JPS592575B2 - Freezing mold manufacturing method and its equipment - Google Patents

Freezing mold manufacturing method and its equipment

Info

Publication number
JPS592575B2
JPS592575B2 JP7342378A JP7342378A JPS592575B2 JP S592575 B2 JPS592575 B2 JP S592575B2 JP 7342378 A JP7342378 A JP 7342378A JP 7342378 A JP7342378 A JP 7342378A JP S592575 B2 JPS592575 B2 JP S592575B2
Authority
JP
Japan
Prior art keywords
mold
cooling chamber
sand
valve hole
moisture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP7342378A
Other languages
Japanese (ja)
Other versions
JPS551905A (en
Inventor
淳策 中島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP7342378A priority Critical patent/JPS592575B2/en
Publication of JPS551905A publication Critical patent/JPS551905A/en
Publication of JPS592575B2 publication Critical patent/JPS592575B2/en
Expired legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/12Treating moulds or cores, e.g. drying, hardening
    • B22C9/126Hardening by freezing

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Molds, Cores, And Manufacturing Methods Thereof (AREA)

Description

【発明の詳細な説明】 本発明は、冷凍鋳型の造型法及びその装置に関する。[Detailed description of the invention] TECHNICAL FIELD The present invention relates to a method for manufacturing a frozen mold and an apparatus therefor.

近時、第1図に示すような冷凍鋳型の造型法が開発され
た。
Recently, a method for making a frozen mold as shown in FIG. 1 has been developed.

すなわち、まず、砂、水、ベントナイト及び溺粉を混練
して、これをつき固めによって型(木型、金型、樹脂型
等)内に充填し、その抜型後に液体窒素等の冷却剤を鋳
型表面にスプレーをし、鋳型内に含まれる水分を凍結せ
しめることにより強固な鋳型を造型しようとするもので
ある。
That is, first, sand, water, bentonite, and drowning powder are kneaded and compacted to fill a mold (wooden mold, metal mold, resin mold, etc.), and after the mold is removed, a coolant such as liquid nitrogen is poured into the mold. The idea is to create a strong mold by spraying the surface and freezing the water contained within the mold.

しかるに、上記した工程中において抜型操作は生型造型
によるものであるから、鋳型の鋳型砂には充分な粘結力
が欠け、したがって抜型操作の段階では鋳型が崩れやす
くて熟練した作業者を必要とする。
However, in the above-mentioned process, the mold removal operation is based on green molding, so the molding sand in the mold lacks sufficient cohesive force, and therefore the mold easily collapses during the mold removal operation, requiring a skilled worker. shall be.

また、その後鋳型内の水分を凍結せしめるのであるが、
上記の様に液体窒素等の冷却剤をM型の表面にスプレー
するだけでは鋳型表面付近の水分は凍結しやすいものの
、鋳型の内部の水分は凍結しに<<、鋳型を短時間に製
造することは困難であった。
Also, the water in the mold is then frozen.
As mentioned above, if you just spray a coolant such as liquid nitrogen onto the surface of the M mold, the moisture near the surface of the mold will easily freeze, but the moisture inside the mold will not freeze. That was difficult.

本発明は、上記した冷凍鋳型の製造技術の欠点に鑑み、
鋳物砂を型内に充填させる前の段階で予め鋳物砂を冷却
しておくとともに、鋳物砂の粒子の表面に水分を供給し
ておき、その後砂を型内に充填させた時点で砂粒子表面
の水を凍結せしめることにより、上記した欠点を排除し
ようとしたものである。
In view of the drawbacks of the above-mentioned freezing mold manufacturing technology, the present invention
Before filling the mold with molding sand, the molding sand is cooled and moisture is supplied to the surface of the molding sand particles. This attempt was made to eliminate the above-mentioned drawbacks by freezing the water.

以下、本発明の一実施例を第2図〜第5図にしたがって
説明する。
An embodiment of the present invention will be described below with reference to FIGS. 2 to 5.

