JPS606896B2 - 有機溶媒相中のインジウムの逆抽出方法 - Google Patents
有機溶媒相中のインジウムの逆抽出方法Info
- Publication number
- JPS606896B2 JPS606896B2 JP56156529A JP15652981A JPS606896B2 JP S606896 B2 JPS606896 B2 JP S606896B2 JP 56156529 A JP56156529 A JP 56156529A JP 15652981 A JP15652981 A JP 15652981A JP S606896 B2 JPS606896 B2 JP S606896B2
- Authority
- JP
- Japan
- Prior art keywords
- indium
- organic solvent
- solvent phase
- hydrochloric acid
- extractant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052738 indium Inorganic materials 0.000 title claims description 73
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 title claims description 73
- 239000003960 organic solvent Substances 0.000 title claims description 40
- 238000000034 method Methods 0.000 title claims description 17
- 238000000605 extraction Methods 0.000 title description 26
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 65
- 239000007864 aqueous solution Substances 0.000 claims description 27
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 229910001510 metal chloride Inorganic materials 0.000 claims description 6
- 239000002585 base Substances 0.000 claims description 5
- 229910001514 alkali metal chloride Inorganic materials 0.000 claims 1
- 229910001617 alkaline earth metal chloride Inorganic materials 0.000 claims 1
- 239000000243 solution Substances 0.000 description 17
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 14
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 14
- 239000003350 kerosene Substances 0.000 description 8
- 239000011780 sodium chloride Substances 0.000 description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 6
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
- 150000001805 chlorine compounds Chemical class 0.000 description 4
- 235000011007 phosphoric acid Nutrition 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 235000011164 potassium chloride Nutrition 0.000 description 3
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 2
- ZDFBXXSHBTVQMB-UHFFFAOYSA-N 2-ethylhexoxy(2-ethylhexyl)phosphinic acid Chemical compound CCCCC(CC)COP(O)(=O)CC(CC)CCCC ZDFBXXSHBTVQMB-UHFFFAOYSA-N 0.000 description 2
- 239000004808 2-ethylhexylester Substances 0.000 description 2
- JJJOZVFVARQUJV-UHFFFAOYSA-N 2-ethylhexylphosphonic acid Chemical compound CCCCC(CC)CP(O)(O)=O JJJOZVFVARQUJV-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical group 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- -1 mono-2-ethylhexyl Chemical group 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000000638 solvent extraction Methods 0.000 description 2
- 229940087291 tridecyl alcohol Drugs 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- DHIXFTVGHROZHD-UHFFFAOYSA-N 2-ethylhexane-1-sulfonic acid Chemical compound CCCCC(CC)CS(O)(=O)=O DHIXFTVGHROZHD-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- 208000021124 Heritable pulmonary arterial hypertension Diseases 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 150000001243 acetic acids Chemical class 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 229910001449 indium ion Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- DJDSLBVSSOQSLW-UHFFFAOYSA-N mono(2-ethylhexyl) phthalate Chemical group CCCCC(CC)COC(=O)C1=CC=CC=C1C(O)=O DJDSLBVSSOQSLW-UHFFFAOYSA-N 0.000 description 1
- 150000004712 monophosphates Chemical class 0.000 description 1
- YNCODRLFXWRMSN-YVLHZVERSA-N n-[(z)-(4-methoxyphenyl)methylideneamino]phthalazin-1-amine Chemical compound C1=CC(OC)=CC=C1\C=N/NC1=NN=CC2=CC=CC=C12 YNCODRLFXWRMSN-YVLHZVERSA-N 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000002639 sodium chloride Nutrition 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G15/00—Compounds of gallium, indium or thallium
- C01G15/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
- C22B3/3844—Phosphonic acid, e.g. H2P(O)(OH)2
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Geochemistry & Mineralogy (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Extraction Or Liquid Replacement (AREA)
- Manufacture And Refinement Of Metals (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56156529A JPS606896B2 (ja) | 1981-10-01 | 1981-10-01 | 有機溶媒相中のインジウムの逆抽出方法 |
