JPS608332A - Sintered porous resin article and its manufacture - Google Patents
Sintered porous resin article and its manufactureInfo
- Publication number
- JPS608332A JPS608332A JP11786783A JP11786783A JPS608332A JP S608332 A JPS608332 A JP S608332A JP 11786783 A JP11786783 A JP 11786783A JP 11786783 A JP11786783 A JP 11786783A JP S608332 A JPS608332 A JP S608332A
- Authority
- JP
- Japan
- Prior art keywords
- melting point
- powder
- synthetic resin
- resin
- porous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920005989 resin Polymers 0.000 title claims abstract description 32
- 239000011347 resin Substances 0.000 title claims abstract description 32
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 238000002844 melting Methods 0.000 claims abstract description 49
- 230000008018 melting Effects 0.000 claims abstract description 49
- 239000000843 powder Substances 0.000 claims abstract description 44
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 18
- 239000000057 synthetic resin Substances 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 5
- 238000010438 heat treatment Methods 0.000 claims description 8
- 239000011148 porous material Substances 0.000 claims description 5
- 229930182556 Polyacetal Natural products 0.000 abstract description 6
- 229920006324 polyoxymethylene Polymers 0.000 abstract description 6
- 229920001519 homopolymer Polymers 0.000 abstract description 3
- 239000002245 particle Substances 0.000 description 10
- -1 polyethylene Polymers 0.000 description 7
- 239000004677 Nylon Substances 0.000 description 5
- 239000011812 mixed powder Substances 0.000 description 5
- 229920001778 nylon Polymers 0.000 description 5
- 229920001903 high density polyethylene Polymers 0.000 description 4
- 239000004700 high-density polyethylene Substances 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- 229920006026 co-polymeric resin Polymers 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000006082 mold release agent Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 235000013334 alcoholic beverage Nutrition 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、相溶性を有する合成樹脂材料を使用して形成
する多孔性樹脂体及びその製造方法に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a porous resin body formed using compatible synthetic resin materials and a method for manufacturing the same.
本発明にか＼る多孔性焼結樹脂ｆｔ−はその多孔性を利
用して特に炉材として使用すれば有効であり、ここに錘
用ＪＦ材と濾過の関係を分析すれば、濾過は固体粒子と
液体との混合物を多孔性物体を介して該混合物゛を通過
させ、該固体粒子の通過を阻止することにより両者を分
離するものであるが、濾過対象物によってＰ拐は例えば
布、網あるいは合成炉材等が使用されてきた。The porous sintered resin ft- according to the present invention is effective especially when used as a furnace material by utilizing its porosity, and if we analyze the relationship between the JF material for weights and filtration, we can see that filtration is solid A mixture of particles and liquid is passed through a porous material to separate the two by blocking the passage of the solid particles. Alternatively, synthetic furnace materials have been used.
ここに該合成ＦＵは通常ポリエチレン等の合成繊維が使
用されＰ布の網目を調整することにより混合液体を通過
させ濾過対象物を操作している。Here, the synthetic FU usually uses synthetic fibers such as polyethylene, and adjusts the mesh of the P cloth to allow the mixed liquid to pass through and manipulate the object to be filtered.
しかし、この様な従来になる炉材は結局は網目が荒く対
象ｐ液によっては微細状の多孔質を具備する炉材を必要
とした。However, such conventional furnace materials had coarse meshes, and depending on the target p-liquid, required furnace materials with fine porosity.
本発明はかかる炉材としての従来技術の欠点に鑑み案出
されたものであってその目的とするところは微細多孔質
を具備する合成闇脂拐による濾過体であって、該合成樹
脂相は相溶性を有し、かつ溶融点の異る同一種類の合成
樹脂粉末体を２種類あるいはそれ以上を混合し、該混合
体の低溶融点を有する合成樹脂粉末体を溶融固化して多
孔質料を形成した多孔性焼結樹脂体及びその製造方法を
提供せんとするものである。The present invention was devised in view of the shortcomings of the prior art as a furnace material, and its object is to provide a filter body made of synthetic dark resin and having fine porosity, the synthetic resin phase being A porous material is produced by mixing two or more types of synthetic resin powders of the same type that are compatible and have different melting points, and melting and solidifying the synthetic resin powders with a low melting point of the mixture. It is an object of the present invention to provide a porous sintered resin body and a method for manufacturing the same.
