JPS565474A - 4-ethoxy-2-pyrone derivative - Google Patents
4-ethoxy-2-pyrone derivativeInfo
- Publication number
- JPS565474A JPS565474A JP8086979A JP8086979A JPS565474A JP S565474 A JPS565474 A JP S565474A JP 8086979 A JP8086979 A JP 8086979A JP 8086979 A JP8086979 A JP 8086979A JP S565474 A JPS565474 A JP S565474A
- Authority
- JP
- Japan
- Prior art keywords
- stirred
- mixture
- thf
- added
- styryl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Pyrane Compounds (AREA)
Abstract
NEW MATERIAL:4-Ethoxy-6-styryl-5,6-dihydro-2H-pyran-2-one of the formula.
USE: A preventive or remedy for hyperlipemia having an antilipemic action.
PROCESS: Ethyl acetoacetate is added dropwise to sodium hydride in anhydrous tetrahydrofuran (THF) under cooling with ice and stirring, and the mixture is stirred and then cooled at -10W-5°C. A solution of n-butyl lithium in n-hexane is added to the mixture, and cooled. Cinnamic aldehyde in an hydrous THF is added to the mixture into and stirred. The reaction mixture is then introduced ice water and stirred. After separating the THF layer, the aqueous layer is acidified with hydrochloric acid and extracted with ethyl acetate. The extract thus obtained is washed with saturated common salt solution, dried over sodium sulfate, and concentrated to give 6-styryl-2,4-dioxo-2H-pyran. The resulting compound is then mixed with diethyl sulfate and stirred. The reaction mixture is concentrated in vacuo, and the resulting residue is dissolved in water, acidified with hydrochloric acid, extracted with ethyl acetate, washed and dried to afford the compound of the formula.
COPYRIGHT: (C)1981,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8086979A JPS565474A (en) | 1979-06-27 | 1979-06-27 | 4-ethoxy-2-pyrone derivative |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8086979A JPS565474A (en) | 1979-06-27 | 1979-06-27 | 4-ethoxy-2-pyrone derivative |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS565474A true JPS565474A (en) | 1981-01-20 |
Family
ID=13730342
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8086979A Pending JPS565474A (en) | 1979-06-27 | 1979-06-27 | 4-ethoxy-2-pyrone derivative |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS565474A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009023975A (en) * | 2007-07-23 | 2009-02-05 | Nagoya Industrial Science Research Inst | Peroxisome proliferator-responsive receptor (PPAR) alpha ligand agent |
-
1979
- 1979-06-27 JP JP8086979A patent/JPS565474A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009023975A (en) * | 2007-07-23 | 2009-02-05 | Nagoya Industrial Science Research Inst | Peroxisome proliferator-responsive receptor (PPAR) alpha ligand agent |
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