| DE3235693A DE3235693C2 (de) | 1981-10-01 | 1982-09-27 | Verfahren zur Rückextraktion von Indiumionen aus einer organischen Lösungsmittelphase |
| BE0/209114A BE894530A (fr) | 1981-10-01 | 1982-09-29 | Procede d'extraction en retour de l'indium de certaines phases de solvant organique |
| CA000412521A CA1193443A (fr) | 1981-10-01 | 1982-09-30 | Extraction de l'indium a contre-courant dans la phase du solvant organique |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56156529A JPS606896B2 (ja) | 1981-10-01 | 1981-10-01 | 有機溶媒相中のインジウムの逆抽出方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5860619A JPS5860619A (ja) | 1983-04-11 |
| JPS606896B2 true JPS606896B2 (ja) | 1985-02-21 |
Family
ID=15629778
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56156529A Expired JPS606896B2 (ja) | 1981-10-01 | 1981-10-01 | 有機溶媒相中のインジウムの逆抽出方法 |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS606896B2 (fr) |
| BE (1) | BE894530A (fr) |
| CA (1) | CA1193443A (fr) |
| DE (1) | DE3235693C2 (fr) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60145913A (ja) * | 1984-01-05 | 1985-08-01 | Sumitomo Chem Co Ltd | キレ−ト樹脂に吸着したインジウムの溶離方法 |
| JPS62141125A (ja) * | 1985-12-09 | 1987-06-24 | Nitto Boseki Co Ltd | ピツチ繊維の不融化および炭化焼成処理方法および装置 |
| FR2623522B1 (fr) * | 1987-11-24 | 1990-04-20 | Metaleurop Sa | Procede de traitement hydrometallurgique d'une solution de chlorure d'indium |
| RU2233900C1 (ru) * | 2003-06-30 | 2004-08-10 | Открытое Акционерное Общество "Челябинский цинковый завод" | Способ концентрирования индия из сульфатных растворов |
| FI125933B (en) * | 2014-06-05 | 2016-04-15 | Outotec Finland Oy | Gold extraction with solvents |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55148737A (en) * | 1979-05-11 | 1980-11-19 | Nippon Mining Co Ltd | Selective separation of indium |
-
1981
- 1981-10-01 JP JP56156529A patent/JPS606896B2/ja not_active Expired
-
1982
- 1982-09-27 DE DE3235693A patent/DE3235693C2/de not_active Expired
- 1982-09-29 BE BE0/209114A patent/BE894530A/fr not_active IP Right Cessation
- 1982-09-30 CA CA000412521A patent/CA1193443A/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CA1193443A (fr) | 1985-09-17 |
| BE894530A (fr) | 1983-01-17 |
| DE3235693C2 (de) | 1985-05-02 |
| DE3235693A1 (de) | 1983-04-21 |
| JPS5860619A (ja) | 1983-04-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4288304A (en) | Hydrometallurgical process for treatment of sulphur ores | |
| CN109576510B (zh) | 从锌置换渣中回收镓的方法 | |
| EP0388250A1 (fr) | Procédé de traitement de minerais de terres rares | |
| US4090871A (en) | Process for the recovery and purification of germanium from zinc ores | |
| CN109852797A (zh) | 一种用于萃取分离锂元素的萃取溶剂及其萃取分离锂元素的方法 | |
| JPS5992915A (ja) | 置換ヒドロキシキノリン及び有機りん化合物によるガリウムの抽出方法 | |
| US4624704A (en) | Selective recovery of zinc from metal containing brines | |
| EP0008992B1 (fr) | Procédé de récupération de l'indium | |
| JPS606896B2 (ja) | 有機溶媒相中のインジウムの逆抽出方法 | |
| US4051219A (en) | Method of preparing fluorine-free rare earth metal compounds from such compounds containing fluorine | |
| JP2000511234A (ja) | 金属回収のためのフルオロホウ酸鉄(▲iii▼)抽出剤湿式冶金法 | |
| SU1215615A3 (ru) | Способ очистки растворов хлорида натри | |
| FI75603C (fi) | Foerfarande foer gemensam utvinning av uran, yttrium, torium och saellsynta jordartsmetaller ur en organisk fas. | |
| US3809624A (en) | Mixed ore treatment of ocean floor nodule ore and iron sulfidic land based ores | |
| EP0298763A2 (fr) | Procédé pour récupérer du titane | |
| KR930007139B1 (ko) | 갈륨을 함유하는 염기성 용액으로부터 갈륨의 회수방법 | |
| US4275037A (en) | Stripping metals from organic solvent with aqueous solution of polymeric phosphates | |
| US3449074A (en) | Process for removing titanium and vanadium from phosphoric acid | |
| RU2260063C2 (ru) | Экстрагент для извлечения металлов и способ его получения | |
| US4127640A (en) | Purification of phosphoric acid by solvent extraction using hexanones | |
| US4836956A (en) | Extraction of polyvalent metals with organodiphosphonic acids | |
| JP2814507B2 (ja) | 塩化インジウム溶液の湿式精錬処理法 | |
| JPH03162529A (ja) | 水溶液からの鉄イオンの抽出方法および抽出溶媒からの鉄イオンの逆抽出方法 | |
| CA1212516A (fr) | Procede de valorisation de l'uranium et des terres rares contenus dans de l'uf.sub.4 impur provenant de l'extraction de l'uranium de l'acide phosphorique | |
| JPS6112010B2 (fr) |