JPS59189925A - 硫化水素の選択的除去方法 - Google Patents

硫化水素の選択的除去方法

Info

Publication number: JPS59189925A
Authority: JP; Japan
Prior art keywords: solution; hydrogen sulfide; gas; chelate; metal chelate
Prior art date: 1982-01-04
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP58062381A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0258966B2 (fr

Inventor

ア−ル・サミユエル・スネイブリイ・ジユニア

テイモシ−・アラン・ジヨ−ンズ

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mobil Oil AS

Original Assignee

Mobil Oil AS

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1982-01-04

Filing date

1983-04-11

Publication date

1984-10-27

1983-04-11 Application filed by Mobil Oil AS filed Critical Mobil Oil AS

1984-10-27 Publication of JPS59189925A publication Critical patent/JPS59189925A/ja

1990-12-11 Publication of JPH0258966B2 publication Critical patent/JPH0258966B2/ja

Status Granted legal-status Critical Current

Links

RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title claims description 84
229910000037 hydrogen sulfide Inorganic materials 0.000 title claims description 83
238000000034 method Methods 0.000 title claims description 44
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 98
239000007789 gas Substances 0.000 claims description 90
239000013522 chelant Substances 0.000 claims description 86
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 52
229910052751 metal Inorganic materials 0.000 claims description 50
239000002184 metal Substances 0.000 claims description 50
229910052742 iron Inorganic materials 0.000 claims description 49
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 45
239000011593 sulfur Substances 0.000 claims description 41
229910052717 sulfur Inorganic materials 0.000 claims description 41
229910002092 carbon dioxide Inorganic materials 0.000 claims description 26
239000001569 carbon dioxide Substances 0.000 claims description 24
230000008929 regeneration Effects 0.000 claims description 22
238000011069 regeneration method Methods 0.000 claims description 22
230000008569 process Effects 0.000 claims description 15
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 13
230000003647 oxidation Effects 0.000 claims description 13
238000007254 oxidation reaction Methods 0.000 claims description 13
229910052760 oxygen Inorganic materials 0.000 claims description 13
239000001301 oxygen Substances 0.000 claims description 13
239000002253 acid Substances 0.000 claims description 10
239000002245 particle Substances 0.000 claims description 9
239000000203 mixture Substances 0.000 claims description 8
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 5
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical group OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 4
230000008018 melting Effects 0.000 claims description 4
238000002844 melting Methods 0.000 claims description 4
239000003795 chemical substances by application Substances 0.000 claims description 3
URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical group OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 claims 1
NPEWZDADCAZMNF-UHFFFAOYSA-N gold iron Chemical compound [Fe].[Au] NPEWZDADCAZMNF-UHFFFAOYSA-N 0.000 claims 1
230000001939 inductive effect Effects 0.000 claims 1
239000000243 solution Substances 0.000 description 100
230000003068 static effect Effects 0.000 description 38
239000007788 liquid Substances 0.000 description 32
238000010521 absorption reaction Methods 0.000 description 25
-1 ethyl diaminetetraacetic acid Chemical compound 0.000 description 16
230000002829 reductive effect Effects 0.000 description 14
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
238000006243 chemical reaction Methods 0.000 description 12
238000005188 flotation Methods 0.000 description 12
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 10
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
239000002738 chelating agent Substances 0.000 description 8
239000006185 dispersion Substances 0.000 description 8
230000000694 effects Effects 0.000 description 8
239000003921 oil Substances 0.000 description 8
239000000126 substance Substances 0.000 description 7
239000007787 solid Substances 0.000 description 6
230000005587 bubbling Effects 0.000 description 5
239000001257 hydrogen Substances 0.000 description 5
229910052739 hydrogen Inorganic materials 0.000 description 5
150000002739 metals Chemical class 0.000 description 5
239000002912 waste gas Substances 0.000 description 5
VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 4
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 4
229910001447 ferric ion Inorganic materials 0.000 description 4
238000007667 floating Methods 0.000 description 4
239000006260 foam Substances 0.000 description 4
239000007791 liquid phase Substances 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
238000002156 mixing Methods 0.000 description 4
229910000029 sodium carbonate Inorganic materials 0.000 description 4
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 4
229910052815 sulfur oxide Inorganic materials 0.000 description 4
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical group C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
230000009471 action Effects 0.000 description 3
238000005273 aeration Methods 0.000 description 3
230000007423 decrease Effects 0.000 description 3
238000010586 diagram Methods 0.000 description 3
238000009826 distribution Methods 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
229910001448 ferrous ion Inorganic materials 0.000 description 3
150000002500 ions Chemical class 0.000 description 3
IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
230000001590 oxidative effect Effects 0.000 description 3
239000012071 phase Substances 0.000 description 3
238000004537 pulping Methods 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
239000012670 alkaline solution Substances 0.000 description 2
150000001413 amino acids Chemical class 0.000 description 2
239000001099 ammonium carbonate Substances 0.000 description 2
150000004056 anthraquinones Chemical class 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
229910052799 carbon Inorganic materials 0.000 description 2