上記に関る本発明の多孔性焼結樹脂体は、合成樹脂相打
特に相溶性のある樹脂材を使用するもので、例えばポリ
アセタール、ナイロンあるいはポリエチレン等の相打を
使用することによって有効な多孔性焼結樹脂体を構成す
るにある。The porous sintered resin body of the present invention related to the above uses a synthetic resin compound, particularly a compatible resin material, for example, by using a compound compound such as polyacetal, nylon, or polyethylene, effective porous The composition of the sintered resin body is as follows.
即ち、該ポリアセタールの場合にあっては溶融点１７５
℃単重合樹脂と溶融点１６５℃共重合９樹脂の相溶性あ
ふ粉末体混合、物を各々生成し、十分に混和した後加圧
溶融するものである。That is, in the case of the polyacetal, the melting point is 175
A compatible fluffy powder mixture of a C homopolymer resin and a copolymer resin having a melting point of 165 C is produced, mixed thoroughly, and then melted under pressure.
この場合、粉末体は粉砕機により加工しメッシュ粒度に
よって分粒する。In this case, the powder is processed using a pulverizer and sized according to the mesh size.
分粒粉末体は必要とする多孔性焼結樹脂体としての気泡
の空孔率により分粒体を選択して使用することになる。The sized powder is selected and used depending on the porosity of the cells required for the porous sintered resin body.
上記多孔性焼結樹脂体は、他の例として相溶性ナイロン
樹脂即ち溶融点２１２℃の６ナイロンと溶融点２５９℃
の６６ナイロンによる混合粉末体を使用することもでき
、また、相溶性ポリエチレン即ち、溶融点１１０℃の低
密度ポリエチレンと、溶融点１３５℃の高密度ポリエチ
レンによる混合粉末体を使用することもでき、あるいは
異種系統の樹脂材にあっても互に相溶性を有する場合例
えば、溶融点１３５℃高密度ポリエチレンと溶融点１７
５℃ポリグロピレンホモポリマーを使用することもでき
、いずれも相互の融解点が少くとも５℃以上異っている
樹脂であれば有効である。Another example of the porous sintered resin body is a compatible nylon resin, that is, nylon 6, which has a melting point of 212°C, and a melting point of 259°C.
A mixed powder of 66 nylon can also be used, or a mixed powder of compatible polyethylene, that is, low-density polyethylene with a melting point of 110°C and high-density polyethylene with a melting point of 135°C, can also be used. Or, if resin materials of different types are compatible with each other, for example, high-density polyethylene with a melting point of 135℃ and high-density polyethylene with a melting point of 17℃
A 5°C polyglopylene homopolymer can also be used, and any resins whose melting points differ by at least 5°C are effective.
また、多孔性焼結樹脂体として必要に応じては、低密度
、高密度ポリエチレン、及びポリプロピレンの単重合樹
脂や共重合樹脂の４種類の混合粉末体を使用することも
できる。Further, as the porous sintered resin body, a mixed powder body of four types of monopolymer resins and copolymer resins of low density polyethylene, high density polyethylene, and polypropylene can also be used if necessary.
上記に従って多孔性焼結樹脂体の製造方法を説明すれば
、相溶性樹脂は各樹脂毎に粉砕機により粉末体に加工さ
れ、所定粉末粒度毎に区分けされる。To explain the method for producing a porous sintered resin body according to the above, each compatible resin is processed into powder by a pulverizer and divided into powders according to predetermined powder particle sizes.
区分けされた粉末体は粒度の異る２種類を均一に混合し
、所定形状を具備する金型に投入し圧縮加圧する。Two types of powder having different particle sizes are uniformly mixed, and the powder is put into a mold having a predetermined shape and compressed.
