxy groups
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    • C10M117/00—Lubricating compositions characterised by the thickener being a non-macromolecular carboxylic acid or salt thereof
    • C10M117/06—Lubricating compositions characterised by the thickener being a non-macromolecular carboxylic acid or salt thereof having more than one carboxyl group bound to an acyclic carbon atom or cycloaliphatic carbon atom
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    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/04—Hydroxy compounds
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    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26—Carboxylic acids; Salts thereof
    • C10M129/56—Acids of unknown or incompletely defined constitution
    • C10M129/58—Naphthenic acids
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    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
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    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/16—Amides; Imides
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    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
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    • C10M133/44—Five-membered ring containing nitrogen and carbon only
    • C10M133/46—Imidazoles
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    • C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
    • C10M135/12—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M135/14—Thio-acids; Thiocyanates; Derivatives thereof having a carbon-to-sulfur double bond
    • C10M135/18—Thio-acids; Thiocyanates; Derivatives thereof having a carbon-to-sulfur double bond thiocarbamic type, e.g. containing the groups
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    • C10M135/32—Heterocyclic sulfur, selenium or tellurium compounds
    • C10M135/36—Heterocyclic sulfur, selenium or tellurium compounds the ring containing sulfur and carbon with nitrogen or oxygen
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    • C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
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    • C10M159/02—Natural products
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Abstract

(57)【要約】 【課題】 本発明の目的は、車輌の運動性能、経済性及
び低公害性を向上させるための、メインテナンスフリー
のジョイント軸用潤滑剤を提供することである。 【解決手段】 （ａ）溶剤精製されたナフテン系又はパ
ラフィン系精製油の単独又は混合物からなる基油、
（ｂ）炭素の数が１０〜２４のヒドロキシ脂肪酸のリチ
ウム塩、又は、炭素の数が２から１２の脂肪族又は脂環
式ジカルボン酸のリチウム塩、（ｃ）少なくと１種の調
整油、（ｄ）ジチオカルバミン酸又はジチオリン酸のモ
リブデン塩、亜鉛塩又はビスマス塩、及びチアジアゾー
ル、並びに（ｅ）潤滑剤に通常用いられる酸化防止剤、
腐食防止剤と耐高圧剤よりなる群から選ばれる少なくと
も１種の添加物を含むメインテナンスフリーのジョイン
ト軸用潤滑剤。

