JPS60215517A - 結晶性アルミノシリケートゼオライト及び有機原料の転化触媒 - Google Patents

結晶性アルミノシリケートゼオライト及び有機原料の転化触媒

Info

Publication number: JPS60215517A
Authority: JP; Japan
Prior art keywords: zeolite composition; conversion catalyst; zeolite; catalyst according; composition
Prior art date: 1985-03-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP60048459A

Other languages

English (en)

Japanese (ja)

Other versions

JPS6257573B2 (fr

Inventor

ロジヤー・アラン・モリソン

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Mobil Oil AS

Original Assignee

Mobil Oil AS

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-03-13

Filing date

1985-03-13

Publication date

1985-10-28

1985-03-13 Application filed by Mobil Oil AS filed Critical Mobil Oil AS

1985-03-13 Priority to JP60048459A priority Critical patent/JPS60215517A/ja

1985-10-28 Publication of JPS60215517A publication Critical patent/JPS60215517A/ja

1987-12-01 Publication of JPS6257573B2 publication Critical patent/JPS6257573B2/ja

Status Granted legal-status Critical Current

Links

HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title claims description 82
239000010457 zeolite Substances 0.000 title claims description 78
229910021536 Zeolite Inorganic materials 0.000 title claims description 69
239000003054 catalyst Substances 0.000 title claims description 64
238000006243 chemical reaction Methods 0.000 title claims description 53
229910000323 aluminium silicate Inorganic materials 0.000 title claims description 16
239000002994 raw material Substances 0.000 title description 6
239000000203 mixture Substances 0.000 claims description 57
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 31
150000001768 cations Chemical class 0.000 claims description 25
229910052751 metal Inorganic materials 0.000 claims description 23
239000002184 metal Substances 0.000 claims description 23
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 19
-1 nitrogen-containing cation Chemical group 0.000 claims description 18
229910052739 hydrogen Inorganic materials 0.000 claims description 16
239000001257 hydrogen Substances 0.000 claims description 15
229910052697 platinum Inorganic materials 0.000 claims description 15
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 11
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 10
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 9
229910052804 chromium Inorganic materials 0.000 claims description 9
239000011651 chromium Substances 0.000 claims description 9
229910052738 indium Inorganic materials 0.000 claims description 9
APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 9
239000000377 silicon dioxide Substances 0.000 claims description 9
229910052720 vanadium Inorganic materials 0.000 claims description 9
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 8
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 8
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 8
BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 8
229910052796 boron Inorganic materials 0.000 claims description 8
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 8
229910052753 mercury Inorganic materials 0.000 claims description 8
229910052750 molybdenum Inorganic materials 0.000 claims description 8
239000011733 molybdenum Substances 0.000 claims description 8
229910052707 ruthenium Inorganic materials 0.000 claims description 8
229910052709 silver Inorganic materials 0.000 claims description 8
239000004332 silver Substances 0.000 claims description 8
229910052714 tellurium Inorganic materials 0.000 claims description 8
PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims description 8
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
150000002739 metals Chemical class 0.000 claims description 7
229910052782 aluminium Inorganic materials 0.000 claims description 6
229910052763 palladium Inorganic materials 0.000 claims description 5
230000000737 periodic effect Effects 0.000 claims description 5
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
239000011734 sodium Substances 0.000 claims description 4
229910052708 sodium Inorganic materials 0.000 claims description 4
125000004432 carbon atom Chemical group C* 0.000 claims description 3
229910052760 oxygen Inorganic materials 0.000 claims description 3
125000005210 alkyl ammonium group Chemical group 0.000 claims description 2
235000012239 silicon dioxide Nutrition 0.000 claims description 2
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 6
229910052684 Cerium Inorganic materials 0.000 claims 3
GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 3
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
229910052799 carbon Inorganic materials 0.000 claims 1
229910052681 coesite Inorganic materials 0.000 claims 1
229910052906 cristobalite Inorganic materials 0.000 claims 1
229910052682 stishovite Inorganic materials 0.000 claims 1
229910052905 tridymite Inorganic materials 0.000 claims 1
238000000034 method Methods 0.000 description 19
229930195733 hydrocarbon Natural products 0.000 description 15
150000002430 hydrocarbons Chemical class 0.000 description 15
