JPS5831355B2 - ９−チアビシクロ〔３，３，１〕ノナンジイル−２，６−ビス〔３−（３，５−ジ−タ−シヤリ−−ブチル−４−ヒドロキシフエニル）プロピオネ−ト - Google Patents

９−チアビシクロ〔３，３，１〕ノナンジイル−２，６−ビス〔３−（３，５−ジ−タ−シヤリ−−ブチル−４−ヒドロキシフエニル）プロピオネ−ト

Info

Publication number: JPS5831355B2
Authority: JP; Japan
Prior art keywords: compounds; butyl; hydroxyphenyl; thiabicyclo; propionate
Prior art date: 1979-08-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP55072131A

Other languages

English (en)

Japanese (ja)

Other versions

JPS5630984A (en

Inventor

エドワード・ロツクウツド・ウイーラー

エルマー・ハリー・ジヤンシス

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Uniroyal Inc

Original Assignee

Uniroyal Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-08-20

Filing date

1980-05-29

Publication date

1983-07-05

1980-05-29 Application filed by Uniroyal Inc filed Critical Uniroyal Inc

1981-03-28 Publication of JPS5630984A publication Critical patent/JPS5630984A/ja

1983-07-05 Publication of JPS5831355B2 publication Critical patent/JPS5831355B2/ja

Status Expired legal-status Critical Current

Links

XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 title 1
150000001875 compounds Chemical class 0.000 description 23
239000000203 mixture Substances 0.000 description 9
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 9
-1 polyethylene Polymers 0.000 description 9
229920001577 copolymer Polymers 0.000 description 8
229920001897 terpolymer Polymers 0.000 description 8
239000004743 Polypropylene Substances 0.000 description 6
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 6
229920001155 polypropylene Polymers 0.000 description 6
239000003381 stabilizer Substances 0.000 description 6
238000010525 oxidative degradation reaction Methods 0.000 description 4
QUZIEYDEASXPSN-UHFFFAOYSA-N 2,6-dichloro-9-thiabicyclo[3.3.1]nonane Chemical compound S1C2C(Cl)CCC1C(Cl)CC2 QUZIEYDEASXPSN-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
239000011368 organic material Substances 0.000 description 3
229920000728 polyester Polymers 0.000 description 3
229920000642 polymer Polymers 0.000 description 3
239000000047 product Substances 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
239000004952 Polyamide Substances 0.000 description 2
239000002253 acid Substances 0.000 description 2
239000000654 additive Substances 0.000 description 2
239000004568 cement Substances 0.000 description 2
229920001971 elastomer Polymers 0.000 description 2
239000000463 material Substances 0.000 description 2
238000000034 method Methods 0.000 description 2
150000002989 phenols Chemical class 0.000 description 2
229920002647 polyamide Polymers 0.000 description 2
239000005060 rubber Substances 0.000 description 2
230000000087 stabilizing effect Effects 0.000 description 2
239000000758 substrate Substances 0.000 description 2
125000000446 sulfanediyl group Chemical group *S* 0.000 description 2
ODJQKYXPKWQWNK-UHFFFAOYSA-L 3-(2-carboxylatoethylsulfanyl)propanoate Chemical class [O-]C(=O)CCSCCC([O-])=O ODJQKYXPKWQWNK-UHFFFAOYSA-L 0.000 description 1
WPMYUUITDBHVQZ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
239000005749 Copper compound Substances 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
244000043261 Hevea brasiliensis Species 0.000 description 1
239000004831 Hot glue Substances 0.000 description 1
YIKSCQDJHCMVMK-UHFFFAOYSA-N Oxamide Chemical class NC(=O)C(N)=O YIKSCQDJHCMVMK-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
239000004264 Petrolatum Substances 0.000 description 1
239000005062 Polybutadiene Substances 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
239000004721 Polyphenylene oxide Substances 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
229920001328 Polyvinylidene chloride Polymers 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 1