さて、図中、1は鋼製の円筒管より作成される冷却管で
あって、該冷却管1内にはその上部から下部へ向って下
記詳述する第1次冷却室2、第2次冷却室3及び水分供
給室4がそれぞれ形成されている。
In the figure, reference numeral 1 denotes a cooling pipe made of a cylindrical steel tube, and inside the cooling pipe 1, from the top to the bottom, there is a primary cooling chamber 2, a secondary cooling chamber, which will be described in detail below. A cooling chamber 3 and a moisture supply chamber 4 are respectively formed.

なお、冷却管1上端は開口しており、該開口部から鋳物
砂Sの補給を行い、また、ガス化した冷却剤の放出口と
もなる。
The upper end of the cooling pipe 1 is open, and the foundry sand S is replenished through the opening, and it also serves as a discharge port for the gasified coolant.

まず、2は上記冷却管1の最上部に形成される第1次冷
却室であって、これと隣接して下部に形成される第2次
冷却室3とは下記の仕切壁5によって分けられている。
First, reference numeral 2 denotes a primary cooling chamber formed at the top of the cooling pipe 1, which is separated from a secondary cooling chamber 3 formed adjacently at the bottom by a partition wall 5 described below. ing.

すなわち、該仕切壁5は下方へ向うにしたがい漸次内方
へ向うように円錐状に形成され、そしてこの仕切壁5の
中高位にはガス吹出口6が第1次冷却室2・第2次冷却
室3間を連通すべく形成され、また該仕切壁5の下端中
心部には第1の弁孔7が形成されている。
That is, the partition wall 5 is formed into a conical shape so as to gradually move inward as it goes downward, and gas outlet ports 6 are provided at the middle and high positions of the partition wall 5 for the primary cooling chamber 2 and the secondary cooling chamber 2. The cooling chambers 3 are formed to communicate with each other, and a first valve hole 7 is formed in the center of the lower end of the partition wall 5 .

なお、上記ガス吹出口6には後述する鋳物砂Sが第2次
冷却室3へ向って落下するのを防止するためのひれ8が
形成されている。
Incidentally, a fin 8 is formed in the gas outlet 6 to prevent casting sand S, which will be described later, from falling toward the secondary cooling chamber 3.

9は第1の弁体であって、上記第1次冷却室2の下部中
心部に昇降動可能に設けられ、該弁体9の昇降動rより
前記第1の弁孔7を開口・閉塞する。
Reference numeral 9 denotes a first valve body, which is provided at the center of the lower part of the primary cooling chamber 2 so as to be movable up and down. do.

次に、3は第2次冷却室であって、これと隣接して下部
に形成される水分供給室4とは下記の絞り部10によっ
て分けられている。
Next, reference numeral 3 denotes a secondary cooling chamber, which is separated from a moisture supply chamber 4 formed adjacently below by a constriction section 10 described below.

すなわち、冷却管1の下端から約3分の1高位附近が内
方へ向って断面V字状に絞られることによって絞り部1
0が形成され、そしてこの絞り部10の中心部には第2
の弁孔11が形成されている。
In other words, the area around one-third higher from the lower end of the cooling pipe 1 is narrowed inward to have a V-shaped cross section, so that the narrowed portion 1
0 is formed, and a second
A valve hole 11 is formed.

また、上記第2次冷却室3の下部中心部には第2の弁体
12が昇降動可能に設けられ、該弁体12の昇降動によ
り前記第2の弁孔11を開口・閉塞する。
Further, a second valve body 12 is provided at the center of the lower part of the secondary cooling chamber 3 so as to be movable up and down, and the second valve hole 11 is opened and closed by the up and down movement of the valve body 12.

そこで、上記第2次冷却室3内の前記第1の弁孔7直下
には後述するように鋳物砂Sを筒状で薄肉のカーテン状
にして落下させる正錐傘状のガイド錐13が設けられ、
そして該ガイド錐13直下には液体窒素、液体二酸化炭
素等の冷却剤Rを水平方向にかつ放射状に噴射させる冷
却ノズル14が備えられる。
Therefore, immediately below the first valve hole 7 in the secondary cooling chamber 3, a right conical umbrella-shaped guide cone 13 is provided to drop the foundry sand S in the form of a cylindrical thin-walled curtain, as will be described later. is,
Directly below the guide cone 13 is a cooling nozzle 14 that sprays a coolant R such as liquid nitrogen or liquid carbon dioxide horizontally and radially.