加工後加熱炉に投入して金型を加熱してゆくが、この時
、２種類の溶融点の異る樹脂粉末体のうち、溶融点の高
い方の樹脂粉末体に合せて加温し、溶融点より低い温度
に一定時間保持すれば、低融点粉末体が溶融し高融点粉
末体の各外周面に接着浸透する。After processing, it is placed in a heating furnace and the mold is heated. At this time, among the two types of resin powders with different melting points, the resin powder with the higher melting point is heated. When maintained at a temperature lower than the melting point for a certain period of time, the low melting point powder melts and adheres to and penetrates each outer peripheral surface of the high melting point powder.
この時、高融点粉末体の外周面も軟化するため該低融点
粉末体の一部が浸透融着し一体化する。At this time, since the outer circumferential surface of the high melting point powder is also softened, a portion of the low melting point powder is penetrated and fused and integrated.
即ち、低融点粉末体は加熱融解することによって高融点
粉末体に対する接着剤の作用を与えると同時に、低融点
粉末体が高融点粉末体に浸透融着することにより接着効
果を高めることになり、更に゛高融点粉末体の粒度の高
いものを使用することにより粉末体間に起生ずる空孔を
大きく形成することができる。That is, by heating and melting the low melting point powder, it acts as an adhesive to the high melting point powder, and at the same time, the low melting point powder penetrates and fuses with the high melting point powder, thereby increasing the adhesive effect. Furthermore, by using a high melting point powder with a high particle size, it is possible to form large pores between the powder particles.
従って、２種類の混合比率は高融点粉末体の方を高い比
率にすることが必要でちる。Therefore, it is necessary to set the high melting point powder at a higher mixing ratio of the two types.
以下実施例について説明する。Examples will be described below.
処施例１゜
粒子２０〜２５メツシユのポリアセタール単重合樹脂粉
末体ｓｏｇと、粒子１００〜１５０メツンユのポリアセ
タール共重合樹脂粉末体２０ｇを各採取し均一に混合す
る。Processing Example 1 A polyacetal monopolymer resin powder sog having 20 to 25 mesh particles and 20 g of a polyacetal copolymer resin powder having 100 to 150 mesh particles were each taken and mixed uniformly.
混合終了後、金型内径２５ｍｍ、内径高さ６０簡の鉄製
金型の内周面にシリコン離型剤を塗布し該混合粉末体を
充填した後上部より同様に７リコン離型剤を塗布した蓋
をして油圧侵で５ Ｋｆの荷重を与え圧縮した。After mixing, a silicon mold release agent was applied to the inner peripheral surface of an iron mold with an inner diameter of 25 mm and an inner diameter height of 60 mm, and after the mixed powder was filled, a 7 recon mold release agent was similarly applied from the upper part. The lid was closed and compressed by applying a load of 5 Kf using hydraulic compression.
圧縮後金型を加熱炉に挿入し加熱した。After compression, the mold was inserted into a heating furnace and heated.
上昇温度１５５℃迄は急速に加熱し、その後の加熱は１
分につき２ｃｍの速度で１６７℃になる迄行った。Heat rapidly until the temperature rises to 155℃, then heat at 1
This was carried out at a rate of 2 cm per minute until the temperature reached 167°C.
更に１６７℃の炉温でそのまま２０分間保温し、次いで
更に１７４℃になる迄１分間につき０．２℃の速度で加
熱した。The mixture was further kept at an oven temperature of 167°C for 20 minutes, and then further heated at a rate of 0.2°C per minute until the temperature reached 174°C.
炉温か１７４℃になった時点で１０分間保温し、その後
炉内温度が室温になる迄自然降下させ、これによって本
発明になる多孔性焼結樹脂体を得だ。When the furnace temperature reached 174° C., it was kept warm for 10 minutes, and then the temperature inside the furnace was naturally lowered to room temperature, thereby obtaining the porous sintered resin body of the present invention.