239000012963 UV stabilizer Substances 0.000 description 1
239000011354 acetal resin Substances 0.000 description 1
238000007792 addition Methods 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
125000002619 bicyclic group Chemical group 0.000 description 1
238000009835 boiling Methods 0.000 description 1
DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
235000010980 cellulose Nutrition 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000012459 cleaning agent Substances 0.000 description 1
239000003026 cod liver oil Substances 0.000 description 1
235000012716 cod liver oil Nutrition 0.000 description 1
230000006835 compression Effects 0.000 description 1
238000007906 compression Methods 0.000 description 1
238000000748 compression moulding Methods 0.000 description 1
235000012343 cottonseed oil Nutrition 0.000 description 1
239000002385 cottonseed oil Substances 0.000 description 1
239000003599 detergent Substances 0.000 description 1
230000032050 esterification Effects 0.000 description 1
238000005886 esterification reaction Methods 0.000 description 1
239000005038 ethylene vinyl acetate Substances 0.000 description 1
125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
239000003925 fat Substances 0.000 description 1
239000000446 fuel Substances 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
239000011630 iodine Substances 0.000 description 1
239000000944 linseed oil Substances 0.000 description 1
235000021388 linseed oil Nutrition 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
229920003052 natural elastomer Polymers 0.000 description 1
229930014626 natural product Natural products 0.000 description 1
229920001194 natural rubber Polymers 0.000 description 1
239000003921 oil Substances 0.000 description 1
235000019198 oils Nutrition 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
229940066842 petrolatum Drugs 0.000 description 1
235000019271 petrolatum Nutrition 0.000 description 1
239000003209 petroleum derivative Substances 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
125000005498 phthalate group Chemical class 0.000 description 1
229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920002857 polybutadiene Polymers 0.000 description 1
229920001748 polybutylene Polymers 0.000 description 1
229920000515 polycarbonate Polymers 0.000 description 1
239000004417 polycarbonate Substances 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920002959 polymer blend Polymers 0.000 description 1
229920000193 polymethacrylate Polymers 0.000 description 1
229920000306 polymethylpentene Polymers 0.000 description 1
239000011116 polymethylpentene Substances 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
229920006324 polyoxymethylene Polymers 0.000 description 1
229920006380 polyphenylene oxide Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
229920002635 polyurethane Polymers 0.000 description 1
239000004814 polyurethane Substances 0.000 description 1
239000005033 polyvinylidene chloride Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000000746 purification Methods 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011347 resin Substances 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
OJRALSIFYBADIE-UHFFFAOYSA-M sodium;3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound [Na+].CC(C)(C)C1=CC(CCC([O-])=O)=CC(C(C)(C)C)=C1O OJRALSIFYBADIE-UHFFFAOYSA-M 0.000 description 1
239000000126 substance Substances 0.000 description 1
229920001059 synthetic polymer Polymers 0.000 description 1
239000003760 tallow Substances 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
239000001993 wax Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/45—Heterocyclic compounds having sulfur in the ring