なお、15は冷却剤を供給するための冷却剤供給管であ
る。
Note that 15 is a coolant supply pipe for supplying coolant.

次に、4は水分供給室であって、その下端は内方へ向っ
て絞られて絞り部16が形成され、該絞り部16の下端
中心部には鋳物砂Sを木型内へ供給する砂吐出口17が
穿設されている。
Next, 4 is a moisture supply chamber, the lower end of which is squeezed inward to form a constricted part 16, and the center of the lower end of the constricted part 16 supplies molding sand S into the wooden mold. A sand discharge port 17 is provided.

そこで、上記水分供給室4内の前記第2の弁孔11直下
には後述するように第2次冷却室3で冷却された鋳物砂
Sを筒状で肉薄のカーテン状にして落下させる正錐傘状
のガイド錐18が設けられ、そして該ガイド錐18直下
には水Wを水平方向にかつ放射状に噴出させる水分供給
ノズル19が備えられる。
Therefore, immediately below the second valve hole 11 in the moisture supply chamber 4, as will be described later, the foundry sand S cooled in the secondary cooling chamber 3 is dropped in the form of a cylindrical thin curtain. An umbrella-shaped guide cone 18 is provided, and a water supply nozzle 19 for spouting water W horizontally and radially is provided directly below the guide cone 18.

なお、20は水を供給するための水分供給管である。Note that 20 is a water supply pipe for supplying water.

また、第」次冷却室2及び第2次冷却室3に相当する冷
却管1の外周には断熱材21が外覆されている。
Further, the outer periphery of the cooling pipe 1 corresponding to the secondary cooling chamber 2 and the secondary cooling chamber 3 is covered with a heat insulating material 21.

引きつづいて、上記の実施例の作用を順を追つて具体的
に説明する。
Continuing, the operation of the above embodiment will be specifically explained step by step.

■ まず(第2図参照)、第1の弁孔7を第1の弁体9
で閉塞しそ状態で第1次冷却室2内に鋳物砂Sを投入す
る。
■ First (see Figure 2), insert the first valve hole 7 into the first valve body 9.
The molding sand S is put into the primary cooling chamber 2 in a closed state.

なお、この投入針は1回処理址の2倍以上の鋳物砂Sを
投入するのが望ましい。
Note that it is preferable that this feeding needle feeds at least twice as much molding sand S as the amount to be treated at one time.

これは、後記■の工程での冷却効果を次回処理量の鋳物
砂Sにも利用することができるからである。
This is because the cooling effect in the step ① below can also be used for the foundry sand S to be processed next time.

しかる後、第2の弁孔11を第2の弁体12で閉塞した
状態で冷却剤供給管15のコックを開いて冷却ノズル1
4から冷却剤Rを噴射させる。
Thereafter, with the second valve hole 11 closed by the second valve body 12, the cock of the coolant supply pipe 15 is opened and the cooling nozzle 1 is opened.
Coolant R is injected from step 4.

なお、この際冷却剤Rの噴射方向は前述したとおり水平
でかつ放射状である。
In this case, the injection direction of the coolant R is horizontal and radial as described above.

すると、この噴射された冷却剤Rは、第2次冷却室3の
雰囲気湯度(常温)から、気化情熱を奪い、急速に気化
膨張して大量の低温ガスとなり、ガス吹出口6から第1
次冷却室2内へ向って噴出することとなる。
Then, the injected coolant R deprives the temperature of the atmosphere (room temperature) of the secondary cooling chamber 3 of its vaporization, rapidly expands by vaporization, and becomes a large amount of low-temperature gas, which flows from the gas outlet 6 to the first
It will then be ejected into the cooling chamber 2.

