JPS606981B2 - 炭素質物質の水素化処理 - Google Patents

炭素質物質の水素化処理

Info

Publication number: JPS606981B2
Authority: JP; Japan
Prior art keywords: coal; reaction; hydrogen sulfide; reagent; alkali metal
Prior art date: 1980-04-15
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP56056857A

Other languages

English (en)

Japanese (ja)

Other versions

JPS5774389A (en

Inventor

ロ−ラン・スワンソン

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Individual

Original Assignee

Individual

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1980-04-15

Filing date

1981-04-14

Publication date

1985-02-21

1981-04-14 Application filed by Individual filed Critical Individual

1982-05-10 Publication of JPS5774389A publication Critical patent/JPS5774389A/ja

1985-02-21 Publication of JPS606981B2 publication Critical patent/JPS606981B2/ja

Status Expired legal-status Critical Current

Links

239000003575 carbonaceous material Substances 0.000 title description 4
239000003153 chemical reaction reagent Substances 0.000 claims description 120
239000003245 coal Substances 0.000 claims description 105
238000006243 chemical reaction Methods 0.000 claims description 83
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 71
229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 68
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 64
229910052717 sulfur Inorganic materials 0.000 claims description 61
239000011593 sulfur Substances 0.000 claims description 60
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 50
238000000034 method Methods 0.000 claims description 45
239000000203 mixture Substances 0.000 claims description 44
239000000047 product Substances 0.000 claims description 44
150000002430 hydrocarbons Chemical class 0.000 claims description 38
229930195733 hydrocarbon Natural products 0.000 claims description 37
239000007788 liquid Substances 0.000 claims description 31
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 24
239000007789 gas Substances 0.000 claims description 24
239000001301 oxygen Substances 0.000 claims description 24
229910052760 oxygen Inorganic materials 0.000 claims description 24
239000004215 Carbon black (E152) Substances 0.000 claims description 20
230000008569 process Effects 0.000 claims description 19
239000003415 peat Substances 0.000 claims description 18
239000002023 wood Substances 0.000 claims description 15
229910052783 alkali metal Inorganic materials 0.000 claims description 14
238000000354 decomposition reaction Methods 0.000 claims description 14
229920001021 polysulfide Polymers 0.000 claims description 13
239000005077 polysulfide Substances 0.000 claims description 13
150000008117 polysulfides Polymers 0.000 claims description 13
-1 alkali metal bisulfide Chemical class 0.000 claims description 11
150000004763 sulfides Chemical class 0.000 claims description 11
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 9
RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 claims description 9
239000003830 anthracite Substances 0.000 claims description 9
229910052700 potassium Inorganic materials 0.000 claims description 9
239000011591 potassium Substances 0.000 claims description 9
239000003077 lignite Substances 0.000 claims description 8
150000001340 alkali metals Chemical class 0.000 claims description 6
238000004519 manufacturing process Methods 0.000 claims description 6
150000008044 alkali metal hydroxides Chemical class 0.000 claims description 5
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 4
239000002802 bituminous coal Substances 0.000 claims description 4
ZOCLAPYLSUCOGI-UHFFFAOYSA-M potassium hydrosulfide Chemical group [SH-].[K+] ZOCLAPYLSUCOGI-UHFFFAOYSA-M 0.000 claims description 4
HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical group [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 claims description 4
229910052977 alkali metal sulfide Inorganic materials 0.000 claims description 3
150000004677 hydrates Chemical class 0.000 claims description 3
229940016373 potassium polysulfide Drugs 0.000 claims description 3
DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 claims description 3
239000007795 chemical reaction product Substances 0.000 claims description 2
239000003476 subbituminous coal Substances 0.000 claims description 2
230000036571 hydration Effects 0.000 claims 1
238000006703 hydration reaction Methods 0.000 claims 1
230000007935 neutral effect Effects 0.000 claims 1
238000004064 recycling Methods 0.000 claims 1
229910052701 rubidium Inorganic materials 0.000 claims 1
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims 1
238000005406 washing Methods 0.000 claims 1
239000010803 wood ash Substances 0.000 claims 1
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 34
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 20
238000011084 recovery Methods 0.000 description 17
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
239000001257 hydrogen Substances 0.000 description 11
229910052739 hydrogen Inorganic materials 0.000 description 11
229910052757 nitrogen Inorganic materials 0.000 description 10
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 9
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
238000009835 boiling Methods 0.000 description 7
238000006356 dehydrogenation reaction Methods 0.000 description 7
238000005984 hydrogenation reaction Methods 0.000 description 7
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 6
238000001816 cooling Methods 0.000 description 6
239000012263 liquid product Substances 0.000 description 6
239000008186 active pharmaceutical agent Substances 0.000 description 5
239000003513 alkali Substances 0.000 description 5
239000007864 aqueous solution Substances 0.000 description 5
229910052799 carbon Inorganic materials 0.000 description 5
239000001307 helium Substances 0.000 description 5
229910052734 helium Inorganic materials 0.000 description 5
