JPS61270236A - ガラス繊維用集束剤及びその製造方法 - Google Patents

ガラス繊維用集束剤及びその製造方法

Info

Publication number: JPS61270236A
Authority: JP; Japan
Prior art keywords: starch; acid; added; weight; parts
Prior art date: 1985-05-24
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP60112641A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0463825B2 (de

Inventor

Hiroyuki Karasuno

烏野　博行

Namio Mizuhashi

水橋　波男

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Shikibo Ltd

Shikishima Boseki KK

Original Assignee

Shikibo Ltd

Shikishima Boseki KK

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1985-05-24

Filing date

1985-05-24

Publication date

1986-11-29

1985-05-24 Application filed by Shikibo Ltd, Shikishima Boseki KK filed Critical Shikibo Ltd

1985-05-24 Priority to JP60112641A priority Critical patent/JPS61270236A/ja

1986-11-29 Publication of JPS61270236A publication Critical patent/JPS61270236A/ja

1992-10-13 Publication of JPH0463825B2 publication Critical patent/JPH0463825B2/ja

Status Granted legal-status Critical Current

Links

239000003365 glass fiber Substances 0.000 title claims abstract description 21
238000004519 manufacturing process Methods 0.000 title claims description 7
239000011230 binding agent Substances 0.000 title abstract 4
229920002472 Starch Polymers 0.000 claims abstract description 75
235000019698 starch Nutrition 0.000 claims abstract description 75
239000008107 starch Substances 0.000 claims abstract description 73
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 22
WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract description 16
235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 16
229930195729 fatty acid Natural products 0.000 claims abstract description 16
239000000194 fatty acid Substances 0.000 claims abstract description 16
150000004665 fatty acids Chemical class 0.000 claims abstract description 12
-1 aliphatic fatty acid Chemical class 0.000 claims abstract description 7
239000003795 chemical substances by application Substances 0.000 claims description 28
238000004513 sizing Methods 0.000 claims description 28
238000003756 stirring Methods 0.000 claims description 21
DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 8
239000004615 ingredient Substances 0.000 claims 1
238000005886 esterification reaction Methods 0.000 abstract description 17
230000032050 esterification Effects 0.000 abstract description 16
239000000853 adhesive Substances 0.000 abstract description 12
230000001070 adhesive effect Effects 0.000 abstract description 12
238000013508 migration Methods 0.000 abstract description 8
230000005012 migration Effects 0.000 abstract description 8
230000007062 hydrolysis Effects 0.000 abstract description 4
238000006460 hydrolysis reaction Methods 0.000 abstract description 4
150000007524 organic acids Chemical class 0.000 abstract description 3
239000011369 resultant mixture Substances 0.000 abstract 1
229920000856 Amylose Polymers 0.000 description 24
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
239000007864 aqueous solution Substances 0.000 description 14
238000000034 method Methods 0.000 description 13
229920002261 Corn starch Polymers 0.000 description 12
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 12
239000008120 corn starch Substances 0.000 description 12
229940099112 cornstarch Drugs 0.000 description 12
235000019441 ethanol Nutrition 0.000 description 12
239000000203 mixture Substances 0.000 description 12
239000002904 solvent Substances 0.000 description 10
QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
239000000047 product Substances 0.000 description 9
239000002253 acid Substances 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 8
239000007795 chemical reaction product Substances 0.000 description 8
WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 6
KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
150000008065 acid anhydrides Chemical class 0.000 description 6
239000000243 solution Substances 0.000 description 6
239000007921 spray Substances 0.000 description 6
238000006467 substitution reaction Methods 0.000 description 6
125000001931 aliphatic group Chemical group 0.000 description 5
230000000052 comparative effect Effects 0.000 description 5
238000000354 decomposition reaction Methods 0.000 description 5
FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 4
125000004432 carbon atom Chemical group C* 0.000 description 4
XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
239000011521 glass Substances 0.000 description 4
239000001254 oxidized starch Substances 0.000 description 4
235000013808 oxidized starch Nutrition 0.000 description 4
229920001353 Dextrin Polymers 0.000 description 3
239000004375 Dextrin Substances 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
235000019425 dextrin Nutrition 0.000 description 3
238000001035 drying Methods 0.000 description 3
239000003995 emulsifying agent Substances 0.000 description 3
