JPS5626896A - Preparation of water-soluble titanium compound - Google Patents
Preparation of water-soluble titanium compoundInfo
- Publication number
- JPS5626896A JPS5626896A JP10164679A JP10164679A JPS5626896A JP S5626896 A JPS5626896 A JP S5626896A JP 10164679 A JP10164679 A JP 10164679A JP 10164679 A JP10164679 A JP 10164679A JP S5626896 A JPS5626896 A JP S5626896A
- Authority
- JP
- Japan
- Prior art keywords
- water
- compound
- acid
- titanium
- oxalic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000003609 titanium compounds Chemical class 0.000 title 1
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 abstract 9
- 150000001875 compounds Chemical class 0.000 abstract 4
- 235000006408 oxalic acid Nutrition 0.000 abstract 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 2
- 239000012736 aqueous medium Substances 0.000 abstract 2
- 239000013078 crystal Substances 0.000 abstract 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 abstract 2
- ZGYRTJADPPDDMY-UHFFFAOYSA-N titanium;tetrahydrate Chemical compound O.O.O.O.[Ti] ZGYRTJADPPDDMY-UHFFFAOYSA-N 0.000 abstract 2
- 150000004718 beta keto acids Chemical class 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- QXDMQSPYEZFLGF-UHFFFAOYSA-L calcium oxalate Chemical compound [Ca+2].[O-]C(=O)C([O-])=O QXDMQSPYEZFLGF-UHFFFAOYSA-L 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000000706 filtrate Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000004310 lactic acid Substances 0.000 abstract 1
- 235000014655 lactic acid Nutrition 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- BBJSDUUHGVDNKL-UHFFFAOYSA-J oxalate;titanium(4+) Chemical compound [Ti+4].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O BBJSDUUHGVDNKL-UHFFFAOYSA-J 0.000 abstract 1
- 150000007519 polyprotic acids Polymers 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 230000009257 reactivity Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- -1 β-diketone Chemical class 0.000 abstract 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
PURPOSE: To prepare the titled compound having high solubility and stability to water and high reactivity, and useful as a surface treating agent for various materials, by reacting a titanium (IV) hydroxide with oxalic acid and a multidantate compound in an aqueous medium.
CONSTITUTION: (A) Titanium (IV) hydroxide is made to react with (B) oxalic acid in an aqueous medium at room temperature to obtain titanium oxalate, which is then mixed with (C) a polydentate compound such as β-diketone, β-ketoacid (ester), water-soluble hydroxycarboxylic acid, water-soluble polybasic acid other than oxalic acid, etc., e.g. lactic acid, and reacted by heating. The reaction mixture thus obtained evolves carbon dioxide gas by addition of calcium carbonate, and calcium oxalate is precipitated as white crystals. After separating the crystal, the filtrate is dried in vacuum to obtain the objective compound, e.g. of formula.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10164679A JPS5626896A (en) | 1979-08-09 | 1979-08-09 | Preparation of water-soluble titanium compound |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10164679A JPS5626896A (en) | 1979-08-09 | 1979-08-09 | Preparation of water-soluble titanium compound |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5626896A true JPS5626896A (en) | 1981-03-16 |
| JPS6230194B2 JPS6230194B2 (en) | 1987-07-01 |
Family
ID=14306135
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10164679A Granted JPS5626896A (en) | 1979-08-09 | 1979-08-09 | Preparation of water-soluble titanium compound |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5626896A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6287242A (en) * | 1985-05-29 | 1987-04-21 | Nippon Shokubai Kagaku Kogyo Co Ltd | Stable metal oxide sol composition |
| WO2002006159A1 (en) * | 2000-07-17 | 2002-01-24 | Industrial Research Limited | Titanium-containing materials |
| WO2003082883A1 (en) * | 2002-04-01 | 2003-10-09 | Daiso Co., Ltd. | Titanium salts, process for preparation thereof, and process for preparing epoxides with the same |
| JP2006022145A (en) * | 2004-07-06 | 2006-01-26 | Kuraray Co Ltd | Polyvinyl alcohol-based hydrogel-forming composition and hydrogel |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS505177A (en) * | 1972-12-25 | 1975-01-20 | ||
| JPS52111518A (en) * | 1976-03-13 | 1977-09-19 | Tioxide Group Ltd | Titanium chelate and process for its preparation |
| JPS5498716A (en) * | 1978-01-17 | 1979-08-03 | Kyokuto Shibosan Kk | Manufacture of waterrsoluble titanous oxalate complex |
-
1979
- 1979-08-09 JP JP10164679A patent/JPS5626896A/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS505177A (en) * | 1972-12-25 | 1975-01-20 | ||
| JPS52111518A (en) * | 1976-03-13 | 1977-09-19 | Tioxide Group Ltd | Titanium chelate and process for its preparation |
| JPS5498716A (en) * | 1978-01-17 | 1979-08-03 | Kyokuto Shibosan Kk | Manufacture of waterrsoluble titanous oxalate complex |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6287242A (en) * | 1985-05-29 | 1987-04-21 | Nippon Shokubai Kagaku Kogyo Co Ltd | Stable metal oxide sol composition |
| WO2002006159A1 (en) * | 2000-07-17 | 2002-01-24 | Industrial Research Limited | Titanium-containing materials |
| WO2003082883A1 (en) * | 2002-04-01 | 2003-10-09 | Daiso Co., Ltd. | Titanium salts, process for preparation thereof, and process for preparing epoxides with the same |
| JP2006022145A (en) * | 2004-07-06 | 2006-01-26 | Kuraray Co Ltd | Polyvinyl alcohol-based hydrogel-forming composition and hydrogel |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6230194B2 (en) | 1987-07-01 |
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