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 5
230000007062 hydrolysis Effects 0.000 description 5
238000006460 hydrolysis reaction Methods 0.000 description 5
230000008018 melting Effects 0.000 description 5
238000002844 melting Methods 0.000 description 5
230000006641 stabilisation Effects 0.000 description 5
238000011105 stabilization Methods 0.000 description 5
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
230000008901 benefit Effects 0.000 description 4
238000004821 distillation Methods 0.000 description 4
238000002309 gasification Methods 0.000 description 4
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
239000000243 solution Substances 0.000 description 4
241000894007 species Species 0.000 description 4
DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 4
OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical class CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
229910021529 ammonia Inorganic materials 0.000 description 3
239000002956 ash Substances 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
235000011187 glycerol Nutrition 0.000 description 3
239000002994 raw material Substances 0.000 description 3
239000007787 solid Substances 0.000 description 3
239000002904 solvent Substances 0.000 description 3
VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
125000004429 atom Chemical group 0.000 description 2
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
230000008859 change Effects 0.000 description 2
239000010883 coal ash Substances 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
239000012530 fluid Substances 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
239000000463 material Substances 0.000 description 2
GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 description 2
125000001741 organic sulfur group Chemical group 0.000 description 2
BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
239000000376 reactant Substances 0.000 description 2
239000007858 starting material Substances 0.000 description 2
239000000126 substance Substances 0.000 description 2
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
101100447665 Mus musculus Gas2 gene Proteins 0.000 description 1
241000277331 Salmonidae Species 0.000 description 1
HXTWSRHHRRWRDG-UHFFFAOYSA-L [K+].[K+].[S-]SSS[S-] Chemical compound [K+].[K+].[S-]SSS[S-] HXTWSRHHRRWRDG-UHFFFAOYSA-L 0.000 description 1
230000009471 action Effects 0.000 description 1
150000007824 aliphatic compounds Chemical class 0.000 description 1
230000003466 anti-cipated effect Effects 0.000 description 1
239000012223 aqueous fraction Substances 0.000 description 1
238000010504 bond cleavage reaction Methods 0.000 description 1
229910000019 calcium carbonate Inorganic materials 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000002864 coal component Substances 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
239000012084 conversion product Substances 0.000 description 1
238000005336 cracking Methods 0.000 description 1
230000009089 cytolysis Effects 0.000 description 1
230000007423 decrease Effects 0.000 description 1
238000006392 deoxygenation reaction Methods 0.000 description 1
238000010586 diagram Methods 0.000 description 1
FGRVOLIFQGXPCT-UHFFFAOYSA-L dipotassium;dioxido-oxo-sulfanylidene-$l^{6}-sulfane Chemical compound [K+].[K+].[O-]S([O-])(=O)=S FGRVOLIFQGXPCT-UHFFFAOYSA-L 0.000 description 1
ZLCCLBKPLLUIJC-UHFFFAOYSA-L disodium tetrasulfane-1,4-diide Chemical compound [Na+].[Na+].[S-]SS[S-] ZLCCLBKPLLUIJC-UHFFFAOYSA-L 0.000 description 1
238000001035 drying Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000000374 eutectic mixture Substances 0.000 description 1
230000005496 eutectics Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
210000003608 fece Anatomy 0.000 description 1
238000007710 freezing Methods 0.000 description 1
230000008014 freezing Effects 0.000 description 1
239000011521 glass Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
238000011068 loading method Methods 0.000 description 1
239000000155 melt Substances 0.000 description 1
239000003595 mist Substances 0.000 description 1
238000003541 multi-stage reaction Methods 0.000 description 1
239000003345 natural gas Substances 0.000 description 1
229910000069 nitrogen hydride Inorganic materials 0.000 description 1
125000001477 organic nitrogen group Chemical group 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
239000002245 particle Substances 0.000 description 1
230000037361 pathway Effects 0.000 description 1
229910000027 potassium carbonate Inorganic materials 0.000 description 1
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
229910052939 potassium sulfate Inorganic materials 0.000 description 1
235000011151 potassium sulphates Nutrition 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
238000011027 product recovery Methods 0.000 description 1
238000010926 purge Methods 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
230000009467 reduction Effects 0.000 description 1
239000011435 rock Substances 0.000 description 1
238000005201 scrubbing Methods 0.000 description 1
238000007086 side reaction Methods 0.000 description 1
SRRKNRDXURUMPP-UHFFFAOYSA-N sodium disulfide Chemical compound [Na+].[Na+].[S-][S-] SRRKNRDXURUMPP-UHFFFAOYSA-N 0.000 description 1
230000003381 solubilizing effect Effects 0.000 description 1
230000000087 stabilizing effect Effects 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
230000019086 sulfide ion homeostasis Effects 0.000 description 1
150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
238000011144 upstream manufacturing Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/06—Metal salts, or metal salts deposited on a carrier
- C10G29/10—Sulfides
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Wood Science & Technology (AREA)
Combustion & Propulsion (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Carbon And Carbon Compounds (AREA)