239000004215 Carbon black (E152) Substances 0.000 description 12
239000000047 product Substances 0.000 description 11
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 10
238000005342 ion exchange Methods 0.000 description 10
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 9
239000013078 crystal Substances 0.000 description 9
230000003197 catalytic effect Effects 0.000 description 7
150000001845 chromium compounds Chemical class 0.000 description 7
239000000463 material Substances 0.000 description 7
239000011541 reaction mixture Substances 0.000 description 7
239000000126 substance Substances 0.000 description 7
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
238000010438 heat treatment Methods 0.000 description 6
238000006317 isomerization reaction Methods 0.000 description 6
238000002441 X-ray diffraction Methods 0.000 description 5
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
239000008096 xylene Substances 0.000 description 5
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
150000001875 compounds Chemical class 0.000 description 4
238000001035 drying Methods 0.000 description 4
150000002500 ions Chemical class 0.000 description 4
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
239000007788 liquid Substances 0.000 description 4
239000011159 matrix material Substances 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
229910001868 water Inorganic materials 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
239000004115 Sodium Silicate Substances 0.000 description 3
MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 3
229910052783 alkali metal Inorganic materials 0.000 description 3
235000012211 aluminium silicate Nutrition 0.000 description 3
125000003118 aryl group Chemical group 0.000 description 3
239000011575 calcium Substances 0.000 description 3
238000004517 catalytic hydrocracking Methods 0.000 description 3
239000000571 coke Substances 0.000 description 3
230000018044 dehydration Effects 0.000 description 3
238000006297 dehydration reaction Methods 0.000 description 3
239000000499 gel Substances 0.000 description 3
238000005984 hydrogenation reaction Methods 0.000 description 3
238000004519 manufacturing process Methods 0.000 description 3
239000011148 porous material Substances 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
229910052710 silicon Chemical group 0.000 description 3
239000010703 silicon Chemical group 0.000 description 3
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
229910052911 sodium silicate Inorganic materials 0.000 description 3
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 3
239000005995 Aluminium silicate Substances 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 2
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
239000002253 acid Substances 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
239000011230 binding agent Substances 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
238000004523 catalytic cracking Methods 0.000 description 2
239000002131 composite material Substances 0.000 description 2
238000002425 crystallisation Methods 0.000 description 2
230000008025 crystallization Effects 0.000 description 2
238000006356 dehydrogenation reaction Methods 0.000 description 2
238000007323 disproportionation reaction Methods 0.000 description 2
238000001914 filtration Methods 0.000 description 2
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
229910052737 gold Inorganic materials 0.000 description 2
239000010931 gold Substances 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 2
239000011572 manganese Substances 0.000 description 2
229910052748 manganese Inorganic materials 0.000 description 2
229910044991 metal oxide Inorganic materials 0.000 description 2
150000004706 metal oxides Chemical class 0.000 description 2
238000002156 mixing Methods 0.000 description 2
239000002808 molecular sieve Substances 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
239000003921 oil Substances 0.000 description 2
125000004430 oxygen atom Chemical group O* 0.000 description 2
239000002245 particle Substances 0.000 description 2
238000005504 petroleum refining Methods 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
238000000634 powder X-ray diffraction Methods 0.000 description 2
229910052761 rare earth metal Inorganic materials 0.000 description 2
150000002910 rare earth metals Chemical class 0.000 description 2
239000000376 reactant Substances 0.000 description 2
238000002407 reforming Methods 0.000 description 2
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
235000012976 tarts Nutrition 0.000 description 2
BGQMOFGZRJUORO-UHFFFAOYSA-M tetrapropylammonium bromide Chemical compound [Br-].CCC[N+](CCC)(CCC)CCC BGQMOFGZRJUORO-UHFFFAOYSA-M 0.000 description 2
238000011282 treatment Methods 0.000 description 2
229910052725 zinc Inorganic materials 0.000 description 2
239000011701 zinc Substances 0.000 description 2
DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
241000771208 Buchanania arborescens Species 0.000 description 1
241000723346 Cinnamomum camphora Species 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 1