空孔率は測定の結果３５．０％を得だ。The porosity was measured to be 35.0%.
該空孔率は、計算重量（体積と比重の積）をＡ１実測重
量をＢとして、−−Ｘ１００＝５孔率としてめた。The porosity was determined by setting the calculated weight (product of volume and specific gravity) to the measured weight of A1 as B, and setting the porosity as --X100=5.
実施例２゜
粒子１５〜２０メツシユの６６ナイロン粉末体７０ｇと
、粒子１２０〜１’６０メツンユの６ナイｊロン粉末体
３０ｇを各採取し均一に混合した。Example 2 70 g of 66 nylon powder with particles of 15 to 20 mesh and 30 g of 6 nylon powder with particles of 120 to 1'60 mesh were each taken and mixed uniformly.
次いで実施例１と同様に７す１ン離型剤を塗布した金型
を使用して該混合粉末体を充填し同一荷重で圧縮した。Next, in the same manner as in Example 1, the mixed powder was filled using a mold coated with a 7S1 mold release agent and compressed under the same load.
蓋をしたあと、加熱炉に挿入し、２０５℃迄１分間につ
いて５℃の加熱速度で加温し更に、１分間２℃の速度で
２１４℃になる迄上昇させた。After the lid was placed, it was inserted into a heating furnace and heated to 205°C at a heating rate of 5°C for 1 minute, and further raised to 214°C at a rate of 2°C for 1 minute.
２１４℃の炉温で２０分間保持し、次いで１分間に０５
℃の速度で２５８℃迄加熱した。Hold at 214°C oven temperature for 20 minutes, then 05°C for 1 minute.
The mixture was heated to 258°C at a rate of 10°C.
更に２５８℃の温度で１ｏ分間保温し、次いで加熱炉の
温度が室温になる迄降下させることにより多孔性焼結樹
脂体を得た。A porous sintered resin body was obtained by further insulating at a temperature of 258°C for 10 minutes, and then lowering the temperature of the heating furnace to room temperature.
測定の結果空孔率２８．３ ％を得だ。The measurement results showed a porosity of 28.3%.
以上の説明の如く、本発明は相溶性を有し、かつ溶融点
の異る同一種類の合成樹脂粉末体の２種類あるいはそれ
以上を混合し、該混合体の低溶融点を有する該合成樹脂
粉末体を溶融固化した多孔性樹脂拐を提供するものであ
るから、該多孔性１ｉｉｊ脂材を炉材として使用すれば
、従来になる布１等に比しはるかに細密な濾過が可能と
なり、飲食水、酒類、廃水等のｒ塊分離に精密さが期待
できるようになると同時に喝好七の効果が得られること
になった。As explained above, the present invention involves mixing two or more types of synthetic resin powders of the same type that are compatible and have different melting points, and the synthetic resin having a low melting point of the mixture. Since it provides a porous resin material made by melting and solidifying a powder, if this porous resin material is used as a furnace material, much finer filtration is possible than with conventional cloths, etc. Precision can now be expected in the separation of bulk water from drinking water, alcoholic beverages, waste water, etc., and at the same time, the effects of the 30-year-old can be obtained.
また、製造上においても加工工程、形状、大きさ等いず
れも比較的簡単に加工できるので価格上有利となった。In addition, since the manufacturing process, shape, size, etc. can be processed relatively easily, it is advantageous in terms of cost.
特許出願人
代理人 弁理士 井 藤 誠
手続補正書
１、事件の表示 特願昭５８−１１７８６７２、発明の
名称 多孔性焼結樹脂体及びその製造方法３、補正をす
る者
事件との関係 特許出願人
加藤発条株式会社
４、献理人〒１００
６、補正の対象
明細書の「特許請求の範囲Ｊ １％力の詳細な説明」の
各欄７、補正の内容
補正の内容
１、 特許請求の範囲を次の通り補正します。Patent Applicant's Representative Patent Attorney Makoto Ito Procedural Amendment 1, Description of the Case Japanese Patent Application No. 1178672/1982, Title of the Invention Porous Sintered Resin Body and Method for Manufacturing the Same 3, Relationship with the Amendment Person's Case Patent Application Person Kato Hatsujo Co., Ltd. 4, Donor 〒100 6, Each column 7 of "Detailed explanation of claims J 1% power" of the specification subject to amendment, Contents of amendment Contents of amendment 1, Patent claims Correct the range as follows.