239000000839 emulsion Substances 0.000 description 3
150000002148 esters Chemical group 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
239000007788 liquid Substances 0.000 description 3
239000000376 reactant Substances 0.000 description 3
230000008961 swelling Effects 0.000 description 3
NOGFHTGYPKWWRX-UHFFFAOYSA-N 2,2,6,6-tetramethyloxan-4-one Chemical compound CC1(C)CC(=O)CC(C)(C)O1 NOGFHTGYPKWWRX-UHFFFAOYSA-N 0.000 description 2
229920001685 Amylomaize Polymers 0.000 description 2
239000005711 Benzoic acid Substances 0.000 description 2
241000196324 Embryophyta Species 0.000 description 2
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
125000002947 alkylene group Chemical group 0.000 description 2
235000010233 benzoic acid Nutrition 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
125000002091 cationic group Chemical group 0.000 description 2
239000004744 fabric Substances 0.000 description 2
239000000835 fiber Substances 0.000 description 2
239000003292 glue Substances 0.000 description 2
239000000314 lubricant Substances 0.000 description 2
239000003921 oil Substances 0.000 description 2
235000019198 oils Nutrition 0.000 description 2
239000012188 paraffin wax Substances 0.000 description 2
238000012545 processing Methods 0.000 description 2
235000019260 propionic acid Nutrition 0.000 description 2
WYVAMUWZEOHJOQ-UHFFFAOYSA-N propionic anhydride Chemical compound CCC(=O)OC(=O)CC WYVAMUWZEOHJOQ-UHFFFAOYSA-N 0.000 description 2
IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 2
239000000126 substance Substances 0.000 description 2
125000001424 substituent group Chemical group 0.000 description 2
GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
239000005708 Sodium hypochlorite Substances 0.000 description 1
HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
235000021355 Stearic acid Nutrition 0.000 description 1
JAWMENYCRQKKJY-UHFFFAOYSA-N [3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-ylmethyl)-1-oxa-2,8-diazaspiro[4.5]dec-2-en-8-yl]-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]methanone Chemical compound N1N=NC=2CN(CCC=21)CC1=NOC2(C1)CCN(CC2)C(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F JAWMENYCRQKKJY-UHFFFAOYSA-N 0.000 description 1
230000021736 acetylation Effects 0.000 description 1
238000006640 acetylation reaction Methods 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
159000000032 aromatic acids Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
238000009835 boiling Methods 0.000 description 1
YHASWHZGWUONAO-UHFFFAOYSA-N butanoyl butanoate Chemical compound CCCC(=O)OC(=O)CCC YHASWHZGWUONAO-UHFFFAOYSA-N 0.000 description 1
239000003818 cinder Substances 0.000 description 1
238000012790 confirmation Methods 0.000 description 1
230000008094 contradictory effect Effects 0.000 description 1
238000001816 cooling Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
238000002845 discoloration Methods 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000006266 etherification reaction Methods 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
235000013312 flour Nutrition 0.000 description 1
150000004820 halides Chemical class 0.000 description 1
239000010514 hydrogenated cottonseed oil Substances 0.000 description 1
239000001341 hydroxy propyl starch Substances 0.000 description 1
125000002768 hydroxyalkyl group Chemical group 0.000 description 1
235000013828 hydroxypropyl starch Nutrition 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
LSACYLWPPQLVSM-UHFFFAOYSA-N isobutyric acid anhydride Chemical compound CC(C)C(=O)OC(=O)C(C)C LSACYLWPPQLVSM-UHFFFAOYSA-N 0.000 description 1
239000000463 material Substances 0.000 description 1
238000002074 melt spinning Methods 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
239000006060 molten glass Substances 0.000 description 1
239000012170 montan wax Substances 0.000 description 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 1
239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 1
238000002360 preparation method Methods 0.000 description 1
239000002994 raw material Substances 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
235000003441 saturated fatty acids Nutrition 0.000 description 1
150000004671 saturated fatty acids Chemical class 0.000 description 1
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
239000001587 sorbitan monostearate Substances 0.000 description 1
235000011076 sorbitan monostearate Nutrition 0.000 description 1
229940035048 sorbitan monostearate Drugs 0.000 description 1
238000009987 spinning Methods 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
239000002344 surface layer Substances 0.000 description 1
FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
238000001291 vacuum drying Methods 0.000 description 1
239000001993 wax Substances 0.000 description 1
238000009941 weaving Methods 0.000 description 1
238000004804 winding Methods 0.000 description 1