そして、この低部カスは第1次冷却室2内に溜積されて
いる鋳物砂Sの間隙を通過しつつ冷却管1上端開口部か
ら放出されるのであるが、この際、第1次冷却室2内の
鋳物砂Sの予備(第1次)冷却を行うこととなる。
This lower part waste is discharged from the upper end opening of the cooling pipe 1 while passing through the gap of the foundry sand S accumulated in the primary cooling chamber 2. Preliminary (first) cooling of the foundry sand S in the chamber 2 will be performed.

■ 次に(第3図参照)、第1の弁体9を上昇させて第
1の弁孔7を開口させることにより、第1次冷却室2内
の鋳物砂Sを該弁孔γから第2次冷却室2内へ向って落
下させる。
■ Next (see Fig. 3), by raising the first valve body 9 and opening the first valve hole 7, the molding sand S in the primary cooling chamber 2 is removed from the valve hole γ. It is dropped into the secondary cooling chamber 2.

すると、上記第1の弁孔7直下にはガイド錐13が位置
しているため、鋳物砂Sはその落下直後に該ガイド錐1
3の上胴面に沿って下方へ案内される。
Then, since the guide aperture 13 is located directly below the first valve hole 7, the molding sand S falls into the guide aperture 1 immediately after falling.
It is guided downward along the upper body surface of 3.

この結果、ガイド錐13T方においては、鋳物砂Sの流
動形状は円筒状で薄肉のカーテン状に形成される。
As a result, on the guide cone 13T side, the flowing shape of the casting sand S is formed into a cylindrical, thin-walled curtain shape.

(第5図も併せて参照)このことは、ガイド錐13直下
で噴射される冷却剤Rが鋳物砂Sを均等疋かつ充分に鋳
物砂Sの芯にまで冷却させること(−40℃±15℃に
冷却)を意味し、この冷却効果は著しく良好である。
(See also Figure 5.) This means that the coolant R injected directly below the guide cone 13 cools the foundry sand S evenly and sufficiently to the core of the foundry sand S (-40°C ± 15°C). ℃), and this cooling effect is extremely good.

■ 次に、第2次冷却室3内に所望量の本(第2次)冷
却された鋳物砂Sが溜積したら、冷却剤Rの供給を停止
し、第1の弁孔1を閉塞して第2の弁孔11を開口する
■Next, when the desired amount of (secondary) cooled foundry sand S has accumulated in the second cooling chamber 3, the supply of the coolant R is stopped and the first valve hole 1 is closed. to open the second valve hole 11.

すると、鋳物砂Sは第2の弁孔11を通って水分供給室
4内へ向って落下するのであるが、この際も前記■の工
程と同様にガイド錐18により鋳物砂Sの流動形状は円
筒状で薄肉のカーテン状に形成されることとなる。
Then, the molding sand S passes through the second valve hole 11 and falls into the moisture supply chamber 4, but at this time as well, the flow shape of the molding sand S is controlled by the guide aperture 18 in the same manner as in step (2) above. It is formed into a cylindrical and thin curtain shape.

このことは、ガイド錐18直下で噴射される水分Wが鋳
物砂Rの粒子の表面にほぼ均等に供給されることを意味
する。
This means that the water W injected directly below the guide cone 18 is almost evenly supplied to the surface of the particles of the foundry sand R.

なお、水分供給室4内の雰囲気温度は常温であり、かつ
供給された水分の温度が常温であることから、鋳物砂S
粒子表面の水は該鋳物砂Sから冷却はされるものの瞬間
的には凍結しなく、したがって鋳物砂Sは流動性を保持
したまま水分供給室4内を下方へ向って落下する。
Note that since the atmospheric temperature in the moisture supply chamber 4 is at room temperature and the temperature of the supplied moisture is at room temperature, the foundry sand S
Although the water on the surface of the particles is cooled by the foundry sand S, it does not freeze instantaneously, and therefore, the foundry sand S falls downward in the water supply chamber 4 while maintaining its fluidity.