244000182067 Fraxinus ornus Species 0.000 description 1
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
241000282373 Panthera pardus Species 0.000 description 1
241000219289 Silene Species 0.000 description 1
FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
239000003463 adsorbent Substances 0.000 description 1
OFHCOWSQAMBJIW-AVJTYSNKSA-N alfacalcidol Chemical compound C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C\C=C1\C[C@@H](O)C[C@H](O)C1=C OFHCOWSQAMBJIW-AVJTYSNKSA-N 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
238000005804 alkylation reaction Methods 0.000 description 1
HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
238000005899 aromatization reaction Methods 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
239000011324 bead Substances 0.000 description 1
239000000440 bentonite Substances 0.000 description 1
229910000278 bentonite Inorganic materials 0.000 description 1
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 1
238000009835 boiling Methods 0.000 description 1
150000003842 bromide salts Chemical class 0.000 description 1
229910052918 calcium silicate Inorganic materials 0.000 description 1
229960000846 camphor Drugs 0.000 description 1
229930008380 camphor Natural products 0.000 description 1
125000002091 cationic group Chemical class 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000003841 chloride salts Chemical class 0.000 description 1
RCTYPNKXASFOBE-UHFFFAOYSA-M chloromercury Chemical compound [Hg]Cl RCTYPNKXASFOBE-UHFFFAOYSA-M 0.000 description 1
239000010724 circulating oil Substances 0.000 description 1
239000004927 clay Substances 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
238000010960 commercial process Methods 0.000 description 1
230000000295 complement effect Effects 0.000 description 1
230000003750 conditioning effect Effects 0.000 description 1
238000001816 cooling Methods 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
238000005336 cracking Methods 0.000 description 1
238000006477 desulfuration reaction Methods 0.000 description 1
230000023556 desulfurization Effects 0.000 description 1
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
230000029087 digestion Effects 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
238000009826 distribution Methods 0.000 description 1
238000005516 engineering process Methods 0.000 description 1
125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
239000007863 gel particle Substances 0.000 description 1
239000008187 granular material Substances 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
238000007654 immersion Methods 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
229910052809 inorganic oxide Inorganic materials 0.000 description 1
239000000077 insect repellent Substances 0.000 description 1
229910052622 kaolinite Inorganic materials 0.000 description 1
238000004898 kneading Methods 0.000 description 1
210000003127 knee Anatomy 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
239000000395 magnesium oxide Substances 0.000 description 1
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
239000011738 major mineral Substances 0.000 description 1
235000011963 major mineral Nutrition 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
150000002736 metal compounds Chemical class 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 1
229910052901 montmorillonite Inorganic materials 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
229910000510 noble metal Inorganic materials 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
239000012071 phase Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
229910052702 rhenium Inorganic materials 0.000 description 1
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
238000007086 side reaction Methods 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
CQLFBEKRDQMJLZ-UHFFFAOYSA-M silver acetate Chemical compound [Ag+].CC([O-])=O CQLFBEKRDQMJLZ-UHFFFAOYSA-M 0.000 description 1
229940071536 silver acetate Drugs 0.000 description 1
238000002791 soaking Methods 0.000 description 1
229910001388 sodium aluminate Inorganic materials 0.000 description 1
229910001415 sodium ion Inorganic materials 0.000 description 1
KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
229910001948 sodium oxide Inorganic materials 0.000 description 1
239000012265 solid product Substances 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
238000003756 stirring Methods 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
125000005207 tetraalkylammonium group Chemical group 0.000 description 1
HWCKGOZZJDHMNC-UHFFFAOYSA-M tetraethylammonium bromide Chemical compound [Br-].CC[N+](CC)(CC)CC HWCKGOZZJDHMNC-UHFFFAOYSA-M 0.000 description 1
OSBSFAARYOCBHB-UHFFFAOYSA-N tetrapropylammonium Chemical class CCC[N+](CCC)(CCC)CCC OSBSFAARYOCBHB-UHFFFAOYSA-N 0.000 description 1
LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 description 1
GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
239000010937 tungsten Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1
238000005303 weighing Methods 0.000 description 1

