JPS57100103A - Photo-insolubilizing polyvinyl alcohol derivative and its preparation - Google Patents
Photo-insolubilizing polyvinyl alcohol derivative and its preparationInfo
- Publication number
- JPS57100103A JPS57100103A JP17565980A JP17565980A JPS57100103A JP S57100103 A JPS57100103 A JP S57100103A JP 17565980 A JP17565980 A JP 17565980A JP 17565980 A JP17565980 A JP 17565980A JP S57100103 A JPS57100103 A JP S57100103A
- Authority
- JP
- Japan
- Prior art keywords
- photo
- derivative
- preparation
- polyvinyl alcohol
- pref
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004372 Polyvinyl alcohol Substances 0.000 title 1
- 150000001298 alcohols Chemical class 0.000 title 1
- 229920002451 polyvinyl alcohol Polymers 0.000 title 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 abstract 2
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 abstract 2
- BGTOWKSIORTVQH-UHFFFAOYSA-N cyclopentanone Chemical compound O=C1CCCC1 BGTOWKSIORTVQH-UHFFFAOYSA-N 0.000 abstract 2
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 2
- 229920002689 polyvinyl acetate Polymers 0.000 abstract 2
- 239000011118 polyvinyl acetate Substances 0.000 abstract 2
- 206010034972 Photosensitivity reaction Diseases 0.000 abstract 1
- 239000003377 acid catalyst Substances 0.000 abstract 1
- 125000000524 functional group Chemical group 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 229920002120 photoresistant polymer Polymers 0.000 abstract 1
- 230000036211 photosensitivity Effects 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- -1 polymethylene Polymers 0.000 abstract 1
- 238000007127 saponification reaction Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
PURPOSE: To prepare the titled PVA derivative having high photo-sensitivity even at a low content of the photo-sensitive functional group, and suitable as a photoresist, etc., by reacting a (partially) saponified polyvinyl acetate with an aldehyde or its acetal derivative.
CONSTITUTION: The objective derivative having the structure substituted with the unit of formula II, is prepared by reacting (A) a (partially) saponified saponified polyvinyl acetate (pref. having a saponification degree of ≥70% and an average polymerization degree of 200W3,000) with (B) the aldehyde of formulaI(A is polymethylene which may have side chain) or its acetal derivative[e.g. 2-(p- formylbenzylidene)cyclopentanone], in water or a hydrous organic solvent, in the presence of an acid catalyst (pref. hydrochloric acid.).
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17565980A JPS5910721B2 (en) | 1980-12-12 | 1980-12-12 | Method for producing photo-insolubilizable polyvinyl alcohol derivative |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17565980A JPS5910721B2 (en) | 1980-12-12 | 1980-12-12 | Method for producing photo-insolubilizable polyvinyl alcohol derivative |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57100103A true JPS57100103A (en) | 1982-06-22 |
| JPS5910721B2 JPS5910721B2 (en) | 1984-03-10 |
Family
ID=15999961
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17565980A Expired JPS5910721B2 (en) | 1980-12-12 | 1980-12-12 | Method for producing photo-insolubilizable polyvinyl alcohol derivative |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5910721B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5358999A (en) * | 1992-05-29 | 1994-10-25 | Ulano Corporation | Process for preparation of photosensitive compositions of stilbazolium quaternary |
| JP2019119771A (en) * | 2017-12-28 | 2019-07-22 | 株式会社クラレ | adhesive |
-
1980
- 1980-12-12 JP JP17565980A patent/JPS5910721B2/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5358999A (en) * | 1992-05-29 | 1994-10-25 | Ulano Corporation | Process for preparation of photosensitive compositions of stilbazolium quaternary |
| JP2019119771A (en) * | 2017-12-28 | 2019-07-22 | 株式会社クラレ | adhesive |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5910721B2 (en) | 1984-03-10 |
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