■ しこうして、鋳物砂Sは砂吐出口17を通って木型
(図示せず)内へ充填され、この時点で鋳物砂S粒子表
面の水分ははじめて凍結し、この凍結により鋳物砂Sは
木型内で自動的に固型化することとなり、抜型に充分に
必要な強度が得られることとなる。
■ In this way, the foundry sand S passes through the sand discharge port 17 and is filled into the wooden mold (not shown), and at this point, the water on the surface of the foundry sand S particles freezes for the first time, and this freezing causes the foundry sand S to become wooden. It will automatically solidify within the mold, providing sufficient strength for cutting.

以上の説明から明らかなように、本発明にあっては鋳物
砂Sを木型内に充填させる前の段階で予め鋳物砂を冷却
しておくとともに、該鋳物砂粒子の表面に水分を供給し
ておき、その後砂を木型内に充填させた時点で砂粒子表
面の水を凍結せしめることにより、鋳型を造形するもの
であり、この点で従来の生型造型に伴なう型崩れが生ず
る余地がなくなる。
As is clear from the above description, in the present invention, the molding sand S is cooled in advance before being filled into the wooden mold, and moisture is supplied to the surface of the molding sand particles. After that, the water on the surface of the sand particles is frozen when the sand is filled into the wooden mold to form the mold, which causes the mold to collapse as with conventional green molding. There's no room left.

また、鋳物砂Sへの冷却を予備(第1次)冷却と本(第
2次)冷却との2段階で行なわしめ、しかも本(第2次
)冷却の段階では鋳物砂Sの流動形状を円筒状で薄肉の
カーテン状にして冷却が行われるものであるから、鋳物
砂Sは充分に冷却され、この冷却効果は著しく良好であ
る。
In addition, cooling of the foundry sand S is performed in two stages: preliminary (first) cooling and main (secondary) cooling, and the flow shape of the foundry sand S is changed in the main (secondary) cooling stage. Since the cooling is carried out in a cylindrical, thin-walled curtain, the foundry sand S is sufficiently cooled, and this cooling effect is extremely good.

さらに、木型内に充填された鋳物砂は、鋳型芯部の鋳物
砂Sも鋳型表面の鋳物砂Sに対し同等の条件のもとで冷
却されていることから、該鋳物砂S表面の水分が凍結す
る場合には、鋳型の表面或は芯部にかかわらず水分には
同等の凍結能が期待される。
Furthermore, since the molding sand filled in the wooden mold is cooled under the same conditions as the molding sand S in the mold core and the molding sand S on the mold surface, moisture content on the surface of the molding sand S increases. When freezing, water is expected to have the same freezing ability regardless of whether it is on the surface or the core of the mold.

なお、木型へ充填する場合の鋳物砂の流動性を助長し、
また凍結時間を調整する目的で水分に界面活性剤を添加
してもよい。
In addition, it promotes the fluidity of the foundry sand when filling it into the wooden mold,
Further, a surfactant may be added to the water for the purpose of adjusting the freezing time.

すなわち、本発明は、特許請求の範囲に記載した発明に
より上記効果を発揮するものであるから、冷凍鋳型の造
型法として資するところきわめて大である。
That is, since the present invention exhibits the above-mentioned effects by the invention described in the claims, it is extremely useful as a method for manufacturing frozen molds.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は近時開発された冷凍鋳型の造型法を示す路体説
明図、第2図〜第5図は本発明の一実施例を示し、第2
図〜第4図はそれぞれ本例の作用効果を示す本装置の縦
断面図、第5図は第3図のX−X線矢視図である。 2・・・・・・第4次冷却室、3・・・・・・第2次冷
却室、4・・・・・・水分供給室、7・・・・・・第1
の弁孔、9・・・・・・第1の弁体、11・・・・・・
第2の弁孔、12・・・・・・第2の弁体、13.18
・・・・・・ガイド錐、14・・・・・・冷却ノズル、
19・・・・・・水分供給ノズル、s−s’・・・・・
・鋳物砂、R・・・・・・冷却剤、W・・・・・・水分
Fig. 1 is an explanatory diagram of a road body showing a recently developed freezing mold manufacturing method, Figs. 2 to 5 show an embodiment of the present invention;
4 to 4 are longitudinal cross-sectional views of the present device showing the effects of this example, respectively, and FIG. 5 is a view taken along the line X--X in FIG. 3. 2...Fourth cooling chamber, 3...Second cooling chamber, 4...Moisture supply chamber, 7...First
valve hole, 9...first valve body, 11...
Second valve hole, 12...Second valve body, 13.18
...Guide awl, 14...Cooling nozzle,
19... Moisture supply nozzle, s-s'...
- Foundry sand, R...coolant, W...moisture.