Description

【発明の詳細な説明】
【０００１】
【発明の属する技術分野】本発明は、面倒なメインテナ
ンスを必要としない、いわゆるメインテナンスフリーの
ジョイント軸（Gelenkwelle)用潤滑油に関する。
【０００２】
【従来の技術】ドイツ特許出願公開公報１９５ ３０ ５
０４によりすでに、高温でも同期作動ジョイントに使用
することが可能、低コストでの製造が可能で、持続的な
固形潤滑充填物として同期作動ジョイントの耐久時間を
長くするグリースが公知である。それには、基油として
鉱物性油及び／又は合成油、増稠剤として尿素化合物、
分散した固体潤滑剤として硫化モリブデン、さらにグラ
ファイト、ポリテトラフルオロエチレン並びに少なくと
も１つのモリブデンの有機化合物が含まれている。
【０００３】さらにＰＣＴ国際公開ＷＯ９７／０３１５
２により、鉱物性油及び／又は合成油を基油にした潤滑
油の中に、耐摩耗添加混合物として硫化モリブデン、ナ
フテン酸の亜鉛塩及び少なくとも１種のジチオリン酸金
属塩を用いる事が公知である。
【０００４】さらにまた、ＰＣＴ国際公開ＷＯ９４／１
１４７０により、さまざまな有機系イオウ化合物とチア
ジアゾールと共に、ジチオカルバミン酸又はジチオリン
酸のモリブデン塩を、ジチオカルバミン酸又はジチオリ
ン酸のビスマス塩、鉛塩、アンチモン塩及び他の重金属
との塩と合わせて添加した、リチウム石鹸を含むグリー
スが公知である。
【０００５】そこで述べられた潤滑油には、その他に、
潤滑剤の特性の改善に非常に重要だと考えられるリンの
有機酸塩、ホスフィン、ホスフォネート又は亜リン酸塩
が含まれている。
【０００６】この種の潤滑剤は、無機系硫化モリブデン
を含有することを特徴とするが、同一運動をする同期作
動ジョイントには適するものの、十字型ジョイント軸に
使用した場合、良い結果を示さなかった。
【０００７】
【発明が解決しようとする課題】それ故、メインテナン
スフリーのカルダン式自在軸継手に代表される十字型ジ
ョイント軸、とりわけ重量のある有用車輌の十字型ジョ
イントセットを開発する際の問題は、潤滑油の特性を改
善させることによって、車輌の運動性能、経済性及び低
公害性を向上させることである。
【０００８】
【課題を解決するための手段】上記の問題は、本発明に
よる （ａ） 溶剤精製されたナフテン系又はパラフィン系の
精製油の単独又は混合物からなる基油、（ｂ） 炭素数
が１０〜２４のヒドロキシ脂肪酸のリチウム塩、又は炭
素数が２〜１２の脂肪族又は脂環式ジカルボン酸のリチ
ウム塩、（ｃ） 少なくとも１種の調整油、（ｄ）ジチ
オカルバミン酸又はジチオリン酸のモリブデン塩、亜鉛
塩又はビスマス塩、及びチアジアゾール、並びに（ｅ）
潤滑剤に通常用いられる酸化防止剤、腐食防止剤及び耐
高圧剤よりなる群から選ばれる少なくとも１種の添加物
を含むことを特徴とする潤滑剤により解決される。
【０００９】本発明による潤滑剤には、基油として鉱物
性油及び／又は合成炭化水素油が適している。好ましい
のは、ナフテンベース(naphthene base)の鉱物油と合成
炭化水素油とを１対３から1対５の割合で混合して得ら
れる溶剤精製されたナフテン系の精製油である。またパ
ラフィンベース(paraffin base)の鉱物油と合成炭化水
素油との１対３から１対５の混合物で、摂氏４０度で約
１００〜１５０センチストークス（ｃＳｔ）の粘度を示
す溶剤精製されたパラフィン系の精製油も同じ様に好ま
しい。
【００１０】本発明による潤滑剤は、増稠剤として、炭
素数が１０〜２４、好ましくは１６〜１８の飽和又は不
飽和の脂肪族モノ又はジカルボン酸から誘導されるリチ
ウム石鹸を含有する。様々な脂肪酸と他の酸との混合物
からなる、複合リチウム石鹸が好ましい。とりわけ１２
−ヒドロキシステアリン酸のリチウム塩と、アゼライン
酸、セバシン酸又はホウ酸のリチウム塩との混合物は、
潤滑剤の増稠剤としてすでに多方面で用いられているも
のであって、比較的高い温度でも用いる事が出来る簡単
なリチウム石鹸である。
【００１１】ホウ酸のリチウム塩同様、脂肪族、脂環式
又は芳香族のモノ又はジカルボン酸のリチウム塩も潤滑
剤の増稠剤として特に適している。リチウム塩は、基油
の量に対して５から２０重量％の割合で基油に加えられ
る。
【００１２】本発明による潤滑油には、芳香族ジカルボ
ン酸のアミド、特にテレフタラメートと呼ばれるテレフ