Classifications

- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

JP60048459A 1985-03-13 1985-03-13 結晶性アルミノシリケートゼオライト及び有機原料の転化触媒 Granted JPS60215517A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP60048459A JPS60215517A (ja)	1985-03-13	1985-03-13	結晶性アルミノシリケートゼオライト及び有機原料の転化触媒

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP60048459A JPS60215517A (ja)	1985-03-13	1985-03-13	結晶性アルミノシリケートゼオライト及び有機原料の転化触媒

Publications (2)

Publication Number	Publication Date
JPS60215517A true JPS60215517A (ja)	1985-10-28
JPS6257573B2 JPS6257573B2 (fr)	1987-12-01

Family

ID=12803943

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP60048459A Granted JPS60215517A (ja)	1985-03-13	1985-03-13	結晶性アルミノシリケートゼオライト及び有機原料の転化触媒

Country Status (1)

Country	Link
JP (1)	JPS60215517A (fr)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5355500A (en) *	1976-10-18	1978-05-19	Standard Oil Co	Crystalline borosilicate and method of conversing hydrocarbon using same

1985
- 1985-03-13 JP JP60048459A patent/JPS60215517A/ja active Granted

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS5355500A (en) *	1976-10-18	1978-05-19	Standard Oil Co	Crystalline borosilicate and method of conversing hydrocarbon using same

Also Published As

Publication number	Publication date
JPS6257573B2 (fr)	1987-12-01

Publication	Publication Date	Title
US4327236A (en)	1982-04-27	Hydrocarbon-conversion catalyst and its method of preparation
US4268420A (en)	1981-05-19	Hydrocarbon-conversion catalyst and its method of preparation
EP0057049B1 (fr)	1984-03-14	Aluminosilicates cristallins et leur utilisation comme catalyseurs
US4269813A (en)	1981-05-26	Crystalline borosilicate and process of preparation
GB2033358A (en)	1980-05-21	Crystalline Zeolite Compositions
US3972983A (en)	1976-08-03	Crystalline zeolite ZSM-20 and method of preparing same
US3702886A (en)	1972-11-14	Crystalline zeolite zsm-5 and method of preparing the same
US4021331A (en)	1977-05-03	Organic compound conversion by zeolite ZSM-20 catalysts
US3970544A (en)	1976-07-20	Hydrocarbon conversion with ZSM-12
US3699139A (en)	1972-10-17	Synthetic crystalline aluminosilicate
US4247416A (en)	1981-01-27	Crystalline zeolite ZSM-25
JPS59136138A (ja)	1984-08-04	スチ−ム脱活性化された触媒の再活性化方法
JPH02222727A (ja)	1990-09-05	ゼオライトを含む触媒及びその製造方法
JPS6172618A (ja)	1986-04-14	ゼオライト、その合成方法及びそれを用いた有機転化反応
JPS6341851B2 (fr)	1988-08-19
JPS6215486B2 (fr)	1987-04-08
US4289607A (en)	1981-09-15	Catalytic conversion with crystalline zeolite product constituting ZSM-5/ZSM-11 intermediates
USRE29857E (en)	1978-12-05	Conversion with ZSM-5 family of crystalline aluminosilicate zeolites
JPS6331257B2 (fr)	1988-06-23
JPH0675679B2 (ja)	1994-09-28	高活性・高選択性の芳香族化触媒
US3783124A (en)	1974-01-01	Hydrocarbon conversion with novel zeolite
JPS6215489B2 (fr)	1987-04-08
JPH0576453B2 (fr)	1993-10-22
EP0188913A2 (fr)	1986-07-30	Composition catalytique sélective quant à la forme contenant des métaux du groupe VIII et consistant en un silicate cristallin et poreux
US6869587B2 (en)	2005-03-22	Crystalline molecular sieve composition MCM-65, its synthesis and use