「（１）相溶性を有しかつ溶融点の異る合成樹脂粉末体
を２種類あるいはその以上混合し、該混合体の低溶融点
を有する合成樹脂粉末体を溶融固化して多孔性材を形成
することを特徴とする多孔性焼結樹脂体。(1) Mix two or more types of synthetic resin powders that are compatible and have different melting points, and melt and solidify the synthetic resin powders with a low melting point of the mixture to form a porous material. A porous sintered resin body characterized by forming.
（２） 相溶性を有し、かつ溶融点の異る合成樹脂で２
種類あるいはそれ以上の粉末体を混合し、更に加圧、圧
縮したあと高溶融点を有する該合成樹脂粉末体の融点以
下に加熱することにより多孔性体を形成することを特徴
とする多孔性焼結樹脂体の製造方法。」２ 明細書第２
頁２０行目の「同一種類の」を削除します。(2) Two synthetic resins that are compatible and have different melting points.
Porous sintered material is characterized in that a porous body is formed by mixing two or more types of powder, pressurizing and compressing the powder, and then heating the powder to a temperature below the melting point of the synthetic resin powder having a high melting point. Method for producing a condensed resin body. ”2 Specification No. 2
Delete "same type" on the 20th line of the page.
３ 明細書の第５頁１９〜２０行目を削除しまず。3. First, delete lines 19-20 on page 5 of the specification.
４、 明細書の第８頁５行目の「同一種類の」を削除し
ます。4. Delete "same type" on page 8, line 5 of the statement.
以 上that's all
Claims (2)
脂粉末体を２種類あるいはそれ以上混合し、該混合体の
低溶融点を有する合成樹脂粉末体を溶融固化して多孔性
材を形成することを特徴とする多孔性焼結樹脂体。(1) Two or more types of synthetic resin powders of the same type that are compatible and have different melting points are mixed, and the synthetic resin powders with a low melting point of the mixture are melted and solidified to form a porous material. A porous sintered resin body characterized by forming a material.
成樹脂で２棟類あるいはそれ以上の粉末体を混合し、更
に加圧、圧縮したあと高溶融点を有する該合成樹脂粉末
体の融点以下に加熱することによ抄多孔性体を形成する
ことを４９徴とする多孔性焼結樹脂体の製造力−法。(2) Synthetic resin powder that has a high melting point after mixing two or more powders of the same type of synthetic resin that are compatible and have different melting points, and further pressurized and compressed. A manufacturing method for a porous sintered resin body, the method of which is to form a porous body by heating the body to a temperature below the melting point of the body.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11786783A JPS608332A (en) | 1983-06-29 | 1983-06-29 | Sintered porous resin article and its manufacture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11786783A JPS608332A (en) | 1983-06-29 | 1983-06-29 | Sintered porous resin article and its manufacture |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS608332A true JPS608332A (en) | 1985-01-17 |
| JPS634864B2 JPS634864B2 (en) | 1988-02-01 |
Family
ID=14722248
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11786783A Granted JPS608332A (en) | 1983-06-29 | 1983-06-29 | Sintered porous resin article and its manufacture |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS608332A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56110741A (en) * | 1980-02-08 | 1981-09-02 | Asahi Chem Ind Co Ltd | Cosintered product |
-
1983
- 1983-06-29 JP JP11786783A patent/JPS608332A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56110741A (en) * | 1980-02-08 | 1981-09-02 | Asahi Chem Ind Co Ltd | Cosintered product |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS634864B2 (en) | 1988-02-01 |
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