230000008859 change Effects 0.000 description 2
238000001311 chemical methods and process Methods 0.000 description 2
239000010779 crude oil Substances 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
239000003546 flue gas Substances 0.000 description 2
239000012530 fluid Substances 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
150000002505 iron Chemical class 0.000 description 2
235000014413 iron hydroxide Nutrition 0.000 description 2
NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 2
230000033001 locomotion Effects 0.000 description 2
229910021645 metal ion Inorganic materials 0.000 description 2
239000003345 natural gas Substances 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
238000012545 processing Methods 0.000 description 2
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical group O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 2
239000000376 reactant Substances 0.000 description 2
238000010008 shearing Methods 0.000 description 2
239000002002 slurry Substances 0.000 description 2
150000004763 sulfides Chemical class 0.000 description 2
238000012360 testing method Methods 0.000 description 2
ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 2
150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 1
229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
241000283690 Bos taurus Species 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical group C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
241000196324 Embryophyta Species 0.000 description 1
239000004471 Glycine Substances 0.000 description 1
108010008488 Glycylglycine Proteins 0.000 description 1
241000282412 Homo Species 0.000 description 1
229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
235000008708 Morus alba Nutrition 0.000 description 1
240000000249 Morus alba Species 0.000 description 1
241000592161 Muhlenbergia Species 0.000 description 1
229930192627 Naphthoquinone Natural products 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
241000190020 Zelkova serrata Species 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
238000005276 aerator Methods 0.000 description 1
238000003915 air pollution Methods 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
235000012538 ammonium bicarbonate Nutrition 0.000 description 1
235000012501 ammonium carbonate Nutrition 0.000 description 1
235000019270 ammonium chloride Nutrition 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
235000011114 ammonium hydroxide Nutrition 0.000 description 1
150000003863 ammonium salts Chemical group 0.000 description 1
PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
230000033228 biological regulation Effects 0.000 description 1
238000007664 blowing Methods 0.000 description 1
239000003054 catalyst Substances 0.000 description 1
150000001768 cations Chemical class 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
150000004697 chelate complex Chemical class 0.000 description 1
229910052804 chromium Inorganic materials 0.000 description 1
239000011651 chromium Substances 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000003245 coal Substances 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
238000012937 correction Methods 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
238000013461 design Methods 0.000 description 1
150000005205 dihydroxybenzenes Chemical class 0.000 description 1
238000005553 drilling Methods 0.000 description 1
239000003792 electrolyte Substances 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000004927 fusion Effects 0.000 description 1
YMAWOPBAYDPSLA-UHFFFAOYSA-N glycylglycine Chemical compound [NH3+]CC(=O)NCC([O-])=O YMAWOPBAYDPSLA-UHFFFAOYSA-N 0.000 description 1
230000036541 health Effects 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229930195733 hydrocarbon Natural products 0.000 description 1
150000002430 hydrocarbons Chemical class 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 1
239000000797 iron chelating agent Substances 0.000 description 1
RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
239000002655 kraft paper Substances 0.000 description 1
229910052748 manganese Inorganic materials 0.000 description 1
239000011572 manganese Substances 0.000 description 1
239000000155 melt Substances 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
239000011733 molybdenum Substances 0.000 description 1
150000002791 naphthoquinones Chemical class 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
239000003129 oil well Substances 0.000 description 1
238000010979 pH adjustment Methods 0.000 description 1
229910052763 palladium Inorganic materials 0.000 description 1
230000036961 partial effect Effects 0.000 description 1
229960003330 pentetic acid Drugs 0.000 description 1
230000002093 peripheral effect Effects 0.000 description 1
238000005504 petroleum refining Methods 0.000 description 1
230000008635 plant growth Effects 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
238000005086 pumping Methods 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000006479 redox reaction Methods 0.000 description 1
238000007670 refining Methods 0.000 description 1
230000001172 regenerating effect Effects 0.000 description 1
230000000717 retained effect Effects 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000010865 sewage Substances 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
150000003464 sulfur compounds Chemical class 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
229910052715 tantalum Inorganic materials 0.000 description 1
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000002699 waste material Substances 0.000 description 1
239000002023 wood Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/02—Preparation of sulfur; Purification
- C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
- C01B17/05—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by wet processes
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Biomedical Technology (AREA)
Environmental & Geological Engineering (AREA)
Analytical Chemistry (AREA)
General Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Chemical Kinetics & Catalysis (AREA)
Inorganic Chemistry (AREA)
Treating Waste Gases (AREA)