JP56056857A 1980-04-15 1981-04-14 炭素質物質の水素化処理 Expired JPS606981B2 (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US14060480A	1980-04-15	1980-04-15
US140604		1981-04-15

Publications (2)

Publication Number	Publication Date
JPS5774389A JPS5774389A (en)	1982-05-10
JPS606981B2 true JPS606981B2 (ja)	1985-02-21

Family

ID=22491987

Family Applications (3)

Application Number	Title	Priority Date	Filing Date
JP56056857A Expired JPS606981B2 (ja)	1980-04-15	1981-04-14	炭素質物質の水素化処理
JP56056858A Expired JPS606982B2 (ja)	1980-04-15	1981-04-14	頁岩の転化による炭化水素、アンモニア、および金属価値物の回収
JP5519481A Pending JPS56157489A (en)	1980-04-15	1981-04-14	Hydrogen treatment of carbonaceous raw material

Family Applications After (2)

Application Number	Title	Priority Date	Filing Date
JP56056858A Expired JPS606982B2 (ja)	1980-04-15	1981-04-14	頁岩の転化による炭化水素、アンモニア、および金属価値物の回収
JP5519481A Pending JPS56157489A (en)	1980-04-15	1981-04-14	Hydrogen treatment of carbonaceous raw material

Country Status (30)

Country	Link
JP (3)	JPS606981B2 (fr)
KR (1)	KR850000672B1 (fr)
AR (1)	AR246302A1 (fr)
AT (1)	AT378198B (fr)
AU (1)	AU540933B2 (fr)
BE (1)	BE888421A (fr)
BR (1)	BR8102305A (fr)
CA (1)	CA1164386A (fr)
CH (1)	CH646453A5 (fr)
DE (1)	DE3115111A1 (fr)
DK (1)	DK170781A (fr)
ES (1)	ES8203951A1 (fr)
FI (1)	FI73458C (fr)
FR (1)	FR2480301B1 (fr)
GB (1)	GB2075542B (fr)
GR (1)	GR74845B (fr)
IL (1)	IL62640A (fr)
IN (2)	IN155056B (fr)
IT (1)	IT1193739B (fr)
MA (1)	MA19118A1 (fr)
NL (1)	NL8101844A (fr)
NO (1)	NO161326C (fr)
NZ (1)	NZ196808A (fr)
OA (1)	OA06785A (fr)
PT (1)	PT72861B (fr)
RO (1)	RO82098B (fr)
SE (1)	SE450491B (fr)
TR (1)	TR22110A (fr)
YU (1)	YU99081A (fr)
ZA (3)	ZA812488B (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4454017A (en) *	1981-03-20	1984-06-12	Rollan Swanson	Process for recovering hydrocarbon and other values from shale oil rock
FI840787A7 (fi) *	1983-03-03	1984-09-04	Rollan Swanson	Raskasjuoksuisten raakaöljyn tislausjätteiden, kuten asfalteenien, hartsien tms. pilkkominen ja hydraus.
JPH0689338B2 (ja) *	1990-02-28	1994-11-09	日揮株式会社	液状炭化水素中の水銀除去法
US7862708B2 (en)	2007-12-13	2011-01-04	Exxonmobil Research And Engineering Company	Process for the desulfurization of heavy oils and bitumens