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Compositions Of Macromolecular Compounds (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)

JP55072131A 1979-08-20 1980-05-29 ９−チアビシクロ〔３，３，１〕ノナンジイル−２，６−ビス〔３−（３，５−ジ−タ−シヤリ−−ブチル−４−ヒドロキシフエニル）プロピオネ−ト Expired JPS5831355B2 (ja)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US06/068,236 US4221702A (en)	1979-08-20	1979-08-20	9-Thiabicyclo [3,3,1] nonanediyl-2,6-bis[3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate]

Publications (2)

Publication Number	Publication Date
JPS5630984A JPS5630984A (en)	1981-03-28
JPS5831355B2 true JPS5831355B2 (ja)	1983-07-05

Family

ID=22081282

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP55072131A Expired JPS5831355B2 (ja)	1979-08-20	1980-05-29	９−チアビシクロ〔３，３，１〕ノナンジイル−２，６−ビス〔３−（３，５−ジ−タ−シヤリ−−ブチル−４−ヒドロキシフエニル）プロピオネ−ト

Country Status (5)

Country	Link
US (1)	US4221702A (fr)
EP (1)	EP0024098B1 (fr)
JP (1)	JPS5831355B2 (fr)
CA (1)	CA1124249A (fr)
DE (1)	DE3061880D1 (fr)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4000113A (en) *	1974-01-14	1976-12-28	Ciba-Geigy Corporation	Acylated derivatives of 2,6-dihydroxy-9-azabicyclo[3.3.1]nonane and stabilized compositions
US4132702A (en) *	1974-03-27	1979-01-02	Ciba-Geigy Corporation	Phenol esters and amides and polymers stabilized therewith
US4000112A (en) *	1975-03-17	1976-12-28	Ciba-Geigy Corporation	Hindered phenol derivatives of 9-thiabicyclononanes and stabilized compositions

1979
- 1979-08-20 US US06/068,236 patent/US4221702A/en not_active Expired - Lifetime
- 1979-12-06 CA CA341,343A patent/CA1124249A/fr not_active Expired
1980
- 1980-05-27 DE DE8080301744T patent/DE3061880D1/de not_active Expired
- 1980-05-27 EP EP80301744A patent/EP0024098B1/fr not_active Expired
- 1980-05-29 JP JP55072131A patent/JPS5831355B2/ja not_active Expired

Also Published As

Publication number	Publication date
CA1124249A (fr)	1982-05-25
EP0024098A1 (fr)	1981-02-25
EP0024098B1 (fr)	1983-02-09
US4221702A (en)	1980-09-09
JPS5630984A (en)	1981-03-28
DE3061880D1 (en)	1983-03-17

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JPS63227594A (ja)	1988-09-21	酸化防止剤の芳香族フルオロリン化合物
HK13794A (en)	1994-03-04	Use of substituted phenols as stabilizers
JPS5910753B2 (ja)	1984-03-10	耐酸化性大なる有機物質組成物
US3870680A (en)	1975-03-11	Copper inhibitors for polyolefins
US4806675A (en)	1989-02-21	Method of making mixed pentaerythritol esters having up to 75 percent thio-containing side chains
US3931103A (en)	1976-01-06	Copper inhibitors for polyolefins
JPH04507247A (ja)	1992-12-17	ビス環状ホスファイト化合物並びにそれらで安定化されたポリマー材料
US3896147A (en)	1975-07-22	Hindered phenolic norbornane-2,3-dicarboximides
DE2529363A1 (de)	1976-01-22	Arylester von heterocyclischen aromatischen saeuren sowie verwendung derselben als u.v.-stabilisatoren
EP0244362B1 (fr)	1994-07-13	Compositions stabilisées par des aminoxysilanes
JPH0219143B2 (fr)	1990-04-27
US4251435A (en)	1981-02-17	High molecular weight piperidine derivatives as UV stabilizers
JPS5831355B2 (ja)	1983-07-05	９−チアビシクロ〔３，３，１〕ノナンジイル−２，６−ビス〔３−（３，５−ジ−タ−シヤリ−−ブチル−４−ヒドロキシフエニル）プロピオネ−ト
US4304714A (en)	1981-12-08	Polyfunctional phenolic oxamide antioxidants
US3927150A (en)	1975-12-16	Bicyclic phosphorus compounds
US4153597A (en)	1979-05-08	Hindered phenolic nitro compounds as antioxidants
US3887516A (en)	1975-06-03	Hindered tris (meta-hydroxybenzylthio)-s-triazine antioxidants
JP2764282B2 (ja)	1998-06-11	長鎖Ｎ−アルキル−α−アルキルニトロン及び安定剤としてのそれらの使用方法
JPH08113545A (ja)	1996-05-07	有機材料のための安定剤
JPH0625270A (ja)	1994-02-01	安定剤として好適な有機ホスフィットおよびそれを含む重合体組成物
US3265661A (en)	1966-08-09	2, 4, 6-tris (3, 5-di-tert butyl-4-hydroxybenzyl) phenyl alkanoates and polypropylene compositions stabilized therewith
US5100940A (en)	1992-03-31	Polymeric compositions stabilized with hindered phenolic N-(amido)imides
JPS60112755A (ja)	1985-06-19	Ｓ‐（２‐ヒドロキシフエニルチオ）アルカノエート、該化合物を含有する組成物及び有機材料の安定化方法
US3103542A (en)	1963-09-10	Natural rubber stabilized with alkyl