JPS5849741A - グラフトコポリマ−および樹脂の配合物 - Google Patents

グラフトコポリマ−および樹脂の配合物

Info

Publication number: JPS5849741A
Authority: JP; Japan
Prior art keywords: resin; styrene; acrylonitrile; graft copolymer; formulation
Prior art date: 1981-06-17
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP9366481A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0310660B2 (fr

Inventor

Ruizu Suton Aren

アレン・ルイズ・ストン

Erain Sonma Rinda

リンダ・エライン・ソンマ

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Sumika Polycarbonate Ltd

Original Assignee

Sumika Polycarbonate Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1981-06-17

Filing date

1981-06-17

Publication date

1983-03-24

1981-06-17 Application filed by Sumika Polycarbonate Ltd filed Critical Sumika Polycarbonate Ltd

1981-06-17 Priority to JP9366481A priority Critical patent/JPS5849741A/ja

1983-03-24 Publication of JPS5849741A publication Critical patent/JPS5849741A/ja

1991-02-14 Publication of JPH0310660B2 publication Critical patent/JPH0310660B2/ja

Status Granted legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 51
229920005989 resin Polymers 0.000 title claims abstract description 44
239000011347 resin Substances 0.000 title claims abstract description 44
229920000578 graft copolymer Polymers 0.000 title claims abstract description 31
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 55
239000000178 monomer Substances 0.000 claims abstract description 27
239000002245 particle Substances 0.000 claims abstract description 23
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 17
150000002825 nitriles Chemical class 0.000 claims abstract description 15
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims abstract description 14
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 8
238000009472 formulation Methods 0.000 claims description 30
150000001875 compounds Chemical class 0.000 claims description 8
229920001577 copolymer Polymers 0.000 claims description 2
JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 claims 2
238000002347 injection Methods 0.000 claims 1
239000007924 injection Substances 0.000 claims 1
239000011159 matrix material Substances 0.000 claims 1
125000003944 tolyl group Chemical group 0.000 claims 1
229920001971 elastomer Polymers 0.000 abstract description 7
230000000704 physical effect Effects 0.000 abstract description 7
239000005060 rubber Substances 0.000 abstract description 7
239000005062 Polybutadiene Substances 0.000 abstract description 4
229920002857 polybutadiene Polymers 0.000 abstract description 4
238000004519 manufacturing process Methods 0.000 abstract description 3
229920003244 diene elastomer Polymers 0.000 abstract 3
238000006243 chemical reaction Methods 0.000 description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
238000000034 method Methods 0.000 description 9
239000007787 solid Substances 0.000 description 9
229920000126 latex Polymers 0.000 description 7
DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 6
239000004816 latex Substances 0.000 description 6
235000019333 sodium laurylsulphate Nutrition 0.000 description 6
238000003756 stirring Methods 0.000 description 6
239000012153 distilled water Substances 0.000 description 5
239000003995 emulsifying agent Substances 0.000 description 5
239000003999 initiator Substances 0.000 description 5
238000010559 graft polymerization reaction Methods 0.000 description 4
239000011541 reaction mixture Substances 0.000 description 4
239000000243 solution Substances 0.000 description 4
239000002253 acid Substances 0.000 description 3
238000013329 compounding Methods 0.000 description 3
239000002270 dispersing agent Substances 0.000 description 3
239000000839 emulsion Substances 0.000 description 3
239000000463 material Substances 0.000 description 3
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
238000005345 coagulation Methods 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
238000001746 injection moulding Methods 0.000 description 2
238000002156 mixing Methods 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
-1 natural ♂mu Chemical class 0.000 description 2
LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 2
229920000642 polymer Polymers 0.000 description 2
USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 2
230000035484 reaction time Effects 0.000 description 2
239000008149 soap solution Substances 0.000 description 2
239000011734 sodium Substances 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
159000000000 sodium salts Chemical class 0.000 description 2
229920000638 styrene acrylonitrile Polymers 0.000 description 2
238000006467 substitution reaction Methods 0.000 description 2
238000012360 testing method Methods 0.000 description 2
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
UMTNVLRKTUVQTC-UHFFFAOYSA-N 5-phenylpenta-2,4-dienenitrile;prop-1-enylbenzene Chemical compound CC=CC1=CC=CC=C1.N#CC=CC=CC1=CC=CC=C1 UMTNVLRKTUVQTC-UHFFFAOYSA-N 0.000 description 1
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Chemical class C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
229940126062 Compound A Drugs 0.000 description 1
QZKRHPLGUJDVAR-UHFFFAOYSA-K EDTA trisodium salt Chemical compound [Na+].[Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O QZKRHPLGUJDVAR-UHFFFAOYSA-K 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
239000005977 Ethylene Substances 0.000 description 1
NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 1
LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
239000005642 Oleic acid Substances 0.000 description 1
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Chemical class O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
239000002174 Styrene-butadiene Substances 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical class [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
241001125929 Trisopterus luscus Species 0.000 description 1
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
239000012874 anionic emulsifier Substances 0.000 description 1
239000003963 antioxidant agent Substances 0.000 description 1
230000003078 antioxidant effect Effects 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
238000005452 bending Methods 0.000 description 1
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
239000002738 chelating agent Substances 0.000 description 1
230000001112 coagulating effect Effects 0.000 description 1
230000015271 coagulation Effects 0.000 description 1
238000007906 compression Methods 0.000 description 1
230000006835 compression Effects 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
235000014113 dietary fatty acids Nutrition 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
230000001747 exhibiting effect Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
229930195729 fatty acid Natural products 0.000 description 1
239000000194 fatty acid Substances 0.000 description 1
150000004665 fatty acids Chemical class 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
239000003607 modifier Substances 0.000 description 1
PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
229920001084 poly(chloroprene) Polymers 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
238000006116 polymerization reaction Methods 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229940096992 potassium oleate Drugs 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 1
SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical group C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
239000007870 radical polymerization initiator Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
238000010992 reflux Methods 0.000 description 1
239000000344 soap Substances 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
229940037312 stearamide Drugs 0.000 description 1
239000011115 styrene butadiene Substances 0.000 description 1
229920003048 styrene butadiene rubber Polymers 0.000 description 1
150000003440 styrenes Chemical class 0.000 description 1
KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Chemical class OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 1
VSRBKQFNFZQRBM-UHFFFAOYSA-N tuaminoheptane Chemical compound CCCCCC(C)N VSRBKQFNFZQRBM-UHFFFAOYSA-N 0.000 description 1
229960003986 tuaminoheptane Drugs 0.000 description 1
238000003828 vacuum filtration Methods 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)