JP58062381A 1982-01-04 1983-04-11 硫化水素の選択的除去方法 Granted JPS59189925A (ja)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US33679682A	1982-01-04	1982-01-04

Publications (2)

Publication Number	Publication Date
JPS59189925A true JPS59189925A (ja)	1984-10-27
JPH0258966B2 JPH0258966B2 (fr)	1990-12-11

Family

ID=23317705

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP58062381A Granted JPS59189925A (ja)	1982-01-04	1983-04-11	硫化水素の選択的除去方法

Country Status (2)

Country	Link
JP (1)	JPS59189925A (fr)
AU (2)	AU565592B2 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2010517750A (ja) *	2007-06-27	2010-05-27	エイチアールディーコーポレーション	気体脱臭用の装置及び方法
JP2012521955A (ja) *	2009-03-30	2012-09-20	シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー	精製合成ガス流を生成する方法

1983
- 1983-04-06 AU AU13197/83A patent/AU565592B2/en not_active Ceased
- 1983-04-11 JP JP58062381A patent/JPS59189925A/ja active Granted
1987
- 1987-07-24 AU AU76108/87A patent/AU7610887A/en not_active Abandoned

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2010517750A (ja) *	2007-06-27	2010-05-27	エイチアールディーコーポレーション	気体脱臭用の装置及び方法
JP2012521955A (ja) *	2009-03-30	2012-09-20	シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー	精製合成ガス流を生成する方法

Also Published As

Publication number	Publication date
AU565592B2 (en)	1987-09-24
AU1319783A (en)	1984-10-11
AU7610887A (en)	1987-10-29
JPH0258966B2 (fr)	1990-12-11

Publication	Publication Date	Title
US5585005A (en)	1996-12-17	Method for effecting gas-liquid contact
US4889701A (en)	1989-12-26	Process for oxidizing multivalent metals
AU667093B2 (en)	1996-03-07	Method and apparatus for effecting gas-liquid contact
US4649032A (en)	1987-03-10	Process for the selective removal of hydrogen sulfide from gaseous streams
CA2267565C (fr)	2004-08-03	Procede d'elimination du mercure et du dioxyde de soufre presents dans des gaz
US3836630A (en)	1974-09-17	Method for treatment of gas containing sulfur dioxide
EP0097303B1 (fr)	1987-01-07	Elimination d'hydrogène sulfuré de courants fluides avec production minimum de solides
EP0086919B1 (fr)	1987-09-16	Procédé pour l'élimination sélective d'hydrogène sulfuré de courants gazeux
CA1080443A (fr)	1980-07-01	Extraction par absorption des oxydes de soufre portes dans des gaz chauds
JPH01231925A (ja)	1989-09-18	排ガス中のイオウ含有有害物質を微生物により変換する方法
US4774071A (en)	1988-09-27	Process and composition for the removal of hydrogen sulfide from gaseous streams
US4283379A (en)	1981-08-11	Method for removing hydrogen sulfide from gas streams
CA2065547C (fr)	1999-04-27	Procede de transfert de masse en continu d'un reactif liquide a l'aide de deux gaz differents
US4325936A (en)	1982-04-20	Method for removing hydrogen sulfide from gas streams
CA2001890A1 (fr)	1990-05-01	Elimination du sulfure d'hydrogene de flux fluidises avec production minimale de matieres solides
JPS593207B2 (ja)	1984-01-23	ガスリユウカラサンカイオウオジヨキヨスルホウホウ
CA1071613A (fr)	1980-02-12	Recuperation de l'hydrogene sulfure en presence dans les gaz
US3459495A (en)	1969-08-05	Method for the removal of hydrogen sulfide in the air of waste gas
JPH05500632A (ja)	1993-02-12	ガス―液体接触を効果的に行う方法および装置
US4432962A (en)	1984-02-21	Method for removing hydrogen sulfide from gas streams
JPS59189925A (ja)	1984-10-27	硫化水素の選択的除去方法
US4078048A (en)	1978-03-07	Process and apparatus for removing sulfur from stack gases in the form of elemental sulfur
US5500130A (en)	1996-03-19	Method for effecting gas-liquid contact
CA1142327A (fr)	1983-03-08	Recuperation des sels d'acide anthraquinone-disulfonique dans le procede de stretford
JPS62225226A (ja)	1987-10-03	湿式排煙脱硫装置

JPS59189925A - 硫化水素の選択的除去方法 - Google Patents

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