Claims (1)

【特許請求の範囲】 1 鋳物砂を型内に充填させる前の段階において、予め
鋳物砂を冷却しておき、その後冷却された鋳物砂をその
砂粒子の表面に水分を供給しながら前記型内に充填させ
るようにすることを特徴とする冷凍鋳型の造型法。 2 弁により開閉可能な第1の弁孔が下端に設けられた
第1次冷却室と、弁により開閉可能な第2の弁孔が下端
に設けられるとともに前記第1の弁孔直下に正錐傘状の
ガイド錐が設けられ、かつ該ガイド錐直下には冷却剤を
水平放射状に噴射させる冷却ノズルが設けられた第2次
冷却室と、前記第2の弁孔直下に正錐傘状のガイド錐が
設けられるとともに該ガイド錐直下疋は水分を水平放射
状に噴射させる水分供給ノズルが設けられた水分供給室
とを備えて構成したことを特徴とする冷凍鋳型の造型装
置。
[Scope of Claims] 1. Before filling the mold with molding sand, the molding sand is cooled in advance, and then the cooled molding sand is poured into the mold while supplying moisture to the surface of the sand particles. A method for making a frozen mold, characterized by filling the mold with 2. A primary cooling chamber in which a first valve hole that can be opened and closed by a valve is provided at the lower end, a second valve hole that can be opened and closed by a valve is provided at the lower end, and a right conical hole is provided directly below the first valve hole. A secondary cooling chamber is provided with an umbrella-shaped guide aperture, and a secondary cooling chamber is provided with a cooling nozzle that injects coolant horizontally and radially just below the guide aperture, and a right-cone umbrella-shaped is provided directly below the second valve hole. 1. A freezing mold making apparatus characterized in that a guide aperture is provided, and the gutter directly below the guide aperture is provided with a moisture supply chamber provided with a moisture supply nozzle that sprays moisture horizontally and radially.
JP7342378A 1978-06-17 1978-06-17 Freezing mold manufacturing method and its equipment Expired JPS592575B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP7342378A JPS592575B2 (en) 1978-06-17 1978-06-17 Freezing mold manufacturing method and its equipment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP7342378A JPS592575B2 (en) 1978-06-17 1978-06-17 Freezing mold manufacturing method and its equipment

Publications (2)

Publication Number Publication Date
JPS551905A JPS551905A (en) 1980-01-09
JPS592575B2 true JPS592575B2 (en) 1984-01-19

Family

ID=13517792

Family Applications (1)

Application Number Title Priority Date Filing Date
JP7342378A Expired JPS592575B2 (en) 1978-06-17 1978-06-17 Freezing mold manufacturing method and its equipment

Country Status (1)

Country Link
JP (1) JPS592575B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60130074U (en) * 1984-02-09 1985-08-31 米良 勅夫 overlay
JPS60166580U (en) * 1984-04-11 1985-11-05 中津紙工株式会社 clear file

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK151776C (en) * 1980-06-23 1988-08-15 Dansk Ind Syndikat PROCEDURE FOR THE PREPARATION OF FROZEN CASTLE OR CORE
JPS59166343A (en) * 1983-03-14 1984-09-19 Mitsubishi Heavy Ind Ltd Production of casting mold
CN104985116B (en) * 2015-05-29 2017-10-10 机械科学研究总院先进制造技术研究中心 A kind of manufacturing process and device of 3D printing ice mold casting sand mold

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60130074U (en) * 1984-02-09 1985-08-31 米良 勅夫 overlay
JPS60166580U (en) * 1984-04-11 1985-11-05 中津紙工株式会社 clear file

Also Published As

Publication number Publication date
JPS551905A (en) 1980-01-09

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