JP9366481A 1981-06-17 1981-06-17 グラフトコポリマ−および樹脂の配合物 Granted JPS5849741A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP9366481A JPS5849741A (ja)	1981-06-17	1981-06-17	グラフトコポリマ−および樹脂の配合物

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP9366481A JPS5849741A (ja)	1981-06-17	1981-06-17	グラフトコポリマ−および樹脂の配合物

Publications (2)

Publication Number	Publication Date
JPS5849741A true JPS5849741A (ja)	1983-03-24
JPH0310660B2 JPH0310660B2 (fr)	1991-02-14

Family

ID=14088655

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP9366481A Granted JPS5849741A (ja)	1981-06-17	1981-06-17	グラフトコポリマ−および樹脂の配合物

Country Status (1)

Country	Link
JP (1)	JPS5849741A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS59147037A (ja) *	1983-02-05	1984-08-23	バイエル・アクチエンゲゼルシヤフト	熱可塑性成型用組成物

Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS57149348A (en) *	1981-03-10	1982-09-14	Japan Synthetic Rubber Co Ltd	Thermoplastic resin composition

1981
- 1981-06-17 JP JP9366481A patent/JPS5849741A/ja active Granted

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS57149348A (en) *	1981-03-10	1982-09-14	Japan Synthetic Rubber Co Ltd	Thermoplastic resin composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS59147037A (ja) *	1983-02-05	1984-08-23	バイエル・アクチエンゲゼルシヤフト	熱可塑性成型用組成物

Also Published As

Publication number	Publication date
JPH0310660B2 (fr)	1991-02-14

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US4248778A (en)	1981-02-03	ABS-Polymers of high notched impact strength
US4520165A (en)	1985-05-28	ABS-moulding compositions
EP3248994B1 (fr)	2019-07-31	Polymère de caoutchouc et procédé de préparation correspondant, copolymère greffé et composition de résine thermoplastique
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DE4414123A1 (de)	1995-10-26	Thermoplastische Formmassen vom ABS-Typ
EP0146035B2 (fr)	1995-02-22	Résine thermoplastique ayant une excellente résistance à l'impact et à la chaleur
EP0051875B1 (fr)	1985-03-20	Composition de résine thermoplastique à grande dureté et à résistance à la déformation par la chaleur
JPS5849741A (ja)	1983-03-24	グラフトコポリマ−および樹脂の配合物
EP0076162B1 (fr)	1985-09-11	Procédé de production d'une résine thermoplastique et composition de résines le contenant
JPH02185554A (ja)	1990-07-19	ポリマーアロイ
KR100419230B1 (ko)	2004-06-30	백색도와내충격성이우수한열가소성수지의제조방법
JPS5813650A (ja)	1983-01-26	熱可塑性樹脂組成物
JPH0586815B2 (fr)	1993-12-14
JPS62223252A (ja)	1987-10-01	ポリフエニレンエ−テル樹脂組成物
JPS63258914A (ja)	1988-10-26	共重合体の製造方法
JPS5861108A (ja)	1983-04-12	熱可塑性樹脂の製造方法
JPH01254756A (ja)	1989-10-11	加熱下で高い寸法安定性を有する熱可塑性成形用組成物
JP2004018684A (ja)	2004-01-22	熱可塑性樹脂組成物及びその成形品
US3607978A (en)	1971-09-21	Nitrile polymeric blends
JPS6268805A (ja)	1987-03-28	マレイミド系共重合体の製造方法
JPS63118320A (ja)	1988-05-23	熱可塑性樹脂組成物
JP2670854B2 (ja)	1997-10-29	耐衝撃性，成形外観，流動性に優れた熱可塑性樹脂の製造方法
JPS63241053A (ja)	1988-10-06	スチレン系樹脂の製造方法

JPS5849741A - グラフトコポリマ−および樹脂の配合物 - Google Patents

Info

Links

Landscapes

Priority Applications (1)

Applications Claiming Priority (1)

Publications (2)

Family

ID=14088655

Family Applications (1)

Country Status (1)

Cited By (1)

Citations (1)

Patent Citations (1)

Cited By (1)

Also Published As

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