タル酸のアミド、中でもテレフタル酸のオクタデシルア
ミドを加えると良い結果が得られる。
【００１３】運転中出来る限り一定した粘度−温度−走
行時間の関係を得るため、基油には、少なくとも１種の
調整油が加えられる。調整油には添加物が溶解していて
もよい。調整油としては、オレフィン共重合体、ポリブ
テン、ポリオールエステル、α−オレフィン重合体、パ
ーフルオロポリエーテル、ポリシロキサン及び水素化処
理したジエン−スチロール共重合体が適している。それ
らは、一般に潤滑剤の総量に対して２〜４０重量％の割
合で加えられる。
【００１４】潤滑剤をピボット式十字型ジョイントのベ
アリング（Lagerung des Zapfenkreuzes）で使う場合
に、熱的及び機械的に高い負荷にさらされるが、この負
荷に対して安定性を与えるために、本発明の潤滑剤に
は、添加物を加える必要がある。このための酸化防止剤
としては、立体障害性のフェノール及びフェニル−α−
ナフチルアミンの様なアミンが適している。
【００１５】本発明による潤滑油の所望の特性は、他の
添加物と並んでジチオカルバミン酸又はジチオリン酸の
モリブデン塩、亜鉛塩又はビスマス塩及びチアジアゾー
ルを用いる事により得られる。ジチオリン酸のモリブデ
ン塩とジチオカルバミン酸のモリブデン塩が特に好まし
い。これらのモリブデン化合物を１−チア−３，４−ジ
アゾール又はイオウにより橋架けされたその２量体と共
に用いると、継続的な高温下又は機械的負荷下において
も潤滑特性が著しく改善される。それにより、メーカー
で一度潤滑剤を塗布すれば車輌の寿命の間は十分であ
る。
【００１６】本発明による潤滑剤に、Ｎ−アシル−サル
コシンのような腐食防止剤及び／又はメチレン−ビス
（ジブチル−ジチオ−カルバメート）の様な耐高圧剤を
加えると、更なる改善が得られる。加えられる添加物の
総量は、潤滑剤全体に対して２〜１０重量％の割合であ
るべきである。
【００１７】
【発明の実施の形態】本発明による潤滑剤の製造は以下
の様に行う。まずリチウム水酸化物と、脂肪族又は芳香
族のモノ又はジカルボン酸、アルキルスルホン酸又はホ
ウ酸との反応によって作られるリチウム塩（ｂ）を基油
（ａ）に溶解させ懸濁させる。一方、添加物（ｄ＋ｅ）
を調整油（ｃ）に加える。その後この２つの混合物を、
摂氏８０度から２４０度の間に高めた温度下で、攪拌又
は混合装置により混ぜ合わせる。本発明による潤滑剤の
製造において、高圧ホモジナイザーが、成分の一様で均
質な分散を行うのに特に適している。熱に敏感な添加物
は、均質化させる前に加える。
【００１８】
【実施例】以下の実施例は、本発明による潤滑剤の配合
割合で、十字型ジョイントのピボット式軸受け部の寿命
の期間において優れた潤滑作用を示すことが実証され
た。
【００１９】実施例１ 本発明による潤滑剤を以下の成分割合で製造した。 １．基油（ａ）＋リチウム塩（ｂ） １．０重量％ アリールカルボン酸 １．０重量％ アルキルスルホン酸 ３．０重量％ 炭素数が１〜６の脂肪族ジカルボン酸 ８．０重量％ 炭素数が１２〜２２の脂肪族モノカルボン酸又 はそのグリセリド ３．０重量％ リチウム水酸化物 ４３．０重量％ 溶剤精製されたナフテン系の精製油 この混合物は、本発明による潤滑剤の中に５３重量％の
割合で含まれている。 ２．調整油（ｃ） ６．０重量％ オレフィン共重合体 １８．０重量％ ポリオールエステル ７６．０重量％ α−オレフィン重合体 この混合物は、本発明による潤滑剤の中に４０重量％の
割合で含まれている。 ３．添加物（ｄ＋ｅ） ０．５重量％ アミノ系酸化防止剤 ０．５重量％ カルボン酸アルカノールアミド ２．０重量％ モリブデン化合物 １．０重量％ 植物性油 １．０重量％ サルコシン誘導体 ２．０重量％ チアジアゾール誘導体 この混合物は、本発明による潤滑剤の中に７重量％の割
合で含まれている。
【００２０】実施例２ 本発明による潤滑剤の成分の更なる例を示す。 １．基油（ａ）＋リチウム塩（ｂ） ２．０重量％ ホウ酸 １４．０重量％ 炭素数が１２〜２２のモノカルボン酸又はその グリセリド １．０重量％ ポリカルボン酸 ３．０重量％ リチウム水酸化物 ６６．０重量％ 溶剤精製されたパラフィン系の精製油 この混合物は、本発明による潤滑剤の中に８６重量％の
割合で含まれている。 ２．調整油（ｃ） １２．０重量％ オレフィン共重合体 ３６．０重量％ ポリオールエステル ５２．０重量％ α−オレフィン重合体 この混合物は、本発明による潤滑剤の中に７重量％の割