Landscapes

Surface Treatment Of Glass Fibres Or Filaments (AREA)

JP60112641A 1985-05-24 1985-05-24 ガラス繊維用集束剤及びその製造方法 Granted JPS61270236A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP60112641A JPS61270236A (ja)	1985-05-24	1985-05-24	ガラス繊維用集束剤及びその製造方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP60112641A JPS61270236A (ja)	1985-05-24	1985-05-24	ガラス繊維用集束剤及びその製造方法

Publications (2)

Publication Number	Publication Date
JPS61270236A true JPS61270236A (ja)	1986-11-29
JPH0463825B2 JPH0463825B2 (de)	1992-10-13

Family

ID=14591813

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP60112641A Granted JPS61270236A (ja)	1985-05-24	1985-05-24	ガラス繊維用集束剤及びその製造方法

Country Status (1)

Country	Link
JP (1)	JPS61270236A (de)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2004029355A1 (ja) *	2002-09-30	2004-04-08	Asahi Fiber Glass Company, Limited	ガラス繊維ヤーン用集束剤及びそれを用いたガラス繊維ヤーン
JP2015117452A (ja) *	2013-12-20	2015-06-25	松本油脂製薬株式会社	繊維用経糸糊剤及びその応用

1985
- 1985-05-24 JP JP60112641A patent/JPS61270236A/ja active Granted

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2004029355A1 (ja) *	2002-09-30	2004-04-08	Asahi Fiber Glass Company, Limited	ガラス繊維ヤーン用集束剤及びそれを用いたガラス繊維ヤーン
CN100412019C (zh) *	2002-09-30	2008-08-20	上海宏联电子材料有限公司	玻璃纤维纱线用集束剂以及采用该集束剂的玻璃纤维纱线
JP2015117452A (ja) *	2013-12-20	2015-06-25	松本油脂製薬株式会社	繊維用経糸糊剤及びその応用

Also Published As

Publication number	Publication date
JPH0463825B2 (de)	1992-10-13

Publication	Publication Date	Title
US6960627B2 (en)	2005-11-01	Partially cross-linked polyvinyl alcohol
KR930001319B1 (ko)	1993-02-25	유기실록산 함유 다당류
US6670470B1 (en)	2003-12-30	Modified starch
CA2276329C (en)	2007-02-13	Hydroxyalkylated starch ester and preparation and use thereof
RU2406705C2 (ru)	2010-12-20	R-, e- и ecr-стекловолокна с водной шлихтой
CZ283879B6 (cs)	1998-06-17	Lepicí tužka na bázi etheru škrobu
US4329181A (en)	1982-05-11	Method for preparing alkaline corrugating adhesive
US3931422A (en)	1976-01-06	Polyester/starch paper sizing
US4241136A (en)	1980-12-23	Glass fiber size composition and process
JPH02212374A (ja)	1990-08-23	無機繊維組成物の製造方法
JPS6392677A (ja)	1988-04-23	完全に加水分解した冷水不溶性ポリビニルアルコ−ル成分を有する急速硬化性でんぷんベ−ス段ボ−ル用接着剤組成物
US3981833A (en)	1976-09-21	Starch/polyester resin composition
JPS62280201A (ja)	1987-12-05	繊維糊剤
DE68917577T2 (de)	1994-12-15	Stärke-Klebstoff von hoher Konzentration.
JPS61270236A (ja)	1986-11-29	ガラス繊維用集束剤及びその製造方法
CA1165059A (en)	1984-04-10	Preparation of a starch glue from native starch
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US4269972A (en)	1981-05-26	Process for producing cellulose diacetate having improved resistance to delustering phenomenon in hot water
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US2640816A (en)	1953-06-02	Preparation of solutions of polyvinyl alcohol-acetate
JPS62501A (ja)	1987-01-06	セルロ−スアセテ−トの製造方法
JPS58148747A (ja)	1983-09-03	エステル化木材の製造法
JP3949746B2 (ja)	2007-07-25	硝子繊維集束剤用化工澱粉
JP2000511588A (ja)	2000-09-05	セルロースアセテートの製造方法