JPS5659789A - 2,3-diamino-2,3-n,n'-carbonyl-2,3,5-trideoxy-5-c-carbomethoxypropane-d-ribofuranose and its preparation - Google Patents

2,3-diamino-2,3-n,n'-carbonyl-2,3,5-trideoxy-5-c-carbomethoxypropane-d-ribofuranose and its preparation

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Publication number
JPS5659789A
JPS5659789A JP14658780A JP14658780A JPS5659789A JP S5659789 A JPS5659789 A JP S5659789A JP 14658780 A JP14658780 A JP 14658780A JP 14658780 A JP14658780 A JP 14658780A JP S5659789 A JPS5659789 A JP S5659789A
Authority
JP
Japan
Prior art keywords
formula
compound
carbomethoxypropane
trideoxy
ribofuranose
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP14658780A
Other languages
Japanese (ja)
Other versions
JPS5643475B2 (en
Inventor
Sakae Emoto
Hiroshi Orui
Noriyoshi Sueda
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
RIKEN
Original Assignee
RIKEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by RIKEN filed Critical RIKEN
Priority to JP14658780A priority Critical patent/JPS5659789A/en
Publication of JPS5659789A publication Critical patent/JPS5659789A/en
Publication of JPS5643475B2 publication Critical patent/JPS5643475B2/ja
Granted legal-status Critical Current

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  • Saccharide Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)

Abstract

NEW MATERIAL:2,3-Diamino-2, 3-N, N'-carbonyl-2, 3, 5-trideoxy-5-C-carbomethoxypropane-D-ribofuranose.
USE: Synthetic intermediate of (+)-biotin. Starting material to various synthetic organic compounds. Especially it is very useful in high selective synthesis of (+)- biotin of formula I, a natural form of a vitamin.
PREPARATION: For example, a compound of formula VIII (Ph is phenyl) derived from D-glucosamine of formula II is oxidized with periodic acid. The product is made to react with [3-carbomethoxypropen-(2)-ylidene-(1)]triphenylphosphorane to give a compound of formula IX. Further, the compound of formula IX is catalytically reduced in a solvent such as ethanol in the presence of a catalyst such as Pd-C to produce the compound of formula X.
COPYRIGHT: (C)1981,JPO&Japio
JP14658780A 1980-10-20 1980-10-20 2,3-diamino-2,3-n,n'-carbonyl-2,3,5-trideoxy-5-c-carbomethoxypropane-d-ribofuranose and its preparation Granted JPS5659789A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP14658780A JPS5659789A (en) 1980-10-20 1980-10-20 2,3-diamino-2,3-n,n'-carbonyl-2,3,5-trideoxy-5-c-carbomethoxypropane-d-ribofuranose and its preparation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14658780A JPS5659789A (en) 1980-10-20 1980-10-20 2,3-diamino-2,3-n,n'-carbonyl-2,3,5-trideoxy-5-c-carbomethoxypropane-d-ribofuranose and its preparation

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP1706378A Division JPS54109972A (en) 1978-02-15 1978-02-15 Preparation of 4-(s)-5-methoxycarbonyl-1-(s)-hy droxypentyl-5-(r)-hydroxymethyl-imidazolidinone and its derivative

Publications (2)

Publication Number Publication Date
JPS5659789A true JPS5659789A (en) 1981-05-23
JPS5643475B2 JPS5643475B2 (en) 1981-10-13

Family

ID=15411077

Family Applications (1)

Application Number Title Priority Date Filing Date
JP14658780A Granted JPS5659789A (en) 1980-10-20 1980-10-20 2,3-diamino-2,3-n,n'-carbonyl-2,3,5-trideoxy-5-c-carbomethoxypropane-d-ribofuranose and its preparation

Country Status (1)

Country Link
JP (1) JPS5659789A (en)

Also Published As

Publication number Publication date
JPS5643475B2 (en) 1981-10-13

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