合で含まれている。 ３．添加物（ｄ＋ｅ） ０．５重量％ アミノ系酸化防止剤 ０．５重量％ カルボン酸アルカノールアミド ２．０重量％ モリブデン化合物 １．０重量％ 植物性油 １．０重量％ サルコシン誘導体 ２．０重量％ チアジアゾール誘導体 この混合物は、本発明による潤滑剤の中に７重量％の割
合で含まれている。
【００２１】実施例３ 本発明による潤滑剤の性能を評価するために、実施例１
の潤滑剤を十字型ジョイント（クロスジョイント）に用
いて耐用時間試験を行なった。その際、実施例１の発明
の潤滑剤を用いた８つのジョイントと、以下に示す従来
の標準潤滑油を用いた６つのジョイントとを比較した。
従来の標準潤滑油 １．基油（ａ）＋リチウム塩（ｂ） ２．０重量％ ホウ酸 １４．０重量％ 炭素の数が１２〜２２のモノカルボン酸又はそ のグリセリド １．０重量％ ポリカルボン酸 ３．０重量％ リチウム水酸化物 ６６．０重量％ 溶剤精製されたパラフィン系の精製油 この混合物は、標準潤滑剤の中に８６重量％の割合で含
まれている。 ２．調整油（ｃ） ５．０重量％ ポリオールエステル この成分は、標準潤滑剤の中に５重量％の割合で含まれ
ている。 ３．添加物（ｄ＋ｅ） ０．５重量％ アミノ系酸化防止剤 ０．７重量％ カルボン酸アルカノールアミド １．０重量％ イミダゾリン誘導体 １．０重量％ 植物性油 ０．５重量％ フェノール系酸化防止剤 １．０重量％ チアジアゾール誘導体 ２．５重量％ ジアルキルジチオリン酸の亜鉛塩 １．５重量％ ナフテン酸の亜鉛塩 これらの添加剤の混合物は、標準潤滑剤の中に９重量％
の割合で含まれている。
【００２２】ワイブル分布（Weibull-Verteilung)（フ
ァウデーアー、自動車産業の品質管理：自動車製造業者
と供給者における信頼度保証、方法と実例、自動車産業
連盟エー ファウ（ファウデーアー）ヴェスト エント
シュトラーセ ６１ フランクフルト アム マイン，１９
７６）［Weibull-Verteilung（VDA: Qualit▲a▼tskont
rolle der Automobilindustrie: Zuverl▲a▼ssigkeits
sicherung bei Automobilherstellern und Lieferante
n, Verfahren und Beispiele; Verband der Automobil-
industrie e.V. (VDA), Westendstra▲β▼e 61, Frank
furt am Main, 1976］による耐久時間の個々の値を評価
した結果、上に述べた従来の標準潤滑剤と本発明による
潤滑剤との比較において、本発明による潤滑剤を用いた
場合、耐久時間が明らかに向上することが判明した。ジ
ョイントは、テスト中８０℃の周囲温度にさらされた。
クロスジョイントセットのベアリングブッシュの底面で
測定したところ、故障したものとしては１００℃も外部
温度を超える値を示すものがあった。本発明による潤滑
剤を使用した場合、標準潤滑剤を使用した場合より明ら
かに高いＢ１０及びＢ６３．２の値が得られた。
【００２３】
【表１】
【００２４】ここにおいてＢ１０の値は、試験されたジ
ョイントでジョイントの９０パーセントがまだ故障して
いない実測耐久時間を表わす。同様に、Ｂ６３．２の値
は、ジョイントの３６．８パーセントがまだ故障してい
ない実測耐久時間を表わす。
【００２５】
【発明の効果】添付された図１は、この試験の結果を示
すグラフである。本発明による潤滑剤を用いた場合の方
が、従来の標準潤滑剤を用いた場合よりジョイントの耐
久時間が明らかに長いのがわかる。又、上記した表１に
示し、図１のグラフの右下にもｔｏ（１）及びｔｏ
（２）で示したクロスジョイントの無故障時間を考慮に
入れれば、従来の標準潤滑剤に比較して本発明の潤滑剤
はクロスジョイント等のジョイントの耐久性を向上させ
るのに極めて有用であることがわかる。
【００２６】
【図面の簡単な説明】
【図１】図１は、クロスジョイントの耐久時間に関する
試験の結果を示すグラフである。
───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.6 識別記号 ＦＩ Ｃ１０Ｍ 143:02 133:14） Ｃ１０Ｎ 10:04 10:10 10:12 40:04