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3354081A (en) *	1965-09-01	1967-11-21	Exxon Research Engineering Co	Process for desulfurization employing k2s
US3787315A (en) *	1972-06-01	1974-01-22	Exxon Research Engineering Co	Alkali metal desulfurization process for petroleum oil stocks using low pressure hydrogen
US4003823A (en) *	1975-04-28	1977-01-18	Exxon Research And Engineering Company	Combined desulfurization and hydroconversion with alkali metal hydroxides
US4018572A (en) *	1975-06-23	1977-04-19	Rollan Swanson	Desulfurization of fossil fuels
US4119528A (en) *	1977-08-01	1978-10-10	Exxon Research & Engineering Co.	Hydroconversion of residua with potassium sulfide
US4160721A (en) *	1978-04-20	1979-07-10	Rollan Swanson	De-sulfurization of petroleum residues using melt of alkali metal sulfide hydrates or hydroxide hydrates
JPS54141808A (en) *	1978-04-24	1979-11-05	Akira Yamaguchi	Method of controlling porosity of chromic oxide sintered body
AU537070B2 (en) *	1979-08-06	1984-06-07	Swanson, Rollan Dr.	Converting coal to gaseous hydrocarbons and volatile distillates

1981
- 1981-04-14 NZ NZ196808A patent/NZ196808A/xx unknown
- 1981-04-14 CH CH248181A patent/CH646453A5/de not_active IP Right Cessation
- 1981-04-14 NO NO811306A patent/NO161326C/no unknown
- 1981-04-14 DE DE19813115111 patent/DE3115111A1/de active Granted
- 1981-04-14 MA MA19323A patent/MA19118A1/fr unknown
- 1981-04-14 BR BR8102305A patent/BR8102305A/pt unknown
- 1981-04-14 NL NL8101844A patent/NL8101844A/nl not_active Application Discontinuation
- 1981-04-14 JP JP56056857A patent/JPS606981B2/ja not_active Expired
- 1981-04-14 GB GB8111836A patent/GB2075542B/en not_active Expired
- 1981-04-14 DK DK170781A patent/DK170781A/da not_active IP Right Cessation
- 1981-04-14 KR KR1019810001268A patent/KR850000672B1/ko not_active Expired
- 1981-04-14 AT AT0170181A patent/AT378198B/de not_active IP Right Cessation
- 1981-04-14 GR GR64692A patent/GR74845B/el unknown
- 1981-04-14 ZA ZA00812488A patent/ZA812488B/xx unknown
- 1981-04-14 CA CA000375480A patent/CA1164386A/fr not_active Expired
- 1981-04-14 IT IT67514/81A patent/IT1193739B/it active
- 1981-04-14 JP JP56056858A patent/JPS606982B2/ja not_active Expired
- 1981-04-14 FR FR8107441A patent/FR2480301B1/fr not_active Expired
- 1981-04-14 SE SE8102412A patent/SE450491B/sv not_active IP Right Cessation
- 1981-04-14 IN IN401/CAL/81A patent/IN155056B/en unknown
- 1981-04-14 ZA ZA00812483A patent/ZA812483B/xx unknown
- 1981-04-14 BE BE0/204485A patent/BE888421A/fr not_active IP Right Cessation
- 1981-04-14 OA OA57374A patent/OA06785A/fr unknown
- 1981-04-14 ZA ZA00812489A patent/ZA812489B/xx unknown
- 1981-04-14 AU AU69532/81A patent/AU540933B2/en not_active Ceased
- 1981-04-14 JP JP5519481A patent/JPS56157489A/ja active Pending
- 1981-04-14 PT PT72861A patent/PT72861B/pt unknown
- 1981-04-14 AR AR81284977A patent/AR246302A1/es active
- 1981-04-14 ES ES501331A patent/ES8203951A1/es not_active Expired
- 1981-04-14 IL IL62640A patent/IL62640A/xx unknown
- 1981-04-14 FI FI811158A patent/FI73458C/fi not_active IP Right Cessation
- 1981-04-15 RO RO104031A patent/RO82098B/ro unknown
- 1981-04-15 YU YU00990/81A patent/YU99081A/xx unknown
- 1981-04-15 TR TR22110A patent/TR22110A/xx unknown
- 1981-04-16 IN IN408/CAL/81A patent/IN154419B/en unknown