Claims (6)

    【特許請求の範囲】
  1. 【請求項１】 （ａ）溶剤精製されたナフテン系又はパ
    ラフィン系精製油の単独又は混合物からなる基油、
    （ｂ）炭素数が１０〜２４のヒドロキシ脂肪酸のリチウ
    ム塩、又は炭素数が２〜１２の脂肪族又は脂環式ジカル
    ボン酸のリチウム塩、（ｃ）少なくとも１種の調整油、
    （ｄ）ジチオカルバミン酸又はジチオリン酸のモリブデ
    ン塩、亜鉛塩又はビスマス塩、及びチアジアゾール、並
    びに（ｅ）潤滑剤に通常用いられる酸化防止剤、腐食防
    止剤及び耐高圧剤よりなる群から選ばれる少なくとも１
    種の添加剤を含むことを特徴とするメインテナンスフリ
    ーのジョイント軸用潤滑剤。
  2. 【請求項２】 上記調整油（ｃ）がオレフィン共重合
    体、ポリブテン、ポリオールエステル、α−オレフィン
    重合体、パーフルオロポリエーテル又はポリシロキサン
    であることを特徴とする請求項１に記載の潤滑剤。
  3. 【請求項３】 上記調整油（ｃ）を、潤滑剤の総量に対
    して、２〜４０重量％含有することを特徴とする請求項
    １〜２のいずれかに記載の潤滑剤。
  4. 【請求項４】 上記リチウム塩（ｂ）を、前記基油に対
    して、５〜２０重量％含有することを特徴とする請求項
    １〜３のいずれかに記載の潤滑剤。
  5. 【請求項５】 上記添加剤（ｅ）としての酸化防止剤が
    アミノ系又はフェノール系化合物であることを特徴とす
    る請求項１〜４のいずれかに記載の潤滑剤。
  6. 【請求項６】 上記添加剤（ｅ）としての腐食防止剤が
    Ｎ−アシル−サルコシンであることを特徴とする請求項
    １〜５のいずれかに記載の潤滑剤。
JP10188073A 1997-06-20 1998-06-19 メインテナンスフリーのジョイント軸用潤滑剤 Pending JPH1121579A (ja)

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Application Number Priority Date Filing Date Title
DE19726127 1997-06-20
DE19726127.2 1997-06-20
DE19817055.6 1998-04-17
DE19817055A DE19817055A1 (de) 1997-06-20 1998-04-17 Schmierstoff für wartungsfreie Gelenkwellen

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JPH1121579A true JPH1121579A (ja) 1999-01-26

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ID=26037601

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EP (1) EP0885949B1 (ja)
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WO2009079337A1 (en) 2007-12-14 2009-06-25 R.T. Vanderbilt Company, Inc. Additive composition for ep greases with excellent antiwear and corrosion properties
KR101080763B1 (ko) * 2009-09-21 2011-11-07 현대자동차주식회사 장수명 가솔린 엔진오일 조성물
KR101543039B1 (ko) * 2009-10-26 2015-08-10 현대자동차주식회사 임피던스 매칭법을 이용한 인버터 커패시터 모듈의 회로 구성방법
CN102703168A (zh) * 2012-06-20 2012-10-03 津滨东宝(天津)科技发展有限公司 一种极压抗磨添加剂组合物及其在润滑脂中的应用
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ES2152724T3 (es) 2001-02-01
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EP0885949A1 (de) 1998-12-23

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