Also Published As

Publication number	Publication date
JPS5774389A (en)	1982-05-10
AU540933B2 (en)	1984-12-06
NO811306L (no)	1981-10-16
AR246302A1 (es)	1994-07-29
NZ196808A (en)	1983-06-14
FR2480301B1 (fr)	1985-11-22
ES501331A0 (es)	1982-04-01
JPS5774387A (en)	1982-05-10
NO161326C (no)	1989-08-02
IN154419B (fr)	1984-10-27
CH646453A5 (de)	1984-11-30
BE888421A (fr)	1981-10-14
YU99081A (en)	1983-04-30
RO82098A (fr)	1984-02-21
NO161326B (no)	1989-04-24
FR2480301A1 (fr)	1981-10-16
NL8101844A (nl)	1981-11-02
KR830005334A (ko)	1983-08-13
GR74845B (fr)	1984-07-12
IT1193739B (it)	1988-08-24
RO82098B (ro)	1984-02-28
FI73458C (fi)	1987-10-09
MA19118A1 (fr)	1981-12-31
IN155056B (fr)	1984-12-29
AU6953281A (en)	1981-10-22
ZA812483B (en)	1982-04-28
FI811158L (fi)	1981-10-16
ATA170181A (de)	1984-11-15
GB2075542A (en)	1981-11-18
DE3115111C2 (fr)	1990-09-27
CA1164386A (fr)	1984-03-27
BR8102305A (pt)	1981-12-08
JPS56157489A (en)	1981-12-04
IT8167514A0 (it)	1981-04-14
PT72861B (en)	1982-04-02
KR850000672B1 (ko)	1985-05-09
DE3115111A1 (de)	1982-02-04
ZA812488B (en)	1982-04-28
ZA812489B (en)	1982-11-24
PT72861A (en)	1981-05-01
JPS606982B2 (ja)	1985-02-21
IL62640A0 (en)	1981-06-29
ES8203951A1 (es)	1982-04-01
TR22110A (tr)	1986-04-21
FI73458B (fi)	1987-06-30
AT378198B (de)	1985-06-25
IL62640A (en)	1984-10-31
OA06785A (fr)	1982-12-31
DK170781A (da)	1981-10-16
SE450491B (sv)	1987-06-29
SE8102412L (sv)	1981-10-16
GB2075542B (en)	1984-01-25

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US7588680B1 (en)	2009-09-15	Desulphurization of petroleum streams using metallic sodium
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US4366045A (en)	1982-12-28	Process for conversion of coal to gaseous hydrocarbons
BE888426R (fr)	1981-07-31	Procede de conversion de charbon en hydrocarbures gazeux,
SU1642955A3 (ru)	1991-04-15	Способ конверсии угл , торфа или древесины в газообразные углеводороды или летучие дистилл ты, или их смеси
CS226017B2 (en)	1984-03-19	Method of converting coal to gaseous hydrocarbons and volatile distillates
KR830002504B1 (ko)	1983-10-27	석탄을 가스상 탄화수소로 전환시키는 방법
CA2791874A1 (fr)	2013-04-10	Systemes et methodes qui integrent un cycle du soufre dans le procede de raffinage d'hydrocarbures pour exploiter le coke du petrole, et systemes et methodes associes de transportet stockage de soufre et de sous-produits de dioxyde de carbone
US2080384A (en)	1937-05-11	Production of sulphur
CA2600037A1 (fr)	2006-09-14	Desulfuration de flux de petrole au moyen de sodium metallique
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Ali et al.	2005	TECHNOECONOMIC ANALYSIS OF AREA II HYDROGEN PRODUCTION-PART
JPS5844107B2 (ja)	1983-09-30	炭化水素類の熱分解方法およびその装置
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